WO2012091002A1 - カーボンナノチューブインク組成物とその塗布方法、カーボンナノチューブ含有薄膜の形成方法 - Google Patents
カーボンナノチューブインク組成物とその塗布方法、カーボンナノチューブ含有薄膜の形成方法 Download PDFInfo
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- WO2012091002A1 WO2012091002A1 PCT/JP2011/080193 JP2011080193W WO2012091002A1 WO 2012091002 A1 WO2012091002 A1 WO 2012091002A1 JP 2011080193 W JP2011080193 W JP 2011080193W WO 2012091002 A1 WO2012091002 A1 WO 2012091002A1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
Definitions
- the present invention is based on the priority claim of Japanese patent application: Japanese Patent Application No. 2010-292855 (filed on Dec. 28, 2010), the entire contents of which are incorporated herein by reference. Shall.
- the present invention relates to a carbon nanotube ink composition in which carbon nanotubes are uniformly dispersed as a dispersoid, and more particularly to a carbon nanotube ink composition capable of obtaining an ink excellent in printability from a printing apparatus.
- the carbon nanotube has a structure in which a graphene sheet is rolled into a cylindrical shape, and generally has a straw-like or straw-like structure.
- Carbon nanotubes are single-walled carbon nanotubes (SWCNT) consisting of a single tube, double-walled carbon nanotubes (DWCNT) where two tubes with different diameters are stacked, and multi-walls where multiple tubes with different diameters are stacked It is classified into carbon nanotubes (MWCNT), and applied research utilizing the features of each structure is underway.
- SWCNT has a structure having semiconductor characteristics depending on how the graphene sheet is wound, and high mobility is expected. Therefore, SWCNT is expected to be applied to a thin film transistor (TFT) and is actively researched.
- TFT thin film transistor
- reports such as Non-Patent Documents 1 to 4 show that TFTs using carbon nanotubes have silicon or higher performance than silicon.
- carbon nanotubes When carbon nanotubes are used as a semiconductor material for a channel, one or several carbon nanotubes or a large number of carbon nanotubes are dispersed to manufacture a TFT. When a small number of carbon nanotubes are used, the length of carbon nanotubes is generally about 1 ⁇ m or less, so fine processing is required when fabricating TFTs, so that the so-called channel length between the source electrode and the drain electrode is reduced. Must be manufactured on a micron scale.
- Non-patent document 5 and the like are mentioned as a report example of manufacturing a TFT by dispersing a large number of carbon nanotubes.
- DWCNT and MWCNT since they exhibit high electrical conductivity, they are expected to be applied to electrode materials, wiring materials, antistatic films, and transparent electrodes, and are being studied.
- Non-Patent Documents 6 to 9 report a method of forming a carbon nanotube thin film from a solution or dispersion.
- the element / device, product substrate, as well as hard materials such as glass, as well as hard materials By applying resin or plastic, it becomes possible to give flexibility to the entire element, device and product. Furthermore, since a coating process can be adopted, there is a possibility that the cost of elements, devices, and products can be reduced by a manufacturing method to which the coating process and the printing process are applied.
- Patent Document 1 a composition having excellent dispersibility and storage stability of carbon nanotubes and excellent compatibility with a printing apparatus.
- This is a composition comprising carbon nanotubes, a solvent and glycol ethers.
- an object of the present invention is to obtain a carbon nanotube composition that is a dispersion containing carbon nanotubes and that is excellent in dispersibility and storage stability of carbon nanotubes.
- Another object of the present invention is to obtain a carbon nanotube composition that is excellent in printability using a printing apparatus, in particular, drying prevention on the printing apparatus.
- Patent Document 1 The present inventor has already reported Patent Document 1, but as a result of intensive investigations to solve the above-mentioned problems, by incorporating a compound having a specific structure in the carbon nanotube ink composition, the ink as an ink has been reported. It has been found that the carbon nanotube ink composition is excellent in storage stability and has excellent printing characteristics, in particular, an ink drying prevention property on a printing apparatus, and the present invention has been invented.
- the carbon nanotube ink composition according to the present invention includes a carbon nanotube, a solvent, an imidazolidinone compound represented by the following chemical formula (1), and propylene urea represented by the following chemical formula (2). And a compound.
