WO2011114647A1 - プラズマディスプレイ装置 - Google Patents
プラズマディスプレイ装置 Download PDFInfo
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- WO2011114647A1 WO2011114647A1 PCT/JP2011/001311 JP2011001311W WO2011114647A1 WO 2011114647 A1 WO2011114647 A1 WO 2011114647A1 JP 2011001311 W JP2011001311 W JP 2011001311W WO 2011114647 A1 WO2011114647 A1 WO 2011114647A1
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
- G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
- G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
- G09G3/22—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
- G09G3/28—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels
- G09G3/288—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels
- G09G3/291—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels controlling the gas discharge to control a cell condition, e.g. by means of specific pulse shapes
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
- G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
- G09G3/001—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes using specific devices not provided for in groups G09G3/02 - G09G3/36, e.g. using an intermediate record carrier such as a film slide; Projection systems; Display of non-alphanumerical information, solely or in combination with alphanumerical information, e.g. digital display on projected diapositive as background
- G09G3/003—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes using specific devices not provided for in groups G09G3/02 - G09G3/36, e.g. using an intermediate record carrier such as a film slide; Projection systems; Display of non-alphanumerical information, solely or in combination with alphanumerical information, e.g. digital display on projected diapositive as background to produce spatial visual effects
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
- G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
- G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
- G09G3/22—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
- G09G3/28—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels
- G09G3/288—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels
- G09G3/291—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels controlling the gas discharge to control a cell condition, e.g. by means of specific pulse shapes
- G09G3/293—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels controlling the gas discharge to control a cell condition, e.g. by means of specific pulse shapes for address discharge
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/34—Vessels, containers or parts thereof, e.g. substrates
- H01J11/40—Layers for protecting or enhancing the electron emission, e.g. MgO layers
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
- G09G2310/00—Command of the display device
- G09G2310/06—Details of flat display driving waveforms
- G09G2310/066—Waveforms comprising a gently increasing or decreasing portion, e.g. ramp
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
- G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
- G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
- G09G3/2007—Display of intermediate tones
- G09G3/2018—Display of intermediate tones by time modulation using two or more time intervals
- G09G3/2022—Display of intermediate tones by time modulation using two or more time intervals using sub-frames
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09G—ARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
- G09G3/00—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
- G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
- G09G3/22—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
- G09G3/28—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels
- G09G3/288—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels
- G09G3/291—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels controlling the gas discharge to control a cell condition, e.g. by means of specific pulse shapes
- G09G3/292—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using luminous gas-discharge panels, e.g. plasma panels using AC panels controlling the gas discharge to control a cell condition, e.g. by means of specific pulse shapes for reset discharge, priming discharge or erase discharge occurring in a phase other than addressing
- G09G3/2927—Details of initialising
Definitions
- the technology disclosed herein relates to a plasma display device used for a display device or the like.
- a plasma display panel (hereinafter referred to as PDP) is composed of a front plate and a back plate.
- the front plate includes a glass substrate, a display electrode formed on one main surface of the glass substrate, a dielectric layer that covers the display electrode and functions as a capacitor, and magnesium oxide formed on the dielectric layer It is comprised with the protective layer which consists of (MgO).
- the back plate includes a glass substrate, a data electrode formed on one main surface of the glass substrate, a base dielectric layer covering the data electrode, a partition formed on the base dielectric layer, and each partition It is comprised with the fluorescent substance layer which light-emits each in red, green, and blue formed in between.
- the front plate and the back plate are hermetically sealed with the electrode forming surface facing each other.
- Neon (Ne) and xenon (Xe) discharge gases are sealed in the discharge space partitioned by the partition walls.
- the discharge gas is discharged by the video signal voltage selectively applied to the display electrodes.
- the ultraviolet rays generated by the discharge excite each color phosphor layer.
- the excited phosphor layer emits red, green, and blue light.
- the PDP realizes color image display in this way (see Patent Document 1).
- the plasma display device includes a PDP that performs gradation display of an image by a subfield driving method.
- the PDP has a front plate and a back plate disposed to face the front plate.
- the front plate includes a display electrode, a dielectric layer that covers the display electrode, and a protective layer that covers the dielectric layer.
- the protective layer includes a base layer formed on the dielectric layer and a plurality of aggregated particles distributed over the entire surface of the base layer. Aggregated particles are composed of a plurality of aggregated metal oxide crystal particles.
- the plasma display device forms an image by a right-eye field for displaying a right-eye image signal and a left-eye field for displaying a left-eye image signal.
- the right eye field and the left eye field have a plurality of subfields. Above a predetermined gradation, gradation is displayed by at least one subfield excluding the last subfield arranged in the right eye field and the left eye field.
- the plasma display device includes a PDP that performs gradation display of an image by a subfield driving method.
- the PDP has a front plate and a back plate disposed to face the front plate.
- the front plate includes a display electrode, a dielectric layer that covers the display electrode, and a protective layer that covers the dielectric layer.
- the protective layer includes a base layer formed on the dielectric layer, a plurality of first particles dispersed over the entire surface of the base layer, and a plurality of dispersed particles disposed over the entire surface of the base layer.
- the first particles are aggregated particles in which a plurality of metal oxide crystal particles are aggregated.
- the second particles are cubic crystal particles made of magnesium oxide.
- the plasma display device forms an image by a right-eye field for displaying a right-eye image signal and a left-eye field for displaying a left-eye image signal, and the right-eye field and the left-eye field have a plurality of subfields. Above a predetermined gradation, gradation is displayed by at least one subfield excluding the last subfield arranged in the right eye field and the left eye field.
- FIG. 1 is a perspective view showing the structure of a PDP.
- FIG. 2 is an electrode array diagram of the PDP.
- FIG. 3 is a block circuit diagram of the plasma display apparatus.
- FIG. 4 is a drive voltage waveform diagram of the plasma display device according to the exemplary embodiment.
- FIG. 5 is a schematic diagram showing a subfield configuration of the plasma display device according to the exemplary embodiment.
- FIG. 6 is a diagram illustrating coding of the plasma display apparatus according to the embodiment.
- FIG. 7 is a schematic diagram showing a subfield configuration of the plasma display device according to the exemplary embodiment.
- FIG. 8 is a schematic cross-sectional view showing the configuration of the front plate according to the embodiment.
- FIG. 9 is an enlarged view of a protective layer portion according to the embodiment.
- FIG. 1 is a perspective view showing the structure of a PDP.
- FIG. 2 is an electrode array diagram of the PDP.
- FIG. 3 is a block circuit diagram of the plasma display apparatus.
- FIG. 10 is an enlarged view of the surface of the protective layer according to the embodiment.
- FIG. 11 is an enlarged view of the aggregated particles according to the embodiment.
- FIG. 12 is a diagram showing a cathodoluminescence spectrum of the crystal particles according to the embodiment.
- FIG. 13 is a diagram showing the relationship between the electron emission performance and the Vscn lighting voltage.
- FIG. 14 is a diagram showing the relationship between the lighting time of the PDP and the electron emission performance.
- FIG. 15 is an enlarged view for explaining the coverage.
- FIG. 16 is a characteristic diagram showing comparison of sustain discharge voltages.
- FIG. 17 is a characteristic diagram showing the relationship between the average particle size of the aggregated particles and the electron emission performance.
- FIG. 18 is a characteristic diagram showing the relationship between the grain size of crystal grains and the incidence of breakage of partition walls.
- FIG. 19 is a process diagram showing a protective layer forming process according to the embodiment.
- the basic structure of the PDP is a general AC surface discharge type PDP.
- the PDP 1 has a front plate 2 made of a front glass substrate 3 and a back plate 10 made of a back glass substrate 11 facing each other.
- the front plate 2 and the back plate 10 are hermetically sealed with a sealing material whose outer peripheral portion is made of glass frit or the like.
- the discharge space 16 inside the sealed PDP 1 is filled with discharge gas such as neon (Ne) and xenon (Xe) at a pressure of 53 kPa (400 Torr) to 80 kPa (600 Torr).
- a pair of strip-shaped display electrodes 6 each consisting of a scanning electrode 4 and a sustain electrode 5 and a plurality of black stripes 7 are arranged in parallel to each other.
