WO2012019509A1 - 新型轴承环材料及其生产工艺 - Google Patents

新型轴承环材料及其生产工艺 Download PDF

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Publication number
WO2012019509A1
WO2012019509A1 PCT/CN2011/077797 CN2011077797W WO2012019509A1 WO 2012019509 A1 WO2012019509 A1 WO 2012019509A1 CN 2011077797 W CN2011077797 W CN 2011077797W WO 2012019509 A1 WO2012019509 A1 WO 2012019509A1
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WIPO (PCT)
Prior art keywords
layer
composite
bearing ring
steel
base layer
Prior art date
Application number
PCT/CN2011/077797
Other languages
English (en)
French (fr)
Inventor
唐勇
王黎晖
李赤波
鲍善勤
高杰
宋亚峰
黄晓斌
Original Assignee
新兴铸管股份有限公司
北京长兴凯达复合材料科技发展有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by 新兴铸管股份有限公司, 北京长兴凯达复合材料科技发展有限公司 filed Critical 新兴铸管股份有限公司
Priority to US13/583,796 priority Critical patent/US20130157077A1/en
Priority to EP11816068.8A priority patent/EP2538099B1/en
Priority to JP2012546356A priority patent/JP2013515614A/ja
Publication of WO2012019509A1 publication Critical patent/WO2012019509A1/zh

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/58Raceways; Race rings
    • F16C33/62Selection of substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D13/00Centrifugal casting; Casting by using centrifugal force
    • B22D13/02Centrifugal casting; Casting by using centrifugal force of elongated solid or hollow bodies, e.g. pipes, in moulds rotating around their longitudinal axis
    • B22D13/023Centrifugal casting; Casting by using centrifugal force of elongated solid or hollow bodies, e.g. pipes, in moulds rotating around their longitudinal axis the longitudinal axis being horizontal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/011Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of iron alloys or steels
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/40Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rings; for bearing races
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121Use of special materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/122Multilayer structures of sleeves, washers or liners
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/14Special methods of manufacture; Running-in
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/58Raceways; Race rings
    • F16C33/64Special methods of manufacture
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2220/00Shaping
    • F16C2220/02Shaping by casting
    • F16C2220/06Shaping by casting in situ casting or moulding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2220/00Shaping
    • F16C2220/40Shaping by deformation without removing material
    • F16C2220/46Shaping by deformation without removing material by forging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2220/00Shaping
    • F16C2220/40Shaping by deformation without removing material
    • F16C2220/48Shaping by deformation without removing material by extrusion, e.g. of metallic profiles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2220/00Shaping
    • F16C2220/60Shaping by removing material, e.g. machining
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2220/00Shaping
    • F16C2220/60Shaping by removing material, e.g. machining
    • F16C2220/66Shaping by removing material, e.g. machining by milling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2223/00Surface treatments; Hardening; Coating
    • F16C2223/10Hardening, e.g. carburizing, carbo-nitriding
    • F16C2223/12Hardening, e.g. carburizing, carbo-nitriding with carburizing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2223/00Surface treatments; Hardening; Coating
    • F16C2223/30Coating surfaces
    • F16C2223/42Coating surfaces by spraying the coating material, e.g. plasma spraying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2223/00Surface treatments; Hardening; Coating
    • F16C2223/30Coating surfaces
    • F16C2223/44Coating surfaces by casting molten material on the substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12639Adjacent, identical composition, components
    • Y10T428/12646Group VIII or IB metal-base
    • Y10T428/12653Fe, containing 0.01-1.7% carbon [i.e., steel]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12951Fe-base component
    • Y10T428/12972Containing 0.01-1.7% carbon [i.e., steel]
    • Y10T428/12979Containing more than 10% nonferrous elements [e.g., high alloy, stainless]

Definitions

  • the invention relates to a bimetal composite pipe and a production process thereof, in particular to a composite pipe material of a bearing ring material and a production process thereof.
  • the bearing materials currently used are mainly divided into the following types:
  • High carbon chromium bearing steels are mainly made of GCr9, GCrl5, GCr9SiMn and GCrl5SiMn.
