WO2013021830A1 - Ruban adhésif - Google Patents

Ruban adhésif Download PDF

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Publication number
WO2013021830A1
WO2013021830A1 PCT/JP2012/069014 JP2012069014W WO2013021830A1 WO 2013021830 A1 WO2013021830 A1 WO 2013021830A1 JP 2012069014 W JP2012069014 W JP 2012069014W WO 2013021830 A1 WO2013021830 A1 WO 2013021830A1
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WO
WIPO (PCT)
Prior art keywords
pressure
layer
sensitive adhesive
adhesive tape
adhesive layer
Prior art date
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PCT/JP2012/069014
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English (en)
Japanese (ja)
Inventor
良平 澤▲崎▼
翔 内田
健太 山下
林　圭治
Original Assignee
日東電工株式会社
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Application filed by 日東電工株式会社 filed Critical 日東電工株式会社
Publication of WO2013021830A1 publication Critical patent/WO2013021830A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature

Definitions

  • the present invention relates to an adhesive tape. More specifically, the present invention relates to a pressure-sensitive adhesive tape that does not generate stamp marks due to local pressure load during manufacturing, storage, transportation, etc., and that does not show uneven appearance due to the stamp marks when fed into a sheet. .
  • the pressure-sensitive adhesive tape is usually locally subjected to pressure load during production, storage and transportation.
  • pressure load for example, a local pressure load due to contact with a coating roll (roller) used in a coating process at the time of production, or a roll of adhesive tape is piled up during storage and transportation.
  • the local pressure load by etc. is mentioned.
  • the appearance of the adhesive tape differs between the loaded part (load part) and the unloaded part (non-load part). This difference in appearance is visually recognized as a so-called imprint.
  • the pressure-sensitive adhesive tape is fed out in a sheet form from the pressure-sensitive adhesive tape of the roll body where the pressing marks are visually recognized, the pressing marks are directly recognized as uneven appearance of the sheet body.
  • the adhesive tape of the sheet body is used as a surface protective film for an optical member such as a prism sheet (see Patent Document 1), and after being attached to the adherend, it is used for an appearance inspection of the adherend. There is a case. When such an appearance inspection is performed, the presence of uneven appearance on the surface protective film is a fatal defect. Furthermore, when performing the appearance inspection as described above, high transparency is required for the surface protective film, and the haze of the surface protective film needs to be small.
  • the present invention has been made in order to solve the above-described conventional problems.
  • the object of the present invention is to prevent the occurrence of stamp marks caused by local pressure loads during production, storage and transportation, and the like. It is an object of the present invention to provide a novel pressure-sensitive adhesive tape that does not show unevenness in appearance due to the imprinted marks when drawn out and has high transparency.
  • the adhesive tape of the present invention is An adhesive tape having a back layer as one outermost layer and an adhesive layer as the other outermost layer,
  • the arithmetic mean low wavelength component roughness of the surface of the back layer is Ra 2 ⁇ m
  • the storage elastic modulus at 23 ° C. at a frequency of 10 Hz of the adhesive layer is G′Pa
  • the thickness of the adhesive layer is d ⁇ m
  • B d / (Ra2 ⁇ G ′) is 20 ⁇ 10 ⁇ 6 Pa ⁇ 1 or more.
  • the surface of the pressure-sensitive adhesive layer is arithmetically applied at a portion where a load of 0.07 kgf / mm 2 is applied and a portion where the load is not applied.
  • the difference in average low wavelength component roughness Ra2 is 0.02 ⁇ m or less.
  • the arithmetic average low wavelength component roughness Ra2 of the surface of the back layer is 1.0 ⁇ m or less.
  • the storage elastic modulus at 23 ° C. at a frequency of 10 Hz of the pressure-sensitive adhesive layer is G ′ of 1.0 ⁇ 10 5 to 1.0 ⁇ 10 7 Pa.
  • the thickness d of the pressure-sensitive adhesive layer is greater than 0 ⁇ m and not greater than 30 ⁇ m.
  • the pressure-sensitive adhesive tape of the present invention has a total light transmittance of 70% or more.
  • the adhesive tape of the present invention has a haze of 40% or less.
  • the pressure-sensitive adhesive tape of the present invention is a roll body, and the back layer and the pressure-sensitive adhesive layer are laminated without using a separator.
  • a novel pressure-sensitive adhesive tape having high transparency can be provided.
  • the adhesive tape of the present invention has a back layer as one outermost layer and an adhesive layer as the other outermost layer.
  • the pressure-sensitive adhesive tape of the present invention may have any other suitable layer as necessary as long as it has a back layer as one outermost layer and a pressure-sensitive adhesive layer as the other outermost layer.
  • FIG. 1 is a schematic cross-sectional view of an adhesive tape according to a preferred embodiment of the present invention.
  • the pressure-sensitive adhesive tape 100 includes a back layer 1 and a pressure-sensitive adhesive layer 2.
