WO2012002417A1 - シート状プリプレグの製造方法および装置 - Google Patents
シート状プリプレグの製造方法および装置 Download PDFInfo
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- WO2012002417A1 WO2012002417A1 PCT/JP2011/064884 JP2011064884W WO2012002417A1 WO 2012002417 A1 WO2012002417 A1 WO 2012002417A1 JP 2011064884 W JP2011064884 W JP 2011064884W WO 2012002417 A1 WO2012002417 A1 WO 2012002417A1
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- reinforcing fiber
- sheet
- prepreg
- band
- fiber bundle
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
- B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
- B29B15/125—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by dipping
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/0872—Prepregs
Definitions
- the present invention relates to a method and apparatus for producing a sheet-like prepreg, and more particularly, to a method and apparatus for producing a sheet-like prepreg using continuous reinforcing fibers in which a resin is impregnated extremely uniformly.
- Sheet-like prepregs obtained by impregnating molten matrix resin into reinforcing fibers arranged in a sheet form and keeping the resin in a semi-cured state are widely used in various fields for reinforcing members and forming surfaces. Further, in order to obtain an excellent reinforcing effect, continuous fibers are often used as reinforcing fibers, and in particular, continuous reinforcing fibers are arranged in a strip (tape shape) in one direction, for example, and impregnated with resin. A thing is preferably used (for example, patent document 1).
- Patent Document 2 Technology to improve the impregnation of molten resin between long fibers by opening the roving when impregnating molten resin into rovings (with a circular or oval cross section) made of long fiber reinforcement (For example, Patent Document 2) and a technique (for example, Patent Document 3) that improves the impregnation property of molten resin between long fibers by sucking air between the long fibers constituting the roving. It has been.
- Patent Document 3 the roving is divided and guided into each die one by one.
- the resin impregnation property mainly depends on the viscosity of the molten resin, so that a high impregnation effect cannot be expected.
- the time for resin impregnation from all directions is a rule for roving with a circular or oval cross section. It is not necessary to improve the impregnation property, and it is considered that the air suction from the roving as described above contributes to the improvement of the impregnation property.
- the time for resin impregnation in the thickness direction is the rule of time until the resin impregnation is completed.
- not only simple fiber opening but also special measures for improving the resin impregnation property in the thickness direction are required.
- Patent Document 5 a technique using a pair of upper and lower uneven rollers (calendar rolls) is known (for example, Patent Document 5).
- this technology only discloses widening by the uneven roller, and does not disclose any requirement regarding narrowing after widening necessary for strictly controlling the sheet width, and sufficient content is disclosed. That's not true.
- JP 60-36136 A Japanese Patent Laying-Open No. 2005-29912 Japanese Patent Laid-Open No. 5-116142 Japanese Patent Laid-Open No. 7-040341 JP 2000-355629 A
- an object of the present invention is to provide a thermoplastic resin having a relatively high melt viscosity particularly for a sheet-like prepreg produced by impregnating a molten resin into a band-shaped reinforcing fiber bundle composed of a plurality of continuous reinforcing fibers. Even when resin is used, the resin can be uniformly and satisfactorily impregnated over the entire thickness, and the resin impregnation time can be greatly shortened. High-quality sheet-like prepregs are highly productive. It is providing the manufacturing method and apparatus of a sheet-like prepreg which can be manufactured.
- a method for producing a sheet-shaped prepreg according to the present invention includes: Introducing a fiber bundle introduced into a die to which a molten thermoplastic resin is supplied by arranging a plurality of layers in the thickness direction of the belt-like reinforcing fiber bundle while continuously running the belt-like reinforcing fiber bundle composed of a plurality of continuous reinforcing fibers Process, A fiber bundle thickness reduction step of widening each of the plurality of layers of belt-like reinforcing fiber bundles by opening and reducing the thickness of each belt-like reinforcing fiber bundle before and after introduction into the die.
- a resin impregnation step in which the molten thermoplastic resin is impregnated in the die in each band-like reinforcing fiber bundle having a reduced thickness
- a laminating step in which the molten thermoplastic resin is being impregnated or / and a plurality of band-shaped reinforcing fiber bundles impregnated with the molten thermoplastic resin are laminated in the die, and It consists of the method characterized by manufacturing a sheet-like prepreg as a whole shape.
- the band-like reinforcing fiber bundle made of continuous reinforcing fibers is at least one stage before and after introduction into the die, and air and ironing before introduction.
- a fiber-opening technique such as applying vibration
- a fiber-opening technique such as applying ironing after the introduction
- the fiber is spread and widened, thereby reducing the thickness of the band-like reinforcing fiber bundle. That is, even when a thermoplastic resin having a relatively high melt viscosity is used, the thickness is reduced to a thickness that can be sufficiently satisfactorily impregnated in a short time.
- a plurality of band-shaped reinforcing fiber bundles each having a reduced thickness are used, and the molten resin supplied in the die is arranged in a plurality of layers in the thickness direction.
- the strip reinforcing fiber bundles are impregnated respectively. Since each band-like reinforcing fiber bundle is formed into a sheet-like material having a small thickness, the molten resin is easily impregnated by the distance in the direction of the small thickness (impregnation distance) with respect to each band-like reinforcing fiber bundle. As a result, uniform impregnation over the entire desired thickness direction is performed within a short time.
- the molten resin is being uniformly impregnated or / and a plurality of individual band-like reinforcing fiber bundles that have been impregnated are laminated in the thickness direction within the same die so that the sheet has a target thickness as a whole.
- a prepreg is formed. Since this sheet-like prepreg may have a short resin impregnation time for each band-like reinforcing fiber bundle, it is produced in a short time just by adding up the resin impregnation time and the subsequent lamination time in the same die. Thus, productivity is greatly improved in terms of manufacturing time.
