WO2012108107A1 - Gant - Google Patents

Gant Download PDF

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Publication number
WO2012108107A1
WO2012108107A1 PCT/JP2011/079538 JP2011079538W WO2012108107A1 WO 2012108107 A1 WO2012108107 A1 WO 2012108107A1 JP 2011079538 W JP2011079538 W JP 2011079538W WO 2012108107 A1 WO2012108107 A1 WO 2012108107A1
Authority
WO
WIPO (PCT)
Prior art keywords
glove
cuff
sleeve
rubber
pleats
Prior art date
Application number
PCT/JP2011/079538
Other languages
English (en)
Japanese (ja)
Inventor
越智　敦子
Original Assignee
住友ゴム工業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友ゴム工業株式会社 filed Critical 住友ゴム工業株式会社
Publication of WO2012108107A1 publication Critical patent/WO2012108107A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0044—Cuff portions

Definitions

  • the present invention relates to a glove integrally formed of a film of rubber or resin as a whole.
  • a substantially cylindrical sleeve and a glove main body which is continuous with one end of the sleeve and protects from the wrist to the fingertip are natural rubber, acrylonitrile-butadiene
  • a glove which is integrally formed of a synthetic rubber such as rubber (NBR) or a resin such as a vinyl chloride resin or a urethane resin and which has the other end of the sleeve open as a cuff is widely used.
  • the gloves have various thicknesses, but in recent years, in order to improve the fit to the hand and the workability in the state of wearing the gloves, in particular, the gloves are formed only by the thin film of rubber or resin.
  • the demand for soft, flexible gloves tends to increase. However, the more flexible and the thinner the film, the lower the rigidity tends to be. Therefore, for example, when the thin glove is worn and actually used, the sleeve that should cover the area from the wrist to the forearm may fall toward the glove body, or the entire glove may be easily detached or detached from the hand. For example, when used for water work, there is a problem that bouncing water comes in and there is no point in wearing gloves.
  • Patent Documents 1 and 2 and the like a prevention tool for clipping a cuff of a glove to prevent slipping is proposed, but such a prevention tool is used prior to use of the glove. Wearing or removing after use is troublesome.
  • Patent Document 3 describes a glove provided with a strap at the cuff of the glove, but it is also troublesome to tighten the strap prior to use of the glove or loosen it after use.
  • Patent Document 4 describes a tubular elbow used in combination with a short glove and provided with a plurality of pleats reaching from the one end side to the other end side.
  • the elbow protector is unlikely to slip off the elbow due to the circumferential stretchability by providing the pleats, but such an elbow protector, together with the glove, has no gap between the two. Wearing or removing with gloves is still cumbersome.
  • the elbow protector may be displaced due to, for example, expansion and contraction of the elbow, causing a gap between the glove and the glove, and water may infiltrate from there, which is not perfect.
  • Patent Documents 5 and 6 disclose that a plurality of pleats extending from the fingertip to the cuff are provided on the back side of the glove from the fingertip to the entire cuff. However, these pleats are all for preventing the gloves from adhering to the hand on the back side of the hand and for ensuring air permeability, and are not considered for slip prevention. That is, since the gloves of Patent Documents 5 and 6 are pleated only on the back side of the hand of the glove as described above, they impart elasticity as in the case of the above-mentioned elbow protection to prevent the sleeves from slipping off. There is no function.
  • the object of the present invention is to allow the sleeves to slip towards the body of the glove, or the entire glove to come off or come out of the hand, without putting on and taking off the guard or attaching it with the elbow protection. It is to provide a glove that can reliably prevent the ingress of water and the like as a result.
  • the inventor forms a pleat over the entire circumference of the sleeve part of the glove to impart good stretchability to the sleeve part, and the sleeve part is shifted toward the glove body
  • pleats with a constant depth such as the pleats of the elbow protection described in Patent Document 4 described above
  • ⁇ The tightness against the narrowest wrist, especially in the forearm, becomes worse, and the workability in the state of wearing the glove decreases.
  • the sleeve was folded back and down in the middle of the work, and the water splashed during water work could not surely be prevented from invading from the cuff.