  • GCr9 is mainly used to manufacture steel balls or rollers with small size on the rotating shaft, bearing rings and rolling elements working under normal conditions;
  • GCrl5 is used to manufacture steel balls, rollers and bearing rings of large mechanical bearings;
  • GCr9SiMn has the same performance as GCrl5 Similar, mainly used to manufacture larger bearing rings;
  • GCrl5SiMn has higher wear resistance and hardenability than GCrl5, and is mainly used to manufacture bearing rings, steel balls and rollers for large bearings.
  • Carburizing bearing materials mainly include G20CrMo, G20Cr2Ni4, G20Cr2Mn2Mo and G20CrM2Mo.
  • This type of bearing steel is mainly used for bearing rings and rolling elements that can withstand impact loads. This is because, after being surface carburized, this kind of steel has good hardness and toughness value and can withstand large impact loads.
  • the carburizing depth is 2.3 mm
  • the impact toughness value is 68.7 J/cm 2 .
  • Stainless steel bearing materials are currently used in 9Crl8 and 9Crl8MoV. These steel grades are mainly used to manufacture corrosion-resistant bearing rings and rolling elements, such as seawater, river water, nitric acid, chemical petroleum, and atomic reactor bearings.
  • the oil-free lubricating bimetal bearing material is made of high-quality low-carbon steel backing, sintered on the surface of lead-tin bronze alloy, which is made of copper-steel integrated bimetal strip after several times of high-temperature sintering and compact rolling. For the manufacture of bushes, thrust washers, etc. that are subjected to medium speed and high impact loads.
  • Rolling bearings are usually operated at higher speeds or under larger loads. Therefore, rolling bearing materials are required to have the following characteristics:
  • the technical problem to be solved by the present invention is to provide a novel bearing ring material which is highly compatible with high hardness, high wear resistance, high toughness and high impact toughness value and a production process thereof.
  • the novel bearing ring material of the present invention is composed of an annular composite layer and a base layer.
  • the composite layer and the base layer are metallurgically bonded together along a radial direction of the ring.
  • the composite layer is made of bearing steel material
  • the base layer is made of bearing steel and carbon steel. , low/medium alloy high strength steel or stainless steel.
  • novel bearing ring material of the present invention wherein the composite layer is a working layer, and the base layer is a support layer.
  • novel bearing ring material of the present invention wherein the composite layer is disposed outside the base layer in the radial direction of the base layer.
  • novel bearing ring material of the present invention wherein the composite layer is disposed on the inner side of the base layer along the radial direction of the base layer.
  • novel bearing ring material of the invention wherein the double layer is made of high carbon chromium bearing steel or stainless bearing steel material.
  • the composite material according to the conditions of use that is, the bearing steel material; select the corresponding base material according to the strength requirement and the thermal expansion coefficient of the composite layer, that is, bearing steel, plain carbon steel, low/medium alloy high strength steel or stainless steel material, base material Toughness is higher than that of composite materials;
  • the metal pipe mold is baked to 200-300 ° C and sprayed with a coating, the thickness of the spray is 1.0-3.0 mm;
  • the metal tube mold after spraying the coating is baked to 200-350 ° C;
  • step C centrifugally pouring the first layer of the layer or the base material metal liquid into the metal pipe mold described in step B, and cooling;
  • step G machining the as-cast composite tube blank obtained in step F, and processing to the required size for longitudinal rolling; H.
  • the composite pipe obtained in the step G is longitudinally rolled to obtain a composite pipe ring for processing the bearing ring.
  • step G machining the as-cast composite tube blank obtained in step F, and processing to the size required for hot extrusion;
  • the composite pipe obtained in the step G is hot extruded to obtain a composite pipe ring for processing the bearing ring.
  • step G machining the as-cast composite tube blank obtained in step F, and processing to the required size for hot rolling;
  • the composite pipe obtained in the step G is hot-pressed to obtain a composite pipe ring for processing the bearing ring.
  • step G machining the as-cast composite tube blank obtained in step F, and processing to the required size for forging;
  • the composite pipe obtained in the step G is forged to obtain a composite pipe ring for processing the bearing ring.
  • the production process of the novel bearing ring material of the present invention wherein the heat treatment in the step F comprises normalizing, spheroidizing annealing or diffusion annealing.
  • the novel bearing ring material of the invention provides a bimetal composite pipe material, which is composed of a composite layer and a base layer, and the double layer is made of bearing steel material, and the base layer is made of bearing steel with relatively high toughness, impact toughness value and thermal expansion coefficient and similar layer.