- the thickness of the band-like reinforcing fiber bundle can be easily made uniform, and in particular, the stage of opening and widening individual band-like reinforcing fiber bundles before resin impregnation. Then, since the thickness of the band-like reinforcing fiber bundle can be easily uniformed and the continuous reinforcing fiber can be easily dispersed uniformly, the sheet-like prepreg in which the resin-impregnated band-like reinforcing fiber bundle is laminated is also included in the prepreg. The dispersion of the reinforcing fibers is also kept in a uniform and good state. In addition, since the individual band-like reinforcing fiber bundles laminated as described above are uniformly impregnated with the molten resin, the obtained sheet-like prepreg has a high quality with uniform physical properties throughout.
- thermoplastic resin is used as the molten resin. That is, as described above, the present invention is more effective for a resin having a high melt viscosity than for a resin having a low melt viscosity, and thus is particularly effective when a thermoplastic resin is used.
- the type of thermoplastic resin to be used is not particularly limited.
- Polyamide (nylon 6, nylon 66, aromatic polyamide, etc.), polyolefin (polyethylene, polypropylene, etc.), polyester (polyethylene terephthalate, polybutylene terephthalate, etc.), polycarbonate, polyamideimide, Use polyphenylene sulfide, polyphenylene oxide, polysulfone, polyethersulfone, polyetheretherketone, polyetherketoneketone, polyketone, polyimide, polyetherimide, polystyrene, ABS, liquid crystal polyester, acrylonitrile-styrene copolymer, etc. it can. A mixture of these may also be used.
- polyphenylene sulfide, polyetheretherketone, polyetherketoneketone, polyetherimide, and aromatic polyamide increase the necessity of using continuous reinforcing fibers having an excellent reinforcing effect. I can say that.
- the type of the continuous reinforcing fiber is not particularly limited, and any reinforcing fiber such as carbon fiber, glass fiber or aramid fiber can be used, and a hybrid configuration using a combination of these can also be adopted.
- carbon fibers when it is desired to improve mechanical properties such as strength of the final molded product, it is preferable to use carbon fibers.
- carbon fibers it is more preferable to use a high-strength one that hardly generates fuzz in the fiber bundle thickness reduction step or the resin impregnation step. Specifically, it refers to those having a tensile strength of 4,500 MPa or more, and further 5,000 MPa or more.
- a sizing agent provided to the reinforcing fiber it is preferable to use a sizing agent having a heat loss at 300 ° C. of 5% or less. More preferably, the heat loss at 350 ° C. is 15% or less.
- Use of a sizing agent that is difficult to thermally decompose makes it difficult to generate fluff in the fiber bundle thickness reduction process and the resin impregnation process, and can minimize the generation of gas in the die, thereby maximizing the effects of the present invention. can do. This effect is particularly remarkable in heat-resistant thermoplastic resins whose processing temperature exceeds about 300 ° C.
- the thickness of the band-shaped reinforcing fiber bundle is measured at least one stage before and after the introduction of the plurality of layers of band-shaped reinforcing fiber bundles into the die. In the direction, it can be arranged in a plurality of stages with an interval between adjacent belt-like reinforcing fiber bundles.
- the molten resin is impregnated in a state where an appropriate gap is provided between the respective strip-shaped reinforcing fiber bundles arranged in a plurality of stages, for each band-shaped reinforcing fiber bundle, the molten resin is From both sides, the impregnation is more easily performed by the distance (impregnation distance) in the direction of the small thickness. Therefore, the desired uniform impregnation is completed in a shorter time, and the productivity is further improved.
- each of the plurality of layers of belt-like reinforcing fiber bundles can be formed by connecting smaller band-like reinforcing fiber bundles in the fiber bundle width direction.
- a method can be adopted. That is, a plurality of small band-shaped reinforcing fiber bundles are connected to each other until a predetermined width is obtained in the width direction (that is, until the width of the sheet-like prepreg to be manufactured is substantially reached), and a predetermined wide band-shaped reinforcing fiber bundle is obtained.
- the wide band-like reinforcing fiber bundle After forming into the form, the wide band-like reinforcing fiber bundle can be impregnated with resin. In this way, a wide sheet prepreg can be manufactured easily and efficiently.
- a band-shaped reinforcing fiber bundle having a smaller width is connected in the fiber bundle width direction to form a predetermined wide band-shaped reinforcing fiber bundle, in the fiber bundle introducing step to be introduced into the die, in the fiber bundle width direction.
- a space can be provided between adjacent small band-like reinforcing fiber bundles.
- the air brought into the die by the band reinforcing fiber bundle is passed through the gap to the die inlet and the after-mentioned removal.
- the air vent can be efficiently discharged out of the die, and the influence of air impairing resin impregnation can be minimized.
- a seal portion capable of reducing the pressure in the passage to a predetermined degree of vacuum is connected immediately upstream of the fiber bundle introducing step, and the plurality of layers of belt-like reinforcing fiber bundles are formed. It is preferable to have a deaeration step of increasing the degree of decompression inside the plurality of layers of belt-shaped reinforcing fiber bundles by passing each of the above through a passage that is decompressed to a predetermined degree of vacuum in the seal portion. In this way, the amount of air that the band-shaped reinforcing fiber bundle brings into the die can be minimized, and the performance of impregnating the band-shaped reinforcing fiber bundle with the molten resin in the die can be maintained well. become.
- each fiber bundle thickness reducing means can be easily disposed at a desired position without interfering with each other, and more with respect to each band-like reinforcing fiber bundle to be subjected to thickness reduction / widening. The desired operation is surely performed.
- the impregnation position or the impregnation completion position of the molten thermoplastic resin into each strip reinforcing fiber bundle can be sequentially shifted in the running direction of the strip reinforcing fiber bundle. This makes it possible to easily dispose each resin impregnation means at a desired position without interfering with each other, and more reliably to each band-like reinforcing fiber bundle to be subjected to resin impregnation. Operation is performed.
