WO2011105072A1 - Substrate treating method and substrate treating apparatus - Google Patents

Substrate treating method and substrate treating apparatus Download PDF

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Publication number
WO2011105072A1
WO2011105072A1 PCT/JP2011/001025 JP2011001025W WO2011105072A1 WO 2011105072 A1 WO2011105072 A1 WO 2011105072A1 JP 2011001025 W JP2011001025 W JP 2011001025W WO 2011105072 A1 WO2011105072 A1 WO 2011105072A1
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Prior art keywords
substrate
substrate processing
solution
tank
processing solution
Prior art date
Application number
PCT/JP2011/001025
Other languages
French (fr)
Japanese (ja)
Inventor
牧野 夏木
加藤 正明
近藤 正芳
Original Assignee
住友ベークライト株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Priority claimed from JP2010038469A external-priority patent/JP2011176085A/en
Priority claimed from JP2010132902A external-priority patent/JP2011256444A/en
Priority claimed from JP2010227118A external-priority patent/JP5488384B2/en
Priority claimed from JP2010227121A external-priority patent/JP2012082448A/en
Priority claimed from JP2010227120A external-priority patent/JP2012082447A/en
Application filed by 住友ベークライト株式会社 filed Critical 住友ベークライト株式会社
Publication of WO2011105072A1 publication Critical patent/WO2011105072A1/en

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/02Tanks; Installations therefor
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1617Purification and regeneration of coating baths
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1619Apparatus for electroless plating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1619Apparatus for electroless plating
    • C23C18/1628Specific elements or parts of the apparatus
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1619Apparatus for electroless plating
    • C23C18/1628Specific elements or parts of the apparatus
    • C23C18/163Supporting devices for articles to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1655Process features
    • C23C18/1664Process features with additional means during the plating process
    • C23C18/1669Agitation, e.g. air introduction
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1675Process conditions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/08Apparatus, e.g. for photomechanical printing surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/06Suspending or supporting devices for articles to be coated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/10Agitating of electrolytes; Moving of racks
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/16Regeneration of process solutions
    • C25D21/18Regeneration of process solutions of electrolytes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/08Electroplating with moving electrolyte e.g. jet electroplating
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/0085Apparatus for treatments of printed circuits with liquids not provided for in groups H05K3/02 - H05K3/46; conveyors and holding means therefor
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/40Forming printed elements for providing electric connections to or between printed circuits
    • H05K3/42Plated through-holes or plated via connections
    • H05K3/425Plated through-holes or plated via connections characterised by the sequence of steps for plating the through-holes or via connections in relation to the conductive pattern
    • H05K3/427Plated through-holes or plated via connections characterised by the sequence of steps for plating the through-holes or via connections in relation to the conductive pattern initial plating of through-holes in metal-clad substrates

Definitions

  • the present invention relates to a substrate processing method and a substrate processing apparatus for processing a substrate such as a printed wiring board with a substrate processing solution.
  • circuit boards are manufactured as follows. A double-sided copper-clad laminate with copper foil attached to both sides of the substrate is prepared. Via holes are formed in the double-sided copper-clad laminate, and plating is further performed on the via holes and the double-sided copper-clad laminate. Thereafter, the double-sided copper-clad laminate is processed to form a circuit (Patent Document 1).
  • a substrate such as a printed wiring board may be treated with a substrate treatment solution.
  • a substrate treatment solution when it is desired to process only the substrate processing region on one surface of the substrate, for example, the other surface that is not processed is sealed with a substrate support jig or the like, and the periphery of the substrate processing region that is not processed is sealed with a sealing material. .
  • Patent Documents 2 and 3 there are various proposals for the substrate processing apparatus as described above.
  • the double-sided copper-clad laminate is immersed in a plating solution when performing plating.
  • a plating solution when performing plating.
  • Possible causes for the failure to obtain the desired plating film include retention of the plating solution and adhesion of foreign matter.
  • the double-sided copper-clad laminate is immersed in the plating solution as described above.
  • this manufacturing method it has been difficult to stably obtain a desired plating film in the via hole.
  • the subject that a desired process cannot be implemented in a via hole arises not only when performing plating but also when the double-sided copper-clad laminate is immersed in water and washed.
  • sealing the other surface of the substrate that is not processed with a substrate support jig or the like, and sealing the periphery of the substrate processing region that is not processed with a sealing material are complicated and produce semiconductor circuits. Will reduce the sex.
  • a first substrate processing method of the present invention is a substrate processing method in which a substrate processing solution is brought into contact with a substrate for processing, and the substrate surface is parallel to the vertical direction or tilted with respect to the vertical direction.
  • the substrate processing solution in the tank is allowed to flow along the substrate surface from the upper side in the vertical direction toward the lower side in a state where the substrate is immersed in the substrate processing solution in the tank. Accordingly, the substrate processing solution is prevented from staying near the substrate surface, and desired processing can be stably performed on the substrate. Furthermore, in the present invention, the substrate processing solution in the tank flows from the upper side in the vertical direction toward the lower side. Since the substrate processing solution flows according to gravity, the substrate processing solution can flow smoothly. Moreover, in this invention, the foreign material in a substrate processing solution can be discharged
  • the first substrate processing apparatus of the present invention is a substrate processing apparatus for processing by bringing a substrate processing solution into contact with a substrate, and the substrate processing solution is supplied to the inside and the substrate is immersed in the supplied substrate processing solution.
  • the substrate processing solution discharge port of the tank is vertically lower than the substrate held by the holding unit, and is vertically lower than the substrate held by the holding unit, and the substrate processing solution is transferred from the tank supply port to the discharge port.
  • the substrate processing solution is configured to flow along the substrate surface from the upper side in the vertical direction toward the lower side.
  • a substrate processing method and a substrate processing apparatus capable of stably performing a desired process are provided.
  • a substrate processing solution is brought into contact with a through hole of a substrate in which a through hole penetrating from one substrate surface side to the other substrate surface side is formed.
  • a substrate processing method for processing which is a tank to which a substrate processing solution is supplied, and prepares a tank that includes a partition that holds a substrate and partitions the tank into a first tank and a second tank together with the held substrate.
  • the average flow velocity of the substrate processing solution flowing along one substrate surface of the substrate is different from the average flow velocity of the substrate processing solution flowing along the other substrate surface of the substrate. Therefore, the substrate processing solution is drawn into the through hole. Therefore, the inside of the through hole can be reliably processed with the substrate processing solution.
  • the second substrate processing apparatus of the present invention contacts the substrate processing solution in the through hole of the substrate in which the through hole penetrating from one substrate surface side to the other substrate surface side is formed.
  • a substrate processing apparatus for processing a substrate a substrate processing solution is supplied inside, the substrate is immersed in the supplied substrate processing solution, the substrate is held, and the tank is held together with the held substrate, the first tank and the second tank.
  • a tank provided with a partition partitioning into two tanks, and a supply means for supplying a substrate processing solution into each of the first tank and the second tank of the tank, and the substrate processing apparatus is provided with the substrate processing supplied from the supply means
  • the solution flows along one substrate surface and the other substrate surface of the substrate, and is configured to contact the through hole of the substrate, and the average flow rate of the substrate processing solution flowing along one substrate surface of the substrate;
  • On the other side of the board Having adjustment means for varying the average flow velocity of the substrate processing solution flowing through me.
  • a processing method and a processing apparatus capable of performing a desired processing in the through hole.
  • a third substrate processing apparatus of the present invention includes a box-shaped substrate holding member in which an opening hole for exposing a substrate processing region on one surface of the substrate is formed on one surface and an insertion port is formed on the upper surface, and a substrate holding And an expandable / contractible member that is disposed inside the other surface of the member and presses the inserted substrate against the inner peripheral surface of the opening hole.
  • an opening hole is formed in one surface of the box-shaped substrate holding member to expose the substrate processing region on one surface of the substrate, and an insertion port is formed in the upper surface.
  • a substrate disposed inside the substrate holding member is brought into contact with the inner surface of the substrate holding member so that the substrate processing region is exposed to the opening hole.
  • the substrate processing solution can be supplied only to the substrate processing region by immersing the substrate holding member on which the substrate is set in this manner in the substrate processing solution in the substrate processing region accommodated in the solution holding container.
  • the substrate processing solution is supplied only to the substrate processing region by immersing the substrate holding member on which the substrate is set in the substrate processing solution in the substrate processing region accommodated in the solution holding container. can do. Therefore, only the substrate processing region on one surface of the substrate can be processed easily and quickly with the substrate processing solution.
  • a fourth substrate processing apparatus of the present invention includes a solution holding container that contains a substrate processing solution and in which the substrate is immersed, and a solution supply mechanism that sequentially supplies the substrate holding solution by dropping it from above to the solution holding container. And a solution turbulence mechanism that pumps the substrate processing solution falling downward from above to the substrate processing region on one surface of the substrate.
  • the substrate is immersed in the substrate processing solution contained in the solution holding container.
  • the solution supply mechanism sequentially supplies the substrate processing solution by dropping the substrate processing solution from above to the solution holding container.
  • the solution turbulence mechanism pumps the substrate processing solution falling downward from above to the substrate processing region on one surface of the substrate. For this reason, the substrate processing region on one surface of the substrate is not only simply dropped from the upper side to the lower side, but is also pumped as a turbulent flow.
  • the substrate processing solution on one surface of the substrate is not only simply dropped from the upper side to the lower side, but is also pumped as a turbulent flow. Therefore, the substrate processing region on one surface of the substrate is satisfactorily processed by the turbulent substrate processing solution.
  • the substrate is immersed in a substrate processing solution contained in a solution holding container, the substrate processing solution is dropped into the solution holding container from the top to the bottom, and sequentially supplied, and from above to below.
  • the substrate processing solution falling on the substrate is pumped to the substrate.
  • the fifth substrate processing apparatus of the present invention includes a solution holding container that contains a substrate processing solution and in which the substrate is immersed, and a solution that pumps and sucks the substrate processing solution to the substrate processing region on one surface of the immersed substrate.
  • a turbulent flow mechanism is included in the solution holding container that contains a substrate processing solution and in which the substrate is immersed, and a solution that pumps and sucks the substrate processing solution to the substrate processing region on one surface of the immersed substrate.
  • the substrate is immersed in the substrate processing solution contained in the solution holding container.
  • the solution supply mechanism pumps and sucks the substrate processing solution into the substrate processing region in such a state. For this reason, the substrate processing region on one surface of the substrate is processed by the substrate processing solution that is pumped and sucked.
  • the substrate processing region on one surface of the substrate is processed by the substrate processing solution that is pumped and sucked. For this reason, it is possible to easily and quickly process only the substrate processing region on one surface of the substrate with the substrate processing solution that becomes a turbulent flow.
  • the substrate holding member is immersed in the substrate processing solution accommodated in the solution holding container, and the substrate processing solution is pumped and sucked to one surface of the immersed substrate processing region.
  • the various components of the present invention do not necessarily have to be independent of each other.
  • a plurality of components are formed as a single member, and a single component is formed of a plurality of members. It may be that a certain component is a part of another component, a part of a certain component overlaps with a part of another component, or the like.
  • the vertical direction referred to in the present invention does not have to be perfectly geometrically vertical, and may be inclined in an arbitrary direction, for example.
  • FIG. 1 is a schematic exploded perspective view showing a substrate processing apparatus according to an embodiment of the present invention. It is a typical vertical side view which shows the internal structure of a substrate processing apparatus. It is a typical front view which shows the structure of the substrate holding member of a substrate processing apparatus. It is process drawing which shows the process of setting a board
  • the processing apparatus 1 is an apparatus that processes the substrate PB by bringing the substrate processing solution TL into contact with the substrate PB.
  • the substrate processing solution TL is supplied to the inside of the processing apparatus 1, and the substrate 11 in which the substrate PB is immersed in the supplied substrate processing solution TL, and the substrate surface of the substrate PB disposed in the tank 11 are in the vertical direction.
  • a holding portion 13 for holding the substrate PB so as to be substantially parallel to.
  • the substrate processing solution TL supply port 111 in the tank 11 is vertically above the substrate PB held by the holding unit 13, and the substrate processing solution TL discharge port 112 in the tank 11 is held by the holding unit 13. It is below the substrate PB in the vertical direction.
  • the processing apparatus 1 flows the substrate processing solution TL from the supply port 111 of the tank 11 toward the discharge port 112, the substrate processing solution TL flows along the substrate surface from the upper side in the vertical direction toward the lower side. It is configured.
  • the substrate processing solution TL is a chemical solution, in this embodiment, an electrolytic plating solution TL. That is, the processing apparatus 1 is an electrolytic plating apparatus in this embodiment.
  • the tank 11 is, for example, a hard PVC tank.
  • the tank 11 is supplied with an electrolytic plating solution TL.
  • a supply port 111 for the electrolytic plating solution TL is formed on the side surface of the tank 11.
  • the supply port 111 is positioned above the substrate PB arranged in the tank 11 in the vertical direction.
  • a discharge port 112 for the electrolytic plating solution TL is formed on the bottom surface of the tank 11. In the present embodiment, a plurality of discharge ports 112 are formed on the bottom surface of the tank 11.
  • the electrolytic plating solution TL can be discharged smoothly along the substrate surface of the substrate PB.
  • the number of the discharge ports 112 may be one.
  • the discharge port 112 is located on the lower side in the vertical direction than the substrate PB disposed in the tank 11. Further, the discharge port 112 is located on the lower side in the vertical direction than the supply port 111.
  • the piping 17 and the pump P2 are connected to the discharge port 112 as needed, and the electroplating discharged from the discharge port 112 by sucking the electrolytic plating solution TL with the pump P2. The flow rate of the liquid TL may be adjusted.
  • the discharge port 112 and the second tank 14 are not connected by piping, and the electrolytic plating solution TL discharged from the discharge port 112 naturally falls into the second tank 14.
  • a plug that blocks a part of the discharge ports 112 may be provided as the adjusting means, and an adjusting unit that adjusts the size of the discharge ports 112 (for example, a part of the discharge ports 112 is blocked to A plate member for adjusting the degree of opening may be provided.
  • one substrate PB is disposed in the tank 11 when performing electrolytic plating.
  • a plurality of anodes 12 are installed in the tank 11.
  • two anodes 12 are installed.
  • One anode 12 is disposed to face one substrate surface of the substrate PB disposed in the tank 11, and the other anode 12 is opposed to the other substrate surface of the substrate PB disposed in the tank 11.
  • the anode 12 is, for example, phosphorous copper.
  • the holding unit 13 holds the substrate PB and connects the metal film 22 (see FIG. 4B) on the surface of the substrate PB to a cathode (not shown).
  • the holding unit 13 includes, for example, a clamping unit that sandwiches the upper end of the substrate PB, and is made of a conductive material such as metal.
  • the holding unit 13 holds the substrate PB and can be driven in the vertical direction, and arranges the substrate PB in the tank 11 or removes the substrate PB from the tank 11.
  • maintenance part 13 will be arrange
  • the processing apparatus 1 includes a second tank (conditioning tank) 14 that is filled with an electrolytic plating solution TL to be supplied to the tank 11. Since the second tank 14 also serves to receive the electrolytic plating solution TL that has overflowed from the tank 11, the second tank 14 is disposed on the lower side in the vertical direction of the tank 11.
  • a bubbling device 15 may be connected to the second tank 14 in order to stir the electrolytic plating solution TL in the second tank 14. By doing in this way, the density
  • the bubbling device 15 may be provided in the processing device 1 shown in FIG.
  • the discharge port of the electrolytic plating solution in the second tank 14 and the supply port 111 of the tank 11 are connected by a pipe 16.
  • the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 via the pipe 16 and the pump P1 connected to the pipe 16.
  • the pipe 16 is provided with a filter (not shown). Foreign matter in the electrolytic plating solution TL passing through the pipe 16 can be removed with a filter.
  • the base material 20 includes an insulating layer 21 and a metal film 22 (for example, a copper film) attached to the front and back surfaces of the insulating layer 21.
  • the thickness of the insulating layer 21 is, for example, 5 ⁇ m or more and 100 ⁇ m or less, and the thickness of the metal film 22 is, for example, 1 ⁇ m or more and 50 ⁇ m or less.
  • the thickness of the whole base material 20 is 10 micrometers or more and 200 micrometers or less, for example.
  • the thickness of the base material 20 is not limited to the above, For example, 600 micrometers etc. are possible.
  • a hole 201 penetrating one metal film 22 and the insulating layer 21 is formed.
  • the hole penetrating one metal film 22 may be formed by etching, and then the hole penetrating the insulating layer 21 may be formed by laser.
  • electroless plating is performed on the metal film 22 and inside the hole 201. Thereby, the substrate PB is obtained.
  • a mask M covering a part of the metal film 22 is disposed on the substrate PB, and electrolytic plating is performed on the inside of the hole 201 and on the metal film 22 using the processing apparatus 1 (see FIG. 5A).
  • the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 through the pipe 16 and the pump P1.
  • the tank 11 is filled with the electrolytic plating solution TL.
  • the substrate PB is held by the holding unit 13, the substrate PB is placed in the tank 11, and the substrate PB is immersed in the electrolytic plating solution TL.
  • the substrate PB is disposed in the tank 11 so that the substrate surface of the substrate PB is substantially parallel to the vertical direction.
  • electroplating on the substrate PB is started by energizing between the cathode (not shown) and the anode 12.
  • the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 as needed.
  • the electrolytic plating solution TL in the tank 11 flows from the upper side in the vertical direction toward the lower side in the vertical direction (see arrow Y1).
  • the electrolytic plating solution TL flowing from the upper side in the vertical direction toward the lower side in the vertical direction flows along the pair of substrate surfaces of the substrate PB, and is also supplied into the holes 201. Further, during the electrolytic plating, the entire substrate PB is immersed in the electrolytic plating solution TL.
  • the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 at any time, and the supply amount of the electrolytic plating solution TL from the second tank 14 to the tank 11 is discharged from the tank 11. More than the amount of electrolytic plating solution TL applied. Therefore, the electrolytic plating solution TL overflows from the upper part of the tank 11. The overflowed electrolytic plating solution TL flows in the direction of the arrow Y2 and is collected in the second tank 14. Further, the electrolytic plating solution TL is supplied to the second tank 14 from the discharge port 112 of the tank 11. The electrolytic plating solution TL in the second tank 14 is supplied again to the tank 11 via the pipe 16 and the pump P1. If necessary, the metal concentration or the like of the electrolytic plating solution TL in the second tank 14 may be analyzed to adjust the metal concentration or the like of the electrolytic plating solution TL in the second tank 14.
  • the conductor 26 serving as a via is formed in the hole 201 and the metal film by electrolytic plating is formed on the metal film 22.
  • the metal film 23 indicates a metal film 22 and a plating film on the metal film 22).
  • the substrate PB that has been subjected to electrolytic plating is taken out of the tank 11 and cleaned. Thereafter, the portion of the metal film 22 on which the mask M has been formed is removed by flash etching, and a first circuit layer 25 and a second circuit layer 24 are formed as shown in FIG.
  • the flexible circuit board PB7 obtained by subjecting the substrate PB to electrolytic plating can be obtained.
  • the substrate surface of the substrate PB is moved from the upper side in the vertical direction toward the lower side while the substrate PB is immersed in the electrolytic plating solution TL in the bath 11. It is flowing along.
  • the electrolytic plating solution TL is prevented from staying near the surface of the substrate PB, and the fresh electrolytic plating solution TL always comes into contact with the substrate PB. Thereby, a desired plating film can be stably formed on the substrate PB.
  • the electrolytic plating solution TL in the tank 11 flows from the upper side in the vertical direction toward the lower side. Since the electroplating solution TL flows according to gravity, the electroplating solution TL can flow smoothly. Moreover, the flow of the electrolytic plating solution TL is stabilized by flowing the electrolytic plating solution TL according to gravity. Furthermore, by flowing the electrolytic plating solution TL from the upper side in the vertical direction toward the lower side according to gravity, it is possible to suppress complication of the apparatus configuration of the processing apparatus 1. Even when the pump P2 for discharging the electrolytic plating solution TL from the tank 11 as shown in FIG. 2 is used, the electrolytic plating from the tank 11 can be performed without using the pump P2 as a pump having a relatively large suction force. The liquid TL can be discharged.
  • the electrolytic plating solution TL in the tank 11 is immersed in the electrolytic plating solution TL in the tank 11 from the upper side in the vertical direction toward the lower side. It flows along the substrate surface and is discharged. Thereby, even if foreign matter is mixed in the electrolytic plating solution TL, the foreign matter can be discharged from the tank 11. Therefore, it can suppress that a foreign material adheres to the board
  • the substrate PB is a substrate for a flexible circuit board, and the thickness thereof is relatively thin, 10 to 200 ⁇ m.
  • the substrate PB will fluctuate in the electroplating solution TL. Therefore, it may be difficult to perform desired electrolytic plating on the substrate PB when the substrate PB approaches or separates from the anode.
  • the electrolytic plating solution TL is allowed to flow while the substrate PB is immersed in the electrolytic plating solution TL.
  • the substrate PB Since the electrolytic plating solution TL flows from the upper side in the vertical direction toward the lower side on the one substrate surface side and the other substrate surface side of the substrate PB, the substrate PB is prevented from fluctuating in the electrolytic plating solution TL. The Thereby, desired electroplating can be performed with respect to the board
  • electrolytic plating is performed by overflowing the electrolytic plating solution TL from the tank 11. By making it overflow, electrolytic plating can be applied to the substrate PB while reliably maintaining the state in which the substrate PB is immersed in the electrolytic plating solution TL.
  • the tank 11 may have a size that allows the substrate PB to be disposed and allows the electrolytic plating solution TL to flow on the substrate surface side of the substrate PB. Thereby, the enlargement of the processing apparatus 1 can be suppressed.
  • the substrate processing apparatus of the present invention is the electroplating apparatus 1, but is not limited thereto.
  • the anode of the processing apparatus 1 may be removed, and the substrate processing apparatus of the present invention may be an electroless plating apparatus 1A.
  • the processing apparatus 1A shown in FIG. 6 is the same as the processing apparatus 1 except that the anode is removed from the processing apparatus 1.
  • the second tank 14 and the tank 11 are filled with an electroless plating solution TL. Further, the processing apparatus 1A shown in FIG.
  • the processing apparatus 1A may be a developing device.
  • the photosensitive resin layer on the substrate surface is irradiated with light, and a developing solution for removing unexposed portions is filled into the second tank 14 and the tank 11, and the photosensitive resin layer on the substrate surface is uncoated by the processing apparatus 1A.
  • the exposed part may be removed.
  • the processing apparatus 1A may be a peeling apparatus that peels off a mask or the like formed on the substrate. In this case, what is necessary is just to fill the 2nd tank 14 and the tank 11 with the peeling liquid for peeling a mask etc.
  • the substrate processing apparatus of the present invention may be a water washing apparatus 1B.
  • the water washing apparatus 1B has the same configuration as the processing apparatus 1 except that the anode of the processing apparatus 1 is removed and tanks 14A to 14C are provided.
  • the second tank 14A of the water washing apparatus 1B is filled with water before substrate cleaning. Water is supplied from the second tank 14A to the tank 11, and the water flows in the tank 11 from the upper side to the lower side in the vertical direction, and the substrate PB is cleaned. Thereafter, the washed water is discharged from the discharge port 112 and supplied to the third tank 14B.
  • the water in the third tank 14B is supplied to the fourth tank (purification tank) 14C, and the water is purified in the fourth tank 14C to remove impurities such as metals.
  • the water cleaned in the fourth tank 14C is supplied to the second tank 14A.
  • the water supplied to the second tank 14A will be supplied to the tank 11 again.
  • clean water always comes into contact with the substrate PB, and the substrate PB can be prevented from being contaminated.
  • the water washing apparatus 1B clean water always comes into contact with the substrate PB, so there is no need to perform water washing in multiple stages, and the processing process of the substrate PB can be simplified.
  • the water in the third tank 14B may be discarded without being purified in the fourth tank 14C.
  • the piping 17 and the pump P2 may be connected to the discharge port 112 as in FIG.
  • the opening of the tank 11 of the processing apparatus 1 ⁇ / b> A is closed with a lid 18 (pressurizing means), and the liquid in the tank 11 is pressurized from above and discharged from the discharge port.
  • the flow rate of the substrate processing solution TL may be adjusted.
  • the substrate PB is held by the holding unit 13B.
  • the opening of the tank 11 is closed with a lid member, and the substrate processing solution in the tank 11 is pressurized from above to apply the substrate processing solution discharged from the discharge port.
  • the flow rate may be adjusted.
  • the piping 17 and the pump P2 may be connected to the discharge port 112 as in FIG.
  • vibration when the substrate processing solution TL flows along the substrate surface from the upper side of the substrate to the lower side
  • vibration during the processing of the substrate PB on the substrate PB in the processing apparatus 1 ⁇ / b> A ( Ultrasonic vibration) may be added.
  • Reference numeral 19 denotes an ultrasonic vibration generator, and an arrow Y3 means an ultrasonic wave from the ultrasonic vibration generator. By doing so, bubbles attached to the substrate PB can be removed.
  • the piping 17 and the pump P2 may be connected to the discharge port 112 as in FIG. Note that the ultrasonic vibration generator 19 may also be provided in the processing apparatuses 1 and 1B.
  • substrate PB was arrange
  • the substrates PB may be disposed on the front and back surfaces of the plate-shaped holding portion 13 ⁇ / b> A, respectively, and electrolytic plating may be performed on one substrate surface of each of the pair of substrates PB.
  • the holding unit 13A may be used instead of the holding unit 13, and one of the substrate surfaces of the pair of substrates PB may be subjected to electrolytic plating.
  • substrate PB was used as the board
  • substrate PB was arrange
  • the substrate PB may be arranged so that the substrate surface of the substrate is inclined with respect to the vertical direction. Even when the substrate PB is disposed in an inclined manner as described above, the same effects as those of the embodiment can be obtained.
  • the substrate processing apparatus 2 includes a substrate processing solution TL in the through hole 201 of the substrate PB in which a through hole 201 (see FIG. 15) penetrating from one substrate surface side to the other substrate surface side of the substrate PB is formed.
  • the substrate processing apparatus 2 includes a tank 21 in which the substrate processing solution TL is supplied and the substrate PB is immersed in the supplied substrate processing solution TL.
  • the substrate PB is held so that a pair of substrate surfaces of the substrate PB is substantially parallel to the vertical direction, and the tank 21 is held in the first tank 211 and the second tank 212 together with the held substrate PB.
  • Partition walls 213 are formed.
  • the first supply port 211A of the substrate processing solution in the first tank 211 and the second supply port 212A of the substrate processing solution in the second tank 212 are vertically above the substrate PB held by the partition wall 213,
  • the first discharge port 211B of the substrate processing solution in the first tank 211 and the second discharge port 212B of the substrate processing solution in the second tank 212 are below the substrate PB held by the partition wall 213 in the vertical direction.
  • the substrate substrate processing apparatus 2 allows the substrate processing solution TL to flow from the first supply port 211A toward the first discharge port 211B, and the substrate processing solution from the second supply port 212A toward the second discharge port 212B.
  • the substrate processing solution TL is configured to flow along one substrate surface and the other substrate surface of the substrate PB from the upper side to the lower side in the vertical direction.
  • the substrate processing solution TL is a chemical solution, in this embodiment, an electrolytic plating solution TL. That is, the substrate processing apparatus 2 is an electrolytic plating apparatus in the present embodiment.
  • the tank 21 is, for example, a hard PVC tank, and in the present embodiment, has a rectangular parallelepiped shape or a cubic shape.
  • the tank 21 includes a partition wall 213.
  • the partition wall 213 is erected on the bottom surface of the tank 21 and holds the substrate PB so that the pair of substrate surfaces of the substrate PB is substantially parallel to the vertical direction.
  • the partition wall 213 partitions the tank 21 into the first tank 211 and the second tank 212 together with the held substrate PB.
  • the partition 213 is shown in FIG.
  • FIG. 13 and FIG. 13 is a view as seen from the x-axis direction of FIG. 12, and FIG. 14 is an exploded view of the partition 213.
  • the partition wall 213 includes a pair of plate members 213A.
  • An opening 213A1 is formed at the center of the plate material 213A, and the substrate PB is arranged so as to close the opening 213A1 of the one plate material 213A.
  • the other plate material 213A is overlapped, and the peripheral portion of the substrate PB is sandwiched between the plate materials 213A.
  • a recess (not shown) for fitting the partition wall 213 is formed on the bottom surface of the tank 21.
  • a first supply port 211 ⁇ / b> A for the electrolytic plating solution TL is formed on the side wall of the tank 21.
  • the electrolytic plating solution TL is supplied into the first tank 211 from the first supply port 211A.
  • the first supply port 211A is located above the substrate PB held by the partition wall 213 in the vertical direction.
  • the electrolytic plating solution TL in the first tank 211 flows along the substrate surface of the substrate PB and is discharged from the first discharge port 211B.
  • the first discharge port 211 ⁇ / b> B is formed on the bottom surface of the tank 21, and is positioned below the substrate PB held by the partition wall 213 in the vertical direction.
  • the first outlet 211B may be a single through hole or a plurality of holes.
  • a second supply port 212 ⁇ / b> A for the electrolytic plating solution TL is formed on the side wall of the tank 21.
  • the electrolytic plating solution TL is supplied into the second tank 212 from the second supply port 212A.
  • the second supply port 212A is located above the substrate PB held by the partition wall 213 in the vertical direction.
  • the electrolytic plating solution TL in the first tank 211 flows along the substrate surface of the substrate PB and is discharged from the second discharge port 212B.
  • the second discharge port 212 ⁇ / b> B is formed on the bottom surface of the tank 21, and is positioned below the substrate PB held by the partition wall 213 in the vertical direction.
  • the second discharge port 212B may be a single through hole, or a plurality of second discharge ports may be provided.
  • the 1st discharge port 211B is comprised by one through-hole
  • the 2nd discharge port 212B is comprised by one through-hole.
  • the opening diameter of the first discharge port 211B is larger than the opening diameter of the second discharge port 212B.
  • the discharge ports 211B and 212B and the tank 24 are not connected by piping, and the electrolytic plating solution TL discharged from the discharge ports 211B and 212B naturally falls into the tank 24.
  • anodes 22 are installed in the tank 21.
  • two anodes 22 are installed.
  • One anode 22 is disposed so as to face one substrate surface of the substrate PB disposed in the tank 21, and the other anode 22 is opposed to the other substrate surface of the substrate PB disposed in the tank 21.
  • the anode 22 is, for example, phosphorous copper.
  • the substrate processing apparatus 2 includes a tank (adjustment tank) 14 filled with an electrolytic plating solution TL to be supplied to the tank 21. Since the tank 24 also serves to receive the electrolytic plating solution TL that has overflowed from the tank 21, the tank 24 is disposed on the lower side in the vertical direction of the tank 21. Here, a bubbling device (not shown) may be connected to the tank 24 in order to stir the electrolytic plating solution TL in the tank 24. By doing in this way, the density
  • the tank 24 and the first supply port 211 ⁇ / b> A of the tank 21 are connected by a pipe 26.
  • the electrolytic plating solution TL is supplied from the tank 24 to the tank 21 through the pipe 26 and the pump P1 connected to the pipe 26.
  • the tank 24 and the second supply port 212 ⁇ / b> A of the tank 21 are connected by a pipe 27.
  • the electrolytic plating solution TL is supplied from the tank 24 to the tank 21 via the pipe 27 and the pump P ⁇ b> 2 connected to the pipe 27.
