WO2011137652A1 - Nouvelle eau de colle et utilisation de cette dernière - Google Patents

Nouvelle eau de colle et utilisation de cette dernière Download PDF

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Publication number
WO2011137652A1
WO2011137652A1 PCT/CN2010/080065 CN2010080065W WO2011137652A1 WO 2011137652 A1 WO2011137652 A1 WO 2011137652A1 CN 2010080065 W CN2010080065 W CN 2010080065W WO 2011137652 A1 WO2011137652 A1 WO 2011137652A1
Authority
WO
WIPO (PCT)
Prior art keywords
glue
agent
hardener
fishing
novel
Prior art date
Application number
PCT/CN2010/080065
Other languages
English (en)
Chinese (zh)
Inventor
张顺
方平章
陈彦良
Original Assignee
尚盟运动用品(惠阳)有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 尚盟运动用品(惠阳)有限公司 filed Critical 尚盟运动用品(惠阳)有限公司
Publication of WO2011137652A1 publication Critical patent/WO2011137652A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene

Definitions

  • the invention relates to the field of water sports articles manufacturing, in particular to a glue for water sports articles and the application of the glue on fishing clothes.
  • Fishing clothes are clothes that need to be worn when fishing.
  • Fishing suits are required to have good waterproof performance. Therefore, during the processing of fishing suits, the workmanship requirements for sewing seams and the like are very strict, and the hot-melt strips must be attached and reinforced at the finishing section of the seam.
  • the traditional hot-melt strips have poor waterproof performance. After soaking in water, the anti-oxidation ability is weakened, which eventually leads to loss of viscosity, which causes water leakage at the seams of the fishing suits and shortens the service life of the fishing suits.
  • Some hot-melt strips are prone to hardening and delamination after bonding, which makes the fishing suit elastically restricted, resulting in discomfort. Serious delamination can also cause the strip to peel off and cause water leakage.
  • the present invention provides a new type of glue which is not easy to be layered, has good paintability, good toughness, high bonding strength, water resistance and corrosion resistance and is used for fishing clothes.
  • the glue comprises the following ingredients (in percentage by weight):
  • the novel glue (in percentage by weight) comprises the following components: 20% neoprene, 6% active agent 4% anti-aging agent, 10% softening oil, 30% xylene solvent, 20% elastic rubber, 5% vulcanizing agent and 5% hardener.
  • the vulcanizing agent is diluted liquid sulfur; the hardening agent is a sulfur-based substance; and the active agent includes zinc oxygen powder and magnesium oxide.
  • the preparation method of the novel glue is as follows:
  • the preferred solution for the application is to first apply a thin layer of glue to the base; after air drying, apply a thicker layer of glue to reinforce.
  • the glue prepared by the formula and method of the invention has high bonding strength, good toughness, good brushing property, and has the characteristics of being difficult to be layered, water and corrosion resistant, and is suitable for water sports articles, especially fishing clothes;
  • the waterproof property is poor, and the phenomenon of hardening and delamination is easy to occur.
  • the invention adopts a new type of glue bonding, and the bonding is more firm and elastic, thereby greatly improving the fishing clothes.
  • the service life, and the surface of the bonding surface is smooth and comfortable to wear; on the other hand, the replacement of the traditional hot-melt tape bonding method by the new glue can simplify the bonding process while reducing the material and labor costs.
  • the new glue includes the following components (in percentage by weight): neoprene 15-25% Active agent 6-10%, anti-aging agent 3-5%, softening oil 10-12%, xylene solvent 25-30%, elastic glue 15-20%, vulcanizing agent 4-5%, hardener 4-5%.
  • the glue of the invention is mainly composed of neoprene rubber.
  • Neoprene has high crystallinity, good elasticity and weather resistance, and has the advantage of being resistant to hydrolysis, so it can maintain good performance even when immersed in water for a long time.
  • Neoprene is an elastomer made by emulsion polymerization of monomeric chloroprene, referred to as CR glue, and its degree of crystallization has an important influence on the processing and application of rubber.
  • the compounding agent in the present invention includes a softening oil, an antioxidant, zinc oxide powder, and magnesium oxide.
  • the mixing process requires that the various compounding agents be completely and evenly dispersed in the raw rubber to ensure uniform performance of the rubber compound, that is, any part of the rubber compound contains the same amount of components, so as to avoid the performance of the rubber compound due to local concentration of the compounding agent. , frosting or scorching.
  • the softening oil can soften and plasticize the rubber and change the elasticity and toughness of the rubber.
  • the raw rubber swells in the softening oil, and the active agent can promote the dispersion of the powder during the kneading and stabilize the dispersion system.
  • zinc oxide powder and magnesium oxide can be used as the active agent, and aromatic hydrocarbon oil can be used as the softening oil.