- a dielectric layer 8 that functions as a capacitor is formed on the front glass substrate 3 so as to cover the display electrodes 6 and the black stripes 7. Further, a protective layer 9 made of magnesium oxide (MgO) or the like is formed on the surface of the dielectric layer 8.
- Scan electrode 4 and sustain electrode 5 are each formed by laminating a bus electrode made of Ag on a transparent electrode made of a conductive metal oxide such as indium tin oxide (ITO), tin oxide (SnO 2 ), and zinc oxide (ZnO). Has been.
- ITO indium tin oxide
- SnO 2 tin oxide
- ZnO zinc oxide
- a plurality of data electrodes 12 made of a conductive material mainly composed of silver (Ag) are arranged in parallel to each other in a direction orthogonal to the display electrodes 6.
- the data electrode 12 is covered with a base dielectric layer 13. Further, a partition wall 14 having a predetermined height is formed on the underlying dielectric layer 13 between the data electrodes 12 to divide the discharge space 16.
- a phosphor layer 15 that emits red light by ultraviolet rays, a phosphor layer 15 that emits green light, and a phosphor layer 15 that emits blue light are sequentially applied and formed for each data electrode 12. Yes.
- a discharge cell is formed at a position where the display electrode 6 and the data electrode 12 intersect. Discharge cells having red, green, and blue phosphor layers 15 arranged in the direction of the display electrode 6 serve as pixels for color display.
- the discharge gas sealed in the discharge space 16 contains 10% by volume or more and 30% or less of Xe.
- the PDP 1 has n scan electrodes SC1 to SCn arranged extending in the long side direction. Further, the PDP 1 has n sustain electrodes SU1 to SUn arranged to extend in the long side direction.
- the PDP 1 has m data electrodes D1 to Dm arranged to extend in the short side direction.
- a discharge cell is formed at a portion where scan electrode SC1 and sustain electrode SU1 intersect data electrode D1.
- M ⁇ n discharge cells are formed in the discharge space.
- An area where the discharge cells are arranged is an image display area.
- the scan electrode and the sustain electrode are connected to a connection terminal provided at a peripheral end portion outside the image display area of the front plate.
- the data electrode is connected to a connection terminal provided at a peripheral end portion outside the image display area of the back plate.
- the plasma display apparatus 100 includes a PDP 1, an image signal processing circuit 21, a data electrode drive circuit 22, a scan electrode drive circuit 23, a sustain electrode drive circuit 24, a timing generation circuit 25, and a power supply circuit (not shown). ).
- the image signal processing circuit 21 alternately inputs the right eye image signal and the left eye image signal for each field. Further, the image signal processing circuit 21 converts the input right-eye image signal into right-eye image data indicating light emission or non-light emission for each subfield. Further, the image signal processing circuit 21 converts the left-eye image signal into left-eye image data indicating light emission or non-light emission for each subfield.
- the data electrode drive circuit 22 converts the right-eye image data and the left-eye image data into address pulses corresponding to the data electrodes D1 to Dm. Further, the data electrode drive circuit 22 applies an address pulse to each of the data electrodes D1 to Dm.
- the timing generation circuit 25 generates various timing signals based on the horizontal synchronization signal H and the vertical synchronization signal V, and supplies them to each drive circuit block.
- a timing signal for opening and closing the shutter of the shutter glasses is output to the timing signal output unit.
- a timing signal output unit (not shown) converts a timing signal into, for example, an infrared signal using a light emitting element such as an LED, and supplies the signal to shutter glasses (not shown).
- the scan electrode drive circuit 23 supplies a drive voltage waveform to each of the scan electrodes based on the timing signal.
- the sustain electrode drive circuit 24 supplies a drive voltage waveform to the sustain electrode based on the timing signal.
- the shutter glasses include a receiving unit that receives a timing signal output from a timing signal output unit (not shown), a right-eye liquid crystal shutter R, and a left-eye liquid crystal shutter L. Furthermore, shutter glasses (not shown) open and close the right-eye liquid crystal shutter R and the left-eye liquid crystal shutter L based on the timing signal.
- one field includes five subfields (SF1, SF2, SF3, SF4, and SF5) as an example.
- SF1 which is a subfield arranged at the beginning of the field
- SF2 to SF5 which are subfields arranged after SF1
- a selective initialization operation is performed.
- the luminance weight of SF1 is 16.
- the luminance weight of SF2 is 8.
- the luminance weight of SF3 is 4, and the luminance weight of SF4 is 2.
- the luminance weight of SF5 is 1. That is, the subfield with the largest luminance weight is arranged in SF1. After SF1, the subfields are arranged in descending order of luminance weight. At the end of the field, a subfield having the smallest luminance weight is arranged.
- PDP 1 in the present embodiment is driven by a subfield driving method.
- the subfield driving method one field is composed of a plurality of subfields.
- the subfield has an initialization period, an address period, and a sustain period.
- the initialization period is a period in which the initialization discharge is generated in the discharge cell.
- the address period is a period for generating an address discharge for selecting a discharge cell to emit light after the initialization period.
- the sustain period is a period in which a sustain discharge is generated in the discharge cell selected in the address period.
- sustain electrodes SU1 to SUn are maintained at positive voltage Ve1 (V).
- a ramp voltage that gently falls from voltage Vi3 (V) to voltage Vi4 (V) is applied to scan electrodes SC1 to SCn.
- the second weak setup discharge is generated in all the discharge cells.
- the wall voltage between scan electrodes SC1 to SCn and sustain electrodes SU1 to SUn is weakened.
- the wall voltage on the data electrodes D1 to Dm is adjusted to a value suitable for the write operation.
- the voltage at the intersection of data electrode Dk and scan electrode SC1 exceeds the discharge start voltage.
- Address discharge occurs between data electrode Dk and scan electrode SC1, and between sustain electrode SU1 and scan electrode SC1.
- a positive wall voltage is accumulated on scan electrode SC1 of the discharge cell in which the address discharge has occurred.
- a negative wall voltage is accumulated on sustain electrode SU1 of the discharge cell in which the address discharge has occurred.
- a negative wall voltage is accumulated on the data electrode Dk of the discharge cell in which the address discharge has occurred.
- the voltage at the intersection between the data electrodes D1 to Dm to which the address pulse voltage Vd (V) is not applied and the scan electrode SC1 does not exceed the discharge start voltage. Accordingly, no address discharge occurs.
- the above address operation is sequentially performed until the discharge cell in the nth row.
- the address period ends when the address operation of the discharge cell in the n-th row ends.
- discharge cells in which an address discharge is generated in the address period by applying sustain pulse voltages Vs (V) corresponding to the luminance weight alternately to scan electrodes SC1 to SCn and sustain electrodes SU1 to SUn are applied. Sustain discharge occurs continuously.
- the sustain operation in the sustain period ends.
- a ramp waveform voltage that gently rises toward voltage Vr is applied to scan electrodes SC1 to SCn.
- the wall voltage on scan electrode SCi and sustain electrode SUi is weakened while leaving a positive wall voltage on data electrode Dk.
- the selective initializing operation is an operation for selectively performing initializing discharge on the discharge cells that have performed the address operation in the address period of the immediately preceding subfield, and thus the discharge cells that have performed the sustain operation in the sustain period.
- the operation during the subsequent writing period is the same as the operation during the writing period of SF1. Therefore, detailed description is omitted.
- the operation in the subsequent sustain period is the same as the operation in the sustain period of SF1 except for the number of sustain pulses.
- the subsequent operations of SF3 to SF5 are the same as those of SF2 except for the number of sustain pulses.
- These voltage values can be appropriately set to optimum values in accordance with the characteristics of the PDP 1 and the specifications of the plasma display device 100.
- the field frequency is set to 120 Hz, which is twice the normal frequency, in order to display a stereoscopic image. Further, the right eye field and the left eye field are alternately arranged.
- the right-eye liquid crystal shutter R and the left-eye liquid crystal shutter L of the shutter glasses receive the timing signal output from the timing signal output unit and control the shutter glasses as follows.
- the right-eye liquid crystal shutter R of the shutter glasses opens the shutter in synchronization with the start of the writing period of SF1 in the right-eye field, and closes the shutter in synchronization with the start of the writing period of SF1 in the left-eye field.