  • the rubber or resin film should be thickened to increase the rigidity, but in that case the amount of rubber or resin forming the glove will increase and the glove will become heavier or the cost will There is a problem of getting expensive. Therefore, as a result of further examination of the depth of the pleats, it was found that the depth of the pleats formed over the entire circumference of the sleeve may be gradually deepened from one end connected to the glove body toward the cuff. It came to complete.
  • the substantially cylindrical sleeve portion and the glove main body connected to one end of the sleeve portion are integrally formed of a film of rubber or resin, and the other end of the sleeve portion is opened as a cuff.
  • the sleeve portion is provided with a plurality of pleats that reach the cuff from one end connected to the glove body over the entire circumference, and each pleat has a gradually increasing depth from the one end to the cuff It is characterized by the fact that
  • the vicinity of the one end corresponding to the narrowest wrist among the forearm can be firmly fitted to the wrist, and the workability in the state of wearing the glove can be improved. Moreover, since the appropriate stretchability can be provided near the one end by the pleat provided on the entire circumference, there is no possibility that the ease of wearing of the glove is impeded.
  • each pleat since the depth of each pleat is gradually increased from the one end toward the cuff, the thickness of the rubber or resin film forming the sleeve is not increased. It is also possible to provide appropriate rigidity to prevent the occurrence of folding or drooping. In addition, it is not necessary to increase the thickness of the sleeves, and the amount of rubber and resin forming the glove can be increased to prevent the glove from becoming heavy and costly.
  • the extent to which the depth of the pleats differs between one end of the sleeve and the cuff is expressed by the expansion ratio E determined by the equation (1). It is preferable to set a range of 1 / 0.9 or more and 1 / 0.6 or less in the cuff and to gradually increase the stretch ratio E from the one end to the cuff.
  • the stretch ratio E is 1 at one end of the sleeve and no pleat is formed at the one end, and the sleeve is in the vicinity of the wrist on the one end side by gradually deepening the pleat from there toward the cuff The effect of making it fit well can be further improved.
  • the expansion ratio E is 1 / 0.9 or more in the cuff, it is possible to further improve the effect of imparting appropriate rigidity to the sleeve to prevent folding and drooping.
  • the stretch ratio E of the cuff is 1 / 0.6 or less because, for example, at the time of manufacture of a glove by a general immersion method, uneven thickness and cracks occur due to the pleat being too deep in the cuff. To prevent In the case where such uneven thickness or cracking occurs, on the contrary, folding or drooping tends to occur.
  • the length of the sleeve from the one end to the cuff is preferably 10 cm or more. Shorter sleeves are less prone to folding and drooping, but if they are shorter than the above-mentioned range, there is a possibility that the splashed water can not be reliably prevented from entering during water work.
  • the thickness of the rubber or resin forming the glove is considered to prevent the glove from becoming heavy or expensive due to an increase in the amount of rubber or resin forming the glove as described above. Then, it is preferable that it is 2.0 mm or less. However, if the thickness of the membrane is too small, even if pleated, it may not be possible to prevent the occurrence of folding or sagging by giving an appropriate rigidity to the sleeve. Therefore, the thickness of the membrane is preferably 0.1 mm or more.
  • the sleeves fall off toward the glove body, or the entire glove slips out of the hand, without putting on and taking off the guard or attaching it with the elbow protection.
  • FIG. 1 It is a front view showing an example of an embodiment of a glove of the present invention. It is a figure explaining the outline of the pleat of the glove of the example of FIG.
  • FIG. 1 is a front view showing an example of the embodiment of the glove of the present invention.
  • FIG. 2 is a view for explaining an outline of pleats of the glove of the example of FIG.
  • a substantially cylindrical sleeve 2 and a glove body 3 connected to one end of the sleeve 2 are integrally formed of a rubber or resin film, and the sleeve The other end of the part 2 is opened as a cuff 4.
  • the glove body 3 has a palm 5 connected to the sleeve 2 and a plurality of fingers 6 connected to the palm 5 corresponding to the shape of a hand as in the prior art.
  • the sleeve portion 2 is formed of a first sleeve portion 8 on one end 7 side connected to the glove body 3 side, and a second sleeve portion 9 constituting the cuff 4. Both sleeves 8 and 9 are integrally connected at the boundary 10.