  • the pressure-sensitive adhesive tape of the present invention has a relatively low arithmetic average low wavelength component roughness Ra2 on the surface of the back layer (that is, the surface of the back layer is reasonably smooth), and the pressure-sensitive adhesive layer has a frequency of 10 ° C. at 23 ° C.
  • the storage elastic modulus G ′ is relatively small (that is, the pressure-sensitive adhesive layer is moderately soft), and the thickness d of the pressure-sensitive adhesive layer is relatively large (that is, the pressure-sensitive adhesive layer is moderately thick). That is, the pressure-sensitive adhesive tape of the present invention has an arithmetic average low-wavelength component roughness Ra of 2 ⁇ m on the surface of the back layer, a storage elastic modulus at 23 ° C.
  • B d / (Ra2 ⁇ G ′) is 20 ⁇ 10 ⁇ 6 Pa ⁇ 1 or more, preferably 40 ⁇ 10 ⁇ 6 Pa ⁇ 1 or more, and more Preferably, it is 60 ⁇ 10 ⁇ 6 Pa ⁇ 1 or more, and more preferably 80 ⁇ 10 ⁇ 6 Pa ⁇ 1 or more.
  • the surface of the back layer is moderately smooth, the pressure-sensitive adhesive layer is moderately soft, and the pressure-sensitive adhesive layer is moderately thick. Therefore, for example, when the roll body is in a state where the back layer and the pressure-sensitive adhesive layer are in close contact with each other by winding, even if a local pressure load is applied, as shown in FIG. Since the moderately soft and moderately thick adhesive layer is already in an adequately uniform state on the smooth surface, the back layer at the load part (load part) and the non-load part (non-load part) There is no difference in the contact state between the adhesive layer and the pressure-sensitive adhesive layer, and no trace is generated.
  • the back layer If the surface of the back layer is not smooth, the adhesive layer is hard, or the adhesive layer is thin, the back layer at the load part (load part) and non-load part (non-load part) A difference occurs in the contact state between the adhesive layer and the pressure-sensitive adhesive layer, and a trace is generated.
  • the pressure-sensitive adhesive tape of the present invention is not applied to a portion where the load is applied (load portion) when a load of 0.07 kgf / mm 2 is locally applied in a state where the back layer and the pressure-sensitive adhesive layer are in close contact with each other.
  • the difference in the arithmetic mean low wavelength component roughness Ra2 of the surface (glue surface) of the pressure-sensitive adhesive layer at the portion (non-loading portion) is preferably 0.02 ⁇ m or less, more preferably 0.015 ⁇ m or less, More preferably, it is 0.01 micrometer or less.
  • the thickness of the pressure-sensitive adhesive tape of the present invention can be set to any appropriate thickness depending on the application. Typically, it is 20 to 200 ⁇ m.
  • the adhesive tape of the present invention has a total light transmittance of preferably 70% or more, more preferably 80% or more, and further preferably 85% or more.
  • the total light transmittance of the pressure-sensitive adhesive tape of the present invention is 70% or more, for example, it can be preferably used as a surface protective film for an adherend to be used for appearance inspection.
  • the adhesive tape of the present invention has a haze of preferably 40% or less, more preferably 30% or less, and further preferably 20% or less.
  • haze of the pressure-sensitive adhesive tape of the present invention is 40% or less, high transparency can be secured, and for example, it can be very preferably used as a surface protective film for an adherend to be subjected to appearance inspection.
  • the pressure-sensitive adhesive tape of the present invention is preferably a roll body, and the back layer and the pressure-sensitive adhesive layer are laminated without using a separator.
  • the pressure-sensitive adhesive tape of the present invention does not generate any traces caused by local pressure load during production, storage, transportation, etc., and has the effect that no unevenness of appearance due to the traces is observed when the sheet is fed into a sheet.
  • such an effect is particularly effective in practical use when the roll body as described above is employed.
  • the effects as described above can be exhibited even when no separator is present between the back layer and the pressure-sensitive adhesive layer. That is, no separator is required, leading to cost reduction in the production of the adhesive tape.
  • the thickness of a back surface layer can employ
  • the thickness of the back layer is preferably 1 to 200 ⁇ m, more preferably 2 to 100 ⁇ m.
  • the arithmetic average low wavelength component roughness Ra2 of the surface of the back layer is preferably 1.0 ⁇ m or less, more preferably 0.5 ⁇ m or less, and even more preferably 0.3 ⁇ m or less.
  • the back layer surface becomes reasonably smooth, which is a local pressure load during manufacturing, storage and transportation. The resulting traces are less likely to occur, and when the sheet is fed out into a sheet, uneven appearance due to the traces is less likely to be seen.
  • Arbitrary appropriate means can be employ
  • a single resin use a resin with a uniform crystal structure and size, use an amorphous material, use a material with a low melt viscosity, select molding conditions that are difficult to apply shear stress, and optionally after film formation For example, the material may be applied.
  • the back layer may be a single layer or a laminate of two or more layers.
