WO2011104573A1 - Metodo y aparato para moldeo rotacional - Google Patents
Metodo y aparato para moldeo rotacional Download PDFInfo
- Publication number
- WO2011104573A1 WO2011104573A1 PCT/IB2010/000336 IB2010000336W WO2011104573A1 WO 2011104573 A1 WO2011104573 A1 WO 2011104573A1 IB 2010000336 W IB2010000336 W IB 2010000336W WO 2011104573 A1 WO2011104573 A1 WO 2011104573A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rotational molding
- molding apparatus
- containers
- container
- molds
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
- B29C41/06—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould about two or more axes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/34—Moulds or cores; Details thereof or accessories therefor movable, e.g. to or from the moulding station
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
- B29C41/042—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould by rotating a mould around its axis of symmetry
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/08—Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/08—Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder
- B29C41/085—Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder by rotating the former around its axis of symmetry
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
- B29C41/36—Feeding the material on to the mould, core or other substrate
Definitions
- the present invention relates to a process and an apparatus for making plastic articles by means of the rotational molding technique, and is more particularly directed to a process and an oven rotational molding apparatus for the production of multi-layer containers. . BACKGROUND OF THE INVENTION
- Rotational molding is a technique for manufacturing hollow items such as containers, from a thermoplastic material.
- the particles of said thermoplastic material in liquid form, powder or granules, are placed inside a hollow mold and the mold is rotated in a hot environment until the thermoplastic material melts on the entire interior surface of the mold.
- the feeding stage especially with the use of "drop-box” is usually done manually, and even in some cases it is necessary to suspend the heating since the material inside the "drop-box” can be plasticized before being emptied into the mold. All of the above implies delays in the global process, losses of heat from the furnace and therefore greater energy expenditure. The feeding stage becomes even more limiting when it comes to manufacturing several multi-layered items in a single cycle.
- US Patent 4,687,531 of Potoczky describes a device for forming structures with uniform walls that are made by means of rotation and heat in a mold, the mold is in a horizontal position, to achieve its objective the device of the prior art uses a device for introducing the material with a material sprinkler, which by means of compressed air spreads the material due to the use of an arm at the end that is inserted into the mold, this arm can move on the horizontal axis and the part where the materials come out has a movement of 90 °, the mold is in an oven which is heated to a desired temperature.
- This device has the disadvantage that at the time of placing the material, there are places where the placement of material is not performed, in addition it makes use of a person who knows how to maneuver the arm and place the materials in a uniform way, however the device of This makes use of molds which can be immediately reused to introduce the same material to the next mold, this is advantageous in a production line of more than one mold, in addition to the formation of two or more layers in the device of the state of the technique is necessary to place another arm with some other material, which by the way is not suggested in it; Finally, the arm does not have cooling means which facilitate the introduction of a different material for two or more layers.
- US Patent 3,744,951 of Szatkowski describes a system for making containers, the system consists of a furnace with carousel-shaped containers, it has different stations in which the molds are passing in each stage of forming, a station has an arm to be able to introducing the material, the arm is introduced into the molds to spread the material in powder form and then withdraw to follow the rotational molding, although this is an arm that enters and leaves the mold has the disadvantage that it is done by means of of sprinklers with which a number of auxiliary elements are used, in addition to moving the arm it must be moved with the entire base assembly, with which the energy consumption is significant, in addition to the formation of two or more containers it is necessary that each mold passes to the position of the arm which leads to a smaller number of containers per unit of time, when using a carousel, this can only be It is necessary to feed a single container, and for the realization of two or more layers it would be necessary to have two or more arms with material which would increase the cost of production since the arm can only be used for
- Publication WO 2008/133535 shows an oven in which molds of different aspects are introduced and in which the horizontal axis is rotated to make parts, this device has a door in which there is a window where a tube is inserted the which by means of pressure spreads the dust of the material inside, this once it comes into contact with the hot mold is forming the desired piece, however this oven only makes one piece at a time and there is no mention that the material is deposited and that this due to the rotation is distributed homogeneously to the mold. The material is blown into the mold and not only deposited so that later through the rotation it is distributed to the mold.
- the process and apparatus of the present invention can be used to make containers and other hollow articles from a thermoplastic resin material that is capable of forming a film under the influence of heat.
- a thermoplastic resin material that is capable of forming a film under the influence of heat.
- examples of such materials are polyethylene or other polyolefins such as polystyrene and PVC, or engineering plastics.
- the thermoplastic material is deposited directly in one or more molds inside the furnace with a molding chamber.
- the feeding system proposed in the present invention consists of a plurality of containers that are introduced through gates formed in the oven walls, without the need to remove the molds from the molding chamber.
- the containers have a cooling system that prevents the thermoplastic material from adhering to the surface of the container, and also undergoes a cleaning step before making the next load to the molds, which prevents the layer (s) ( s) become contaminated with material from the previous load.
- the present invention also proposes a highly efficient automated feeding system, ideal for processes involving various molds within the same production cycle.
- This system is based on the simultaneous feeding of two molds by the introduction of two containers containing the thermoplastic material towards the oven, subsequently the positioning of two other molds and the introduction of two other containers with material to be melted, and so on, until all the molds have the charge of the thermoplastic material.
- the rotational movement of the molds is then carried out within the molding chamber to form a first layer.
- the material that will form the second layer is fed by the feeding method described above, and the rotation of the molds to form the second layer, and so on. It is important to emphasize that the oven is at a practically constant temperature throughout the production cycle, which constitutes an advantage in the energy and economic aspect.
