WO2012108107A1 - Glove - Google Patents

Glove Download PDF

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Publication number
WO2012108107A1
WO2012108107A1 PCT/JP2011/079538 JP2011079538W WO2012108107A1 WO 2012108107 A1 WO2012108107 A1 WO 2012108107A1 JP 2011079538 W JP2011079538 W JP 2011079538W WO 2012108107 A1 WO2012108107 A1 WO 2012108107A1
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WO
WIPO (PCT)
Prior art keywords
glove
cuff
sleeve
rubber
pleats
Prior art date
Application number
PCT/JP2011/079538
Other languages
French (fr)
Japanese (ja)
Inventor
越智 敦子
Original Assignee
住友ゴム工業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友ゴム工業株式会社 filed Critical 住友ゴム工業株式会社
Publication of WO2012108107A1 publication Critical patent/WO2012108107A1/en

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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/0044Cuff portions

Definitions

  • the present invention relates to a glove integrally formed of a film of rubber or resin as a whole.
  • a substantially cylindrical sleeve and a glove main body which is continuous with one end of the sleeve and protects from the wrist to the fingertip are natural rubber, acrylonitrile-butadiene
  • a glove which is integrally formed of a synthetic rubber such as rubber (NBR) or a resin such as a vinyl chloride resin or a urethane resin and which has the other end of the sleeve open as a cuff is widely used.
  • the gloves have various thicknesses, but in recent years, in order to improve the fit to the hand and the workability in the state of wearing the gloves, in particular, the gloves are formed only by the thin film of rubber or resin.
  • the demand for soft, flexible gloves tends to increase. However, the more flexible and the thinner the film, the lower the rigidity tends to be. Therefore, for example, when the thin glove is worn and actually used, the sleeve that should cover the area from the wrist to the forearm may fall toward the glove body, or the entire glove may be easily detached or detached from the hand. For example, when used for water work, there is a problem that bouncing water comes in and there is no point in wearing gloves.
  • Patent Documents 1 and 2 and the like a prevention tool for clipping a cuff of a glove to prevent slipping is proposed, but such a prevention tool is used prior to use of the glove. Wearing or removing after use is troublesome.
  • Patent Document 3 describes a glove provided with a strap at the cuff of the glove, but it is also troublesome to tighten the strap prior to use of the glove or loosen it after use.
  • Patent Document 4 describes a tubular elbow used in combination with a short glove and provided with a plurality of pleats reaching from the one end side to the other end side.
  • the elbow protector is unlikely to slip off the elbow due to the circumferential stretchability by providing the pleats, but such an elbow protector, together with the glove, has no gap between the two. Wearing or removing with gloves is still cumbersome.
  • the elbow protector may be displaced due to, for example, expansion and contraction of the elbow, causing a gap between the glove and the glove, and water may infiltrate from there, which is not perfect.
  • Patent Documents 5 and 6 disclose that a plurality of pleats extending from the fingertip to the cuff are provided on the back side of the glove from the fingertip to the entire cuff. However, these pleats are all for preventing the gloves from adhering to the hand on the back side of the hand and for ensuring air permeability, and are not considered for slip prevention. That is, since the gloves of Patent Documents 5 and 6 are pleated only on the back side of the hand of the glove as described above, they impart elasticity as in the case of the above-mentioned elbow protection to prevent the sleeves from slipping off. There is no function.
  • the object of the present invention is to allow the sleeves to slip towards the body of the glove, or the entire glove to come off or come out of the hand, without putting on and taking off the guard or attaching it with the elbow protection. It is to provide a glove that can reliably prevent the ingress of water and the like as a result.
  • the inventor forms a pleat over the entire circumference of the sleeve part of the glove to impart good stretchability to the sleeve part, and the sleeve part is shifted toward the glove body
  • pleats with a constant depth such as the pleats of the elbow protection described in Patent Document 4 described above
  • The tightness against the narrowest wrist, especially in the forearm, becomes worse, and the workability in the state of wearing the glove decreases.
  • the sleeve was folded back and down in the middle of the work, and the water splashed during water work could not surely be prevented from invading from the cuff.
  • the rubber or resin film should be thickened to increase the rigidity, but in that case the amount of rubber or resin forming the glove will increase and the glove will become heavier or the cost will There is a problem of getting expensive. Therefore, as a result of further examination of the depth of the pleats, it was found that the depth of the pleats formed over the entire circumference of the sleeve may be gradually deepened from one end connected to the glove body toward the cuff. It came to complete.
  • the substantially cylindrical sleeve portion and the glove main body connected to one end of the sleeve portion are integrally formed of a film of rubber or resin, and the other end of the sleeve portion is opened as a cuff.
  • the sleeve portion is provided with a plurality of pleats that reach the cuff from one end connected to the glove body over the entire circumference, and each pleat has a gradually increasing depth from the one end to the cuff It is characterized by the fact that
  • the vicinity of the one end corresponding to the narrowest wrist among the forearm can be firmly fitted to the wrist, and the workability in the state of wearing the glove can be improved. Moreover, since the appropriate stretchability can be provided near the one end by the pleat provided on the entire circumference, there is no possibility that the ease of wearing of the glove is impeded.
  • each pleat since the depth of each pleat is gradually increased from the one end toward the cuff, the thickness of the rubber or resin film forming the sleeve is not increased. It is also possible to provide appropriate rigidity to prevent the occurrence of folding or drooping. In addition, it is not necessary to increase the thickness of the sleeves, and the amount of rubber and resin forming the glove can be increased to prevent the glove from becoming heavy and costly.
  • the extent to which the depth of the pleats differs between one end of the sleeve and the cuff is expressed by the expansion ratio E determined by the equation (1). It is preferable to set a range of 1 / 0.9 or more and 1 / 0.6 or less in the cuff and to gradually increase the stretch ratio E from the one end to the cuff.
  • the stretch ratio E is 1 at one end of the sleeve and no pleat is formed at the one end, and the sleeve is in the vicinity of the wrist on the one end side by gradually deepening the pleat from there toward the cuff The effect of making it fit well can be further improved.
  • the expansion ratio E is 1 / 0.9 or more in the cuff, it is possible to further improve the effect of imparting appropriate rigidity to the sleeve to prevent folding and drooping.
  • the stretch ratio E of the cuff is 1 / 0.6 or less because, for example, at the time of manufacture of a glove by a general immersion method, uneven thickness and cracks occur due to the pleat being too deep in the cuff. To prevent In the case where such uneven thickness or cracking occurs, on the contrary, folding or drooping tends to occur.
  • the length of the sleeve from the one end to the cuff is preferably 10 cm or more. Shorter sleeves are less prone to folding and drooping, but if they are shorter than the above-mentioned range, there is a possibility that the splashed water can not be reliably prevented from entering during water work.
  • the thickness of the rubber or resin forming the glove is considered to prevent the glove from becoming heavy or expensive due to an increase in the amount of rubber or resin forming the glove as described above. Then, it is preferable that it is 2.0 mm or less. However, if the thickness of the membrane is too small, even if pleated, it may not be possible to prevent the occurrence of folding or sagging by giving an appropriate rigidity to the sleeve. Therefore, the thickness of the membrane is preferably 0.1 mm or more.
  • the sleeves fall off toward the glove body, or the entire glove slips out of the hand, without putting on and taking off the guard or attaching it with the elbow protection.
  • FIG. 1 It is a front view showing an example of an embodiment of a glove of the present invention. It is a figure explaining the outline of the pleat of the glove of the example of FIG.
  • FIG. 1 is a front view showing an example of the embodiment of the glove of the present invention.
  • FIG. 2 is a view for explaining an outline of pleats of the glove of the example of FIG.
  • a substantially cylindrical sleeve 2 and a glove body 3 connected to one end of the sleeve 2 are integrally formed of a rubber or resin film, and the sleeve The other end of the part 2 is opened as a cuff 4.
  • the glove body 3 has a palm 5 connected to the sleeve 2 and a plurality of fingers 6 connected to the palm 5 corresponding to the shape of a hand as in the prior art.
  • the sleeve portion 2 is formed of a first sleeve portion 8 on one end 7 side connected to the glove body 3 side, and a second sleeve portion 9 constituting the cuff 4. Both sleeves 8 and 9 are integrally connected at the boundary 10.
  • the first sleeve portion 8 is formed in a substantially truncated cone shape whose circumferential length gradually increases from the one end 7 side toward the boundary portion 10.
  • the second sleeve 9 is formed in a substantially truncated cone shape whose circumferential length gradually increases from the boundary 10 to the cuff 4.
  • the circumferential lengths of the two sleeves 8 and 9 at the boundary 10 are the same, whereby the two sleeves 8 and 9 are integrally connected over the entire circumference.
  • the slope of the generatrices forming the conical surface of the second sleeve 9 is greater than the slope of the generatrices constituting the conical surface of the first sleeve 8 so that the second sleeve 9 opens largely at the cuff 4 It is done.
  • Plural pleats 11 that reach the cuff 4 from one end 7 connected to the palm part 5 of the glove body 3 are provided on the sleeve part 2 consisting of both sleeve parts 8 and 9 over the entire circumference.
  • Each pleat 11 is formed in a substantially sine curve shape in cross section as shown in FIG.
  • Each pleat 11 has a depth D shown in FIG. 2 gradually deepened from one end 7 to the cuff 4. There is no particular limitation on how much the depths of the pleats 11 are different between one end 7 of the sleeve 2 and the cuff 4, but in the free state where no stress is applied to the parts forming the glove 1.
  • the first sleeve 8 at the one end 7 side It can be fitted firmly around the wrist. Moreover, since the appropriate stretchability can be provided near the one end 7 by the pleats 11 provided on the entire circumference, there is no possibility that the ease of wearing the glove 1 is impeded.
  • the sleeve 2 that is, the first and second sleeves 8, 9 is given appropriate rigidity to prevent folding and sagging. can do.
  • the stretch ratio E of the cuff 4 is preferably 1 / 0.6 or less because, for example, when the glove 1 is manufactured by a general immersion method, the uneven thickness associated with the pleat 11 being too deep in the cuff 4 or It is for preventing that a crack arises. In the case where such uneven thickness or cracking occurs, on the contrary, folding or drooping tends to occur.
  • the specific depth D of the pleats 11 can be arbitrarily set to satisfy the expansion ratio E according to the size of the glove 1 etc., but the cuff 4 is preferably 3 mm or more, particularly 4 mm or more, It is preferably 7 mm or less, particularly 6 mm or less.
  • the cuff 4 is given appropriate rigidity while preventing occurrence of uneven thickness or cracking during manufacturing of the glove 1, and folding or sagging is caused. It can be prevented.
  • the length L of the sleeve 2 from the one end 7 to the cuff 4 is preferably 10 cm or more, and more preferably 20 cm or more. As the sleeve 2 is shorter, it is less likely to cause folding or drooping, but if it is shorter than the above range, there is a possibility that the splashed water can not be reliably prevented from entering during water work.
  • the length L is preferably 40 cm or less, particularly 30 cm or less, in consideration of covering up to the vicinity of the elbow, for example.
  • the thickness of the rubber or resin forming the glove 1 is to prevent the glove from becoming heavy or costly because the amount of rubber or resin forming the glove 1 is increased as described above. It is preferable that it is 2.0 mm or less, especially 1.5 mm or less in consideration of. However, if the thickness of the membrane is too small, even if the pleats 11 are attached, there is a possibility that the sleeve 2 can not be provided with an appropriate rigidity to prevent the occurrence of folding or drooping. Therefore, the thickness of the film is preferably 0.1 mm or more, particularly 0.2 mm or more.
  • the entire glove 1 does not have to be within the above thickness range, and for example, the cuff 4 is made thicker than the other portions to give appropriate rigidity so as to further prevent folding or drooping, or the tip of the finger 6 May be thicker than other parts to protect the fingertip.
  • the glove 1 can be configured in the same manner as the conventional one except that the sleeve 2 has the pleats 11.
  • the glove 1 is formed by depositing a rubber latex in the shape of the glove 1 shown in FIG. 1 by dipping as in the prior art and vulcanizing the rubber or forming an emulsion of resin into the shape of the glove 1 by dipping. It can be manufactured by drying and solidifying the resin while filming.
  • a mold corresponding to the shape of the glove 1 shown in FIG. 1 is prepared, and the surface of the mold is treated with a coagulant such as calcium nitrate.
  • various additives such as a vulcanizing agent, a vulcanization accelerator, a vulcanization acceleration assistant (activator), an antiaging agent, a filler, a dispersant and the like are added to the rubber latex to obtain an unvulcanized or prevulcanized state.
  • a vulcanizing agent such as a vulcanizing agent, a vulcanization accelerator, a vulcanization acceleration assistant (activator), an antiaging agent, a filler, a dispersant and the like are added to the rubber latex to obtain an unvulcanized or prevulcanized state.
  • the mold is immersed in the immersion liquid for a certain period of time and then pulled up, thereby adhering the immersion liquid to the surface of the mold.
  • the glove as shown in FIG. 1 is then heated either to heat the mold so as to dry the immersion liquid and to vulcanize the rubber, or to heat it once to cure it and then to vulcanize the rubber and then to demold it. 1 is manufactured.
  • any of natural rubber and various rubbers which can be made into latex from synthetic rubber can be used, and as such rubber, for example, natural rubber, deproteinized natural rubber, NBR, styrene-butadiene rubber ( 1 type or 2 types or more, such as SBR) and chloroprene rubber (CR), are mentioned.
  • the vulcanizing agent include sulfur and organic sulfur-containing compounds. The amount of the vulcanizing agent added is preferably about 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the solid content (rubber part) in the rubber latex.
  • vulcanization accelerator for example, PX (zinc-ethyl-N-phenyldithiocarbamate), PZ (zinc dimethyldithiocarbamate), EZ (zinc diethyldithiocarbamate), BZ (zinc dibutyldithiocarbamate), MZ (2- The zinc salt of mercaptobenzothiazole), TT (tetramethyl thiuram disulfide), etc. 1 type, or 2 or more types are mentioned.
  • the amount of the vulcanization accelerator added is preferably 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
  • the vulcanization acceleration auxiliary for example, one or two kinds of zinc flower (zinc oxide), stearic acid and the like can be mentioned. It is preferable that the addition amount of the said vulcanization acceleration adjuvant is about 0.5 mass part or more and about 3 mass parts or less per 100 mass parts of rubber components in rubber latex.
  • non-staining phenols are preferably used as the antiaging agent, but amines may be used.
  • the amount of the anti-aging agent added is preferably about 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
  • the filler include one or more of kaolin clay, hard clay, calcium carbonate and the like.
  • the amount of the filler added is preferably about 10 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
  • the dispersant is added to disperse the various additives in the rubber latex well, and examples of the dispersant include one or more of anionic surfactants and the like. .
  • the addition amount of the dispersant is preferably about 0.3 parts by mass or more and about 1 part by mass or less of the total amount of the components to be dispersed.
  • a mold corresponding to the shape of the glove 1 shown in FIG. 1 is prepared, and the surface of the mold is treated with a coagulant such as calcium nitrate as needed.
  • various additives such as an antiaging agent, a filler, and a dispersing agent are added to the resin emulsion as necessary to prepare an immersion liquid.
  • the mold is immersed in the immersion liquid for a certain period of time and then pulled up, thereby adhering the immersion liquid to the surface of the mold.
  • the mold is heated as required to solidify the resin, or the pulled up mold is heated to dry the immersion liquid and the resin is solidified and then demolded as shown in FIG.
  • the glove 1 shown is manufactured.
  • resin 1 type (s) or 2 or more types of resin which can be emulsified, such as vinyl chloride resin, urethane type resin, acrylic resin, etc. are mentioned.
  • an antiaging agent 1 type (s) or 2 or more types, such as non-staining property phenols and amines which were illustrated previously are mentioned. It is preferable that the addition amount of the said antiaging agent is about 0.5 mass part or more and 3 mass parts or less with respect to 100 mass parts of solid content (resin part) in a resin emulsion.
  • the filler one or more of the above-mentioned fillers may be mentioned.
  • the amount of the filler added is preferably about 10 parts by mass or less per 100 parts by mass of the resin component in the resin emulsion.
  • a dispersing agent 1 type (s) or 2 or more types, such as an anionic surfactant of the said illustration, are mentioned.
  • the addition amount of the dispersant is preferably about 0.3 parts by mass or more and about 1 part by mass or less of the total amount of the components to be dispersed.
  • the glove 1 of the present invention is basically formed in a single layer structure by only a thin film of the rubber or resin, it may be reinforced by a fiber or the like as needed. That is, a so-called support type glove may be configured, in which a woven glove made of fiber and a rubber or resin film are integrated. In order to manufacture the support type glove, it is sufficient to form a film of rubber or resin by the above-described immersion method and integrate it with the knitted glove in a state where the knitted glove is attached to the surface of the type in advance. .
  • knitted gloves examples include seamless knitted gloves and knitted knitted gloves in which fibers such as cotton, nylon and polyester are knitted.
  • Example 1 (Preparation of immersion liquid) Natural rubber latex, 1 part by mass of sulfur (vulcanizing agent), 1 part by mass of vulcanization accelerator BZ (zinc dibutyldithiocarbamate), 100 parts by mass of the rubber component in the natural rubber latex, An additive was prepared by adding 1 part by mass of the anti-aging agent and an appropriate amount of an anti-aging agent (butylated product of p-cresol and dichloropentadiene) and then pre-curing at 30 ° C. for 24 to 48 hours to prepare an immersion liquid.
  • an anti-aging agent butylated product of p-cresol and dichloropentadiene
  • the surface of the mold was treated with calcium nitrate as a coagulant by immersing the mold in an aqueous solution of calcium nitrate, pulling it up and drying it.
  • the mold was immersed at a constant speed in the former immersion liquid kept at a liquid temperature of 25 ° C., held for 30 seconds, and then pulled up at a constant speed to cause the immersion liquid to adhere to the surface of the mold.
  • each pulled mold is placed in an oven heated to 100 ° C. and heated for 60 minutes to dry the immersion liquid while vulcanizing the rubber and then demolding to obtain a natural rubber having a three-dimensional shape shown in FIG.
  • the glove 1 of the single layer structure which consists only of a film was manufactured.
  • the thickness of the sleeve 2 of the glove 1 was measured using a micrometer, and the average thickness was 0.45 mm.
  • Examples 2 to 4 The shape of the mold was adjusted so that the stretch ratio E at the cuff 4 was 1 / 0.9 (Example 2), 1 / 0.8 (Example 3), and 1 / 0.6 (Example 4).
  • Example 2 The stretch ratio E at the cuff 4 was 1 / 0.9 (Example 2), 1 / 0.8 (Example 3), and 1 / 0.6 (Example 4).
  • a glove 1 having a single-layer structure consisting only of a natural rubber film was produced. In all cases, the depth D of the pleats 11 at the cuff 4 was 5 mm.
  • Example 5 The shape of the mold was adjusted, and in the same manner as in Example 1 except that the length L of the sleeve portion 2 was 9 cm, a single-layered glove 1 consisting only of a natural rubber film was produced. Comparative Example 1 A single-layered glove consisting only of a natural rubber film was manufactured in the same manner as in Example 1 except that the shape of the mold was adjusted and the depth of the pleats 11 was made constant from one end 7 to the cuff 4. The constant depth D is 5 mm, and the expansion ratio E is 1 / 0.85.
  • Comparative Example 2 The shape of the mold was adjusted, and the start position of the pleat 11 was set 5 cm below the end 7 to the side of the cuff 4 and the pleat 11 gradually deepened from there to the cuff 4 and Example 1 and Similarly, a single-layered glove consisting only of a film of natural rubber was manufactured.
  • the stretch ratio E at the start position was 1, the stretch ratio E at the cuff 4 was 1 / 0.85, and the depth D was 5 mm.
  • Comparative Example 3 The shape of the mold was adjusted, and in the same manner as in Example 1 except that the pleats 11 were not provided in the sleeve portion 2, a glove having a single layer structure consisting only of a natural rubber film was produced.
  • ⁇ Removability evaluation> The subject manufactured the gloves manufactured in the example and the comparative example to be repeatedly attached and detached 10 times, and the time required during that time was measured to evaluate the detachment according to the following criteria.
  • 20 seconds or less. ⁇ : More than 20 seconds, 25 seconds or less. :: more than 25 seconds, less than 30 seconds. X: more than 30 seconds. ⁇ Evaluation of the effect to prevent folding and sagging> After having the subject wear the gloves manufactured in the example and the comparative example and raising and lowering the arm 10 times, measure the distance the cuff is shifted toward the glove body compared with immediately after wearing, and fold back according to the following criteria The dripping prevention effect was evaluated.
  • the sleeve 2 is provided with the pleats 11 which reach the cuff 4 from the one end 7 and the depth D gradually increases from the one end 7 toward the cuff 4
  • the expansion and contraction ratio E of the sleeve 2 is in the range of 1 / 0.9 or more and 1 / 0.6 or less for the cuff 7 and 1 at one end 7. understood.
  • the length L of the sleeve 2 is preferably 10 cm or more.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Gloves (AREA)