- the carbon nanotube ink composition application method includes a step of spraying the carbon nanotube ink composition according to the first aspect from an inkjet head device.
- the method for forming a carbon nanotube-containing thin film according to the present invention comprises a step of spraying the carbon nanotube ink composition according to the first aspect from a inkjet head device onto a material substrate, and the carbon nanotube ink composition And heating the material substrate sprayed with an object to evaporate the solvent.
- a carbon nanotube ink composition comprising the carbon nanotube, a solvent, an imidazolidinone compound represented by the chemical formula (1), and a propylene urea compound represented by the chemical formula (2), wherein the imidazolidinone compound and the propylene urea compound Is a compound having a cyclic imide structure and having a hydrocarbon group, particularly a methyl group, on two nitrogens.
- Imidazolidinone compounds and propylene urea compounds have similar structures and differ only in the number of carbon atoms constituting the ring.
- imidazolidinone compounds with small size are particularly stable in dispersion of nanotubes.
- the propylene urea compound having a large size contributes to the improvement of the anti-drying property on the printing apparatus.
- the hydrocarbon group contained in the imidazolidinone compound and the propylene urea compound can basically be substituted if it is a linear, branched, saturated or unsaturated hydrocarbon group having an affinity for carbon nanotubes.
- a linear or branched saturated hydrocarbon group having about 1 to 5 carbon atoms is preferred, and a methyl group-substituted product is most readily available and preferred.
- urea is often used to prevent ink drying, but in the case of ink in which nanotubes are dispersed, the dispersion stability of the nanotubes is deteriorated, and therefore, drying inhibitors other than urea have been required.
- the propylene urea compound of the present invention is an ideal additive because it not only acts to prevent drying on the printing apparatus but also does not affect the dispersion stability of the nanotubes.
- this imidazolidinone compound and propylene urea compound have an imide group part and an alkyl chain part, it is possible to maintain a good dispersion state by having a parent carbon nanotube part and a parent solvent part in the molecule. .
- R 1 , R 2 , R 3 and R 4 are all methyl groups.
- the solvent is preferably water or an organic solvent.
- the carbon nanotube content is preferably 100 ppm (0.01 wt%) to 1 wt%.
- the total content of the imidazolidinone compound and the propylene urea compound is preferably 100 ppm to 5% by weight.
- the total weight content of the imidazolidinone compound and the propylene urea compound is larger than the weight content of the carbon nanotubes.
- polyethylene glycol compound containing an alkoxy group having 10 or more carbon atoms as a substituent it is preferable to further contain a polyethylene glycol compound containing an alkoxy group having 10 or more carbon atoms as a substituent.
- the weight content of the polyethylene glycol compound is preferably 0.5 to 1.5 times the weight content of the carbon nanotube. Moreover, it is more preferable that it is the same weight content rate.
- the carbon nanotube content (% by weight) is not particularly limited. However, when the content of the carbon nanotubes exceeds 10%, the ink composition itself becomes more viscous and becomes a paste. In consideration of printing, particularly when using an inkjet apparatus, a concentration of up to about 1% is easy to handle. On the other hand, if it is less than 0.01% (100 ppm), the CNT density in the CNT thin film becomes too small, and a device such as overcoating is required, and the number of steps increases. If it exceeds 1% by weight, the dispersion stability of the ink deteriorates rapidly. Therefore, it is preferably in the range of 0.01 to 1% by weight.
- the content of the imidazolidinone compound represented by the chemical formula (1) and the propylene urea compound represented by the chemical formula (2) is not particularly limited.
- the content concentration in the ink is extremely small, the printing stability is lowered and the dispersion is reduced. Since stability is also lowered, the concentration in the ink is preferably about 100 ppm to 5%.
- the concentration is lower than that of the carbon nanotubes by weight ratio, the dispersion stability is lowered, the carbon nanotubes are precipitated and precipitated, the ink is dried on the printing apparatus, and printing is impossible.
- the carbon nanotube composition contains an alkoxy group having 10 or more carbon atoms as a substituent.