  • Carbon steel, low/medium alloy high-strength steel or stainless steel to ensure the required toughness and high impact toughness of bearing materials under the performance requirements of normal bearing steel materials, to prevent large impact loads Underneath, the impact damage of the bearing is caused, and at the same time, the problem of low shear fatigue resistance of the surface of the working surface due to the unevenness of the carburized layer is overcome.
  • FIG. 1 is a schematic structural view of a first embodiment of a novel bearing ring material according to the present invention
  • FIG. 2 is a schematic structural view of a second embodiment of a novel bearing ring material of the present invention.
  • the outer layer (base layer) is made of low-alloy high-strength steel 16MnV, and the inner layer (multilayer) is made of bearing steel GCrl5, which has two layers.
  • 16MnV composition (mass content): C 0.14-0.2%, Si 0.3-0.6%, Mn 1.0 ⁇ 1.6%, P ⁇ 0.025%, S ⁇ 0.025%,
  • V 0.05 ⁇ 0.15%, others are Fe; melting point is about 1510 ° C, 1783.15K.
  • GCrl5 composition (mass content): C 0.95 ⁇ 1.05%, Si 0.15-0.35%, Mn 0.25-0.45%, P ⁇ 0.025%,
  • the thickness of the coating is 2.0-2. lmm; B. The metal tube mold after spraying the coating is baked to 260-290 ° C;
  • step E Machining the as-cast composite pipe obtained in step E to the required size of the extruder, processing size 0248/0142/0108 X 573 mm;
  • step F The composite pipe obtained in step F is hot extruded, the extrusion temperature is 1195 ° C, the pressing force is 22 to 25 MPa, the extrusion ratio is 12.0, and the finished pipe size is 09O/064/058x56OOmm.
  • FIG. 1 A schematic structural view of the new bearing ring material obtained in the step G is shown in Fig. 1.
  • the inner layer 1 is a working layer
  • the outer layer 2 is a supporting layer.
  • Example 2
  • the outer layer (multilayer) is made of bearing steel GCrl5, and the inner layer (base layer) is made of medium alloy high-strength steel 30CrMnSi, which has two layers.
  • 30CrMnSi composition (mass content): C 0.27-0.34%, Si 0.9-1.2%, Mn 0.8-1.1%, Cr 0.8-1.1%,
  • P ⁇ 0.035%, S ⁇ 0.035%, others are Fe; melting point is about 1480 ⁇ 1500°C, 1753.15-1773.15Ko
  • GCrl5 composition (mass content): C 0.95 ⁇ 1.05%, Si 0.15-0.35%, Mn 0.25-0.45%, P ⁇ 0.025%,
  • the metal tube mold is baked to 250-260 ° C and sprayed with a coating thickness of 2.0-2.2 mm;
  • the metal tube mold after spraying the coating is baked to 270-300 ° C;
  • step F machining the as-cast composite pipe obtained in step E, processing to the required size of extrusion, processing size 0280/0260/0130x780mm;
  • step F The composite pipe obtained in step F is hot extruded, the extrusion temperature is 1200 ° C, the pressing force is 22 to 25 MPa, the extrusion ratio is 11.3, and the finished pipe size is 0139.7/0136/0118.6 x 7000 mm.
  • the outer layer (base layer) is made of low-alloy high-strength steel 16MnV, and the inner layer (multilayer) is made of bearing steel GCrl5, which has two layers.
  • 16MnV composition (mass content): C 0.14-0.2%, Si 0.3-0.6%, Mn 1.0-1.6%, P ⁇ 0.025%,
  • GCrl5 composition (mass content): C 0.95 ⁇ 1.05%, Si 0.15-0.35%, Mn 0.25-0.45%, P ⁇ 0.025%,
  • the metal tube mold is baked to 250-260 ° C and sprayed with a coating thickness of 2.0-2.2 mm;
  • the metal tube mold after spraying the coating is baked to 270-300 ° C;
  • step F Machining the as-cast composite pipe obtained in step E, processing to the required size of continuous rolling, processing size 0220/0140/0110 2000mm;
  • the outer layer (base layer) is made of carburized bearing steel G20CrNi2Mo, and the inner layer (multilayer) is made of bearing steel GCrl5, which has two layers.