  • the back layer is preferably 2 to 5 layers, more preferably 2 to 3 layers.
  • the back layer is only one layer, the production of the adhesive tape can be facilitated.
  • the back layer is a laminate of two or more layers, the function can be divided by each layer.
  • the back surface layer is composed of a plurality of layers, the interface between these layers may not be clear. Therefore, after the back surface layer is formed, the layers constituting the back surface layer may not be clearly separated. is there.
  • the back layer can be composed of any suitable material.
  • a thermoplastic resin is a thermoplastic resin.
  • the content of the thermoplastic resin in the back layer is preferably 50% by weight or more, more preferably 70 to 100% by weight, still more preferably 90 to 100% by weight, and particularly preferably 95 to 100% by weight. %, Most preferably substantially 100% by weight.
  • thermoplastic resin any appropriate one can be adopted as long as the film can be formed by melt extrusion.
  • thermoplastic resins include polyolefin resins such as propylene-based polymers, polyethylene, olefin-based thermoplastic elastomers (TPO), and modified products thereof; ⁇ -olefins and vinyl compounds (for example, vinyl acetate, (meth) acrylic). Acid ester), polyamides, polyesters, polycarbonates, polyurethanes, polyvinyl chlorides, and the like.
  • TPO olefin-based thermoplastic elastomers
  • vinyl compounds for example, vinyl acetate, (meth) acrylic.
  • Acid ester polyamides
  • polyesters polycarbonates
  • polyurethanes polyvinyl chlorides
  • propylene-based polymer include homopolypropylene, block polypropylene, and random polypropylene.
  • the structure of the homopolypropylene may be isotactic, atactic, or syndiotactic.
  • the polyethylene when polyethylene is used as the thermoplastic resin, the polyethylene may be any of low density polyethylene, medium density polyethylene, and high density polyethylene.
  • the thermoplastic resin may be only one kind or two or more kinds. Examples of the combined form of two or more include a blend form and a copolymer form.
  • thermoplastic resin may be used.
  • specific examples of commercially available thermoplastic resins include trade name “PF380A” (block polypropylene) manufactured by Sun Allomer.
  • the back layer may contain any appropriate other resin as long as the effects of the present invention are not impaired.
  • the back layer may contain any appropriate additive as required.
  • Additives that can be contained in the back layer include, for example, ultraviolet absorbers, heat stabilizers, fillers, lubricants, colorants (such as dyes), antioxidants, anti-spot agents, anti-blocking agents, foaming agents, Polyethyleneimine etc. are mentioned.
  • the type, number and amount of additives contained in the back layer can be appropriately set depending on the purpose.
  • the ultraviolet absorber examples include benzotriazole compounds, benzophenone compounds, benzoate compounds, and the like. Any appropriate content can be adopted as the content of the ultraviolet absorber as long as it does not bleed out during the production of the pressure-sensitive adhesive tape. Typically, the amount is preferably 0.01 to 5 parts by weight with respect to 100 parts by weight of the resin in the back layer.
  • the heat stabilizer examples include hindered amine compounds, phosphorus compounds, and cyanoacrylate compounds. Any appropriate content can be adopted as the content of the heat-resistant stabilizer as long as it does not bleed out during the production of the pressure-sensitive adhesive tape. Typically, the amount is preferably 0.01 to 5 parts by weight with respect to 100 parts by weight of the resin in the back layer.
  • the filler examples include inorganic fillers such as talc, titanium oxide, calcium oxide, magnesium oxide, zinc oxide, calcium carbonate, silica, clay, mica, barium sulfate, whisker, and magnesium hydroxide.
  • the average particle size of the filler is preferably 0.1 to 10 ⁇ m.
  • the content of the filler is preferably 1 to 200 parts by weight with respect to 100 parts by weight of the resin in the back layer.
  • any appropriate other layer may be included in the back layer.
  • examples of such other layers include a surface layer (also referred to as a release layer).
  • the surface layer may be included on the surface side of the back layer opposite to the surface on which the pressure-sensitive adhesive layer is provided.
  • the surface layer When the surface layer is included in the back layer, the surface layer is laminated with the pressure-sensitive adhesive layer when the pressure-sensitive adhesive tape of the present invention is stored in a roll body, for example. Therefore, the surface layer is required to have good releasability from the pressure-sensitive adhesive layer, and preferably the surface layer contains a release agent. If the surface layer includes a release agent, for example, the surface protective film of the present invention is stored in a roll form, and thus the surface layer and the pressure-sensitive adhesive layer are prevented from sticking in a state where the surface protective films overlap each other. be able to. Moreover, it is not necessary to cover the surface layer with a separator layer.
  • the release agent for example, a silicone release agent, a fluorine release agent, a long chain alkyl release agent, a fatty acid amide release agent, or the like may be employed.
  • the thickness of the surface layer is preferably 2 ⁇ m to 10 ⁇ m, more preferably 2 ⁇ m to 8 ⁇ m, and particularly preferably 2 ⁇ m to 5 ⁇ m.