- the plurality of strip reinforcing fiber bundles impregnated with the molten thermoplastic resin or / and the melt thermoplastic resin impregnated are sequentially shifted in the running direction of the strip reinforcing fiber bundle. They can also be stacked in order.
- a plurality of fixing guides (for example, squeeze bars) arranged in the running direction of the belt-like reinforcing fiber bundles are used to sequentially open or / and melt thermoplastic resin.
- the impregnated belt-like reinforcing fiber bundle is sequentially laminated, and a passage opening for the belt-like reinforcing fiber bundle is provided in at least a part of the plurality of fixing guides used for opening or / and laminating, and at least at the passage opening.
- a part of the band-like reinforcing fiber bundles may be allowed to pass therethrough.
- a fixed guide that does not require a large space for opening or / and laminating in the die.
- a band-shaped reinforcing fiber bundle passage opening is provided in at least a part of the plurality of fixing guides, the opening or / and laminating some of the band-shaped reinforcing fiber bundles is opened.
- impregnation or completion of impregnation of the molten thermoplastic resin into each band-shaped reinforcing fiber bundle is performed at the same position in the running direction of the band-shaped reinforcing fiber bundle. It can also be done at. That is, the resin can be impregnated substantially simultaneously at the same traveling direction position with respect to the plural layers of belt-like reinforcing fiber bundles. In this way, it is possible to shorten the die length.
- the plurality of belt-shaped reinforcing fiber bundles that are being impregnated with the molten thermoplastic resin or / and impregnated with the molten thermoplastic resin are placed at predetermined positions in the running direction of the band-shaped reinforcing fiber bundle. At the same time.
- gas and / or resin in the die is discharged from a deaeration vent and / or a resin discharge vent provided in the die. It is preferable to do.
- a molten resin of a predetermined thermoplastic resin is supplied into the die, but in order to achieve smooth resin impregnation, the gas generated inside, the air brought in by the band-like reinforcing fiber bundle, etc. are vented. Is preferably discharged from Further, it is preferable to discharge deteriorated molten resin, fluff of a band-like reinforcing fiber bundle, or the like from the resin discharge vent.
- the prepreg laminated in the die and formed into a sheet shape as a whole may have a further impregnation step of pulling out from the die and further passing through a calender roll. it can. If calendering is performed with a calender roll, it is possible to add more resin by pressing between the rolls, it is possible to achieve a better resin impregnation state, and a small amount of thickness adjustment is possible. It becomes possible to increase the accuracy of the thickness of the prepreg in the manufacturing form.
- the calendar roll is composed of at least a first calendar roll and a second calendar roll, and at least the second calendar roll is a grooved roll and passes through the first calendar roll.
- the width of the sheet-shaped prepreg is adjusted so as to have a predetermined width in the width direction while narrowing the widened sheet prepreg by passing through a second calendar roll.
- the first calender roll it is slightly widened by pressing between the rolls and achieves a good resin-impregnated state.
- the first roll is a grooved roll having a groove with a predetermined width. Since the width of the sheet-shaped prepreg can be regulated so as to be a predetermined width by passing it through the calender roll No. 2, it is possible to increase the accuracy of the prepreg width of the final manufacturing form. .
- the sheet-shaped prepreg manufacturing apparatus is a sheet-shaped prepreg manufacturing apparatus that manufactures a sheet-shaped prepreg as an overall shape, A die to which a molten thermoplastic resin is supplied; A fiber bundle introduction means for introducing a plurality of continuous reinforcing fiber bundles made of a plurality of continuous reinforcing fibers into the die by arranging a plurality of layers in the thickness direction of the belt-like reinforcing fiber bundles, Fiber bundle thickness reducing means for expanding the width of each of the plurality of layers of band-like reinforcing fiber bundles by opening and reducing the thickness of each of the band-like reinforcing fiber bundles before and after introduction into the die.
- Resin impregnation means for impregnating the molten thermoplastic resin in the die in each band-shaped reinforcing fiber bundle with reduced thickness;
- Laminating means that is being impregnated with the molten thermoplastic resin or / and laminating a plurality of belt-shaped reinforcing fiber bundles impregnated with the molten thermoplastic resin in the die; It consists of what is characterized by having.
- the kind of the thermoplastic resin to be used is not particularly limited, and the same thermoplastic resin as described above can be used.
- the type of the continuous reinforcing fiber is not particularly limited, and the same reinforcing fiber as described above can be used.
- the carbon fiber is used. Is preferably used. It is more preferable to use the same carbon fiber and sizing agent as described above.
- the plurality of layers of belt-like reinforcing fiber bundles are arranged in the thickness direction of the belt-like reinforcing fiber bundles at least one position before and after introduction into the die. Further, it is possible to adopt a configuration having means for arranging in a plurality of stages at intervals between adjacent belt-like reinforcing fiber bundles. Further, each of the plurality of layers of belt-like reinforcing fiber bundles can be formed by connecting smaller band-like reinforcing fiber bundles in the fiber bundle width direction.
- a band-shaped reinforcing fiber bundle having a smaller width is connected in the fiber bundle width direction to form a predetermined wide band-shaped reinforcing fiber bundle
- an interval can be provided between adjacent small band-like reinforcing fiber bundles.
- a seal part capable of reducing the pressure inside the passage to a predetermined degree of vacuum is connected immediately upstream of the fiber bundle introducing means, and each of the plurality of layers of belt-like reinforcing fiber bundles is reduced to a predetermined degree of vacuum of the seal part. It is also possible to adopt a configuration having deaeration means for increasing the degree of decompression inside a plurality of layers of band-like reinforcing fiber bundles by passing through the passage.
- the position at which the adjacent band-like reinforcing fiber bundles of the plurality of layers of band-like reinforcing fiber bundles are widened by opening is belt-like reinforcing. It can be set as the structure shifted mutually with respect to the running direction of a fiber bundle.
- the impregnation position or impregnation completion position of the molten thermoplastic resin into each band-like reinforcing fiber bundle may be sequentially shifted in the running direction of the band-like reinforcing fiber bundle.