Abstract

Provided is a glove, whereby a slip off of a sleeve section toward a glove body or a slip off or drop off of the glove as a whole from the hand can be surely prevented, without attaching/detaching a stopper or wearing the glove together with an elbow protector and, as a result, the invasion of water into the glove is hardly allowed. A glove (1), which comprises a roughly tubular sleeve section (2), a glove body (3) connected to one end (7) thereof, said sleeve section (2) and said glove body (3) being integrally formed of a rubber or resin film, and a cuff (4) that is an opening located at the other end of the sleeve section (2), wherein multiple pleats (11) reaching the cuff (4) are formed over the whole circumference of the sleeve section (2), said pleats (11) running from the aforesaid end (7) toward the cuff (4) with a gradual increase in the depth thereof.

Description

手袋gloves
 本発明は、全体がゴムまたは樹脂の膜によって一体に形成された手袋に関するものである。 The present invention relates to a glove integrally formed of a film of rubber or resin as a whole.
 一般家庭用から各種産業における作業用、さらには医療用の手袋として、略筒状の袖部と、前記袖部の一端に連なり手首から指先までを保護する手袋本体とを天然ゴム、アクリロニトリル-ブタジエンゴム(NBR)等の合成ゴム、あるいは塩化ビニル系樹脂、ウレタン系樹脂等の樹脂等によって一体に形成し、かつ前記袖部の他端を袖口として開口した手袋が広く普及している。 As a glove for work in general household use to various industries, and as a medical glove, a substantially cylindrical sleeve and a glove main body which is continuous with one end of the sleeve and protects from the wrist to the fingertip are natural rubber, acrylonitrile-butadiene A glove which is integrally formed of a synthetic rubber such as rubber (NBR) or a resin such as a vinyl chloride resin or a urethane resin and which has the other end of the sleeve open as a cuff is widely used.
 また前記手袋としては様々な厚みを有するものがあるが、特に近年は、手に対するフィット性や手袋を装着した状態での作業性等を向上するために、前記ゴムや樹脂の薄い膜のみによって形成された、軟らかく柔軟性のある手袋に対する需要が増加する傾向にある。
 しかし前記膜は柔軟であるほど、また薄いほど剛性が低下する傾向にある。そのため、例えば前記薄手の手袋を装着して実際に使用した際に、手首から前腕にかけてを覆うべき袖部が手袋本体の方にずれ落ちたり、手袋の全体が手からずれたり外れたりしやすくなって、例えば水仕事に使用した際に、跳ねた水が中に入って手袋をしている意味がなくなってしまうといった問題がある。
The gloves have various thicknesses, but in recent years, in order to improve the fit to the hand and the workability in the state of wearing the gloves, in particular, the gloves are formed only by the thin film of rubber or resin. The demand for soft, flexible gloves tends to increase.
However, the more flexible and the thinner the film, the lower the rigidity tends to be. Therefore, for example, when the thin glove is worn and actually used, the sleeve that should cover the area from the wrist to the forearm may fall toward the glove body, or the entire glove may be easily detached or detached from the hand. For example, when used for water work, there is a problem that bouncing water comes in and there is no point in wearing gloves.
 前記問題を解決するため、例えば特許文献1、2等においては、手袋の袖口をクリップしてずれ落ちを防止するための防止具が提案されているが、手袋の使用に先立ってかかる防止具を装着したり、使用後に取り外したりするのは面倒である。
 また特許文献3には、前記手袋の袖口に締め紐を設けた手袋が記載されているが、手袋の使用に先立ってかかる締めひもを締めたり、使用後に緩めたりするのはやはり面倒である。
In order to solve the above-mentioned problems, for example, in Patent Documents 1 and 2 and the like, a prevention tool for clipping a cuff of a glove to prevent slipping is proposed, but such a prevention tool is used prior to use of the glove. Wearing or removing after use is troublesome.
Patent Document 3 describes a glove provided with a strap at the cuff of the glove, but it is also troublesome to tighten the strap prior to use of the glove or loosen it after use.
 特許文献4には、短い手袋と併用する筒状で、かつその一端側から他端側に達する複数のプリーツが設けられた肘保護物が記載されている。前記肘保護物は、前記プリーツを設けたことによる周方向の伸縮性によって肘からずれ落ちたりしにくいものであるが、かかる肘保護物を、手袋とともに、両者の間に隙間が生じないように装着したり、あるいは手袋とともに外したりするのはやはり面倒である。また使用中に、例えば肘の伸縮等によって肘保護物がずれて手袋との間に隙間を生じて、そこから水が侵入してしまう場合があり、万全ではない。 Patent Document 4 describes a tubular elbow used in combination with a short glove and provided with a plurality of pleats reaching from the one end side to the other end side. The elbow protector is unlikely to slip off the elbow due to the circumferential stretchability by providing the pleats, but such an elbow protector, together with the glove, has no gap between the two. Wearing or removing with gloves is still cumbersome. In addition, during use, the elbow protector may be displaced due to, for example, expansion and contraction of the elbow, causing a gap between the glove and the glove, and water may infiltrate from there, which is not perfect.
 特許文献5、6には、手袋の手の甲側の、指先から袖口にかけての全体に、前記指先から袖口に達する複数のプリーツを設けることが記載されている。しかしこれらのプリーツは、いずれも手の甲側で手袋が手に密着するのを防止し、通気性を確保するためのものであって、ずれ防止用としての考慮はされていない。
 すなわち特許文献5、6の手袋は、前記のように手袋の手の甲側にのみプリーツが形成されるため、先の肘保護物のように伸縮性を付与して袖部がずれ落ちるのを防止する機能は備えていない。
Patent Documents 5 and 6 disclose that a plurality of pleats extending from the fingertip to the cuff are provided on the back side of the glove from the fingertip to the entire cuff. However, these pleats are all for preventing the gloves from adhering to the hand on the back side of the hand and for ensuring air permeability, and are not considered for slip prevention.
That is, since the gloves of Patent Documents 5 and 6 are pleated only on the back side of the hand of the glove as described above, they impart elasticity as in the case of the above-mentioned elbow protection to prevent the sleeves from slipping off. There is no function.
特開2007-119982号公報JP 2007-119982 A 特開2008-2044号公報JP 2008-2044 A 特開平11-286809号公報Japanese Patent Application Laid-Open No. 11-286809 実開平4-97805号公報Japanese Utility Model Application Publication No. 4-97805 実開昭49-82913号公報Japanese Utility Model Publication No. 49-82913 実開平3-24114号公報Japanese Utility Model Application Publication No. 3-24114
 本発明の目的は、防止具を着脱したり、肘保護物と一緒に装着したりすることなしに、袖部が手袋本体の方にずれ落ちたり、手袋の全体が手からずれたり外れたりするのを確実に防止でき、結果的に水等が侵入し難い手袋を提供することにある。 The object of the present invention is to allow the sleeves to slip towards the body of the glove, or the entire glove to come off or come out of the hand, without putting on and taking off the guard or attaching it with the elbow protection. It is to provide a glove that can reliably prevent the ingress of water and the like as a result.
 前記課題を解決するため、発明者は、手袋の袖部の全周に亘ってプリーツを形成することで、袖部に良好な伸縮性を付与して、前記袖部が手袋本体の方にずれ落ちたり、手袋の全体が手からずれたり外れたりするのを防止することを検討した。しかし、前記特許文献4に記載された肘保護物のプリーツのような、深さが一定のプリーツを袖部に設けた場合には、
・ 特に前腕部の中で最も細い手首に対する締りが悪くなって、手袋を装着した状態での作業性が低下したり、
・ 作業途中に袖部が途中で折り返されたり垂れ下がったりして、水仕事の際に跳ねた水が袖口から侵入するのを確実に防止できなかったり、することが判った。
In order to solve the above problems, the inventor forms a pleat over the entire circumference of the sleeve part of the glove to impart good stretchability to the sleeve part, and the sleeve part is shifted toward the glove body We considered to prevent falling and the whole glove from coming off the hand or coming off. However, in the case where pleats with a constant depth, such as the pleats of the elbow protection described in Patent Document 4 described above, are provided in the sleeves,
・ The tightness against the narrowest wrist, especially in the forearm, becomes worse, and the workability in the state of wearing the glove decreases.
・ It was found that the sleeve was folded back and down in the middle of the work, and the water splashed during water work could not surely be prevented from invading from the cuff.
 折り返しや垂れ下がりを防止するには、ゴムまたは樹脂の膜を厚くして剛性を高めればよいが、その場合には手袋を形成するゴムや樹脂の量が増加して手袋が重くなったり、コストが高くついたりするという問題がある。
 そこでプリーツの深さについてさらに検討した結果、袖部の全周に亘って形成するプリーツの深さを、手袋本体に連なる一端から袖口に向けて徐々に深くすればよいことを見出し、本発明を完成するに至った。
In order to prevent folding and sagging, the rubber or resin film should be thickened to increase the rigidity, but in that case the amount of rubber or resin forming the glove will increase and the glove will become heavier or the cost will There is a problem of getting expensive.
Therefore, as a result of further examination of the depth of the pleats, it was found that the depth of the pleats formed over the entire circumference of the sleeve may be gradually deepened from one end connected to the glove body toward the cuff. It came to complete.
