WO2012170421A1 - Catalyseur métal du groupe du platine (pgm) pour le traitement de gaz d'échappement - Google Patents
Catalyseur métal du groupe du platine (pgm) pour le traitement de gaz d'échappement Download PDFInfo
- Publication number
- WO2012170421A1 WO2012170421A1 PCT/US2012/040909 US2012040909W WO2012170421A1 WO 2012170421 A1 WO2012170421 A1 WO 2012170421A1 US 2012040909 W US2012040909 W US 2012040909W WO 2012170421 A1 WO2012170421 A1 WO 2012170421A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- pgm
- molecular sieve
- exhaust gas
- temperature
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 198
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 30
- 239000002808 molecular sieve Substances 0.000 claims abstract description 84
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 84
- 239000011148 porous material Substances 0.000 claims abstract description 64
- 238000000034 method Methods 0.000 claims abstract description 37
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 76
- 239000000758 substrate Substances 0.000 claims description 47
- 239000013078 crystal Substances 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 239000003638 chemical reducing agent Substances 0.000 claims description 30
- 229910021529 ammonia Inorganic materials 0.000 claims description 26
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 22
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 17
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 17
- 229910052763 palladium Inorganic materials 0.000 claims description 16
- 229910052697 platinum Inorganic materials 0.000 claims description 15
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 238000011144 upstream manufacturing Methods 0.000 claims description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000011800 void material Substances 0.000 claims description 9
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 8
- 239000010948 rhodium Substances 0.000 claims description 8
- 229910052703 rhodium Inorganic materials 0.000 claims description 7
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 143
- 239000007789 gas Substances 0.000 description 88
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 22
- 238000007254 oxidation reaction Methods 0.000 description 18
- 230000003647 oxidation Effects 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 238000006722 reduction reaction Methods 0.000 description 13
- 230000009467 reduction Effects 0.000 description 12
- 238000002485 combustion reaction Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 229910001868 water Inorganic materials 0.000 description 11
- 230000003197 catalytic effect Effects 0.000 description 10
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 10
- 239000004071 soot Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- -1 RHO Chemical compound 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 229910052723 transition metal Inorganic materials 0.000 description 7
- 150000003624 transition metals Chemical class 0.000 description 7
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000013618 particulate matter Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 229910052676 chabazite Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 4
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052878 cordierite Inorganic materials 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 description 3
- 229910001744 pollucite Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 101100008649 Caenorhabditis elegans daf-5 gene Proteins 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- LSQZJLSUYDQPKJ-NJBDSQKTSA-N amoxicillin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@H]3SC([C@@H](N3C2=O)C(O)=O)(C)C)=CC=C(O)C=C1 LSQZJLSUYDQPKJ-NJBDSQKTSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000013507 mapping Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- OVGWMUWIRHGGJP-WTODYLRWSA-N (z)-7-[(1r,3s,4s,5r)-3-[(e,3r)-3-hydroxyoct-1-enyl]-6-thiabicyclo[3.1.1]heptan-4-yl]hept-5-enoic acid Chemical compound OC(=O)CCC\C=C/C[C@H]1[C@H](/C=C/[C@H](O)CCCCC)C[C@H]2S[C@@H]1C2 OVGWMUWIRHGGJP-WTODYLRWSA-N 0.000 description 1