  • the thickness of the surface layer is less than 2 ⁇ m, the function as the surface layer may not be sufficiently exhibited.
  • the thickness of the surface layer is greater than 10 ⁇ m, the mechanical properties of the surface layer affect the mechanical properties of the entire pressure-sensitive adhesive tape, and the handling of the pressure-sensitive adhesive tape may be deteriorated.
  • thermoplastic resin can be adopted as the main forming material of the surface layer.
  • the main material for forming the surface layer is, for example, a polyolefin resin such as propylene-based polymer, polyethylene, olefin-based thermoplastic elastomer (TPO) or a modified product thereof; ⁇ -olefin and a vinyl compound (for example, vinyl acetate, (meth) acrylic) Acid ester), polyamides, polyesters, polycarbonates, polyurethanes, polyvinyl chlorides, and the like.
  • TPO olefin-based thermoplastic elastomer
  • vinyl compound for example, vinyl acetate, (meth) acrylic) Acid ester
  • the structure of the homopolypropylene may be isotactic, atactic, or syndiotactic.
  • the polyethylene when polyethylene is used as the thermoplastic resin, the polyethylene may be any of low density polyethylene, medium density polyethylene, and high density polyethylene.
  • the thermoplastic resin may be only one kind or two or more kinds. Examples of the combined form of two or more include a blend form and a copolymer form.
  • thermoplastic resin may be used.
  • specific examples of commercially available thermoplastic resins include trade name “PF380A” (block polypropylene) manufactured by Sun Allomer.
  • the surface layer may contain any appropriate additive as required.
  • the thickness d of the pressure-sensitive adhesive layer is preferably greater than 0 ⁇ m and 30 ⁇ m or less, more preferably 0.1 to 25 ⁇ m, even more preferably 1 to 20 ⁇ m, and particularly preferably 3 to 15 ⁇ m.
  • the pressure-sensitive adhesive layer falls within the above range, the pressure-sensitive adhesive layer becomes moderately thick, and it is difficult to generate a trace caused by a local pressure load during production, storage, and transportation. When it is drawn out, it becomes difficult to see the uneven appearance due to the imprint.
  • the pressure-sensitive adhesive layer may be a single layer or a laminate of two or more layers.
  • the storage elastic modulus G ′ at 23 ° C. at a frequency of 10 Hz of the pressure-sensitive adhesive layer is preferably 1.0 ⁇ 10 5 to 1.0 ⁇ 10 7 Pa, more preferably 2.0 ⁇ 10 5 to 5.0. ⁇ 10 6 Pa, more preferably 5.0 ⁇ 10 5 to 2.0 ⁇ 10 6 Pa.
  • the pressure-sensitive adhesive layer becomes moderately soft, resulting from local pressure load during production, storage, transportation, etc. This makes it difficult to generate an imprint mark, and when the sheet is fed out into a sheet, uneven appearance due to the imprint mark is difficult to be seen.
  • any appropriate means can be adopted as means for keeping the storage elastic modulus G ′ at 23 ° C. at a frequency of 10 Hz of the pressure-sensitive adhesive layer within the above range.
  • polymer molecular design selection of monomer type
  • hard segment content for styrene elastomers, styrene content and crystallinity
  • additives include softeners and tackifiers.
  • the storage elastic modulus G ′ in the present invention is -50 ° C. to 100 ° C. at a frequency of 10 Hz and a heating rate of 5 ° C./min using a dynamic viscoelasticity spectrum measuring instrument (ARES manufactured by Rheometric Scientific). The value measured in the range.
  • the laminate is obliquely cut using, for example, SAICAS (Surface And Interfacial Cutting Analysis System) or the like, and the cut surface is micro-hard such as a nano indenter. A plurality of locations may be measured using a measuring device.
  • Arbitrary appropriate adhesive can be employ
  • adhesives include rubber adhesives, acrylic adhesives, and silicone adhesives.
  • thermoplastic adhesive can also be used.
  • the material constituting the thermoplastic pressure-sensitive adhesive include any appropriate styrene block copolymer and acrylic thermoplastic resin as the pressure-sensitive adhesive material.
  • styrenic block copolymer examples include styrenic AB type diblock copolymers such as styrene-ethylene-butylene copolymer (SEB); styrene-butadiene-styrene copolymer (SBS), SBS Hydrogenated products (styrene-ethylene-butylene-styrene copolymer (SEBS)), styrene-isoprene-styrene copolymers (SIS), SIS hydrogenated products (styrene-ethylene-propylene-styrene copolymers (SEPS)) ), Styrene-ABA type triblock copolymer such as styrene-isobutylene-styrene copolymer (SIBS); styrene type ABAB type tetrablock copolymer such as styrene-butadiene-styrene-butad
  • the content of the styrene block structure in the styrenic block copolymer is preferably 5 to 40% by weight, more preferably 7 to 30% by weight, and particularly preferably 9 to 20% by weight.