  • the first sleeve portion 8 is formed in a substantially truncated cone shape whose circumferential length gradually increases from the one end 7 side toward the boundary portion 10.
  • the second sleeve 9 is formed in a substantially truncated cone shape whose circumferential length gradually increases from the boundary 10 to the cuff 4.
  • the circumferential lengths of the two sleeves 8 and 9 at the boundary 10 are the same, whereby the two sleeves 8 and 9 are integrally connected over the entire circumference.
  • the slope of the generatrices forming the conical surface of the second sleeve 9 is greater than the slope of the generatrices constituting the conical surface of the first sleeve 8 so that the second sleeve 9 opens largely at the cuff 4 It is done.
  • Plural pleats 11 that reach the cuff 4 from one end 7 connected to the palm part 5 of the glove body 3 are provided on the sleeve part 2 consisting of both sleeve parts 8 and 9 over the entire circumference.
  • Each pleat 11 is formed in a substantially sine curve shape in cross section as shown in FIG.
  • Each pleat 11 has a depth D shown in FIG. 2 gradually deepened from one end 7 to the cuff 4. There is no particular limitation on how much the depths of the pleats 11 are different between one end 7 of the sleeve 2 and the cuff 4, but in the free state where no stress is applied to the parts forming the glove 1.
  • the first sleeve 8 at the one end 7 side It can be fitted firmly around the wrist. Moreover, since the appropriate stretchability can be provided near the one end 7 by the pleats 11 provided on the entire circumference, there is no possibility that the ease of wearing the glove 1 is impeded.
  • the sleeve 2 that is, the first and second sleeves 8, 9 is given appropriate rigidity to prevent folding and sagging. can do.
  • the stretch ratio E of the cuff 4 is preferably 1 / 0.6 or less because, for example, when the glove 1 is manufactured by a general immersion method, the uneven thickness associated with the pleat 11 being too deep in the cuff 4 or It is for preventing that a crack arises. In the case where such uneven thickness or cracking occurs, on the contrary, folding or drooping tends to occur.
  • the specific depth D of the pleats 11 can be arbitrarily set to satisfy the expansion ratio E according to the size of the glove 1 etc., but the cuff 4 is preferably 3 mm or more, particularly 4 mm or more, It is preferably 7 mm or less, particularly 6 mm or less.
  • the cuff 4 is given appropriate rigidity while preventing occurrence of uneven thickness or cracking during manufacturing of the glove 1, and folding or sagging is caused. It can be prevented.
  • the length L of the sleeve 2 from the one end 7 to the cuff 4 is preferably 10 cm or more, and more preferably 20 cm or more. As the sleeve 2 is shorter, it is less likely to cause folding or drooping, but if it is shorter than the above range, there is a possibility that the splashed water can not be reliably prevented from entering during water work.
  • the length L is preferably 40 cm or less, particularly 30 cm or less, in consideration of covering up to the vicinity of the elbow, for example.
  • the thickness of the rubber or resin forming the glove 1 is to prevent the glove from becoming heavy or costly because the amount of rubber or resin forming the glove 1 is increased as described above. It is preferable that it is 2.0 mm or less, especially 1.5 mm or less in consideration of. However, if the thickness of the membrane is too small, even if the pleats 11 are attached, there is a possibility that the sleeve 2 can not be provided with an appropriate rigidity to prevent the occurrence of folding or drooping. Therefore, the thickness of the film is preferably 0.1 mm or more, particularly 0.2 mm or more.
  • the entire glove 1 does not have to be within the above thickness range, and for example, the cuff 4 is made thicker than the other portions to give appropriate rigidity so as to further prevent folding or drooping, or the tip of the finger 6 May be thicker than other parts to protect the fingertip.
  • the glove 1 can be configured in the same manner as the conventional one except that the sleeve 2 has the pleats 11.
  • the glove 1 is formed by depositing a rubber latex in the shape of the glove 1 shown in FIG. 1 by dipping as in the prior art and vulcanizing the rubber or forming an emulsion of resin into the shape of the glove 1 by dipping. It can be manufactured by drying and solidifying the resin while filming.
  • a mold corresponding to the shape of the glove 1 shown in FIG. 1 is prepared, and the surface of the mold is treated with a coagulant such as calcium nitrate.
  • various additives such as a vulcanizing agent, a vulcanization accelerator, a vulcanization acceleration assistant (activator), an antiaging agent, a filler, a dispersant and the like are added to the rubber latex to obtain an unvulcanized or prevulcanized state.