  • Zinc oxide powder and magnesium oxide act as active agents, which can promote the dispersion of the powder during the mixing and stabilize the dispersion system.
  • the new glue is used to bond the seams of water sportswear, especially fishing clothes, because people use fishing clothes for water sports, and when they wear other water sportswear, the amount of activity is large, the range of motion is large, and the sewing is performed. The wear is also large, so the traditional fishing suits are made of wear-resistant hot-melt strips to fit the seams of the fishing suits. When the hot-melt strip is glued to glue, the waterproof property, adhesive strength, weather resistance and wear resistance of the glue are required to be high. Therefore, more active agent components need to be added during the mixing process.
  • an anti-aging agent to the rubber is very effective in preventing rubber heat and oxygen aging, and also inhibits the catalytic oxidation of the metal.
  • a ketone amine antioxidant such as an RD antioxidant, or an AW antioxidant can be used.
  • RD anti-aging agent has low toxicity and is very effective for thermal oxygen aging.
  • AW anti-aging agent has good anti-ozone aging performance and has obvious protective effect on thermal oxygen and weathering.
  • Xylene is a colorless liquid with aromatic odor, volatile, hardly soluble in water, less dense than water, and can dissolve a variety of organic substances. It is a commonly used solvent. The kneaded material is dissolved in xylene to make it gelatinous, and then elastic rubber is added.
  • Elastic rubber is a blend of pure acrylic synthetic resin and neoprene rubber. It is environmentally friendly and non-toxic. It has high elasticity and high strength of rubber. In addition, the elastic rubber has a wide range of hardness, excellent coloring, soft touch, weather resistance and fatigue resistance. Excellent performance in temperature and temperature resistance. Adding glue can greatly enhance the toughness of the glue and effectively reduce the processing cost.
  • the hardener also known as a curing agent, can cause cross-linking between the molecules of the polymer, and the adhesion of the glue can be improved after the addition, and the hardener is a sulfur-based substance.
  • the vulcanizing agent is diluted liquid sulfur. After foaming, it usually takes 12 hours to defoam time, and the finished glue performance is better.
  • the above formula glue is applied to the field of fishing clothes, that is, the above formula glue is applied at the end of the seam of the fishing clothes for reinforcement and fitting.
  • the glue is manually operated using a dedicated gluing machine.
  • When applying first apply a thin layer of glue to make a base to fill the gap between the seams and increase the fastness of the fit. After air drying, apply a thicker layer of glue to reinforce it. After air drying for 24 hours, it can be used.
  • the traditional fishing clothing sewing seam is made of hot melt belt and glue, the process is complicated and the cost is high.
  • the new glue can be directly applied to the seam of the fishing clothing, simplifying the processing process, saving the cost of the hot melt belt, and obtaining the ratio.
  • the hot melt tape fits the firmer and longer-lasting waterproofing while improving the comfort of the fishing suit.
  • the test water test uses the glue to fit the fishing coat at the seam, and the life can be increased by 10%.
  • the glue of the invention can also be applied to the bonding between other products, for example, the product is used for the bonding between the seams of the wetsuit, and the bonding place is firm, smooth, water-rich and elastic, and can effectively avoid the lane. Was broken.
  • the glue includes the following components:
  • neoprene 20% Percentage by weight, neoprene 20%, zinc oxide 3% , magnesium oxide 3%, RD anti-aging agent 4%, softening oil 10%, xylene solvent 30%, op elastic rubber 20%, vulcanizing agent 5%, hardener 5%.
  • the glue includes the following components:
  • neoprene 20% Percentage by weight, neoprene 20%, zinc oxide 4% , magnesium oxide 4%, RD anti-aging agent 2%, AW anti-aging agent 3%, softening oil 10%, xylene solvent 28%, op elastic rubber 20%, vulcanizing agent 4.5%, hardener 4.5%.
  • neoprene, zinc oxide powder, magnesium oxide, RD anti-aging agent, AW anti-aging agent and softening oil are added to the mixer for mixing; then the xylene solvent is added to the kneaded material, and elastic rubber is added; After the mixture was allowed to stand for 6 hours, it was stirred for 12 hours via a stirrer to thoroughly mix and dissolve various substances. Finally, a hardener, a vulcanizing agent, a vulcanization foaming, and natural defoaming were added to prepare the novel glue.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne une formulation d'une nouvelle eau de colle, qui est appliquée sur un manteau de pêche. L'eau de colle comprend (en pourcentages en poids) : 15-25% de caoutchouc chloroprène, 6-10% d'activateur, 3-5% d'agent anti-vieillissement, 10-12% d'huile plastifiante, 25-30% de solvant de xylène, 15-20% de gomme élastique, 4-5% d'agent de vulcanisation et 4-5% d'agent de durcissement.
PCT/CN2010/080065 2010-05-06 2010-12-21 Nouvelle eau de colle et utilisation de cette dernière WO2011137652A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201010167755.2 2010-05-06
CN 201010167755 CN101831257A (zh) 2010-05-06 2010-05-06 一种新型胶水及其用途