- a polyethylene glycol compound By further containing a polyethylene glycol compound, dispersion stability at a higher concentration can be imparted.
- the alkoxy group having 10 or more carbon atoms may be either a saturated alkoxy group or an unsaturated alkoxy group, and high dispersion stability can be obtained with either a straight-chain alkoxy group or a branched alkoxy group. When 20 straight-chain saturated alkoxy groups are used, the dispersion stability is particularly high.
- the concentration of carbon nanotubes can be stably dispersed up to 10%.
- the addition amount of the polyethylene glycol compound containing an alkoxy group having 10 or more carbon atoms as a substituent is not particularly limited, but is preferably about 0.5 to 1.5 times the addition amount of carbon nanotubes by weight. Can maintain high dispersion stability by adding the same amount.
- the carbon nanotube ink composition of the present invention comprising the carbon nanotube, a solvent, an imidazolidinone compound represented by the chemical formula (1), and a propylene urea compound represented by the chemical formula (2), Since the wettability of the ink composition to the member can be effectively improved, the familiarity with the printing apparatus is very good, and high printing characteristics can be provided when the printing apparatus is used. In particular, when spraying and discharging from an inkjet head device, if the wettability is poor, ink filling into the inkjet head and stable ink spraying and discharging cannot be obtained, but the carbon nanotube ink composition of the present invention is not used. By using it, ink can be easily filled into the ink jet head, and stable ink spraying and ejection can be performed.
- the solvent is water or an organic solvent.
- Organic solvents include aliphatic hydrocarbons such as decane and undecane, aromatic hydrocarbons such as toluene and xylene, ketones such as methyl ethyl ketone and cyclohexanone, ethers such as diethyl ether and ethyl methyl ether, ethyl acetate, and methyl propionate.
- Preferred examples include carboxylic acid alkyl esters such as dichloroethane, N, N-dimethylformamide and the like. These can be used alone or in combination of two or more.
- the carbon nanotube can be any of SWCNT, DWCNT, and MWCNT, and is not limited to a shape.
- SWCNT When used as a semiconductor material, SWCNT is used, and when used as a conductive material, SWCNT, DWCNT, and MWCNT are used.
- There are various carbon nanotube production methods such as CVD and laser ablation, and any carbon nanotube produced by any production method can be used.
- Example 1 a carbon nanotube ink composition 1 was produced according to the following procedure. First, 10 mg of single wall carbon nanotubes prepared by the Hipco method was weighed in a glass container, and 100 mg of an imidazolidinone compound of the chemical formula (1) was added. Next, 10 g of water was added to the glass container, and ultrasonic treatment was performed for 1 hour using an ultrasonic device. The dispersion immediately after sonication showed a uniform black form, and no residue or precipitate was observed. Further, when this dispersion was observed after 5 days and 10 days, no residue and precipitate were observed as in the case immediately after the treatment.
- the carbon nanotube ink composition 1 was filled into an ink jet head manufactured by Konica Minolta, and the ink filling state and the spraying state were observed.
- the ink jet head filled with the carbon nanotube ink composition 1 was operated, a stable ink discharge state was obtained immediately after filling.
- the inkjet head was left as it was and operated after 5 days, some nozzles were clogged. After 10 days, clogging occurred with more than half of the nozzles.
- Example 2 a carbon nanotube ink composition 2 was produced according to the following procedure. First, 10 mg of a single-walled carbon nanotube prepared by the Hipco method was weighed in a glass container, and 100 mg of a propylene urea compound represented by the chemical formula (2) was added. Next, 10 g of water was added to the glass container, and ultrasonic treatment was performed for 1 hour using an ultrasonic device. The dispersion immediately after sonication showed a uniform black form, and no residue or precipitate was observed. When this dispersion was observed after 5 days and 10 days, a small amount of precipitate was found at the bottom of the glass container, which was not observed immediately after the treatment.
- the carbon nanotube ink composition 2 was filled into an ink jet head manufactured by Konica Minolta, and the ink filling state and the spraying state were observed.
- the ink jet head filled with the carbon nanotube ink composition 1 was operated, a stable ink ejection state was obtained just like the ink composition immediately after filling.