  • G20CrM2Mo composition (mass content): C 0.17-0.23%, Si 0.15-0.40%, Mn 0.40-0.70%, P ⁇ 0.02%, S ⁇ 0.02%, Cr 0.4-0.6%, Ni 1.6-2.0%; Mo 0.2- 0.3%, Al 0.1-0.5%, Cu ⁇ 0.2% ; , others are Fe; melting point is about 1490 °C.
  • GCrl5 composition (mass content): C 0.95 ⁇ 1.05%, Si 0.15-0.35%, Mn 0.25-0.45%, P ⁇ 0.025%, S ⁇ 0.025%, Cr 1.4-1.65%, others are Fe; melting point about 1450°C .
  • the metal tube mold is baked to 250-260 ° C and sprayed with a coating thickness of 2.0-2.2 mm;
  • the metal tube mold after spraying the coating is baked to 270-300 ° C;
  • the composite pipe is cooled to room temperature and demoulded, and at this time, a sufficient metallurgical bond is achieved between the inner layer and the outer layer, and the metallurgical fusion thickness is 0.8 to 1.2 mm; the tube blank is subjected to normalizing treatment, Fire temperature 930 ° C;
  • step F Machining the as-cast composite pipe obtained in step E, processing to the required size of rolling, processing size 0219/0162/0135x75mm ;
  • step G Pressing the composite pipe obtained in step F, the rolling temperature is 1180 ° C, and the finished ring size is 0275/0230/0211 X 71 mm.
  • the sampling of the pipe obtained in step G of Examples 1, 2, 3 and 4 is carried out according to the heat treatment process of conventional bearing steel.
  • the performance of the base and composite layers after heat treatment is shown in Table 1.
  • the new bearing ring material obtained in step G of the above four embodiments is subjected to conventional heat treatment, and the bearing ring can be formed by a conventional bearing ring production process.
  • the novel bearing ring material of the invention and the production process thereof utilize the existing metal materials and production equipment to produce a bearing ring material with better performance through a special production process, and the bearing ring material can improve the performance and the service life of the bearing. Therefore, it has great market prospects and strong industrial applicability.