  • a vulcanizing agent such as a vulcanizing agent, a vulcanization accelerator, a vulcanization acceleration assistant (activator), an antiaging agent, a filler, a dispersant and the like are added to the rubber latex to obtain an unvulcanized or prevulcanized state.
  • the mold is immersed in the immersion liquid for a certain period of time and then pulled up, thereby adhering the immersion liquid to the surface of the mold.
  • the glove as shown in FIG. 1 is then heated either to heat the mold so as to dry the immersion liquid and to vulcanize the rubber, or to heat it once to cure it and then to vulcanize the rubber and then to demold it. 1 is manufactured.
  • any of natural rubber and various rubbers which can be made into latex from synthetic rubber can be used, and as such rubber, for example, natural rubber, deproteinized natural rubber, NBR, styrene-butadiene rubber ( 1 type or 2 types or more, such as SBR) and chloroprene rubber (CR), are mentioned.
  • the vulcanizing agent include sulfur and organic sulfur-containing compounds. The amount of the vulcanizing agent added is preferably about 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the solid content (rubber part) in the rubber latex.
  • vulcanization accelerator for example, PX (zinc-ethyl-N-phenyldithiocarbamate), PZ (zinc dimethyldithiocarbamate), EZ (zinc diethyldithiocarbamate), BZ (zinc dibutyldithiocarbamate), MZ (2- The zinc salt of mercaptobenzothiazole), TT (tetramethyl thiuram disulfide), etc. 1 type, or 2 or more types are mentioned.
  • the amount of the vulcanization accelerator added is preferably 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
  • the vulcanization acceleration auxiliary for example, one or two kinds of zinc flower (zinc oxide), stearic acid and the like can be mentioned. It is preferable that the addition amount of the said vulcanization acceleration adjuvant is about 0.5 mass part or more and about 3 mass parts or less per 100 mass parts of rubber components in rubber latex.
  • non-staining phenols are preferably used as the antiaging agent, but amines may be used.
  • the amount of the anti-aging agent added is preferably about 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
  • the filler include one or more of kaolin clay, hard clay, calcium carbonate and the like.
  • the amount of the filler added is preferably about 10 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
  • the dispersant is added to disperse the various additives in the rubber latex well, and examples of the dispersant include one or more of anionic surfactants and the like. .
  • the addition amount of the dispersant is preferably about 0.3 parts by mass or more and about 1 part by mass or less of the total amount of the components to be dispersed.
  • a mold corresponding to the shape of the glove 1 shown in FIG. 1 is prepared, and the surface of the mold is treated with a coagulant such as calcium nitrate as needed.
  • various additives such as an antiaging agent, a filler, and a dispersing agent are added to the resin emulsion as necessary to prepare an immersion liquid.
  • the mold is immersed in the immersion liquid for a certain period of time and then pulled up, thereby adhering the immersion liquid to the surface of the mold.
  • the mold is heated as required to solidify the resin, or the pulled up mold is heated to dry the immersion liquid and the resin is solidified and then demolded as shown in FIG.
  • the glove 1 shown is manufactured.
  • resin 1 type (s) or 2 or more types of resin which can be emulsified, such as vinyl chloride resin, urethane type resin, acrylic resin, etc. are mentioned.
  • an antiaging agent 1 type (s) or 2 or more types, such as non-staining property phenols and amines which were illustrated previously are mentioned. It is preferable that the addition amount of the said antiaging agent is about 0.5 mass part or more and 3 mass parts or less with respect to 100 mass parts of solid content (resin part) in a resin emulsion.
  • the filler one or more of the above-mentioned fillers may be mentioned.
  • the amount of the filler added is preferably about 10 parts by mass or less per 100 parts by mass of the resin component in the resin emulsion.
  • a dispersing agent 1 type (s) or 2 or more types, such as an anionic surfactant of the said illustration, are mentioned.
  • the addition amount of the dispersant is preferably about 0.3 parts by mass or more and about 1 part by mass or less of the total amount of the components to be dispersed.
  • the glove 1 of the present invention is basically formed in a single layer structure by only a thin film of the rubber or resin, it may be reinforced by a fiber or the like as needed. That is, a so-called support type glove may be configured, in which a woven glove made of fiber and a rubber or resin film are integrated. In order to manufacture the support type glove, it is sufficient to form a film of rubber or resin by the above-described immersion method and integrate it with the knitted glove in a state where the knitted glove is attached to the surface of the type in advance. .
