WO2012031500A1 - Composé organique de silicium, son procédé de préparation et son utilisation - Google Patents

Composé organique de silicium, son procédé de préparation et son utilisation Download PDF

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Publication number
WO2012031500A1
WO2012031500A1 PCT/CN2011/076753 CN2011076753W WO2012031500A1 WO 2012031500 A1 WO2012031500 A1 WO 2012031500A1 CN 2011076753 W CN2011076753 W CN 2011076753W WO 2012031500 A1 WO2012031500 A1 WO 2012031500A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyether
preparation
bisallyl
organosilicon compound
reaction
Prior art date
Application number
PCT/CN2011/076753
Other languages
English (en)
Chinese (zh)
Inventor
黄振宏
谢秀鸿
黄晓梅
Original Assignee
广东标美硅氟新材料有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 广东标美硅氟新材料有限公司 filed Critical 广东标美硅氟新材料有限公司
Publication of WO2012031500A1 publication Critical patent/WO2012031500A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/682—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of chemical compounds for dispersing an oily layer on water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/485—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms containing less than 25 silicon atoms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/681—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of solid materials for removing an oily layer on water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/32—Hydrocarbons, e.g. oil
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences

Definitions

  • the invention belongs to the technical field of organosilicon compound synthesis, and particularly relates to an organosilicon compound and a preparation method and application thereof.
  • Chinese patent CN 1149612A discloses an oil spill collector composition for oil spills of diesel oil, from 1% to 10% by mass of natural carboxylic acid and 90% by mass. ⁇ 99% alcohol or kerosene organic solvent composition; oil collector for crude oil spill, from 1% to 10% by mass of natural carboxylic acid and polyoxyethylene oleate and 90% to 99% of the above organic solvent composition.
  • Cisoka Patent CN 1473767A discloses a surface oil film oil collecting agent having an active component and a carrier, the active component being a solid fatty alcohol, a solid fatty carboxylic acid, and a water-poor pear One, two or three of the alcohol fatty acid esters, and their total weight percentage is from 1 to 25%.
  • organosilicon compound in the preparation of an oil spill inducing agent.
  • the organosilicon compound of the invention has a hydrophobic structure at both ends, a hydrophilic structure in the middle section, and a special structure. Compared with other hydrocarbon surfactants, the surface tension is lower, the preparation is simple, and the oil collecting effect is better. It is convenient to use, and is non-toxic and environmentally friendly; the preparation method of the organosilicon compound adopts two molecules of halogenated propylene to simultaneously treat both ends of the -hydro- ⁇ -hydroxy polyether to obtain diene.

Abstract

L'invention concerne un composé organique de silicium et son procédé de préparation. Le composé organique de silicium comprend une structure représentée par la formule (I) dans laquelle a=0-40 ; b=0-30; c=0-40 ; a, b et c sont des nombres entiers et a+b+c>6. Le procédé de préparation comprend les étapes suivantes : un polyéther α-hydrogéné-ω-hydroxylé et un propylène halogéné sont mis à réagir en présence d'un hydroxyde de métal alcalin pour former un polyéther de diallyle ; le polyéther de diallyle obtenu et un 1,1,1,3,5,5,5-heptamethyl trisiloxane sont mis à réagir en présence d'un catalyseur Pt afin de produire un composé organique de silicium. Le composé organique de silicium possède un effet de collecte d'huile et peut être utilisé pour traiter l'huile déversée dans un environnement aqueux.
PCT/CN2011/076753 2010-09-10 2011-07-01 Composé organique de silicium, son procédé de préparation et son utilisation WO2012031500A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2010102813677A CN101942083B (zh) 2010-09-10 2010-09-10 一种有机硅化合物及其制备方法和应用
CN201010281367.7 2010-09-10

Publications (1)

Publication Number Publication Date
WO2012031500A1 true WO2012031500A1 (fr) 2012-03-15