  • the base material 220 includes an insulating layer 221 and a metal film 222 (for example, a copper film) attached to the front and back surfaces of the insulating layer 221.
  • the thickness of the insulating layer 221 is, for example, 5 ⁇ m or more and 100 ⁇ m or less, and the thickness of the metal film 222 is, for example, 1 ⁇ m or more and 50 ⁇ m or less.
  • the entire thickness of the base material 220 is, for example, 10 ⁇ m or more and 200 ⁇ m or less.
  • a through-hole 201 that penetrates the pair of metal films 222 and the insulating layer 221 is formed.
  • electroless plating is performed on the metal film 222 and inside the through hole 201. Thereby, the substrate PB is obtained.
  • Electrolytic plating is performed as follows. First, as shown in FIG. 12, the electrolytic plating solution TL is supplied from the tank 24 to the first tank 211 of the tank 21 through the pipe 26 and the pump P1. Further, the electrolytic plating solution TL is supplied from the tank 24 to the second tank 212 via the pipe 27 and the pump P2, and the inside of the tank 21 is filled with the electrolytic plating solution TL.
  • the electrolytic plating solution TL continues to be supplied to the bath 21 so that the electrolytic plating solution TL overflows from the bath 21 and the inside of the bath 21 is filled with the electrolytic plating solution TL.
  • the substrate PB is held by the partition wall 213, the substrate PB is placed in the tank 21, and the substrate PB is immersed in the electrolytic plating solution TL.
  • the substrate PB is disposed in the tank 21 so that the substrate surface of the substrate PB is substantially in the vertical direction.
  • electroplating on the substrate PB is started by energizing between the cathode (not shown) and the anode 22.
  • the electrolytic plating solution TL is supplied from the tank 24 to the first tank 211 and the second tank 212 as needed. Thereby, the electrolytic plating solution TL in the tank 21 flows from the upper side in the vertical direction toward the lower side in the vertical direction (see arrows Y1 and Y2).
  • the electrolytic plating solution TL that flows from the upper side in the vertical direction toward the lower side in the vertical direction flows along the pair of substrate surfaces of the substrate PB and is also supplied to the inside of the through hole 201.
  • the entire substrate PB is immersed in the electrolytic plating solution TL.
  • the opening diameter of the first discharge port 211B is larger than the opening diameter of the second discharge port 212B, electrolysis flowing on one substrate surface (surface on the first tank 211 side) of the substrate PB.
  • the average flow rate of the plating solution TL is faster than the average flow rate of the electrolytic plating solution TL that flows on the other substrate surface (the surface on the second tank 212 side). Therefore, as shown in the enlarged cross-sectional view of FIG.
  • the average flow rate of the electrolytic plating solution TL flowing on the substrate surface of the substrate PB is the flow rate V1 per unit time of the electrolytic plating solution TL discharged from the first discharge port 211B and the electrolytic plating discharged from the second discharge port 212B. It can be calculated from the flow rate V2 per unit time of the liquid TL. First, the flow rate V1 per unit time of the electrolytic plating solution TL discharged from the first discharge port 211B is measured. Further, the flow rate V2 per unit time of the electrolytic plating solution TL discharged from the second discharge port 212B is measured.
  • the shape of the tank 21 is a rectangular parallelepiped or a cube
  • one substrate of the substrate PB is obtained by dividing V1 by the area S1 surrounded by the substrate PB, the partition wall 213, and the tank 21, as shown in FIG.
  • the average flow rate of the electrolytic plating solution TL flowing through the surface can be calculated.
  • the average flow velocity of the electrolytic plating solution TL flowing on the other substrate surface of the substrate PB is calculated by dividing V2 by the area S2 surrounded by the substrate PB, the partition 213, and the tank. Can do.
  • substrate PB may be inclined.
  • the average flow velocity of the electrolytic plating solution TL flowing on the substrate surface of the substrate PB can be calculated by calculation simulation or the like.
  • the difference between the average flow rate of the electrolytic plating solution TL flowing on one substrate surface of the substrate PB and the average flow rate of the electrolytic plating solution TL flowing on the other substrate surface of the substrate PB is preferably 1 m / s or more. More preferably, it is 10 m / s or more.
  • the mask M is omitted in the enlarged sectional view of FIG. In the drawing of FIG. 22, the anode 22 is omitted, but the average flow velocity may be calculated in consideration of the thickness of the anode 22 and the like.
  • the electrolytic plating solution TL is supplied from the tank 24 to the first tank 211 as needed, and the supply amount of the electrolytic plating solution TL from the tank 24 to the first tank 211 is the first tank 211. More than the amount of electrolytic plating solution TL discharged from Similarly, when electrolytic plating is performed, the electrolytic plating solution TL is supplied from the tank 24 to the second tank 212 as needed, and the supply amount of the electrolytic plating solution TL from the tank 24 to the second tank 212 is the second tank. More than the amount of electrolytic plating solution TL discharged from 212. Therefore, the electrolytic plating solution TL overflows from the upper part of the first tank 211 and the second tank 212.
  • the overflowed electrolytic plating solution TL flows in the direction of the arrow Y3 and is collected in the tank 24. Further, the electrolytic plating solution TL is supplied to the tank 24 from the first discharge port 211B and the second discharge port 212B. The electrolytic plating solution TL in the tank 24 is supplied again to the tank 21 via the pipes 26 and 27 and the pumps P1 and P2. If necessary, the metal concentration or the like of the electrolytic plating solution TL in the tank 24 may be analyzed to adjust the metal concentration or the like of the electrolytic plating solution TL in the tank 24. Further, the amount of electrolytic plating solution TL per unit time supplied from the pipe 26 into the first tank 211 is the same as the amount of electrolytic plating solution TL per unit time supplied from the pipe 27 into the second tank 212. May be different.
  • a conductor 26 serving as a via is formed in the through hole 201, and a metal film by electrolytic plating is formed on the metal film 222.
  • the metal film 223 is a metal film 222 and a plating film on the metal film 222).
  • the substrate PB that has been subjected to electrolytic plating is taken out of the bath 21 and cleaned. Thereafter, the portion of the metal film 222 where the mask M has been formed is removed by flash etching, and a first circuit layer 225 and a second circuit layer 224 are formed as shown in FIG.
  • a flexible circuit board PB obtained by subjecting the substrate PB to electrolytic plating can be obtained.
  • the average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on one substrate surface (first tank 211 side) of the substrate PB is the average flow velocity (electrolytic plating solution TL flowing on the other substrate surface (second tank 212 side) ( It is faster than (line speed). Therefore, as shown in the enlarged cross-sectional view of FIG. 17, a speed difference between the electrolytic plating solution TL flowing on one substrate surface and the electrolytic plating L flowing on the other substrate surface is generated, so that the flow from the slow side to the fast side
  • the electrolytic plating solution TL is drawn into the through hole 201 toward the top, and electrolytic plating is performed in the through hole 201.
  • the electrolytic plating solution TL in the bath 21 is immersed in the electrolytic plating solution TL in the bath 21 from the upper side in the vertical direction toward the lower side of the substrate PB. It flows along the substrate surface. As a result, the electrolytic plating solution TL is prevented from staying near the surface of the substrate PB, and the fresh electrolytic plating solution TL always comes into contact with the substrate PB. Thereby, a desired plating film can be stably formed on the substrate PB.
  • the electrolytic plating solution TL in the tank 21 flows from the upper side in the vertical direction toward the lower side. Since the electroplating solution TL flows according to gravity, the electroplating solution TL can flow smoothly. Moreover, the flow of the electrolytic plating solution TL is stabilized by flowing the electrolytic plating solution TL according to gravity. Further, the electrolytic plating solution TL is flowed according to gravity from the upper side in the vertical direction toward the lower side, so that the apparatus configuration of the substrate processing apparatus 2 can be prevented from becoming complicated. Furthermore, in the present embodiment, the electrolytic plating solution TL in the tank 21 is immersed in the electrolytic plating solution TL in the tank 21 from the upper side in the vertical direction toward the lower side. It flows along the substrate surface and is discharged. Thereby, even if foreign matter is mixed in the electrolytic plating solution TL, the foreign matter can be discharged from the tank 21. Therefore, it can suppress that a foreign material adheres to the board
  • the substrate PB is a substrate for a flexible circuit board, and the thickness thereof is relatively thin, 10 to 200 ⁇ m.
  • the substrate PB will fluctuate in the electroplating solution TL. Therefore, it may be difficult to perform desired electrolytic plating on the substrate PB when the substrate PB approaches or separates from the anode.
  • the electrolytic plating solution TL is allowed to flow while the substrate PB is immersed in the electrolytic plating solution TL.
  • the substrate PB Since the electrolytic plating solution TL flows from the upper side in the vertical direction toward the lower side on the one substrate surface side and the other substrate surface side of the substrate PB, the substrate PB is prevented from fluctuating in the electrolytic plating solution TL. The Thereby, desired electroplating can be performed with respect to the board
  • electrolytic plating is performed by overflowing the electrolytic plating solution TL from the tank 21. By making it overflow, electrolytic plating can be applied to the substrate PB while reliably maintaining the state in which the substrate PB is immersed in the electrolytic plating solution TL.
  • the tank 21 may have a size that allows the substrate PB to be disposed and allows the electrolytic plating solution TL to flow on the substrate surface side of the substrate PB. Thereby, the enlargement of the substrate processing apparatus 2 can be suppressed.
  • the present invention is not limited to the above-described embodiments, and modifications, improvements, and the like within the scope that can achieve the object of the present invention are included in the present invention.
  • the electrolytic plating solution TL that flows on one substrate surface (the first tank 211 side) of the substrate PB is set so that the opening diameter of the first discharge port 211B is larger than the opening diameter of the second discharge port 212B.
  • the average flow velocity (linear velocity) is made faster than the average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on the other substrate surface (second tank 212 side), but is not limited thereto. For example, as shown in FIG.
  • the pipe 28 is connected to the first outlet 211B, and the electrolytic plating solution is sucked by the pump P3.
  • the pipe 29 is connected to the second discharge port 212B, and the electrolytic plating solution is sucked by the pump P4.
  • the suction force of the pump P3 larger than the suction force of the pump P4
  • the average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on one substrate surface (first tank 211 side) of the substrate PB is set to the other substrate. You may make it faster than the average flow velocity (linear velocity) of the electroplating liquid TL which flows through the surface (the 2nd tank 212 side).
  • the first discharge port 211B may be larger than the second discharge port 212B, but the first discharge port 211B may have the same size as the second discharge port 212B. .
  • the first pressurizing means 231 for pressurizing the electrolytic plating solution in the first tank from the upper side to the lower side and discharging it from the first discharge port, and the electrolytic plating in the second tank.
  • a second pressurizing unit 232 configured to pressurize the liquid from the upper side to the lower side and discharge the liquid from the first discharge port.
  • the pressure applied to the electrolytic plating solution from the first pressurizing unit 231 is set to the second pressurizing unit 232.
  • the average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on the one substrate surface (first tank 211 side) of the substrate PB is increased by the pressure applied to the electrolytic plating solution from the other substrate surface (second tank).
  • the first discharge port 211B may be larger than the second discharge port 212B, but the first discharge port 211B may have the same size as the second discharge port 212B.
  • both pumps P3 and P4 and pressurizing means 231 and 232 may be provided.
  • the electroplating apparatus 2 is used.
  • the present invention is not limited to this.
  • the anode of the substrate processing apparatus 2 may be removed, and the substrate processing apparatus of the present invention may be an electroless plating apparatus 2A.
  • the substrate processing apparatus 2A shown in FIG. 20 is the same as the substrate processing apparatus 2 except that the anode is removed from the substrate processing apparatus 2.
  • the tank 24 and the tank 21 are filled with an electroless plating solution TL.
  • the substrate processing apparatus 2A shown in FIG. 20 may be an etching apparatus that etches a metal layer or the like on the substrate surface.
  • the substrate processing apparatus 2A may be a developing device.
  • the photosensitive resin layer on the substrate surface is irradiated with light, and a developer for removing unexposed portions is filled into the tank 24 and the tank 21, and the photosensitive resin layer on the substrate surface is unexposed by the substrate processing apparatus 2 ⁇ / b> A.
  • the portion may be removed.
  • the substrate processing apparatus 2 ⁇ / b> A may be a peeling apparatus that peels off a mask or the like formed on the substrate.
  • the tank 24 and the tank 21 may be filled with a stripping solution for stripping the mask or the like.
  • the substrate processing apparatus of the present invention may be a water washing apparatus 2B.
  • the water washing apparatus 2B has the same configuration as the substrate processing apparatus 2 except that the anode of the substrate processing apparatus 2 is removed and tanks 24A to 14C are provided.
  • the tank 24A of the water washing apparatus 2B is filled with water before substrate cleaning. Water is supplied from the tank 24A to the tank 21, and the water flows in the tank 21 from the upper side to the lower side in the vertical direction, and the substrate PB is cleaned. Thereafter, the washed water is discharged from the discharge port 212 and supplied to the tank 24B.
  • the water in the tank 24B is supplied to the tank (septic tank) 14C, and the water is purified in the tank 24C to remove impurities such as metals.
  • the water cleaned in the tank 24C is supplied to the tank 24A.
  • the water supplied to the tank 24A will be supplied to the tank 21 again.
  • clean water always comes into contact with the substrate PB, and the substrate PB can be prevented from being contaminated. Further, the inside of the through hole 201 can be reliably cleaned. Furthermore, in the method of simply immersing the substrate in the water tank and washing with water, it is difficult to reliably wash with one water tank, and it is necessary to provide a plurality of water tanks and perform water washing in multiple stages.
  • the water washing apparatus 2B is used, clean water always comes into contact with the substrate PB, so there is no need to perform water washing in multiple stages, and the processing process of the substrate PB can be simplified. In the washing apparatus 2B, the water in the tank 24B may be discarded without being cleaned in the tank 24C.
  • an opening 311 through which the substrate processing region TS of one surface OF of the substrate PB is exposed is formed on one surface, and an insertion port 312 is formed on the upper surface.
  • a box-shaped substrate holding member 310, and a balloon member 321 that is an expandable / contractible member that is arranged inside the other surface of the substrate holding member 310 and presses the inserted substrate PB against the inner peripheral surface of the opening 311. Have.
  • the balloon member 321 is made of, for example, a silicon tube having a diameter of 10 mm and a thickness of 1 mm.
  • the balloon member 321 presses the substrate PB by expansion, and is contracted by a negative pressure when the substrate PB is inserted.
  • the balloon member 321 is required to expand and contract.
  • the balloon member 321 which consists of a syringe tube is illustrated here as an expansion / contraction member, a bellows and an air cylinder can also be utilized as such an expansion / contraction member (not shown).
  • the substrate PB is processed by the substrate processing solution TL only on the substrate processing region TS of one surface OF.
  • bump plating an electrically conductive layer with a via in the insulating layer and a face on the bottom
  • electrolytic copper / Ni / solder plating Starting from the bottom of the via with electrolytic copper / Ni / solder plating
  • electroless gold plating laand with solder balls.
  • the substrate PB is formed in, for example, 500 ⁇ 500 mm.
  • the substrate processing apparatus 300 of the present embodiment includes a solution holding container 330 that contains the substrate processing solution TL in the substrate processing region TS and into which the substrate holding member 310 on which the substrate PB is set, and the substrate PB. It further has a substrate support jig 322 supported on the other surface.
  • the substrate processing solution TL for example, copper sulfate / Ni / solder is used in the case of bump plating as described above, and cyan gold is used in the case of electrolytic plating.
  • the substrate holding member 310 and the solution holding container 330 are made of engineering plastics such as PVC (polyvinyl chloride) because they need chemical resistance and rigidity.
  • PVC polyvinyl chloride
  • the substrate holding member 310 is formed with a rectangular opening 311 corresponding to the substrate processing region TS of the substrate PB on the front surface, and as shown in FIG. A balloon member 321 is disposed.
  • an air pump is connected to the balloon member 321 with a flexible tube member (not shown) and is expanded by a positive pressure.
  • the positive pressure may be maintained by an air pump or may be maintained by closing the tube member.
  • a sealing material 323 that is in close contact with the substrate PB is attached to the outer periphery of the inner surface of the opening hole 311 of the substrate holding member 310. Since the sealing material 323 requires chemical resistance, it is made of rubber sponge such as EPDM (Ethylene-Propylene-Methylene Linkage) or FKM (Fluorocarbon rubber).
  • EPDM Ethylene-Propylene-Methylene Linkage
  • FKM Fluorocarbon rubber
  • the sealing material 323 needs discontinuous pores because the substrate processing solution TL leaks out in the continuous pores. Also, flexibility is required to seal by pressing. For this reason, since it is not crushed with a rubber sheet, it is difficult to use it as a seal.
  • the wrap width In order to seal firmly, the wrap width needs to be at least 5 mm or more on the outer periphery of the substrate. The larger the wrap width, the higher the reliability of the seal, but the smaller the substrate processing effective area, the smaller the ideal.
  • the substrate support jig 322 is made of a plate material that simply supports the substrate PB, and does not seal the other surface of the substrate PB. However, the strength which does not break even if pressed by the balloon member 321 is required.
  • the substrate processing method of the substrate PB by the substrate processing apparatus 300 of the present embodiment in the configuration as described above will be described below.
  • the substrate PB is mounted on the substrate support jig 322 with the one surface OF of the substrate processing region TS as the front.
  • the substrate PB is inserted into the substrate holding member 310 from the insertion port 312 together with the substrate support jig 322. At this time, since the balloon member 321 is reduced, the insertion of the substrate PB is smoothly executed.
  • the balloon member 321 is expanded, whereby the substrate PB is brought into close contact with the sealing material 323 of the substrate holding member 310.
  • the substrate processing region TS is positioned in the opening hole 311 of the substrate holding member 310.
  • the substrate holding member 310 on which the substrate PB is set as described above is immersed in the solution holding container 330 containing the substrate processing solution TL as shown in FIG. Then, only the substrate processing region TS of the substrate PB is processed with the substrate processing solution TL from the opening 311 of the substrate holding member 310.
  • the substrate PB processed only in the substrate processing region TS can be obtained by executing the above-described operation in reverse.
  • the substrate holding member 310 on which the substrate PB is set as described above is immersed in the substrate processing solution TL in the substrate processing region TS accommodated in the solution holding container 330.
  • the substrate processing solution TL can be supplied only to the substrate processing region TS of the substrate PB. For this reason, only the substrate processing region TS of the one surface OF of the substrate PB can be easily and quickly processed with the substrate processing solution TL.
  • the present invention is not limited to the present embodiment, and various modifications are allowed without departing from the scope of the present invention.
  • only the substrate holding member 310 on which the substrate PB is set is immersed in the solution holding container 330 containing the substrate processing solution TL.
  • the substrate processing solution TL may be sequentially supplied to the solution holding container 330 by the solution supply mechanism 341 as shown in FIG.
  • a solution supply mechanism 341 can drop the substrate processing solution TL from above to below.
  • the flow rate of the substrate processing solution TL falling from the upper side to the lower side is, for example, about 0.1 to 2 m / s.
  • the substrate processing solution TL falling from above to below as described above may be pumped to the substrate processing region TS by the solution turbulence mechanism 342.
  • the substrate processing solution TL flowing downward from above is turbulent by the substrate processing solution TL supplied from the nozzle 143 and is pumped to the substrate processing region TS of the substrate PB.
  • the region TS can be processed satisfactorily.
  • the substrate processing solution TL may be pumped to the substrate processing region TS by the solution turbulence mechanism 351 and sucked.
  • the turbulent substrate processing solution TL since the turbulent substrate processing solution TL is supplied to the substrate processing region TS of the substrate PB, the substrate processing region TS can be satisfactorily processed with the substrate processing solution TL.
  • the horizontally long slit-shaped nozzles 143, 152, 153 may be arranged in the vertical direction.
  • circular nozzles having an inner diameter of 1 to 5 mm are arranged at intervals of 1 to They may be formed in a matrix shape or zigzag shape at 20 mm (not shown).
  • the rectangular opening hole 311 corresponding to the substrate processing region TS is formed in the substrate holding member 310, and the rectangular annular balloon member 321 is disposed behind the rectangular opening hole 311.
  • the balloon member 321 only needs to be able to press-contact the substrate PB to the opening hole 311 of the substrate holding member 310 and, for example, one large expansion member, two upper and lower expansion members, two left and right members
  • the expansion / contraction member may be used (not shown).
  • the substrate processing apparatus 400 of the present invention contains a substrate processing solution TL and a substrate holding solution 430 in which the substrate PB is immersed, and the substrate processing solution TL in the solution holding container 430 from below. And a solution supply mechanism 441 that sequentially drops and supplies the substrate processing solution TL that drops downward from above to a substrate processing region TS on one surface of the substrate PB.
  • the substrate PB is processed by the substrate processing solution TL only on the substrate processing region TS of one surface OF.
  • bump plating an electrically conductive layer with a via in the insulating layer and a face on the bottom
  • electrolytic copper / Ni / solder plating Starting from the bottom of the via with electrolytic copper / Ni / solder plating
  • electroless gold plating laand with solder balls.
  • the substrate PB is formed in, for example, 500 ⁇ 500 mm.
  • the substrate processing solution TL for example, copper sulfate / Ni / solder is used in the case of bump plating as described above, and cyan gold is used in the case of electrolytic plating.
  • the substrate holding member 410 and the solution holding container 430 are made of engineering plastics such as PVC (polyvinyl chloride) because they need chemical resistance and rigidity.
  • PVC polyvinyl chloride
  • the substrate processing apparatus 400 of the present embodiment has an insertion hole 412 into which the substrate PB is inserted, and an opening hole 411 through which the substrate processing region TS is exposed.
  • a balloon member 421 and a substrate support jig 422 for supporting the substrate PB on the other surface are also provided.
  • the balloon member 421 is made of a silicon tube having a diameter of 10 mm and a thickness of 1 mm, for example.
  • the balloon member 421 presses the substrate PB by expansion, and is contracted by negative pressure when the substrate PB is inserted.
  • the balloon member 421 is required to expand and contract.
  • the balloon member 421 which consists of a syringe tube is illustrated here as an expansion / contraction member, a bellows and an air cylinder can also be utilized as such an expansion / contraction member (not shown).
  • the solution holding container 430 is formed in a box shape having an open top surface, and a solution supply mechanism 441 is disposed at the front upper portion thereof.
  • a solution discharge port 444 for the substrate processing solution TL is formed below the solution holding container 430, and the substrate processing solution TL is discharged from the solution discharge port 444 by gravity.
  • the flow rate of the substrate processing solution TL falling from the upper side to the lower side is, for example, about 0.1 to 2 m / s.
  • the solution turbulence mechanism 442 includes a plurality of solution discharge ports 443 that are flat in the horizontal direction, and the substrate processing solution TL is supplied to the substrate on one surface of the substrate PB from the plurality of solution discharge ports 443. Pump to processing area TS.
  • the substrate holding member 410 is formed with a rectangular opening hole 411 corresponding to the substrate processing region TS of the substrate PB in FIG. 32 and the front surface, and as shown in FIG. A member 421 is disposed.
  • an air pump is connected to the balloon member 421 with a flexible tube member (not shown) and is expanded by a positive pressure.
  • the positive pressure may be maintained by an air pump or may be maintained by closing the tube member.
  • a sealing material 423 that is in close contact with the substrate PB is attached to the outer periphery of the inner surface of the opening hole 411 of the substrate holding member 410. Since the sealing material 423 requires chemical resistance, it is made of, for example, a rubber sponge such as EPDM or FKM.
  • the sealing material 423 needs discontinuous pores because the substrate processing solution TL leaks out in the continuous pores. Also, flexibility is required to seal by pressing. For this reason, since it is not crushed with a rubber sheet, it is difficult to use it as a seal.
  • the wrap width In order to seal firmly, the wrap width needs to be at least 5 mm or more on the outer periphery of the substrate. The larger the wrap width, the higher the reliability of the seal, but the smaller the substrate processing effective area, the smaller the ideal.
  • the substrate support jig 422 is made of a plate material that simply supports the substrate PB, and does not seal the other surface of the substrate PB. However, the strength which does not break even if pressed by the balloon member 421 is required.
  • the substrate PB processing method by the substrate processing apparatus 400 of the present embodiment in the configuration as described above will be described below.
  • the substrate PB is mounted on the substrate support jig 422 with the one surface OF of the substrate processing region TS as the front.
  • the substrate PB is inserted into the substrate holding member 410 from the insertion port 412 together with the substrate support jig 422. At this time, since the balloon member 421 is reduced, the insertion of the substrate PB is performed smoothly.
  • the balloon member 421 is expanded, whereby the substrate PB is brought into close contact with the sealing material 423 of the substrate holding member 410.
  • the substrate processing region TS is positioned in the opening hole 411 of the substrate holding member 410.
  • the substrate holding member 410 on which the substrate PB is set as described above is immersed in the solution holding container 430 containing the substrate processing solution TL as shown in FIGS.
  • the substrate processing solution TL is supplied from the solution supply mechanism 441 to the solution holding container 430, and the substrate processing solution TL falls downward from above and is sequentially discharged from the solution discharge port 444.
  • the substrate processing solution TL is simultaneously pumped from the plurality of solution discharge ports 443 of the solution turbulence mechanism 442 to the substrate processing region TS of the substrate PB.
  • the substrate processing solution TL in which the substrate processing solution TL flows on the surface of the substrate PB from the upper side to the lower side becomes a turbulent flow due to the substrate processing solution TL discharged from the plurality of solution discharge ports 443, so that the substrate processing solution TL is It is pumped to the substrate processing region TS of the substrate PB.
  • the substrate PB processed only in the substrate processing region TS can be obtained by executing the above operations in reverse.
  • the solution supply mechanism 441 sequentially drops the substrate processing solution TL from the upper side to the lower side in the solution holding container 430 in which the substrate PB is immersed as described above. In this way, the solution turbulence mechanism 442 pumps the substrate processing solution TL falling from the upper side to the lower side to the substrate processing region TS on one surface of the substrate PB.
  • the substrate processing solution TS on one surface of the substrate PB is not only simply dropped from the upper side to the lower side, but is also pumped as a turbulent flow. Therefore, the substrate processing region TS on one surface of the substrate PB is quickly and satisfactorily processed by the turbulent substrate processing solution TL.
  • the solution turbulence mechanism 442 discharges the substrate processing solution TL from the plurality of solution discharge ports 443, the substrate processing solution TL in which the substrate processing solution TL flows on the surface of the substrate PB from the upper side to the lower side becomes a good turbulent flow. The process is performed quickly and successfully.
  • the substrate holding member 410 on which the substrate PB is set as described above is immersed in the substrate processing solution TL in the substrate processing region TS accommodated in the solution holding container 430.
  • the substrate processing solution TL can be supplied only to the substrate processing region TS of the substrate PB. For this reason, only the substrate processing region TS of the one surface OF of the substrate PB can be easily and quickly processed with the substrate processing solution TL.
  • the present invention is not limited to the present embodiment, and various modifications are allowed without departing from the scope of the present invention.
  • a substrate swing mechanism (not shown) that swings the substrate PB immersed in the substrate processing solution TL in the solution holding container 430 in the vertical direction may be provided. In this case, it is possible to reduce unevenness in the pumping of the substrate processing solution TL due to the separation of the plurality of solution discharge ports 443 by swinging.
  • a rectangular opening hole 411 corresponding to the substrate processing region TS is formed in the substrate holding member 410, and a rectangular annular balloon member 421 is disposed behind the rectangular opening hole 411.
  • the balloon member 421 only needs to be able to press-contact the substrate PB to the opening hole 411 of the substrate holding member 410 and, for example, one large balloon member, two upper and lower balloon members, two left and right Or a balloon member (not shown).
  • the substrate PB is set on the box-shaped substrate holding member 410 and only one substrate processing region TS is processed with the substrate processing solution TL.
  • the other surface of the substrate PB may be sealed and attached to the substrate support jig 422, and the substrate processing region TS may be processed by immersing the substrate PB together with the substrate support jig 422 in the substrate processing solution TL. .
  • the substrate processing apparatus 500 of the present invention contains a solution holding container 530 in which a substrate processing solution TL is stored and the substrate PB is immersed, and a substrate processing region TS on one surface OF of the immersed substrate PB. And a solution turbulence mechanism 551 for feeding and sucking the substrate processing solution TL.
  • the substrate PB is processed by the substrate processing solution TL only on the substrate processing region TS of one surface OF.
  • bump plating an electrically conductive layer with a via in the insulating layer and a face on the bottom
  • electrolytic copper / Ni / solder plating Starting from the bottom of the via with electrolytic copper / Ni / solder plating
  • electroless gold plating laand with solder balls.
  • the substrate PB is formed in, for example, 500 ⁇ 500 mm.
  • the substrate processing solution TL for example, copper sulfate / Ni / solder is used in the case of bump plating as described above, and cyan gold is used in the case of electrolytic plating.
  • the substrate holding member 510 and the solution holding container 530 require chemical resistance and rigidity, they are made of, for example, engineering plastics such as PVC (polyvinyl chloride).
  • the solution turbulence mechanism 551 pumps the substrate processing solution TL from the plurality of solution discharge ports 552 to the substrate processing region TS of the one surface OF of the substrate PB and sucks the substrate processing solution TL from the plurality of solution suction ports 553.
  • solution discharge ports 552 and solution suction ports 553 are alternately arranged.
  • the horizontally long slit-shaped solution discharge ports 552 are arranged in the vertical direction.
  • circular solution discharge ports having an inner diameter of 1 to 5 mm are arranged in a matrix shape or a zigzag shape at intervals of 1 to 20 mm. (Not shown).
  • the substrate processing apparatus 500 of the present embodiment has an insertion hole 512 into which the substrate PB is inserted, and an opening hole 511 through which the substrate processing region TS is exposed.
  • a balloon member 521 that can be expanded and contracted to press-contact the inserted substrate PB disposed inside the other surface of the substrate holding member 510 to the inner surface of the outer periphery of the opening hole 511.
  • a substrate support jig 522 that supports the substrate PB on the other surface.
  • the balloon member 521 is made of, for example, a silicon tube having a diameter of 10 mm ⁇ t1.
  • the balloon member 521 presses the substrate PB by expansion, and is contracted by a negative pressure when the substrate PB is inserted.
  • the balloon member 521 is required to have a property of expanding and contracting.
  • the balloon member 521 which consists of a syringe tube is illustrated here as an expansion / contraction member, a bellows and an air cylinder can also be utilized as such an expansion / contraction member (not shown).
  • the solution turbulence mechanism 551 includes a plurality of solution discharge ports 552 and a solution suction port 553 that are flat in the horizontal direction.
  • the substrate processing solution TL is pumped to the substrate processing region TS on one surface of the substrate PB, and the pumped substrate processing solution TL is sucked from the solution suction port 553.
  • Such pumping and suction of the substrate processing solution TL is performed by, for example, a pump mechanism.
  • the substrate processing solution TL thus pumped and sucked may be sequentially replaced with a new one, may be circulated without being replaced, or may be appropriately replaced with a new one while being circulated.
  • the substrate holding member 510 has a rectangular opening hole 511 corresponding to the substrate processing region TS of the substrate PB formed in FIG. 36 and the front surface, and as shown in FIG. A member 521 is disposed.
  • an air pump is connected to the balloon member 521 by a flexible tube member (not shown), and is expanded by a positive pressure.
  • the positive pressure may be maintained by an air pump or may be maintained by closing the tube member.