- the laminating means is in a position where the molten thermoplastic resin is being impregnated or / and the plurality of strip reinforcing fiber bundles impregnated with the molten thermoplastic resin are sequentially shifted in the running direction of the strip reinforcing fiber bundle. It is possible to adopt a configuration comprising means for sequentially stacking.
- a fixed guide for example, a squeeze bar
- a fixed guide used to sequentially open the band-like reinforcing fiber bundles and / or to laminate the band-like reinforcing fiber bundles impregnated with the molten thermoplastic resin in the die
- the resin impregnation means may be configured by means for performing impregnation or impregnation completion of the molten thermoplastic resin into each strip reinforcing fiber bundle at the same position in the running direction of the strip reinforcing fiber bundle. it can.
- the laminating means a plurality of belt-shaped reinforcing fiber bundles impregnated with molten thermoplastic resin or / and impregnated with molten thermoplastic resin are placed at predetermined positions in the running direction of the band-shaped reinforcing fiber bundle. It is possible to have a configuration comprising means for simultaneously laminating.
- the die may be provided with a deaeration vent and / or a resin discharge vent.
- the calender roll is at least a first calender roll that widens the prepreg formed in a sheet shape to have a predetermined width in the width direction, and a widened sheet that is arranged downstream of the first calender roll.
- the prepreg can be configured to include a grooved second calender roll that restricts the prepreg to a predetermined width in the width direction while narrowing.
- thermoplastic sheet-like prepreg in which a resin is uniformly and satisfactorily impregnated throughout a predetermined thickness and the reinforcing fibers are also uniformly dispersed. Moreover, the resin impregnation time can be greatly shortened, and this high-quality sheet-like prepreg can be manufactured with high productivity.
- FIG. 1 is a schematic configuration diagram showing a sheet-like prepreg manufacturing method and apparatus according to an embodiment of the present invention. It is a schematic sectional drawing of the band-shaped wrinkle reinforcement fiber bundle which shows an example of the fiber spread widening in the manufacturing method of the sheet-like prepreg of this invention. It is the schematic side view (A) and schematic plan view (B) which show an example of the fiber opening in the fiber opening machine of the apparatus of FIG. It is a schematic sectional drawing of the die
- FIG. 1 shows a method and apparatus for producing a sheet-like prepreg according to an embodiment of the present invention
- 100 shows the whole apparatus for producing a sheet-like prepreg.
- a fiber bundle introduction process fiber bundle introduction means
- a fiber bundle thickness reduction process fiber bundle thickness reduction means
- deaeration process deaeration means
- a resin impregnation process resin impregnation process
- a laminating step laminating means
- a further impregnation step additional impregnation means 5
- the spreader 12 may have an oven and may be heated, or a mechanism that directly heats the spread roll 13 may be used.
- each of the belt-shaped reinforcing fiber bundles 10 that has been introduced is opened by a plurality of fiber-opening rolls 13 or the like (or a bar for fiber-opening), and the band-shaped reinforcing fiber bundle is widened by the opening. The thickness of 10 is reduced.
- the spread widening is performed in a form as shown in FIG. 2, for example, and the initial thickness T of the band-like reinforcing fiber bundle 10 composed of the continuous reinforcing fibers 30 is reduced to the thickness t by the spread widening, so that the thin amplification band-like reinforcing fiber is thin. It is in the form of a bundle 31.
- the width of the sheet-like prepreg to be finally produced is wider than the width of the amplified band-like reinforcing fiber bundle 31, at the stage of the band-like reinforcing fiber bundle 10, or at the stage of the band-like reinforcing fiber bundle 31, A necessary number of strip-shaped reinforcing fiber bundles can be connected in the width direction. For example, as shown in FIG.
- the plurality of strip-shaped reinforcing fiber bundles 10 that have been run side by side are widened by the spread rolls 13 at different positions shifted in the running direction of the strip-shaped reinforcing fiber bundle 10, and the plurality of strip-shaped strips that have been widened.
- the reinforcing fiber bundles 10 are connected in the width direction to form a wider amplification band-like reinforcing fiber bundle 31 having a predetermined width.
- illustration is abbreviate
- the band-like reinforcing fiber bundle 31 whose thickness is reduced by the spread spread is subjected to the deaeration step 3 as shown in FIG. 1, and more specifically, via the vacuum sealing means 15 as the deaeration means. And introduced into the die 19 for resin impregnation.
- the vacuum sealing means 15 for example, a passage 16 that is blocked as much as possible from the outside and through which the belt-like reinforcing fiber bundle 31 can pass is formed, and a vacuum pump (in the illustrated example, a two-stage vacuum pump) is formed from inside the formed passage 16. 17 and 18), air is sucked.
- the molten resin and the belt-shaped reinforcing fiber bundle are indirectly long. That is, in the die 19 for resin impregnation, it is preferable that air or gas is filled with molten resin without mixing as much as possible.
- the strip-shaped reinforcing fiber bundle 31 brings a large amount of air into the die, the molten resin This is not preferable because the direct contact between the reinforced fiber bundle and the band-like reinforcing fiber bundle is hindered.
- the amount of air brought in increases as the production rate increases, making it more difficult to impregnate the resin. By such degassing, the air brought into the die by the band-like reinforcing fiber bundle 31 can be suppressed to the minimum, and the resin impregnation becomes easy and the effects of the present invention can be maximized.
- the die 19 is supplied with a molten resin of a predetermined thermoplastic resin from an extruder 20 connected to the die 19, and the gas generated inside, the air brought in by the band-like reinforcing fiber bundle 31, etc. are discharged from the deaeration vent 21 to a vacuum pump. It is preferable to be discharged by 22 or the like. It is also a preferable aspect to discharge the deteriorated molten resin, the fluff of the band-like reinforcing fiber bundle, or the like from the resin discharge vent 27.