- the left-eye liquid crystal shutter L opens the shutter in synchronization with the start of the writing period of SF1 in the left-eye field, and closes the shutter in synchronization with the start of the writing period of SF1 in the right-eye field.
- the crosstalk between the right eye image and the left eye image is suppressed.
- the address discharge can be stabilized and a high-quality stereoscopic image can be displayed.
- the intensity of afterglow of the phosphor is proportional to the luminance when the phosphor emits light. Further, the intensity of afterglow of the phosphor is attenuated with a constant time constant.
- the emission luminance in the sustain period is higher as the subfield has a larger luminance weight. Therefore, in order to weaken the afterglow, it is desirable to arrange a subfield having a large luminance weight early in the field. Therefore, in this embodiment, in order to suppress crosstalk due to afterglow, the subfields having the largest luminance weight are arranged in order from the subfield having the smallest luminance weight.
- the address operation is not performed in all the subfields SF1 to SF5. Then, the discharge cell never sustains discharge, and the luminance becomes the lowest.
- the address operation is performed only in SF5 which is a subfield having the luminance weight “1”. Further, no write operation is performed in SF1 to SF4. Accordingly, the discharge cell is displayed with a brightness of “1” by generating a sustain discharge of the number of times corresponding to the luminance weight “1”.
- the address operation is performed by SF3 having the luminance weight “4”, SF4 having the luminance weight “2”, and SF5 having the luminance weight “1”. Then, the discharge cell generates the number of sustain discharges corresponding to the luminance weight “4” during the sustain period of SF3.
- the sustain discharge is generated the number of times corresponding to the luminance weight “2”.
- the sustain discharge is generated the number of times corresponding to the luminance weight “1”. Therefore, the brightness of “7” is displayed in total.
- the display of other gradations is the same. That is, according to the coding shown in FIG. 6, the presence or absence of the sustain discharge is controlled by the presence or absence of the address operation in each subfield.
- SF5 which is a subfield arranged at the end of the field is used. It is controlled not to perform a write operation.
- SF5 is a subfield arranged at the end of the field, and is the subfield having the shortest time from the end of the maintenance period to the shutter switching time as shown in FIG.
- the intensity of afterglow of the phosphor is proportional to the luminance when the phosphor emits light, and exhibits a characteristic of decaying with a constant time constant. Therefore, SF5 having the smallest luminance weight and arranged at the end of the field is a subfield having a large contribution to the afterimage for a small contribution to the display luminance.
- the after-image is effectively eliminated without greatly affecting the display image by not performing the address operation of the subfield SF5 that has the smallest luminance weight and is arranged at the end of the field. Can be suppressed. Therefore, a higher quality stereoscopic image can be displayed.
- gradations such as gradations “17”, “19”, and “21” cannot be displayed.
- these gradations can be displayed in a pseudo manner by performing image signal processing using, for example, an error diffusion method or a dither method.
- the coding has been described in which, when displaying gradations that are equal to or higher than the threshold value, the writing operation is not performed only with SF5 having the smallest luminance weight and arranged at the end of the field.
- the present invention is not limited to this.
- a plurality of threshold values may be provided for gradation display.
- it can also be set as follows.
- the threshold value is equal to or higher than the first threshold, the writing operation is not performed on the subfield arranged at the end of the field and the second subfield from the end. Above the second threshold, it is set not to perform the write operation of the subfield arranged at the end of the field.
- Scan electrode 4, sustain electrode 5, and black stripe 7 are formed on front glass substrate 3 by photolithography.
- scan electrode 4 and sustain electrode 5 have metal bus electrodes 4b and 5b containing silver (Ag) for ensuring conductivity.
- Scan electrode 4 and sustain electrode 5 have transparent electrodes 4a and 5a.
- the metal bus electrode 4b is laminated on the transparent electrode 4a.
- the metal bus electrode 5b is laminated on the transparent electrode 5a.
- ITO or the like is used to ensure transparency and electrical conductivity.
- an ITO thin film is formed on the front glass substrate 3 by sputtering or the like.
- transparent electrodes 4a and 5a having a predetermined pattern are formed by lithography.
- a metal bus electrode paste containing silver (Ag), a glass frit for binding silver, a photosensitive resin, a solvent, and the like is used as the material of the metal bus electrodes 4b and 5b.
- a metal bus electrode paste containing silver (Ag), a glass frit for binding silver, a photosensitive resin, a solvent, and the like is used.
- a metal bus electrode paste is applied to the front glass substrate 3 by a screen printing method or the like.
- the solvent in the metal bus electrode paste is removed by a drying furnace.
- the metal bus electrode paste is exposed through a photomask having a predetermined pattern.
- metal bus electrode paste is developed to form a metal bus electrode pattern.
- the metal bus electrode pattern is fired at a predetermined temperature in a firing furnace. That is, the photosensitive resin in the metal bus electrode pattern is removed. Further, the glass frit in the metal bus electrode pattern is melted. The molten glass frit is vitrified again after firing.
- Metal bus electrodes 4b and 5b are formed by the above steps.
- the black stripe 7 is formed of a material containing a black pigment.
- the dielectric layer 8 is formed.
- a dielectric paste containing a dielectric glass frit, a resin, a solvent, and the like is used as a material for the dielectric layer 8.
- a dielectric paste is applied on the front glass substrate 3 by a die coating method or the like so as to cover the scan electrodes 4, the sustain electrodes 5 and the black stripes 7 with a predetermined thickness.
- the solvent in the dielectric paste is removed by a drying furnace.
- the dielectric paste is fired at a predetermined temperature in a firing furnace. That is, the resin in the dielectric paste is removed. Further, the dielectric glass frit is melted. The molten glass frit is vitrified again after firing.
- the dielectric layer 8 is formed.
- a screen printing method, a spin coating method, or the like can be used.
- a film that becomes the dielectric layer 8 can be formed by CVD (Chemical Vapor Deposition) method or the like without using the dielectric paste.
- a protective layer 9 is formed on the dielectric layer 8. Details of the protective layer 9 will be described later.
- the front plate 2 having a predetermined configuration on the front glass substrate 3 is completed through the above steps.
- Data electrodes 12 are formed on the rear glass substrate 11 by photolithography.
- a data electrode paste containing silver (Ag) for ensuring conductivity, a glass frit for binding silver, a photosensitive resin, a solvent, and the like is used as a material of the data electrode 12.
- the data electrode paste is applied on the rear glass substrate 11 with a predetermined thickness by a screen printing method or the like.
- the solvent in the data electrode paste is removed by a drying furnace.
- the data electrode paste is exposed through a photomask having a predetermined pattern.
- the data electrode paste is developed to form a data electrode pattern.
- the data electrode pattern is fired at a predetermined temperature in a firing furnace.
- the data electrode 12 is formed by the above process.
- a sputtering method, a vapor deposition method, or the like can be used.
- the base dielectric layer 13 is formed.
- a base dielectric paste containing a dielectric glass frit, a resin, a solvent, and the like is used as a material for the base dielectric layer 13.
- a base dielectric paste is applied by a screen printing method or the like so as to cover the data electrode 12 on the rear glass substrate 11 on which the data electrode 12 is formed with a predetermined thickness.
- the solvent in the base dielectric paste is removed by a drying furnace.
- the base dielectric paste is fired at a predetermined temperature in a firing furnace. That is, the resin in the base dielectric paste is removed.
- a dielectric glass frit is formed. The molten glass frit is vitrified again after firing.
- the base dielectric layer 13 is formed.
- a die coating method, a spin coating method, or the like can be used.
- a film to be the base dielectric layer 13 can be formed by CVD (Chemical Vapor Deposition) method or the like without using the base dielectric paste.
- the barrier ribs 14 are formed by photolithography.
- a partition paste containing a filler, a glass frit for binding the filler, a photosensitive resin, a solvent, and the like is used as a material for the partition wall 14.
- the barrier rib paste is applied on the underlying dielectric layer 13 with a predetermined thickness by a die coating method or the like.
- the solvent in the partition wall paste is removed by a drying furnace.
- the barrier rib paste is exposed through a photomask having a predetermined pattern.
- the barrier rib paste is developed to form a barrier rib pattern.
