WO2012072527A3 - Mechanochemische herstellung von zeolithen - Google Patents

Mechanochemische herstellung von zeolithen Download PDF

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Publication number
WO2012072527A3
WO2012072527A3 PCT/EP2011/071099 EP2011071099W WO2012072527A3 WO 2012072527 A3 WO2012072527 A3 WO 2012072527A3 EP 2011071099 W EP2011071099 W EP 2011071099W WO 2012072527 A3 WO2012072527 A3 WO 2012072527A3
Authority
WO
WIPO (PCT)
Prior art keywords
zeolites
provision
synthesis
synthesis gel
template
Prior art date
Application number
PCT/EP2011/071099
Other languages
English (en)
French (fr)
Other versions
WO2012072527A2 (de
Inventor
Josef SCHÖNLINNER
Jürgen Ladebeck
Jürgen Koy
Stephan Wellach
Götz BURGFELS
Original Assignee
Süd-Chemie Ip Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Süd-Chemie Ip Gmbh & Co. Kg filed Critical Süd-Chemie Ip Gmbh & Co. Kg
Priority to JP2013541310A priority Critical patent/JP2014501683A/ja
Priority to EP11788450.2A priority patent/EP2646367A2/de
Priority to US13/988,598 priority patent/US20130266507A1/en
Priority to CN2011800573934A priority patent/CN103269978A/zh
Publication of WO2012072527A2 publication Critical patent/WO2012072527A2/de
Publication of WO2012072527A3 publication Critical patent/WO2012072527A3/de
Priority to ZA2013/03567A priority patent/ZA201303567B/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

Gegenstand der Erfindung ist ein Verfahren zur Synthese von Zeolithen, umfassend die folgenden Schritte: a) Bereitstellen einer Silizium-Quelle; b) Bereitstellen einer Aluminium-Quelle; c) gegebenenfalls Bereitstellen mindestens eines Templats; d) Mischen der Silizium-Quelle, der Aluminium-Quelle und des optionalen Templats zur Erzeugung eines Synthesegels; e) Vermahlung des Synthesegels; f) Behandlung des vermahlenen Synthesegels unter hydrothermalen Bedingungen zur Erzeugung von kristallinem Zeolith, sowie nach diesem Verfahren erhältliche Zeolithe. Die nach dem Verfahren erhaltenen Produkte können als Katalysatoren oder Katalysatorträger verwendet werden.
PCT/EP2011/071099 2010-12-01 2011-11-28 Mechanochemische herstellung von zeolithen WO2012072527A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2013541310A JP2014501683A (ja) 2010-12-01 2011-11-28 ゼオライトのメカノケミカル製造
EP11788450.2A EP2646367A2 (de) 2010-12-01 2011-11-28 Mechanochemische herstellung von zeolithen
US13/988,598 US20130266507A1 (en) 2010-12-01 2011-11-28 Mechanochemical production of zeolites
CN2011800573934A CN103269978A (zh) 2010-12-01 2011-11-28 沸石的机械化学生产
ZA2013/03567A ZA201303567B (en) 2010-12-01 2013-05-16 Mechanochemical production of zeolites

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010053054.9 2010-12-01
DE102010053054A DE102010053054A1 (de) 2010-12-01 2010-12-01 Mechanochemische Herstellung von Zeolithen

Publications (2)

Publication Number Publication Date
WO2012072527A2 WO2012072527A2 (de) 2012-06-07
WO2012072527A3 true WO2012072527A3 (de) 2012-10-11

Family

ID=45047780

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/071099 WO2012072527A2 (de) 2010-12-01 2011-11-28 Mechanochemische herstellung von zeolithen

Country Status (7)

Country Link
US (1) US20130266507A1 (de)
EP (1) EP2646367A2 (de)
JP (1) JP2014501683A (de)
CN (1) CN103269978A (de)
DE (1) DE102010053054A1 (de)
WO (1) WO2012072527A2 (de)
ZA (1) ZA201303567B (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102951656B (zh) * 2012-10-16 2014-06-04 大连瑞克科技有限公司 一种颗粒均匀zsm-5分子筛的合成方法
JP6173196B2 (ja) * 2012-12-21 2017-08-02 日揮触媒化成株式会社 ナノサイズゼオライトの合成方法
CN104860332A (zh) * 2014-02-21 2015-08-26 中国石油化工股份有限公司 一种制备NaY分子筛的方法
CN109665541B (zh) * 2017-10-17 2022-04-01 中国石油化工股份有限公司 低硅铝比zsm-12型沸石分子筛的合成方法
CN108408737A (zh) * 2018-05-29 2018-08-17 王子韩 一种快速制备y型分子筛的方法
KR20200012812A (ko) * 2018-07-27 2020-02-05 에스케이이노베이션 주식회사 입자 균일도가 우수한 모데나이트 제올라이트 및 그 제조방법
KR102020445B1 (ko) 2018-09-21 2019-09-10 에스케이이노베이션 주식회사 입자 크기의 제어가 가능한 모데나이트 제올라이트의 제조방법
WO2020109290A1 (en) 2018-11-27 2020-06-04 Basf Se Solvent-free mechanochemical activation in zeolite synthesis
WO2020108482A1 (en) * 2018-11-27 2020-06-04 Basf Se Mechanochemical activation in solvent-free zeolite synthesis
WO2020109292A1 (en) 2018-11-27 2020-06-04 Basf Se Mechanochemical activation in zeolite synthesis
WO2021067077A1 (en) * 2019-09-30 2021-04-08 Dow Global Technologies Llc Methods of etherification
CN110893491B (zh) * 2019-12-13 2021-07-27 湖南中镆科技有限公司 一种铝模板铣槽固定装置
CN111001265B (zh) * 2019-12-26 2021-11-12 维珂瑞（北京）环境科技有限公司 高质量沸石转轮生产工艺及其生产设备
CN116102032A (zh) * 2023-02-06 2023-05-12 淄博恒亿化工科技有限公司 一种zsm-5分子筛的制备方法

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EP0187522A2 (de) * 1984-12-31 1986-07-16 Exxon Research And Engineering Company Herstellung von beta-Zeolith
EP0915056A1 (de) * 1997-11-07 1999-05-12 Ngk Insulators, Ltd. Hochwärmebeständiger Beta-Zeolith und Adsorptionsmittel zur Reinigung von Autoabgasen
US7119245B1 (en) * 2001-10-25 2006-10-10 Sandia Corporation Synthesis of an un-supported, high-flow ZSM-22 zeolite membrane

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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0187522A2 (de) * 1984-12-31 1986-07-16 Exxon Research And Engineering Company Herstellung von beta-Zeolith
EP0915056A1 (de) * 1997-11-07 1999-05-12 Ngk Insulators, Ltd. Hochwärmebeständiger Beta-Zeolith und Adsorptionsmittel zur Reinigung von Autoabgasen
US7119245B1 (en) * 2001-10-25 2006-10-10 Sandia Corporation Synthesis of an un-supported, high-flow ZSM-22 zeolite membrane

Non-Patent Citations (2)

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Title
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Also Published As

Publication number Publication date
DE102010053054A1 (de) 2012-06-06
EP2646367A2 (de) 2013-10-09
JP2014501683A (ja) 2014-01-23
WO2012072527A2 (de) 2012-06-07
ZA201303567B (en) 2014-07-30
US20130266507A1 (en) 2013-10-10
CN103269978A (zh) 2013-08-28

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