- a plurality of strip-shaped reinforcing fiber bundles 31 whose thickness is reduced by the above-described spread widening are in a plurality of stages in the thickness direction of the strip-shaped reinforcing fiber bundle 31 (in the illustrated example, four stages).
- the molten resin 23 is introduced into the die 19 to which the molten resin 23 is supplied in a state where it is arranged and has an appropriate interval between the adjacent band-like reinforcing fiber bundles 31.
- guide bars 32 for guiding the respective band-like reinforcing fiber bundles 31 are arranged at a position immediately after introduction into the die 19 in order to maintain the above-described multi-stage state with the interval.
- the belt-like reinforcing fiber bundles 31 that have passed through the guide bar 32 are approached so as to be laminated with each other, but between the adjacent belt-like reinforcing fiber bundles 31 until they are laminated from the position immediately after introduction into the die 19. Since the gaps are maintained, the belt-like reinforcing fiber bundles 31 having a reduced thickness are impregnated with the molten resin 23 from both sides.
- a plurality of strip-like reinforcing fiber bundles 31 are introduced from one entrance of the die 19.
- a plurality of strip-shaped reinforcing fiber bundles may be introduced into the die from the entrances at a plurality of locations of the die.
- Such an embodiment can be said to be one of the preferred embodiments because it can be introduced into the die in a state where an appropriate interval is provided between the adjacent belt-like reinforcing fiber bundles 31 more reliably.
- Each band-like reinforcing fiber bundle 31 impregnated with the molten resin 23 is laminated in the same die 19.
- This lamination can be performed by any appropriate technique.
- a plurality of fixed guides 33 a squeeze bars having a cylindrical surface are provided in the traveling direction of the belt-like reinforcing fiber bundle 31.
- the outer surface is alternately arranged in contact with the belt-like reinforcing fiber bundles 31 at opposite positions, and a plurality of stacked belt-like reinforcing fiber bundles 31 are sequentially passed through the fixed guides 33a.
- the fixed guide having such a circular surface or a semicircular surface exemplified below is being impregnated with the molten resin 23 or passed while contacting the band-shaped reinforcing fiber bundle 31 impregnated with the molten resin 23.
- a gap narrowed like a wedge is formed between the band-like reinforcing fiber bundle 31 immediately before contact and the fixed guide surface, and in this gap, the resin pressure is gradually increased toward the band-like reinforcing fiber bundle 31 side. Therefore, the resin impregnation into the belt-like reinforcing fiber bundle 31 is promoted or supplemented. That is, on the fixed guide, the resin impregnation can be promoted or replenished together with the lamination as described above.
- the fiber bundle thickness reduction by the opening and widening of the band-shaped reinforcing fiber bundle may be performed at least one step before the introduction to the die and after the introduction. It is only necessary to impregnate the resin and laminate the resin-impregnated band-like reinforcing fiber bundle 31.
- a plurality of strip-shaped reinforcing fiber bundles 31 whose thickness has been reduced by the spread spread are in a state of a plurality of layers in the thickness direction of the strip-shaped reinforcing fiber bundle 31 (although it appears in two stages in the illustrated state).
- Each stage is once divided in the die 19 and laminated again, so that a total of four stages) is introduced into the die 19 to which the molten resin 23 is supplied.
- the fixed guides 33 b squeeze bars having a semicircular surface are arranged in the running direction of the belt-shaped reinforcing fiber bundle 31 so that the outer surfaces of the semicircular fibers are alternately directed in opposite directions.
- the fixed guide may have a cylindrical surface as shown in FIG. 4 or a semicircular surface as shown in FIG. In order to minimize deterioration of the resin, it is preferable to minimize the amount of molten resin present in the die 19. From this point of view, it can be said that it is preferable to use a fixed guide having a semicircular surface that does not require a space and can minimize the volume of the die 19.
- the belt-like reinforcing fiber bundle 31 of each layer is impregnated with resin, the resin impregnation is promoted and supplemented, and the lamination of the band-like reinforcing fiber bundle 31 impregnated with the resin is performed. It is preferable that the belt-shaped reinforcing fiber bundle 31 is sequentially moved in the traveling direction.
- a plurality of fixed guides 33b are arranged in the running direction of the band-shaped reinforcing fiber bundles 31 and the band-shaped reinforcing fiber bundles 31 to be actuated in the arranged fixed guides 33b are partly formed into a band-shaped reinforcing fiber bundle 31.
- a certain fixed guide 33b is required to operate only for a specific part of the band-shaped reinforcing fiber bundles 31 and to simply pass through the remaining band-shaped reinforcing fiber bundles 31.
- a passage opening 35 through which a part of the band-like reinforcing fiber bundle 31 can pass is provided in the fixed guide 33 b.
- a passage opening 35 as shown in FIG. 7 may be provided for the columnar fixed guide 33a as in the example shown in FIG.
- the laminated body of the band-shaped reinforcing fiber bundles 31 impregnated with the molten resin as described above already has a predetermined prepreg configuration in the state of being pulled out from the die 19, but in this embodiment, the additional impregnation step 5 Further, calendar processing is performed by a calendar roll 24 in which a plurality of rolls are arranged. Pressing from both sides by this calendering process enables more reliable and good resin impregnation, and fine adjustment of the final thickness and final width of the sheet-like prepreg 34 as a product by adjusting the press pressure in the calendering process. In addition, it is possible to impart a predetermined uneven shape to the surface of the sheet-like prepreg 34. In addition, this uneven
- the second calender roll 25b (having a groove of a predetermined width) is used. It is preferable that the sheet-shaped prepreg is narrowed by passing it and is regulated so as to have a predetermined width in the width direction. By narrowing after widening as described above, the target width can be accurately and stably controlled. Moreover, the composite material by the obtained sheet-like prepreg 34 has the effect that it is excellent in the quality stability of mechanical characteristics (the variation is small).