  • the content of the styrene block structure is less than 5% by weight, adhesive residue due to insufficient cohesive force of the pressure-sensitive adhesive layer is likely to occur.
  • there is more content rate of a styrene block structure than 40 weight% an adhesive layer becomes hard and there exists a possibility that favorable adhesiveness cannot be obtained with respect to a rough surface.
  • the content of the structural unit derived from butylene in the ethylene-butylene block structure is preferably 50% by weight or more, more preferably 60% by weight or more, particularly It is preferably 70% by weight or more, and most preferably 70 to 90% by weight.
  • the content ratio of the structural unit derived from butylene is in such a range, a pressure-sensitive adhesive layer that is excellent in wettability and adhesiveness and can adhere well to a rough surface can be obtained.
  • acrylic thermoplastic resin examples include polymethyl methacrylate-polybutyl acrylate-polymethyl methacrylate copolymer (PMMA-PBA-PMMA copolymer); polybutyl acrylate having a carboxylic acid as a functional group. And the type of PMMA-functional group-containing PBA-PMMA copolymer.
  • a commercially available product may be used as the acrylic thermoplastic resin.
  • Specific examples of commercially available acrylic thermoplastic resins include trade name “NABSTAR” manufactured by Kaneka Co., Ltd., and trade name “KULARITY” (“LA polymer”) manufactured by Kuraray Co., Ltd.
  • the pressure-sensitive adhesive layer may contain other components as necessary.
  • other components include olefin resins; silicone resins; liquid acrylic copolymers; polyethyleneimines; fatty acid amides; phosphate esters;
  • the type, number and amount of other components contained in the pressure-sensitive adhesive layer can be appropriately set according to the purpose.
  • additives examples include tackifiers; softeners; anti-aging agents; hindered amine light stabilizers; ultraviolet absorbers; heat stabilizers; filling with calcium oxide, magnesium oxide, silica, zinc oxide, titanium oxide, and the like. Agent or pigment; and the like.
  • Tackifier formulation is effective in improving adhesive strength.
  • the amount of the tackifier is appropriately determined to be any appropriate amount depending on the adherend in order to avoid the occurrence of the adhesive residue problem due to the decrease in cohesive force.
  • the amount is preferably 0 to 40 parts by weight, more preferably 0 to 30 parts by weight, and still more preferably 0 to 10 parts by weight with respect to 100 parts by weight of the resin material forming the pressure-sensitive adhesive.
  • tackifiers examples include hydrocarbon-based tackifier resins, terpene-based tackifier resins, rosin-based tackifier resins, and phenol-based tackifier resins.
  • a tackifier may be used independently and may use 2 or more types together.
  • hydrocarbon-based tackifying resins examples include aliphatic hydrocarbon resins, aromatic hydrocarbon resins (for example, xylene resins), aliphatic cyclic hydrocarbon resins, aliphatic / aromatic petroleum resins (for example, Styrene-olefin copolymers), aliphatic / alicyclic petroleum resins, hydrogenated hydrocarbon resins, coumarone resins, coumarone-indene resins, and the like.
  • terpene-based tackifier resins include terpene resins such as ⁇ -pinene polymers and ⁇ -pinene polymers; modified terpenes obtained by modifying terpene resins (eg, phenol modification, aromatic modification, hydrogenation modification, etc.) Resin (for example, terpene-phenol resin, styrene-modified terpene resin, hydrogenated terpene resin, etc.);
  • rosin-based tackifier resins examples include unmodified rosins such as gum rosin and wood rosin (raw rosin); modified rosins modified by hydrogenation, disproportionation, polymerization, etc. (for example, hydrogenated rosin, non-modified rosin) Averaged rosin, polymerized rosin, other chemically modified rosins, etc.); other various rosin derivatives: and the like.
  • phenolic tackifier resin examples include resol type or novolac type alkylphenol.
  • tackifier hydrogenated tackifiers such as “Arcon P-125” manufactured by Arakawa Chemical Industries, Ltd. are preferable from the viewpoint of peelability and weather resistance.
  • tackifier hydrogenated tackifiers such as “Arcon P-125” manufactured by Arakawa Chemical Industries, Ltd. are preferable from the viewpoint of peelability and weather resistance.
  • what is marketed as a blend with an olefin resin and a thermoplastic elastomer can also be used for a tackifier.
  • Softener formulation is effective in improving adhesive strength.
  • the softening agent include low molecular weight diene polymers, polyisobutylene, hydrogenated polyisoprene, hydrogenated polybutadiene, and derivatives thereof.
  • the derivative include those having an OH group or a COOH group at one or both ends.
  • Specific examples include hydrogenated polybutadiene diol, hydrogenated polybutadiene monool, hydrogenated polyisoprene diol, and hydrogenated polyisoprene monool.
  • hydrogenated products of diene polymers such as hydrogenated polybutadiene and hydrogenated polyisoprene, olefinic softeners, and the like are preferable.