Family

ID=43434304

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2011/076753 WO2012031500A1 (fr) 2010-09-10 2011-07-01 Composé organique de silicium, son procédé de préparation et son utilisation

Country Status (2)

Country Link
CN (1) CN101942083B (fr)
WO (1) WO2012031500A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942083B (zh) * 2010-09-10 2012-08-22 广东标美硅氟新材料有限公司 一种有机硅化合物及其制备方法和应用
EP2809729B1 (fr) * 2012-02-01 2019-04-24 Momentive Performance Materials Inc. Copolymères de siloxane-polyéther
DE102012203267A1 (de) * 2012-03-01 2013-09-05 Wacker Chemie Ag Organosiliciumverbindungen und deren Verwendung zur Herstellung von hydrophilen Oberflächen
CN103421035A (zh) * 2013-07-29 2013-12-04 惠州学院 开链式三硅氧烷冠醚表面活性剂及其制备方法
CN105727940B (zh) * 2014-12-09 2018-10-23 仲恺农业工程学院 一种采用响应面优化法制备超微孔铂催化剂催化合成有机硅增稠剂的方法
CN105001408B (zh) * 2015-07-30 2017-05-10 浙江皇马科技股份有限公司 一种高分子量双烯丙基封端聚醚的制备方法
CN106398677B (zh) * 2016-08-31 2019-04-09 湖北新四海化工股份有限公司 一种驱油有机硅表面活性剂及其制备方法

Citations (6)

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US20070134283A1 (en) * 2005-12-13 2007-06-14 General Electric Company Surfactant-based composition and associated methods
CN101418071A (zh) * 2008-10-27 2009-04-29 淮安凯悦科技开发有限公司 循环铂催化剂复合聚氧烷烯化聚甲基三硅氧烷的制备方法
CN101434615A (zh) * 2008-12-15 2009-05-20 蓝星化工新材料股份有限公司江西星火有机硅厂 超低表面张力的聚醚改性硅油及其合成工艺
US7601680B2 (en) * 2005-12-13 2009-10-13 Momentive Performance Materials Gemini silicone surfactant compositions and associated methods
CN101942083A (zh) * 2010-09-10 2011-01-12 广东标美硅氟新材料有限公司 一种有机硅化合物及其制备方法和应用
WO2011022827A1 (fr) * 2009-08-27 2011-03-03 Mcmaster University Élastomères siliconés modificateurs de surface

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6032022A (ja) * 1983-08-03 1985-02-19 Nippon Contact Lens Seizo Kk コンタクトレンズ材料
CN1461764A (zh) * 2002-05-29 2003-12-17 黄振宏 一种含氟、硅有机高分子多元聚合物及其生产工艺
CN1468887A (zh) * 2002-07-17 2004-01-21 黄振宏 有机硅季铵盐高分子聚合物制备与应用方法
CN1468886A (zh) * 2002-07-17 2004-01-21 黄振宏 一种氨基酸改性聚有机硅氧烷

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070134283A1 (en) * 2005-12-13 2007-06-14 General Electric Company Surfactant-based composition and associated methods
US7601680B2 (en) * 2005-12-13 2009-10-13 Momentive Performance Materials Gemini silicone surfactant compositions and associated methods
CN101418071A (zh) * 2008-10-27 2009-04-29 淮安凯悦科技开发有限公司 循环铂催化剂复合聚氧烷烯化聚甲基三硅氧烷的制备方法
CN101434615A (zh) * 2008-12-15 2009-05-20 蓝星化工新材料股份有限公司江西星火有机硅厂 超低表面张力的聚醚改性硅油及其合成工艺
WO2011022827A1 (fr) * 2009-08-27 2011-03-03 Mcmaster University Élastomères siliconés modificateurs de surface
CN101942083A (zh) * 2010-09-10 2011-01-12 广东标美硅氟新材料有限公司 一种有机硅化合物及其制备方法和应用

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CN101942083A (zh) 2011-01-12
CN101942083B (zh) 2012-08-22

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