  • a sealing material 523 that is in close contact with the substrate PB is attached to the inner periphery of the opening hole 511 of the substrate holding member 510. Since the sealing material 523 needs chemical resistance, it is made of, for example, a rubber sponge such as EPDM or FKM.
  • the sealing material 523 requires discontinuous pores because the substrate processing solution TL leaks out in the continuous pores. Also, flexibility is required to seal by pressing. For this reason, since it is not crushed with a rubber sheet, it is difficult to use it as a seal.
  • the wrap width In order to seal firmly, the wrap width needs to be at least 5 mm or more on the outer periphery of the substrate. The larger the wrap width, the higher the reliability of the seal, but the smaller the substrate processing effective area, the smaller the ideal.
  • the substrate support jig 522 is made of a plate material that simply supports the substrate PB, and does not seal the other surface of the substrate PB. However, the strength which does not break even if pressed by the balloon member 521 is required.
  • the substrate processing method of the substrate PB by the substrate processing apparatus 500 of the present embodiment in the configuration as described above will be described below.
  • the substrate PB is mounted on the substrate support jig 522 with the one surface OF of the substrate processing region TS as the front.
  • the substrate PB is inserted into the substrate holding member 510 from the insertion port 512 together with the substrate support jig 522. At this time, since the balloon member 521 is reduced, the insertion of the substrate PB is executed smoothly.
  • the balloon member 521 is expanded, whereby the substrate PB is brought into close contact with the sealing material 523 of the substrate holding member 510.
  • the substrate processing region TS is positioned in the opening hole 511 of the substrate holding member 510.
  • the substrate holding member 510 on which the substrate PB is set as described above is immersed in a solution holding container 530 containing the substrate processing solution TL as shown in FIGS.
  • the substrate processing solution TL is pumped from the solution discharge port 552 of the solution turbulence mechanism 551 to the solution holding container 530, and the pumped substrate processing solution TL is sucked from the solution suction port 553.
  • the substrate processing solution TL flows in a turbulent manner on the surface of the substrate PB, and the substrate processing region TS of the substrate PB is processed with the turbulent substrate processing solution TL.
  • the substrate PB processed only in the substrate processing region TS can be obtained by executing the above operations in reverse.
  • the substrate PB is immersed in the substrate processing solution TL stored in the solution holding container 530 as described above.
  • the solution supply mechanism pumps and sucks the substrate processing solution TL into the substrate processing region TS of the substrate PB in such a state.
  • the substrate processing region TS of the one surface OF of the substrate PB is processed by the substrate processing solution TL that is pumped and sucked. Accordingly, only the substrate processing region TS of the one surface OF of the substrate PB can be processed easily and quickly by the substrate processing solution TL that becomes a turbulent flow.
  • the solution turbulence mechanism 551 pumps the substrate processing solution TL from the plurality of solution discharge ports 552 and sucks the substrate processing solution TL from the plurality of solution suction ports 553, so that the surface of the substrate processing solution TL on the surface of the substrate PB.
  • the substrate processing solution TL becomes a good turbulent flow, and the processing is performed quickly and satisfactorily.
  • the substrate processing region TS of the substrate PB is uniformly processed with the turbulent substrate processing solution TL. Can do.
  • the substrate holding member 510 on which the substrate PB is set as described above is immersed in the substrate processing solution TL in the substrate processing region TS accommodated in the solution holding container 530.
  • the substrate processing solution TL can be supplied only to the substrate processing region TS of the substrate PB. For this reason, only the substrate processing region TS of the one surface OF of the substrate PB can be easily and quickly processed with the substrate processing solution TL.
  • the present invention is not limited to the present embodiment, and various modifications are allowed without departing from the scope of the present invention.
  • a substrate swing mechanism (not shown) that swings the substrate PB immersed in the substrate processing solution TL of the solution holding container 530 in the vertical direction may be provided. In this case, it is possible to reduce unevenness in the pumping of the substrate processing solution TL due to the separation of the plurality of solution discharge ports 552 by swinging.
  • the substrate holding member 510 is formed with the rectangular opening hole 511 corresponding to the substrate processing region TS, and the rectangular annular balloon member 521 is disposed behind the rectangular opening hole 511.
  • the balloon member 521 only needs to be able to press-contact the substrate PB to the opening hole 511 of the substrate holding member 510 and, for example, one large balloon member, two upper and lower balloon members, two left and right Or a balloon member (not shown).
  • the substrate PB is set on the box-shaped substrate holding member 510 and only one substrate processing region TS is processed with the substrate processing solution TL.
  • the other surface of the substrate PB may be sealed and attached to the substrate support jig 522, and the substrate processing region TS may be processed by immersing the substrate PB in the substrate processing solution TL together with the substrate support jig 522. .

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Abstract

A substrate treating apparatus (1) is provided with: a bath (11) wherein a substrate treatment solution (TL) is supplied thereto, and a substrate (PB) is immersed in the supplied substrate treatment solution (TL); and a holding section (13) which holds the substrate (PB) such that the surface of the substrate (PB) disposed in the bath (11) is substantially parallel to the vertical direction. The treating apparatus (1) is configured such that, when the substrate treatment solution (TL) is made to flow from the supply port (111) of the bath (11) toward the discharge port (112) thereof, the substrate treatment solution (TL) flows from the upper side toward the lower side in the vertical direction along the substrate surface. Thus, a substrate treating method and the substrate treating apparatus, whereby the substrate can be stably treated, are provided.

Description

基板処理方法および基板処理装置Substrate processing method and substrate processing apparatus
 本発明は、プリント配線基板などの基板を基板処理溶液で処理する基板処理方法および基板処理装置に関する。 The present invention relates to a substrate processing method and a substrate processing apparatus for processing a substrate such as a printed wiring board with a substrate processing solution.
 従来、回路基板は、以下のようにして製造されている。
 基材の両面に銅箔が貼り付けられた両面銅貼積層板を用意する。この両面銅貼積層板にビアホールを形成し、さらに、ビアホールおよび両面銅貼積層板上にめっきを行う。その後、両面銅貼積層板を加工して回路を形成する(特許文献1)。
Conventionally, circuit boards are manufactured as follows.
A double-sided copper-clad laminate with copper foil attached to both sides of the substrate is prepared. Via holes are formed in the double-sided copper-clad laminate, and plating is further performed on the via holes and the double-sided copper-clad laminate. Thereafter, the double-sided copper-clad laminate is processed to form a circuit (Patent Document 1).
 また、半導体回路の製造工程の一つとしてプリント配線基板などの基板を基板処理溶液で処理することがある。ただし、基板の一面の基板処理領域のみ処理したい場合には、例えば、処理しない他面を基板支持治具などで密閉し、処理しない基板処理領域の周囲を封止材で封止することになる。現在、上述のような基板処理装置として各種の提案がある(特許文献2,3)。 Also, as one of semiconductor circuit manufacturing processes, a substrate such as a printed wiring board may be treated with a substrate treatment solution. However, when it is desired to process only the substrate processing region on one surface of the substrate, for example, the other surface that is not processed is sealed with a substrate support jig or the like, and the periphery of the substrate processing region that is not processed is sealed with a sealing material. . Currently, there are various proposals for the substrate processing apparatus as described above (Patent Documents 2 and 3).
特開平11-186737号公報Japanese Patent Laid-Open No. 11-186737 特開2005-052702号公報Japanese Patent Laying-Open No. 2005-052702 特開2005-286162号公報JP 2005-286162 A
 従来の基板処理方法では、めっきを行う際に、両面銅貼積層板をめっき液に浸漬させている。しかしながら、この製造方法では、所望のめっき膜を安定的に得ることが難しかった。所望のめっき膜が得られない原因としては、めっき液の滞留や、異物の付着等が考えられる。 In the conventional substrate processing method, the double-sided copper-clad laminate is immersed in a plating solution when performing plating. However, with this manufacturing method, it has been difficult to stably obtain a desired plating film. Possible causes for the failure to obtain the desired plating film include retention of the plating solution and adhesion of foreign matter.
 めっき液をバブリング等で撹拌することも行われているが、めっき槽は比較的大きいため、バブリング等で撹拌しても、めっき液の滞留や、異物の付着を確実に抑制することは非常に困難であった。なお、このように、滞留が生じるという課題、異物が付着するという課題は、めっきを行う場合のみならず、両面銅貼積層板を水に浸して水洗する場合や、エッチング液に両面銅貼積層板を浸してエッチングを行う場合等にも生じる。 Stirring the plating solution by bubbling, etc. is also performed, but the plating tank is relatively large, so it is extremely difficult to reliably retain the plating solution and prevent foreign matter from adhering even if it is stirred by bubbling. It was difficult. In addition, in this way, the problem that retention occurs and the problem that foreign matter adheres are not only when performing plating, but also when immersing a double-sided copper-clad laminate in water and washing it with water, or laminating double-sided copper in an etching solution This also occurs when etching is performed by immersing the plate.
 また、従来の基板処理方法では、めっきを行う際に、上述のように両面銅貼積層板をめっき液に浸漬させている。しかしながら、この製造方法では、ビアホール内に所望のめっき膜を安定的に得ることが難しかった。なお、このように、ビアホール内に所望の処理を実施できないという課題は、めっきを行う場合のみならず、両面銅貼積層板を水に浸して水洗する場合等にも生じる。 In the conventional substrate processing method, when performing plating, the double-sided copper-clad laminate is immersed in the plating solution as described above. However, with this manufacturing method, it has been difficult to stably obtain a desired plating film in the via hole. In addition, the subject that a desired process cannot be implemented in a via hole arises not only when performing plating but also when the double-sided copper-clad laminate is immersed in water and washed.
 また、前述のような従来の基板処理装置では、基板を基板処理溶液に浸漬しただけなので、実際には基板処理領域を短時間で良好に処理することが困難である。 In the conventional substrate processing apparatus as described above, since the substrate is simply immersed in the substrate processing solution, it is actually difficult to satisfactorily process the substrate processing region in a short time.
 また、前述のように基板の処理しない他面を基板支持治具などで密閉することや、処理しない基板処理領域の周囲を封止材で封止することは、作業が煩雑で半導体回路の生産性を低下させることになる。 In addition, as described above, sealing the other surface of the substrate that is not processed with a substrate support jig or the like, and sealing the periphery of the substrate processing region that is not processed with a sealing material are complicated and produce semiconductor circuits. Will reduce the sex.
 本発明の第一の基板処理方法は、基板に基板処理溶液を接触させて処理する基板処理方法であって、基板面が鉛直方向と平行または、鉛直方向に対し傾斜するように、槽内に基板を配置する工程と、基板を槽内の基板処理溶液中に浸漬させるとともに、基板処理溶液を鉛直方向の上方側から、下方側に向かって基板面に沿って流す工程と、基板面に沿って流れた基板処理溶液を槽から排出する工程とを含む。 A first substrate processing method of the present invention is a substrate processing method in which a substrate processing solution is brought into contact with a substrate for processing, and the substrate surface is parallel to the vertical direction or tilted with respect to the vertical direction. A step of arranging the substrate, a step of immersing the substrate in the substrate processing solution in the tank, and a step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side; And discharging the substrate processing solution that has flown from the tank.
 この発明によれば、基板を槽内の基板処理溶液中に浸漬させた状態で、槽内の基板処理溶液を鉛直方向の上方側から、下方側に向かって基板面に沿って流している。これにより基板表面付近で基板処理溶液が滞留してしまうことが防止され、基板に対し、所望の処理を安定的に実施することができる。
 さらに、本発明では、槽内の基板処理溶液を鉛直方向の上方側から、下方側に向かって流している。基板処理溶液が重力に従って流れることとなるので、基板処理溶液をスムーズに流すことができる。
 また、本発明では、槽内の基板処理溶液を鉛直方向の上方側から、下方側に向かって基板面に沿って流すことで、基板処理溶液中の異物を槽から排出することができる。これにより、基板に異物が付着することを抑制でき、所望の処理を安定的に実施することができる。
According to this invention, the substrate processing solution in the tank is allowed to flow along the substrate surface from the upper side in the vertical direction toward the lower side in a state where the substrate is immersed in the substrate processing solution in the tank. Accordingly, the substrate processing solution is prevented from staying near the substrate surface, and desired processing can be stably performed on the substrate.
Furthermore, in the present invention, the substrate processing solution in the tank flows from the upper side in the vertical direction toward the lower side. Since the substrate processing solution flows according to gravity, the substrate processing solution can flow smoothly.
Moreover, in this invention, the foreign material in a substrate processing solution can be discharged | emitted from a tank by flowing the substrate processing solution in a tank along a substrate surface toward the downward side from the upper side of a perpendicular direction. Thereby, it can suppress that a foreign material adheres to a board | substrate, and can perform a desired process stably.
 さらに、本発明の第一の基板処理装置は、基板に基板処理溶液を接触させて処理する基板処理装置において、内部に基板処理溶液が供給されるとともに、供給された基板処理溶液に基板を浸積させる槽と、槽内部に配置される基板面が鉛直方向に平行あるいは、鉛直方向に対し傾斜するように基板を保持する保持部とを備え、槽の基板処理溶液の供給口は、保持部で保持された基板よりも鉛直方向上方にあり、槽の基板処理溶液の排出口は、保持部で保持された基板よりも鉛直方向下方にあり、基板処理溶液を槽の供給口から排出口に向かって基板処理溶液を流すと、基板処理溶液が、鉛直方向の上方側から下方側に向かって基板面に沿って流れるように構成される。 Furthermore, the first substrate processing apparatus of the present invention is a substrate processing apparatus for processing by bringing a substrate processing solution into contact with a substrate, and the substrate processing solution is supplied to the inside and the substrate is immersed in the supplied substrate processing solution. A tank to be stacked, and a holding unit for holding the substrate so that the substrate surface disposed inside the tank is parallel to or inclined with respect to the vertical direction. The substrate processing solution discharge port of the tank is vertically lower than the substrate held by the holding unit, and is vertically lower than the substrate held by the holding unit, and the substrate processing solution is transferred from the tank supply port to the discharge port. When the substrate processing solution is caused to flow toward the substrate, the substrate processing solution is configured to flow along the substrate surface from the upper side in the vertical direction toward the lower side.
 本発明によれば、所望の処理を安定的に実施することができる基板処理方法および基板処理装置が提供される。 According to the present invention, a substrate processing method and a substrate processing apparatus capable of stably performing a desired process are provided.
 本発明の第二の基板処理方法は、基板の一方の基板面側から他方の基板面側にむかって貫通する貫通孔が形成された基板の貫通孔に基板処理溶液を接触させて、基板を処理する基板処理方法であって、基板処理溶液が供給される槽であり、基板を保持し、保持した基板とともに当該槽を、第一槽および第二槽に区画する隔壁を備える槽を用意する工程と、基板を隔壁に保持させて、槽内に基板を設置する工程と、第一槽および第二槽内に基板処理溶液を供給して基板を基板処理溶液に浸漬させた状態とし、第一槽および第二槽それぞれからめっき液を排出することで、基板処理溶液を基板の一方の基板面および他方の基板面に沿って流すとともに、貫通孔内に基板処理溶液を接触させる工程とを含み、基板処理溶液を基板の一方の基板面および他方の基板面に沿って流すとともに、貫通孔内に基板処理溶液を接触させる工程において、基板の一方の基板面に沿って流れる基板処理溶液の平均流速と、基板の他方の基板面に沿って流れる基板処理溶液の平均流速とが異なる。 According to a second substrate processing method of the present invention, a substrate processing solution is brought into contact with a through hole of a substrate in which a through hole penetrating from one substrate surface side to the other substrate surface side is formed. A substrate processing method for processing, which is a tank to which a substrate processing solution is supplied, and prepares a tank that includes a partition that holds a substrate and partitions the tank into a first tank and a second tank together with the held substrate. A step of holding the substrate in the partition and setting the substrate in the tank; and supplying the substrate processing solution into the first tank and the second tank to immerse the substrate in the substrate processing solution; Discharging the plating solution from each of the one tank and the second tank to flow the substrate processing solution along one substrate surface and the other substrate surface of the substrate, and bringing the substrate processing solution into contact with the through hole; Substrate treatment solution on one side of the substrate. And flowing along the other substrate surface, and in the step of bringing the substrate processing solution into contact with the through hole, the average flow rate of the substrate processing solution flowing along one substrate surface of the substrate and the other substrate surface of the substrate The average flow rate of the substrate processing solution that flows through is different.
 この発明によれば、基板の一方の基板面に沿って流れる基板処理溶液の平均流速と、基板の他方の基板面に沿って流れる基板処理溶液の平均流速とが異なっている。これにより、基板処理溶液が貫通孔内に引き込まれることとなる。したがって、貫通孔内を基板処理溶液で確実に処理することができる。 According to the present invention, the average flow velocity of the substrate processing solution flowing along one substrate surface of the substrate is different from the average flow velocity of the substrate processing solution flowing along the other substrate surface of the substrate. Thereby, the substrate processing solution is drawn into the through hole. Therefore, the inside of the through hole can be reliably processed with the substrate processing solution.
 また、本発明の第二の基板処理装置は、基板の一方の基板面側から他方の基板面側にむかって貫通する貫通孔が形成された基板の貫通孔内に基板処理溶液を接触させて、基板を処理する基板処理装置において、内部に基板処理溶液が供給され、供給された基板処理溶液に基板を浸積させるとともに、基板を保持し、保持した基板とともに槽を、第一槽および第二槽に区画する隔壁を備える槽と、槽の第一槽および第二槽内にそれぞれに基板処理溶液を供給する供給手段とを備え、当該基板処理装置は、供給手段から供給された基板処理溶液が、基板の一方の基板面および他方の基板面に沿って流れるとともに、基板の貫通孔に接触するように構成され、基板の一方の基板面に沿って流れる基板処理溶液の平均流速と、基板の他方の基板面に沿って流れる基板処理溶液の平均流速とを異ならせる調整手段を有する。 Further, the second substrate processing apparatus of the present invention contacts the substrate processing solution in the through hole of the substrate in which the through hole penetrating from one substrate surface side to the other substrate surface side is formed. In a substrate processing apparatus for processing a substrate, a substrate processing solution is supplied inside, the substrate is immersed in the supplied substrate processing solution, the substrate is held, and the tank is held together with the held substrate, the first tank and the second tank. A tank provided with a partition partitioning into two tanks, and a supply means for supplying a substrate processing solution into each of the first tank and the second tank of the tank, and the substrate processing apparatus is provided with the substrate processing supplied from the supply means The solution flows along one substrate surface and the other substrate surface of the substrate, and is configured to contact the through hole of the substrate, and the average flow rate of the substrate processing solution flowing along one substrate surface of the substrate; On the other side of the board Having adjustment means for varying the average flow velocity of the substrate processing solution flowing through me.
 本発明によれば、貫通孔内に所望の処理を施すことができる処理方法および処理装置が提供される。 According to the present invention, there is provided a processing method and a processing apparatus capable of performing a desired processing in the through hole.
 本発明の第三の基板処理装置は、基板の一面の基板処理領域が露出する開口孔が一面に形成されているとともに挿入口が上面に形成されているボックス状の基板保持部材と、基板保持部材の他面内側に配置されていて挿入された基板を開口孔の外周内面に圧接させる拡縮自在な拡縮部材と、を有する。 A third substrate processing apparatus of the present invention includes a box-shaped substrate holding member in which an opening hole for exposing a substrate processing region on one surface of the substrate is formed on one surface and an insertion port is formed on the upper surface, and a substrate holding And an expandable / contractible member that is disposed inside the other surface of the member and presses the inserted substrate against the inner peripheral surface of the opening hole.
 従って、本発明の基板処理装置では、ボックス状の基板保持部材の一面に基板の一面の基板処理領域が露出する開口孔が形成されているとともに上面に挿入口が形成されている。基板処理領域が開口孔に露出する状態に基板保持部材の内部に配置された基板を拡縮自在な拡縮部材が内面に圧接させる。例えば、このように基板がセットされた基板保持部材を溶液保持容器に収容されている基板処理領域の基板処理溶液に浸漬することにより、基板処理領域のみに基板処理溶液を供給することができる。 Therefore, in the substrate processing apparatus of the present invention, an opening hole is formed in one surface of the box-shaped substrate holding member to expose the substrate processing region on one surface of the substrate, and an insertion port is formed in the upper surface. A substrate disposed inside the substrate holding member is brought into contact with the inner surface of the substrate holding member so that the substrate processing region is exposed to the opening hole. For example, the substrate processing solution can be supplied only to the substrate processing region by immersing the substrate holding member on which the substrate is set in this manner in the substrate processing solution in the substrate processing region accommodated in the solution holding container.
 本発明の基板処理装置では、例えば、基板がセットされた基板保持部材を溶液保持容器に収容されている基板処理領域の基板処理溶液に浸漬することにより、基板処理領域のみに基板処理溶液を供給することができる。このため、基板の一面の基板処理領域のみを簡単かつ迅速に基板処理溶液で処理することができる。 In the substrate processing apparatus of the present invention, for example, the substrate processing solution is supplied only to the substrate processing region by immersing the substrate holding member on which the substrate is set in the substrate processing solution in the substrate processing region accommodated in the solution holding container. can do. Therefore, only the substrate processing region on one surface of the substrate can be processed easily and quickly with the substrate processing solution.
 本発明の第四の基板処理装置は、基板処理溶液を収容していて基板が浸漬される溶液保持容器と、溶液保持容器に基板処理溶液を上方から下方に落下させて順次供給する溶液供給機構と、上方から下方に落下する基板処理溶液を基板の一面の基板処理領域に圧送する溶液乱流機構と、を有する。 A fourth substrate processing apparatus of the present invention includes a solution holding container that contains a substrate processing solution and in which the substrate is immersed, and a solution supply mechanism that sequentially supplies the substrate holding solution by dropping it from above to the solution holding container. And a solution turbulence mechanism that pumps the substrate processing solution falling downward from above to the substrate processing region on one surface of the substrate.
 従って、本発明の基板処理装置では、溶液保持容器に収容されている基板処理溶液に基板が浸漬される。このような溶液保持容器に溶液供給機構が基板処理溶液を上方から下方に落下させて順次供給する。このように上方から下方に落下する基板処理溶液を溶液乱流機構が基板の一面の基板処理領域に圧送する。このため、基板の一面の基板処理領域は基板処理溶液が単純に上方から下方へ落下するだけではなく、乱流となって圧送されることになる。 Therefore, in the substrate processing apparatus of the present invention, the substrate is immersed in the substrate processing solution contained in the solution holding container. The solution supply mechanism sequentially supplies the substrate processing solution by dropping the substrate processing solution from above to the solution holding container. Thus, the solution turbulence mechanism pumps the substrate processing solution falling downward from above to the substrate processing region on one surface of the substrate. For this reason, the substrate processing region on one surface of the substrate is not only simply dropped from the upper side to the lower side, but is also pumped as a turbulent flow.
 本発明の基板処理装置では、基板の一面の基板処理領域は基板処理溶液が単純に上方から下方へ落下するだけではなく、乱流となって圧送されることになる。従って、この乱流の基板処理溶液により基板の一面の基板処理領域が良好に処理されることになる。 In the substrate processing apparatus of the present invention, the substrate processing solution on one surface of the substrate is not only simply dropped from the upper side to the lower side, but is also pumped as a turbulent flow. Therefore, the substrate processing region on one surface of the substrate is satisfactorily processed by the turbulent substrate processing solution.
 本発明の第三の基板処理方法は、基板を溶液保持容器に収容されている基板処理溶液に浸漬させ、溶液保持容器に基板処理溶液を上方から下方に落下させて順次供給し、上方から下方に落下する基板処理溶液を基板に圧送する。 In the third substrate processing method of the present invention, the substrate is immersed in a substrate processing solution contained in a solution holding container, the substrate processing solution is dropped into the solution holding container from the top to the bottom, and sequentially supplied, and from above to below. The substrate processing solution falling on the substrate is pumped to the substrate.
 本発明の第五の基板処理装置は、基板処理溶液を収容していて基板が浸漬される溶液保持容器と、浸漬された基板の一面の基板処理領域に基板処理溶液を圧送するとともに吸引する溶液乱流機構と、を有する。 The fifth substrate processing apparatus of the present invention includes a solution holding container that contains a substrate processing solution and in which the substrate is immersed, and a solution that pumps and sucks the substrate processing solution to the substrate processing region on one surface of the immersed substrate. A turbulent flow mechanism.
 従って、本発明の基板処理装置では、溶液保持容器に収容されている基板処理溶液に基板が浸漬される。このような状態の基板処理領域に溶液供給機構が基板処理溶液を圧送するとともに吸引する。このため、基板の一面の基板処理領域は圧送されるとともに吸引される基板処理溶液により処理されることになる。 Therefore, in the substrate processing apparatus of the present invention, the substrate is immersed in the substrate processing solution contained in the solution holding container. The solution supply mechanism pumps and sucks the substrate processing solution into the substrate processing region in such a state. For this reason, the substrate processing region on one surface of the substrate is processed by the substrate processing solution that is pumped and sucked.
 本発明の基板処理装置では、基板の一面の基板処理領域は圧送されるとともに吸引される基板処理溶液により処理されることになる。このため、乱流となる基板処理溶液により基板の一面の基板処理領域のみを簡単かつ迅速に処理することができる。 In the substrate processing apparatus of the present invention, the substrate processing region on one surface of the substrate is processed by the substrate processing solution that is pumped and sucked. For this reason, it is possible to easily and quickly process only the substrate processing region on one surface of the substrate with the substrate processing solution that becomes a turbulent flow.
 本発明の第四の基板処理方法は、溶液保持容器に収容されている基板処理溶液に基板保持部材を浸漬させ、浸漬された基板処理領域の一面に基板処理溶液を圧送するとともに吸引する。 In the fourth substrate processing method of the present invention, the substrate holding member is immersed in the substrate processing solution accommodated in the solution holding container, and the substrate processing solution is pumped and sucked to one surface of the immersed substrate processing region.
 なお、本発明の各種の構成要素は、必ずしも個々に独立した存在である必要はなく、複数の構成要素が一個の部材として形成されていること、一つの構成要素が複数の部材で形成されていること、ある構成要素が他の構成要素の一部であること、ある構成要素の一部と他の構成要素の一部とが重複していること、等でもよい。また、本発明で云う上下方向とは、完全に幾何学的に鉛直である必要はなく、例えば、任意の方向に傾斜していてもよい。 The various components of the present invention do not necessarily have to be independent of each other. A plurality of components are formed as a single member, and a single component is formed of a plurality of members. It may be that a certain component is a part of another component, a part of a certain component overlaps with a part of another component, or the like. Further, the vertical direction referred to in the present invention does not have to be perfectly geometrically vertical, and may be inclined in an arbitrary direction, for example.
 上述した目的、および、その他の目的、特徴および利点は、以下に述べる好適な実施の形態、および、それに付随する以下の図面によって、さらに明らかになる。 The above-described object and other objects, features, and advantages will be further clarified by a preferred embodiment described below and the following accompanying drawings.
本発明の実施形態にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning embodiment of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. フレキシブル回路基板の製造工程を示す工程断面図である。It is process sectional drawing which shows the manufacturing process of a flexible circuit board. フレキシブル回路基板の製造工程を示す工程断面図である。It is process sectional drawing which shows the manufacturing process of a flexible circuit board. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の基板処理装置の変形例を示す断面図である。It is sectional drawing which shows the modification of the substrate processing apparatus of this invention. 本発明の一実施形態にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning one Embodiment of this invention. 隔壁を示す図である。It is a figure which shows a partition. 隔壁を示す図である。It is a figure which shows a partition. 基板処理方法を示す工程図である。It is process drawing which shows a substrate processing method. 基板処理方法を示す工程図である。It is process drawing which shows a substrate processing method. 基板の貫通孔中に電解めっき液が入っていく様子を示す模式図である。It is a schematic diagram which shows a mode that an electrolytic plating solution enters into the through-hole of a board | substrate. 本発明の変形例にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning the modification of this invention. 本発明の変形例にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning the modification of this invention. 本発明の変形例にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning the modification of this invention. 本発明の変形例にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning the modification of this invention. 基板処理装置を槽の上側からみた際の断面図である。It is sectional drawing at the time of seeing a substrate processing apparatus from the upper side of a tank. 本発明の変形例にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning the modification of this invention. 本発明の変形例にかかる基板処理装置を示す断面図である。It is sectional drawing which shows the substrate processing apparatus concerning the modification of this invention. 本発明の実施の形態の基板処理装置を示す模式的な分解斜視図である。1 is a schematic exploded perspective view showing a substrate processing apparatus according to an embodiment of the present invention. 基板処理装置の内部構造を示す模式的な縦断側面図である。It is a typical vertical side view which shows the internal structure of a substrate processing apparatus. 基板処理装置の基板保持部材の構造を示す模式的な正面図である。It is a typical front view which shows the structure of the substrate holding member of a substrate processing apparatus. 基板保持部材に基板をセットする工程を示す工程図である。It is process drawing which shows the process of setting a board | substrate to a board | substrate holding member. 一の変形例の基板処理装置の内部構造を示す模式的な縦断側面図である。It is a typical vertical side view which shows the internal structure of the substrate processing apparatus of one modification. 他の変形例の基板処理装置の内部構造を示す模式的な縦断側面図である。It is a typical vertical side view which shows the internal structure of the substrate processing apparatus of another modification. 本発明の実施の形態の基板処理装置の内部構造を示す模式的な縦断側面図である。It is a typical vertical side view which shows the internal structure of the substrate processing apparatus of embodiment of this invention. 基板処理装置を示す模式的な分解斜視図である。It is a typical disassembled perspective view which shows a substrate processing apparatus. 基板処理装置の構造を示す模式的な正面図である。It is a typical front view which shows the structure of a substrate processing apparatus. 基板処理装置の基板保持部材に基板をセットする工程を示す工程図である。It is process drawing which shows the process of setting a board | substrate to the substrate holding member of a substrate processing apparatus. 本発明の実施の形態の基板処理装置を示す模式的な縦断側面図である。It is a typical vertical side view which shows the substrate processing apparatus of embodiment of this invention. 基板処理装置の内部構造を示す模式的な分解斜視図である。It is a typical disassembled perspective view which shows the internal structure of a substrate processing apparatus. 基板処理装置の構造を示す模式的な正面図である。It is a typical front view which shows the structure of a substrate processing apparatus. 基板処理装置の基板保持部材に基板をセットする工程を示す工程図である。It is process drawing which shows the process of setting a board | substrate to the substrate holding member of a substrate processing apparatus.
 以下、本発明の実施の第一の形態を図面に基づいて説明する。
 はじめに、図1を参照して、本実施形態の基板処理装置1の概要について説明する。
 処理装置1は、基板PBに対し基板処理溶液TLを接触させて、基板PBを処理する装置である。処理装置1は、内部に基板処理溶液TLが供給されるとともに、供給された基板処理溶液TLに基板PBを浸積させる槽11と、槽11内部に配置される基板PBの基板面が鉛直方向に略平行となるように前記基板PBを保持する保持部13とを備える。
 槽11の基板処理溶液TLの供給口111は、保持部13で保持された基板PBよりも鉛直方向上方にあり、槽11の基板処理溶液TLの排出口112は、保持部13で保持された基板PBよりも鉛直方向下方にある。
 処理装置1は、槽11の供給口111から排出口112に向かって基板処理溶液TLを流すと、基板処理溶液TLが、鉛直方向の上方側から下方側に向かって基板面に沿って流れるように構成されている。
Hereinafter, a first embodiment of the present invention will be described with reference to the drawings.