 すなわち本発明は、略筒状の袖部と、前記袖部の一端に連なる手袋本体とがゴムまたは樹脂の膜によって一体に形成され、かつ前記袖部の他端が袖口として開口された手袋であって、前記袖部には、前記手袋本体に連なる一端から袖口に達する複数のプリーツが全周に亘って設けられているとともに、前記各プリーツは、前記一端から袖口に向けて深さが徐々に深くなっていることを特徴とする。 That is, according to the present invention, the substantially cylindrical sleeve portion and the glove main body connected to one end of the sleeve portion are integrally formed of a film of rubber or resin, and the other end of the sleeve portion is opened as a cuff. The sleeve portion is provided with a plurality of pleats that reach the cuff from one end connected to the glove body over the entire circumference, and each pleat has a gradually increasing depth from the one end to the cuff It is characterized by the fact that
 本発明によれば、前記のように袖部の全周に亘って、手袋本体に連なる一端から袖口に達するプリーツを設けるとともに、各プリーツの深さを、前記一端近傍において浅くすることで、式(1):
 伸縮比E=R/R   (1)
〔式中、Rは手袋を形成する各部に応力を加えないフリーの状態での周長、Rは、同じ場所でプリーツがなくなるまで引き伸ばした時の周長を示す。〕によって求められる伸縮比Eを、前記一端近傍において小さくしている。
According to the present invention, as described above, while providing pleats that reach the cuff from one end connected to the glove body over the entire circumference of the sleeve, the depth of each pleat is made shallow in the vicinity of the one end. (1):
Expansion ratio E = R 2 / R 1 (1)
[Wherein, R 1 represents the circumferential length in a free state where no stress is applied to each part forming the glove, and R 2 represents the circumferential length when stretching is performed until pleats disappear in the same place. The expansion and contraction ratio E determined by
 そのため前記袖部のうち、前腕部の中でも最も細い手首に対応する前記一端近傍を、前記手首に対してしっかりフィットさせることができ、手袋を装着した状態での作業性を向上することができる。
 しかも前記一端近傍には、その全周に設けたプリーツによって適度な伸縮性を付与できるため、手袋の装着のしやすさが妨げられるおそれもない。
Therefore, among the sleeves, the vicinity of the one end corresponding to the narrowest wrist among the forearm can be firmly fitted to the wrist, and the workability in the state of wearing the glove can be improved.
Moreover, since the appropriate stretchability can be provided near the one end by the pleat provided on the entire circumference, there is no possibility that the ease of wearing of the glove is impeded.
 その上、前記各プリーツの深さを、前記一端から袖口へ向けて徐々に深くしているため、前記袖部を形成するゴムや樹脂の膜の厚みを大きくすることなしに、前記袖部に適度な剛性を付与して折り返しや垂れ下がりが発生するのを防止することもできる。また、そのために袖部の厚みを大きくする必要がなくなり、手袋を形成するゴムや樹脂の量が増加して手袋が重くなったり、コストが高くついたりするのを防止することもできる。 In addition, since the depth of each pleat is gradually increased from the one end toward the cuff, the thickness of the rubber or resin film forming the sleeve is not increased. It is also possible to provide appropriate rigidity to prevent the occurrence of folding or drooping. In addition, it is not necessary to increase the thickness of the sleeves, and the amount of rubber and resin forming the glove can be increased to prevent the glove from becoming heavy and costly.
 前記プリーツの深さを、袖部の一端と袖口との間でどの程度まで違えるかは特に限定されないが、前記式(1)によって求められる伸縮比Eで表して、袖部の一端において1、袖口において1/0.9以上、1/0.6以下の範囲内とするとともに、前記一端から袖口にかけて前記伸縮比Eが徐々に増加するように設定するのが好ましい。
 前記伸縮比Eを、袖部の一端において1として前記一端にはプリーツを形成せず、そこから袖口に向けてプリーツを徐々に深くしてゆくことにより、前記一端側で袖部を手首の付近にしっかりフィットさせる効果をさらに向上できる。
There is no particular limitation on the extent to which the depth of the pleats differs between one end of the sleeve and the cuff, but it is expressed by the expansion ratio E determined by the equation (1). It is preferable to set a range of 1 / 0.9 or more and 1 / 0.6 or less in the cuff and to gradually increase the stretch ratio E from the one end to the cuff.
The stretch ratio E is 1 at one end of the sleeve and no pleat is formed at the one end, and the sleeve is in the vicinity of the wrist on the one end side by gradually deepening the pleat from there toward the cuff The effect of making it fit well can be further improved.
 また、袖口において伸縮比Eを1/0.9以上に設定することにより、袖部に適度な剛性を付与して折り返しや垂れ下がりを防止する効果をさらに向上できる。なお袖口の伸縮比Eが1/0.6以下であるのが好ましいのは、例えば通常の浸漬法による手袋の製造時に、前記袖口において、プリーツが深すぎることに伴う偏肉や割れが生じるのを防止するためである。かかる偏肉や割れが生じた場合には、却って折り返しや垂れ下がりが発生しやすくなってしまう。 In addition, by setting the expansion ratio E to 1 / 0.9 or more in the cuff, it is possible to further improve the effect of imparting appropriate rigidity to the sleeve to prevent folding and drooping. In addition, it is preferable that the stretch ratio E of the cuff is 1 / 0.6 or less because, for example, at the time of manufacture of a glove by a general immersion method, uneven thickness and cracks occur due to the pleat being too deep in the cuff. To prevent In the case where such uneven thickness or cracking occurs, on the contrary, folding or drooping tends to occur.
 前記袖部の、前記一端から袖口までの長さは10cm以上であるのが好ましい。袖部が短いほど折り返しや垂れ下がりは生じにくいものの、前記範囲より短い場合には、水仕事の際に跳ねた水が中に入るのを確実に防止できないおそれがある。
 前記手袋を形成するゴムまたは樹脂の厚みは、先に説明したように手袋を形成するゴムや樹脂の量が増加して手袋が重くなったり、コストが高くついたりするのを防止することを考慮すると2.0mm以下であるのが好ましい。ただし膜の厚みが小さすぎる場合には、たとえプリーツをつけても、袖部に適度な剛性を付与して折り返しや垂れ下がりが発生するのを防止できないおそれがある。そのため膜の厚みは0.1mm以上であるのが好ましい。
The length of the sleeve from the one end to the cuff is preferably 10 cm or more. Shorter sleeves are less prone to folding and drooping, but if they are shorter than the above-mentioned range, there is a possibility that the splashed water can not be reliably prevented from entering during water work.
The thickness of the rubber or resin forming the glove is considered to prevent the glove from becoming heavy or expensive due to an increase in the amount of rubber or resin forming the glove as described above. Then, it is preferable that it is 2.0 mm or less. However, if the thickness of the membrane is too small, even if pleated, it may not be possible to prevent the occurrence of folding or sagging by giving an appropriate rigidity to the sleeve. Therefore, the thickness of the membrane is preferably 0.1 mm or more.
 本発明によれば、防止具を着脱したり、肘保護物と一緒に装着したりすることなしに、袖部が手袋本体の方にずれ落ちたり、手袋の全体が手からずれたり外れたりするのを確実に防止でき、結果的に水等が侵入し難い手袋を提供することができる。 According to the present invention, the sleeves fall off toward the glove body, or the entire glove slips out of the hand, without putting on and taking off the guard or attaching it with the elbow protection. As a result, it is possible to provide a glove in which water and the like are less likely to intrude.
本発明の手袋の、実施の形態の一例を示す正面図である。It is a front view showing an example of an embodiment of a glove of the present invention. 図1の例の手袋の、プリーツの概略を説明する図である。It is a figure explaining the outline of the pleat of the glove of the example of FIG.
 図1は、本発明の手袋の、実施の形態の一例を示す正面図である。図2は、図1の例の手袋の、プリーツの概略を説明する図である。
 両図を参照して、この例の手袋1は、略筒状の袖部2と、前記袖部2の一端に連なる手袋本体3とをゴムまたは樹脂の膜によって一体に形成し、かつ前記袖部2の他端を袖口4として開口したものである。
FIG. 1 is a front view showing an example of the embodiment of the glove of the present invention. FIG. 2 is a view for explaining an outline of pleats of the glove of the example of FIG.
With reference to both figures, in the glove 1 of this example, a substantially cylindrical sleeve 2 and a glove body 3 connected to one end of the sleeve 2 are integrally formed of a rubber or resin film, and the sleeve The other end of the part 2 is opened as a cuff 4.
 手袋本体3は、従来同様に手の形に対応させて、袖部2に繋がる掌部5と、前記掌部5に連なる複数の指部6とを備えている。
 袖部2は、前記手袋本体3側に繋がる一端7側の第一袖部8と、袖口4を構成する第二袖部9とで形成されている。両袖部8、9は、境界部10で一体に繋がれている。
 第一袖部8は、一端7側から境界部10へかけて周長が徐々に大きくなる略円錐台状に形成されている。また第二袖部9は、前記境界部10から袖口4へかけて周長が徐々に大きくなる略円錐台状に形成されている。両袖部8、9の、境界部10での周長は同一とされ、それによって両袖部8、9は全周に亘って一体に繋がれている。
The glove body 3 has a palm 5 connected to the sleeve 2 and a plurality of fingers 6 connected to the palm 5 corresponding to the shape of a hand as in the prior art.
The sleeve portion 2 is formed of a first sleeve portion 8 on one end 7 side connected to the glove body 3 side, and a second sleeve portion 9 constituting the cuff 4. Both sleeves 8 and 9 are integrally connected at the boundary 10.