  • Specific examples include “Kuraprene LIR-200” manufactured by Kuraray Co., Ltd. These softeners may be used alone or in combination of two or more.
  • the molecular weight of the softening agent can be appropriately set to any appropriate amount. If the molecular weight of the softening agent is too small, it may cause the material transfer from the pressure-sensitive adhesive layer to the adherend or heavy release, while if the molecular weight of the softening agent is too large, the effect of improving the adhesive force Therefore, the number average molecular weight of the softener is preferably 5000 to 100,000, more preferably 10,000 to 50,000.
  • any appropriate amount can be adopted as the addition amount. If the amount of the softener added is too large, the adhesive residue tends to increase at high temperatures and when exposed outdoors. Therefore, preferably 100 parts by weight or less with respect to 100 parts by weight of the resin material forming the adhesive, More preferably, it is 20 weight part or less, More preferably, it is 10 weight part or less. When the addition amount of the softening agent exceeds 40 parts by weight with respect to 100 parts by weight of the resin material forming the pressure-sensitive adhesive, the adhesive residue becomes remarkable under outdoor exposure in a high temperature environment.
  • the ultraviolet absorber examples include benzotriazole compounds, benzophenone compounds, benzoate compounds, and the like. Any appropriate content can be adopted as the content of the ultraviolet absorber as long as it does not bleed out during the production of the pressure-sensitive adhesive tape. Typically, it is 0.01 to 5 parts by weight with respect to 100 parts by weight of the adhesive.
  • heat stabilizer examples include hindered amine compounds, phosphorus compounds, and cyanoacrylate compounds. Any appropriate content can be adopted as the content of the heat-resistant stabilizer as long as it does not bleed out during the production of the pressure-sensitive adhesive tape. Typically, it is 0.01 to 5 parts by weight with respect to 100 parts by weight of the adhesive.
  • the pressure-sensitive adhesive layer may be surface-treated on one side or both sides as necessary.
  • Examples of the surface treatment include corona discharge treatment, ultraviolet irradiation treatment, flame treatment, plasma treatment, and sputter etching treatment.
  • the pressure-sensitive adhesive layer can contain any appropriate additive as required.
  • additives that can be contained in the pressure-sensitive adhesive layer include fillers, colorants (dyes, etc.), antioxidants, metal chelate compounds, crosslinking agents (for example, polyfunctional isocyanates, polyfunctional amines, polyfunctional alcohols, etc.) ) And the like.
  • the type, number and amount of additives contained in the pressure-sensitive adhesive layer can be appropriately set according to the purpose.
  • the amount of the additive is preferably 5% by weight or less, more preferably 1% by weight or less, based on the entire pressure-sensitive adhesive layer.
  • the filler examples include inorganic fillers such as talc, titanium oxide, calcium oxide, magnesium oxide, zinc oxide, calcium carbonate, silica, clay, mica, barium sulfate, whisker, and magnesium hydroxide.
  • the average particle size of the filler is preferably 0.1 ⁇ m to 10 ⁇ m.
  • the pressure-sensitive adhesive layer may be temporarily protected with a separator or the like until it is put to practical use.
  • the adhesive tape of this invention can be obtained by arbitrary appropriate manufacturing methods.
  • the pressure-sensitive adhesive tape of the present invention includes, for example, a method of coextruding the back layer and the pressure-sensitive adhesive layer constituting the pressure-sensitive adhesive tape of the present invention (manufacturing method 1), and a method of hot-melt coating the pressure-sensitive adhesive layer on the back layer (manufacturing).
  • Examples of the method 2) include a method of applying an organic solvent coating solution in which the pressure-sensitive adhesive layer is dissolved or an emulsion liquid in which the pressure-sensitive adhesive layer is dispersed in water on the back layer (production method 3).
  • thermoplastic adhesive is preferably used as an adhesive which comprises an adhesive layer.
  • the co-extrusion method can be performed by using a back layer forming material and a pressure-sensitive adhesive layer forming material in accordance with an inflation method, a T-die method, or the like, using an extruder and a co-extrusion die. .
  • an easy adhesion treatment is performed on the surface on which the pressure-sensitive adhesive layer is formed, that is, the back surface layer.
  • the easy adhesion treatment include corona discharge treatment, itro treatment (silicic acid flame treatment), and anchor coat treatment.
  • the rubber adhesive, the acrylic adhesive, and the silicone adhesive are preferably used as the adhesive constituting the adhesive layer.
  • the said organic solvent can employ
  • the organic solvent include aromatic hydrocarbon solvents such as toluene and xylene; aliphatic carboxylic acid ester solvents such as ethyl acetate; aliphatic hydrocarbon solvents such as hexane, heptane and octane.
  • aromatic hydrocarbon solvents such as toluene and xylene
  • aliphatic carboxylic acid ester solvents such as ethyl acetate
  • aliphatic hydrocarbon solvents such as hexane, heptane and octane.
  • the said organic solvent may be used independently and may use 2 or more types together.
  • the crosslinking agent may be included in the organic solvent coating liquid.