First, the outline of the substrate processing apparatus 1 of the present embodiment will be described with reference to FIG.
The processing apparatus 1 is an apparatus that processes the substrate PB by bringing the substrate processing solution TL into contact with the substrate PB. In the processing apparatus 1, the substrate processing solution TL is supplied to the inside of the processing apparatus 1, and the substrate 11 in which the substrate PB is immersed in the supplied substrate processing solution TL, and the substrate surface of the substrate PB disposed in the tank 11 are in the vertical direction. And a holding portion 13 for holding the substrate PB so as to be substantially parallel to.
The substrate processing solution TL supply port 111 in the tank 11 is vertically above the substrate PB held by the holding unit 13, and the substrate processing solution TL discharge port 112 in the tank 11 is held by the holding unit 13. It is below the substrate PB in the vertical direction.
When the processing apparatus 1 flows the substrate processing solution TL from the supply port 111 of the tank 11 toward the discharge port 112, the substrate processing solution TL flows along the substrate surface from the upper side in the vertical direction toward the lower side. It is configured.
 次に、処理装置1について詳細に説明する。
 基板処理溶液TLは薬液、本実施形態では、電解めっき液TLである。すなわち、処理装置1は、本実施形態では電解めっき装置である。
 槽11は、たとえば、硬質塩ビ槽である。
 槽11には、電解めっき液TLが供給される。槽11の側面には、電解めっき液TLの供給口111が形成されている。この供給口111は、槽11内に配置される基板PBよりも鉛直方向上方に位置する。
 また、槽11の底面には、電解めっき液TLの排出口112が形成されている。排出口112は、本実施形態では、槽11の底面に複数個形成されている。このように複数個排出口112を形成することで、電解めっき液TLを基板PBの基板面に沿ってスムーズに排出することができる。ただし、排出口112は一つであってもよい。
 排出口112は、槽11内に配置される基板PBよりも鉛直方向下方側に位置する。また、排出口112は、供給口111よりも鉛直方向下方側に位置している。
 なお、必要に応じて、図2に示すように、排出口112に、配管17およびポンプP2を接続し、ポンプP2で電解めっき液TLを吸引することで、排出口112から排出される電解めっき液TLの流速を調整してもよい。
 なお、本実施形態では、排出口112と、第二槽14とは配管で接続されておらず、排出口112から排出される電解めっき液TLは、第二槽14内に自然落下する。
 また、必要に応じて、槽11から排出される電解めっき液TLの量を調整する調整手段を設けてもよい。たとえば、一部の排出口112をふさぐ栓を前記調整手段として設けてもよく、また、排出口112の大きさを調整する調整手段(たとえば、排出口112の一部をふさぎ、排出口112の開口度合いを調整する板材)を設けてもよい。
 なお、本実施形態では、電解めっきを行う際、槽11内には、基板PBが一枚配置される。
Next, the processing apparatus 1 will be described in detail.
The substrate processing solution TL is a chemical solution, in this embodiment, an electrolytic plating solution TL. That is, the processing apparatus 1 is an electrolytic plating apparatus in this embodiment.
The tank 11 is, for example, a hard PVC tank.
The tank 11 is supplied with an electrolytic plating solution TL. A supply port 111 for the electrolytic plating solution TL is formed on the side surface of the tank 11. The supply port 111 is positioned above the substrate PB arranged in the tank 11 in the vertical direction.
Further, a discharge port 112 for the electrolytic plating solution TL is formed on the bottom surface of the tank 11. In the present embodiment, a plurality of discharge ports 112 are formed on the bottom surface of the tank 11. By forming a plurality of discharge ports 112 in this way, the electrolytic plating solution TL can be discharged smoothly along the substrate surface of the substrate PB. However, the number of the discharge ports 112 may be one.
The discharge port 112 is located on the lower side in the vertical direction than the substrate PB disposed in the tank 11. Further, the discharge port 112 is located on the lower side in the vertical direction than the supply port 111.
In addition, as shown in FIG. 2, the piping 17 and the pump P2 are connected to the discharge port 112 as needed, and the electroplating discharged from the discharge port 112 by sucking the electrolytic plating solution TL with the pump P2. The flow rate of the liquid TL may be adjusted.
In the present embodiment, the discharge port 112 and the second tank 14 are not connected by piping, and the electrolytic plating solution TL discharged from the discharge port 112 naturally falls into the second tank 14.
Moreover, you may provide the adjustment means which adjusts the quantity of the electroplating liquid TL discharged | emitted from the tank 11, as needed. For example, a plug that blocks a part of the discharge ports 112 may be provided as the adjusting means, and an adjusting unit that adjusts the size of the discharge ports 112 (for example, a part of the discharge ports 112 is blocked to A plate member for adjusting the degree of opening may be provided.
In the present embodiment, one substrate PB is disposed in the tank 11 when performing electrolytic plating.
 この槽11内には、複数の陽極12が設置されている。本実施形態では、陽極12は2つ設置されている。一方の陽極12は、槽11内に配置された基板PBの一方の基板面と対向するように配置され、他方の陽極12は、槽11内に配置された基板PBの他方の基板面と対向するように配置されている。陽極12は、たとえば、含リン銅である。 A plurality of anodes 12 are installed in the tank 11. In the present embodiment, two anodes 12 are installed. One anode 12 is disposed to face one substrate surface of the substrate PB disposed in the tank 11, and the other anode 12 is opposed to the other substrate surface of the substrate PB disposed in the tank 11. Are arranged to be. The anode 12 is, for example, phosphorous copper.
 保持部13は、基板PBを保持するとともに、基板PB表面の金属膜22(図4(B)参照)を図示しない陰極に接続するものである。保持部13は、たとえば、基板PBの上端部を挟む挟持部を備えたものであり、金属等の導電性材料で構成される。保持部13は、基板PBを保持し上下方向に駆動可能であり、槽11内に基板PBを配置したり、槽11から基板PBを除去したりする。
 保持部13に保持された基板PBは、基板面が鉛直方向と略平行となるように槽11内に配置されることとなる。
The holding unit 13 holds the substrate PB and connects the metal film 22 (see FIG. 4B) on the surface of the substrate PB to a cathode (not shown). The holding unit 13 includes, for example, a clamping unit that sandwiches the upper end of the substrate PB, and is made of a conductive material such as metal. The holding unit 13 holds the substrate PB and can be driven in the vertical direction, and arranges the substrate PB in the tank 11 or removes the substrate PB from the tank 11.
The board | substrate PB hold | maintained at the holding | maintenance part 13 will be arrange | positioned in the tank 11 so that a board | substrate surface may become substantially parallel to a perpendicular direction.
 処理装置1は、槽11へ供給するための電解めっき液TLが充填された第二槽(調整槽)14を備える。第二槽14は、槽11からオーバーフローした電解めっき液TLを受ける役割も果たすため、第二槽14は槽11の鉛直方向下方側に配置される。
 ここで、図3に示すように、第二槽14内の電解めっき液TLを撹拌するために、バブリング装置15を第二槽14に接続してもよい。このようにすることで、第二槽14内の電解めっき液TLの濃度を均一なものとすることができる。なお、バブリング装置15は、図2に示す処理装置1に設けてもよい。
 第二槽14の電解めっき液の排出口と、槽11の供給口111とは、配管16で接続されている。配管16および配管16に接続されているポンプP1を介して電解めっき液TLが第二槽14から槽11へと供給される。
 なお、配管16には、フィルター(図示せず)が設けられている。配管16を通る電解めっき液TL中の異物をフィルターで除去することができる。
The processing apparatus 1 includes a second tank (conditioning tank) 14 that is filled with an electrolytic plating solution TL to be supplied to the tank 11. Since the second tank 14 also serves to receive the electrolytic plating solution TL that has overflowed from the tank 11, the second tank 14 is disposed on the lower side in the vertical direction of the tank 11.
Here, as shown in FIG. 3, a bubbling device 15 may be connected to the second tank 14 in order to stir the electrolytic plating solution TL in the second tank 14. By doing in this way, the density | concentration of the electroplating liquid TL in the 2nd tank 14 can be made uniform. The bubbling device 15 may be provided in the processing device 1 shown in FIG.
The discharge port of the electrolytic plating solution in the second tank 14 and the supply port 111 of the tank 11 are connected by a pipe 16. The electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 via the pipe 16 and the pump P1 connected to the pipe 16.
The pipe 16 is provided with a filter (not shown). Foreign matter in the electrolytic plating solution TL passing through the pipe 16 can be removed with a filter.
 次に、処理装置1を使用した基板PBの基板処理方法について説明する。
 はじめに、図4(A)に示すような基材20を用意する。
 この基材20は、絶縁層21と、この絶縁層21の表裏面に貼り付けられた金属膜22(たとえば、銅膜)とを有する。絶縁層21の厚みは、たとえば、5μm以上、100μm以下であり、金属膜22の厚みは、たとえば、1μm以上、50μm以下である。基材20全体の厚みは、たとえば、10μm以上、200μm以下である。
 なお、基材20の厚みは上記に限定されるものではなく、例えば、600μmなどでも可能である。
Next, a substrate processing method for the substrate PB using the processing apparatus 1 will be described.
First, a base material 20 as shown in FIG. 4 (A) is prepared.
The base material 20 includes an insulating layer 21 and a metal film 22 (for example, a copper film) attached to the front and back surfaces of the insulating layer 21. The thickness of the insulating layer 21 is, for example, 5 μm or more and 100 μm or less, and the thickness of the metal film 22 is, for example, 1 μm or more and 50 μm or less. The thickness of the whole base material 20 is 10 micrometers or more and 200 micrometers or less, for example.
In addition, the thickness of the base material 20 is not limited to the above, For example, 600 micrometers etc. are possible.
 次に、図4(B)に示すように、一方の金属膜22および絶縁層21を貫通する孔201を形成する。一方の金属膜22を貫通する孔は、エッチングにより形成し、その後、絶縁層21を貫通する孔をレーザで形成してもよい。
 次に、金属膜22上および孔201内部に無電解めっきを施す。これにより、基板PBが得られる。
Next, as shown in FIG. 4B, a hole 201 penetrating one metal film 22 and the insulating layer 21 is formed. The hole penetrating one metal film 22 may be formed by etching, and then the hole penetrating the insulating layer 21 may be formed by laser.
Next, electroless plating is performed on the metal film 22 and inside the hole 201. Thereby, the substrate PB is obtained.
 その後、基板PB上に金属膜22の一部を被覆するマスクMを配置し、処理装置1を使用して、孔201内部および金属膜22上に電解めっきを施す(図5(A)参照)。
 はじめに、第二槽14から槽11へ、配管16およびポンプP1を介して、電解めっき液TLを供給する。槽11内を電解めっき液TLで満たしておく。
 その後、基板PBを保持部13に保持させて、基板PBを槽11内に配置し、基板PBを電解めっき液TL中に浸漬させる。このとき、基板PBの基板面が鉛直方向と略平行方向となるように、基板PBが槽11内に配置される。その後、陰極(図示略)および陽極12間を通電することで、基板PBに対する電解めっきが開始される。電解めっきを行う際、第二槽14から槽11へは随時電解めっき液TLが供給される。これにより、槽11内の電解めっき液TLは、鉛直方向上側から、鉛直方向下側に向かって、流れることとなる(矢印Y1参照)。鉛直方向上側から鉛直方向下側に向かって流れる電解めっき液TLは、基板PBの一対の基板面に沿って流れ、さらには、孔201内部にも供給される。
 また、電解めっきを行う間、基板PB全体が電解めっき液TL中に浸漬した状態となる。
Thereafter, a mask M covering a part of the metal film 22 is disposed on the substrate PB, and electrolytic plating is performed on the inside of the hole 201 and on the metal film 22 using the processing apparatus 1 (see FIG. 5A). .
First, the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 through the pipe 16 and the pump P1. The tank 11 is filled with the electrolytic plating solution TL.
Thereafter, the substrate PB is held by the holding unit 13, the substrate PB is placed in the tank 11, and the substrate PB is immersed in the electrolytic plating solution TL. At this time, the substrate PB is disposed in the tank 11 so that the substrate surface of the substrate PB is substantially parallel to the vertical direction. Thereafter, electroplating on the substrate PB is started by energizing between the cathode (not shown) and the anode 12. When performing electrolytic plating, the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 as needed. As a result, the electrolytic plating solution TL in the tank 11 flows from the upper side in the vertical direction toward the lower side in the vertical direction (see arrow Y1). The electrolytic plating solution TL flowing from the upper side in the vertical direction toward the lower side in the vertical direction flows along the pair of substrate surfaces of the substrate PB, and is also supplied into the holes 201.
Further, during the electrolytic plating, the entire substrate PB is immersed in the electrolytic plating solution TL.
 さらに、電解めっきを行う際、第二槽14から槽11へは随時電解めっき液TLが供給されており、電解めっき液TLの第二槽14から槽11への供給量は、槽11から排出される電解めっき液TLの量よりも多い。従って、槽11の上部からは、電解めっき液TLがオーバーフローする。オーバーフローした電解めっき液TLは、矢印Y2方向に流れ、第二槽14で回収される。
 さらに、第二槽14には、槽11の排出口112からの電解めっき液TLが供給される。
 第二槽14内の電解めっき液TLは、配管16およびポンプP1を介して再度槽11に供給されることとなる。
 なお、必要に応じて、第二槽14内の電解めっき液TLの金属濃度等を分析し、第二槽14内の電解めっき液TLの金属濃度等を調整してもよい。
Furthermore, when performing electroplating, the electrolytic plating solution TL is supplied from the second tank 14 to the tank 11 at any time, and the supply amount of the electrolytic plating solution TL from the second tank 14 to the tank 11 is discharged from the tank 11. More than the amount of electrolytic plating solution TL applied. Therefore, the electrolytic plating solution TL overflows from the upper part of the tank 11. The overflowed electrolytic plating solution TL flows in the direction of the arrow Y2 and is collected in the second tank 14.
Further, the electrolytic plating solution TL is supplied to the second tank 14 from the discharge port 112 of the tank 11.
The electrolytic plating solution TL in the second tank 14 is supplied again to the tank 11 via the pipe 16 and the pump P1.
If necessary, the metal concentration or the like of the electrolytic plating solution TL in the second tank 14 may be analyzed to adjust the metal concentration or the like of the electrolytic plating solution TL in the second tank 14.
 以上のような電解めっきの工程により、図5(A)に示すように、孔201内にビアとなる導電体26が形成されるとともに、金属膜22上に電解めっきによる金属膜が形成される(金属膜23は、金属膜22と金属膜22上のめっき膜を示す)。 By the electrolytic plating process as described above, as shown in FIG. 5A, the conductor 26 serving as a via is formed in the hole 201 and the metal film by electrolytic plating is formed on the metal film 22. (The metal film 23 indicates a metal film 22 and a plating film on the metal film 22).
 次に、槽11から電解めっきが施された基板PBを取り出し、洗浄する。
 その後、マスクMが形成されていた部分の金属膜22をフラッシュエッチングにより除去し、図5(B)に示すように、第一回路層25、第二回路層24を形成する。
 以上の工程により、基板PBに対し電解めっき処理したフレキシブル回路基板PB7を得ることができる。
Next, the substrate PB that has been subjected to electrolytic plating is taken out of the tank 11 and cleaned.
Thereafter, the portion of the metal film 22 on which the mask M has been formed is removed by flash etching, and a first circuit layer 25 and a second circuit layer 24 are formed as shown in FIG.
Through the above steps, the flexible circuit board PB7 obtained by subjecting the substrate PB to electrolytic plating can be obtained.
 次に、本実施形態の作用効果について説明する。
 本実施形態では、基板PBを槽11内の電解めっき液TL中に浸漬させた状態で、槽11内の電解めっき液TLを鉛直方向の上方側から、下方側に向かって基板PBの基板面に沿って流している。
 これにより基板PB表面付近で電解めっき液TLが滞留してしまうことが防止され、基板PBには、常に新鮮な電解めっき液TLが接触することとなる。これにより、基板PBに対し所望のめっき膜を安定的に成膜することができる。
Next, the effect of this embodiment is demonstrated.
In the present embodiment, the substrate surface of the substrate PB is moved from the upper side in the vertical direction toward the lower side while the substrate PB is immersed in the electrolytic plating solution TL in the bath 11. It is flowing along.
As a result, the electrolytic plating solution TL is prevented from staying near the surface of the substrate PB, and the fresh electrolytic plating solution TL always comes into contact with the substrate PB. Thereby, a desired plating film can be stably formed on the substrate PB.
 また、本実施形態では、槽11内の電解めっき液TLを鉛直方向の上方側から、下方側に向かって流している。電解めっき液TLが重力に従って流れることとなるので、電解めっき液TLをスムーズに流すことができる。また、電解めっき液TLを重力に従って流すことで、電解めっき液TLの流れが安定したものとなる。
 さらに、電解めっき液TLを鉛直方向の上方側から、下方側に向かって重力に従って流すことで、処理装置1の装置構成の複雑化を抑制できる。図2に示すような、電解めっき液TLを槽11から排出するためのポンプP2を使用した場合であっても、ポンプP2を吸引力が比較的大きいポンプとしなくても、槽11から電解めっき液TLを排出させることができる。
In the present embodiment, the electrolytic plating solution TL in the tank 11 flows from the upper side in the vertical direction toward the lower side. Since the electroplating solution TL flows according to gravity, the electroplating solution TL can flow smoothly. Moreover, the flow of the electrolytic plating solution TL is stabilized by flowing the electrolytic plating solution TL according to gravity.
Furthermore, by flowing the electrolytic plating solution TL from the upper side in the vertical direction toward the lower side according to gravity, it is possible to suppress complication of the apparatus configuration of the processing apparatus 1. Even when the pump P2 for discharging the electrolytic plating solution TL from the tank 11 as shown in FIG. 2 is used, the electrolytic plating from the tank 11 can be performed without using the pump P2 as a pump having a relatively large suction force. The liquid TL can be discharged.
 さらに、本実施形態では、基板PBを槽11内の電解めっき液TL中に浸漬させた状態で、槽11内の電解めっき液TLを鉛直方向の上方側から、下方側に向かって基板PBの基板面に沿って流し、排出している。
 これにより、電解めっき液TL中に異物が混入していても、槽11内から異物を排出することができる。そのため基板PBに異物が付着することを抑制することができる。
Furthermore, in the present embodiment, the electrolytic plating solution TL in the tank 11 is immersed in the electrolytic plating solution TL in the tank 11 from the upper side in the vertical direction toward the lower side. It flows along the substrate surface and is discharged.
Thereby, even if foreign matter is mixed in the electrolytic plating solution TL, the foreign matter can be discharged from the tank 11. Therefore, it can suppress that a foreign material adheres to the board | substrate PB.
 また、本実施形態では、基板PBはフレキシブル回路基板用の基板であり、その厚みが10~200μmと比較的薄いものとなっている。
 このような基板PBを電解めっきL中に浸漬させた場合、電解めっき液TL中で基板PBがふらついてしまう。そのため、基板PBが陽極に近づいたり、離れたりすることで、基板PBに対し所望の電解めっきを施すことが難しいことがある。
 これに対し、本実施形態では、基板PBを電解めっき液TL中で浸漬させた状態で、電解めっき液TLを流している。基板PBの一方の基板面側および他方の基板面側で、電解めっき液TLが鉛直方向の上方側から、下方側に向かって流れるため、基板PBが電解めっき液TL中でふらつくことが防止される。これにより、基板PBに対し所望の電解めっきを施すことができる。また、基板PBのふらつきを防止できるので、基板PBにしわが発生したり、基板PBが破損してしまうことを抑制することができる。
In the present embodiment, the substrate PB is a substrate for a flexible circuit board, and the thickness thereof is relatively thin, 10 to 200 μm.
When such a substrate PB is immersed in the electroplating L, the substrate PB will fluctuate in the electroplating solution TL. Therefore, it may be difficult to perform desired electrolytic plating on the substrate PB when the substrate PB approaches or separates from the anode.
On the other hand, in this embodiment, the electrolytic plating solution TL is allowed to flow while the substrate PB is immersed in the electrolytic plating solution TL. Since the electrolytic plating solution TL flows from the upper side in the vertical direction toward the lower side on the one substrate surface side and the other substrate surface side of the substrate PB, the substrate PB is prevented from fluctuating in the electrolytic plating solution TL. The Thereby, desired electroplating can be performed with respect to the board | substrate PB. Moreover, since the wobbling of the substrate PB can be prevented, it is possible to prevent the substrate PB from being wrinkled or damaged.
 さらに、本実施形態では、槽11から電解めっき液TLをオーバーフローさせて電解めっきを行っている。オーバーフローさせることで、基板PBが電解めっき液TLに浸漬した状態を確実に維持しながら電解めっきを基板PBに対し施すことができる。 Furthermore, in this embodiment, electrolytic plating is performed by overflowing the electrolytic plating solution TL from the tank 11. By making it overflow, electrolytic plating can be applied to the substrate PB while reliably maintaining the state in which the substrate PB is immersed in the electrolytic plating solution TL.
 また、本実施形態では、槽11内に基板PBを一枚配置して、電解めっきを行っている。そのため、槽11は、基板PBを配置でき、基板PBの基板面側で電解めっき液TLを流すことができる程度の大きさでよい。これにより、処理装置1の大型化を抑制することができる。 Further, in the present embodiment, one substrate PB is disposed in the tank 11 and electrolytic plating is performed. Therefore, the tank 11 may have a size that allows the substrate PB to be disposed and allows the electrolytic plating solution TL to flow on the substrate surface side of the substrate PB. Thereby, the enlargement of the processing apparatus 1 can be suppressed.
 なお、本発明は前述の実施形態に限定されるものではなく、本発明の目的を達成できる範囲での変形、改良等は本発明に含まれるものである。
 例えば、前記実施形態では、本発明の基板処理装置は、電解めっき装置1であるとしたが、これに限られるものではない。図6に示すように、処理装置1の陽極を取り除き、本発明の基板処理装置を無電解めっき装置1Aとしてもよい。
 図6に示す処理装置1Aは、処理装置1から陽極を取り除いた点以外は、処理装置1と同じである。第二槽14、槽11内には、無電解めっき液TLが充填されている。
 また、図6に示す処理装置1Aを基板表面の金属層等をエッチングするエッチング装置としてもよい。さらに、処理装置1Aを現像装置としてもよい。基板表面の感光性樹脂層に光を照射し、未露光部分を除去するための現像液を第二槽14、槽11内に充填し、処理装置1Aにより、基板表面の感光性樹脂層の未露光部分を除去してもよい。
 さらに、処理装置1Aを、基板に形成されたマスク等を剥離処理する剥離装置としてもよい。この場合には、マスク等を剥離するための剥離液を第二槽14、槽11内に充填すればよい。
It should be noted that the present invention is not limited to the above-described embodiments, and modifications, improvements, and the like within the scope that can achieve the object of the present invention are included in the present invention.
For example, in the above embodiment, the substrate processing apparatus of the present invention is the electroplating apparatus 1, but is not limited thereto. As shown in FIG. 6, the anode of the processing apparatus 1 may be removed, and the substrate processing apparatus of the present invention may be an electroless plating apparatus 1A.
The processing apparatus 1A shown in FIG. 6 is the same as the processing apparatus 1 except that the anode is removed from the processing apparatus 1. The second tank 14 and the tank 11 are filled with an electroless plating solution TL.
Further, the processing apparatus 1A shown in FIG. 6 may be an etching apparatus for etching a metal layer or the like on the substrate surface. Furthermore, the processing apparatus 1A may be a developing device. The photosensitive resin layer on the substrate surface is irradiated with light, and a developing solution for removing unexposed portions is filled into the second tank 14 and the tank 11, and the photosensitive resin layer on the substrate surface is uncoated by the processing apparatus 1A. The exposed part may be removed.
Furthermore, the processing apparatus 1A may be a peeling apparatus that peels off a mask or the like formed on the substrate. In this case, what is necessary is just to fill the 2nd tank 14 and the tank 11 with the peeling liquid for peeling a mask etc.
 また、図7に示すように、本発明の基板処理装置を水洗装置1Bとしてもよい。水洗装置1Bは、処理装置1の陽極を取り除くとともに、槽14A~14Cを設けた点以外は、処理装置1と同じ構成である。
 水洗装置1Bの第二槽14A内には基板洗浄前の水が充填されている。
 第二槽14Aから槽11へ水が供給され、槽11内で水が鉛直方向の上方側から下方側にむかって流れ、基板PBが洗浄される。
 その後、排出口112からは洗浄後の水が排出され第三槽14Bに供給される。
第三槽14B内の水は、第四槽(浄化槽)14Cに供給され、第四槽14C内で水が清浄化され、金属等の不純物が除去される。第四槽14C内で清浄化された水は、第二槽14Aに供給される。第二槽14Aに供給された水は、再度槽11に供給されることととなる。
 このような水洗装置1Bにおいては、基板PBには常にきれいな水が接触することとなり、基板PBが汚染されてしまうことを防止できる。
 さらには、基板を水槽に単に浸漬させて水洗する方法では、一つの水槽で確実に洗浄することが難しく、水槽を複数設けて、多段階で水洗する必要がある。
 これに対し、水洗装置1Bを使用すれば、基板PBには常にきれいな水が接触するため、多段階で水洗を行う必要がなく、基板PBの処理プロセスを簡略化することができる。
 なお、水洗装置1Bにおいて、第三槽14B内の水を第四槽14Cにて清浄化せずに、廃棄してもよい。
 また、処理装置1A、1Bにおいて、図2と同様に、排出口112に配管17およびポンプP2を接続してもよい。
Further, as shown in FIG. 7, the substrate processing apparatus of the present invention may be a water washing apparatus 1B. The water washing apparatus 1B has the same configuration as the processing apparatus 1 except that the anode of the processing apparatus 1 is removed and tanks 14A to 14C are provided.
The second tank 14A of the water washing apparatus 1B is filled with water before substrate cleaning.
Water is supplied from the second tank 14A to the tank 11, and the water flows in the tank 11 from the upper side to the lower side in the vertical direction, and the substrate PB is cleaned.
Thereafter, the washed water is discharged from the discharge port 112 and supplied to the third tank 14B.
The water in the third tank 14B is supplied to the fourth tank (purification tank) 14C, and the water is purified in the fourth tank 14C to remove impurities such as metals. The water cleaned in the fourth tank 14C is supplied to the second tank 14A. The water supplied to the second tank 14A will be supplied to the tank 11 again.
In such a water washing apparatus 1B, clean water always comes into contact with the substrate PB, and the substrate PB can be prevented from being contaminated.
Furthermore, in the method of simply immersing the substrate in the water tank and washing with water, it is difficult to reliably wash with one water tank, and it is necessary to provide a plurality of water tanks and perform water washing in multiple stages.
On the other hand, if the water washing apparatus 1B is used, clean water always comes into contact with the substrate PB, so there is no need to perform water washing in multiple stages, and the processing process of the substrate PB can be simplified.
In the washing apparatus 1B, the water in the third tank 14B may be discarded without being purified in the fourth tank 14C.
Further, in the processing apparatuses 1A and 1B, the piping 17 and the pump P2 may be connected to the discharge port 112 as in FIG.
 さらに、図8に示すように、処理装置1Aの槽11の開口を蓋材18(加圧手段)で塞ぎ、槽11内の液に対し、上方から圧力をかけて、排出口から排出される基板処理溶液TLの流速を調整してもよい。この場合、保持部13Bで基板PBを保持する。
 処理装置1Bや処理装置1においても、同様に、槽11の開口を蓋材で塞ぎ、槽11内の基板処理溶液に対し、上方から圧力をかけて、排出口から排出される基板処理溶液の流速を調整してもよい。
 この場合においても、図2と同様に、排出口112に配管17およびポンプP2を接続してもよい。
Further, as shown in FIG. 8, the opening of the tank 11 of the processing apparatus 1 </ b> A is closed with a lid 18 (pressurizing means), and the liquid in the tank 11 is pressurized from above and discharged from the discharge port. The flow rate of the substrate processing solution TL may be adjusted. In this case, the substrate PB is held by the holding unit 13B.
Similarly, in the processing apparatus 1 </ b> B and the processing apparatus 1, the opening of the tank 11 is closed with a lid member, and the substrate processing solution in the tank 11 is pressurized from above to apply the substrate processing solution discharged from the discharge port. The flow rate may be adjusted.
Also in this case, the piping 17 and the pump P2 may be connected to the discharge port 112 as in FIG.
 さらに、図9に示すように、処理装置1A内の基板PBに対し、基板PBの処理中(基板処理溶液TLを基板上方側から下方側に向かって基板面に沿って流す際)に振動(超音波振動)を加えてもよい。符号19は超音波振動発生装置であり、矢印Y3は、超音波振動発生装置からの超音波を意味する。
 このようにすることで、基板PBに付着した気泡を除去することができる。この場合においても、図2と同様に、排出口112に配管17およびポンプP2を接続してもよい。
 なお、処理装置1、1Bにおいても、超音波振動発生装置19を設けてもよい。
Further, as shown in FIG. 9, vibration (when the substrate processing solution TL flows along the substrate surface from the upper side of the substrate to the lower side) during the processing of the substrate PB on the substrate PB in the processing apparatus 1 </ b> A ( Ultrasonic vibration) may be added. Reference numeral 19 denotes an ultrasonic vibration generator, and an arrow Y3 means an ultrasonic wave from the ultrasonic vibration generator.
By doing so, bubbles attached to the substrate PB can be removed. Also in this case, the piping 17 and the pump P2 may be connected to the discharge port 112 as in FIG.
Note that the ultrasonic vibration generator 19 may also be provided in the processing apparatuses 1 and 1B.
 さらに、前記実施形態では、処理装置1の槽11内に一枚の基板PBを配置し、基板PBの一対の基板面に対し電解めっき処理したが、これに限られるものではない。
 たとえば、図10に示すように、板状の保持部13Aの表裏面にそれぞれ基板PBを配置して、一対の基板PBそれぞれの一方の基板面に電解めっきを施してもよい。なお、処理装置1A、1B等においても、保持部13にかえて、保持部13Aを使用し、一対の基板PBそれぞれの一方の基板面に電解めっきを施してもよい。
Furthermore, in the said embodiment, although one board | substrate PB was arrange | positioned in the tank 11 of the processing apparatus 1, and it electroplated with respect to a pair of board | substrate surface of the board | substrate PB, it is not restricted to this.
For example, as shown in FIG. 10, the substrates PB may be disposed on the front and back surfaces of the plate-shaped holding portion 13 </ b> A, respectively, and electrolytic plating may be performed on one substrate surface of each of the pair of substrates PB. In the processing apparatuses 1A, 1B, etc., the holding unit 13A may be used instead of the holding unit 13, and one of the substrate surfaces of the pair of substrates PB may be subjected to electrolytic plating.
 また、前記実施形態では、基板PBの孔201内にも電解めっきを施したが、孔201が形成されていない基板表面に電解めっきを施してもよい。処理装置1A、1Bにおいても同様であり、孔201が形成されていない基板表面を処理してもよい。
 さらに、前記実施形態では、基板PBをフレキシブル回路基板用の基板としたが、これに限らず、リジッド回路基板用の基板を使用してもよい。
 また、前記実施形態では、基板PBの基板面が鉛直方向と平行となるように、基板PBが槽内に配置されていたが、これに限らず、たとえば、図11に示すように、基板PBの基板面が鉛直方向に対し傾斜するように基板PBを配置してもよい。このように基板PBを傾斜して配置した場合であっても、前記実施形態と同様の効果を奏することができる。
Moreover, in the said embodiment, although electroplating was performed also in the hole 201 of the board | substrate PB, you may electroplate on the board | substrate surface in which the hole 201 is not formed. The same applies to the processing apparatuses 1A and 1B, and the surface of the substrate on which the hole 201 is not formed may be processed.