The first sleeve portion 8 is formed in a substantially truncated cone shape whose circumferential length gradually increases from the one end 7 side toward the boundary portion 10. The second sleeve 9 is formed in a substantially truncated cone shape whose circumferential length gradually increases from the boundary 10 to the cuff 4. The circumferential lengths of the two sleeves 8 and 9 at the boundary 10 are the same, whereby the two sleeves 8 and 9 are integrally connected over the entire circumference.
 第二袖部9の円錐面を構成する母線の傾斜は、第一袖部8の円錐面を構成する母線の傾斜より大きくされており、それによって第二袖部9は、袖口4において大きく開口されている。
 両袖部8、9からなる袖部2には、手袋本体3の掌部5に連なる一端7から袖口4に達する複数のプリーツ11が、全周に亘って設けられている。
The slope of the generatrices forming the conical surface of the second sleeve 9 is greater than the slope of the generatrices constituting the conical surface of the first sleeve 8 so that the second sleeve 9 opens largely at the cuff 4 It is done.
Plural pleats 11 that reach the cuff 4 from one end 7 connected to the palm part 5 of the glove body 3 are provided on the sleeve part 2 consisting of both sleeve parts 8 and 9 over the entire circumference.
 各プリーツ11は、図2に示すように断面形状が略サインカーブ状に形成されている。前記各プリーツ11は、図2中に示す深さDが、一端7から袖口4にかけて徐々に深くされている。
 袖部2の一端7と袖口4との間でプリーツ11の深さをどの程度違えるかは特に限定されないが、前記深さを、手袋1を形成する各部に応力を加えないフリーの状態での周長Rと、プリーツを伸ばした時の周長Rとから、式(1):
 伸縮比E=R/R1   (1)
で求められる伸縮比Eで表したとき、前記一端7において1、袖口4において1/0.9以上、1/0.6以下の範囲内とするのが好ましい。
Each pleat 11 is formed in a substantially sine curve shape in cross section as shown in FIG. Each pleat 11 has a depth D shown in FIG. 2 gradually deepened from one end 7 to the cuff 4.
There is no particular limitation on how much the depths of the pleats 11 are different between one end 7 of the sleeve 2 and the cuff 4, but in the free state where no stress is applied to the parts forming the glove 1. From the circumferential length R 1 and the circumferential length R 2 when the pleats are extended, Formula (1):
Expansion ratio E = R 2 / R 1 (1)
When it is expressed by an expansion ratio E which is obtained by the equation (1), it is preferable to set it in the range of 1 / 0.9 or more and 1 / 0.6 or less in 1 at the one end 7 and in the cuff 4.
 前記伸縮比Eを一端7において1として前記一端7にはプリーツを形成せず、そこから袖口4に向けてプリーツを徐々に深くしてゆくことにより、前記一端7側で第一袖部8を手首の付近にしっかりフィットさせることができる。
 しかも前記一端7の近傍には、その全周に設けたプリーツ11によって適度な伸縮性を付与できるため、手袋1の装着のしやすさが妨げられるおそれもない。
By setting the expansion ratio E to 1 at one end 7 and forming no pleats at the one end 7, gradually deepening the pleat from there toward the cuff 4, the first sleeve 8 at the one end 7 side It can be fitted firmly around the wrist.
Moreover, since the appropriate stretchability can be provided near the one end 7 by the pleats 11 provided on the entire circumference, there is no possibility that the ease of wearing the glove 1 is impeded.
 また伸縮比Eを袖口4において1/0.9以上に設定することにより、袖部2、すなわち第一および第二の両袖部8、9に適度な剛性を付与して折り返しや垂れ下がりを防止することができる。なお袖口4の伸縮比Eが1/0.6以下であるのが好ましいのは、例えば通常の浸漬法による手袋1の製造時に、前記袖口4において、プリーツ11が深すぎることに伴う偏肉や割れが生じるのを防止するためである。かかる偏肉や割れが生じた場合には、却って折り返しや垂れ下がりが発生しやすくなってしまう。 In addition, by setting the expansion ratio E to 1 / 0.9 or more in the sleeve 4, the sleeve 2, that is, the first and second sleeves 8, 9 is given appropriate rigidity to prevent folding and sagging. can do. The stretch ratio E of the cuff 4 is preferably 1 / 0.6 or less because, for example, when the glove 1 is manufactured by a general immersion method, the uneven thickness associated with the pleat 11 being too deep in the cuff 4 or It is for preventing that a crack arises. In the case where such uneven thickness or cracking occurs, on the contrary, folding or drooping tends to occur.
 なおプリーツ11の具体的な深さDは、手袋1のサイズ等に応じて、前記伸縮比Eを満足するべく任意に設定できるが、袖口4において3mm以上、特に4mm以上であるのが好ましく、7mm以下、特に6mm以下であるのが好ましい。
 袖口4におけるプリーツ11の深さDを前記範囲内とすることで、手袋1の製造時に偏肉や割れが生じるのを防止しながら、前記袖口4に適度な剛性を付与して折り返しや垂れ下がりを防止することができる。
The specific depth D of the pleats 11 can be arbitrarily set to satisfy the expansion ratio E according to the size of the glove 1 etc., but the cuff 4 is preferably 3 mm or more, particularly 4 mm or more, It is preferably 7 mm or less, particularly 6 mm or less.
By setting the depth D of the pleats 11 in the cuff 4 within the above range, the cuff 4 is given appropriate rigidity while preventing occurrence of uneven thickness or cracking during manufacturing of the glove 1, and folding or sagging is caused. It can be prevented.
 前記袖部2の、前記一端7から袖口4までの長さLは10cm以上、特に20cm以上であるのが好ましい。袖部2が短いほど折り返しや垂れ下がりは生じにくいものの、前記範囲より短い場合には、水仕事の際に跳ねた水が中に入るのを確実に防止できないおそれがある。
 なお長さLは、例えば肘の付近までを覆うことを考慮すると40cm以下、特に30cm以下であるのが好ましい。
The length L of the sleeve 2 from the one end 7 to the cuff 4 is preferably 10 cm or more, and more preferably 20 cm or more. As the sleeve 2 is shorter, it is less likely to cause folding or drooping, but if it is shorter than the above range, there is a possibility that the splashed water can not be reliably prevented from entering during water work.
The length L is preferably 40 cm or less, particularly 30 cm or less, in consideration of covering up to the vicinity of the elbow, for example.
 前記手袋1を形成するゴムまたは樹脂の厚みは、先に説明したように手袋1を形成するゴムや樹脂の量が増加して手袋が重くなったり、コストが高くついたりするのを防止することを考慮すると2.0mm以下、特に1.5mm以下であるのが好ましい。ただし膜の厚みが小さすぎる場合には、たとえプリーツ11をつけても、袖部2に適度な剛性を付与して折り返しや垂れ下がりが発生するのを防止できないおそれがある。そのため膜の厚みは0.1mm以上、特に0.2mm以上であるのが好ましい。 The thickness of the rubber or resin forming the glove 1 is to prevent the glove from becoming heavy or costly because the amount of rubber or resin forming the glove 1 is increased as described above. It is preferable that it is 2.0 mm or less, especially 1.5 mm or less in consideration of. However, if the thickness of the membrane is too small, even if the pleats 11 are attached, there is a possibility that the sleeve 2 can not be provided with an appropriate rigidity to prevent the occurrence of folding or drooping. Therefore, the thickness of the film is preferably 0.1 mm or more, particularly 0.2 mm or more.
 なお手袋1の全体が前記厚みの範囲内である必要はなく、例えば袖口4を他の部分より厚肉として適度な剛性を持たせることでさらに折り返しや垂れ下がりを防止したり、指部6の先端を他の部分より厚肉として指先を保護したりしてもよい。
 前記手袋1は、袖部2にプリーツ11を有すること以外は従来同様に構成できる。
 例えば手袋1は、従来同様に浸漬法によってゴムのラテックスを図1に示す手袋1の形状に成膜するとともにゴムを加硫させるか、あるいは浸漬法によって樹脂のエマルションを前記手袋1の形状に成膜するとともに樹脂を乾燥固化させることで製造できる。
The entire glove 1 does not have to be within the above thickness range, and for example, the cuff 4 is made thicker than the other portions to give appropriate rigidity so as to further prevent folding or drooping, or the tip of the finger 6 May be thicker than other parts to protect the fingertip.
The glove 1 can be configured in the same manner as the conventional one except that the sleeve 2 has the pleats 11.
For example, the glove 1 is formed by depositing a rubber latex in the shape of the glove 1 shown in FIG. 1 by dipping as in the prior art and vulcanizing the rubber or forming an emulsion of resin into the shape of the glove 1 by dipping. It can be manufactured by drying and solidifying the resin while filming.
 例えばゴムからなる手袋1を製造する場合には、図1に示す手袋1の形状に対応した型を用意するとともに、前記型の表面を硝酸カルシウム等の凝固剤で処理する。
 またゴムラテックスに加硫剤、加硫促進剤、加硫促進助剤(活性化剤)、老化防止剤、充填剤、分散剤等の各種添加剤を加えて、未加硫もしくは前加硫状態の浸漬液を調製する。
For example, when manufacturing a glove 1 made of rubber, a mold corresponding to the shape of the glove 1 shown in FIG. 1 is prepared, and the surface of the mold is treated with a coagulant such as calcium nitrate.
In addition, various additives such as a vulcanizing agent, a vulcanization accelerator, a vulcanization acceleration assistant (activator), an antiaging agent, a filler, a dispersant and the like are added to the rubber latex to obtain an unvulcanized or prevulcanized state. Prepare an immersion liquid for
 次に、前記浸漬液に型を一定時間に亘って浸漬したのち引き上げることで、前記型の表面に浸漬液を付着させる。
 そして引き上げた型ごと加熱して浸漬液を乾燥させるとともにゴムを加硫させるか、あるいは一旦乾燥させた後に型ごと加熱してゴムを加硫させたのち脱型することにより、図1に示す手袋1が製造される。
Next, the mold is immersed in the immersion liquid for a certain period of time and then pulled up, thereby adhering the immersion liquid to the surface of the mold.
The glove as shown in FIG. 1 is then heated either to heat the mold so as to dry the immersion liquid and to vulcanize the rubber, or to heat it once to cure it and then to vulcanize the rubber and then to demold it. 1 is manufactured.