Description

新型轴承环材料及其生产工艺 技术领域
本发明涉及一种双金属复合管材及其生产工艺, 特别是涉及一种轴承环材料的复合管材 及其生产工艺。
背景技术
目前应用的轴承材料主要分为以下几种:
1 ) 高碳铬轴承钢材料 (GB/T 18254-2002);
高碳铬轴承钢主要有 GCr9、 GCrl5、 GCr9SiMn和 GCrl5SiMn等材质。 GCr9主要用于 制造转动轴上尺寸较小的钢球或者滚子, 一般条件下工作的轴承环及滚动体; GCrl5用于制 造大型机械轴承的钢球、 滚子和轴承环; GCr9SiMn性能同 GCrl5相近, 主要用于制造尺寸 较大的轴承环; GCrl5SiMn的耐磨性和淬透性比 GCrl5高,主要用于制造大型轴承的轴承环、 钢球和滚子。
2) 渗碳轴承钢材料 (GB/T3203— 1982);
渗碳轴承材料主要有 G20CrMo、 G20Cr2Ni4 G20Cr2Mn2Mo和 G20CrM2Mo等材质, 此类型轴承钢主要用于承受冲击荷载的轴承环和滚动体。 这是因为, 此类钢经表面渗碳后, 具有良好的硬度和韧性值, 可以承受较大的冲击荷载, 如 G20Cr2Ni4渗碳轴承钢经渗碳 +热 处理后, 表面硬度 HRC62, 心部硬度 HRC43 , 渗碳深度 2.3mm, 冲击韧性值达到 68.7J/cm2
3 ) 不锈轴承钢材料 (GB/T3086— 1982);
不锈轴承钢材料目前应用较多的是 9Crl8和 9Crl8MoV, 该类钢种主要用于制造耐蚀的 轴承环及滚动体, 如海水、 河水、 硝酸、 化工石油、 原子反应堆用轴承等。
4) 无油润滑双金属轴承材料
无油润滑双金属轴承材料是以优质低碳钢背为基体, 表面烧结铅锡青铜合金, 经数次高 温烧结和致密轧制而成铜 -钢一体的双金属带材卷制而成, 适合于制造承受中速、 高冲击载荷 的衬套、 止推垫圈等。
滚动轴承通常都在较高的转速或较大的荷载下运行, 因此, 要求滚动轴承材料须具备下 述特点:
1 ) 必须可以充分淬硬, 具有较高的硬度和耐磨性;
2) 必须具有较高的疲劳强度、 特别是工作面的抗剪切疲劳强度;
3 ) 在工作温度下, 保证轴承零件具有结构和尺寸的稳定性; 4) 对于承受冲击荷载情况下的轴承具备较大的抗冲击能力;
但是, 对于同一种材料而言, 硬度、 耐磨性和韧性、 抗冲击能力是相互矛盾的, 要求足 够高的硬度、 强度和耐磨性必然会以降低材料的韧性和抗冲击性能为代价。 虽然渗碳轴承钢 材料可在一定程度上满足工作面硬度和整体韧性的配合, 但渗碳层的碳含量不均匀性又大大 降低了工作面的抗剪切疲劳性能。如何保证在足够的硬度、耐磨性下不降低材料的冲击韧性, 同时又保证工作面具有较高的抗剪切疲劳性能, 正是本专利所解决的。
发明内容
本发明要解决的技术问题是提供一种高硬度、 高耐磨性和高韧性、 高冲击韧性值相互配 合的新型轴承环材料及其生产工艺。
本发明新型轴承环材料由环形的复层和基层构成, 所述复层和基层沿环形的径向冶金结 合在一起, 所述复层采用轴承钢材料, 所述基层采用轴承钢、 普碳钢、 低 /中合金高强度钢或 不锈钢材料。
本发明新型轴承环材料, 其中所述复层为工作层, 所述基层为支撑层。
本发明新型轴承环材料, 其中所述复层沿基层的径向设置在基层的外侧。
本发明新型轴承环材料, 其中所述复层沿基层的径向设置在基层的内侧。
本发明新型轴承环材料, 其中所述复层采用高碳铬轴承钢或不锈轴承钢材料。
本发明新型轴承环材料的生产工艺, 按照如下步骤进行:
( 1 ) 选材
根据使用条件选择复层材料, 即轴承钢材料; 根据强度要求和复层的热膨胀系数选择相 应的基层材料, 即轴承钢、 普碳钢、 低 /中合金高强度钢或不锈钢材料, 基层材料的韧性高于 复层材料;
(2) 离心浇注
A、 将金属管模烘烤至 200-300°C后喷涂涂料, 喷涂厚度为 1.0-3.0mm;
B、 将喷涂涂料后的金属管模烘烤至 200-350°C ;
C、 向步骤 B所述的金属管模中离心浇注第一层复层或基层材料金属液, 并冷却;
D、 对浇注并凝固后的第一层金属进行传热数值模拟分析, 根据温度分析结果浇注第二 层基层或复层材料金属液;
E、 将浇注完成后的复合管坯冷却至 <700°C时脱模;
F、 根据后续加工条件对步骤 E所得管坯进行热处理;
(3 ) 纵轧