  • knitted gloves examples include seamless knitted gloves and knitted knitted gloves in which fibers such as cotton, nylon and polyester are knitted.
  • Example 1 (Preparation of immersion liquid) Natural rubber latex, 1 part by mass of sulfur (vulcanizing agent), 1 part by mass of vulcanization accelerator BZ (zinc dibutyldithiocarbamate), 100 parts by mass of the rubber component in the natural rubber latex, An additive was prepared by adding 1 part by mass of the anti-aging agent and an appropriate amount of an anti-aging agent (butylated product of p-cresol and dichloropentadiene) and then pre-curing at 30 ° C. for 24 to 48 hours to prepare an immersion liquid.
  • an anti-aging agent butylated product of p-cresol and dichloropentadiene
  • the surface of the mold was treated with calcium nitrate as a coagulant by immersing the mold in an aqueous solution of calcium nitrate, pulling it up and drying it.
  • the mold was immersed at a constant speed in the former immersion liquid kept at a liquid temperature of 25 ° C., held for 30 seconds, and then pulled up at a constant speed to cause the immersion liquid to adhere to the surface of the mold.
  • each pulled mold is placed in an oven heated to 100 ° C. and heated for 60 minutes to dry the immersion liquid while vulcanizing the rubber and then demolding to obtain a natural rubber having a three-dimensional shape shown in FIG.
  • the glove 1 of the single layer structure which consists only of a film was manufactured.
  • the thickness of the sleeve 2 of the glove 1 was measured using a micrometer, and the average thickness was 0.45 mm.
  • Examples 2 to 4 The shape of the mold was adjusted so that the stretch ratio E at the cuff 4 was 1 / 0.9 (Example 2), 1 / 0.8 (Example 3), and 1 / 0.6 (Example 4).
  • Example 2 The stretch ratio E at the cuff 4 was 1 / 0.9 (Example 2), 1 / 0.8 (Example 3), and 1 / 0.6 (Example 4).
  • a glove 1 having a single-layer structure consisting only of a natural rubber film was produced. In all cases, the depth D of the pleats 11 at the cuff 4 was 5 mm.
  • Example 5 The shape of the mold was adjusted, and in the same manner as in Example 1 except that the length L of the sleeve portion 2 was 9 cm, a single-layered glove 1 consisting only of a natural rubber film was produced. Comparative Example 1 A single-layered glove consisting only of a natural rubber film was manufactured in the same manner as in Example 1 except that the shape of the mold was adjusted and the depth of the pleats 11 was made constant from one end 7 to the cuff 4. The constant depth D is 5 mm, and the expansion ratio E is 1 / 0.85.
  • Comparative Example 2 The shape of the mold was adjusted, and the start position of the pleat 11 was set 5 cm below the end 7 to the side of the cuff 4 and the pleat 11 gradually deepened from there to the cuff 4 and Example 1 and Similarly, a single-layered glove consisting only of a film of natural rubber was manufactured.
  • the stretch ratio E at the start position was 1, the stretch ratio E at the cuff 4 was 1 / 0.85, and the depth D was 5 mm.
  • Comparative Example 3 The shape of the mold was adjusted, and in the same manner as in Example 1 except that the pleats 11 were not provided in the sleeve portion 2, a glove having a single layer structure consisting only of a natural rubber film was produced.
  • ⁇ Removability evaluation> The subject manufactured the gloves manufactured in the example and the comparative example to be repeatedly attached and detached 10 times, and the time required during that time was measured to evaluate the detachment according to the following criteria.
  • ⁇ 20 seconds or less. ⁇ : More than 20 seconds, 25 seconds or less. :: more than 25 seconds, less than 30 seconds. X: more than 30 seconds. ⁇ Evaluation of the effect to prevent folding and sagging> After having the subject wear the gloves manufactured in the example and the comparative example and raising and lowering the arm 10 times, measure the distance the cuff is shifted toward the glove body compared with immediately after wearing, and fold back according to the following criteria The dripping prevention effect was evaluated.
  • the sleeve 2 is provided with the pleats 11 which reach the cuff 4 from the one end 7 and the depth D gradually increases from the one end 7 toward the cuff 4
  • the expansion and contraction ratio E of the sleeve 2 is in the range of 1 / 0.9 or more and 1 / 0.6 or less for the cuff 7 and 1 at one end 7. understood.
  • the length L of the sleeve 2 is preferably 10 cm or more.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Gloves (AREA)