- the partition pattern is fired at a predetermined temperature in a firing furnace. That is, the photosensitive resin in the partition pattern is removed.
- the glass frit in a partition pattern is carried out.
- the molten glass frit is vitrified again after firing.
- the partition wall 14 is formed by the above process.
- a sandblast method or the like can be used.
- the phosphor layer 15 is formed.
- a phosphor paste containing phosphor particles, a binder, a solvent, and the like is used as the material of the phosphor layer 15.
- a phosphor paste is applied on the base dielectric layer 13 between adjacent barrier ribs 14 and on the side surfaces of the barrier ribs 14 by a dispensing method or the like.
- the solvent in the phosphor paste is removed by a drying furnace.
- the phosphor paste is fired at a predetermined temperature in a firing furnace. That is, the resin in the phosphor paste is removed.
- the phosphor layer 15 is formed by the above steps.
- a screen printing method or the like can be used.
- the back plate 10 having predetermined constituent members on the back glass substrate 11 is completed.
- a sealing material (not shown) is formed around the back plate 10 by the dispensing method.
- a sealing paste containing glass frit, a binder, a solvent, and the like is used.
- the solvent in the sealing paste is removed by a drying furnace.
- the front plate 2 and the back plate 10 are arranged to face each other so that the display electrode 6 and the data electrode 12 are orthogonal to each other.
- the periphery of the front plate 2 and the back plate 10 is sealed with glass frit.
- the discharge space 16 is filled with a discharge gas containing Ne, Xe, etc., thereby completing the PDP 1.
- the dielectric material includes the following components.
- Bismuth oxide (Bi 2 O 3 ) is 20 wt% to 40 wt%, and at least one selected from calcium oxide (CaO), strontium oxide (SrO), and barium oxide (BaO) is 0.5 wt% to 12 wt%.
- the dielectric material is substantially free of lead components.
- the film thickness of the dielectric layer 8 is 40 ⁇ m or less.
- the relative dielectric constant ⁇ of the dielectric layer 8 is 4 or more and 7 or less. The effect that the dielectric constant ⁇ of the dielectric layer 8 is 4 or more and 7 or less will be described later.
- the dielectric material powder composed of these composition components is pulverized by a wet jet mill or a ball mill so that the average particle diameter becomes 0.5 ⁇ m to 2.5 ⁇ m, thereby producing a dielectric material powder.
- 55 wt% to 70 wt% of the dielectric material powder and 30 wt% to 45 wt% of the binder component are well kneaded with three rolls to obtain a first dielectric layer paste for die coating or printing. Complete.
- the binder component is ethyl cellulose, terpineol containing 1% to 20% by weight of acrylic resin, or butyl carbitol acetate.
- dioctyl phthalate, dibutyl phthalate, triphenyl phosphate, and tributyl phosphate are added as plasticizers as needed, and glycerol monooleate, sorbitan sesquioleate, and homogenol (Kao Corporation) as dispersants. Company name), phosphoric esters of alkylallyl groups, and the like may be added. When a dispersant is added, printability is improved.
- the protective layer has mainly four functions. The first is to protect the dielectric layer from ion bombardment due to discharge. The second is to release initial electrons for generating an address discharge. The third is to hold a charge for generating a discharge. Fourth, secondary electrons are emitted during the sustain discharge.
- an increase in discharge voltage is suppressed.
- address discharge errors that cause image flickering are reduced.
- the applied voltage is reduced by improving the charge retention performance. As the number of secondary electron emission increases, the sustain discharge voltage is reduced.
- the attenuation rate at which the charge accumulated in the protective layer decreases with time increases. Therefore, it is necessary to take measures such as increasing the applied voltage to compensate for the attenuated charge.
- the protective layer is required to have two contradictory characteristics such as high initial electron emission performance and low charge decay rate, that is, high charge retention performance.
- the protective layer 9 includes a base film 91 that is a base layer, aggregated particles 92 that are first particles, and crystal particles 93 that are second particles.
- the base film 91 is, for example, a magnesium oxide (MgO) film containing aluminum (Al) as an impurity.
- the agglomerated particles 92 are obtained by aggregating a plurality of crystal particles 92b having a particle diameter smaller than the crystal particles 92a on MgO crystal particles 92a.
- the crystal particles 93 are cubic crystal particles made of MgO. The shape can be confirmed by a scanning electron microscope (SEM).
- SEM scanning electron microscope
- a plurality of aggregated particles 92 are distributed over the entire surface of the base film 91.
- a plurality of crystal particles 93 are distributed over the entire surface of the base film 91.
- the crystal particles 92a are particles having an average particle diameter in the range of 0.9 ⁇ m to 2 ⁇ m.
- the crystal particles 92b are particles having an average particle diameter in the range of 0.3 ⁇ m to 0.9 ⁇ m.
- the average particle diameter is a volume cumulative average diameter (D50).
- a laser diffraction particle size distribution measuring device MT-3300 manufactured by Nikkiso Co., Ltd. was used for measuring the average particle size.
- the surface of the protective layer 9 is formed on the base film 91 by agglomerated particles 92 obtained by agglomerating several polyhedral crystal particles 92b on polyhedral crystal particles 92a, and cubic crystal particles 93.
- the cubic crystal particles 93 include particles having a particle size of about 200 nm and nanoparticles having a particle size of 100 nm or less.
- the cubic crystal particles 93 are aggregated, the polyhedral crystal particles 92 a or the polyhedral crystal particles 92 b, or the aggregate particles 92 of the polyhedral crystal particles 92 a and 92 b.
- MgO cubic crystal particles 93 were present.
- the polyhedral crystal particles 92a and 92b were produced by a liquid phase method.
- the cubic-shaped crystal particles 93 were produced by a vapor phase method.
- the “cubic shape” does not indicate a strict cube in a geometric sense. It refers to a shape that can be recognized as a cube by visually observing an electron micrograph.
- the “polyhedron shape” refers to a shape that can be recognized as having approximately seven or more surfaces by visually observing an electron micrograph.
- the aggregated particles 92 are those in which a plurality of crystal particles 92a and 92b having a predetermined primary particle size are aggregated as shown in FIG. Alternatively, the aggregated particles 92 are in a state in which a plurality of crystal particles 92a having a predetermined primary particle size are aggregated. Aggregated particles 92 are not bonded as a solid by a strong bonding force. The agglomerated particles 92 are a collection of a plurality of primary particles due to static electricity, van der Waals force, or the like. In addition, the aggregated particles 92 are bonded with a force such that part or all of the aggregated particles 92 are decomposed into primary particles by an external force such as ultrasonic waves.
- the particle diameter of the agglomerated particles 92 is about 1 ⁇ m, and the crystal particles 92a and 92b have a polyhedral shape having seven or more faces such as a tetrahedron and a dodecahedron.
- the crystal particles 92a and 92b were produced by a liquid phase method in which a crystal solution of MgO precursor such as magnesium carbonate or magnesium hydroxide was baked.
- the particle size can be controlled by adjusting the firing temperature and firing atmosphere by the liquid phase method.
- the firing temperature can be selected in the range of about 700 ° C. to 1500 ° C. When the firing temperature is 1000 ° C. or higher, the primary particle size can be controlled to about 0.3 to 2 ⁇ m.
- the crystal particles 92a and 92b are obtained in the form of aggregated particles 92 in which a plurality of primary particles are aggregated in the production process by the liquid phase method.
- the cubic crystal particles 93 are obtained by a gas phase method in which magnesium is heated to a boiling point or more to generate magnesium vapor and gas phase oxidation is performed. Crystal particles having a cubic single crystal structure with a particle size of 200 nm or more (measurement result by the BET method) or a multiple crystal structure in which crystals are fitted to each other are obtained.
- a method for synthesizing magnesium powder by the vapor phase method is known in the Journal of Materials, Vol. 36, No. 410, “Synthesis and Properties of Magnesia Powder by Gas Phase Method”.
- the heating temperature for generating magnesium vapor is increased, and the length of the flame in which magnesium and oxygen react is increased. To do.
- MgO crystal particles can be obtained by a gas phase method having a larger particle size.
- Cathode luminescence (CL) emission characteristics of the polyhedral crystal particles 92a and 92b and the cubic crystal particle 93 were measured.