- the above-described series of belt-shaped reinforcing fiber bundles travel is performed by the upper and lower belts being circulated by the pulling device 26 disposed on the downstream side of the calendar roll 24.
- a sheet-like prepreg 34 as a product is wound up as a prepreg roll 29 by a winder 28.
- the thickness of each of the plurality of belt-shaped reinforcing fiber bundles 10 used for manufacturing the sheet-shaped prepreg 34 as a final product is reduced by the spread width. Then, the molten resin 23 is impregnated from both sides in the die 19 into the individual band-like reinforcing fiber bundles 31 whose thickness is reduced. Therefore, even when a relatively high melt viscosity resin such as a thermoplastic resin is used, the individual band-like reinforcing fiber bundles 31 are sufficiently satisfactorily impregnated in a short time.
- the resin-impregnated belt-like reinforcing fiber bundles 31 each sufficiently satisfactorily impregnated with the molten resin are laminated in the same die 19 to form a desired sheet-like prepreg 34. It is kept in a good resin impregnation state.
- the sheet-like prepreg 34 as the final product has a uniform thickness.
- the dispersion state of the reinforcing fibers 30 is also maintained in an excellent and uniform state. Therefore, the sheet-like prepreg 34 is ensured in a uniform dispersed state of the reinforcing fibers 30 and a good resin impregnated state throughout, and desirable physical properties are achieved throughout.
- the belt-like reinforcing fiber bundles 31 are impregnated with the molten resin 23 in a state in which the belt-like reinforcing fiber bundles 31 are arranged in a plurality of stages in the thickness direction and are spaced from each other. Then, in the case of the individual band-like reinforcing fiber bundles 31, the resin impregnation is performed by a distance in the direction of a small thickness of the reinforcing fiber bundle 31 from the both sides (impregnation distance). Even in this case, the uniform impregnation throughout the thickness direction can be easily completed within a short time.
- the difficulty of impregnating the reinforcing fiber bundle with such a high-viscosity molten resin can be explained by using, for example, a simple model based on Darcy's law (Darcy's law) represented by FIG.
- the time required for the resin impregnation is proportional to the melt viscosity ⁇ , and the higher the melt viscosity ⁇ , the more time is required (that is, the impregnation becomes difficult) and the proportional to the square of the impregnation distance X. Since this impregnation distance corresponds to the thickness of each band-shaped reinforcing fiber bundle 31 in the present invention, in the present invention, the band-shaped reinforcing fiber bundle 10 is changed to a band-shaped reinforcing fiber bundle 31 whose thickness is reduced by the spread width. It is understood how this can greatly contribute to shortening the impregnation time.
- the resin impregnation time for each band-like reinforcing fiber bundle 31 may be short, and a desired sheet-like prepreg can be obtained simply by laminating the band-like reinforcing fiber bundle 31 impregnated with resin in the same die 19. Therefore, the manufacturing time of the sheet-like prepreg is greatly shortened, and the productivity is greatly improved.
- the method and apparatus for producing a sheet-like prepreg according to the present invention can be applied to the production of any sheet-like prepreg using continuous reinforcing fibers and a thermoplastic resin.