- XEZNGIUYQVAUSS-UHFFFAOYSA-N 18-crown-6 Chemical compound C1COCCOCCOCCOCCOCCO1 XEZNGIUYQVAUSS-UHFFFAOYSA-N 0.000 description 1
- LTYUPYUWXRTNFQ-UHFFFAOYSA-N 5,6-diamino-3',6'-dihydroxyspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound C12=CC=C(O)C=C2OC2=CC(O)=CC=C2C11OC(=O)C2=C1C=C(N)C(N)=C2 LTYUPYUWXRTNFQ-UHFFFAOYSA-N 0.000 description 1
- 101710204136 Acyl carrier protein 1 Proteins 0.000 description 1
- 101710204139 Acyl carrier protein 2 Proteins 0.000 description 1
- 229910000505 Al2TiO5 Inorganic materials 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 101100386238 Caenorhabditis elegans daf-8 gene Proteins 0.000 description 1
- 101100366889 Caenorhabditis elegans sta-2 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 101710113788 Candidapepsin-1 Proteins 0.000 description 1
- 101710113789 Candidapepsin-2 Proteins 0.000 description 1
- 101710113783 Candidapepsin-3 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000012922 MOF pore Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 101710116852 Molybdenum cofactor sulfurase 1 Proteins 0.000 description 1
- 229910014084 Na—B Inorganic materials 0.000 description 1
- 229910014134 Na—P1 Inorganic materials 0.000 description 1
- 229910014152 Na—P2 Inorganic materials 0.000 description 1
- 102100033118 Phosphatidate cytidylyltransferase 1 Human genes 0.000 description 1
- 101710178747 Phosphatidate cytidylyltransferase 1 Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100035703 Prostatic acid phosphatase Human genes 0.000 description 1
- 230000010757 Reduction Activity Effects 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000184 acid digestion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- JEWHCPOELGJVCB-UHFFFAOYSA-N aluminum;calcium;oxido-[oxido(oxo)silyl]oxy-oxosilane;potassium;sodium;tridecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.[Na].[Al].[K].[Ca].[O-][Si](=O)O[Si]([O-])=O JEWHCPOELGJVCB-UHFFFAOYSA-N 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- 229910052908 analcime Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910001942 caesium oxide Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910001690 harmotome Inorganic materials 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052907 leucite Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910001743 phillipsite Inorganic materials 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 239000013354 porous framework Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000012703 sol-gel precursor Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 238000013316 zoning Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
- B01J29/52—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
- B01J29/54—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9431—Processes characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9436—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/743—CHA-type, e.g. Chabazite, LZ-218
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates (SAPO compounds)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
-
- B01J35/19—
-
- B01J35/40—
-
- B01J35/56—
-
- B01J35/58—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/911—NH3-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/915—Catalyst supported on particulate filters
- B01D2255/9155—Wall flow filters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9205—Porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
- B01D2258/012—Diesel engines and lean burn gasoline engines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
- B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/783—CHA-type, e.g. Chabazite, LZ-218