- the thin solid line is the emission intensity of the polyhedral crystal particles 92a and 92b of MgO, that is, the cathodoluminescence (emission) intensity of the aggregated particles 92.
- the thick solid line is the cathodoluminescence (light emission) intensity of the cubic crystal particles 93 of MgO.
- the aggregated particle 92 in which several polyhedral crystal particles 92a and 92b are aggregated has a peak of emission intensity in a wavelength region of a wavelength of 200 nm to 300 nm, particularly a wavelength of 230 nm to 250 nm.
- the cubic crystal particles 93 of MgO have no emission intensity peak in the wavelength region of 200 nm to 300 nm. However, it has a peak of light emission intensity in a wavelength region of 400 nm to 450 nm. That is, the aggregated particles 92 that are agglomerated several MgO polyhedral crystal particles 92a and 92b and the MgO cubic crystal particles 93 attached on the base film 91 correspond to the wavelength of the emission intensity peak. Has energy levels.
- Prototype 1 is a PDP having a protective layer made only of an MgO film.
- Prototype 2 is a PDP having a protective layer made only of MgO doped with impurities such as Al and Si.
- Prototype 3 is a PDP in which only primary particles of crystal particles made of metal oxide are dispersedly arranged on a base film 91 made of MgO.
- Prototype 4 is PDP 1 in which agglomerated particles 92 obtained by aggregating MgO crystal particles having the same particle diameter are adhered on a base film 91 made of MgO so as to be distributed over the entire surface. That is, the prototype 4 is a PDP 1 in which a plurality of aggregated particles 92 are dispersedly arranged on the entire surface of the base film 91.
- Prototype 5 is an MgO crystal particle having a particle size smaller than that of crystal particle 92a around MgO crystal particle 92a having an average particle size of 0.9 ⁇ m to 2 ⁇ m on base film 91 made of MgO.
- the protective layer 9 has a polyhedral aggregated particle 92 in which 92b is aggregated and cubic MgO crystal particles 93 attached so as to be distributed over the entire surface.
- PDP polyhedral aggregated particle 92 in which 92b is aggregated and cubic MgO crystal particles 93 attached so as to be distributed over the entire surface.
- the prototype 5 is a PDP 1 in which a plurality of agglomerated particles 92 and a plurality of crystal particles 93 are distributed over the entire surface of the base film 91.
- PDP 1 in which a plurality of aggregated particles 92 and a plurality of crystal particles 93 are uniformly distributed over the entire surface of base film 91 is more preferable. This is because variations in discharge characteristics can be suppressed
- the electron emission performance is a numerical value indicating that the larger the electron emission performance, the larger the amount of electron emission.
- the electron emission performance is expressed as the initial electron emission amount determined by the surface state of the discharge, the gas type and the state.
- the initial electron emission amount can be measured by a method of measuring the amount of electron current emitted from the surface by irradiating the surface with ions or an electron beam.
- a numerical value called a statistical delay time which is a measure of the likelihood of occurrence of discharge, was measured.
- a numerical value linearly corresponding to the initial electron emission amount is obtained.
- the delay time at the time of discharge is the time from the rise of the address discharge pulse until the address discharge is delayed. It is considered that the discharge delay is mainly caused by the fact that initial electrons that become a trigger when the address discharge is generated are not easily released from the surface of the protective layer into the discharge space.
- a voltage value of a voltage (hereinafter referred to as a Vscn lighting voltage) applied to the scan electrode necessary for suppressing the charge emission phenomenon when used as a PDP was used. That is, a lower Vscn lighting voltage indicates a higher charge retention capability.
- the Vscn lighting voltage is low, the PDP can be driven at a low voltage. Therefore, it is possible to use components having a low withstand voltage and a small capacity as the power source and each electrical component.
- an element having a withstand voltage of about 150 V is used as a semiconductor switching element such as a MOSFET for sequentially applying a scanning voltage to a panel.
- the Vscn lighting voltage is preferably suppressed to 120 V or less in consideration of variation due to temperature.
- the Vscn lighting voltage was able to be 120 V or less in the evaluation of the charge retention performance.
- Prototypes 4 and 5 were able to obtain good characteristics with an electron emission performance of 6 or more.
- the electron emission ability and the charge retention ability of the protective layer of the PDP are contradictory.
- the Vscn lighting voltage also increases.
- the PDP having the protective layer of the present embodiment it is possible to obtain an electron emission capability having characteristics of 6 or more and a charge retention capability of Vscn lighting voltage of 120 V or less. That is, it is possible to obtain a protective layer having both an electron emission capability and a charge retention capability that can cope with a PDP in which the number of scanning lines increases and the cell size tends to decrease due to high definition.
- FIG. 14 shows the transition of the electron emission performance with respect to the lighting time of the PDP as a result of examining the time-dependent deterioration of the electron emission performance of the prototypes 4 and 5 that have obtained good characteristics in FIG.
- MgO having a particle diameter smaller than that of the crystal particles 92a around the MgO crystal particles 92a having an average particle diameter in the range of 0.9 ⁇ m to 2 ⁇ m.
- the prototype 5 in which the polyhedral aggregated particles 92 in which the crystal particles 92b are aggregated and the cubic MgO crystal particles 93 are dispersed over the entire surface is less deteriorated with time in the electron emission performance than the prototype 4. .
- Prototype 4 it is estimated that the ions 92 generated by the discharge in the PDP cell impact the protective layer, causing the aggregated particles 92 to peel off.
- MgO crystal particles 92b having a smaller average particle size are aggregated around MgO crystal particles 92a having an average particle size in the range of 0.9 ⁇ m to 2 ⁇ m. That is, since the crystal particle 92b having a small particle size has a large surface area, the adhesion with the base film 91 is enhanced, and it is presumed that the agglomerated particles 92 are unlikely to peel off due to ion bombardment.
- the prototype 5 PDP it is possible to obtain an electron emission ability having characteristics of 6 or more and a charge holding ability of Vscn lighting voltage of 120 V or less. That is, it is possible to obtain a protective layer having both an electron emission capability and a charge retention capability that can cope with a PDP in which the number of scanning lines increases and the cell size tends to decrease due to high definition. Furthermore, since the deterioration over time of the electron emission performance is small, stable image quality can be obtained over a long period of time.
- the aggregated particles 92 and the crystal particles 93 are attached so as to be distributed over the entire surface with a coverage of 10% or more and 20% or less when attached on the base film 91. .
- an image of a region corresponding to one discharge cell divided by the barrier ribs 14 is taken.
- the image is trimmed to the size of one cell of x ⁇ y.
- the trimmed image is binarized into black and white data.
- the area a of the black area by the aggregated particles 92 and the crystal particles 93 is obtained. Finally, it is calculated by a / b ⁇ 100.
- the prototype A has only the aggregated particles 92 made of MgO crystal particles 92 a and 92 b having CL emission peaks in the wavelength region of 200 nm or more and 300 nm or less on the base film 91 made of MgO. It is made PDP.
- Prototypes B and C have MgO having a particle size smaller than that of crystal particles 92a around MgO polyhedral crystal particles 92a having an average particle size in the range of 0.9 ⁇ m to 2 ⁇ m on the base film made of MgO.
- aggregated particles 92 obtained by agglomerating the polyhedral crystal particles 92b and cubic MgO crystal particles 93 are dispersed over the entire surface.
- the prototype B and the prototype C differ in the dielectric constant ⁇ of the dielectric layer 8. That is, in the prototype B, the dielectric constant ⁇ of the dielectric layer 8 is about 9.7. In the prototype C, the relative dielectric constant ⁇ of the dielectric layer 8 is 7. About a coverage, all are about 13% of 20% or less.
- the prototypes B and C can reduce the sustain discharge voltage with respect to the prototype A. That is, MgO polyhedral crystal particles 92a and 92b having a characteristic of performing CL emission having a peak in a wavelength region of 200 nm to 300 nm and CL emission having a peak in a wavelength region of 400 nm to 450 nm are performed.
- a PDP having a protective layer on which cubic crystal particles 93 of the characteristic MgO are attached can reduce the sustain discharge voltage. That is, the power consumption of the PDP can be reduced.