- Sheet-like prepregs obtained from such production methods and apparatuses are preferably used for transportation equipment such as automobiles, airplanes, ships, etc., leisure / sports members, pressure vessels, oilfield drilling, civil engineering construction members / quasi-structure members, etc. Can do.
- Fiber bundle introduction process (fiber bundle introduction means) 2 Fiber bundle thickness reduction process (fiber bundle thickness reduction means) 3 Deaeration process (deaeration means) 4 Resin impregnation process (resin impregnation means) 5 Additional impregnation process (additional impregnation means) 6 Lamination process (lamination means) DESCRIPTION OF SYMBOLS 10 Band-shaped reinforcing fiber bundle 11 Creel 12 Opening machine 13 Opening roll 15 Vacuum sealing means 16 Passage 17, 18, 22 Vacuum pump 19 Die 20 Extruder 21 Deaeration vent 23 Molten resin 24 Calendar roll 25a First calendar roll 25b First 2 calendar rolls 26 pulling device 27 resin discharge vent 28 winder 29 prepreg roll 30 continuous reinforcing fiber 31 amplifying belt-like reinforcing fiber bundle 32 guide bar 33a, 33b fixed guide 34 sheet-like prepreg 35 passage port 100 sheet-like prepreg manufacturing apparatus
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Abstract
Description
複数の連続強化繊維からなる帯状強化繊維束を、連続的に走行させつつ、該帯状強化繊維束の厚み方向に複数層配置して溶融熱可塑性樹脂が供給されたダイ内に導入する繊維束導入工程と、
前記複数層の帯状強化繊維束のそれぞれを、前記ダイ内への導入前および導入後の少なくとも一方の段階で、開繊により拡幅して各帯状強化繊維束の厚みを縮小する繊維束厚み縮小工程と、
前記厚みが縮小された各帯状強化繊維束内に、前記ダイ内で前記溶融熱可塑性樹脂を含浸させる樹脂含浸工程と、
前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を前記ダイ内で積層する積層工程と、を有し、
全体形状としてシート状のプリプレグを製造することを特徴とする方法からなる。
溶融熱可塑性樹脂が供給されるダイと、
複数の連続強化繊維からなる帯状強化繊維束を、連続的に走行させつつ、該帯状強化繊維束の厚み方向に複数層配置して前記ダイ内に導入する繊維束導入手段と、
前記複数層の帯状強化繊維束のそれぞれを、前記ダイ内への導入前および導入後の少なくとも一方の段階で、開繊により拡幅して各帯状強化繊維束の厚みを縮小する繊維束厚み縮小手段と、
前記厚みが縮小された各帯状強化繊維束内に、前記ダイ内で前記溶融熱可塑性樹脂を含浸させる樹脂含浸手段と、
前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を前記ダイ内で積層する積層手段と、
を有することを特徴とするものからなる。
図1は、本発明の一実施態様に係るシート状プリプレグの製造方法および装置を示しており、100は、シート状プリプレグの製造装置全体を示している。本実施態様では、繊維束導入工程(繊維束導入手段)1、繊維束厚み縮小工程(繊維束厚み縮小手段)2、脱気工程(脱気手段)3、樹脂含浸工程(樹脂含浸手段)4、積層工程(積層手段)6、追含浸工程(追含浸手段)5を有している。
2 繊維束厚み縮小工程(繊維束厚み縮小手段)
3 脱気工程(脱気手段)
4 樹脂含浸工程(樹脂含浸手段)
5 追含浸工程(追含浸手段)
6 積層工程(積層手段)
10 帯状強化繊維束
11 クリール
12 開繊機
13 開繊ロール
15 真空シール手段
16 通路
17、18、22 真空ポンプ
19 ダイ
20 押出機
21 脱気ベント
23 溶融樹脂
24 カレンダーロール
25a 第1のカレンダーロール
25b 第2のカレンダーロール
26 牽引装置
27 樹脂排出ベント
28 巻取機
29 プリプレグロール
30 連続強化繊維
31 増幅帯状強化繊維束
32 ガイドバー
33a、33b 固定ガイド
34 シート状プリプレグ
35 通過口
100 シート状プリプレグの製造装置
Claims (28)
- 複数の連続強化繊維からなる帯状強化繊維束を、連続的に走行させつつ、該帯状強化繊維束の厚み方向に複数層配置して溶融熱可塑性樹脂が供給されたダイ内に導入する繊維束導入工程と、
前記複数層の帯状強化繊維束のそれぞれを、前記ダイ内への導入前および導入後の少なくとも一方の段階で、開繊により拡幅して各帯状強化繊維束の厚みを縮小する繊維束厚み縮小工程と、
前記厚みが縮小された各帯状強化繊維束内に、前記ダイ内で前記溶融熱可塑性樹脂を含浸させる樹脂含浸工程と、
前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を前記ダイ内で積層する積層工程と、を有し、
全体形状としてシート状のプリプレグを製造することを特徴とする、シート状プリプレグの製造方法。 - 前記複数層の帯状強化繊維束を、前記ダイ内への導入前および導入後の少なくとも一方の段階で、該帯状強化繊維束の厚み方向に、隣接帯状強化繊維束間に間隔をもたせた複数段に配置する、請求項1に記載のシート状プリプレグの製造方法。
- 前記複数層の帯状強化繊維束のそれぞれを、より小幅の帯状強化繊維束を繊維束幅方向に連接することにより形成する、請求項1または2に記載のシート状プリプレグの製造方法。
- 前記繊維束導入工程の直上流に、通路内を所定の真空度に減圧可能なシール部を接続し、前記複数層の帯状強化繊維束のそれぞれを、前記シール部の所定の真空度に減圧された通路内を通過させることにより前記複数層の帯状強化繊維束内部の減圧度を高める脱気工程を有する、請求項1~3のいずれかに記載のシート状プリプレグの製造方法。
- 前記繊維束厚み縮小工程において、前記複数層の帯状強化繊維束のうち互いに隣接する帯状強化繊維束を開繊により拡幅する位置を、帯状強化繊維束の走行方向に互いにずらす、請求項1~4のいずれかに記載のシート状プリプレグの製造方法。
- 前記樹脂含浸工程において、各帯状強化繊維束内への前記溶融熱可塑性樹脂の含浸位置または含浸完了位置を、帯状強化繊維束の走行方向に順次ずらす、請求項1~5のいずれかに記載のシート状プリプレグの製造方法。
- 前記積層工程において、前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を、帯状強化繊維束の走行方向に順次ずらした位置にて順に積層する、請求項6に記載のシート状プリプレグの製造方法。
- 前記ダイ内において、帯状強化繊維束の走行方向に配列された複数の固定ガイドを用いて、各帯状強化繊維束を順次開繊または/および溶融熱可塑性樹脂が含浸された帯状強化繊維束を順次積層し、該開繊または/および積層に用いる複数の固定ガイドの少なくとも一部の固定ガイド中に帯状強化繊維束の通過口を設けて、該通過口に少なくとも一部の帯状強化繊維束を通過させる、請求項1~7のいずれかに記載のシート状プリプレグの製造方法。