- the inkjet head was left as it was and operated after 5 days and 10 days, no clogging was observed.
- Example 3 a carbon nanotube ink composition 3 was produced according to the following procedure. First, 10 mg of single wall carbon nanotubes prepared by the Hipco method was weighed in a glass container, and 100 mg of an imidazolidinone compound of the chemical formula (1) was added. Further, 100 mg of a propylene urea compound represented by the chemical formula (2) was added to obtain an ink composition 3. Next, 10 g of water was added to the glass container, and ultrasonic treatment was performed for 1 hour using an ultrasonic device. The dispersion immediately after sonication showed a uniform black form, and no residue or precipitate was observed. Further, when this dispersion was observed after 5 days and 10 days, no residue and precipitate were observed as in the case immediately after the treatment.
- the carbon nanotube ink composition 3 was filled into an ink jet head manufactured by Konica Minolta, and the ink filling state and the spraying state were observed.
- the ink jet head filled with the carbon nanotube ink composition 1 was operated, a stable ink ejection state was obtained just like the ink composition immediately after filling.
- the inkjet head was left as it was and operated after 5 days and 10 days, no clogging was observed.
- the ink composition 101 immediately after the ultrasonic treatment showed a uniform black form, and no residue or precipitate was observed.
- this dispersion was observed after 5 days and 10 days, a small amount of precipitate was found at the bottom of the glass container, which was not observed immediately after the treatment.
- the carbon nanotube ink composition 101 was filled into an inkjet head made of Konica Minolta, and the ink filling state and the spraying state were observed.
- an inkjet head made of Konica Minolta
- the ink jet head filled with the carbon nanotube ink composition 1 was operated, a stable ink ejection state was obtained just like the ink composition immediately after filling.
- the inkjet head was left as it was and operated after 5 days and 10 days, no clogging was observed.
- Example 4 a carbon nanotube ink composition 4 was produced according to the following procedure. First, 100 mg of single-walled carbon nanotubes prepared by the Hipco method are weighed in a glass container, 100 mg of the imidazolidinone compound of the chemical formula (1), 100 mg of the propylene urea compound represented by the chemical formula (2), and the terminal 1 g of polyethylene glycol (molecular weight 1000) introduced with C18H37O (laurylalkoxy group) was added.
- polyethylene glycol molecular weight 1000
- the carbon nanotube ink composition 4 was filled into an ink jet head manufactured by Konica Minolta, and the ink filling state and the spraying state were observed.
- the ink jet head filled with the carbon nanotube ink composition 4 was operated, a stable ink ejection state was obtained just like the ink composition immediately after filling.
- the inkjet head was left as it was and operated after 5 days and 10 days, no clogging was observed.
- the present invention has been described based on the preferred embodiment examples.
- the carbon nanotube ink composition according to the present invention is not limited to the configuration of the above embodiment examples, and the configuration of the above embodiment examples.
- carbon nanotube ink compositions subjected to various modifications and changes are also included in the scope of the present invention.
- the embodiments and examples can be changed and adjusted based on the basic technical concept.
- various combinations or selections of various disclosed elements including each element of each claim, each element of each embodiment, each element of each drawing, etc.) are possible within the scope of the claims of the present invention. It is. That is, the present invention of course includes various variations and modifications that could be made by those skilled in the art according to the entire disclosure including the claims and the technical idea.