- the sustain discharge voltage can be further reduced by reducing the relative dielectric constant ⁇ of the dielectric layer 8. In particular, according to experiments by the present inventors, it has been found that the effect can be obtained more significantly by setting the relative dielectric constant ⁇ of the dielectric layer 8 to 4 or more and 7 or less.
- FIG. 17 shows the experimental results of examining the electron emission performance by changing the average particle diameter of the MgO aggregated particles 92 in the protective layer.
- the average particle diameter of the aggregated particles 92 was measured by observing the aggregated particles 92 with an SEM.
- the number of crystal particles per unit area on the protective layer 9 is large. According to the experiments by the present inventors, if the crystal particles 92a, 92b, 93 are present in the portion corresponding to the top of the partition 14 that is in close contact with the protective layer 9, the top of the partition 14 may be damaged. In this case, it has been found that a phenomenon in which the corresponding cell does not normally turn on or off due to, for example, the damaged material of the partition wall 14 getting on the phosphor. The phenomenon of the partition wall breakage is unlikely to occur unless the crystal particles 92a, 92b, and 93 are present at the portion corresponding to the top of the partition wall. .
- the aggregated particles 92 preferably have an average particle size of 0.9 ⁇ m or more and 2.5 ⁇ m or less.
- mass production is actually performed as a PDP, it is necessary to consider variations in manufacturing crystal grains and manufacturing variations when forming a protective layer.
- a plurality of agglomerated particles 92 and a plurality of crystal particles 93 are discretely dispersed and adhered onto the unfired base film 91. That is, the aggregated particles 92 and the crystal particles 93 are dispersed and arranged over the entire surface of the base film 91.
- an aggregated particle paste in which polyhedral crystal particles 92a and 92b having a predetermined particle size distribution are mixed in a solvent is prepared.
- a crystal particle paste in which cubic crystal particles 93 are mixed in a solvent is produced. That is, the agglomerated particle paste and the crystal particle paste are prepared separately. Thereafter, the agglomerated particle paste and the crystal particle paste are mixed to produce a mixed crystal particle paste in which polyhedral crystal particles 92a and 92b and crystal particles 93 are mixed in a solvent.
- the mixed crystal particle paste is applied onto the base film 91, whereby a mixed crystal particle paste film having an average film thickness of 8 ⁇ m to 20 ⁇ m is formed.
- a screen printing method, a spray method, a spin coating method, a die coating method, a slit coating method, or the like can also be used.
- the affinity for the MgO base film 91, the agglomerated particles 92, and the crystal particles 93 is high, and the solvent is removed by evaporation in the subsequent drying step A4.
- a vapor pressure of about several tens Pa at room temperature is suitable.
- an organic solvent alone such as methylmethoxybutanol, terpineol, propylene glycol, benzyl alcohol or a mixed solvent thereof is used.
- the viscosity of the paste containing these solvents is several mPa ⁇ s to several tens mPa ⁇ s.
- the substrate coated with the mixed crystal particle paste is immediately transferred to the drying step A4.
- the mixed crystal particle paste film is dried under reduced pressure. Specifically, the mixed crystal particle paste film is rapidly dried within several tens of seconds in a vacuum chamber. Therefore, convection in the film, which is remarkable in heat drying, does not occur. Therefore, the agglomerated particles 92 and the crystal particles 93 are more uniformly deposited on the base film 91.
- the unfired base film 91 formed in the base film deposition step A2 and the mixed crystal particle paste film that has undergone the drying step A4 are simultaneously fired at a temperature of several hundred degrees Celsius. .
- the solvent and the resin component remaining in the mixed crystal particle paste film are removed.
- the protective layer 9 is formed on the base film 91 in which aggregated particles 92 composed of a plurality of polyhedral crystal particles 92a and 92b and cubic crystal particles 93 are attached.
- a method of spraying a particle group directly with a gas or the like without using a solvent, or a method of simply spraying using gravity may be used.
- the agglomerated particle paste in which polyhedral crystal particles 92a and 92b having a predetermined particle size distribution are mixed in a solvent the agglomerated particles 92 in which the crystal particles 92a and 92b are aggregated are spread over the entire surface. Can be distributed.
- the agglomerated particles 92 in which the plurality of crystal particles 92a are aggregated can be dispersed and arranged over the entire surface of the base film 91.
- the first plasma display device 100 includes a PDP 1 that performs gradation display of an image by a subfield driving method.
- the PDP 1 includes a front plate 2 and a back plate 10 disposed to face the front plate 2.
- the front plate 2 includes a display electrode 6, a dielectric layer 8 that covers the display electrode 6, and a protective layer 9 that covers the dielectric layer 8.
- the protective layer 9 includes a base film 91 that is a base layer formed on the dielectric layer 8 and a plurality of agglomerated particles 92 that are distributed over the entire surface of the base film 91.
- the aggregated particles 92 are composed of a plurality of aggregated metal oxide crystal particles 92a.
- the plasma display apparatus 100 forms an image by a right-eye field that displays a right-eye image signal and a left-eye field that displays a left-eye image signal.
- the right eye field and the left eye field have a plurality of subfields.
- gradation is displayed by at least one or more subfields excluding the last subfield arranged in the right-eye field and the left-eye field.
- the second plasma display device 100 includes a PDP 1 that performs gradation display of an image by a subfield driving method.
- the PDP 1 includes a front plate 2 and a back plate 10 disposed to face the front plate 2.
- the front plate 2 includes a display electrode 6, a dielectric layer 8 that covers the display electrode 6, and a protective layer 9 that covers the dielectric layer 8.
- the protective layer 9 is a base film 91 formed on the dielectric layer 8, a plurality of first particles distributed over the entire surface of the base film 91, and a base layer 91 distributed over the entire surface of the base layer.
- the first particles are aggregated particles 92 in which a plurality of metal oxide crystal particles 92 a are aggregated.
- the second particles are cubic crystal particles 93 made of magnesium oxide.
- the plasma display apparatus 100 forms an image by a right-eye field that displays a right-eye image signal and a left-eye field that displays a left-eye image signal.
- the right eye field and the left eye field have a plurality of subfields.
- gradation is displayed by at least one or more subfields excluding the last subfield arranged in the right eye field and the left eye field.
- the plasma display device 100 has high initial electron emission performance and high charge retention performance. Furthermore, the discharge delay that occurs during high-speed driving with a short address period such that the right-eye field and the left-eye field are displayed alternately is suppressed. Therefore, occurrence of image flicker due to writing failure is suppressed. Furthermore, crosstalk between the right-eye image and the left-eye image is suppressed.
- MgO is taken as an example of the base film 91.
- the performance required for the base film 91 is to have high sputtering resistance performance to protect the dielectric from ion bombardment.
- a protective layer composed mainly of MgO is very often formed in order to achieve both the electron emission performance above a certain level and the sputter resistance.
- the electron emission performance is controlled predominantly by the agglomerated particles 92, there is no need to be MgO, and other materials having excellent impact resistance such as Al 2 O 3 are used. It doesn't matter at all.
- MgO particles as single crystal particles, but other single crystal particles also oxidize metals such as Sr, Ca, Ba, and Al, which have high electron emission performance like MgO. The same effect can be obtained even when crystal grains made of a material are used. Therefore, the particle type is not limited to MgO.
- the technology disclosed in the present embodiment is useful for realizing a PDP having high-definition and high-luminance display performance and low power consumption.