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Toxicology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR112013031349A BR112013031349A2 (pt) | 2011-06-05 | 2012-06-05 | catalisador, artigo catalisador, método para tratar emissões, e, sistema para tratar gás de escape |
RU2013158339A RU2665464C2 (ru) | 2011-06-05 | 2012-06-05 | Катализатор на основе металла платиновой группы (мпг) для обработки выхлопных газов |
KR1020197000488A KR102018484B1 (ko) | 2011-06-05 | 2012-06-05 | 배기 가스를 처리하기 위한 백금족 금속(pgm) 촉매 |
KR1020137035084A KR101938432B1 (ko) | 2011-06-05 | 2012-06-05 | 배기 가스를 처리하기 위한 백금족 금속(pgm) 촉매 |
JP2014513802A JP6073298B2 (ja) | 2011-06-05 | 2012-06-05 | 排気ガスを処理するための白金族(pgm)触媒 |
EP12727049.4A EP2718010A1 (fr) | 2011-06-05 | 2012-06-05 | Catalyseur métal du groupe du platine (pgm) pour le traitement de gaz d'échappement |
US14/124,075 US9114376B2 (en) | 2011-06-05 | 2012-06-05 | Platinum group metal (PGM) catalyst for treating exhaust gas |
CN201280034827.3A CN103648643B (zh) | 2011-06-05 | 2012-06-05 | 用于处理废气的pgm催化剂 |
US14/685,793 US9751080B2 (en) | 2011-06-05 | 2015-04-14 | PGM catalyst for treating exhaust gas |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161493465P | 2011-06-05 | 2011-06-05 | |
US61/493,465 | 2011-06-05 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/124,075 A-371-Of-International US9114376B2 (en) | 2011-06-05 | 2012-06-05 | Platinum group metal (PGM) catalyst for treating exhaust gas |
US14/685,793 Continuation US9751080B2 (en) | 2011-06-05 | 2015-04-14 | PGM catalyst for treating exhaust gas |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012170421A1 true WO2012170421A1 (fr) | 2012-12-13 |
Family
ID=46246283
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2012/040909 WO2012170421A1 (fr) | 2011-06-05 | 2012-06-05 | Catalyseur métal du groupe du platine (pgm) pour le traitement de gaz d'échappement |
Country Status (8)
Country | Link |
---|---|
US (2) | US9114376B2 (fr) |
EP (1) | EP2718010A1 (fr) |
JP (1) | JP6073298B2 (fr) |
KR (2) | KR102018484B1 (fr) |
CN (2) | CN106423258B (fr) |
BR (1) | BR112013031349A2 (fr) |
RU (1) | RU2665464C2 (fr) |
WO (1) | WO2012170421A1 (fr) |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014124830A1 (fr) * | 2013-02-14 | 2014-08-21 | Haldor Topsøe A/S | Procédé et catalyseur pour le retrait simultané de monoxyde de carbone et d'oxydes d'azote de gaz de cheminée ou d'échappement |
JP2014210221A (ja) * | 2013-04-17 | 2014-11-13 | 株式会社キャタラー | Scr触媒および排ガス浄化触媒システム |
WO2015085303A1 (fr) * | 2013-12-06 | 2015-06-11 | Johnson Matthey Public Limited Company | Adsorbeur de nox passif comprenant un métal noble et un tamis moléculaire à petits pores |
US9333461B2 (en) | 2011-12-12 | 2016-05-10 | Johnson Matthey Public Limited Company | Substrate monolith comprising SCR catalyst |
CN105797582A (zh) * | 2016-04-29 | 2016-07-27 | 大唐环境产业集团股份有限公司 | 一种scr脱硝的差异化喷氨反应器及喷氨方法 |
EP3031777A4 (fr) * | 2013-08-05 | 2016-08-03 | Mitsubishi Chem Corp | Zéolite et procédé de production et utilisation s'y rapportant |
GB2538877A (en) * | 2014-12-08 | 2016-11-30 | Johnson Matthey Plc | Passive NOx adsorber |
WO2016203253A1 (fr) * | 2015-06-18 | 2016-12-22 | Johnson Matthey Public Limited Company | Catalyseur de rejet d'ammoniac conçu pour être le premier dans un système de réduction catalytique sélective (rcs) |
US9878309B2 (en) | 2013-12-06 | 2018-01-30 | Danmarks Tekniske Universitet | Catalyst for ammonia oxidation |
US10179329B2 (en) | 2014-11-19 | 2019-01-15 | Johnson Matthey Public Limited Company | Combining SCR with PNA for low temperature emission control |
RU2740186C2 (ru) * | 2016-05-24 | 2021-01-12 | Эксонмобил Кемикэл Пейтентс Инк. | Синтетический цеолит, содержащий каталитический металл |
RU2744763C2 (ru) * | 2013-12-02 | 2021-03-15 | Джонсон Мэтти Паблик Лимитед Компани | Синтез цеолита aei |
JP2021049525A (ja) * | 2013-03-15 | 2021-04-01 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | 排気ガスを処理するための触媒 |