 前記ゴムとしては天然ゴム、および合成ゴムの中からラテックス化が可能な種々のゴムがいずれも使用可能であり、かかるゴムとしては、例えば天然ゴム、脱蛋白天然ゴム、NBR、スチレン-ブタジエンゴム(SBR)、クロロプレンゴム(CR)等の1種または2種以上が挙げられる。
 加硫剤としては硫黄や有機含硫黄化合物等が挙げられる。前記加硫剤の添加量は、ゴムラテックス中の固形分(ゴム分)100質量部あたり0.5質量部以上、3質量部以下程度であるのが好ましい。
As the rubber, any of natural rubber and various rubbers which can be made into latex from synthetic rubber can be used, and as such rubber, for example, natural rubber, deproteinized natural rubber, NBR, styrene-butadiene rubber ( 1 type or 2 types or more, such as SBR) and chloroprene rubber (CR), are mentioned.
Examples of the vulcanizing agent include sulfur and organic sulfur-containing compounds. The amount of the vulcanizing agent added is preferably about 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the solid content (rubber part) in the rubber latex.
 加硫促進剤としては、例えばPX(N-エチル-N-フェニルジチオカルバミン酸亜鉛)、PZ(ジメチルジチオカルバミン酸亜鉛)、EZ(ジエチルジチオカルバミン酸亜鉛)、BZ(ジブチルジチオカルバミン酸亜鉛)、MZ(2-メルカプトベンゾチアゾールの亜鉛塩)、TT(テトラメチルチウラムジスルフィド)等の1種または2種以上が挙げられる。 As the vulcanization accelerator, for example, PX (zinc-ethyl-N-phenyldithiocarbamate), PZ (zinc dimethyldithiocarbamate), EZ (zinc diethyldithiocarbamate), BZ (zinc dibutyldithiocarbamate), MZ (2- The zinc salt of mercaptobenzothiazole), TT (tetramethyl thiuram disulfide), etc. 1 type, or 2 or more types are mentioned.
 前記加硫促進剤の添加量は、ゴムラテックス中のゴム分100質量部あたり0.5質量部以上、3質量部以下程度であるのが好ましい。
 加硫促進助剤としては、例えば亜鉛華(酸化亜鉛)やステアリン酸等の1種または2種が挙げられる。前記加硫促進助剤の添加量は、ゴムラテックス中のゴム分100質量部あたり0.5質量部以上、3質量部以下程度であるのが好ましい。
The amount of the vulcanization accelerator added is preferably 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
As the vulcanization acceleration auxiliary, for example, one or two kinds of zinc flower (zinc oxide), stearic acid and the like can be mentioned. It is preferable that the addition amount of the said vulcanization acceleration adjuvant is about 0.5 mass part or more and about 3 mass parts or less per 100 mass parts of rubber components in rubber latex.
 老化防止剤としては、一般に非汚染性のフェノール類が好適に用いられるが、アミン類を使用してもよい。前記老化防止剤の添加量は、ゴムラテックス中のゴム分100質量部あたり0.5質量部以上、3質量部以下程度であるのが好ましい。
 充填剤としては、例えばカオリンクレー、ハードクレー、炭酸カルシウム等の1種または2種以上が挙げられる。前記充填剤の添加量は、ゴムラテックス中のゴム分100質量部あたり10質量部以下程度であるのが好ましい。
In general, non-staining phenols are preferably used as the antiaging agent, but amines may be used. The amount of the anti-aging agent added is preferably about 0.5 parts by mass or more and 3 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
Examples of the filler include one or more of kaolin clay, hard clay, calcium carbonate and the like. The amount of the filler added is preferably about 10 parts by mass or less per 100 parts by mass of the rubber component in the rubber latex.
 分散剤は、前記各種添加剤をゴムラテックス中に良好に分散させるために添加されるものであり、前記分散剤としては、例えば陰イオン系界面活性剤等の1種または2種以上が挙げられる。前記分散剤の添加量は、分散対象である成分の総量の0.3質量部以上、1質量部以下程度であるのが好ましい。
 一方、樹脂からなる手袋を製造する場合は、図1に示す手袋1の形状に対応した型を用意するとともに、前記型の表面を、必要に応じて硝酸カルシウム等の凝固剤で処理する。
The dispersant is added to disperse the various additives in the rubber latex well, and examples of the dispersant include one or more of anionic surfactants and the like. . The addition amount of the dispersant is preferably about 0.3 parts by mass or more and about 1 part by mass or less of the total amount of the components to be dispersed.
On the other hand, when manufacturing gloves made of resin, a mold corresponding to the shape of the glove 1 shown in FIG. 1 is prepared, and the surface of the mold is treated with a coagulant such as calcium nitrate as needed.
 また樹脂エマルションに、必要に応じて老化防止剤、充填剤、分散剤等の各種添加剤を加えて浸漬液を調製する。
 次に、前記浸漬液に型を一定時間に亘って浸漬したのち引き上げることで、前記型の表面に浸漬液を付着させる。
 そして一旦乾燥させた後に必要に応じて型ごと加熱して樹脂を固化させるか、あるいは引き上げた型ごと加熱して浸漬液を乾燥させるとともに樹脂を固化させたのち脱型することにより、図1に示す手袋1が製造される。
In addition, various additives such as an antiaging agent, a filler, and a dispersing agent are added to the resin emulsion as necessary to prepare an immersion liquid.
Next, the mold is immersed in the immersion liquid for a certain period of time and then pulled up, thereby adhering the immersion liquid to the surface of the mold.
Once dried, the mold is heated as required to solidify the resin, or the pulled up mold is heated to dry the immersion liquid and the resin is solidified and then demolded as shown in FIG. The glove 1 shown is manufactured.
 樹脂としては、塩化ビニル系樹脂、ウレタン系樹脂、アクリル系樹脂等の、エマルション化が可能な樹脂の1種または2種以上が挙げられる。
 老化防止剤としては、先に例示した非汚染性のフェノール類やアミン類等の1種または2種以上が挙げられる。前記老化防止剤の添加量は、樹脂エマルション中の固形分(樹脂分)100質量部あたり0.5質量部以上、3質量部以下程度であるのが好ましい。
As resin, 1 type (s) or 2 or more types of resin which can be emulsified, such as vinyl chloride resin, urethane type resin, acrylic resin, etc. are mentioned.
As an antiaging agent, 1 type (s) or 2 or more types, such as non-staining property phenols and amines which were illustrated previously are mentioned. It is preferable that the addition amount of the said antiaging agent is about 0.5 mass part or more and 3 mass parts or less with respect to 100 mass parts of solid content (resin part) in a resin emulsion.
 充填剤としては、前記例示の充填剤の1種または2種以上が挙げられる。前記充填剤の添加量は、樹脂エマルション中の樹脂分100質量部あたり10質量部以下程度であるのが好ましい。
 分散剤としては、前記例示の陰イオン系界面活性剤等の1種または2種以上が挙げられる。前記分散剤の添加量は、分散対象である成分の総量の0.3質量部以上、1質量部以下程度であるのが好ましい。
As the filler, one or more of the above-mentioned fillers may be mentioned. The amount of the filler added is preferably about 10 parts by mass or less per 100 parts by mass of the resin component in the resin emulsion.
As a dispersing agent, 1 type (s) or 2 or more types, such as an anionic surfactant of the said illustration, are mentioned. The addition amount of the dispersant is preferably about 0.3 parts by mass or more and about 1 part by mass or less of the total amount of the components to be dispersed.
 本発明の手袋1は、基本的に前記ゴムまたは樹脂の薄い膜のみによって単層構造に形成するのが好ましいが、必要に応じて繊維等で補強してもよい。すなわち繊維製の編手袋と、ゴムまたは樹脂の膜とを一体化させた、いわゆるサポートタイプの手袋を構成してもよい。
 前記サポートタイプの手袋を製造するには、前記型の表面にあらかじめ編手袋を装着した状態で、先に説明した浸漬法によりゴムまたは樹脂の膜を形成するとともに編手袋と一体化させればよい。
Although it is preferable that the glove 1 of the present invention is basically formed in a single layer structure by only a thin film of the rubber or resin, it may be reinforced by a fiber or the like as needed. That is, a so-called support type glove may be configured, in which a woven glove made of fiber and a rubber or resin film are integrated.
In order to manufacture the support type glove, it is sufficient to form a film of rubber or resin by the above-described immersion method and integrate it with the knitted glove in a state where the knitted glove is attached to the surface of the type in advance. .
 前記編手袋としては、例えば綿、ナイロン、ポリエステル等の繊維を編み上げたシームレス編手袋やメリヤス編手袋等が挙げられる。 Examples of the knitted gloves include seamless knitted gloves and knitted knitted gloves in which fibers such as cotton, nylon and polyester are knitted.
 〈実施例1〉
 (浸漬液の調製)
 天然ゴムラテックスに、前記天然ゴムラテックス中のゴム分100質量部あたり、硫黄(加硫剤)1質量部、加硫促進剤BZ(ジブチルジチオカルバミン酸亜鉛)1質量部、亜鉛華(加硫促進助剤)1質量部、および老化防止剤(p-クレゾールとジクロロペンタジエンのブチル化生成物)適量を添加したのち30℃で24~48時間前加硫させて浸漬液を調製した。
Example 1
(Preparation of immersion liquid)
Natural rubber latex, 1 part by mass of sulfur (vulcanizing agent), 1 part by mass of vulcanization accelerator BZ (zinc dibutyldithiocarbamate), 100 parts by mass of the rubber component in the natural rubber latex, An additive was prepared by adding 1 part by mass of the anti-aging agent and an appropriate amount of an anti-aging agent (butylated product of p-cresol and dichloropentadiene) and then pre-curing at 30 ° C. for 24 to 48 hours to prepare an immersion liquid.
 (手袋の製造)
 型としては、陶器製で、図1に示す手袋1の形状に対応し、かつ製造する手袋1の各部の寸法が下記のとおりであるものを用意した。
 袖部2の長さL=25cm
 一端7における伸縮比E=1
 袖口4における伸縮比E=1/0.85
 袖口4におけるプリーツ11の深さD=5mm
 プリーツ11は、前記一端7から袖口4に向けて徐々に深くなるようにした。
(Manufacture of gloves)
As a type | mold, what was made of ceramics and corresponded to the shape of the glove 1 shown in FIG. 1, and the dimension of each part of the glove 1 to manufacture was as follows was prepared.
Length of sleeve 2 L = 25 cm
