WO2012074419A2 - Procédé de fabrication de matériaux barrière textiles - Google Patents
Procédé de fabrication de matériaux barrière textiles Download PDFInfo
- Publication number
- WO2012074419A2 WO2012074419A2 PCT/PL2011/000120 PL2011000120W WO2012074419A2 WO 2012074419 A2 WO2012074419 A2 WO 2012074419A2 PL 2011000120 W PL2011000120 W PL 2011000120W WO 2012074419 A2 WO2012074419 A2 WO 2012074419A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- modified
- anatase
- amount
- titanium dioxide
- oxide composite
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000004753 textile Substances 0.000 title claims abstract description 32
- 230000008569 process Effects 0.000 title claims abstract description 30
- 239000000463 material Substances 0.000 title claims abstract description 21
- 230000004888 barrier function Effects 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 72
- 229920000728 polyester Polymers 0.000 claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 238000001556 precipitation Methods 0.000 claims abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000080 wetting agent Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 10
- 239000002562 thickening agent Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 238000009832 plasma treatment Methods 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 239000012298 atmosphere Substances 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920005792 styrene-acrylic resin Polymers 0.000 claims description 2
- 230000005855 radiation Effects 0.000 abstract description 18
- 244000005700 microbiome Species 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- 239000006096 absorbing agent Substances 0.000 description 7
- 229910000077 silane Inorganic materials 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000004745 nonwoven fabric Substances 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000002203 pretreatment Methods 0.000 description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- -1 silane compound Chemical class 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 238000000265 homogenisation Methods 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003980 solgel method Methods 0.000 description 3
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910000348 titanium sulfate Inorganic materials 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- RCZPHVPIOWNERS-UHFFFAOYSA-N CCCO[Ti] Chemical compound CCCO[Ti] RCZPHVPIOWNERS-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000192041 Micrococcus Species 0.000 description 1
- 229910003849 O-Si Inorganic materials 0.000 description 1
- 229910003872 O—Si Inorganic materials 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000012451 post-reaction mixture Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
Definitions
- the present invention relates to a process of manufacturing textile barrier materials from polyester fibers or their blends containing other fibers by sulfate and/or emulsion precipitation method as opposed to well-known hydrolysis and condensation of organic precursors (the so-called sol-gel method).
- These materials demonstrate an exceptional resistance to UV radiation and microorganisms as well as photocatalytic properties thanks to introducing into the structure of the textile material the anatase type of titanium dioxide or its oxygen composite Ti0 2 -Si0 2 the size of nano- and micrometric particles.
- the barrier properties of the textiles against UV radiation may result from the dense textile texture, as described in the patent EP644820B 1. They can also be effectively improved by, among other things, the use of UV absorbers, which are colorless substances that absorb radiation in the wavelength range of 290-400 nm. Depending on the mechanism of action, the UV absorbers can be divided into two groups:
- Inorganic absorbers or so-called physical blockers, which reflect and scatter UV radiation.
- the most commonly used blockers are zinc oxide (ZnO) and titanium dioxide (Ti0 2 ).
- Nano- Ti0 2 with highly developed surface of contact has the ability to block UV radiation and possesses self-cleaning (photocatalytic) properties. For this reason, it is readily applied to textiles. Due to its high capacity for UV absorption, as well as reflection and scattering of UV radiation, titanium dioxide is used as a physical blocker of UV radiation, increasing the barrier capacity of the textiles it modifies.
- the patent application JP 2006321087 (A) describes the barrier material based on polyester containing metal oxides such as silicon, titanium, tin, zinc, aluminum, indium.
- the anatase type titanium dioxide for modification of polyester textile material is also described in the following JP patent applications: 08-276397, 08-281715, 07-206059, 06- 142167, 01-115764, 01-014066.
- Ti0 2 -Si0 2 oxide composite One functional material with special useful properties is the Ti0 2 -Si0 2 oxide composite.
- the degree of dispersion of titanium dioxide is much greater, and its activity is higher. This also contributes to the transformation from anatase to rutile form, which prevents the growth of titanium dioxide particles during thermal treatment.