EP3632554A4 (fr) * | 2017-05-31 | 2021-04-21 | Furukawa Electric Co., Ltd. | Structure de catalyseur d'oxydation pour purification de gaz d'échappement et son procédé de production, dispositif de traitement de gaz d'échappement pour véhicule, corps moulé de catalyseur et procédé de purification de gaz. |
US11161101B2 (en) | 2017-05-31 | 2021-11-02 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing the catalyst structure |
RU2759839C2 (ru) * | 2016-08-05 | 2021-11-18 | Басф Корпорейшн | Изделия и системы для селективного каталитического восстановления |
US11648543B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11648542B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11648538B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11655157B2 (en) | 2017-05-31 | 2023-05-23 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11654422B2 (en) | 2017-05-31 | 2023-05-23 | Furukawa Electric Co., Ltd. | Structured catalyst for catalytic cracking or hydrodesulfurization, catalytic cracking apparatus and hydrodesulfurization apparatus including the structured catalyst, and method for producing structured catalyst for catalytic cracking or hydrodesulfurization |
US11666894B2 (en) | 2017-05-31 | 2023-06-06 | Furukawa Electric Co., Ltd. | Structured catalyst for CO shift or reverse shift and method for producing same, CO shift or reverse shift reactor, method for producing carbon dioxide and hydrogen, and method for producing carbon monoxide and water |
US11680211B2 (en) | 2017-05-31 | 2023-06-20 | Furukawa Electric Co., Ltd. | Structured catalyst for hydrodesulfurization, hydrodesulfurization device including the structured catalyst, and method for producing structured catalyst for hydrodesulfurization |
US11684909B2 (en) | 2017-05-31 | 2023-06-27 | Furukawa Electric Co., Ltd. | Structured catalyst for methanol reforming, methanol reforming device, method for producing structured catalyst for methanol reforming, and method for producing at least one of olefin or aromatic hydrocarbon |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2665464C2 (ru) * | 2011-06-05 | 2018-08-30 | Джонсон Мэтти Паблик Лимитед Компани | Катализатор на основе металла платиновой группы (мпг) для обработки выхлопных газов |
JP6474809B2 (ja) * | 2013-07-30 | 2019-02-27 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | アンモニアスリップ触媒 |
US9744529B2 (en) * | 2014-03-21 | 2017-08-29 | Basf Corporation | Integrated LNT-TWC catalyst |
EP3140038A1 (fr) * | 2014-05-09 | 2017-03-15 | Johnson Matthey Public Limited Company | Catalyseur de conversion d'ammoniac dans lequel du platine est imprégné sur des substrats de porosité élevée |
WO2016057456A1 (fr) * | 2014-10-07 | 2016-04-14 | Johnson Matthey Public Limited Company | Catalyseur à tamis moléculaire pour le traitement de gaz d'échappement |
JP6796084B2 (ja) * | 2015-05-19 | 2020-12-02 | ビーエーエスエフ コーポレーション | パッシブ選択触媒還元に使用するための触媒スートフィルタ |
US9937489B2 (en) * | 2015-06-18 | 2018-04-10 | Johnson Matthey Public Limited Company | Exhaust system without a DOC having an ASC acting as a DOC in a system with an SCR catalyst before the ASC |
GB2564333B (en) | 2015-06-28 | 2019-12-04 | Johnson Matthey Plc | Catalytic wall-flow filter having a membrane |
CN108136373A (zh) * | 2015-07-30 | 2018-06-08 | 巴斯夫公司 | 柴油机氧化催化剂 |
BR112018006283B1 (pt) * | 2015-09-29 | 2023-02-14 | Johnson Matthey Public Limited Company | Artigo catalítico, sistema de escape, turbina de combustão, e, métodos para aumentar a conversão de monóxido de carbono (co) e hidrocarbonetos (hc) em um gás de escape, para reduzir escorregamento de amônia e para aumentar a tolerância ao enxofre de um artigo catalítico em um gás de escape |
US10046310B2 (en) * | 2015-10-05 | 2018-08-14 | GM Global Technology Operations LLC | Catalytic converters with age-suppressing catalysts |
GB201517580D0 (en) * | 2015-10-06 | 2015-11-18 | Johnson Matthey Plc | Exhaust system comprising a passive nox adsorber |
WO2017085646A1 (fr) * | 2015-11-17 | 2017-05-26 | Basf Corporation | Catalyseur pour le traitement de gaz d'échappement |