Stretching ratio E at one end 7 = 1
Stretch ratio at cuff 4 E = 1 / 0.85
Depth D of pleat 11 in cuff 4 = 5 mm
The pleats 11 were made to be gradually deeper from the one end 7 toward the cuff 4.
 前記型を硝酸カルシウム水溶液に浸漬し、引き上げたのち乾燥させることで、前記型の表面を凝固剤としての硝酸カルシウムによって処理した。
 次いで前記型を、液温を25℃に保持した先の浸漬液に一定の速度で浸漬し、30秒間保持したのち一定の速度で引き上げることで、前記型の表面に浸漬液を付着させた。
 そして引き上げた型ごと100℃に加熱したオーブン中に入れて60分間加熱して浸漬液を乾燥させるとともにゴムを加硫させたのち脱型して、図1に示す立体形状を有する、天然ゴムの膜のみからなる単層構造の手袋1を製造した。
The surface of the mold was treated with calcium nitrate as a coagulant by immersing the mold in an aqueous solution of calcium nitrate, pulling it up and drying it.
Next, the mold was immersed at a constant speed in the former immersion liquid kept at a liquid temperature of 25 ° C., held for 30 seconds, and then pulled up at a constant speed to cause the immersion liquid to adhere to the surface of the mold.
Then, each pulled mold is placed in an oven heated to 100 ° C. and heated for 60 minutes to dry the immersion liquid while vulcanizing the rubber and then demolding to obtain a natural rubber having a three-dimensional shape shown in FIG. The glove 1 of the single layer structure which consists only of a film was manufactured.
 前記手袋1のうち袖部2の厚みを、マイクロメータを用いて測定したところ平均厚みは0.45mmであった。
 〈実施例2~4〉
 型の形状を調整して、袖口4における伸縮比Eを1/0.9(実施例2)、1/0.8(実施例3)、および1/0.6(実施例4)としたこと以外は実施例1と同様にして、天然ゴムの膜のみからなる単層構造の手袋1を製造した。いずれも袖口4におけるプリーツ11の深さDは5mmとした。
The thickness of the sleeve 2 of the glove 1 was measured using a micrometer, and the average thickness was 0.45 mm.
Examples 2 to 4
The shape of the mold was adjusted so that the stretch ratio E at the cuff 4 was 1 / 0.9 (Example 2), 1 / 0.8 (Example 3), and 1 / 0.6 (Example 4). In the same manner as in Example 1 except for the above, a glove 1 having a single-layer structure consisting only of a natural rubber film was produced. In all cases, the depth D of the pleats 11 at the cuff 4 was 5 mm.
 〈実施例5〉
 型の形状を調整して、袖部2の長さLを9cmとしたこと以外は実施例1と同様にして、天然ゴムの膜のみからなる単層構造の手袋1を製造した。
 〈比較例1〉
 型の形状を調整して、一端7から袖口4までプリーツ11の深さを一定にしたこと以外は実施例1と同様にして、天然ゴムの膜のみからなる単層構造の手袋を製造した。前記一定の深さDは5mm、伸縮比Eは1/0.85とした。
Example 5
The shape of the mold was adjusted, and in the same manner as in Example 1 except that the length L of the sleeve portion 2 was 9 cm, a single-layered glove 1 consisting only of a natural rubber film was produced.
Comparative Example 1
A single-layered glove consisting only of a natural rubber film was manufactured in the same manner as in Example 1 except that the shape of the mold was adjusted and the depth of the pleats 11 was made constant from one end 7 to the cuff 4. The constant depth D is 5 mm, and the expansion ratio E is 1 / 0.85.
 〈比較例2〉
 型の形状を調整して、プリーツ11の開始位置を一端7の直下から袖口4側へ5cm下とし、そこから袖口4へ向けて徐々に深くなるプリーツ11を設けたこと以外は実施例1と同様にして、天然ゴムの膜のみからなる単層構造の手袋を製造した。開始位置での伸縮比Eは1、袖口4における伸縮比Eは1/0.85、深さDは5mmとした。
Comparative Example 2
The shape of the mold was adjusted, and the start position of the pleat 11 was set 5 cm below the end 7 to the side of the cuff 4 and the pleat 11 gradually deepened from there to the cuff 4 and Example 1 and Similarly, a single-layered glove consisting only of a film of natural rubber was manufactured. The stretch ratio E at the start position was 1, the stretch ratio E at the cuff 4 was 1 / 0.85, and the depth D was 5 mm.
 〈比較例3〉
 型の形状を調整して、袖部2にプリーツ11を設けなかったこと以外は実施例1と同様にして、天然ゴムの膜のみからなる単層構造の手袋を製造した。
 〈着脱性評価〉
 実施例、比較例で製造した手袋を被験者に10回着脱を繰り返してもらい、その間に要した時間を計測して、下記の基準で着脱性を評価した。
Comparative Example 3
The shape of the mold was adjusted, and in the same manner as in Example 1 except that the pleats 11 were not provided in the sleeve portion 2, a glove having a single layer structure consisting only of a natural rubber film was produced.
<Removability evaluation>
The subject manufactured the gloves manufactured in the example and the comparative example to be repeatedly attached and detached 10 times, and the time required during that time was measured to evaluate the detachment according to the following criteria.
 ◎:20秒以下。
 ○:20秒超、25秒以下。
 △:25秒超、30秒以下。
 ×:30秒超。
 〈折り返し、垂れ下がり防止効果の評価〉
 実施例、比較例で製造した手袋を被験者に装着してもらい、腕を10回上げ下ろしした後、装着直後と比べて袖口が手袋本体の方にずれた距離を計測して、下記の基準で折り返し、垂れ下がり防止効果を評価した。
◎: 20 seconds or less.
○: More than 20 seconds, 25 seconds or less.
:: more than 25 seconds, less than 30 seconds.
X: more than 30 seconds.
<Evaluation of the effect to prevent folding and sagging>
After having the subject wear the gloves manufactured in the example and the comparative example and raising and lowering the arm 10 times, measure the distance the cuff is shifted toward the glove body compared with immediately after wearing, and fold back according to the following criteria The dripping prevention effect was evaluated.
 ◎:1cm以下。
 ○:1cm超、3cm以下。
 △:3cm超、5cm以下。
 ×:5cm超。
 〈水跳ね防止効果の評価〉
 実施例、比較例で製造した手袋を被験者に装着してもらい、20分間、食器洗いをしてもらった後、腕に付着した水跳ねの個数を数えた。そして全体の個数のうち、前腕部に付着した水跳ねの個数の占める割合を求めで、下記の基準で水跳ね防止効果を評価した。
: 1: 1 cm or less.
○: 1 cm or more, 3 cm or less.
Δ: more than 3 cm, 5 cm or less.
X: more than 5 cm.
<Evaluation of water splash prevention effect>
After subjecting the subject to wear the gloves manufactured in Examples and Comparative Examples and washing the dishes for 20 minutes, the number of splashes attached to the arm was counted. And the ratio of the number of the splashing of the water adhering to the forearm part was calculated | required among the number of whole objects, and the splashing prevention effect was evaluated by the following reference | standard.
 ◎:0%。
 ○:0%超、10%以下。
 △:10%超、30%以下。
 ×:30%超。
 以上の結果を表1に示す。
: 0: 0%.
○: More than 0%, 10% or less.
Δ: more than 10% and 30% or less.
X: over 30%.
The above results are shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1の比較例3の結果より、袖部にプリーツを設けない場合には折り返しや垂れ下がりを防止する効果は得られず、また水跳ね防止の効果も得られないことが判った。
 また比較例1の結果より、袖部に深さが一定のプリーツを設けても、折り返しや垂れ下がりを防止する効果、あるいは水跳ね防止の効果は改善されないことが判った。
 さらに比較例2の結果より、袖口へ向けて徐々に深くなるプリーツを設けても、その開始位置が袖口の一端よりかなり下にある場合には、着脱性が低下することが判った。
From the results of Comparative Example 3 in Table 1, it was found that when the sleeve portion was not provided with pleats, the effect of preventing folding and sagging was not obtained, and the effect of preventing water splashing was not obtained.
Further, from the results of Comparative Example 1, it was found that the effect of preventing folding and drooping or the effect of preventing water splashing was not improved even if a pleat having a constant depth was provided in the sleeve.
Furthermore, it was found from the results of Comparative Example 2 that, even if the pleats gradually deepening toward the cuff are provided, the removability is lowered when the start position is considerably lower than one end of the cuff.
 これに対し、実施例1~5の結果より、袖部2に、一端7から袖口4に達するとともに、前記一端7から袖口4に向けて深さDが徐々に深くなっているプリーツ11を設けることにより、良好な着脱性を維持しながら、折り返しや垂れ下がりを防止する効果、および水跳ね防止の効果を向上できることが判った。
 また実施例1~4の結果より、袖部2の伸縮比Eは、一端7で1、袖口4で1/0.9以上、1/0.6以下の範囲内であるのが好ましいことが判った。さらに実施例1~4と実施例5の結果より、袖部2の長さLは10cm以上であるのが好ましいことが判った。
On the other hand, according to the results of Examples 1 to 5, the sleeve 2 is provided with the pleats 11 which reach the cuff 4 from the one end 7 and the depth D gradually increases from the one end 7 toward the cuff 4 Thus, it has been found that the effect of preventing folding and sagging and the effect of preventing water splashing can be improved while maintaining good removability.
From the results of Examples 1 to 4, it is preferable that the expansion and contraction ratio E of the sleeve 2 is in the range of 1 / 0.9 or more and 1 / 0.6 or less for the cuff 7 and 1 at one end 7. understood. Further, from the results of Examples 1 to 4 and Example 5, it was found that the length L of the sleeve 2 is preferably 10 cm or more.
1     手袋
2     袖部
3     手袋本体
4     袖口
5     掌部
6     指部
7     一端
8     第一袖部
9     第二袖部
10   境界部
11   プリーツ
Reference Signs List 1 glove 2 sleeve 3 glove body 4 cuff 5 palm 6 finger 7 end 8 first sleeve 9 second sleeve 10 boundary 11 pleat