- 前記樹脂含浸工程において、各帯状強化繊維束内への前記溶融熱可塑性樹脂の含浸または含浸完了を、帯状強化繊維束の走行方向における同じ位置にて行う、請求項1~5のいずれかに記載のシート状プリプレグの製造方法。
- 前記積層工程において、前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を、帯状強化繊維束の走行方向における所定の位置にて同時に積層する、請求項9に記載のシート状プリプレグの製造方法。
- 前記樹脂含浸工程または積層工程において、前記ダイに設けられた脱気ベントおよび/または樹脂排出ベントから、ダイ内のガスおよび/または樹脂を排出する、請求項1~10のいずれかに記載のシート状プリプレグの製造方法。
- 前記ダイ内で積層され全体としてシート形状に形成されたプリプレグを、ダイから引き抜いた後、さらにカレンダーロールに通す追含浸工程を有する、請求項1~11のいずれかに記載のシート状プリプレグの製造方法。
- 前記カレンダーロールが少なくとも第1のカレンダーロールと第2のカレンダーロールとからなり、少なくとも第2のカレンダーロールは溝つきロールであり、第1のカレンダーロールに通すことにより、シート状に形成されたプリプレグを拡幅した後、第2のカレンダーロールに通すことにより、拡幅されたシート状プリプレグを狭幅しながら幅方向に所定幅となるようにシート状プリプレグの幅を規制する、請求項12に記載のシート状プリプレグの製造方法。
- 前記連続強化繊維が炭素繊維を含む、請求項1~13のいずれかに記載のシート状プリプレグの製造方法。
- 全体形状としてシート状のプリプレグを製造するシート状プリプレグの製造装置であって、
溶融熱可塑性樹脂が供給されるダイと、
複数の連続強化繊維からなる帯状強化繊維束を、連続的に走行させつつ、該帯状強化繊維束の厚み方向に複数層配置して前記ダイ内に導入する繊維束導入手段と、
前記複数層の帯状強化繊維束のそれぞれを、前記ダイ内への導入前および導入後の少なくとも一方の段階で、開繊により拡幅して各帯状強化繊維束の厚みを縮小する繊維束厚み縮小手段と、
前記厚みが縮小された各帯状強化繊維束内に、前記ダイ内で前記溶融熱可塑性樹脂を含浸させる樹脂含浸手段と、
前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を前記ダイ内で積層する積層手段と、
を有することを特徴とする、シート状プリプレグの製造装置。 - 前記複数層の帯状強化繊維束を、前記ダイ内への導入前および導入後の少なくとも一方の位置で、該帯状強化繊維束の厚み方向に、隣接帯状強化繊維束間に間隔をもたせた複数段に配置する手段を有する、請求項15に記載のシート状プリプレグの製造装置。
- 前記複数層の帯状強化繊維束のそれぞれが、より小幅の帯状強化繊維束を繊維束幅方向に連接することにより形成されている、請求項15または16に記載のシート状プリプレグの製造装置。
- 前記繊維束導入手段の直上流に、通路内を所定の真空度に減圧可能なシール部を接続し、前記複数層の帯状強化繊維束のそれぞれを、前記シール部の所定の真空度に減圧された通路内を通過させることにより前記複数層の帯状強化繊維束内部の減圧度を高める脱気手段を有する、請求項15~17のいずれかに記載のシート状プリプレグの製造装置。
- 前記繊維束厚み縮小手段において、前記複数層の帯状強化繊維束のうち互いに隣接する帯状強化繊維束を開繊により拡幅する位置が、帯状強化繊維束の走行方向に互いにずらされている、請求項15~18のいずれかに記載のシート状プリプレグの製造装置。
- 前記樹脂含浸手段において、各帯状強化繊維束内への前記溶融熱可塑性樹脂の含浸位置または含浸完了位置が、帯状強化繊維束の走行方向に順次ずらされている、請求項15~19のいずれかに記載のシート状プリプレグの製造装置。
- 前記積層手段が、前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を、帯状強化繊維束の走行方向に順次ずらした位置にて順に積層する手段からなる、請求項20に記載のシート状プリプレグの製造装置。
- 前記ダイ内に、各帯状強化繊維束を順次開繊または/および溶融熱可塑性樹脂が含浸された帯状強化繊維束を順次積層するのに用いられる固定ガイドが帯状強化繊維束の走行方向に複数配列されており、該複数の固定ガイドの少なくとも一部の固定ガイド中に、少なくとも一部の帯状強化繊維束を通過させることが可能な通過口が設けられている、請求項15~21のいずれかに記載のシート状プリプレグの製造装置。
- 前記樹脂含浸手段が、各帯状強化繊維束内への前記溶融熱可塑性樹脂の含浸または含浸完了を、帯状強化繊維束の走行方向における同じ位置にて行う手段からなる、請求項15~19のいずれかに記載のシート状プリプレグの製造装置。
- 前記積層手段が、前記溶融熱可塑性樹脂が含浸されつつある、または/および、前記溶融熱可塑性樹脂が含浸された複数の帯状強化繊維束を、帯状強化繊維束の走行方向における所定の位置にて同時に積層する手段からなる、請求項23に記載のシート状プリプレグの製造装置。
- 前記ダイに、脱気ベントおよび/または樹脂排出ベントが装着されている、請求項15~24のいずれかに記載のシート状プリプレグの製造装置。
- 前記ダイの下流に配置され、前記ダイ内で積層され全体としてシート状に形成されダイから引き抜かれたプリプレグに対しカレンダー処理を施すカレンダーロールを備えた追含浸手段を有する、請求項15~25のいずれかに記載のシート状プリプレグの製造装置。
- 前記カレンダーロールは、少なくとも、シート状に形成されたプリプレグを幅方向に所定幅となるように拡幅する第1のカレンダーロールと、該第1のカレンダーロールの下流に配置され、拡幅したシート状プリプレグを狭幅しながら幅方向に所定幅となるように規制する、溝つきの第2のカレンダーロールとを備えている、請求項26に記載のシート状プリプレグの製造装置。
- 前記連続強化繊維が炭素繊維を含む、請求項15~27のいずれかに記載のシート状プリプレグの製造装置。
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CN201180029051.1A CN102958657B (zh) | 2010-06-30 | 2011-06-29 | 片状预浸料的制造方法和装置 |
KR1020127033832A KR101787143B1 (ko) | 2010-06-30 | 2011-06-29 | 시트상 프리프레그의 제조 방법 및 장치 |
US13/806,356 US9238336B2 (en) | 2010-06-30 | 2011-06-29 | Process and apparatus for producing sheet-shaped prepreg |
JP2011529388A JP5626660B2 (ja) | 2010-06-30 | 2011-06-29 | シート状プリプレグの製造方法および装置 |
EP11800879.6A EP2589475B1 (en) | 2010-06-30 | 2011-06-29 | Process and apparatus for producing sheet-shaped prepreg |
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JPWO2012002417A1 (ja) | 2013-08-29 |
JP5626660B2 (ja) | 2014-11-19 |
KR20130091255A (ko) | 2013-08-16 |
EP2589475A1 (en) | 2013-05-08 |
CN102958657A (zh) | 2013-03-06 |
EP2589475A4 (en) | 2017-11-01 |
KR101787143B1 (ko) | 2017-10-18 |
CN102958657B (zh) | 2015-08-12 |
US20130106014A1 (en) | 2013-05-02 |
US9238336B2 (en) | 2016-01-19 |
EP2589475B1 (en) | 2020-06-17 |
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