GB201521123D0 (en) * | 2015-11-30 | 2016-01-13 | Johnson Matthey Plc | Diesel oxidation catalyst having a capture region for exhaust gas impurities |
EP3205398A1 (fr) * | 2016-02-12 | 2017-08-16 | Hyundai Motor Company | Procédé de préparation d'un catalyseur zéolite |
US10343925B2 (en) | 2016-02-12 | 2019-07-09 | Hyundai Motor Company | Method for preparing zeolite catalyst |
KR101982040B1 (ko) | 2016-06-21 | 2019-05-24 | 삼성전기주식회사 | 팬-아웃 반도체 패키지 |
KR101846914B1 (ko) * | 2016-10-21 | 2018-04-09 | 현대자동차 주식회사 | 촉매 및 촉매의 제조 방법 |
US10159960B2 (en) | 2016-10-25 | 2018-12-25 | GM Global Technology Operations LLC | Catalysts with atomically dispersed platinum group metal complexes |
KR101846918B1 (ko) * | 2016-11-16 | 2018-04-09 | 현대자동차 주식회사 | Cu/LTA 촉매 및 이를 포함하는 배기 시스템, 그리고 Cu/LTA 촉매 제조 방법 |
GB201705158D0 (en) * | 2017-03-30 | 2017-05-17 | Johnson Matthey Plc | Catalyst article for use in a emission treatment system |
US10926221B2 (en) * | 2017-03-30 | 2021-02-23 | Johnson Matthey Public Limited Company | Single brick SCR/ASC/PNA/DOC close-coupled catalyst |
EP3450016A1 (fr) * | 2017-08-31 | 2019-03-06 | Umicore Ag & Co. Kg | Adsorbant passif d'oxyde d'azote à base de palladium et zéolithe pour le traitement de gaz d'échappement |
KR20200045550A (ko) | 2017-08-31 | 2020-05-04 | 우미코레 아게 운트 코 카게 | 배기 가스 정화용 팔라듐/제올라이트 기반 수동적 질소 산화물 흡착제 촉매 |
EP3450015A1 (fr) * | 2017-08-31 | 2019-03-06 | Umicore Ag & Co. Kg | Adsorbant passif d'oxyde d'azote à base de palladium et zéolithe pour le traitement de gaz d'échappement |
JP2020531241A (ja) | 2017-08-31 | 2020-11-05 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG | 排気ガスを浄化するための受動的窒素酸化物吸着剤としてのパラジウム/白金/ゼオライト系触媒の使用 |
CN109985662B (zh) * | 2017-12-29 | 2020-10-16 | 华中科技大学 | 一种高硅Cu-LTA催化剂的制备方法及其应用 |
US10456746B2 (en) * | 2018-02-12 | 2019-10-29 | GM Global Technology Operations LLC | Selective catalytic reduction filter for reducing nitrous oxide formation and methods of using the same |
GB201805312D0 (en) * | 2018-03-29 | 2018-05-16 | Johnson Matthey Plc | Catalyst article for use in emission treatment system |
US10953366B2 (en) * | 2018-04-20 | 2021-03-23 | GM Global Technology Operations LLC | Nitrogen oxides and hydrocarbon storage catalyst and methods of using the same |
US11278874B2 (en) * | 2018-11-30 | 2022-03-22 | Johnson Matthey Public Limited Company | Enhanced introduction of extra-framework metal into aluminosilicate zeolites |
EP3698865A1 (fr) * | 2019-02-20 | 2020-08-26 | Umicore Ag & Co. Kg | Zéolite contenant de la platine et du manganèse |
CN111111429A (zh) * | 2019-12-16 | 2020-05-08 | 山东金城柯瑞化学有限公司 | 一种利用单活性中心多相催化剂技术治理乙酰呋喃氧化尾气的方法 |
KR20210087743A (ko) * | 2020-01-03 | 2021-07-13 | 현대자동차주식회사 | 촉매 및 촉매의 제조 방법 |
CN111974444A (zh) * | 2020-07-29 | 2020-11-24 | 华南理工大学 | 一种一锅法制备的小孔分子筛负载贵金属材料的制备方法及其应用 |
KR20220069375A (ko) * | 2020-11-20 | 2022-05-27 | 현대자동차주식회사 | 탄화수소 산화용 제올라이트 촉매 및 이의 제조방법 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100111791A1 (en) * | 2008-11-03 | 2010-05-06 | Basf Catalysts Llc | Bimetallic Catalysts for Selective Ammonia Oxidation |
GB2475740A (en) * | 2009-11-30 | 2011-06-01 | Johnson Matthey Plc | An SCR catalyst comprising two molecular sieve components |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3226339A (en) * | 1958-11-17 | 1965-12-28 | Socony Mobil Oil Co Inc | Process for preparing a platinum metalcrystalline zeolite catalyst |
US3373110A (en) * | 1966-04-14 | 1968-03-12 | Mobil Oil Corp | Process for the preparation of platinum metal containing aluminosilicates |
US4544538A (en) | 1982-07-09 | 1985-10-01 | Chevron Research Company | Zeolite SSZ-13 and its method of preparation |
US4582650A (en) * | 1985-02-11 | 1986-04-15 | Monsanto Company | Oxidation with encapsulated co-catalyst |
US4724275A (en) * | 1985-07-01 | 1988-02-09 | National Distillers And Chemical Corporation | Crystalline aluminosilicates and their use in the conversion of methanol to low molecular weight hydrocarbons |