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至纵轧所需尺寸; H、 对步骤 G所得复合管材进行纵轧, 从而得到用于加工轴承环的复合管环。
本发明新型轴承环材料的生产工艺, 其中所述步骤 (3 ) 用热挤压方式替换, 即
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至热挤压所需尺寸;
H、 对步骤 G所得复合管材进行热挤压, 从而得到用于加工轴承环的复合管环。
本发明新型轴承环材料的生产工艺, 其中所述步骤 (3 ) 用热辗压方式替换, 即
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至热辗压所需尺寸;
H、 对步骤 G所得复合管材进行热辗压, 从而得到用于加工轴承环的复合管环。
本发明新型轴承环材料的生产工艺, 其中所述步骤 (3 ) 用锻造方式替换, 即
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至锻造所需尺寸;
H、 对步骤 G所得复合管材进行锻造, 从而得到用于加工轴承环的复合管环。
本发明新型轴承环材料的生产工艺,其中所述步骤 F中的热处理包括正火、球化退火或扩 散退火。
本发明新型轴承环材料提供了一种双金属复合管材, 由复层和基层构成, 复层选用轴承 钢材料, 基层选用韧性、 冲击韧性值相对较高、 热膨胀系数与复层相近的轴承钢、 普碳钢、 低 /中合金高强度钢或不锈钢, 在保证正常轴承钢材料所需的性能要求下, 极大的提高轴承材 料所需的韧性和高冲击韧性值, 以防止在大冲击荷载情况下, 造成的轴承的冲击破坏, 同时 又克服了渗碳轴承钢由于渗碳层不均性带来的工作面表层抗剪切疲劳性低的问题。
下面结合附图对本发明的新型轴承环材料及其生产工艺作进一步说明。
附图说明
图 1为本发明新型轴承环材料第一种实施方式的结构示意图;
图 2为本发明新型轴承环材料第二种实施方式的结构示意图。
具体实施方式
实施例 1
( 1 ) 选材;
外层 (基层) 选用低合金高强度钢 16MnV, 内层 (复层) 选用轴承钢 GCrl5, 共两层。
16MnV成分(质量含量): C 0.14-0.2%, Si 0.3-0.6%, Mn 1.0〜1.6%, P≤0.025%, S<0.025%,
V 0.05〜0.15%, 其他为 Fe; 熔点约 1510°C, 1783.15K。
GCrl5成分 (质量含量) : C 0.95~1.05%, Si 0.15-0.35%, Mn 0.25-0.45%, P<0.025%,
S<0.025%, Cr 1.4-1.65%, 其他为 Fe; 熔点约 1450°C, 1723.15K。
(2) 离心浇注
A、 将金属管模烘烤至 250-260°C后喷涂涂料, 喷涂厚度为 2.0-2. lmm; B、 将喷涂涂料后的金属管模烘烤至 260-290°C ;
C、 向 B所述的金属管模中离心浇注 16MnV金属液并冷却, 浇注温度 1587°C, 浇注重 量 360Kg;
D、 对浇注并凝固后的外层金属 16MnV进行传热数值模拟分析, 为了使内外层金属具有 较好的结合厚度, 待外层内表面温度降低至 1400°C时, 浇注内层 GCrl5 金属液, 浇注温度 1504 °C, 浇注重量 90Kg;
E、将上述浇注完成后的复合管材冷却至室温,此时内层与外层之间达到了充分的冶金结 合, 冶金熔合厚度 1.0 1.5mm;
(3 ) 热挤压
F、 对步骤 E 所得铸态复合管材进行机加工, 加工至挤压机所需尺寸, 加工尺寸 0248/0142/0108 X 573 mm;
G、 对步骤 F所得复合管材进行热挤压, 挤压温度 1195°C, 挤压力 22~25MPa, 挤压比 12.0, 成品管尺寸, 09O/064/058x56OOmm。
由步骤 G得到的新型轴承环材料的结构示意图如图 1所示, 内层复层 1为工作层, 外层 基层 2为支撑层。 实施例 2
( 1 ) 选材;
外层(复层)选用轴承钢 GCrl5, 内层(基层)选用中合金高强度钢 30CrMnSi, 共两层。 30CrMnSi成分 (质量含量): C 0.27-0.34%, Si 0.9-1.2%, Mn 0.8—1.1%, Cr 0.8—1.1%,
P<0.035%, S<0.035%, 其他为 Fe; 熔点约 1480~1500°C, 1753.15-1773.15Ko
GCrl5成分 (质量含量) : C 0.95~1.05%, Si 0.15-0.35%, Mn 0.25—0.45%, P<0.025%,