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Abstract
Description
PDPの基本構造は、一般的な交流面放電型PDPである。図1に示すように、PDP1は前面ガラス基板3などよりなる前面板2と、背面ガラス基板11などよりなる背面板10とが対向して配置されている。前面板2と背面板10とは、外周部がガラスフリットなどからなる封着材によって気密封着されている。封着されたPDP1内部の放電空間16には、ネオン(Ne)およびキセノン(Xe)などの放電ガスが53kPa(400Torr)~80kPa(600Torr)の圧力で封入されている。
図3に示すように、プラズマディスプレイ装置100は、PDP1、画像信号処理回路21、データ電極駆動回路22、走査電極駆動回路23、維持電極駆動回路24、タイミング発生回路25および電源回路(図示せず)を備えている。
図4に示すように本実施の形態におけるPDP1は、サブフィールド駆動法により駆動される。サブフィールド駆動法では、1フィールドが複数のサブフィールドにより構成される。サブフィールドは、初期化期間と、書込み期間と、維持期間とを有する。初期化期間は放電セルにおいて初期化放電を発生させる期間である。書込み期間は、初期化期間のあと、発光させる放電セルを選択する書込み放電を発生させる期間である。維持期間は、書込み期間において選択された放電セルに維持放電を発生させる期間である。
第1サブフィールドの初期化期間では、データ電極D1~Dmおよび維持電極SU1~SUnが0(V)に保持される。また、走査電極SC1~SCnに対して放電開始電圧以下となる電圧Vi1(V)から放電開始電圧を超える電圧Vi2(V)に向かって緩やかに上昇するランプ電圧が印加される。すると、全ての放電セルにおいて1回目の微弱な初期化放電が発生する。初期化放電によって、走査電極SC1~SCn上に負の壁電圧が蓄えられる。維持電極SU1~SUn上およびデータ電極D1~Dm上に正の壁電圧が蓄えられる。壁電圧とは保護層9や蛍光体層15上などに蓄積した壁電荷により生じる電圧である。
続く書込み期間では、維持電極SU1~SUnに電圧Ve2が印加される。走査電極SC1~SCには電圧Vcが印加される。次に、走査電極SC1に負の走査パルス電圧Va(V)が印加される。さらに、データ電極D1~Dmのうち1行目に表示すべき放電セルのデータ電極Dk(k=1~m)に正の書込みパルス電圧Vd(V)が印加される。このときデータ電極Dkと走査電極SC1との交差部の電圧は、外部印加電圧(Vd-Va)(V)にデータ電極Dk上の壁電圧と走査電極SC1上の壁電圧とが加算されたものとなる。つまり、データ電極Dkと走査電極SC1との交差部の電圧は、放電開始電圧を超える。そして、データ電極Dkと走査電極SC1との間および維持電極SU1と走査電極SC1との間に書込み放電が発生する。書込み放電が発生した放電セルの走査電極SC1上には正の壁電圧が蓄積される。書込み放電が発生した放電セルの維持電極SU1上には負の壁電圧が蓄積される。書込み放電が発生した放電セルのデータ電極Dk上には負の壁電圧が蓄積される。
続く維持期間では、走査電極SC1~SCnには第1の電圧として正の維持パルス電圧Vs(V)が印加される。維持電極SU1~SUnには第2の電圧として接地電位、すなわち0(V)が印加される。このとき書込み放電が発生した放電セルにおいては、走査電極SCi上と維持電極SUi上との間の電圧は維持パルス電圧Vs(V)に走査電極SCi上の壁電圧と維持電極SUi上の壁電圧とが加算されたものとなり、放電開始電圧を超える。そして、走査電極SCiと維持電極SUiとの間に維持放電が発生する。維持放電により発生した紫外線により蛍光体層が励起されて発光する。そして走査電極SCi上に負の壁電圧が蓄積される。維持電極SUi上に正の壁電圧が蓄積される。データ電極Dk上には正の壁電圧が蓄積される。
選択初期化動作を行うSF2の初期化期間では、維持電極SU1~SUnに電圧Ve1が印加される。データ電極D1~Dmに電圧0(V)が印加される。走査電極SC1~SCnには電圧Vi4に向かって緩やかに下降する傾斜波形電圧が印加される。すると直前のサブフィールドであるSF1で維持放電を起こした放電セルでは微弱な初期化放電が発生し、走査電極SCi上および維持電極SUi上の壁電圧が弱められる。またデータ電極Dkに対しては、直前の維持放電によってデータ電極Dk上に十分な正の壁電圧が蓄積されている。壁電圧の過剰な部分が放電されることにより、書込み動作に適した壁電圧に調整される。一方、前のサブフィールドで維持放電を起こさなかった放電セルについては放電することはなく、前のサブフィールドの初期化期間終了時における壁電圧が保たれる。選択初期化動作は、直前のサブフィールドの書込み期間で書込み動作を行った放電セル、したがって維持期間で維持動作を行った放電セルに対して選択的に初期化放電を行う動作である。
図5に示すように、本実施の形態においては立体画像を表示するために、フィールド周波数は通常の2倍の120Hzに設定されている。さらに、右目用フィールドと左目用フィールドとが交互に配置される。
図6に示すように、表示すべき階調とそのときのサブフィールドの書込み動作の有無との関係(以下、コーディングと称する)において、「1」は書込み動作が行われることを示す。「0」は書込み動作が行われないことを示す。
[4-1.前面板2の製造方法]
フォトリソグラフィ法によって、前面ガラス基板3上に、走査電極4および維持電極5とブラックストライプ7とが形成される。図8に示すように、走査電極4および維持電極5は、導電性を確保するための銀(Ag)を含む金属バス電極4b、5bを有する。また、走査電極4および維持電極5は、透明電極4a、5aを有する。金属バス電極4bは、透明電極4aに積層される。金属バス電極5bは、透明電極5aに積層される。
フォトリソグラフィ法によって、背面ガラス基板11上に、データ電極12が形成される。データ電極12の材料には、導電性を確保するための銀(Ag)と銀を結着させるためのガラスフリットと感光性樹脂と溶剤などを含むデータ電極ペーストが用いられる。まず、スクリーン印刷法などによって、データ電極ペーストが所定の厚みで背面ガラス基板11上に塗布される。次に、乾燥炉によって、データ電極ペースト中の溶剤が除去される。次に、所定のパターンのフォトマスクを介して、データ電極ペーストが露光される。次に、データ電極ペーストが現像され、データ電極パターンが形成される。最後に、焼成炉によって、データ電極パターンが所定の温度で焼成される。つまり、データ電極パターン中の感光性樹脂が除去される。また、データ電極パターン中のガラスフリットが溶融する。溶融したガラスフリットは、焼成後に再びガラス化する。以上の工程によって、データ電極12が形成される。ここで、データ電極ペーストをスクリーン印刷する方法以外にも、スパッタ法、蒸着法などを用いることができる。
次に、前面板2と、背面板10とが組み立てられる。まず、ディスペンス法によって、背面板10の周囲に封着材(図示せず)が形成される。封着材(図示せず)の材料には、ガラスフリットとバインダと溶剤などを含む封着ペーストが用いられる。次に乾燥炉によって、封着ペースト中の溶剤が除去される。次に、表示電極6とデータ電極12とが直交するように、前面板2と背面板10とが対向配置される。次に、前面板2と背面板10の周囲がガラスフリットで封着される。最後に、放電空間16にNe、Xeなどを含む放電ガスが封入されることによりPDP1が完成する。
誘電体材料は、以下の成分を含む。酸化ビスマス(Bi2O3)が20重量%~40重量%、酸化カルシウム(CaO)、酸化ストロンチウム(SrO)、酸化バリウム(BaO)から選ばれる少なくとも1種が0.5重量%~12重量%、酸化モリブデン(MoO3)、酸化タングステン(WO3)、酸化セリウム(CeO2)、二酸化マンガン(MnO2)から選ばれる少なくとも1種が0.1重量%~7重量%、酸化亜鉛(ZnO)が0重量%~40重量%、酸化硼素(B2O3)が0重量%~35重量%、二酸化硅素(SiO2)が0重量%~15重量%、酸化アルミニウム(Al2O3)が0重量%~10重量%である。誘電体材料は、実質的に鉛成分を含まない。
保護層には、主に4つの機能がある。1つめは、放電によるイオン衝撃から誘電体層を保護することである。2つめは、アドレス放電を発生させるための初期電子を放出することである。3つめは、放電を発生させるための電荷を保持することである。4つめは、維持放電の際に二次電子を放出することである。イオン衝撃から誘電体層が保護されることにより、放電電圧の上昇が抑制される。初期電子放出数が増加することにより、画像のちらつきの原因となるアドレス放電ミスが低減される。電荷保持性能が向上することにより、印加電圧が低減される。二次電子放出数が増加することにより、維持放電電圧が低減される。初期電子放出数を増加させるために、たとえば保護層のMgOに珪素(Si)やアルミニウム(Al)を添加するなどの試みが行われている。