Furthermore, in the said embodiment, although the board | substrate PB was used as the board | substrate for flexible circuit boards, it is not restricted to this, You may use the board | substrate for rigid circuit boards.
Moreover, in the said embodiment, although the board | substrate PB was arrange | positioned in the tank so that the board | substrate surface of the board | substrate PB might become parallel to a perpendicular direction, it is not restricted to this, For example, as shown in FIG. The substrate PB may be arranged so that the substrate surface of the substrate is inclined with respect to the vertical direction. Even when the substrate PB is disposed in an inclined manner as described above, the same effects as those of the embodiment can be obtained.
 つぎに、本発明の実施の第二の形態を図面に基づいて説明する。
 はじめに、図12を参照して、本実施形態の基板基板処理装置2の概要について説明する。
 基板処理装置2は、基板PBの一方の基板面側から他方の基板面側にむかって貫通する貫通孔201(図15参照)が形成された基板PBの前記貫通孔201内に基板処理溶液TLを接触させて、基板PBを処理するものである。
 基板処理装置2は、内部に前記基板処理溶液TLが供給されるとともに、供給された前記基板処理溶液TLに前記基板PBを浸積させる槽21を有する。槽21内には、基板PBの一対の基板面が鉛直方向と略平行となるように基板PBを保持し、保持した前記基板PBとともに前記槽21を、第一槽211および第二槽212に区画する隔壁213が形成されている。
 第一槽211の基板処理溶液の第一供給口211Aおよび前記第二槽212の基板処理溶液の第二供給口212Aは、前記隔壁213で保持された前記基板PBよりも鉛直方向上方にあり、第一槽211の基板処理溶液の第一排出口211Bおよび前記第二槽212の基板処理溶液の第二排出口212Bは、前記隔壁213で保持された前記基板PBよりも鉛直方向下方にある。
 当該基板基板処理装置2は、第一供給口211Aから第一排出口211Bに向かって前記基板処理溶液TLを流すとともに、前記第二供給口212Aから第二排出口212Bに向かって前記基板処理溶液TLを流すと、前記基板処理溶液TLが、鉛直方向の上方側から下方側に向かって前記基板PBの一方の基板面および他方の基板面に沿って流れるように構成され、基板PBの一方の基板面に沿って流れる基板処理溶液TLの平均流速(平均線速)と、基板PBの他方の基板面に沿って流れる基板処理溶液TLの平均流速(平均線速)とを異ならせる調整手段を有する。
Next, a second embodiment of the present invention will be described with reference to the drawings.
First, the outline of the substrate processing apparatus 2 of the present embodiment will be described with reference to FIG.
The substrate processing apparatus 2 includes a substrate processing solution TL in the through hole 201 of the substrate PB in which a through hole 201 (see FIG. 15) penetrating from one substrate surface side to the other substrate surface side of the substrate PB is formed. To process the substrate PB.
The substrate processing apparatus 2 includes a tank 21 in which the substrate processing solution TL is supplied and the substrate PB is immersed in the supplied substrate processing solution TL. In the tank 21, the substrate PB is held so that a pair of substrate surfaces of the substrate PB is substantially parallel to the vertical direction, and the tank 21 is held in the first tank 211 and the second tank 212 together with the held substrate PB. Partition walls 213 are formed.
The first supply port 211A of the substrate processing solution in the first tank 211 and the second supply port 212A of the substrate processing solution in the second tank 212 are vertically above the substrate PB held by the partition wall 213, The first discharge port 211B of the substrate processing solution in the first tank 211 and the second discharge port 212B of the substrate processing solution in the second tank 212 are below the substrate PB held by the partition wall 213 in the vertical direction.
The substrate substrate processing apparatus 2 allows the substrate processing solution TL to flow from the first supply port 211A toward the first discharge port 211B, and the substrate processing solution from the second supply port 212A toward the second discharge port 212B. When the TL is flowed, the substrate processing solution TL is configured to flow along one substrate surface and the other substrate surface of the substrate PB from the upper side to the lower side in the vertical direction. Adjusting means for differentiating the average flow velocity (average linear velocity) of the substrate treatment solution TL flowing along the substrate surface and the average flow velocity (average linear velocity) of the substrate treatment solution TL flowing along the other substrate surface of the substrate PB; Have.
 次に、基板処理装置2について詳細に説明する。
 基板処理溶液TLは薬液、本実施形態では、電解めっき液TLである。すなわち、基板処理装置2は、本実施形態では電解めっき装置である。
 槽21は、たとえば、硬質塩ビ槽であり、本実施形態では、直方体あるいは立方体形状である。
 槽21は、隔壁213を備える。この隔壁213は、たとえば、槽21の底面部に立設され、基板PBの一対の基板面が鉛直方向と略平行となるように基板PBを保持する。そして、隔壁213は、保持した基板PBとともに槽21を、第一槽211および第二槽212に区画する。
 ここで、図13および図14に隔壁213を示す。図13は、図12のx軸方向から見た図であり、図14は、隔壁213の分解図である。
 本実施形態では、隔壁213は、一対の板材213Aで構成される。板材213Aの中央部には、開口213A1が形成されており、この一方の板材213Aの開口213A1をふさぐように、基板PBを配置する。そして、他方の板材213Aを重ね合わせ、基板PBの周縁部を板材213Aで挟む。これにより、隔壁213に基板PBが保持されることとなる。
 槽21の底面部には、隔壁213をはめ込むための、凹部(図示略)が形成されている。
Next, the substrate processing apparatus 2 will be described in detail.
The substrate processing solution TL is a chemical solution, in this embodiment, an electrolytic plating solution TL. That is, the substrate processing apparatus 2 is an electrolytic plating apparatus in the present embodiment.
The tank 21 is, for example, a hard PVC tank, and in the present embodiment, has a rectangular parallelepiped shape or a cubic shape.
The tank 21 includes a partition wall 213. For example, the partition wall 213 is erected on the bottom surface of the tank 21 and holds the substrate PB so that the pair of substrate surfaces of the substrate PB is substantially parallel to the vertical direction. The partition wall 213 partitions the tank 21 into the first tank 211 and the second tank 212 together with the held substrate PB.
Here, the partition 213 is shown in FIG. 13 and FIG. 13 is a view as seen from the x-axis direction of FIG. 12, and FIG. 14 is an exploded view of the partition 213.
In the present embodiment, the partition wall 213 includes a pair of plate members 213A. An opening 213A1 is formed at the center of the plate material 213A, and the substrate PB is arranged so as to close the opening 213A1 of the one plate material 213A. Then, the other plate material 213A is overlapped, and the peripheral portion of the substrate PB is sandwiched between the plate materials 213A. As a result, the substrate PB is held on the partition wall 213.
A recess (not shown) for fitting the partition wall 213 is formed on the bottom surface of the tank 21.
 図12に示すように、槽21の側壁には、電解めっき液TLの第一供給口211Aが形成されている。第一供給口211Aから第一槽211内に電解めっき液TLが供給される。第一供給口211Aは、隔壁213に保持された基板PBよりも鉛直方向上方に位置している。そして、第一槽211内の電解めっき液TLは、基板PBの基板面に沿って流れ、第一排出口211Bから排出される。
 第一排出口211Bは、槽21の底面部に形成されており、隔壁213に保持された基板PBよりも鉛直方向下方に位置している。
 ここで、第一排出口211Bは、ひとつの貫通孔であってもよく、複数あってもよい。
As shown in FIG. 12, a first supply port 211 </ b> A for the electrolytic plating solution TL is formed on the side wall of the tank 21. The electrolytic plating solution TL is supplied into the first tank 211 from the first supply port 211A. The first supply port 211A is located above the substrate PB held by the partition wall 213 in the vertical direction. The electrolytic plating solution TL in the first tank 211 flows along the substrate surface of the substrate PB and is discharged from the first discharge port 211B.
The first discharge port 211 </ b> B is formed on the bottom surface of the tank 21, and is positioned below the substrate PB held by the partition wall 213 in the vertical direction.
Here, the first outlet 211B may be a single through hole or a plurality of holes.
 槽21の側壁には、電解めっき液TLの第二供給口212Aが形成されている。第二供給口212Aから第二槽212内に電解めっき液TLが供給される。第二供給口212Aは、隔壁213に保持された基板PBよりも鉛直方向上方に位置している。そして、第一槽211内の電解めっき液TLは、基板PBの基板面に沿って流れ、第二排出口212Bから排出される。
 第二排出口212Bは、槽21の底面部に形成されており、隔壁213に保持された基板PBよりも鉛直方向下方に位置している。
 ここで、第二排出口212Bは、ひとつの貫通孔であってもよく、複数あってもよい。
 本実施形態では、第一排出口211Bは、ひとつの貫通孔で構成され、第二排出口212Bはひとつの貫通孔で構成されている。そして、第一排出口211Bの開口径は、第二排出口212Bの開口径よりも大きい。
A second supply port 212 </ b> A for the electrolytic plating solution TL is formed on the side wall of the tank 21. The electrolytic plating solution TL is supplied into the second tank 212 from the second supply port 212A. The second supply port 212A is located above the substrate PB held by the partition wall 213 in the vertical direction. The electrolytic plating solution TL in the first tank 211 flows along the substrate surface of the substrate PB and is discharged from the second discharge port 212B.
The second discharge port 212 </ b> B is formed on the bottom surface of the tank 21, and is positioned below the substrate PB held by the partition wall 213 in the vertical direction.
Here, the second discharge port 212B may be a single through hole, or a plurality of second discharge ports may be provided.
In this embodiment, the 1st discharge port 211B is comprised by one through-hole, and the 2nd discharge port 212B is comprised by one through-hole. The opening diameter of the first discharge port 211B is larger than the opening diameter of the second discharge port 212B.
 なお、本実施形態では、排出口211B,212Bと、槽24とは配管で接続されておらず、排出口211B,212Bから排出される電解めっき液TLは、槽24内に自然落下する。 In this embodiment, the discharge ports 211B and 212B and the tank 24 are not connected by piping, and the electrolytic plating solution TL discharged from the discharge ports 211B and 212B naturally falls into the tank 24.
 また、槽21内には、複数の陽極22が設置されている。本実施形態では、陽極22は2つ設置されている。一方の陽極22は、槽21内に配置された基板PBの一方の基板面と対向するように配置され、他方の陽極22は、槽21内に配置された基板PBの他方の基板面と対向するように配置されている。陽極22は、たとえば、含リン銅である。 Further, a plurality of anodes 22 are installed in the tank 21. In the present embodiment, two anodes 22 are installed. One anode 22 is disposed so as to face one substrate surface of the substrate PB disposed in the tank 21, and the other anode 22 is opposed to the other substrate surface of the substrate PB disposed in the tank 21. Are arranged to be. The anode 22 is, for example, phosphorous copper.
 基板処理装置2は、槽21へ供給するための電解めっき液TLが充填された槽(調整槽)14を備える。槽24は、槽21からオーバーフローした電解めっき液TLを受ける役割も果たすため、槽24は槽21の鉛直方向下方側に配置される。
 ここで、槽24内の電解めっき液TLを撹拌するために、バブリング装置(図示略)を槽24に接続してもよい。このようにすることで、槽24内の電解めっき液TLの濃度を均一なものとすることができる。
 槽24と、槽21の第一供給口211Aとは、配管26で接続されている。配管26および配管26に接続されているポンプP1を介して電解めっき液TLが槽24から槽21へと供給される。
 また、槽24と、槽21の第二供給口212Aとは、配管27で接続されている。配管27および配管27に接続されているポンプP2を介して電解めっき液TLが槽24から槽21へと供給される。
The substrate processing apparatus 2 includes a tank (adjustment tank) 14 filled with an electrolytic plating solution TL to be supplied to the tank 21. Since the tank 24 also serves to receive the electrolytic plating solution TL that has overflowed from the tank 21, the tank 24 is disposed on the lower side in the vertical direction of the tank 21.
Here, a bubbling device (not shown) may be connected to the tank 24 in order to stir the electrolytic plating solution TL in the tank 24. By doing in this way, the density | concentration of the electroplating liquid TL in the tank 24 can be made uniform.
The tank 24 and the first supply port 211 </ b> A of the tank 21 are connected by a pipe 26. The electrolytic plating solution TL is supplied from the tank 24 to the tank 21 through the pipe 26 and the pump P1 connected to the pipe 26.
The tank 24 and the second supply port 212 </ b> A of the tank 21 are connected by a pipe 27. The electrolytic plating solution TL is supplied from the tank 24 to the tank 21 via the pipe 27 and the pump P <b> 2 connected to the pipe 27.
 次に、基板処理装置2を使用した基板PBの基板処理方法について説明する。
 はじめに、図15(A)に示すような基材220を用意する。
 この基材220は、絶縁層221と、この絶縁層221の表裏面に貼り付けられた金属膜222(たとえば、銅膜)とを有する。絶縁層221の厚みは、たとえば、5μm以上、100μm以下であり、金属膜222の厚みは、たとえば、1μm以上、50μm以下である。基材220全体の厚みは、たとえば、10μm以上、200μm以下である。
Next, a substrate processing method for the substrate PB using the substrate processing apparatus 2 will be described.
First, a base material 220 as shown in FIG.
The base material 220 includes an insulating layer 221 and a metal film 222 (for example, a copper film) attached to the front and back surfaces of the insulating layer 221. The thickness of the insulating layer 221 is, for example, 5 μm or more and 100 μm or less, and the thickness of the metal film 222 is, for example, 1 μm or more and 50 μm or less. The entire thickness of the base material 220 is, for example, 10 μm or more and 200 μm or less.
 次に、図15(B)に示すように、一対の金属膜222および絶縁層221を貫通する貫通孔201を形成する。次に、金属膜222上および貫通孔201内部に無電解めっきを施す。これにより、基板PBが得られる。 Next, as shown in FIG. 15B, a through-hole 201 that penetrates the pair of metal films 222 and the insulating layer 221 is formed. Next, electroless plating is performed on the metal film 222 and inside the through hole 201. Thereby, the substrate PB is obtained.
 その後、基板PB上に金属膜222の一部を被覆するマスクMを配置し、基板処理装置2を使用して、貫通孔201内部および金属膜222上に電解めっきを施す(図16(A)参照)。
 電解めっきは以下のように行う。
 はじめに、図12に示すように、槽24から槽21の第一槽211へ、配管26およびポンプP1を介して、電解めっき液TLを供給する。また、槽24から第二槽212へ配管27およびポンプP2を介して、電解めっき液TLを供給し、槽21内を電解めっき液TLで満たしておく。
 なお、槽21からは電解めっき液TLがオーバーフローするとともに、槽21内が電解めっき液TLで満ちるように、槽21へ電解めっき液TLを供給しつづける。
 その後、基板PBを隔壁213に保持させて、基板PBを槽21内に配置し、基板PBを電解めっき液TL中に浸漬させる。このとき、基板PBの基板面が鉛直方向と略方向となるように、基板PBが槽21内に配置される。その後、陰極(図示略)および陽極22間を通電することで、基板PBに対する電解めっきが開始される。電解めっきを行う際、槽24から、第一槽211および第二槽212へは随時電解めっき液TLが供給される。これにより、槽21内の電解めっき液TLは、鉛直方向上側から、鉛直方向下側に向かって、流れることとなる(矢印Y1、Y2参照)。鉛直方向上側から鉛直方向下側に向かって流れる電解めっき液TLは、基板PBの一対の基板面に沿って流れ、さらには、貫通孔201内部にも供給される。
 なお、電解めっきを行う間、基板PB全体が電解めっき液TL中に浸漬した状態となる。
Thereafter, a mask M covering a part of the metal film 222 is disposed on the substrate PB, and electrolytic plating is performed on the inside of the through hole 201 and on the metal film 222 using the substrate processing apparatus 2 (FIG. 16A). reference).
Electrolytic plating is performed as follows.
First, as shown in FIG. 12, the electrolytic plating solution TL is supplied from the tank 24 to the first tank 211 of the tank 21 through the pipe 26 and the pump P1. Further, the electrolytic plating solution TL is supplied from the tank 24 to the second tank 212 via the pipe 27 and the pump P2, and the inside of the tank 21 is filled with the electrolytic plating solution TL.
The electrolytic plating solution TL continues to be supplied to the bath 21 so that the electrolytic plating solution TL overflows from the bath 21 and the inside of the bath 21 is filled with the electrolytic plating solution TL.
Thereafter, the substrate PB is held by the partition wall 213, the substrate PB is placed in the tank 21, and the substrate PB is immersed in the electrolytic plating solution TL. At this time, the substrate PB is disposed in the tank 21 so that the substrate surface of the substrate PB is substantially in the vertical direction. Thereafter, electroplating on the substrate PB is started by energizing between the cathode (not shown) and the anode 22. When electrolytic plating is performed, the electrolytic plating solution TL is supplied from the tank 24 to the first tank 211 and the second tank 212 as needed. Thereby, the electrolytic plating solution TL in the tank 21 flows from the upper side in the vertical direction toward the lower side in the vertical direction (see arrows Y1 and Y2). The electrolytic plating solution TL that flows from the upper side in the vertical direction toward the lower side in the vertical direction flows along the pair of substrate surfaces of the substrate PB and is also supplied to the inside of the through hole 201.
During the electrolytic plating, the entire substrate PB is immersed in the electrolytic plating solution TL.
 ここで、本実施形態では、第一排出口211Bの開口径が、第二排出口212Bの開口径よりも大きいため、基板PBの一方の基板面(第一槽211側の面)を流れる電解めっき液TLの平均流速は、他方の基板面(第二槽212側の面)を流れる電解めっき液TLの平均流速よりも速くなっている。そのため、図17の拡大断面図に示すように、一方の基板面を流れる電解めっき液TLと、他方の基板面を流れる電解めっきLとの速度差が生じることで、流れが遅い側から速い側へ向かって電解めっき液TLが貫通孔201内に引き込まれ、貫通孔201内に電解めっきが施されることとなる。これにより、貫通孔201内に電解めっきが施されることとなる。したがって、第一排出口211B、第二排出口212Bが調整手段となる。 Here, in this embodiment, since the opening diameter of the first discharge port 211B is larger than the opening diameter of the second discharge port 212B, electrolysis flowing on one substrate surface (surface on the first tank 211 side) of the substrate PB. The average flow rate of the plating solution TL is faster than the average flow rate of the electrolytic plating solution TL that flows on the other substrate surface (the surface on the second tank 212 side). Therefore, as shown in the enlarged cross-sectional view of FIG. 17, a speed difference between the electrolytic plating solution TL flowing on one substrate surface and the electrolytic plating L flowing on the other substrate surface is generated, so that the flow from the slow side to the fast side The electrolytic plating solution TL is drawn into the through hole 201 toward the top, and electrolytic plating is performed in the through hole 201. As a result, electrolytic plating is performed in the through hole 201. Therefore, the first discharge port 211B and the second discharge port 212B are the adjusting means.
 なお、基板PBの基板面を流れる電解めっき液TLの平均流速は、第一排出口211Bから排出される電解めっき液TLの単位時間当たりの流量V1、第二排出口212Bから排出される電解めっき液TLの単位時間当たりの流量V2から、算出することができる。
 まず、第一排出口211Bから排出される電解めっき液TLの単位時間当たりの流量V1を計測する。また、第二排出口212Bから排出される電解めっき液TLの単位時間当たりの流量V2を計測する。本実施形態では、槽21の形状が直方体あるいは立方体であるため、図22に示すように基板PBと隔壁213と槽21とで囲まれる面積S1でV1を割ることで、基板PBの一方の基板面を流れる電解めっき液TLの平均流速を算出することができる。
 同様にして、図22に示すように基板PBと隔壁213と槽とで囲まれる面積S2でV2を割ることで、基板PBの他方の基板面を流れる電解めっき液TLの平均流速を算出することができる。
 また、図23に示すように、隔壁213および基板PBで構成される壁面が傾斜しているような場合もある。この場合には、計算シミュレーション等により、基板PBの基板面を流れる電解めっき液TLの平均流速を算出することが可能である。
 なお、基板PBの一方の基板面を流れる電解めっき液TLの平均流速と、基板PBの他方の基板面を流れる電解めっき液TLの平均流速との差は、1m/s以上であることが好ましく、より好ましくは10m/s以上である。
 なお、図17の拡大断面図では、マスクMを省略している。
 また、図22の図面では、陽極22を省略しているが、陽極22の厚み等を考慮して、平均流速を算出してもよい。
The average flow rate of the electrolytic plating solution TL flowing on the substrate surface of the substrate PB is the flow rate V1 per unit time of the electrolytic plating solution TL discharged from the first discharge port 211B and the electrolytic plating discharged from the second discharge port 212B. It can be calculated from the flow rate V2 per unit time of the liquid TL.
First, the flow rate V1 per unit time of the electrolytic plating solution TL discharged from the first discharge port 211B is measured. Further, the flow rate V2 per unit time of the electrolytic plating solution TL discharged from the second discharge port 212B is measured. In this embodiment, since the shape of the tank 21 is a rectangular parallelepiped or a cube, one substrate of the substrate PB is obtained by dividing V1 by the area S1 surrounded by the substrate PB, the partition wall 213, and the tank 21, as shown in FIG. The average flow rate of the electrolytic plating solution TL flowing through the surface can be calculated.
Similarly, as shown in FIG. 22, the average flow velocity of the electrolytic plating solution TL flowing on the other substrate surface of the substrate PB is calculated by dividing V2 by the area S2 surrounded by the substrate PB, the partition 213, and the tank. Can do.
Moreover, as shown in FIG. 23, the wall surface comprised by the partition 213 and the board | substrate PB may be inclined. In this case, the average flow velocity of the electrolytic plating solution TL flowing on the substrate surface of the substrate PB can be calculated by calculation simulation or the like.
The difference between the average flow rate of the electrolytic plating solution TL flowing on one substrate surface of the substrate PB and the average flow rate of the electrolytic plating solution TL flowing on the other substrate surface of the substrate PB is preferably 1 m / s or more. More preferably, it is 10 m / s or more.
Note that the mask M is omitted in the enlarged sectional view of FIG.
In the drawing of FIG. 22, the anode 22 is omitted, but the average flow velocity may be calculated in consideration of the thickness of the anode 22 and the like.
 さらに、電解めっきを行う際、槽24から第一槽211へは随時電解めっき液TLが供給されており、電解めっき液TLの槽24から第一槽211への供給量は、第一槽211から排出される電解めっき液TLの量よりも多い。同様に、電解めっきを行う際、槽24から第二槽212へは随時電解めっき液TLが供給されており、電解めっき液TLの槽24から第二槽212への供給量は、第二槽212から排出される電解めっき液TLの量よりも多い。
従って、第一槽211、第二槽212の上部からは、電解めっき液TLがオーバーフローする。オーバーフローした電解めっき液TLは、矢印Y3方向に流れ、槽24で回収される。
 さらに、槽24には、第一排出口211B、第二排出口212Bからの電解めっき液TLが供給される。
 槽24内の電解めっき液TLは、配管26、27およびポンプP1、P2を介して再度槽21に供給されることとなる。
 なお、必要に応じて、槽24内の電解めっき液TLの金属濃度等を分析し、槽24内の電解めっき液TLの金属濃度等を調整してもよい。
 また、配管26から第一槽211内に供給される単位時間あたりの電解めっき液TLの量は、配管27から第二槽212内に供給される単位時間あたりの電解めっき液TLの量と同じであってもよく、異なっていてもよい。
Furthermore, when performing electroplating, the electrolytic plating solution TL is supplied from the tank 24 to the first tank 211 as needed, and the supply amount of the electrolytic plating solution TL from the tank 24 to the first tank 211 is the first tank 211. More than the amount of electrolytic plating solution TL discharged from Similarly, when electrolytic plating is performed, the electrolytic plating solution TL is supplied from the tank 24 to the second tank 212 as needed, and the supply amount of the electrolytic plating solution TL from the tank 24 to the second tank 212 is the second tank. More than the amount of electrolytic plating solution TL discharged from 212.
Therefore, the electrolytic plating solution TL overflows from the upper part of the first tank 211 and the second tank 212. The overflowed electrolytic plating solution TL flows in the direction of the arrow Y3 and is collected in the tank 24.
Further, the electrolytic plating solution TL is supplied to the tank 24 from the first discharge port 211B and the second discharge port 212B.
The electrolytic plating solution TL in the tank 24 is supplied again to the tank 21 via the pipes 26 and 27 and the pumps P1 and P2.
If necessary, the metal concentration or the like of the electrolytic plating solution TL in the tank 24 may be analyzed to adjust the metal concentration or the like of the electrolytic plating solution TL in the tank 24.
Further, the amount of electrolytic plating solution TL per unit time supplied from the pipe 26 into the first tank 211 is the same as the amount of electrolytic plating solution TL per unit time supplied from the pipe 27 into the second tank 212. May be different.
 以上のような電解めっきの工程により、図16(A)に示すように、貫通孔201内にビアとなる導電体26が形成されるとともに、金属膜222上に電解めっきによる金属膜が形成される(金属膜223は、金属膜222と金属膜222上のめっき膜を示す)。 By the electrolytic plating process as described above, as shown in FIG. 16A, a conductor 26 serving as a via is formed in the through hole 201, and a metal film by electrolytic plating is formed on the metal film 222. (The metal film 223 is a metal film 222 and a plating film on the metal film 222).
 次に、槽21から電解めっきが施された基板PBを取り出し、洗浄する。
 その後、マスクMが形成されていた部分の金属膜222をフラッシュエッチングにより除去し、図16(B)に示すように、第一回路層225、第二回路層224を形成する。
 以上の工程により、基板PBに対し電解めっき処理したフレキシブル回路基板PBを得ることができる。
Next, the substrate PB that has been subjected to electrolytic plating is taken out of the bath 21 and cleaned.
Thereafter, the portion of the metal film 222 where the mask M has been formed is removed by flash etching, and a first circuit layer 225 and a second circuit layer 224 are formed as shown in FIG.
Through the above steps, a flexible circuit board PB obtained by subjecting the substrate PB to electrolytic plating can be obtained.
 次に、本実施形態の作用効果について説明する。
 基板PBの一方の基板面(第一槽211側)を流れる電解めっき液TLの平均流速(線速)は、他方の基板面(第二槽212側)を流れる電解めっき液TLの平均流速(線速)よりも速くなっている。そのため、図17の拡大断面図に示すように、一方の基板面を流れる電解めっき液TLと、他方の基板面を流れる電解めっきLとの速度差が生じることで、流れが遅い側から速い側へ向かって電解めっき液TLが貫通孔201内に引き込まれ、貫通孔201内に電解めっきが施されることとなる。これにより、貫通孔201内に電解めっきを確実に施すことができ、貫通孔201内のめっき膜にボイド等が発生してしまうことを抑制できる。
 また、本実施形態では、基板PBを槽21内の電解めっき液TL中に浸漬させた状態で、槽21内の電解めっき液TLを鉛直方向の上方側から、下方側に向かって基板PBの基板面に沿って流している。
 これにより基板PB表面付近で電解めっき液TLが滞留してしまうことが防止され、基板PBには、常に新鮮な電解めっき液TLが接触することとなる。これにより、基板PBに対し所望のめっき膜を安定的に成膜することができる。
Next, the effect of this embodiment is demonstrated.
The average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on one substrate surface (first tank 211 side) of the substrate PB is the average flow velocity (electrolytic plating solution TL flowing on the other substrate surface (second tank 212 side) ( It is faster than (line speed). Therefore, as shown in the enlarged cross-sectional view of FIG. 17, a speed difference between the electrolytic plating solution TL flowing on one substrate surface and the electrolytic plating L flowing on the other substrate surface is generated, so that the flow from the slow side to the fast side The electrolytic plating solution TL is drawn into the through hole 201 toward the top, and electrolytic plating is performed in the through hole 201. Thereby, electrolytic plating can be reliably performed in the through hole 201, and generation of voids or the like in the plating film in the through hole 201 can be suppressed.
In the present embodiment, the electrolytic plating solution TL in the bath 21 is immersed in the electrolytic plating solution TL in the bath 21 from the upper side in the vertical direction toward the lower side of the substrate PB. It flows along the substrate surface.
As a result, the electrolytic plating solution TL is prevented from staying near the surface of the substrate PB, and the fresh electrolytic plating solution TL always comes into contact with the substrate PB. Thereby, a desired plating film can be stably formed on the substrate PB.
 また、本実施形態では、槽21内の電解めっき液TLを鉛直方向の上方側から、下方側に向かって流している。電解めっき液TLが重力に従って流れることとなるので、電解めっき液TLをスムーズに流すことができる。また、電解めっき液TLを重力に従って流すことで、電解めっき液TLの流れが安定したものとなる。
 さらに、電解めっき液TLを鉛直方向の上方側から、下方側に向かって重力に従って流すことで、基板処理装置2の装置構成の複雑化を抑制できる。
 さらに、本実施形態では、基板PBを槽21内の電解めっき液TL中に浸漬させた状態で、槽21内の電解めっき液TLを鉛直方向の上方側から、下方側に向かって基板PBの基板面に沿って流し、排出している。
 これにより、電解めっき液TL中に異物が混入していても、槽21内から異物を排出することができる。そのため基板PBに異物が付着することを抑制することができる。
In the present embodiment, the electrolytic plating solution TL in the tank 21 flows from the upper side in the vertical direction toward the lower side. Since the electroplating solution TL flows according to gravity, the electroplating solution TL can flow smoothly. Moreover, the flow of the electrolytic plating solution TL is stabilized by flowing the electrolytic plating solution TL according to gravity.
Further, the electrolytic plating solution TL is flowed according to gravity from the upper side in the vertical direction toward the lower side, so that the apparatus configuration of the substrate processing apparatus 2 can be prevented from becoming complicated.
Furthermore, in the present embodiment, the electrolytic plating solution TL in the tank 21 is immersed in the electrolytic plating solution TL in the tank 21 from the upper side in the vertical direction toward the lower side. It flows along the substrate surface and is discharged.
Thereby, even if foreign matter is mixed in the electrolytic plating solution TL, the foreign matter can be discharged from the tank 21. Therefore, it can suppress that a foreign material adheres to the board | substrate PB.
 また、本実施形態では、基板PBはフレキシブル回路基板用の基板であり、その厚みが10~200μmと比較的薄いものとなっている。
 このような基板PBを電解めっきL中に浸漬させた場合、電解めっき液TL中で基板PBがふらついてしまう。そのため、基板PBが陽極に近づいたり、離れたりすることで、基板PBに対し所望の電解めっきを施すことが難しいことがある。
 これに対し、本実施形態では、基板PBを電解めっき液TL中で浸漬させた状態で、電解めっき液TLを流している。基板PBの一方の基板面側および他方の基板面側で、電解めっき液TLが鉛直方向の上方側から、下方側に向かって流れるため、基板PBが電解めっき液TL中でふらつくことが防止される。これにより、基板PBに対し所望の電解めっきを施すことができる。また、基板PBのふらつきを防止できるので、基板PBにしわが発生したり、基板PBが破損してしまうことを抑制することができる。
In the present embodiment, the substrate PB is a substrate for a flexible circuit board, and the thickness thereof is relatively thin, 10 to 200 μm.