  • the crosslinking agent include an epoxy-based crosslinking agent, an isocyanate-based crosslinking agent, and an aziridine crosslinking agent.
  • any appropriate coating method can be adopted as a coating method when the adhesive tape is manufactured by the manufacturing method 3 described above.
  • the coating method include a method using a bar coater, a gravure coater, a spin coater, a roll coater, a knife coater, an applicator and the like.
  • a part means a weight part.
  • the pressure-sensitive adhesive tape is a roll body in which the back layer and the pressure-sensitive adhesive layer are laminated without using a separator, and a load of 0.07 kgf / mm 2 is formed on a part of this roll body with a stainless steel plate.
  • ⁇ No mark is seen.
  • X A trace is seen.
  • the pressure-sensitive adhesive tape is a roll body in which the back layer and the pressure-sensitive adhesive layer are laminated without a separator, and a load of 0.07 kgf / mm 2 is formed on a part of this roll body with a stainless steel plate. After applying for 10 seconds and applying a load, the sheet-like adhesive tape was drawn out from the roll body, and the external appearance of the sheet-like adhesive tape was visually confirmed. ⁇ : Appearance unevenness is not seen. X: Appearance unevenness is observed.
  • Example 1 (Preparation of the back layer) A polypropylene film (1a) having a thickness of 40 ⁇ m and a surface arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m was prepared.
  • Adhesive layer which is a mixture of 100 parts of styrene-ethylene-butylene-styrene block copolymer (SEBS) (Clayton: G1657) and 30 parts of tackifier (Arakawa Chemical Industries: Alcon P-125) A forming material (1b) was prepared.
  • SEBS styrene-ethylene-butylene-styrene block copolymer
  • tackifier Arakawa Chemical Industries: Alcon P-125
  • the pressure-sensitive adhesive layer forming material (1b) is dissolved in a diluting solvent (toluene) and applied to the surface opposite to the surface of the polypropylene film (1a) having an arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m. And dried to form an adhesive layer having a thickness of 7 ⁇ m to obtain an adhesive tape (1c).
  • a diluting solvent toluene
  • Example 2 (Preparation of the back layer) A polypropylene film (2a) having a thickness of 40 ⁇ m and a surface arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m was prepared.
  • Adhesive layer which is a mixture of 100 parts of styrene-ethylene-butylene-styrene block copolymer (SEBS) (Clayton: G1657) and 30 parts of tackifier (Arakawa Chemical Industries: Alcon P-125) A forming material (2b) was prepared.
  • SEBS styrene-ethylene-butylene-styrene block copolymer
  • tackifier Arakawa Chemical Industries: Alcon P-125
  • the pressure-sensitive adhesive layer forming material (2b) is dissolved in a diluting solvent (toluene) and applied to the surface opposite to the surface of the polypropylene film (2a) having an arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m. And dried to form an adhesive layer having a thickness of 3 ⁇ m to obtain an adhesive tape (2c).
  • a diluting solvent toluene
  • Example 3 (Preparation of the back layer) A polypropylene film (3a) having a thickness of 40 ⁇ m and a surface arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m was prepared.
  • Adhesive layer which is a mixture of 100 parts of styrene-ethylene-butylene-styrene block copolymer (SEBS) (Clayton: G1657) and 30 parts of tackifier (Arakawa Chemical Industries: Alcon P-125) A forming material (3b) was prepared.
  • the pressure-sensitive adhesive layer forming material (3b) is dissolved in a diluting solvent (toluene), and applied to the surface opposite to the surface of the polypropylene film (3a) where the arithmetic average low wavelength component roughness Ra2 is 0.22 ⁇ m. And dried to form an adhesive layer having a thickness of 10 ⁇ m to obtain an adhesive tape (3c).
  • a diluting solvent toluene
  • Example 4 (Preparation of the back layer) A polypropylene film (4a) having a thickness of 40 ⁇ m and a surface arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m was prepared.
  • Adhesion which is a mixture of 100 parts of styrene-ethylene-butylene-styrene block copolymer (SEBS) (Asahi Kasei Chemicals: Tuftec H1062) and 30 parts of tackifier (Arakawa Chemical Industries: Alcon P-125) The agent layer forming material (4b) was prepared.
  • SEBS styrene-ethylene-butylene-styrene block copolymer
  • tackifier Arakawa Chemical Industries: Alcon P-125
  • the pressure-sensitive adhesive layer forming material (4b) is dissolved in a diluting solvent (toluene) and applied to the surface opposite to the surface of the polypropylene film (4a) having an arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m. And dried to form an adhesive layer having a thickness of 5 ⁇ m to obtain an adhesive tape (4c).
  • a diluting solvent toluene
  • Example 5 (Preparation of the back layer) A polypropylene film (5a) having a thickness of 40 ⁇ m and a surface arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m was prepared.