S<0.025%, Cr 1.4-1.65%, 其他为 Fe; 熔点约 1450°C, 1723.15K。
(2) 离心浇注
A、 将金属管模烘烤至 250-260°C后喷涂涂料, 喷涂厚度为 2.0-2.2mm;
B、 将喷涂涂料后的金属管模烘烤至 270-300°C ;
C、向 B所述的管模中离心浇注 GCrl5金属液并冷却,浇注温度 1556°C,浇注重量 270Kg;
D、 对浇注并凝固后的外层金属 GCrl5进行传热数值模拟分析, 为了使内外层金属具有 较好的结合厚度, 待外层内表面温度降低至 1387°C时, 浇注内层金属 30CrMnSi, 浇注温度 1587°C, 浇注重量 858Kg;
E、将上述浇注完成后的复合管材冷却至室温,此时内层与外层之间达到了充分的冶金结 合, 冶金熔合厚度 1.0 1.5mm;
( 3 ) 热挤压
F、 对步骤 E 所得铸态复合管材进行机加工, 加工至挤压所需尺寸, 加工尺寸 0280/0260/0130x780mm;
G、 对步骤 F所得复合管材进行热挤压, 挤压温度 1200°C, 挤压力 22~25MPa, 挤压比 11.3 , 成品管尺寸, 0139.7/0136/0118.6x7000mm。
由步骤 G得到的新型轴承环材料的结构示意图如图 2所示, 外层复层 Γ为工作层, 内层 基层 2'为支撑层。 实施例 3
( 1 ) 选材;
外层 (基层) 选用低合金高强度钢 16MnV, 内层 (复层) 选用轴承钢 GCrl5, 共两层。
16MnV成分 (质量含量) : C 0.14-0.2%, Si 0.3-0.6%, Mn 1.0—1.6%, P<0.025%,
S<0.025%, V 0.05〜0.15%, 其他为 Fe; 熔点约 1510°C, 1783.15K。
GCrl5成分 (质量含量) : C 0.95~1.05%, Si 0.15-0.35%, Mn 0.25—0.45%, P<0.025%,
S<0.025%, Cr 1.4-1.65%, 其他为 Fe; 熔点约 1450°C, 1723.15K。
(2) 离心浇注
A、 将金属管模烘烤至 250-260°C后喷涂涂料, 喷涂厚度为 2.0-2.2mm;
B、 将喷涂涂料后的金属管模烘烤至 270-300°C ;
C、向 B所述的管模中离心浇注 16MnV金属液并冷却,浇注温度 1576°C,浇注重量 372Kg;
D、 对浇注并凝固后的外层金属 16MnV进行传热数值模拟分析, 为了使内外层金属具有 较好的结合厚度,待外层内表面温度降低至 1395 °C时,浇注内层金属 GCrl5,浇注温度 1555 °C, 浇注重量 135Kg;
E、将上述浇注完成后的复合管材冷却至室温,此时内层与外层之间达到了充分的冶金结 合, 冶金熔合厚度 1.0 1.5mm;
( 3 ) 连轧
F、 对步骤 E 所得铸态复合管材进行机加工, 加工至连轧所需尺寸, 加工尺寸 0220/0140/0110 2000mm;
G、 对步骤 F 所得复合管材进行连轧, 轧制温度 1210°C, 成品管尺寸 0219/0198.6/0193 X 6000mm。 实施例 4
( 1 ) 选材;
外层 (基层) 选用渗碳轴承钢 G20CrNi2Mo, 内层 (复层) 选用轴承钢 GCrl5, 共两层。
G20CrM2Mo成分(质量含量): C 0.17-0.23%, Si 0.15-0.40%, Mn 0.40-0.70%, P<0.02%, S<0.02%, Cr 0.4-0.6%, Ni 1.6-2.0%; Mo 0.2-0.3%, Al 0.1-0.5%, Cu<0.2%; , 其他为 Fe; 熔点约 1490°C。
GCrl5成分 (质量含量) : C 0.95~1.05%, Si 0.15-0.35%, Mn 0.25—0.45%, P<0.025%, S<0.025%, Cr 1.4-1.65%, 其他为 Fe; 熔点约 1450°C。
(2) 离心浇注
A、 将金属管模烘烤至 250-260°C后喷涂涂料, 喷涂厚度为 2.0-2.2mm;
B、 将喷涂涂料后的金属管模烘烤至 270-300°C ;
C、 向 B所述的管模中离心浇注 G20CrNi2Mo金属液并冷却, 浇注温度 1589°C, 浇注重 量 204Kg;
D、 对浇注并凝固后的外层金属 G20CrNi2Mo进行传热数值模拟分析, 为了使内外层金 属具有较好的结合厚度, 待外层内表面温度降低至 1362 °C时, 浇注内层金属 GCrl5, 浇注温 度 1570°C, 浇注重量 105Kg;