図9に示すように、保護層9は、下地層である下地膜91と第1の粒子である凝集粒子92と第2の粒子である結晶粒子93とを含む。下地膜91は、一例として、アルミニウム(Al)を不純物として含有する酸化マグネシウム(MgO)膜である。凝集粒子92は、MgOの結晶粒子92aに、結晶粒子92aより粒径の小さい結晶粒子92bが複数個凝集したものである。結晶粒子93は、MgOからなる立方体形状の結晶粒子である。形状は走査型電子顕微鏡(SEM)によって確認することができる。本実施の形態においては、複数個の凝集粒子92が、下地膜91の全面に亘って分散配置されている。複数個の結晶粒子93が、下地膜91の全面に亘って分散配置されている。
凝集粒子92とは、図11に示すように、所定の一次粒径の結晶粒子92a、92bが複数個凝集した状態のものである。あるいは、凝集粒子92は、所定の一次粒径の結晶粒子92aが複数個凝集した状態のものである。凝集粒子92は、固体として強い結合力によって結合しているのではない。凝集粒子92は、静電気やファンデルワールス力などによって複数の一次粒子が集合したものである。また、凝集粒子92は、超音波などの外力により、その一部または全部が一次粒子の状態に分解する程度の力で結合している。凝集粒子92の粒径としては、約1μm程度のもので、結晶粒子92a、92bとしては、14面体や12面体などの7面以上の面を持つ多面体形状を有する。また、結晶粒子92a、92bは、炭酸マグネシウムや水酸化マグネシウムなどのMgO前駆体の溶液を焼成することにより生成する液相法により作製された。液相法による焼成温度や焼成雰囲気を調整することにより、粒径の制御ができる。焼成温度は700℃程度から1500℃程度の範囲で選択できる。焼成温度が1000℃以上では、一次粒径を0.3~2μm程度に制御可能である。結晶粒子92a、92bは液相法による生成過程において、複数個の一次粒子同士が凝集した凝集粒子92の状態で得られる。
[7-1.試作品の構成]
まず、構成の異なる保護層を有する複数のPDPが試作された。
これらの5種類の保護層の構成を有するPDPについて、電子放出性能と電荷保持性能が測定された。
図19に示すように、誘電体層8を形成する誘電体層形成工程A1を行った後、下地膜蒸着工程A2では、Alを含むMgOの焼結体を原材料とした真空蒸着法によって、不純物としてAlを含むMgOからなる下地膜91が誘電体層8上に形成される。
本実施の形態にかかる第1のプラズマディスプレイ装置100は、はサブフィールド駆動法により画像の階調表示を行うPDP1を備える。PDP1は、前面板2と、前面板2と対向配置された背面板10と、を有する。前面板2は、表示電極6と表示電極6を覆う誘電体層8と誘電体層8を覆う保護層9とを有する。保護層9は、誘電体層8上に形成された下地層である下地膜91および下地膜91の全面に亘って分散配置された複数の凝集粒子92を含む。凝集粒子92は、複数の凝集した金属酸化物の結晶粒子92aからなる。さらに、プラズマディスプレイ装置100は、右目用画像信号を表示する右目用フィールドおよび左目用画像信号を表示する左目用フィールドによって画像を構成する。右目用フィールドおよび左目用フィールドは、複数のサブフィールドを有する。所定の階調以上において、右目用フィールドおよび左目用フィールドにおける最後に配置されたサブフィールドを除く、少なくとも一つ以上のサブフィールドにより階調が表示される。
2 前面板
3 前面ガラス基板
4 走査電極
4a,5a 透明電極
4b,5b 金属バス電極
5 維持電極
6 表示電極
7 ブラックストライプ
8 誘電体層
9 保護層
10 背面板
11 背面ガラス基板
12 データ電極
13 下地誘電体層
14 隔壁
15 蛍光体層
16 放電空間
21 画像信号処理回路
22 データ電極駆動回路
23 走査電極駆動回路
24 維持電極駆動回路
25 タイミング発生回路
91 下地膜
92 凝集粒子
92a,92b,93 結晶粒子
100 プラズマディスプレイ装置
Claims (6)
- サブフィールド駆動法により画像の階調表示を行うプラズマディスプレイパネルを備え、
前記プラズマディスプレイパネルは、前面板と、前記前面板と対向配置された背面板と、を有し、前記前面板は、表示電極と前記表示電極を覆う誘電体層と前記誘電体層を覆う保護層とを有し、前記保護層は、前記誘電体層上に形成された下地層および前記下地層の全面に亘って分散配置した複数の凝集粒子を含み、前記凝集粒子は、複数の凝集した金属酸化物結晶粒子からなり、
さらに、右目用画像信号を表示する右目用フィールドおよび左目用画像信号を表示する左目用フィールドによって画像を構成し、
前記右目用フィールドおよび前記左目用フィールドは、複数のサブフィールドを有し、
所定の階調以上において、前記右目用フィールドおよび前記左目用フィールドにおける最後に配置されたサブフィールドを除く、少なくとも一つ以上のサブフィールドにより階調が表示される、
プラズマディスプレイ装置。 - サブフィールド駆動法により画像の階調表示を行うプラズマディスプレイパネルを備え、
前記プラズマディスプレイパネルは、前面板と、前記前面板と対向配置された背面板と、を有し、前記前面板は、表示電極と前記表示電極を覆う誘電体層と前記誘電体層を覆う保護層とを有し、前記保護層は、前記誘電体層上に形成された下地層と、前記下地層の全面に亘って分散配置した複数個の第1の粒子と、前記下地層の全面に亘って分散配置した複数個の第2の粒子と、を含み、前記第1の粒子は、金属酸化物結晶粒子が複数個凝集した凝集粒子であり、
前記第2の粒子は、酸化マグネシウムからなる立方体形状の結晶粒子であり、
さらに、右目用画像信号を表示する右目用フィールドおよび左目用画像信号を表示する左目用フィールドによって画像を構成し、
前記右目用フィールドおよび前記左目用フィールドは、複数のサブフィールドを有し、
所定の階調以上において、前記右目用フィールドおよび前記左目用フィールドにおける最後に配置されたサブフィールドを除く、少なくとも一つ以上のサブフィールドにより階調が表示される、
プラズマディスプレイ装置。 - 前記サブフィールドは、発光させる放電セルを選択する書込み放電を発生させる書込み期間と、前記書込み放電により選択された放電セルに維持放電を発生させる維持期間とを有し、
前記所定の階調以上を表示する場合は前記右目用フィールドおよび前記左目用フィールドの最後に配置されたサブフィールドの書込み放電を発生させない、
請求項1または2のいずれか一項に記載のプラズマディスプレイ装置。 - 前記凝集粒子の平均粒径は0.9μm以上2.0μm以下である、
請求項1または2のいずれか一項に記載のプラズマディスプレイ装置。 - 前記金属酸化物結晶粒子は、7面以上の面を有する多面体形状である、
請求項1または2のいずれか一項に記載のプラズマディスプレイ装置。 - 前記下地層は、酸化マグネシウムを含む、
請求項1または2のいずれか一項に記載のプラズマディスプレイ装置。
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CN102667901A (zh) * | 2010-04-23 | 2012-09-12 | 松下电器产业株式会社 | 等离子显示装置的驱动方法、等离子显示装置及等离子显示系统 |
KR20120114390A (ko) * | 2010-04-23 | 2012-10-16 | 파나소닉 주식회사 | 플라즈마 디스플레이 장치의 구동 방법, 플라즈마 디스플레이 장치 및 플라즈마 디스플레이 시스템 |
KR101871549B1 (ko) * | 2014-10-29 | 2018-07-03 | 삼성에스디아이 주식회사 | 디스플레이 밀봉재용 조성물, 이를 포함하는 유기보호층, 및 이를 포함하는 디스플레이 장치 |
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JPWO2011114647A1 (ja) | 2013-06-27 |
CN102449683A (zh) | 2012-05-09 |
JP5240401B2 (ja) | 2013-07-17 |
KR101238565B1 (ko) | 2013-02-28 |
KR20120024701A (ko) | 2012-03-14 |
US20120086736A1 (en) | 2012-04-12 |
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