  • Adhesion which is a mixture of 100 parts of styrene-ethylene-butylene-styrene block copolymer (SEBS) (Asahi Kasei Chemicals: Tuftec H1062) and 30 parts of tackifier (Arakawa Chemical Industries: Alcon P-125)
  • SEBS styrene-ethylene-butylene-styrene block copolymer
  • tackifier Arakawa Chemical Industries: Alcon P-125
  • the pressure-sensitive adhesive layer forming material (5b) is dissolved in a diluting solvent (toluene) and applied to the surface opposite to the surface of the polypropylene film (5a) having an arithmetic average low wavelength component roughness Ra2 of 0.22 ⁇ m. And dried to form a pressure-sensitive adhesive layer having a thickness of 10 ⁇ m to obtain a pressure-sensitive adhesive tape (5c).
  • a diluting solvent toluene
  • the pressure-sensitive adhesive layer forming material (C1b) is dissolved in a diluting solvent (toluene), and applied to the surface opposite to the surface of the polypropylene film (C1a) where the arithmetic average low wavelength component roughness Ra2 is 0.37 ⁇ m. And dried to form an adhesive layer having a thickness of 3 ⁇ m to obtain an adhesive tape (C1c).
  • a diluting solvent toluene
  • the pressure-sensitive adhesive layer forming material (C2b) is dissolved in a diluting solvent (toluene) and applied to the surface opposite to the surface of the polypropylene film (C2a) where the arithmetic average low wavelength component roughness Ra2 is 0.37 ⁇ m. And dried to form an adhesive layer having a thickness of 5 ⁇ m to obtain an adhesive tape (C2c).
  • a diluting solvent toluene
  • the pressure-sensitive adhesive tape of the present invention is useful as a surface protective film for a prism sheet.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

L'invention concerne un nouveau ruban adhésif hautement transparent, qui ne porte pas de marques d'impression provoquées par une charge de pression locale pendant la production, l'entreposage, le transport ou analogue, et qui est exempt d'irrégularités d'aspect dues à des marques d'impression dans les cas où le ruban adhésif est distribué sous une forme analogue à une feuille. Un ruban adhésif de la présente invention comprend une couche de surface arrière constituant une couche la plus externe et une couche adhésive constituant une autre couche la plus externe. Lorsque la rugosité moyenne arithmétique du composant de basse longueur d'onde de la surface de la couche de surface arrière est représentée par Ra2 (μm), le module de conservation de la couche adhésive à une fréquence de 10 Hz à 23˚C est représenté par G' (Pa), et l'épaisseur de la couche adhésive est représentée par d (µm), la valeur de B qui est définie comme B = d/(Ra2 × G') valant 20 × 10-6 Pa-1 ou plus.
PCT/JP2012/069014 2011-08-05 2012-07-26 Ruban adhésif WO2013021830A1 (fr)

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Publication number Priority date Publication date Assignee Title
WO2018139175A1 (fr) * 2017-01-26 2018-08-02 コニカミノルタ株式会社 Film stratifié fonctionnel, et procédé de production d'un film stratifié fonctionnel
JP6677939B2 (ja) * 2017-10-31 2020-04-08 東レフィルム加工株式会社 積層フィルム
JP7138448B2 (ja) * 2018-02-22 2022-09-16 リンテック株式会社 粘着シート巻回体
JP7369536B2 (ja) * 2019-03-27 2023-10-26 リンテック株式会社 積層シートのロール体
JP6761084B2 (ja) * 2019-07-17 2020-09-23 藤森工業株式会社 帯電防止表面保護フィルムの製造方法
JP2021006404A (ja) * 2020-09-02 2021-01-21 藤森工業株式会社 帯電防止表面保護フィルム

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11199832A (ja) * 1998-01-16 1999-07-27 Nitto Denko Corp 感圧性接着シ―ト類とその製造方法
JP2008030349A (ja) * 2006-07-31 2008-02-14 Toray Advanced Film Co Ltd 表面保護フィルム
WO2008047593A1 (fr) * 2006-10-18 2008-04-24 Nitto Denko Corporation film de protection de surface et film optique comportant un tel film
JP2011021103A (ja) * 2009-07-16 2011-02-03 Daio Paper Corp 難燃性粘着シート
JP2011116916A (ja) * 2009-12-07 2011-06-16 Daio Paper Corp 粘着剤組成物、及び粘着シート

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11199832A (ja) * 1998-01-16 1999-07-27 Nitto Denko Corp 感圧性接着シ―ト類とその製造方法
JP2008030349A (ja) * 2006-07-31 2008-02-14 Toray Advanced Film Co Ltd 表面保護フィルム
WO2008047593A1 (fr) * 2006-10-18 2008-04-24 Nitto Denko Corporation film de protection de surface et film optique comportant un tel film
JP2011021103A (ja) * 2009-07-16 2011-02-03 Daio Paper Corp 難燃性粘着シート
JP2011116916A (ja) * 2009-12-07 2011-06-16 Daio Paper Corp 粘着剤組成物、及び粘着シート

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