- silica increases the specific surface area of titanium dioxide and contributes to the formation of ⁇ Ti-O-Si ⁇ bonds. All of this increases photocatalytic activity of the Ti0 2 - Si0 2 composite [Ren S., Zhao X., Zhao L., Yuan M., Yu Y., Guo Y., Wang Z., Journal of Solid State Chemistry.
- Silica-coated titanium dioxide shows a higher thermal and mechanical stability, at the same time a reduced tendency for agglomeration of the particles and an increase the surface activity of the final product are observed.
- the nature of the invention is the method for obtaining textile barrier material against UV radiation and microbes, while using titanium dioxide particles of the anatase type which are micronized by means of alkoxysilanes or its Ti0 2 -Si0 2 oxide composite introduced into the structure of textile material.
- the process is performed in two stages.
- the first stage consists in proper preparation of the textile material in order to increase its adhesive properties.
- the surface of the polyester fibers is modified by low temperature plasma treatment (non-equilibrium) in the atmosphere of various gases, preferably carbon dioxide or argon.
- Another way to modify the surface is a controlled treatment of the textile product in a solution of sodium hydroxide at a temperature above 90° C.
- micronized particles of titanium dioxide of the anatase type or its oxide composites are introduced into the structure of the textile material in the amount that is not less than 0.5 wt%. and not more than 10% by weight.
- Polyester fiber products are padded with aqueous dispersion containing micronized particles of functionalized Ti0 2, a wetting agent, and a thickening agent.
- the dispersion is subjected to intense homogenization by means of a homogenizer at the proper time and speed. Once the padding has been completed in a two-roller padding machine, the excess of dispersion is removed from the samples in order to obtain an adequate level of deposition. Then, the samples are dried and heated up in a heat coating machine.
- aqueous dispersion with 1-5 wt.% of the modified Ti0 2 preparation, a wetting agent - polyethylene glycol (PEG) in the amount of 5-15 wt%. and hydroxyethyl cellulose thickener (HEC) - in the amount of 1-5 wt%.
- PEG polyethylene glycol
- HEC hydroxyethyl cellulose thickener
- Another way of incorporating Ti0 2 particles into the structure of the textile product is coating.
- a properly prepared paste on the basis of acrylic resin and containing the modified titanium dioxide of nano- and micrometric size, a thickening agent, and a wetting agent are applied to a textile carrier using a special kit for application of nanostructured film coatings.
- the film's thickness is controlled by adjusting the feeding slot/gap between the coating blade and the textile material being coated.
- the product with the applied coating is dried and heated up.
- paste containing 1-3 wt.% of modified Ti0 2, a wetting agent - polyethylene glycol (PEG) in the amount of 5-15 wt.%, styrene-acrylic resin with no more than 20 wt.%, acrylic thickening agent of 3-10 wt.%.
- PEG polyethylene glycol
- An anatase sample was placed in a reactor with the capacity of 500 cm 3 and sprayed with the 3-Methacryloxypropyltrimethoxysilane solution by means of a special spray system (atomizer).
- the solution contained a binding silane compound in the amount of 0.5 wt. parts of silane per 100 wt. parts of anatase.
- the binding silane compound was hydrolyzed in a mixture of methanol and water at the volume ratio of 4: 1. Then, the system was stirred for 1 hour in order to perfectly homogenize the anatase sample with the solution of the modifying compound and the solvent was distilled off.
- the modified sample was dried at the temperature of 105°C in a stationary dryer for 2 hours.
- an aqueous dispersion was made containing 3 wt%. of this sample, a wetting agent - polyethylene glycol in the amount of 10 wt%., and a thickening agent - hydroxyethyl cellulose in the amount of 1 wt%., with which the polyester fabric was padded after having been subjected to alkaline pre- treatment process.
- the dispersion was subjected to intense homogenization using a homogenizer for the duration of 60 s with the assumed speed of 20000 r / min. After the padding in a two-roller padding machine and removing the excess dispersion, the samples were dried for 3 minutes at the temperature of 100°C in a heating unit and heated up at the same temperature for 10 minutes.
- the alkaline pre-treatment of polyester fabric was conducted in a laboratory dyeing apparatus at bath ratio 10:1, in a bath composed of sodium hydroxide, 38° BE - 1.8 g/dm3, sodium carbonate - 4.1 g/dm3, sequestering and wetting agent - 1,0 g/dm3.