Abstract
Description
本発明は、日本国特許出願:特願2010-292851号(2010年12月28日出願)の優先権主張に基づくものであり、同出願の全記載内容は引用をもって本書に組み込み記載されているものとする。
本発明は、カーボンナノチューブを分散質として均一に分散させたカーボンナノチューブインク組成物に関し、特に、印刷装置からの印刷性に優れたインクを得ることが可能なカーボンナノチューブインク組成物に関する。
以下に関連技術の分析を与える。
しかしながら、カーボンナノチューブの溶液や分散液を作製することは非常に困難であり、保存安定性に優れたカーボンナノチューブの分散液を作製するためには、イオン性の界面活性剤や、特殊な構造を有する分散剤を用いる必要があった。これらの界面活性剤や、分散剤は保存安定性を向上させることは出来るが、この分散液を用いてインクを印刷に用いると印刷性が低下したり、印刷装置に影響を及ぼしたりすることが多かった。
以上説明したように、本発明のカーボンナノチューブインク組成物によると、印刷特性に優れかつ分散安定性の優れたカーボンナノチューブインク組成物を提供することができる。
本実施例1では、カーボンナノチューブインク組成物1を以下の手順で作製した。まず、ガラス製の容器にHipco法で作成したシングルウォールカーボンナノチューブを10mg秤量し、化学式(1)のイミダゾリジノン化合物を100mg加えた。ついで、ガラス容器に水を10g添加し、超音波装置を用いて、1時間超音波処理を行った。超音波処理直後の分散液は均一な黒色形態を示し、残留物、沈殿物は見られなかった。また、この分散液を5日後、10日後に観察したところ、処理直後と同様に、残留物、沈殿物は見られなかった。
本実施例2では、カーボンナノチューブインク組成物2を以下の手順で作製した。まず、ガラス製の容器にHipco法で作成したシングルウォールカーボンナノチューブを10mg秤量し、化学式(2)であらわされるプロピレン尿素化合物を100mg加えた。ついで、ガラス容器に水を10g添加し、超音波装置を用いて、1時間超音波処理を行った。超音波処理直後の分散液は均一な黒色形態を示し、残留物、沈殿物は見られなかった。この分散液を5日後、10日後に観察したところ、処理直後には見られなかった沈殿物が少量ガラス容器の底部に見られた。
本実施例3では、カーボンナノチューブインク組成物3を以下の手順で作製した。まず、ガラス製の容器にHipco法で作成したシングルウォールカーボンナノチューブを10mg秤量し、化学式(1)のイミダゾリジノン化合物を100mg加えた。さらに化学式(2)であらわされるプロピレン尿素化合物を100mg加えてインク組成物3を得た。ついで、ガラス容器に水を10g添加し、超音波装置を用いて、1時間超音波処理を行った。超音波処理直後の分散液は均一な黒色形態を示し、残留物、沈殿物は見られなかった。また、この分散液を5日後、10日後に観察したところ、処理直後と同様に、残留物、沈殿物は見られなかった。
化合物(2)の代わりに尿素を用いた以外は実施例3と全く同様にカーボンナノチューブインク組成物を作製し、カーボンナノチューブインク組成物101を得た。
本実施例4では、カーボンナノチューブインク組成物4を以下の手順で作製した。まず、ガラス製の容器にHipco法で作成したシングルウォールカーボンナノチューブを100mg秤量し、化学式(1)のイミダゾリジノン化合物を100mg及び、化学式(2)であらわされるプロピレン尿素化合物を100mg及び、末端にC18H37O(ラウリルアルコキシ基)を導入したポリエチレングリコール(分子量1000)を1g加えた。
Claims (10)
- R1,R2,R3及びR4がすべてメチル基であることを特徴とする、請求項1に記載のカーボンナノチューブインク組成物。
- 前記溶媒が水又は有機溶媒であることを特徴とする、請求項1又は2に記載のカーボンナノチューブインク組成物。
- 前記カーボンナノチューブの含有率が100ppm~1重量%であることを特徴とする、請求項1~3のいずれか一に記載のカーボンナノチューブインク組成物。
- 前記イミダゾリジノン化合物と前記プロピレン尿素化合物を合計した含有率が、100ppm~5重量%であることを特徴とする、請求項1~4のいずれか一に記載のカーボンナノチューブインク組成物。
- 前記イミダゾリジノン化合物と前記プロピレン尿素化合物を合計した重量含有率が、前記カーボンナノチューブの重量含有率よりも大きいことを特徴とする、請求項1~5のいずれか一に記載のカーボンナノチューブインク組成物。
- 炭素数が10以上のアルコキシ基を置換基として含有するポリエチレングリコール化合物をさらに含有することを特徴とする、請求項1~6のいずれか一に記載のカーボンナノチューブインク組成物。
- 前記ポリエチレングリコール化合物の重量含有率が、前記カーボンナノチューブの重量含有率の0.5~1.5倍であることを特徴とする、請求項7に記載のカーボンナノチューブインク組成物。
- カーボンナノチューブ含有薄膜を形成するために、カーボンナノチューブを含有する組成物を材料基板に塗布する方法であって、請求項1~8のいずれか一に記載のカーボンナノチューブインク組成物を、インクジェットヘッド装置から噴霧させる工程を含むことを特徴とする、カーボンナノチューブインク組成物の塗布方法。
- カーボンナノチューブ含有薄膜の形成方法であって、
請求項1~8のいずれか一に記載のカーボンナノチューブインク組成物を、インクジェットヘッド装置から材料基板に噴霧させる工程と、