When such a substrate PB is immersed in the electroplating L, the substrate PB will fluctuate in the electroplating solution TL. Therefore, it may be difficult to perform desired electrolytic plating on the substrate PB when the substrate PB approaches or separates from the anode.
On the other hand, in this embodiment, the electrolytic plating solution TL is allowed to flow while the substrate PB is immersed in the electrolytic plating solution TL. Since the electrolytic plating solution TL flows from the upper side in the vertical direction toward the lower side on the one substrate surface side and the other substrate surface side of the substrate PB, the substrate PB is prevented from fluctuating in the electrolytic plating solution TL. The Thereby, desired electroplating can be performed with respect to the board | substrate PB. Moreover, since the wobbling of the substrate PB can be prevented, it is possible to prevent the substrate PB from being wrinkled or damaged.
 さらに、本実施形態では、槽21から電解めっき液TLをオーバーフローさせて電解めっきを行っている。オーバーフローさせることで、基板PBが電解めっき液TLに浸漬した状態を確実に維持しながら電解めっきを基板PBに対し施すことができる。 Furthermore, in this embodiment, electrolytic plating is performed by overflowing the electrolytic plating solution TL from the tank 21. By making it overflow, electrolytic plating can be applied to the substrate PB while reliably maintaining the state in which the substrate PB is immersed in the electrolytic plating solution TL.
 また、本実施形態では、槽21内に基板PBを一枚配置して、電解めっきを行っている。そのため、槽21は、基板PBを配置でき、基板PBの基板面側で電解めっき液TLを流すことができる程度の大きさでよい。これにより、基板処理装置2の大型化を抑制することができる。 Further, in the present embodiment, one substrate PB is disposed in the tank 21 and electrolytic plating is performed. Therefore, the tank 21 may have a size that allows the substrate PB to be disposed and allows the electrolytic plating solution TL to flow on the substrate surface side of the substrate PB. Thereby, the enlargement of the substrate processing apparatus 2 can be suppressed.
 なお、本発明は前述の実施形態に限定されるものではなく、本発明の目的を達成できる範囲での変形、改良等は本発明に含まれるものである。
 例えば、前記実施形態では、第一排出口211Bの開口径を、第二排出口212Bの開口径よりも大きくし、基板PBの一方の基板面(第一槽211側)を流れる電解めっき液TLの平均流速(線速)を他方の基板面(第二槽212側)を流れる電解めっき液TLの平均流速(線速)よりも速くなるようにしたが、これに限られるものではない。
 たとえば、図18に示すように、第一排出口211Bに配管28を接続し、ポンプP3で電解めっき液を吸引する。同様に、第二排出口212Bに配管29を接続し、ポンプP4で電解めっき液を吸引する。ポンプP3の吸引力を、ポンプP4の吸引力よりも大きくすることで、基板PBの一方の基板面(第一槽211側)を流れる電解めっき液TLの平均流速(線速)を他方の基板面(第二槽212側)を流れる電解めっき液TLの平均流速(線速)よりも速くしてもよい。この場合には、第一排出口211Bの大きさは、第二排出口212Bよりも大きくてもよいが、第一排出口211Bの大きさを、第二排出口212Bの大きさと同じとしてもよい。
It should be noted that the present invention is not limited to the above-described embodiments, and modifications, improvements, and the like within the scope that can achieve the object of the present invention are included in the present invention.
For example, in the above embodiment, the electrolytic plating solution TL that flows on one substrate surface (the first tank 211 side) of the substrate PB is set so that the opening diameter of the first discharge port 211B is larger than the opening diameter of the second discharge port 212B. The average flow velocity (linear velocity) is made faster than the average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on the other substrate surface (second tank 212 side), but is not limited thereto.
For example, as shown in FIG. 18, the pipe 28 is connected to the first outlet 211B, and the electrolytic plating solution is sucked by the pump P3. Similarly, the pipe 29 is connected to the second discharge port 212B, and the electrolytic plating solution is sucked by the pump P4. By making the suction force of the pump P3 larger than the suction force of the pump P4, the average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on one substrate surface (first tank 211 side) of the substrate PB is set to the other substrate. You may make it faster than the average flow velocity (linear velocity) of the electroplating liquid TL which flows through the surface (the 2nd tank 212 side). In this case, the first discharge port 211B may be larger than the second discharge port 212B, but the first discharge port 211B may have the same size as the second discharge port 212B. .
 さらに、図19に示すように、第一槽内の電解めっき液を上方から下方に向かって加圧して、第一排出口から排出させる第一加圧手段231と、第二槽内の電解めっき液を上方から下方に向かって加圧して、第一排出口から排出させる第二加圧手段232とを設け、第一加圧手段231から電解めっき液に加わる圧力を、第二加圧手段232から電解めっき液に加わる圧力よりも大きくすることで、基板PBの一方の基板面(第一槽211側)を流れる電解めっき液TLの平均流速(線速)を他方の基板面(第二槽212側)を流れる電解めっき液TLの平均流速(線速)よりも速くしてもよい。この場合には、第一排出口211Bの大きさは、第二排出口212Bよりも大きくてもよいが、第一排出口211Bの大きさを、第二排出口212Bの大きさと同じとしてもよい。
 さらに、ポンプP3、P4と、加圧手段231、232両方を備えるものとしてもよい。
Further, as shown in FIG. 19, the first pressurizing means 231 for pressurizing the electrolytic plating solution in the first tank from the upper side to the lower side and discharging it from the first discharge port, and the electrolytic plating in the second tank. A second pressurizing unit 232 configured to pressurize the liquid from the upper side to the lower side and discharge the liquid from the first discharge port. The pressure applied to the electrolytic plating solution from the first pressurizing unit 231 is set to the second pressurizing unit 232. The average flow velocity (linear velocity) of the electrolytic plating solution TL flowing on the one substrate surface (first tank 211 side) of the substrate PB is increased by the pressure applied to the electrolytic plating solution from the other substrate surface (second tank). 212 side) may be faster than the average flow velocity (linear velocity) of the electrolytic plating solution TL. In this case, the first discharge port 211B may be larger than the second discharge port 212B, but the first discharge port 211B may have the same size as the second discharge port 212B. .
Furthermore, both pumps P3 and P4 and pressurizing means 231 and 232 may be provided.
 また、前記実施形態では、電解めっき装置2であるとしたが、これに限られるものではない。図20に示すように、基板処理装置2の陽極を取り除き、本発明の基板処理装置を無電解めっき装置2Aとしてもよい。
 図20に示す基板処理装置2Aは、基板処理装置2から陽極を取り除いた点以外は、基板処理装置2と同じである。槽24、槽21内には、無電解めっき液TLが充填されている。
 また、図20に示す基板処理装置2Aを基板表面の金属層等をエッチングするエッチング装置としてもよい。さらに、基板処理装置2Aを現像装置としてもよい。基板表面の感光性樹脂層に光を照射し、未露光部分を除去するための現像液を槽24、槽21内に充填し、基板処理装置2Aにより、基板表面の感光性樹脂層の未露光部分を除去してもよい。
 さらに、基板処理装置2Aを、基板に形成されたマスク等を剥離処理する剥離装置としてもよい。この場合には、マスク等を剥離するための剥離液を槽24、槽21内に充填すればよい。
In the embodiment, the electroplating apparatus 2 is used. However, the present invention is not limited to this. As shown in FIG. 20, the anode of the substrate processing apparatus 2 may be removed, and the substrate processing apparatus of the present invention may be an electroless plating apparatus 2A.
The substrate processing apparatus 2A shown in FIG. 20 is the same as the substrate processing apparatus 2 except that the anode is removed from the substrate processing apparatus 2. The tank 24 and the tank 21 are filled with an electroless plating solution TL.
Alternatively, the substrate processing apparatus 2A shown in FIG. 20 may be an etching apparatus that etches a metal layer or the like on the substrate surface. Further, the substrate processing apparatus 2A may be a developing device. The photosensitive resin layer on the substrate surface is irradiated with light, and a developer for removing unexposed portions is filled into the tank 24 and the tank 21, and the photosensitive resin layer on the substrate surface is unexposed by the substrate processing apparatus 2 </ b> A. The portion may be removed.
Furthermore, the substrate processing apparatus 2 </ b> A may be a peeling apparatus that peels off a mask or the like formed on the substrate. In this case, the tank 24 and the tank 21 may be filled with a stripping solution for stripping the mask or the like.
 また、図21に示すように、本発明の基板処理装置を水洗装置2Bとしてもよい。水洗装置2Bは、基板処理装置2の陽極を取り除くとともに、槽24A~14Cを設けた点以外は、基板処理装置2と同じ構成である。
 水洗装置2Bの槽24A内には基板洗浄前の水が充填されている。
 槽24Aから槽21へ水が供給され、槽21内で水が鉛直方向の上方側から下方側にむかって流れ、基板PBが洗浄される。
 その後、排出口212からは洗浄後の水が排出され槽24Bに供給される。
槽24B内の水は、槽(浄化槽)14Cに供給され、槽24C内で水が清浄化され、金属等の不純物が除される。槽24C内で清浄化された水は、槽24Aに供給される。槽24Aに供給された水は、再度槽21に供給されることとなる。
 このような水洗装置2Bにおいては、基板PBには常にきれいな水が接触することとなり、基板PBが汚染されてしまうことを防止できる。また、貫通孔201内の洗浄を確実に実施することができる。
 さらには、基板を水槽に単に浸漬させて水洗する方法では、一つの水槽で確実に洗浄することが難しく、水槽を複数設けて、多段階で水洗する必要がある。
 これに対し、水洗装置2Bを使用すれば、基板PBには常にきれいな水が接触するため、多段階で水洗を行う必要がなく、基板PBの処理プロセスを簡略化することができる。
 なお、水洗装置2Bにおいて、槽24B内の水を槽24Cにて清浄化せずに、廃棄してもよい。
Further, as shown in FIG. 21, the substrate processing apparatus of the present invention may be a water washing apparatus 2B. The water washing apparatus 2B has the same configuration as the substrate processing apparatus 2 except that the anode of the substrate processing apparatus 2 is removed and tanks 24A to 14C are provided.
The tank 24A of the water washing apparatus 2B is filled with water before substrate cleaning.
Water is supplied from the tank 24A to the tank 21, and the water flows in the tank 21 from the upper side to the lower side in the vertical direction, and the substrate PB is cleaned.
Thereafter, the washed water is discharged from the discharge port 212 and supplied to the tank 24B.
The water in the tank 24B is supplied to the tank (septic tank) 14C, and the water is purified in the tank 24C to remove impurities such as metals. The water cleaned in the tank 24C is supplied to the tank 24A. The water supplied to the tank 24A will be supplied to the tank 21 again.
In such a water washing apparatus 2B, clean water always comes into contact with the substrate PB, and the substrate PB can be prevented from being contaminated. Further, the inside of the through hole 201 can be reliably cleaned.
Furthermore, in the method of simply immersing the substrate in the water tank and washing with water, it is difficult to reliably wash with one water tank, and it is necessary to provide a plurality of water tanks and perform water washing in multiple stages.
On the other hand, if the water washing apparatus 2B is used, clean water always comes into contact with the substrate PB, so there is no need to perform water washing in multiple stages, and the processing process of the substrate PB can be simplified.
In the washing apparatus 2B, the water in the tank 24B may be discarded without being cleaned in the tank 24C.
 さらに、前記実施形態では、槽21内で基板PBの基板面が鉛直方向と平行となるように配置したが、これに限らず、図24に示すように、槽21内で基板PBの基板面が鉛直方向と直交するように、配置してもよい。 Furthermore, in the said embodiment, although it arrange | positioned so that the board | substrate surface of the board | substrate PB might become parallel to a perpendicular direction in the tank 21, it is not restricted to this, As shown in FIG. May be arranged so that is perpendicular to the vertical direction.
 つぎに、本発明の実施の第三の形態を図面を参照して以下に説明する。なお、本実施の形態では図示するように上下方向以外にも前後左右の方向を規定して説明する。しかし、これは構成要素の相対関係を簡単に説明するために便宜的に規定するものである。従って、本発明を実施する製品の製造時や使用時の方向を限定するものではない。 Next, a third embodiment of the present invention will be described below with reference to the drawings. In this embodiment, as shown in the drawing, the front / rear / left / right directions are defined in addition to the up / down direction. However, this is provided for the sake of convenience in order to briefly explain the relative relationship between the components. Therefore, the direction at the time of manufacture and use of the product which implements the present invention is not limited.
 本実施の形態の基板処理装置300は、図25に示すように、基板PBの一面OFの基板処理領域TSが露出する開口孔311が一面に形成されているとともに挿入口312が上面に形成されているボックス状の基板保持部材310と、基板保持部材310の他面内側に配置されていて挿入された基板PBを開口孔311の外周内面に圧接させる拡縮自在な拡縮部材であるバルーン部材321と、を有する。 In the substrate processing apparatus 300 of the present embodiment, as shown in FIG. 25, an opening 311 through which the substrate processing region TS of one surface OF of the substrate PB is exposed is formed on one surface, and an insertion port 312 is formed on the upper surface. A box-shaped substrate holding member 310, and a balloon member 321 that is an expandable / contractible member that is arranged inside the other surface of the substrate holding member 310 and presses the inserted substrate PB against the inner peripheral surface of the opening 311. Have.
 このバルーン部材321は、例えば、直径10mm×厚さ1mmのシリコンチューブからなる。バルーン部材321は拡張により基板PBを押圧するとともに、基板PBが挿入されるときには負圧で収縮される。 The balloon member 321 is made of, for example, a silicon tube having a diameter of 10 mm and a thickness of 1 mm. The balloon member 321 presses the substrate PB by expansion, and is contracted by a negative pressure when the substrate PB is inserted.
 このため、バルーン部材321は拡縮する特性が要求される。ただし、ここでは拡縮部材としてシリンジチューブからなるバルーン部材321を例示するが、このような拡縮部材としてベローズやエアシリンダを利用することもできる(図示せず)。 For this reason, the balloon member 321 is required to expand and contract. However, although the balloon member 321 which consists of a syringe tube is illustrated here as an expansion / contraction member, a bellows and an air cylinder can also be utilized as such an expansion / contraction member (not shown).
 基板PBは、一面OFの基板処理領域TSのみ基板処理溶液TLで処理されるものであり、その処理としては、例えば、バンプめっき(絶縁層にビアがあきその底部に顔を出している通電層を起点に、ビアを電解銅/Ni/半田めっきでボトムアップする)や無電解金めっき(半田ボール搭載ランド)等がある。基板PBは、例えば、500×500mmなどに形成されている。 The substrate PB is processed by the substrate processing solution TL only on the substrate processing region TS of one surface OF. For example, bump plating (an electrically conductive layer with a via in the insulating layer and a face on the bottom) Starting from the bottom of the via with electrolytic copper / Ni / solder plating) and electroless gold plating (land with solder balls). The substrate PB is formed in, for example, 500 × 500 mm.
 さらに、本実施の形態の基板処理装置300は、基板処理領域TSの基板処理溶液TLを収容していて基板PBがセットされた基板保持部材310が浸漬される溶液保持容器330と、基板PBを他面で支持する基板支持治具322とを、さらに有する。 Furthermore, the substrate processing apparatus 300 of the present embodiment includes a solution holding container 330 that contains the substrate processing solution TL in the substrate processing region TS and into which the substrate holding member 310 on which the substrate PB is set, and the substrate PB. It further has a substrate support jig 322 supported on the other surface.
 基板処理溶液TLは、例えば、処理が前述したバンプめっきの場合、硫酸銅/Ni/半田、などが利用され、電解めっきの場合は、シアン金などが利用される。これら薬液は処理したくない部分に接液するだけで無用な腐食溶解、また無用なめっき膜が付くなど、不具合が発生する。 For the substrate processing solution TL, for example, copper sulfate / Ni / solder is used in the case of bump plating as described above, and cyan gold is used in the case of electrolytic plating. These chemical solutions cause problems such as unnecessary corrosion and dissolution, and useless plating film just by contacting the parts that you do not want to treat.
 基板保持部材310および溶液保持容器330は、耐薬性と剛性とが必要となるため、例えば、PVC(polyvinyl chloride)などのエンジニアリングプラスチック等で形成されている。 The substrate holding member 310 and the solution holding container 330 are made of engineering plastics such as PVC (polyvinyl chloride) because they need chemical resistance and rigidity.
 より具体的には、基板保持部材310は、前面に基板PBの基板処理領域TSに対応した矩形の開口孔311が形成されており、図27に示すように、その後方には矩形の環状のバルーン部材321が配置されている。 More specifically, the substrate holding member 310 is formed with a rectangular opening 311 corresponding to the substrate processing region TS of the substrate PB on the front surface, and as shown in FIG. A balloon member 321 is disposed.
 このバルーン部材321には、例えば、柔軟なチューブ部材で空気ポンプが連結されており(図示せず)、正圧により拡張される。なお、この正圧は空気ポンプにより維持されてもよく、チューブ部材の閉鎖により維持されてもよい。 For example, an air pump is connected to the balloon member 321 with a flexible tube member (not shown) and is expanded by a positive pressure. The positive pressure may be maintained by an air pump or may be maintained by closing the tube member.
 基板保持部材310の開口孔311の内面外周には、図26および図28に示すように、基板PBに密着するシール材323が装着されている。このシール材323は耐薬性が必要なため、例えば、EPDM(Ethylene Propylene Methylene Linkage)やFKM(Fluorocarbon rubber)などのゴムスポンジからなる。 As shown in FIGS. 26 and 28, a sealing material 323 that is in close contact with the substrate PB is attached to the outer periphery of the inner surface of the opening hole 311 of the substrate holding member 310. Since the sealing material 323 requires chemical resistance, it is made of rubber sponge such as EPDM (Ethylene-Propylene-Methylene Linkage) or FKM (Fluorocarbon rubber).
 シール材323は、連続気孔では基板処理溶液TLが漏出するので、不連続気孔が必要とされる。また、押し付けてシールするために柔軟性も必要とされる。このため、ゴムシートでは潰れないのでシールとして利用は困難である。 The sealing material 323 needs discontinuous pores because the substrate processing solution TL leaks out in the continuous pores. Also, flexibility is required to seal by pressing. For this reason, since it is not crushed with a rubber sheet, it is difficult to use it as a seal.
 しっかりシールするには、ラップ幅は基板外周最低5mm程度以上は必要で、ラップ幅が大きいほどシール信頼性は上がるが、基板処理有効面積が狭まるので、小さいのが本来理想である。 In order to seal firmly, the wrap width needs to be at least 5 mm or more on the outer periphery of the substrate. The larger the wrap width, the higher the reliability of the seal, but the smaller the substrate processing effective area, the smaller the ideal.
 基板支持治具322は、単純に基板PBを支持するだけの板材からなり、基板PBの他面を密閉するようなものではない。ただし、バルーン部材321に押圧されても破損しない強度は要求される。 The substrate support jig 322 is made of a plate material that simply supports the substrate PB, and does not seal the other surface of the substrate PB. However, the strength which does not break even if pressed by the balloon member 321 is required.
 上述のような構成において、本実施の形態の基板処理装置300による基板PBの基板処理方法を以下に説明する。まず、図28(a)に示すように、基板PBが基板処理領域TSの一面OFを前方として基板支持治具322に装着される。 The substrate processing method of the substrate PB by the substrate processing apparatus 300 of the present embodiment in the configuration as described above will be described below. First, as shown in FIG. 28A, the substrate PB is mounted on the substrate support jig 322 with the one surface OF of the substrate processing region TS as the front.
 つぎに、図28(b)に示すように、この基板支持治具322とともに基板PBが基板保持部材310の内部に挿入口312から挿入される。このとき、バルーン部材321は縮小されているので、基板PBの挿入は円滑に実行される。 Next, as shown in FIG. 28 (b), the substrate PB is inserted into the substrate holding member 310 from the insertion port 312 together with the substrate support jig 322. At this time, since the balloon member 321 is reduced, the insertion of the substrate PB is smoothly executed.
 つぎに、図28(c)に示すように、バルーン部材321が拡張されることにより、基板PBが基板保持部材310のシール材323に密着される。このとき、基板保持部材310の開口孔311に基板処理領域TSが位置することになる。 Next, as shown in FIG. 28C, the balloon member 321 is expanded, whereby the substrate PB is brought into close contact with the sealing material 323 of the substrate holding member 310. At this time, the substrate processing region TS is positioned in the opening hole 311 of the substrate holding member 310.
 そして、上述のように基板PBがセットされた基板保持部材310が、図26に示すように、基板処理溶液TLを収容している溶液保持容器330に浸漬される。すると、基板保持部材310の開口孔311から基板PBの基板処理領域TSのみが基板処理溶液TLで処理されることになる。この処理が完了すると、上述の作業を反対に実行することで、基板処理領域TSのみ処理された基板PBを獲得できることになる。 Then, the substrate holding member 310 on which the substrate PB is set as described above is immersed in the solution holding container 330 containing the substrate processing solution TL as shown in FIG. Then, only the substrate processing region TS of the substrate PB is processed with the substrate processing solution TL from the opening 311 of the substrate holding member 310. When this processing is completed, the substrate PB processed only in the substrate processing region TS can be obtained by executing the above-described operation in reverse.
 本実施の形態の基板処理装置300では、上述のように基板PBがセットされた基板保持部材310を溶液保持容器330に収容されている基板処理領域TSの基板処理溶液TLに浸漬することにより、基板PBの基板処理領域TSのみに基板処理溶液TLを供給することができる。このため、基板PBの一面OFの基板処理領域TSのみを簡単かつ迅速に基板処理溶液TLで処理することができる。 In the substrate processing apparatus 300 according to the present embodiment, the substrate holding member 310 on which the substrate PB is set as described above is immersed in the substrate processing solution TL in the substrate processing region TS accommodated in the solution holding container 330. The substrate processing solution TL can be supplied only to the substrate processing region TS of the substrate PB. For this reason, only the substrate processing region TS of the one surface OF of the substrate PB can be easily and quickly processed with the substrate processing solution TL.
 なお、本発明は本実施の形態に限定されるものではなく、その要旨を逸脱しない範囲で各種の変形を許容する。例えば、上記形態では基板PBがセットされた基板保持部材310を、基板処理溶液TLを収容した溶液保持容器330に浸漬することのみ例示した。 The present invention is not limited to the present embodiment, and various modifications are allowed without departing from the scope of the present invention. For example, in the above embodiment, only the substrate holding member 310 on which the substrate PB is set is immersed in the solution holding container 330 containing the substrate processing solution TL.
 しかし、このような状態で、図29に示すように、溶液保持容器330に基板処理溶液TLを溶液供給機構341で順次供給してもよい。このような溶液供給機構341は、基板処理溶液TLを上方から下方に落下させることができる。このように上方から下方に落下する基板処理溶液TLの流量は、例えば、0.1~2m/s程度である。 However, in this state, the substrate processing solution TL may be sequentially supplied to the solution holding container 330 by the solution supply mechanism 341 as shown in FIG. Such a solution supply mechanism 341 can drop the substrate processing solution TL from above to below. Thus, the flow rate of the substrate processing solution TL falling from the upper side to the lower side is, for example, about 0.1 to 2 m / s.
 さらに、図29に示すように、上述のように上方から下方に落下する基板処理溶液TLを基板処理領域TSに溶液乱流機構342で圧送してもよい。この場合、上方から下方に流動する基板処理溶液TLがノズル143から供給される基板処理溶液TLにより乱流となって基板PBの基板処理領域TSに圧送されるので、基板処理溶液TLで基板処理領域TSを良好に処理することができる。 Furthermore, as shown in FIG. 29, the substrate processing solution TL falling from above to below as described above may be pumped to the substrate processing region TS by the solution turbulence mechanism 342. In this case, the substrate processing solution TL flowing downward from above is turbulent by the substrate processing solution TL supplied from the nozzle 143 and is pumped to the substrate processing region TS of the substrate PB. The region TS can be processed satisfactorily.
 また、図30に示すように、基板処理溶液TLを基板処理領域TSに溶液乱流機構351で圧送するとともに吸引してもよい。この場合、基板PBの基板処理領域TSに乱流の基板処理溶液TLが供給されるので、やはり基板処理溶液TLで基板処理領域TSを良好に処理することができる。 Further, as shown in FIG. 30, the substrate processing solution TL may be pumped to the substrate processing region TS by the solution turbulence mechanism 351 and sucked. In this case, since the turbulent substrate processing solution TL is supplied to the substrate processing region TS of the substrate PB, the substrate processing region TS can be satisfactorily processed with the substrate processing solution TL.
 上述のような溶液乱流機構342,351は、横長のスリット状のノズル143,152,153を上下方向に配列してもよいが、例えば、内径1~5mmの円形のノズルを、間隔1~20mmで行列形状や千鳥形状に配列させて形成してもよい(図示せず)。 In the solution turbulence mechanism 342, 351 as described above, the horizontally long slit-shaped nozzles 143, 152, 153 may be arranged in the vertical direction. For example, circular nozzles having an inner diameter of 1 to 5 mm are arranged at intervals of 1 to They may be formed in a matrix shape or zigzag shape at 20 mm (not shown).
 さらに、上記形態では基板保持部材310に基板処理領域TSに対応した矩形の開口孔311が形成されており、その後方に矩形の環状のバルーン部材321が配置されていることを例示した。 Furthermore, in the above embodiment, the rectangular opening hole 311 corresponding to the substrate processing region TS is formed in the substrate holding member 310, and the rectangular annular balloon member 321 is disposed behind the rectangular opening hole 311.
 しかし、このバルーン部材321は、基板PBを基板保持部材310の開口孔311に圧接させて密着させることができればよく、例えば、一個の大型の拡縮部材や、上下二個の拡縮部材、左右二個の拡縮部材、等でもよい(図示せず)。 However, the balloon member 321 only needs to be able to press-contact the substrate PB to the opening hole 311 of the substrate holding member 310 and, for example, one large expansion member, two upper and lower expansion members, two left and right members The expansion / contraction member may be used (not shown).
 なお、当然ながら、上述した実施の形態および複数の変形例は、その内容が相反しない範囲で組み合わせることができる。また、上述した実施の形態および変形例では、各部の構造などを具体的に説明したが、その構造などは本願発明を満足する範囲で各種に変更することができる。 Of course, the embodiment and the plurality of modifications described above can be combined within a range in which the contents do not conflict with each other. Further, in the above-described embodiments and modifications, the structure of each part has been specifically described, but the structure and the like can be changed in various ways within a range that satisfies the present invention.
 本発明の実施の第四の形態を図面を参照して以下に説明する。なお、本実施の形態では図示するように上下方向以外にも前後左右の方向を規定して説明する。しかし、これは構成要素の相対関係を簡単に説明するために便宜的に規定するものである。従って、本発明を実施する製品の製造時や使用時の方向を限定するものではない。 A fourth embodiment of the present invention will be described below with reference to the drawings. In this embodiment, as shown in the figure, the front / rear and left / right directions are defined in addition to the up / down direction. However, this is provided for the sake of convenience in order to briefly explain the relative relationship between the components. Therefore, the direction at the time of manufacture and use of the product which implements the present invention is not limited.
 本発明の基板処理装置400は、図31に示すように、基板処理溶液TLを収容していて基板PBが浸漬される溶液保持容器430と、溶液保持容器430に基板処理溶液TLを上方から下方に落下させて順次供給する溶液供給機構441と、上方から下方に落下する基板処理溶液TLを基板PBの一面の基板処理領域TSに圧送する溶液乱流機構442と、を有する。 As shown in FIG. 31, the substrate processing apparatus 400 of the present invention contains a substrate processing solution TL and a substrate holding solution 430 in which the substrate PB is immersed, and the substrate processing solution TL in the solution holding container 430 from below. And a solution supply mechanism 441 that sequentially drops and supplies the substrate processing solution TL that drops downward from above to a substrate processing region TS on one surface of the substrate PB.
 基板PBは、一面OFの基板処理領域TSのみ基板処理溶液TLで処理されるものであり、その処理としては、例えば、バンプめっき(絶縁層にビアがあきその底部に顔を出している通電層を起点に、ビアを電解銅/Ni/半田めっきでボトムアップする)や無電解金めっき(半田ボール搭載ランド)等がある。基板PBは、例えば、500×500mmなどに形成されている。 The substrate PB is processed by the substrate processing solution TL only on the substrate processing region TS of one surface OF. For example, bump plating (an electrically conductive layer with a via in the insulating layer and a face on the bottom) Starting from the bottom of the via with electrolytic copper / Ni / solder plating) and electroless gold plating (land with solder balls). The substrate PB is formed in, for example, 500 × 500 mm.
 基板処理溶液TLは、例えば、処理が前述したバンプめっきの場合、硫酸銅/Ni/半田、などが利用され、電解めっきの場合は、シアン金などが利用される。これら薬液は処理したくない部分に接液するだけで無用な腐食溶解、また無用なめっき膜が付くなど、不具合が発生する。 For the substrate processing solution TL, for example, copper sulfate / Ni / solder is used in the case of bump plating as described above, and cyan gold is used in the case of electrolytic plating. These chemical solutions cause problems such as unnecessary corrosion and dissolution, and useless plating film just by contacting the parts that you do not want to treat.
 基板保持部材410および溶液保持容器430は、耐薬性と剛性とが必要となるため、例えば、PVC(polyvinyl chloride)などのエンジニアリングプラスチック等で形成されている。 The substrate holding member 410 and the solution holding container 430 are made of engineering plastics such as PVC (polyvinyl chloride) because they need chemical resistance and rigidity.
 さらに、本実施の形態の基板処理装置400は、図31ないし図34に示すように、基板PBが挿入される挿入口412が上面に形成されているとともに基板処理領域TSが露出する開口孔411が一面に形成されているボックス状の基板保持部材410と、基板保持部材410の他面内側に配置されていて挿入された基板PBを開口孔411の外周内面に圧接させる拡縮自在な拡縮部材であるバルーン部材421と、基板PBを他面で支持する基板支持治具422と、も有する。 Further, as shown in FIGS. 31 to 34, the substrate processing apparatus 400 of the present embodiment has an insertion hole 412 into which the substrate PB is inserted, and an opening hole 411 through which the substrate processing region TS is exposed. Is a box-shaped substrate holding member 410 formed on one surface, and an expandable / contractible member that is disposed inside the other surface of the substrate holding member 410 and presses the inserted substrate PB against the inner peripheral surface of the opening hole 411. A balloon member 421 and a substrate support jig 422 for supporting the substrate PB on the other surface are also provided.
 このバルーン部材421は、例えば、直径10mm×厚さ1mmのシリコンチューブからなる。バルーン部材421は拡張により基板PBを押圧するとともに、基板PBが挿入されるときには負圧で収縮される。 The balloon member 421 is made of a silicon tube having a diameter of 10 mm and a thickness of 1 mm, for example. The balloon member 421 presses the substrate PB by expansion, and is contracted by negative pressure when the substrate PB is inserted.
 このため、バルーン部材421は拡縮する特性が要求される。ただし、ここでは拡縮部材としてシリンジチューブからなるバルーン部材421を例示するが、このような拡縮部材としてベローズやエアシリンダを利用することもできる(図示せず)。 For this reason, the balloon member 421 is required to expand and contract. However, although the balloon member 421 which consists of a syringe tube is illustrated here as an expansion / contraction member, a bellows and an air cylinder can also be utilized as such an expansion / contraction member (not shown).