JP3157555B2 (ja) * | 1991-09-24 | 2001-04-16 | マツダ株式会社 | 排気ガス浄化用触媒 |
US5391533A (en) * | 1993-02-19 | 1995-02-21 | Amtx, Inc. | Catalyst system for producing chlorine dioxide |
DE69402766T2 (de) | 1993-07-09 | 1997-07-31 | N E Chemcat Corp | Methode und Katalysator zur Reinigung von Abgasen |
JPH0768181A (ja) * | 1993-07-09 | 1995-03-14 | N E Chemcat Corp | 排気ガスの浄化用触媒および浄化方法 |
US6667018B2 (en) * | 1994-07-05 | 2003-12-23 | Ngk Insulators, Ltd. | Catalyst-adsorbent for purification of exhaust gases and method for purification of exhaust gases |
AU3475797A (en) * | 1996-05-29 | 1998-01-05 | Exxon Chemical Patents Inc. | Metal-containing zeolite catalyst, preparation thereof and use for hydrocarbon conversion |
FR2754468B1 (fr) * | 1996-10-10 | 2001-12-14 | Gaz De France | Catalyseur, en particulier de reduction des nox, et procede de reduction des nox |
ES2250035T3 (es) * | 2000-03-01 | 2006-04-16 | UMICORE AG & CO. KG | Catalizador para la purificacion de los gases de escape de motores diesel y proceso para su preparacion. |
RU2665464C2 (ru) * | 2011-06-05 | 2018-08-30 | Джонсон Мэтти Паблик Лимитед Компани | Катализатор на основе металла платиновой группы (мпг) для обработки выхлопных газов |
-
2012
- 2012-06-05 RU RU2013158339A patent/RU2665464C2/ru not_active IP Right Cessation
- 2012-06-05 JP JP2014513802A patent/JP6073298B2/ja not_active Expired - Fee Related
- 2012-06-05 EP EP12727049.4A patent/EP2718010A1/fr active Pending
- 2012-06-05 US US14/124,075 patent/US9114376B2/en active Active
- 2012-06-05 KR KR1020197000488A patent/KR102018484B1/ko active IP Right Grant
- 2012-06-05 CN CN201610832331.0A patent/CN106423258B/zh active Active
- 2012-06-05 CN CN201280034827.3A patent/CN103648643B/zh active Active
- 2012-06-05 BR BR112013031349A patent/BR112013031349A2/pt not_active Application Discontinuation
- 2012-06-05 KR KR1020137035084A patent/KR101938432B1/ko active IP Right Grant
- 2012-06-05 WO PCT/US2012/040909 patent/WO2012170421A1/fr active Application Filing
-
2015
- 2015-04-14 US US14/685,793 patent/US9751080B2/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100111791A1 (en) * | 2008-11-03 | 2010-05-06 | Basf Catalysts Llc | Bimetallic Catalysts for Selective Ammonia Oxidation |
GB2475740A (en) * | 2009-11-30 | 2011-06-01 | Johnson Matthey Plc | An SCR catalyst comprising two molecular sieve components |
Non-Patent Citations (6)
Title |
---|
ALTWASSER ET AL: "Ruthenium-containing small-pore zeolites for shape-selective catalysis", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 104, no. 1-3, 31 July 2007 (2007-07-31), pages 281 - 288, XP022180612, ISSN: 1387-1811, DOI: 10.1016/J.MICROMESO.2007.02.046 * |
CHEN H ET AL: "Contribution of hydrogen spillover to the hydrogenation of naphthalene over diluted Pt/RHO catalysts", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 358, no. 2, 1 May 2009 (2009-05-01), pages 103 - 109, XP026076721, ISSN: 0926-860X, [retrieved on 20090220], DOI: 10.1016/J.APCATA.2008.12.045 * |
JOHANN KECHT ET AL: "Exceptionally Small Colloidal Zeolites Templated by Pd and Pt Amines", LANGMUIR, vol. 24, no. 8, 1 April 2008 (2008-04-01), pages 4310 - 4315, XP055035017, ISSN: 0743-7463, DOI: 10.1021/la7033033 * |
P.B. WEISZ, V.J.FRILETTE, R.W.MAATMAN, E.B.MOWER: "Catalysis by Crystalline Aluminosilicates II. Molecular-Shape Selective Reactions", JOURNAL OF CATALYSIS, vol. 1, 1962, pages 307 - 312, XP002681723 * |
WEITKAMP J ET AL: "Introduction of noble metals into small pore zeolites via solid state ion exchange", STUDIES IN SURFACE SCIENCE AND CATALYSIS, ELSEVIER B.V, vol. 94, 1 January 1995 (1995-01-01), pages 278 - 285, XP009161892, ISSN: 0167-2991 * |
YANG H ET AL: "Incorporating platinum precursors into a NaA-zeolite synthesis mixture promoting the formation of nanosized zeolite", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 117, no. 1-2, 1 January 2009 (2009-01-01), pages 33 - 40, XP025658742, ISSN: 1387-1811, [retrieved on 20080614], DOI: 10.1016/J.MICROMESO.2008.06.009 * |
Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012222804B4 (de) * | 2011-12-12 | 2021-05-20 | Johnson Matthey Public Limited Company | Abgassystem mit Substratmonolith, der einen SCR-Katalysator umfasst |
US9333461B2 (en) | 2011-12-12 | 2016-05-10 | Johnson Matthey Public Limited Company | Substrate monolith comprising SCR catalyst |
US10493436B2 (en) | 2013-02-14 | 2019-12-03 | Haldor Topsoe A/S | Method for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas |
WO2014124830A1 (fr) * | 2013-02-14 | 2014-08-21 | Haldor Topsøe A/S | Procédé et catalyseur pour le retrait simultané de monoxyde de carbone et d'oxydes d'azote de gaz de cheminée ou d'échappement |
JP7108007B2 (ja) | 2013-03-15 | 2022-07-27 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | 排気ガスを処理するための触媒 |
JP2021049525A (ja) * | 2013-03-15 | 2021-04-01 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | 排気ガスを処理するための触媒 |
JP2014210221A (ja) * | 2013-04-17 | 2014-11-13 | 株式会社キャタラー | Scr触媒および排ガス浄化触媒システム |
US9919297B2 (en) | 2013-08-05 | 2018-03-20 | Mitsubishi Chemical Corporation | Zeolite, and production method and use therefor |
EP3031777A4 (fr) * | 2013-08-05 | 2016-08-03 | Mitsubishi Chem Corp | Zéolite et procédé de production et utilisation s'y rapportant |
JP2019001707A (ja) * | 2013-08-05 | 2019-01-10 | 三菱ケミカル株式会社 | ゼオライト及びその製造方法と用途 |
RU2744763C2 (ru) * | 2013-12-02 | 2021-03-15 | Джонсон Мэтти Паблик Лимитед Компани | Синтез цеолита aei |
US9878309B2 (en) | 2013-12-06 | 2018-01-30 | Danmarks Tekniske Universitet | Catalyst for ammonia oxidation |
EP3626330A1 (fr) * | 2013-12-06 | 2020-03-25 | Johnson Matthey Public Limited Company | Adsorbeur nox passif comprenant métal précieux et zéolite avec de pores petites |
US10005075B2 (en) | 2013-12-06 | 2018-06-26 | Johnson Matthey Public Limited Company | Passive NOx adsorber |
RU2675905C1 (ru) * | 2013-12-06 | 2018-12-25 | Джонсон Мэтти Паблик Лимитед Компани | ПАССИВНЫЙ АДСОРБЕНТ NOx, СОДЕРЖАЩИЙ БЛАГОРОДНЫЙ МЕТАЛЛ И МЕЛКОПОРИСТОЕ МОЛЕКУЛЯРНОЕ СИТО |
WO2015085303A1 (fr) * | 2013-12-06 | 2015-06-11 | Johnson Matthey Public Limited Company | Adsorbeur de nox passif comprenant un métal noble et un tamis moléculaire à petits pores |
GB2522977B (en) * | 2013-12-06 | 2017-02-08 | Johnson Matthey Plc | Passive NOx adsorber |
CN105813717A (zh) * | 2013-12-06 | 2016-07-27 | 庄信万丰股份有限公司 | 包含贵金属和小孔分子筛的被动式NOx吸附剂 |
US10179329B2 (en) | 2014-11-19 | 2019-01-15 | Johnson Matthey Public Limited Company | Combining SCR with PNA for low temperature emission control |
GB2535274B (en) * | 2014-11-19 | 2019-06-12 | Johnson Matthey Plc | An exhaust system combining a molecular-sieve-containing SCR catalyst and a molecular-sieve-containing NOx adsorber catalyst |
GB2538877B (en) * | 2014-12-08 | 2017-04-26 | Johnson Matthey Plc | Passive NOx adsorber |
GB2538877A (en) * | 2014-12-08 | 2016-11-30 | Johnson Matthey Plc | Passive NOx adsorber |
US20190168198A1 (en) | 2015-06-18 | 2019-06-06 | Johnson Matthey Public Limited Company | Ammonia slip catalyst designed to be first in an scr system |
WO2016203253A1 (fr) * | 2015-06-18 | 2016-12-22 | Johnson Matthey Public Limited Company | Catalyseur de rejet d'ammoniac conçu pour être le premier dans un système de réduction catalytique sélective (rcs) |
US10807081B2 (en) | 2015-06-18 | 2020-10-20 | Johnson Matthey Public Limited Company | Ammonia slip catalyst designed to be first in an SCR system |
CN105797582A (zh) * | 2016-04-29 | 2016-07-27 | 大唐环境产业集团股份有限公司 | 一种scr脱硝的差异化喷氨反应器及喷氨方法 |
RU2740186C2 (ru) * | 2016-05-24 | 2021-01-12 | Эксонмобил Кемикэл Пейтентс Инк. | Синтетический цеолит, содержащий каталитический металл |
US11448110B2 (en) | 2016-08-05 | 2022-09-20 | Basf Corporation | Selective catalytic reduction articles and systems |