- the process was carried out at the temperature of 98°C for the duration of 60 minutes.
- the fabric was rinsed for 10 minutes in a water bath at the temperature of 80 ° C, and then under running water.
- Example I using 1 wt. part of silane per 100 wt. parts of anatase.
- the process of modifying titanium dioxide was carried out in the same way as in Example I using 3 wt. parts of silane per 100 wt. parts of anatase.
- the modification process was carried out in the same way as in Example I.
- Vinyltrimethoxysilane was used as a silane.
- an aqueous dispersion was made containing 3 wt% of the sample, a wetting agent - polyethylene glycol in the amount of 10 wt%. and a thickening agent - hydroxyethyl cellulose in the amount of 1 wt%. It was then padded onto the polyester nonwoven fabric which had previously been subjected to plasma pre-treatment.
- the dispersion was subjected to intense homogenization by means of a homogenizer for the duration of 60 s with the assumed speed of 20 000 r/min.
- the samples were dried for 3 minutes at the temperature of 100°C in a heating unit and heated up at the same temperature for 10 minutes.
- the plasma treatment of the polyester nonwoven fabric was carried out at RF discharge (13.56 MHz frequency). Plasma was generated in argon. The duration of the treatment was 15 s.
- N-2-(aminoethyl)-3-aminopropyltrimethoxysilane was used as silane.
- a coating paste was obtained on the basis of acrylic resin in the amount of 10 wt.% containing 3 wt.% of anatase preparation, a thickening agent of 4.5 wt.%, and a wetting agent (polyethylene glycol) of 10 wt.% with uniform dispersion and viscosity of 68 dPas which was applied to a polyester fabric previously subjected to alkaline pre-treatment process.
- polyester fabric was performed using a special kit for application of nanostructured coatings.
- the film's thickness was controlled by adjusting the feeding slot/gap between the coating blade and the textile material being coated - 0.05 mm.
- the samples were dried (heated up) at the temperature of 120°C for the duration of 6 minutes.
- the alkaline pre-treatment of polyester fabric was conducted in a laboratory dyeing apparatus at 10: 1 bath ratio, in a bath composed of sodium hydroxide, 38° BE - 1.8 g/dm3, sodium carbonate - 4.1 g/dm3, sequestering and wetting agent - 1,0 g/dm3.
- the process was carried out at the temperature of 98°C for the duration of 60 minutes.
- the fabric was rinsed for 10 minutes in a water bath at the temperature of 80° C, and then under running water.
- a suspension of titanium sulfate was centrifuged for 30 minutes at the speed of 2500 rpm/min, until a clear solution was obtained.
- two emulsions were prepared.
- the E2 emulsion was formed, which consisted of cyclohexane, titanium sulfate, and nonionic surfactants. The components of this emulsion were homogenized.
- the El emulsion was prepared consisting of cyclohexane, 20% solution of sodium silicate and hydrophobizing agents. The El emulsion was also homogenized.
- the process of coating polyester nonwoven fabric was performed using a special kit for application of nanostructured coatings. The film's thickness was controlled by adjusting the feeding slot/gap between the coating blade and the textile material being coated - 0.05 mm.
- the samples were dried (heated up) at the temperature of 120°C for the duration of 6 minutes.
- the plasma treatment of the polyester nonwoven fabric was carried out at RF discharge (13.56 MHz frequency). Plasma was generated in carbon dioxide. The duration of the treatment was 15 s.
- the barrier properties of the modified textiles for UV radiation were determined based on the measurements of the transmittance of UV radiation of fabric by means of the spectrophotometric method.
- the photooxidative activity was assessed based on the possibility of removing organic pollutant - formaldehyde, from the air in a closed system in which a sample of a textile product with titanium dioxide was placed - photocatalysing decomposition reactions of simple inorganic compounds.
- a product is obtained with barrier properties for UV radiation expressed by a reduced value of spectral transmittance in the whole UV range (increasing of absorption) and by the value of the coefficient UPF>50 determined in accordance to the standard EN 13758-1. It is characterized by a very good photooxidative activity (the decomposition efficiency of formaldehyde is 90-98%) and the inhibitory action of microorganisms like Bacillus subtilis, Micrococcus fla s, Pseudomonas aureginosa, Escherichia coli (Table 1).