該カーボンナノチューブインク組成物を噴霧した該材料基板を加熱して前記溶媒を蒸発させる工程と、を含むことを特徴とする、カーボンナノチューブ含有薄膜の形成方法。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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JP2012550975A JP5942854B2 (ja) | 2010-12-28 | 2011-12-27 | カーボンナノチューブインク組成物とその塗布方法、カーボンナノチューブ含有薄膜の形成方法 |
US13/976,857 US9051483B2 (en) | 2010-12-28 | 2011-12-27 | Carbon nanotube ink composition and a coating method thereof and a forming method of a thin film containing carbon nanotubes |
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Application Number | Priority Date | Filing Date | Title |
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JP2010-292851 | 2010-12-28 | ||
JP2010292851 | 2010-12-28 |
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JP2015529835A (ja) * | 2012-07-23 | 2015-10-08 | ヒューレット−パッカード・インデイゴ・ビー・ブイHewlett−Packard Indigo B.V. | 静電インク組成物 |
JPWO2016039225A1 (ja) * | 2014-09-08 | 2017-08-10 | 富士フイルム株式会社 | 熱電変換素子、n型熱電変換層、および、n型熱電変換層形成用組成物 |
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CN110031108A (zh) * | 2018-01-11 | 2019-07-19 | 清华大学 | 黑体辐射源及黑体辐射源的制备方法 |
CN110031106B (zh) * | 2018-01-11 | 2021-04-02 | 清华大学 | 黑体辐射源 |
KR102230238B1 (ko) * | 2020-11-09 | 2021-03-19 | (주)케이에이치 케미컬 | 연속식 탄소나노튜브의 제조 방법 |
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EP1745525A4 (en) * | 2004-05-10 | 2011-03-16 | Nippon Catalytic Chem Ind | MATERIAL FOR AN ELECTROLYTIC SOLUTION, ION MATERIAL CONTAINING COMPOSITION AND USE THEREOF |
WO2009031525A1 (ja) * | 2007-09-07 | 2009-03-12 | Nec Corporation | カーボンナノチューブ構造物及び薄膜トランジスタ |
WO2009031681A1 (ja) * | 2007-09-07 | 2009-03-12 | Nec Corporation | スイッチング素子及びその製造方法 |
WO2010053171A1 (ja) * | 2008-11-10 | 2010-05-14 | 日本電気株式会社 | スイッチング素子及びその製造方法 |
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JP5838815B2 (ja) * | 2010-01-19 | 2016-01-06 | 日本電気株式会社 | カーボンナノチューブ分散液および半導体装置の製造方法 |
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JP2002255528A (ja) * | 2000-09-18 | 2002-09-11 | Matsushita Electric Ind Co Ltd | 微粒子分散液およびその製造方法 |
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JP2010180263A (ja) * | 2009-02-03 | 2010-08-19 | Nec Corp | カーボンナノチューブインク組成物及びカーボンナノチューブ膜の製造方法 |
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JP2015529835A (ja) * | 2012-07-23 | 2015-10-08 | ヒューレット−パッカード・インデイゴ・ビー・ブイHewlett−Packard Indigo B.V. | 静電インク組成物 |
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JPWO2016039225A1 (ja) * | 2014-09-08 | 2017-08-10 | 富士フイルム株式会社 | 熱電変換素子、n型熱電変換層、および、n型熱電変換層形成用組成物 |
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US20130273257A1 (en) | 2013-10-17 |
US9051483B2 (en) | 2015-06-09 |
JP5942854B2 (ja) | 2016-06-29 |
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