RU2759839C2 (ru) * | 2016-08-05 | 2021-11-18 | Басф Корпорейшн | Изделия и системы для селективного каталитического восстановления |
US11547987B2 (en) | 2017-05-31 | 2023-01-10 | Furukawa Electric Co., Ltd. | Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method |
US11161101B2 (en) | 2017-05-31 | 2021-11-02 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing the catalyst structure |
EP3632554A4 (fr) * | 2017-05-31 | 2021-04-21 | Furukawa Electric Co., Ltd. | Structure de catalyseur d'oxydation pour purification de gaz d'échappement et son procédé de production, dispositif de traitement de gaz d'échappement pour véhicule, corps moulé de catalyseur et procédé de purification de gaz. |
US11648543B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11648542B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11648538B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11655157B2 (en) | 2017-05-31 | 2023-05-23 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11654422B2 (en) | 2017-05-31 | 2023-05-23 | Furukawa Electric Co., Ltd. | Structured catalyst for catalytic cracking or hydrodesulfurization, catalytic cracking apparatus and hydrodesulfurization apparatus including the structured catalyst, and method for producing structured catalyst for catalytic cracking or hydrodesulfurization |
US11666894B2 (en) | 2017-05-31 | 2023-06-06 | Furukawa Electric Co., Ltd. | Structured catalyst for CO shift or reverse shift and method for producing same, CO shift or reverse shift reactor, method for producing carbon dioxide and hydrogen, and method for producing carbon monoxide and water |
US11680211B2 (en) | 2017-05-31 | 2023-06-20 | Furukawa Electric Co., Ltd. | Structured catalyst for hydrodesulfurization, hydrodesulfurization device including the structured catalyst, and method for producing structured catalyst for hydrodesulfurization |
US11684909B2 (en) | 2017-05-31 | 2023-06-27 | Furukawa Electric Co., Ltd. | Structured catalyst for methanol reforming, methanol reforming device, method for producing structured catalyst for methanol reforming, and method for producing at least one of olefin or aromatic hydrocarbon |
US11904306B2 (en) | 2017-05-31 | 2024-02-20 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing the catalyst structure |
Also Published As
Publication number | Publication date |
---|---|
KR20140049992A (ko) | 2014-04-28 |
RU2013158339A (ru) | 2015-07-20 |
US9114376B2 (en) | 2015-08-25 |
JP6073298B2 (ja) | 2017-02-01 |
RU2665464C2 (ru) | 2018-08-30 |
KR102018484B1 (ko) | 2019-09-05 |
CN103648643A (zh) | 2014-03-19 |
US20150217282A1 (en) | 2015-08-06 |
US9751080B2 (en) | 2017-09-05 |
CN106423258B (zh) | 2019-03-08 |
KR20190006077A (ko) | 2019-01-16 |
CN106423258A (zh) | 2017-02-22 |
KR101938432B1 (ko) | 2019-01-14 |
EP2718010A1 (fr) | 2014-04-16 |
BR112013031349A2 (pt) | 2016-11-29 |
US20140170045A1 (en) | 2014-06-19 |
JP2014522308A (ja) | 2014-09-04 |
CN103648643B (zh) | 2016-10-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9751080B2 (en) | PGM catalyst for treating exhaust gas | |
US11478748B2 (en) | Transition metal/zeolite SCR catalysts | |
US9802156B2 (en) | Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides | |
EP2995367B1 (fr) | Catalyseurs durables a base de cuivre supportes par un tamis moleculaire a petits pores contre le vieillissement pauvre/riche pour la reduction d'oxydes d'azote |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12727049 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2014513802 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20137035084 Country of ref document: KR Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2013158339 Country of ref document: RU Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14124075 Country of ref document: US |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112013031349 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 112013031349 Country of ref document: BR Kind code of ref document: A2 Effective date: 20131205 |