Claims (8)

  1.  略筒状の袖部と、前記袖部の一端に連なる手袋本体とがゴムまたは樹脂の膜によって一体に形成され、かつ前記袖部の他端が袖口として開口された手袋であって、前記袖部には、前記手袋本体に連なる一端から袖口に達する複数のプリーツが全周に亘って設けられているとともに、前記各プリーツは、前記一端から袖口に向けて深さが徐々に深くなっていることを特徴とする手袋。 A sleeve is an integral part of a substantially cylindrical sleeve and a glove main body connected to one end of the sleeve, the rubber or resin film, and the other end of the sleeve is opened as a cuff. The section is provided with a plurality of pleats extending from the end connected to the glove body to the cuff over the entire circumference, and each pleat is gradually deepened from the end toward the cuff Gloves characterized by.
  2.  前記手袋を形成する各部に応力を加えないフリーの状態での周長Rと、プリーツを伸ばした時の周長Rとから、式(1):
     伸縮比E=R/R   (1)
    で求められる伸縮比Eが、前記袖部の一端において1、袖口において1/0.9以上、1/0.6以下の範囲内で、かつ前記一端から前記袖口にかけて伸縮比Eが前記1から徐々に増加している請求項1に記載の手袋。
    From the circumferential length R 1 in a free state where no stress is applied to each part forming the glove, and the circumferential length R 2 when the pleats are extended, Formula (1):
    Expansion ratio E = R 2 / R 1 (1)
    The stretch ratio E determined in step 1 is in the range of 1 / 0.9 to 1 / 0.6 in the cuff at one end of the sleeve and in the stretch ratio E from the one to the cuff from the one end to the cuff. The glove according to claim 1, which is gradually increasing.
  3.  前記袖部の、前記一端から袖口までの長さが10cm以上である請求項1に記載の手袋。 The glove according to claim 1, wherein a length of the sleeve from the one end to the cuff is 10 cm or more.
  4.  前記袖部の、前記一端から袖口までの長さが10cm以上である請求項2に記載の手袋。 The glove according to claim 2, wherein a length of the sleeve from the one end to the cuff is 10 cm or more.
  5.  前記膜の厚みが0.1mm以上、2mm以下である請求項1に記載の手袋。 The glove according to claim 1, wherein the thickness of the film is 0.1 mm or more and 2 mm or less.
  6.  前記膜の厚みが0.1mm以上、2mm以下である請求項2に記載の手袋。 The glove according to claim 2, wherein the thickness of the film is 0.1 mm or more and 2 mm or less.
  7.  前記膜の厚みが0.1mm以上、2mm以下である請求項3に記載の手袋。 The glove according to claim 3, wherein the thickness of the film is 0.1 mm or more and 2 mm or less.
  8.  前記膜の厚みが0.1mm以上、2mm以下である請求項4に記載の手袋。 The glove according to claim 4, wherein the thickness of the film is 0.1 mm or more and 2 mm or less.
PCT/JP2011/079538 2011-02-07 2011-12-20 Glove WO2012108107A1 (en)