E、将上述浇注完成后的复合管材冷却至室温脱模,此时内层与外层之间达到了充分的冶 金结合, 冶金熔合厚度 0.8~1.2mm; 对上述管坯进行正火处理, 正火温度 930°C ;
( 3 ) 辗压
F、 对步骤 E 所得铸态复合管材进行机加工, 加工至辗压所需尺寸, 加工尺寸 0219/0162/0135x75mm;
G、 对步骤 F 所得复合管材进行辗压, 辗压温度 1180°C, 成品环尺寸 0275/0230/0211 X 71 mm。 对实例 1、 2、 3和 4中步骤 G所获得的管材取样按照常规轴承钢的热处理工艺制度进行 热处理后的基层和复层性能见附表 1。
表 1新型轴承材料的性能
Figure imgf000008_0001
Figure imgf000009_0001
对上述 4个实施例中步骤 G得到的新型轴承环材料进行常规热处理, 再通过常规的轴承 环生产工艺即可制成轴承环。
以上所述的实施例仅仅是对本发明的优选实施方式进行描述, 并非对本发明的范围进行 限定, 在不脱离本发明设计精神的前提下, 本领域普通技术人员对本发明的技术方案作出的 各种变形和改进, 均应落入本发明权利要求书确定的保护范围内。
工业实用性
本发明新型轴承环材料及其生产工艺是利用现有的金属材料和生产设备, 通过特殊的生 产工艺生产出性能更加优秀的轴承环材料,这种轴承环材料能够提高轴承的性能和使用寿命, 因此具有很大的市场前景和很强的工业实用性。

Claims

权 利 要 求
1、 一种新型轴承环材料, 其特征在于: 由环形的复层和基层构成, 所述复层和基层沿环 形的径向冶金结合在一起, 所述复层采用轴承钢材料, 所述基层采用轴承钢、 普碳钢、 低 /中 合金高强度钢或不锈钢材料。
2、 根据权利要求 1所述的新型轴承环材料, 其特征在于: 所述复层为工作层, 所述基层 为支撑层。
3、 根据权利要求 2所述的新型轴承环材料, 其特征在于: 所述复层沿基层的径向设置在 基层的外侧。
4、 根据权利要求 2所述的新型轴承环材料, 其特征在于: 所述复层沿基层的径向设置在 基层的内侧。
5、 根据权利要求 1至 4所述之一的新型轴承环材料, 其特征在于: 所述复层采用高碳铬 轴承钢或不锈轴承钢材料。
6、一种如权利要求 1所述新型轴承环材料的生产工艺,其特征在于:按照如下步骤进行:
( 1 ) 选材
根据使用条件选择复层材料, 即轴承钢材料; 根据强度要求和复层的热膨胀系数选择相 应的基层材料, 即轴承钢、 普碳钢、 低 /中合金高强度钢或不锈钢材料, 基层材料的韧性高于 复层材料;
(2) 离心浇注
A、 将金属管模烘烤至 200-300°C后喷涂涂料, 喷涂厚度为 1.0-3.0mm;
B、 将喷涂涂料后的金属管模烘烤至 200-350°C ;
C、 向步骤 B所述的金属管模中离心浇注第一层复层或基层材料金属液, 并冷却;
D、 对浇注并凝固后的第一层金属进行传热数值模拟分析, 根据温度分析结果浇注第二 层基层或复层材料金属液;
E、 将浇注完成后的复合管坯冷却至 <700°C时脱模;
F、 根据后续加工条件对步骤 E所得管坯进行热处理;
(3 ) 纵轧
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至纵轧所需尺寸;
H、 对步骤 G所得复合管材进行纵轧, 从而得到用于加工轴承环的复合管环。
7、 根据权利要求 6所述的新型轴承环材料生产工艺, 其特征在于: 所述步骤 (3 ) 用热 挤压方式替换, 即 G、 对步骤 F所得铸态复合管坯进行机加工, 加工至热挤压所需尺寸;
H、 对步骤 G所得复合管材进行热挤压, 从而得到用于加工轴承环的复合管环。
8、 根据权利要求 6所述的新型轴承环材料生产工艺, 其特征在于: 所述步骤 (3 ) 用热 辗压方式替换, 即
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至热辗压所需尺寸;
H、 对步骤 G所得复合管材进行热辗压, 从而得到用于加工轴承环的复合管环。
9、 根据权利要求 6所述的新型轴承环材料生产工艺, 其特征在于: 所述步骤 (3 ) 用锻 造方式替换, 即
G、 对步骤 F所得铸态复合管坯进行机加工, 加工至锻造所需尺寸;
H、 对步骤 G所得复合管材进行锻造, 从而得到用于加工轴承环的复合管环。
10、 根据权利要求 6至 9所述之一的新型轴承环材料生产工艺, 其特征在于: 所述步骤 F中的热处理包括正火、 球化退火或扩散退火。
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