 より具体的には、図32に示すように、溶液保持容器430は、上面が開口したボックス状に形成されており、その前方上部に溶液供給機構441が配置される。溶液保持容器430の下部には、基板処理溶液TLの溶液排出口444が形成されており、この溶液排出口444から基板処理溶液TLが重力により排出される。このように上方から下方に落下する基板処理溶液TLの流量は、例えば、0.1~2m/s程度である。 More specifically, as shown in FIG. 32, the solution holding container 430 is formed in a box shape having an open top surface, and a solution supply mechanism 441 is disposed at the front upper portion thereof. A solution discharge port 444 for the substrate processing solution TL is formed below the solution holding container 430, and the substrate processing solution TL is discharged from the solution discharge port 444 by gravity. Thus, the flow rate of the substrate processing solution TL falling from the upper side to the lower side is, for example, about 0.1 to 2 m / s.
 溶液乱流機構442は、図31および図32に示すように、水平方向に扁平な複数の溶液吐出口443からなり、その複数の溶液吐出口443から基板処理溶液TLを基板PBの一面の基板処理領域TSに圧送する。 As shown in FIGS. 31 and 32, the solution turbulence mechanism 442 includes a plurality of solution discharge ports 443 that are flat in the horizontal direction, and the substrate processing solution TL is supplied to the substrate on one surface of the substrate PB from the plurality of solution discharge ports 443. Pump to processing area TS.
 また、基板保持部材410は、図32および前面に基板PBの基板処理領域TSに対応した矩形の開口孔411が形成されており、図33に示すように、その後方には矩形の環状のバルーン部材421が配置されている。 Further, the substrate holding member 410 is formed with a rectangular opening hole 411 corresponding to the substrate processing region TS of the substrate PB in FIG. 32 and the front surface, and as shown in FIG. A member 421 is disposed.
 このバルーン部材421には、例えば、柔軟なチューブ部材で空気ポンプが連結されており(図示せず)、正圧により拡張される。なお、この正圧は空気ポンプにより維持されてもよく、チューブ部材の閉鎖により維持されてもよい。 For example, an air pump is connected to the balloon member 421 with a flexible tube member (not shown) and is expanded by a positive pressure. The positive pressure may be maintained by an air pump or may be maintained by closing the tube member.
 基板保持部材410の開口孔411の内面外周には、図32および図34に示すように、基板PBに密着するシール材423が装着されている。このシール材423は耐薬性が必要なため、例えば、EPDMやFKMなどのゴムスポンジからなる。 As shown in FIGS. 32 and 34, a sealing material 423 that is in close contact with the substrate PB is attached to the outer periphery of the inner surface of the opening hole 411 of the substrate holding member 410. Since the sealing material 423 requires chemical resistance, it is made of, for example, a rubber sponge such as EPDM or FKM.
 シール材423は、連続気孔では基板処理溶液TLが漏出するので、不連続気孔が必要とされる。また、押し付けてシールするために柔軟性も必要とされる。このため、ゴムシートでは潰れないのでシールとして利用は困難である。 The sealing material 423 needs discontinuous pores because the substrate processing solution TL leaks out in the continuous pores. Also, flexibility is required to seal by pressing. For this reason, since it is not crushed with a rubber sheet, it is difficult to use it as a seal.
 しっかりシールするには、ラップ幅は基板外周最低5mm程度以上は必要で、ラップ幅が大きいほどシール信頼性は上がるが、基板処理有効面積が狭まるので、小さいのが本来理想である。 In order to seal firmly, the wrap width needs to be at least 5 mm or more on the outer periphery of the substrate. The larger the wrap width, the higher the reliability of the seal, but the smaller the substrate processing effective area, the smaller the ideal.
 基板支持治具422は単純に基板PBを支持するだけの板材からなり、基板PBの他面を密閉するようなものではない。ただし、バルーン部材421に押圧されても破損しない強度は要求される。 The substrate support jig 422 is made of a plate material that simply supports the substrate PB, and does not seal the other surface of the substrate PB. However, the strength which does not break even if pressed by the balloon member 421 is required.
 上述のような構成において、本実施の形態の基板処理装置400による基板PBの処理方法を以下に説明する。まず、図34(a)に示すように、基板PBが基板処理領域TSの一面OFを前方として基板支持治具422に装着される。 The substrate PB processing method by the substrate processing apparatus 400 of the present embodiment in the configuration as described above will be described below. First, as shown in FIG. 34A, the substrate PB is mounted on the substrate support jig 422 with the one surface OF of the substrate processing region TS as the front.
 つぎに、図34(b)に示すように、この基板支持治具422とともに基板PBが基板保持部材410の内部に挿入口412から挿入される。このとき、バルーン部材421は縮小されているので、基板PBの挿入は円滑に実行される。 Next, as shown in FIG. 34B, the substrate PB is inserted into the substrate holding member 410 from the insertion port 412 together with the substrate support jig 422. At this time, since the balloon member 421 is reduced, the insertion of the substrate PB is performed smoothly.
 つぎに、図34(c)に示すように、バルーン部材421が拡張されることにより、基板PBが基板保持部材410のシール材423に密着される。このとき、基板保持部材410の開口孔411に基板処理領域TSが位置することになる。 Next, as shown in FIG. 34C, the balloon member 421 is expanded, whereby the substrate PB is brought into close contact with the sealing material 423 of the substrate holding member 410. At this time, the substrate processing region TS is positioned in the opening hole 411 of the substrate holding member 410.
 そして、上述のように基板PBがセットされた基板保持部材410が、図31および図32に示すように、基板処理溶液TLを収容している溶液保持容器430に浸漬される。 Then, the substrate holding member 410 on which the substrate PB is set as described above is immersed in the solution holding container 430 containing the substrate processing solution TL as shown in FIGS.
 すると、基板保持部材410の開口孔411から基板PBの基板処理領域TSのみが基板処理溶液TLで処理されることになる。このような状態で、溶液供給機構441から基板処理溶液TLが溶液保持容器430に供給され、この基板処理溶液TLは上方から下方に落下して溶液排出口444から順次排出される。 Then, only the substrate processing region TS of the substrate PB is processed with the substrate processing solution TL from the opening hole 411 of the substrate holding member 410. In such a state, the substrate processing solution TL is supplied from the solution supply mechanism 441 to the solution holding container 430, and the substrate processing solution TL falls downward from above and is sequentially discharged from the solution discharge port 444.
 このとき、同時に溶液乱流機構442の複数の溶液吐出口443から基板処理溶液TLが基板PBの基板処理領域TSに圧送される。このため、基板処理溶液TLが基板PBの表面を上方から下方に流動する基板処理溶液TLが、複数の溶液吐出口443から吐出される基板処理溶液TLにより乱流となって基板処理溶液TLが基板PBの基板処理領域TSに圧送される。 At this time, the substrate processing solution TL is simultaneously pumped from the plurality of solution discharge ports 443 of the solution turbulence mechanism 442 to the substrate processing region TS of the substrate PB. For this reason, the substrate processing solution TL in which the substrate processing solution TL flows on the surface of the substrate PB from the upper side to the lower side becomes a turbulent flow due to the substrate processing solution TL discharged from the plurality of solution discharge ports 443, so that the substrate processing solution TL is It is pumped to the substrate processing region TS of the substrate PB.
 上述のような基板PBの基板処理領域TSの処理が完了すると、上述の作業を反対に実行することで、基板処理領域TSのみ処理された基板PBを獲得できることになる。 When the processing of the substrate processing region TS of the substrate PB as described above is completed, the substrate PB processed only in the substrate processing region TS can be obtained by executing the above operations in reverse.
 本実施の形態の基板処理装置400では、上述のように基板PBが浸漬された溶液保持容器430に溶液供給機構441が基板処理溶液TLを上方から下方に落下させて順次供給する。このように上方から下方に落下する基板処理溶液TLを溶液乱流機構442が基板PBの一面の基板処理領域TSに圧送する。 In the substrate processing apparatus 400 of the present embodiment, the solution supply mechanism 441 sequentially drops the substrate processing solution TL from the upper side to the lower side in the solution holding container 430 in which the substrate PB is immersed as described above. In this way, the solution turbulence mechanism 442 pumps the substrate processing solution TL falling from the upper side to the lower side to the substrate processing region TS on one surface of the substrate PB.
 このため、基板PBの一面の基板処理領域TSは基板処理溶液TLが単純に上方から下方へ落下するだけではなく、乱流となって圧送されることになる。従って、この乱流の基板処理溶液TLにより基板PBの一面の基板処理領域TSが迅速に良好に処理されることになる。 For this reason, the substrate processing solution TS on one surface of the substrate PB is not only simply dropped from the upper side to the lower side, but is also pumped as a turbulent flow. Therefore, the substrate processing region TS on one surface of the substrate PB is quickly and satisfactorily processed by the turbulent substrate processing solution TL.
 特に、溶液乱流機構442は複数の溶液吐出口443から基板処理溶液TLを吐出するので、基板処理溶液TLが基板PBの表面を上方から下方に流動する基板処理溶液TLが良好に乱流となり、その処理が迅速に良好に実行される。 In particular, since the solution turbulence mechanism 442 discharges the substrate processing solution TL from the plurality of solution discharge ports 443, the substrate processing solution TL in which the substrate processing solution TL flows on the surface of the substrate PB from the upper side to the lower side becomes a good turbulent flow. The process is performed quickly and successfully.
 しかも、本実施の形態の基板処理装置400では、上述のように基板PBがセットされた基板保持部材410を溶液保持容器430に収容されている基板処理領域TSの基板処理溶液TLに浸漬することにより、基板PBの基板処理領域TSのみに基板処理溶液TLを供給することができる。このため、基板PBの一面OFの基板処理領域TSのみを簡単かつ迅速に基板処理溶液TLで処理することができる。 Moreover, in the substrate processing apparatus 400 of the present embodiment, the substrate holding member 410 on which the substrate PB is set as described above is immersed in the substrate processing solution TL in the substrate processing region TS accommodated in the solution holding container 430. Thus, the substrate processing solution TL can be supplied only to the substrate processing region TS of the substrate PB. For this reason, only the substrate processing region TS of the one surface OF of the substrate PB can be easily and quickly processed with the substrate processing solution TL.
 なお、本発明は本実施の形態に限定されるものではなく、その要旨を逸脱しない範囲で各種の変形を許容する。例えば、上記形態では溶液保持容器430の基板処理溶液TLに浸漬された基板PBを静止させておくことを想定した。 The present invention is not limited to the present embodiment, and various modifications are allowed without departing from the scope of the present invention. For example, in the above embodiment, it is assumed that the substrate PB immersed in the substrate processing solution TL in the solution holding container 430 is kept stationary.
 しかし、このように溶液保持容器430の基板処理溶液TLに浸漬された基板PBを上下方向に揺動させる基板揺動機構(図示せず)を有してもよい。この場合、複数の溶液吐出口443の離間による基板処理溶液TLの圧送ムラを揺動により低減することができる。 However, a substrate swing mechanism (not shown) that swings the substrate PB immersed in the substrate processing solution TL in the solution holding container 430 in the vertical direction may be provided. In this case, it is possible to reduce unevenness in the pumping of the substrate processing solution TL due to the separation of the plurality of solution discharge ports 443 by swinging.
 また、上記形態では基板保持部材410に基板処理領域TSに対応した矩形の開口孔411が形成されており、その後方に矩形の環状のバルーン部材421が配置されていることを例示した。 Further, in the above embodiment, a rectangular opening hole 411 corresponding to the substrate processing region TS is formed in the substrate holding member 410, and a rectangular annular balloon member 421 is disposed behind the rectangular opening hole 411.
 しかし、このバルーン部材421は、基板PBを基板保持部材410の開口孔411に圧接させて密着させることができればよく、例えば、一個の大型のバルーン部材や、上下二個のバルーン部材、左右二個のバルーン部材、等でもよい(図示せず)。 However, the balloon member 421 only needs to be able to press-contact the substrate PB to the opening hole 411 of the substrate holding member 410 and, for example, one large balloon member, two upper and lower balloon members, two left and right Or a balloon member (not shown).
 また、上記形態ではボックス状の基板保持部材410に基板PBをセットして一面の基板処理領域TSのみを基板処理溶液TLで処理することを例示した。しかし、基板PBの他面を基板支持治具422に密閉させて装着し、この基板支持治具422とともに基板PBを基板処理溶液TLに浸漬させて一面の基板処理領域TSを処理してもよい。 In the above embodiment, the substrate PB is set on the box-shaped substrate holding member 410 and only one substrate processing region TS is processed with the substrate processing solution TL. However, the other surface of the substrate PB may be sealed and attached to the substrate support jig 422, and the substrate processing region TS may be processed by immersing the substrate PB together with the substrate support jig 422 in the substrate processing solution TL. .
 なお、当然ながら、上述した実施の形態および複数の変形例は、その内容が相反しない範囲で組み合わせることができる。また、上述した実施の形態および変形例では、各部の構造などを具体的に説明したが、その構造などは本願発明を満足する範囲で各種に変更することができる。 Of course, the embodiment and the plurality of modifications described above can be combined within a range in which the contents do not conflict with each other. Further, in the above-described embodiments and modifications, the structure of each part has been specifically described, but the structure and the like can be changed in various ways within a range that satisfies the present invention.
 本発明の実施の第五の形態を図面を参照して以下に説明する。なお、本実施の形態では図示するように上下方向以外にも前後左右の方向を規定して説明する。しかし、これは構成要素の相対関係を簡単に説明するために便宜的に規定するものである。従って、本発明を実施する製品の製造時や使用時の方向を限定するものではない。 A fifth embodiment of the present invention will be described below with reference to the drawings. In this embodiment, as shown in the figure, the front / rear and left / right directions are defined in addition to the up / down direction. However, this is provided for the sake of convenience in order to briefly explain the relative relationship between the components. Therefore, the direction at the time of manufacture and use of the product which implements the present invention is not limited.
 本発明の基板処理装置500は、図35に示すように、基板処理溶液TLを収容していて基板PBが浸漬される溶液保持容器530と、浸漬された基板PBの一面OFの基板処理領域TSに基板処理溶液TLを圧送するとともに吸引する溶液乱流機構551と、を有する。 As shown in FIG. 35, the substrate processing apparatus 500 of the present invention contains a solution holding container 530 in which a substrate processing solution TL is stored and the substrate PB is immersed, and a substrate processing region TS on one surface OF of the immersed substrate PB. And a solution turbulence mechanism 551 for feeding and sucking the substrate processing solution TL.
 基板PBは、一面OFの基板処理領域TSのみ基板処理溶液TLで処理されるものであり、その処理としては、例えば、バンプめっき(絶縁層にビアがあきその底部に顔を出している通電層を起点に、ビアを電解銅/Ni/半田めっきでボトムアップする)や無電解金めっき(半田ボール搭載ランド)等がある。基板PBは、例えば、500×500mmなどに形成されている。 The substrate PB is processed by the substrate processing solution TL only on the substrate processing region TS of one surface OF. For example, bump plating (an electrically conductive layer with a via in the insulating layer and a face on the bottom) Starting from the bottom of the via with electrolytic copper / Ni / solder plating) and electroless gold plating (land with solder balls). The substrate PB is formed in, for example, 500 × 500 mm.
 基板処理溶液TLは、例えば、処理が前述したバンプめっきの場合、硫酸銅/Ni/半田、などが利用され、電解めっきの場合は、シアン金などが利用される。これら薬液は処理したくない部分に接液するだけで無用な腐食溶解、また無用なめっき膜が付くなど、不具合が発生する。 For the substrate processing solution TL, for example, copper sulfate / Ni / solder is used in the case of bump plating as described above, and cyan gold is used in the case of electrolytic plating. These chemical solutions cause problems such as unnecessary corrosion and dissolution, and useless plating film just by contacting the parts that you do not want to treat.
 基板保持部材510および溶液保持容器530は、耐薬性と剛性とが必要となるため、例えば、PVC(polyvinyl chloride)などのエンジニアリングプラスチック等で形成されている。 Since the substrate holding member 510 and the solution holding container 530 require chemical resistance and rigidity, they are made of, for example, engineering plastics such as PVC (polyvinyl chloride).
 溶液乱流機構551は、複数の溶液吐出口552から基板処理溶液TLを基板PBの一面OFの基板処理領域TSに圧送するとともに複数の溶液吸引口553から基板処理溶液TLを吸引する。この溶液乱流機構551は、溶液吐出口552と溶液吸引口553とが交互に配列されている。 The solution turbulence mechanism 551 pumps the substrate processing solution TL from the plurality of solution discharge ports 552 to the substrate processing region TS of the one surface OF of the substrate PB and sucks the substrate processing solution TL from the plurality of solution suction ports 553. In the solution turbulence mechanism 551, solution discharge ports 552 and solution suction ports 553 are alternately arranged.
 なお、ここでは横長のスリット状の溶液吐出口552を上下方向に配列しているが、例えば、内径1~5mmの円形の溶液吐出口を、間隔1~20mmで行列形状や千鳥形状に配列させて形成してもよい(図示せず)。 Here, the horizontally long slit-shaped solution discharge ports 552 are arranged in the vertical direction. For example, circular solution discharge ports having an inner diameter of 1 to 5 mm are arranged in a matrix shape or a zigzag shape at intervals of 1 to 20 mm. (Not shown).
 さらに、本実施の形態の基板処理装置500は、図35ないし図38に示すように、基板PBが挿入される挿入口512が上面に形成されているとともに基板処理領域TSが露出する開口孔511が一面に形成されているボックス状の基板保持部材510と、基板保持部材510の他面内側に配置されていて挿入された基板PBを開口孔511の外周内面に圧接させる拡縮自在なバルーン部材521と、基板PBを他面で支持する基板支持治具522と、も有する。 Further, as shown in FIGS. 35 to 38, the substrate processing apparatus 500 of the present embodiment has an insertion hole 512 into which the substrate PB is inserted, and an opening hole 511 through which the substrate processing region TS is exposed. And a balloon member 521 that can be expanded and contracted to press-contact the inserted substrate PB disposed inside the other surface of the substrate holding member 510 to the inner surface of the outer periphery of the opening hole 511. And a substrate support jig 522 that supports the substrate PB on the other surface.
 このバルーン部材521は、例えば、直径10mm×t1のシリコンチューブからなる。バルーン部材521は拡張により基板PBを押圧するとともに、基板PBが挿入されるときには負圧で収縮される。 The balloon member 521 is made of, for example, a silicon tube having a diameter of 10 mm × t1. The balloon member 521 presses the substrate PB by expansion, and is contracted by a negative pressure when the substrate PB is inserted.
 このため、バルーン部材521は拡縮する特性が要求される。ただし、ここでは拡縮部材としてシリンジチューブからなるバルーン部材521を例示するが、このような拡縮部材としてベローズやエアシリンダを利用することもできる(図示せず)。 For this reason, the balloon member 521 is required to have a property of expanding and contracting. However, although the balloon member 521 which consists of a syringe tube is illustrated here as an expansion / contraction member, a bellows and an air cylinder can also be utilized as such an expansion / contraction member (not shown).
 より具体的には、溶液乱流機構551は、図35および図36に示すように、水平方向に扁平な複数の溶液吐出口552および溶液吸引口553からなり、その複数の溶液吐出口552から基板処理溶液TLを基板PBの一面の基板処理領域TSに圧送するとともに、この圧送された基板処理溶液TLを溶液吸引口553から吸引する。 More specifically, as shown in FIGS. 35 and 36, the solution turbulence mechanism 551 includes a plurality of solution discharge ports 552 and a solution suction port 553 that are flat in the horizontal direction. The substrate processing solution TL is pumped to the substrate processing region TS on one surface of the substrate PB, and the pumped substrate processing solution TL is sucked from the solution suction port 553.
 このような基板処理溶液TLの圧送および吸引は、例えば、ポンプ機構などにより実行される。このように圧送および吸引される基板処理溶液TLは、順次新品と交換されてもよく、交換されることなく循環されてもよく、循環させながら適宜新品と交換してもよい。 Such pumping and suction of the substrate processing solution TL is performed by, for example, a pump mechanism. The substrate processing solution TL thus pumped and sucked may be sequentially replaced with a new one, may be circulated without being replaced, or may be appropriately replaced with a new one while being circulated.
 また、基板保持部材510は、図36および前面に基板PBの基板処理領域TSに対応した矩形の開口孔511が形成されており、図37に示すように、その後方には矩形の環状のバルーン部材521が配置されている。 In addition, the substrate holding member 510 has a rectangular opening hole 511 corresponding to the substrate processing region TS of the substrate PB formed in FIG. 36 and the front surface, and as shown in FIG. A member 521 is disposed.
 このバルーン部材521には、例えば、柔軟なチューブ部材で空気ポンプが連結されており(図示せず)、正圧により拡張される。なお、この正圧は空気ポンプにより維持されてもよく、チューブ部材の閉鎖により維持されてもよい。 For example, an air pump is connected to the balloon member 521 by a flexible tube member (not shown), and is expanded by a positive pressure. The positive pressure may be maintained by an air pump or may be maintained by closing the tube member.
 基板保持部材510の開口孔511の内面外周には、図36および図38に示すように、基板PBに密着するシール材523が装着されている。このシール材523は耐薬性が必要なため、例えば、EPDMやFKMなどのゴムスポンジからなる。 As shown in FIGS. 36 and 38, a sealing material 523 that is in close contact with the substrate PB is attached to the inner periphery of the opening hole 511 of the substrate holding member 510. Since the sealing material 523 needs chemical resistance, it is made of, for example, a rubber sponge such as EPDM or FKM.
 シール材523は、連続気孔では基板処理溶液TLが漏出するので、不連続気孔が必要とされる。また、押し付けてシールするために柔軟性も必要とされる。このため、ゴムシートでは潰れないのでシールとして利用は困難である。 The sealing material 523 requires discontinuous pores because the substrate processing solution TL leaks out in the continuous pores. Also, flexibility is required to seal by pressing. For this reason, since it is not crushed with a rubber sheet, it is difficult to use it as a seal.
 しっかりシールするには、ラップ幅は基板外周最低5mm程度以上は必要で、ラップ幅が大きいほどシール信頼性は上がるが、基板処理有効面積が狭まるので、小さいのが本来理想である。 In order to seal firmly, the wrap width needs to be at least 5 mm or more on the outer periphery of the substrate. The larger the wrap width, the higher the reliability of the seal, but the smaller the substrate processing effective area, the smaller the ideal.
 基板支持治具522は単純に基板PBを支持するだけの板材からなり、基板PBの他面を密閉するようなものではない。ただし、バルーン部材521に押圧されても破損しない強度は要求される。 The substrate support jig 522 is made of a plate material that simply supports the substrate PB, and does not seal the other surface of the substrate PB. However, the strength which does not break even if pressed by the balloon member 521 is required.
 上述のような構成において、本実施の形態の基板処理装置500による基板PBの基板処理方法を以下に説明する。まず、図38(a)に示すように、基板PBが基板処理領域TSの一面OFを前方として基板支持治具522に装着される。 The substrate processing method of the substrate PB by the substrate processing apparatus 500 of the present embodiment in the configuration as described above will be described below. First, as shown in FIG. 38A, the substrate PB is mounted on the substrate support jig 522 with the one surface OF of the substrate processing region TS as the front.
 つぎに、図38(b)に示すように、この基板支持治具522とともに基板PBが基板保持部材510の内部に挿入口512から挿入される。このとき、バルーン部材521は縮小されているので、基板PBの挿入は円滑に実行される。 Next, as shown in FIG. 38 (b), the substrate PB is inserted into the substrate holding member 510 from the insertion port 512 together with the substrate support jig 522. At this time, since the balloon member 521 is reduced, the insertion of the substrate PB is executed smoothly.
 つぎに、図38(c)に示すように、バルーン部材521が拡張されることにより、基板PBが基板保持部材510のシール材523に密着される。このとき、基板保持部材510の開口孔511に基板処理領域TSが位置することになる。 Next, as shown in FIG. 38C, the balloon member 521 is expanded, whereby the substrate PB is brought into close contact with the sealing material 523 of the substrate holding member 510. At this time, the substrate processing region TS is positioned in the opening hole 511 of the substrate holding member 510.
 そして、上述のように基板PBがセットされた基板保持部材510が、図35および図36に示すように、基板処理溶液TLを収容している溶液保持容器530に浸漬される。 Then, the substrate holding member 510 on which the substrate PB is set as described above is immersed in a solution holding container 530 containing the substrate processing solution TL as shown in FIGS.
 すると、基板保持部材510の開口孔511から基板PBの基板処理領域TSのみが基板処理溶液TLで処理されることになる。このような状態で、溶液乱流機構551の溶液吐出口552から基板処理溶液TLが溶液保持容器530に圧送され、この圧送された基板処理溶液TLが溶液吸引口553から吸引される。 Then, only the substrate processing region TS of the substrate PB is processed with the substrate processing solution TL from the opening hole 511 of the substrate holding member 510. In this state, the substrate processing solution TL is pumped from the solution discharge port 552 of the solution turbulence mechanism 551 to the solution holding container 530, and the pumped substrate processing solution TL is sucked from the solution suction port 553.
 このため、基板処理溶液TLが基板PBの表面を乱流となって流動することになり、この乱流となった基板処理溶液TLで基板PBの基板処理領域TSが処理される。 For this reason, the substrate processing solution TL flows in a turbulent manner on the surface of the substrate PB, and the substrate processing region TS of the substrate PB is processed with the turbulent substrate processing solution TL.
 上述のような基板PBの基板処理領域TSの処理が完了すると、上述の作業を反対に実行することで、基板処理領域TSのみ処理された基板PBを獲得できることになる。 When the processing of the substrate processing region TS of the substrate PB as described above is completed, the substrate PB processed only in the substrate processing region TS can be obtained by executing the above operations in reverse.
 本実施の形態の基板処理装置500では、上述のように溶液保持容器530に収容されている基板処理溶液TLに基板PBが浸漬される。このような状態の基板PBの基板処理領域TSに溶液供給機構が基板処理溶液TLを圧送するとともに吸引する。 In the substrate processing apparatus 500 of this embodiment, the substrate PB is immersed in the substrate processing solution TL stored in the solution holding container 530 as described above. The solution supply mechanism pumps and sucks the substrate processing solution TL into the substrate processing region TS of the substrate PB in such a state.
 このため、基板PBの一面OFの基板処理領域TSは圧送されるとともに吸引される基板処理溶液TLにより処理されることになる。従って、乱流となる基板処理溶液TLにより基板PBの一面OFの基板処理領域TSのみを簡単かつ迅速に処理することができる。 For this reason, the substrate processing region TS of the one surface OF of the substrate PB is processed by the substrate processing solution TL that is pumped and sucked. Accordingly, only the substrate processing region TS of the one surface OF of the substrate PB can be processed easily and quickly by the substrate processing solution TL that becomes a turbulent flow.
 特に、溶液乱流機構551は複数の溶液吐出口552から基板処理溶液TLを圧送するとともに、複数の溶液吸引口553から基板処理溶液TLを吸引するので、基板処理溶液TLの基板PBの表面で基板処理溶液TLが良好に乱流となり、その処理が迅速に良好に実行される。 In particular, the solution turbulence mechanism 551 pumps the substrate processing solution TL from the plurality of solution discharge ports 552 and sucks the substrate processing solution TL from the plurality of solution suction ports 553, so that the surface of the substrate processing solution TL on the surface of the substrate PB. The substrate processing solution TL becomes a good turbulent flow, and the processing is performed quickly and satisfactorily.
 しかも、上述のような複数の溶液吐出口552と複数の溶液吸引口553とが交互に配列されているので、基板PBの基板処理領域TSを乱流の基板処理溶液TLで均質に処理することができる。 In addition, since the plurality of solution discharge ports 552 and the plurality of solution suction ports 553 as described above are alternately arranged, the substrate processing region TS of the substrate PB is uniformly processed with the turbulent substrate processing solution TL. Can do.
 しかも、本実施の形態の基板処理装置500では、上述のように基板PBがセットされた基板保持部材510を溶液保持容器530に収容されている基板処理領域TSの基板処理溶液TLに浸漬することにより、基板PBの基板処理領域TSのみに基板処理溶液TLを供給することができる。このため、基板PBの一面OFの基板処理領域TSのみを簡単かつ迅速に基板処理溶液TLで処理することができる。 In addition, in the substrate processing apparatus 500 of the present embodiment, the substrate holding member 510 on which the substrate PB is set as described above is immersed in the substrate processing solution TL in the substrate processing region TS accommodated in the solution holding container 530. Thus, the substrate processing solution TL can be supplied only to the substrate processing region TS of the substrate PB. For this reason, only the substrate processing region TS of the one surface OF of the substrate PB can be easily and quickly processed with the substrate processing solution TL.
 なお、本発明は本実施の形態に限定されるものではなく、その要旨を逸脱しない範囲で各種の変形を許容する。例えば、上記形態では溶液保持容器530の基板処理溶液TLに浸漬された基板PBを静止させておくことを想定した。 The present invention is not limited to the present embodiment, and various modifications are allowed without departing from the scope of the present invention. For example, in the above embodiment, it is assumed that the substrate PB immersed in the substrate processing solution TL in the solution holding container 530 is kept stationary.
 しかし、このように溶液保持容器530の基板処理溶液TLに浸漬された基板PBを上下方向に揺動させる基板揺動機構(図示せず)を有してもよい。この場合、複数の溶液吐出口552の離間による基板処理溶液TLの圧送ムラを揺動により低減することができる。 However, a substrate swing mechanism (not shown) that swings the substrate PB immersed in the substrate processing solution TL of the solution holding container 530 in the vertical direction may be provided. In this case, it is possible to reduce unevenness in the pumping of the substrate processing solution TL due to the separation of the plurality of solution discharge ports 552 by swinging.
 また、上記形態では基板保持部材510に基板処理領域TSに対応した矩形の開口孔511が形成されており、その後方に矩形の環状のバルーン部材521が配置されていることを例示した。 In the above embodiment, the substrate holding member 510 is formed with the rectangular opening hole 511 corresponding to the substrate processing region TS, and the rectangular annular balloon member 521 is disposed behind the rectangular opening hole 511.
 しかし、このバルーン部材521は、基板PBを基板保持部材510の開口孔511に圧接させて密着させることができればよく、例えば、一個の大型のバルーン部材や、上下二個のバルーン部材、左右二個のバルーン部材、等でもよい(図示せず)。 However, the balloon member 521 only needs to be able to press-contact the substrate PB to the opening hole 511 of the substrate holding member 510 and, for example, one large balloon member, two upper and lower balloon members, two left and right Or a balloon member (not shown).
 また、上記形態ではボックス状の基板保持部材510に基板PBをセットして一面の基板処理領域TSのみを基板処理溶液TLで処理することを例示した。しかし、基板PBの他面を基板支持治具522に密閉させて装着し、この基板支持治具522とともに基板PBを基板処理溶液TLに浸漬させて一面の基板処理領域TSを処理してもよい。 In the above embodiment, the substrate PB is set on the box-shaped substrate holding member 510 and only one substrate processing region TS is processed with the substrate processing solution TL. However, the other surface of the substrate PB may be sealed and attached to the substrate support jig 522, and the substrate processing region TS may be processed by immersing the substrate PB in the substrate processing solution TL together with the substrate support jig 522. .
 なお、当然ながら、上述した実施の形態および複数の変形例は、その内容が相反しない範囲で組み合わせることができる。また、上述した実施の形態および変形例では、各部の構造などを具体的に説明したが、その構造などは本願発明を満足する範囲で各種に変更することができる。 Of course, the embodiment and the plurality of modifications described above can be combined within a range in which the contents do not conflict with each other. Further, in the above-described embodiments and modifications, the structure of each part has been specifically described, but the structure and the like can be changed in various ways within a range that satisfies the present invention.