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JP2011-024210 2011-02-07
JP2011024210A JP2012162825A (en) 2011-02-07 2011-02-07 Glove

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014136858A (en) * 2013-01-15 2014-07-28 Tzong-Dar Wu Method of manufacturing waterproof air-permeable socks and product thereof
CN110613195A (en) * 2018-06-18 2019-12-27 尚和手套株式会社 Gloves

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6305022B2 (en) * 2013-11-13 2018-04-04 住友ゴム工業株式会社 Natural rubber gloves
JP6308652B2 (en) * 2013-12-11 2018-04-11 住友ゴム工業株式会社 Manufacturing method of thin film products
JP7386497B2 (en) * 2018-06-18 2023-11-27 ショーワグローブ株式会社 gloves

Citations (3)

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Publication number Priority date Publication date Assignee Title
JPS49128419U (en) * 1973-03-05 1974-11-05
JPS61180114U (en) * 1985-04-25 1986-11-10
JP2004162222A (en) * 2002-11-14 2004-06-10 Sumitomo Rubber Ind Ltd Support-type glove

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49128419U (en) * 1973-03-05 1974-11-05
JPS61180114U (en) * 1985-04-25 1986-11-10
JP2004162222A (en) * 2002-11-14 2004-06-10 Sumitomo Rubber Ind Ltd Support-type glove

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014136858A (en) * 2013-01-15 2014-07-28 Tzong-Dar Wu Method of manufacturing waterproof air-permeable socks and product thereof
CN110613195A (en) * 2018-06-18 2019-12-27 尚和手套株式会社 Gloves

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