- the antimicrobial properties of the modified textile product containing Ti0 2 of the anatase type in its structure were assessed by a screening method according to the standard EN ISO 20645 (agar plate diffusion test), based on the presence and size of the inhibition zone inhibiting the growth of the tested microorganisms around the examined sample and the growth, or lack thereof, in the contact zone of the sample with the culture medium.
- the resulting protective effect against UV radiation and the development of microorganisms is stable and maintained even after 10 laundry cycles.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Inorganic Chemistry (AREA)
- Toxicology (AREA)
- Plasma & Fusion (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Physics & Mathematics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Catalysts (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
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GB1307313.5A GB2500125B (en) | 2010-11-29 | 2011-11-28 | Process of manufacturing textile barrier materials |
BR112013012019-3A BR112013012019B1 (pt) | 2010-11-29 | 2011-11-28 | processo de fabricação de materiais de barreira de tecido |
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PLP-393076 | 2010-11-29 | ||
PL393076A PL219301B1 (pl) | 2010-11-29 | 2010-11-29 | Sposób wytwarzania barierowych materiałów włókienniczych |
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WO2012074419A3 WO2012074419A3 (fr) | 2012-08-02 |
WO2012074419A4 WO2012074419A4 (fr) | 2012-11-01 |
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BR (1) | BR112013012019B1 (fr) |
GB (1) | GB2500125B (fr) |
PL (1) | PL219301B1 (fr) |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015011725A2 (fr) | 2013-07-22 | 2015-01-29 | Reliance Industries Limited | Fibre pouvant être utilisée pour le conditionnement et le stockage de produits agricoles végétaux |
CN110102352A (zh) * | 2019-06-11 | 2019-08-09 | 河北燕园众欣石墨烯科技有限公司 | 一种负载型TiO2/纤维复合光催化剂的制备方法 |
CN111139550A (zh) * | 2019-12-30 | 2020-05-12 | 江苏众恒可来比家具有限公司 | 一种床品填充用自清洁聚酯纤维及其制备方法 |
CN112552061A (zh) * | 2020-12-28 | 2021-03-26 | 海鹰空天材料研究院(苏州)有限责任公司 | 一种陶瓷纤维板的制备方法 |
CN114875659A (zh) * | 2022-06-13 | 2022-08-09 | 安徽元琛环保科技股份有限公司 | 一种超疏水滤料及其制备方法 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015011725A2 (fr) | 2013-07-22 | 2015-01-29 | Reliance Industries Limited | Fibre pouvant être utilisée pour le conditionnement et le stockage de produits agricoles végétaux |
EP3024968A4 (fr) * | 2013-07-22 | 2017-05-03 | Reliance Industries Limited | Fibre pouvant être utilisée pour le conditionnement et le stockage de produits agricoles végétaux |
CN110102352A (zh) * | 2019-06-11 | 2019-08-09 | 河北燕园众欣石墨烯科技有限公司 | 一种负载型TiO2/纤维复合光催化剂的制备方法 |
CN111139550A (zh) * | 2019-12-30 | 2020-05-12 | 江苏众恒可来比家具有限公司 | 一种床品填充用自清洁聚酯纤维及其制备方法 |
CN111139550B (zh) * | 2019-12-30 | 2022-05-03 | 江苏众恒可来比家具有限公司 | 一种床品填充用自清洁聚酯纤维及其制备方法 |
CN112552061A (zh) * | 2020-12-28 | 2021-03-26 | 海鹰空天材料研究院(苏州)有限责任公司 | 一种陶瓷纤维板的制备方法 |
CN114875659A (zh) * | 2022-06-13 | 2022-08-09 | 安徽元琛环保科技股份有限公司 | 一种超疏水滤料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
PL219301B1 (pl) | 2015-04-30 |
PL393076A1 (pl) | 2012-06-04 |
WO2012074419A4 (fr) | 2012-11-01 |
BR112013012019B1 (pt) | 2020-11-10 |
WO2012074419A3 (fr) | 2012-08-02 |
BR112013012019A2 (pt) | 2017-10-17 |
GB201307313D0 (en) | 2013-05-29 |
GB2500125B (en) | 2016-06-29 |
GB2500125A (en) | 2013-09-11 |
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