 この出願は、2010年02月24日に出願された日本出願特願2010-038469号、2010年06月10日に出願された日本出願特願2010-132902号、2010年10月07日に出願された日本出願特願2010-227118号、2010年10月07日に出願された日本出願特願2010-227120号、2010年10月07日に出願された日本出願特願2010-227121号、を基礎とする優先権を主張し、その開示の全てを、ここに取り込む。 This application is Japanese Patent Application No. 2010-038469 filed on Feb. 24, 2010, Japanese Application No. 2010-132902 filed on Jun. 10, 2010, and filed on Oct. 07, 2010. Japanese Patent Application No. 2010-227118, Japanese Application No. 2010-227120 filed on October 07, 2010, Japanese Patent Application No. 2010-227121 filed on October 07, 2010, Claims the underlying priority and incorporates all of its disclosure here.

Claims (49)

  1.  基板に基板処理溶液を接触させて処理する基板処理方法であって、
     前記基板面が鉛直方向と平行または鉛直方向に対し傾斜するように、槽内に前記基板を配置する工程と、
     前記基板を前記槽内の前記基板処理溶液中に浸漬させるとともに、前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す工程と、
     前記基板面に沿って流れた前記基板処理溶液を前記槽から排出する工程とを含む基板処理方法。
    A substrate processing method for processing by bringing a substrate processing solution into contact with a substrate,
    Arranging the substrate in the tank so that the substrate surface is parallel to the vertical direction or inclined with respect to the vertical direction;
    Immersing the substrate in the substrate processing solution in the tank, and flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side;
    Discharging the substrate processing solution flowing along the substrate surface from the tank.
  2.  請求項1に記載の基板処理方法において、
     前記基板処理溶液は薬液であり、
     前記槽から排出された前記薬液を調整槽にて回収する工程と、
     前記調整槽中で前記薬液の濃度を調整し、再度、前記槽内に前記薬液を供給し、
     前記薬液を前記基板面に沿って流す前記工程と、
     前記基板面に沿って流れた前記薬液を前記槽から排出する前記工程とを再度実施する基板処理方法。
    The substrate processing method according to claim 1,
    The substrate processing solution is a chemical solution,
    Recovering the chemical solution discharged from the tank in an adjustment tank;
    Adjust the concentration of the chemical in the adjustment tank, and again supply the chemical in the tank,
    The step of flowing the chemical solution along the substrate surface;
    The substrate processing method which implements again the said process of discharging | emitting the said chemical | medical solution which flowed along the said substrate surface from the said tank.
  3.  請求項2に記載の基板処理方法において、
     前記薬液は、めっき液であり、
     前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す前記工程では、
     前記薬液を前記基板面に沿って流すことで、前記基板にめっき処理を行う基板処理方法。
    The substrate processing method according to claim 2,
    The chemical solution is a plating solution,
    In the step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side,
    A substrate processing method for performing a plating process on the substrate by flowing the chemical solution along the substrate surface.
  4.  請求項1に記載の基板処理方法において、
     前記基板処理溶液は水であり、
     前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す前記工程では、
     前記水を前記基板面に沿って流すことで、前記基板の洗浄を行い、
     前記基板面に沿って流れた前記水を前記槽から排出する前記工程の後段で、
     前記水を回収して、再度、前記槽内に供給する基板処理方法。
    The substrate processing method according to claim 1,
    The substrate treatment solution is water;
    In the step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side,
    The substrate is washed by flowing the water along the substrate surface,
    In the latter stage of the step of discharging the water flowing along the substrate surface from the tank,
    The substrate processing method which collect | recovers the said water and supplies it in the said tank again.
  5.  請求項1ないし4のいずれかに記載の基板処理方法において、
     前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す前記工程では、
     前記基板を振動させる基板処理方法。
    In the substrate processing method in any one of Claims 1 thru | or 4,
    In the step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side,
    A substrate processing method for vibrating the substrate.
  6.  請求項1ないし5のいずれかに記載の基板処理方法において、
     前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す前記工程では、
     前記槽内に設置された前記基板よりも鉛直方向下方側に位置する部分に形成された排出口に基板処理溶液排出用のポンプを接続し、
     前記ポンプにより、前記槽内の基板処理溶液を吸引して、前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す基板処理方法。
    In the substrate processing method in any one of Claims 1 thru | or 5,
    In the step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side,
    Connect a pump for discharging the substrate processing solution to a discharge port formed in a portion located on the lower side in the vertical direction than the substrate installed in the tank,
    A substrate processing method for sucking a substrate processing solution in the tank by the pump and causing the substrate processing solution to flow along the substrate surface from an upper side in a vertical direction toward a lower side.
  7.  請求項1ないし6のいずれかに記載の基板処理方法において、
     前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す前記工程では、
     前記槽内の前記基板処理溶液を鉛直方向の上方側から下方側に向かって加圧して、前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す基板処理方法。
    In the substrate processing method in any one of Claim 1 thru | or 6,
    In the step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side,
    Substrate processing that pressurizes the substrate processing solution in the tank from the upper side to the lower side in the vertical direction and causes the substrate processing solution to flow along the substrate surface from the upper side in the vertical direction toward the lower side. Method.
  8.  請求項1ないし6のいずれかに記載の基板処理方法において、
     前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す前記工程において、
     前記槽から前記基板処理溶液をオーバーフローさせながら、前記基板処理溶液を前記基板面に沿って前記槽内で前記基板処理溶液を流す基板処理方法。
    In the substrate processing method in any one of Claim 1 thru | or 6,
    In the step of flowing the substrate processing solution along the substrate surface from the upper side in the vertical direction toward the lower side,
    A substrate processing method of flowing the substrate processing solution in the tank along the substrate surface while overflowing the substrate processing solution from the tank.
  9.  請求項1ないし8のいずれかに記載の基板処理方法において、
     前記基板は、厚みが10~200μmである基板処理方法。
    In the substrate processing method in any one of Claims 1 thru | or 8,
    The substrate processing method, wherein the substrate has a thickness of 10 to 200 μm.
  10.  基板に基板処理溶液を接触させて処理する基板処理装置において、
     内部に前記基板処理溶液が供給されるとともに、供給された前記基板処理溶液に前記基板を浸積させるための槽と、
     前記槽内部に配置される前記基板面が鉛直方向に平行あるいは、鉛直方向に対し傾斜するように前記基板を保持する保持部とを備え、
     前記槽の前記基板処理溶液の供給口は、前記保持部で保持された前記基板よりも鉛直方向上方にあり、
     前記槽の前記基板処理溶液の排出口は、前記保持部で保持された前記基板よりも鉛直方向下方にあり、
     前記基板処理溶液を前記槽の供給口から前記排出口に向かって前記基板処理溶液を流すと、前記基板処理溶液が、鉛直方向の上方側から下方側に向かって前記基板面に沿って流れるように構成される基板処理装置。
    In a substrate processing apparatus for processing by bringing a substrate processing solution into contact with a substrate,
    A tank for immersing the substrate in the supplied substrate processing solution while the substrate processing solution is supplied therein;
    A holding unit for holding the substrate so that the substrate surface arranged in the tank is parallel to the vertical direction or inclined with respect to the vertical direction;
    The supply port of the substrate processing solution in the tank is vertically above the substrate held by the holding unit,
    The discharge port of the substrate processing solution in the tank is vertically lower than the substrate held by the holding unit,
    When the substrate processing solution is flowed from the supply port of the tank toward the discharge port, the substrate processing solution flows along the substrate surface from the upper side to the lower side in the vertical direction. The substrate processing apparatus comprised in.
  11.  請求項10に記載の基板処理装置において、
     前記基板処理溶液は、薬液であり、
     前記槽から排出された薬液を回収し、前記薬液の濃度を調整するための調整槽と、
     前記調整槽内の薬液を前記槽内に供給する供給手段とを備える基板処理装置。
    The substrate processing apparatus according to claim 10, wherein
    The substrate processing solution is a chemical solution,
    An adjustment tank for recovering the chemical liquid discharged from the tank and adjusting the concentration of the chemical liquid;
    A substrate processing apparatus comprising supply means for supplying a chemical solution in the adjustment tank into the tank.
  12.  請求項11に記載の基板処理装置において、
     前記薬液はめっき液であり、
     当該基板処理装置はめっき装置である基板処理装置。
    The substrate processing apparatus according to claim 11, wherein
    The chemical solution is a plating solution,
    The substrate processing apparatus is a substrate processing apparatus which is a plating apparatus.
  13.  請求項10に記載の基板処理装置において、
     前記基板処理溶液は水であり、
     前記槽の排出口から排出された水を回収する回収手段と、
     回収した水を浄化する浄化手段とを備える基板処理装置。
    The substrate processing apparatus according to claim 10, wherein
    The substrate treatment solution is water;
    Recovery means for recovering water discharged from the outlet of the tank;
    A substrate processing apparatus comprising purification means for purifying collected water.
  14.  請求項10ないし13のいずれかに記載の基板処理装置において、
     前記槽内の前記基板を振動させるための振動手段を備える基板処理装置。
    The substrate processing apparatus according to any one of claims 10 to 13,
    A substrate processing apparatus comprising a vibrating means for vibrating the substrate in the tank.
  15.  請求項10ないし14のいずれかに記載の基板処理装置において、
     前記排出口に基板処理溶液排出用のポンプを接続し、
     前記ポンプにより、前記槽内の基板処理溶液を吸引する基板処理装置。
    15. The substrate processing apparatus according to claim 10, wherein
    Connect the substrate processing solution discharge pump to the discharge port,
    A substrate processing apparatus for sucking a substrate processing solution in the tank by the pump.
  16.  請求項10ないし15のいずれかに記載の基板処理装置において、
     前記槽内の前記基板処理溶液を鉛直方向の上方側から下方に向かって加圧する加圧手段を備え、
     前記加圧手段により、前記基板処理溶液を加圧して、前記基板処理溶液を鉛直方向の上方側から、下方側に向かって前記基板面に沿って流す基板処理装置。
    The substrate processing apparatus according to claim 10, wherein
    A pressurizing means for pressurizing the substrate processing solution in the tank downward from the upper side in the vertical direction;
    The substrate processing apparatus which pressurizes the substrate processing solution by the pressurizing unit and causes the substrate processing solution to flow along the substrate surface from the upper side in the vertical direction toward the lower side.
  17.  請求項10ないし15のいずれかに記載の基板処理装置において、
     前記槽はオーバーフロー槽である基板処理装置。
    The substrate processing apparatus according to claim 10, wherein
    The substrate processing apparatus is an overflow tank.
  18.  請求項10ないし17のいずれかに記載の基板処理装置において、
     前記槽から排出される基板処理溶液の量を調整する調整手段が設けられている基板処理装置。
    The substrate processing apparatus according to any one of claims 10 to 17,
    The substrate processing apparatus provided with the adjustment means which adjusts the quantity of the substrate processing solution discharged | emitted from the said tank.
  19.  請求項10ないし18のいずれかに記載の基板処理装置において、
     処理対象となる前記基板は、厚みが10~200μmである基板処理装置。
    The substrate processing apparatus according to any one of claims 10 to 18,
    The substrate processing apparatus, wherein the substrate to be processed has a thickness of 10 to 200 μm.
  20.  基板の一方の基板面側から他方の基板面側にむかって貫通する貫通孔が形成された基板の前記貫通孔に基板処理溶液を接触させて、前記基板を処理する基板処理方法であって、
     前記基板処理溶液が供給される槽であり、前記基板を保持し、保持した前記基板とともに当該槽を、第一槽および第二槽に区画する隔壁を備える前記槽を用意する工程と、
     前記基板を前記隔壁に保持させて、前記槽内に前記基板を設置する工程と、
     前記第一槽および第二槽内に基板処理溶液を供給して前記基板を前記基板処理溶液に浸漬させた状態とし、前記第一槽および第二槽それぞれから前記基板処理溶液を排出することで、前記基板処理溶液を前記基板の一方の基板面および他方の基板面に沿って流すとともに、前記貫通孔内に前記基板処理溶液を接触させる工程とを含み、
     前記基板処理溶液を前記基板の一方の基板面および他方の基板面に沿って流すとともに、前記貫通孔内に前記基板処理溶液を接触させる前記工程において、
     前記基板の一方の基板面に沿って流れる前記基板処理溶液の平均流速と、前記基板の他方の基板面に沿って流れる前記基板処理溶液の平均流速とが異なる基板処理方法。
    A substrate processing method for processing a substrate by bringing a substrate processing solution into contact with the through hole of the substrate in which a through hole penetrating from one substrate surface side to the other substrate surface side of the substrate is formed,
    A step of supplying the substrate processing solution, and preparing the tank including a partition that holds the substrate and partitions the tank into a first tank and a second tank together with the held substrate;
    Holding the substrate on the partition wall and installing the substrate in the tank;
    By supplying a substrate processing solution into the first tank and the second tank to immerse the substrate in the substrate processing solution, and discharging the substrate processing solution from the first tank and the second tank, respectively. And flowing the substrate processing solution along one substrate surface and the other substrate surface of the substrate, and contacting the substrate processing solution in the through hole,
    In the step of causing the substrate processing solution to flow along one substrate surface and the other substrate surface of the substrate and bringing the substrate processing solution into contact with the through hole,
    A substrate processing method in which an average flow velocity of the substrate processing solution flowing along one substrate surface of the substrate is different from an average flow velocity of the substrate processing solution flowing along the other substrate surface of the substrate.
  21.  請求項20に記載の基板処理方法において、
     前記槽内において、前記基板は一対の基板面が鉛直方向と略平行となるように前記隔壁に保持され、
     前記第一槽および前記第二槽において、前記基板処理溶液を鉛直方向上側から下側にむかって流すことで、前記基板の一方の基板面および他方の基板面にそって前記基板処理溶液を流す基板処理方法。
    The substrate processing method according to claim 20, wherein
    In the tank, the substrate is held by the partition so that a pair of substrate surfaces are substantially parallel to the vertical direction,
    In the first tank and the second tank, the substrate processing solution is allowed to flow along one substrate surface and the other substrate surface of the substrate by flowing the substrate processing solution from the upper side to the lower side in the vertical direction. Substrate processing method.
  22.  請求項20または21に記載の基板処理方法において、
     前記第一槽の第一排出口と、前記第二の槽の第二排出口との大きさとを異なる大きさとすることで、前記基板の一方の基板面に沿って流れる前記基板処理溶液の平均流速と、前記基板の他方の基板面に沿って流れる前記基板処理溶液の平均流速とを異なるものとする基板処理方法。
    The substrate processing method according to claim 20 or 21,
    The average of the substrate processing solution that flows along one substrate surface of the substrate by setting the first discharge port of the first tank and the second discharge port of the second tank to different sizes. A substrate processing method in which a flow rate is different from an average flow rate of the substrate processing solution flowing along the other substrate surface of the substrate.
  23.  請求項20または21に記載の基板処理方法において、
     前記第一槽の第一排出口に接続された排液用の第一ポンプの吸引力と、前記第二の槽の第二排出口に接続された排液用の第二ポンプの吸引力とを異なるものとすることで、前記基板の一方の基板面に沿って流れる前記基板処理溶液の平均流速と、前記基板の他方の基板面に沿って流れる前記基板処理溶液の平均流速とを異なるものとする基板処理方法。
    The substrate processing method according to claim 20 or 21,
    The suction force of the first pump for drainage connected to the first discharge port of the first tank, and the suction force of the second pump for drainage connected to the second discharge port of the second tank The average flow velocity of the substrate processing solution flowing along one substrate surface of the substrate is different from the average flow velocity of the substrate processing solution flowing along the other substrate surface of the substrate. A substrate processing method.
  24.  請求項20または21に記載の基板処理方法において、
     前記第一槽内に供給された前記基板処理溶液を加圧して第一槽の第一排出口から排出させるとともに、第二槽内に供給された前記基板処理溶液を加圧して第二槽の第二排出口から排出させ、
     前記第一槽内に供給された前記基板処理溶液への加圧力と、前記第二槽に供給された前記基板処理溶液への加圧力とを異なる圧力とすることで、前記基板の一方の基板面に沿って流れる前記基板処理溶液の平均流速と、前記基板の他方の基板面に沿って流れる前記基板処理溶液の平均流速とを異なるものとする基板処理方法。
    The substrate processing method according to claim 20 or 21,
    The substrate treatment solution supplied into the first tank is pressurized and discharged from the first discharge port of the first tank, and the substrate treatment solution supplied into the second tank is pressurized to Let it drain from the second outlet,
    One substrate of the substrate is formed by setting a pressure applied to the substrate processing solution supplied into the first tank and a pressure applied to the substrate processing solution supplied to the second tank to different pressures. The substrate processing method which makes the average flow velocity of the said substrate processing solution which flows along a surface differ from the average flow velocity of the said substrate processing solution which flows along the other substrate surface of the said board | substrate.
  25.  請求項20ないし24のいずれか一項に記載の基板処理方法において、
     前記基板処理溶液は、めっき液であり、
     前記基板処理溶液を前記基板の一方の基板面および他方の基板面に沿って流すとともに、前記貫通孔内に前記基板処理溶液を接触させる前記工程において、
     前記基板の前記貫通孔内にめっき処理を行う基板処理方法。
    The substrate processing method according to any one of claims 20 to 24,
    The substrate processing solution is a plating solution,
    In the step of causing the substrate processing solution to flow along one substrate surface and the other substrate surface of the substrate and bringing the substrate processing solution into contact with the through hole,
    A substrate processing method for performing plating in the through hole of the substrate.
  26.  基板の一方の基板面側から他方の基板面側にむかって貫通する貫通孔が形成された基板の前記貫通孔内に基板処理溶液を接触させて、前記基板を処理する基板処理装置において、
     内部に前記基板処理溶液が供給され、供給された前記基板処理溶液に前記基板を浸積させるとともに、前記基板を保持し、保持した前記基板とともに槽を、第一槽および第二槽に区画する隔壁を備える槽と、
     前記槽の第一槽および第二槽内にそれぞれに前記基板処理溶液を供給する供給手段とを備え、
     当該基板処理装置は、前記供給手段から供給された前記基板処理溶液が、前記基板の一方の基板面および他方の基板面に沿って流れるとともに、前記基板の貫通孔に接触するように構成され、
     前記基板の一方の基板面に沿って流れる前記基板処理溶液の平均流速と、前記基板の他方の基板面に沿って流れる前記基板処理溶液の平均流速とを異ならせる調整手段を有する基板処理装置。
    In the substrate processing apparatus for processing the substrate by bringing a substrate processing solution into contact with the through hole of the substrate in which a through hole penetrating from one substrate surface side to the other substrate surface side is formed,
    The substrate processing solution is supplied inside, the substrate is immersed in the supplied substrate processing solution, the substrate is held, and the tank is partitioned into a first tank and a second tank together with the held substrate. A tank with a partition;
    A supply means for supplying the substrate processing solution into the first tank and the second tank of the tank,
    The substrate processing apparatus is configured such that the substrate processing solution supplied from the supply unit flows along one substrate surface and the other substrate surface of the substrate and contacts a through hole of the substrate,
    The substrate processing apparatus which has an adjustment means which makes different the average flow velocity of the said substrate processing solution which flows along the one substrate surface of the said substrate, and the average flow velocity of the said substrate processing solution which flows along the other substrate surface of the said substrate.
  27.  請求項26に記載の基板処理装置において、
     前記第一槽の基板処理溶液の第一供給口および前記第二槽の基板処理溶液の第二供給口は、前記隔壁で保持された前記基板よりも鉛直方向上方にあり、
     前記第一槽の基板処理溶液の第一排出口および前記第二槽の基板処理溶液の第二排出口は、前記隔壁で保持された前記基板よりも鉛直方向下方にあり、
     当該基板処理装置は、前記第一供給口から第一排出口に向かって前記基板処理溶液を流すとともに、前記第二供給口から第二排出口に向かって前記基板処理溶液を流すと、前記基板処理溶液が、鉛直方向の上方側から下方側に向かって前記基板の一方の基板面および他方の基板面に沿って流れるように構成される基板処理装置。
    The substrate processing apparatus according to claim 26, wherein
    The first supply port of the substrate treatment solution in the first tank and the second supply port of the substrate treatment solution in the second tank are vertically above the substrate held by the partition wall,
    The first discharge port of the substrate processing solution in the first tank and the second discharge port of the substrate processing solution in the second tank are below the substrate held by the partition wall in the vertical direction,
    When the substrate processing apparatus flows the substrate processing solution from the first supply port toward the first discharge port, and flows the substrate processing solution from the second supply port toward the second discharge port, A substrate processing apparatus configured such that a processing solution flows along one substrate surface and the other substrate surface of the substrate from an upper side in a vertical direction toward a lower side.
  28.  請求項26または27に記載の基板処理装置において、
     前記調整手段は、前記第一槽の基板処理溶液の第一排出口と、この第一排出口と大きさが異なる前記第二槽の基板処理溶液の第二排出口とを含んで構成される基板処理装置。
    28. The substrate processing apparatus according to claim 26 or 27, wherein:
    The adjusting means includes a first discharge port for the substrate processing solution in the first tank and a second discharge port for the substrate processing solution in the second tank that is different in size from the first discharge port. Substrate processing equipment.
  29.  請求項26または27に記載の基板処理装置において、
     前記調整手段は、前記第一槽の第一排出口に接続された排液用の第一ポンプと、
     前記第二の槽の第二排出口に接続された排液用の第二ポンプとで構成され、
     前記第一ポンプの吸引力は第二ポンプの吸引力とは異なる基板処理装置。
    The substrate processing apparatus according to claim 26 or 27,
    The adjusting means includes a first pump for drainage connected to the first outlet of the first tank;
    A second pump for drainage connected to the second outlet of the second tank;
    The substrate processing apparatus, wherein the suction force of the first pump is different from the suction force of the second pump.
  30.  請求項26または27に記載の基板処理装置において、
     前記調整手段は、前記第一槽内に供給された前記基板処理溶液を加圧して第一槽の第一排出口から排出させる第一加圧手段と、
     第二槽内に供給された前記基板処理溶液を加圧して第二槽の第二排出口から排出させる第二加圧手段とで構成され、
     第一加圧手段からの前記基板処理溶液に加わる加圧力と、第二加圧手段からの前記基板処理溶液への加圧力とが異なる基板処理装置。
    The substrate processing apparatus according to claim 26 or 27,
    The adjusting means pressurizes the substrate processing solution supplied into the first tank and discharges it from the first outlet of the first tank;
    A second pressurizing unit configured to pressurize the substrate processing solution supplied into the second tank and discharge it from the second discharge port of the second tank;
    A substrate processing apparatus in which a pressing force applied to the substrate processing solution from a first pressurizing unit is different from a pressing force applied to the substrate processing solution from a second pressurizing unit.
  31.  請求項26ないし30のいずれか一項に記載の基板処理装置において、
     前記基板処理溶液は、めっき液であり、
     当該処理装置は、前記基板の前記貫通孔内にめっき処理を行う装置である基板処理装置。
    The substrate processing apparatus according to any one of claims 26 to 30, wherein
    The substrate processing solution is a plating solution,
    The said processing apparatus is a substrate processing apparatus which is an apparatus which performs a plating process in the said through-hole of the said board | substrate.
  32.  基板の一面の基板処理領域が露出する開口孔が一面に形成されているとともに挿入口が上面に形成されているボックス状の基板保持部材と、
     前記基板保持部材の他面内側に配置されていて挿入された前記基板を前記開口孔の外周内面に圧接させる拡縮自在な拡縮部材と、
    を有する基板処理装置。
    A box-shaped substrate holding member in which an opening hole for exposing a substrate processing region on one surface of the substrate is formed on one surface and an insertion port is formed on the upper surface;
    An expandable / contractible member that is arranged inside the other surface of the substrate holding member and presses the inserted substrate against the inner surface of the outer periphery of the opening hole;
    A substrate processing apparatus.
  33.  前記基板処理領域の基板処理溶液を収容していて前記基板がセットされた前記基板保持部材が浸漬される溶液保持容器を、さらに有する請求項32に記載の基板処理装置。 The substrate processing apparatus according to claim 32, further comprising a solution holding container that contains the substrate processing solution in the substrate processing region and in which the substrate holding member on which the substrate is set is immersed.
  34.  前記溶液保持容器に前記基板処理溶液を順次供給する溶液供給機構を、さらに有する請求項32または33に記載の基板処理装置。 34. The substrate processing apparatus according to claim 32, further comprising a solution supply mechanism that sequentially supplies the substrate processing solution to the solution holding container.
  35.  前記溶液供給機構は、前記基板処理溶液を上方から下方に落下させる請求項34に記載の基板処理装置。 35. The substrate processing apparatus according to claim 34, wherein the solution supply mechanism drops the substrate processing solution from above to below.
  36.  上方から下方に落下する前記基板処理溶液を前記基板処理領域に圧送する溶液乱流機構を、さらに有する請求項35に記載の基板処理装置。 36. The substrate processing apparatus according to claim 35, further comprising a solution turbulence mechanism that pumps the substrate processing solution falling from above to the substrate processing region.
  37.  前記基板処理溶液を前記基板処理領域に圧送するとともに吸引する溶液乱流機構を、さらに有する請求項35に記載の基板処理装置。 36. The substrate processing apparatus according to claim 35, further comprising a solution turbulence mechanism that pumps and sucks the substrate processing solution to the substrate processing region.
  38.  基板処理溶液を収容していて基板が浸漬される溶液保持容器と、
     前記溶液保持容器に前記基板処理溶液を上方から下方に落下させて順次供給する溶液供給機構と、
     上方から下方に落下する前記基板処理溶液を前記基板の一面の基板処理領域に圧送する溶液乱流機構と、
    を有する基板処理装置。
    A solution holding container in which the substrate processing solution is stored and the substrate is immersed;
    A solution supply mechanism that sequentially supplies the substrate holding solution by dropping it from above to the solution holding container;
    A solution turbulence mechanism for pumping the substrate processing solution falling downward from above to a substrate processing region on one side of the substrate;
    A substrate processing apparatus.
  39.  前記溶液乱流機構は、複数の溶液吐出口から前記基板処理溶液を前記基板の一面の前記基板処理領域に圧送する請求項38に記載の基板処理装置。 39. The substrate processing apparatus according to claim 38, wherein the solution turbulence mechanism pumps the substrate processing solution from a plurality of solution discharge ports to the substrate processing region on one surface of the substrate.
  40.  前記溶液保持容器の前記基板処理溶液に浸漬された前記基板を上下方向に揺動させる基板揺動機構を、さらに有する請求項38または39に記載の基板処理装置。 40. The substrate processing apparatus according to claim 38, further comprising a substrate swinging mechanism that swings the substrate immersed in the substrate processing solution in the solution holding container in a vertical direction.
  41.  前記基板が挿入される挿入口が上面に形成されているとともに前記基板処理領域が露出する開口孔が一面に形成されているボックス状の基板保持部材と、
     前記基板保持部材の他面内側に配置されていて挿入された前記基板を前記開口孔の外周内面に圧接させる拡縮自在な拡縮部材と、
    を有する請求項38ないし40の何れか一項に記載の基板処理装置。
    A box-shaped substrate holding member in which an insertion hole into which the substrate is inserted is formed on the upper surface and an opening hole through which the substrate processing region is exposed is formed on one surface;
    An expandable / contractible member that is arranged inside the other surface of the substrate holding member and presses the inserted substrate against the inner surface of the outer periphery of the opening hole;
    41. The substrate processing apparatus according to claim 38, comprising:
  42.  基板を溶液保持容器に収容されている基板処理溶液に浸漬させ、
     前記溶液保持容器に前記基板処理溶液を上方から下方に落下させて順次供給し、
     上方から下方に落下する前記基板処理溶液を前記基板に圧送する、基板処理方法。
    Immerse the substrate in the substrate processing solution stored in the solution holding container,
    The substrate processing solution is dropped from above into the solution holding container and supplied sequentially,
    A substrate processing method, wherein the substrate processing solution falling downward from above is pumped to the substrate.
  43.  基板処理溶液を収容していて基板が浸漬される溶液保持容器と、
     浸漬された前記基板の一面の基板処理領域に対して前記基板処理溶液が圧送されるとともに吸引される溶液乱流機構と、
    を有する基板処理装置。
    A solution holding container in which the substrate processing solution is stored and the substrate is immersed;
    A solution turbulence mechanism in which the substrate processing solution is pumped and sucked against a substrate processing region on one surface of the immersed substrate;
    A substrate processing apparatus.
  44.  前記溶液乱流機構は、複数の溶液吐出口から前記基板処理溶液を前記基板の一面の基板処理領域に圧送するとともに複数の溶液吸引口から前記基板処理溶液を吸引する請求項43に記載の基板処理装置。 44. The substrate according to claim 43, wherein the solution turbulence mechanism pumps the substrate processing solution from a plurality of solution discharge ports to a substrate processing region on one surface of the substrate and sucks the substrate processing solution from a plurality of solution suction ports. Processing equipment.
  45.  前記溶液乱流機構は、前記溶液吐出口と前記溶液吸引口とが所定の順番に配列されている請求項44に記載の基板処理装置。 45. The substrate processing apparatus according to claim 44, wherein the solution turbulence mechanism has the solution discharge port and the solution suction port arranged in a predetermined order.
  46.  前記溶液乱流機構は、前記溶液吐出口と前記溶液吸引口とが交互に配列されている請求項45に記載の基板処理装置。 46. The substrate processing apparatus of claim 45, wherein the solution turbulence mechanism has the solution discharge ports and the solution suction ports arranged alternately.
  47.  前記溶液保持容器の前記基板処理溶液に浸漬された前記基板を上下方向に揺動させる基板揺動機構を、さらに有する請求項43ないし46の何れか一項に記載の基板処理装置。 47. The substrate processing apparatus according to claim 43, further comprising a substrate swinging mechanism that swings the substrate immersed in the substrate processing solution of the solution holding container in a vertical direction.
  48.  前記基板が挿入される挿入口が上面に形成されているとともに前記基板処理領域が露出する開口孔が一面に形成されているボックス状の基板保持部材と、
     前記基板保持部材の他面内側に配置されていて挿入された前記基板を前記開口孔の外周内面に圧接させる拡縮自在なバルーン部材と、
    を有する請求項43ないし47の何れか一項に記載の基板処理装置。
    A box-shaped substrate holding member in which an insertion hole into which the substrate is inserted is formed on the upper surface and an opening hole through which the substrate processing region is exposed is formed on one surface;
    An expandable / contractible balloon member that is disposed inside the other surface of the substrate holding member and presses the inserted substrate against the inner surface of the outer periphery of the opening;
    48. A substrate processing apparatus according to any one of claims 43 to 47, comprising:
  49.  溶液保持容器に収容されている基板処理溶液に基板保持部材を浸漬させ、
     浸漬された前記基板処理領域の一面に前記基板処理溶液を圧送するとともに吸引する、基板処理方法。
    Immerse the substrate holding member in the substrate processing solution stored in the solution holding container,
    A substrate processing method for pumping and sucking the substrate processing solution to one surface of the immersed substrate processing region.
PCT/JP2011/001025 2010-02-24 2011-02-23 Substrate treating method and substrate treating apparatus WO2011105072A1 (en)

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JP2010132902A JP2011256444A (en) 2010-06-10 2010-06-10 Substrate treating method and substrate treating apparatus
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JP2010227118A JP5488384B2 (en) 2010-10-07 2010-10-07 Substrate processing equipment
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