Publications (1)

Publication Number Publication Date
WO2011137652A1 true WO2011137652A1 (fr) 2011-11-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2010/080065 WO2011137652A1 (fr) 2010-05-06 2010-12-21 Nouvelle eau de colle et utilisation de cette dernière

Country Status (2)

Country Link
CN (1) CN101831257A (fr)
WO (1) WO2011137652A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831257A (zh) * 2010-05-06 2010-09-15 尚盟运动用品(惠阳)有限公司 一种新型胶水及其用途
CN102286256B (zh) * 2011-06-21 2012-11-14 中潜股份有限公司 一种用于涂覆潜水服切缝线的胶水及其制备方法
CN106398588B (zh) * 2016-08-31 2019-02-19 中潜股份有限公司 一种高粘结强度耐水胶粘剂及其制备方法和应用
CN106398589A (zh) * 2016-08-31 2017-02-15 中潜股份有限公司 一种高韧性抗老化胶粘剂及其制备方法和应用
CN109385226A (zh) * 2018-09-25 2019-02-26 中山华沙利科技有限公司 一种衣服接缝高强度胶条
CN110093118B (zh) * 2019-05-05 2020-10-09 扬州动易运动用品有限公司 一种潜水服用线缝涂胶及其制造方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5684777A (en) * 1979-12-14 1981-07-10 Toyo Ink Mfg Co Ltd Adhesive composition
CN1065082A (zh) * 1991-03-15 1992-10-07 辛辉 一种改进型氯丁橡胶接枝粘合剂及其制造方法
CN101048479A (zh) * 2004-12-08 2007-10-03 昭和高分子株式会社 氯丁二烯橡胶粘合剂组合物
CN101270267A (zh) * 2007-03-22 2008-09-24 上海五同同步带有限公司 一种粘合胶
CN101492594A (zh) * 2008-12-23 2009-07-29 华南理工大学 一种氯丁胶乳胶黏剂及其制备方法和应用
CN101506322A (zh) * 2006-08-28 2009-08-12 电气化学工业株式会社 硫化型水性粘接剂及其用途
CN101831257A (zh) * 2010-05-06 2010-09-15 尚盟运动用品(惠阳)有限公司 一种新型胶水及其用途

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5527846A (en) * 1995-03-27 1996-06-18 E. I. Du Pont De Nemours And Company Polychloroprene adhesive latex composition
JP3652860B2 (ja) * 1997-11-27 2005-05-25 電気化学工業株式会社 クロロプレンラテックス組成物及びその製造方法、それを用いた接着剤組成物
CN1228407C (zh) * 2004-02-06 2005-11-23 方学平 一种氯丁橡胶粘合剂及其制备方法
CN101333424A (zh) * 2007-06-25 2008-12-31 林润强 一种水性喷胶及其制备方法
CN101343515A (zh) * 2008-08-14 2009-01-14 任占国 一种水性氯丁粘合剂及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5684777A (en) * 1979-12-14 1981-07-10 Toyo Ink Mfg Co Ltd Adhesive composition
CN1065082A (zh) * 1991-03-15 1992-10-07 辛辉 一种改进型氯丁橡胶接枝粘合剂及其制造方法
CN101048479A (zh) * 2004-12-08 2007-10-03 昭和高分子株式会社 氯丁二烯橡胶粘合剂组合物
CN101506322A (zh) * 2006-08-28 2009-08-12 电气化学工业株式会社 硫化型水性粘接剂及其用途
CN101270267A (zh) * 2007-03-22 2008-09-24 上海五同同步带有限公司 一种粘合胶
CN101492594A (zh) * 2008-12-23 2009-07-29 华南理工大学 一种氯丁胶乳胶黏剂及其制备方法和应用
CN101831257A (zh) * 2010-05-06 2010-09-15 尚盟运动用品(惠阳)有限公司 一种新型胶水及其用途

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
LI ZIDONG ET AL.: "Current situation and development trend of chloroprene rubber adhesives", ADHESION, September 2009 (2009-09-01) *
ZHANG YUEJUN ET AL.: "New Product and New Technology of Adhesive", JIANGSU SCIENCE AND TECHNOLOGY PRESS, March 2003 (2003-03-01), pages 76 - 77 *
ZHOU DONGQI ET AL.: "Study on high-tenacity adhesives by chloronorgutta graft modified", CHEMICAL ENGINEER, June 2005 (2005-06-01), pages 53 1 *

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