Abstract

L'invention concerne un gant pour lequel on peut éviter efficacement qu'il ne s'enlève à partir d'une section manche vers le corps du gant ou qu'il ne s'enlève ou ne tombe de la main en une seule pièce, sans attacher ou détacher un mécanisme d'arrêt ou porter le gant avec un protecteur de coude et, de ce fait, l'incursion d'eau dans le gant est quasiment impossible. Un gant (1) qui comprend une section manche à peu près tubulaire (2), un corps de gant (3) raccordé à une extrémité (7) de celle-ci, ladite section manche (2) et ledit corps de gant (3) étant fabriqués intégralement à partir d'un film de caoutchouc ou de résine, et un revers (4) constituant une ouverture située à l'autre extrémité de la section manche (2), plusieurs plis (11) rejoignant le revers (4) étant formés sur toute la circonférence de la section manche (2), lesdits plis (11) étant formés de ladite extrémité (7) vers le revers (4) et augmentant de taille vers ce dernier.
PCT/JP2011/079538 2011-02-07 2011-12-20 Gant WO2012108107A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-024210 2011-02-07
JP2011024210A JP2012162825A (ja) 2011-02-07 2011-02-07 手袋

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WO2012108107A1 true WO2012108107A1 (fr) 2012-08-16

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PCT/JP2011/079538 WO2012108107A1 (fr) 2011-02-07 2011-12-20 Gant

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014136858A (ja) * 2013-01-15 2014-07-28 Tzong-Dar Wu 防水通気ソックスの製造方法及びその製品
CN110613195A (zh) * 2018-06-18 2019-12-27 尚和手套株式会社 手套

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6305022B2 (ja) * 2013-11-13 2018-04-04 住友ゴム工業株式会社 天然ゴム手袋
JP6308652B2 (ja) * 2013-12-11 2018-04-11 住友ゴム工業株式会社 薄膜製品の製造方法
JP7386497B2 (ja) * 2018-06-18 2023-11-27 ショーワグローブ株式会社 手袋

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49128419U (fr) * 1973-03-05 1974-11-05
JPS61180114U (fr) * 1985-04-25 1986-11-10
JP2004162222A (ja) * 2002-11-14 2004-06-10 Sumitomo Rubber Ind Ltd サポート型手袋

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49128419U (fr) * 1973-03-05 1974-11-05
JPS61180114U (fr) * 1985-04-25 1986-11-10
JP2004162222A (ja) * 2002-11-14 2004-06-10 Sumitomo Rubber Ind Ltd サポート型手袋

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014136858A (ja) * 2013-01-15 2014-07-28 Tzong-Dar Wu 防水通気ソックスの製造方法及びその製品
CN110613195A (zh) * 2018-06-18 2019-12-27 尚和手套株式会社 手套

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