- the present invention constitutes an improvement to the prior art since it allows the production of multilayer articles in a furnace with a molding chamber, through a highly efficient process, without delays in the feeding stage of the thermoplastic material, without energy losses, achieving high quality articles and large volumes of production in a short time, and that uses a series of containers for the introduction of the materials to melt in the molds, without using spray or injection means to supply the thermomplastic material.
- Figure 1 is a perspective view of the rotational molding apparatus of the present invention.
- Figure 2 is a side view of the rotational molding apparatus of the present invention.
- Figure 3 constitutes a perspective view of the furnace which also shows the gates by means of which the material to be melted is introduced.
- Figure 4 represents a plan view of one of the plates that support the molds.
- Figures 5a and 5b are perspective views of one of the containers that transport the material to be melted into the oven, the container being coupled to a rotating arm; Figure 5a shows the container in position to contain the material to be melted, and Figure 5b shows the container in position to empty its contents.
- Figure 6 is a top perspective view of one of the containers to which the upper bottom has been omitted.
- Figure 7 is a top plan view of the container carrying the thermoplastic material, without the top bottom.
- Figure 8 is a perspective view of the container cooling system. DETAILED DESCRIPTION OF THE INVENTION
- Figure 1 shows a perspective view of the system of the present invention, which is mainly constituted by a furnace (1) with a molding chamber and a thermoplastic material feeding system, adjacent to the furnace.
- the oven (1) is a thermally insulated structure, preferably with sheet steel panels.
- the oven has an octagonal shape, as this configuration allows for better heating efficiency.
- cameras of any other polygonal shape such as hexagonal, or even cylindrical, spherical, cubic or other parallelepiped shaped cameras can be used.
- the oven (1) has heating means (not shown in the figures) that raise the temperature of the chamber sufficiently to plasticize the thermoplastic material.
- the preferred heating means are selected from burners powered by methane gas or LP gas (liquefied propane gas), digital burners, by electric arc, among others.
- the oven (1) has doors for opening / closing the oven (not shown in the figures) and additionally, one or more gates (8), (9) formed at least on one of the faces sides of oven, which preferably have a door to close and open the gate, to avoid thermal losses; said gates allow the material to be plasticized to enter the oven chamber.
- the oven has two side gates (8) located at the same height, and also has a central gate (9) that will be used to make larger tanks.
- the gates (8) and (9) are at an intermediate height with respect to the length of the oven chamber.
- the oven (1) has a means of holding the molds, traditionally known as spider.
- the spider consists of two plates, a front plate (3) and a rear plate (3 ') (see figures 1 and 2).
- the plates instead of the plates, other support units can be used, such as multi-arm frames.
- the plates (3), (3 ') are coupled in their center to an arrow (13) placed on the "X" axis, as shown in Figure 2.
- the plates are placed opposite each other so that the External faces are free to receive and hold the molds (2).
- the rotating arrow (13) in turn is perpendicularly coupled to another arrow (30) that transmits the turning movement to the spider on the ⁇ "axis.
- the arrow (30) is shown in segmented lines in Figure 1.
- the arrow (30) allows the spider to be rotated 180 ° to move the molds (2) of the front plate (3) back and the molds (2) of the rear plate (3 ') to the front.
- each mold (2 ) is able to receive the material to melt through the gates (8), (9).
- the number of molds (2) is eight, four placed on one plate and the other four on the other plate.
- the dish can withstand a greater number of molds.
- the use of larger molds will imply a smaller number of them. You can even opt for a single mold on each side of the spider, depending on the production needs. In this case, the introduction of the material to be melted can be done through the central gate (9).
- the thermoplastic material that is introduced to the molds (2) comes from one or more feeder containers (4).
- Each feeder container (4) is a tray that receives and contains the material to be melted.
- the container (4) is connected at its rear end to an arm (5) which in turn is coupled to a geared motor (6), this motor (6) transmits a 180 ° turning movement to the arm to turn the container (4) and thus empty the material to melt inside the mold.
- Each of the arms (5) is also coupled to a second gearmotor (16) that transmits the movement of the arm (4) forward to introduce the container (4) through one of the gates (8) or (9) , and back, to be aligned again with the rest of the arms (4).
- the number of containers (4) corresponds to the number of molds (2), so that each container (4) empties its contents into a given mold.
- the eight containers (4) are placed at the same height and are aligned with each other, as shown in Figure 1.
- the containers are also grouped into two groups of four, so that four containers (4) are close to one side gate (8) and the other four containers (4) are close to the other side gate (8).
- This configuration allows a container (4) of a first group to be introduced through a gate (8) and another container (4) of the second group through the other gate (8). Ideally, the introduction of the two containers (4) is carried out simultaneously.
- the arms (5) with their respective vessels (4) also have a horizontal displacement that is achieved by means of a third gearmotor. This displacement allows each of the containers (4) to be positioned at the height of the gates, so that all the containers can discharge their contents into the molds as required during the overall process.
- the movement of the containers (4) is not limited to the use of gearmotors, but hydraulic, mechanical, pneumatic, manual means, etc. can be used.
- each feeder container (4) has rounded walls, as seen in Figures 5a and 5b, to facilitate the emptying of the material to the mold and to prevent residual material adhering to the container (4).
- the feeder container (4) should be cooled to prevent particles from adhering to it, since the hot container can easily allow adhesion of the plastic material of the previous discharge.
- the present invention proposes a cooling system by means of water or another cooling liquid, wherein the cold liquid from a liquid cooling equipment is circulated to each of the containers (4), as will be explained below with reference to figures 6 and 7.
- the cooling liquid is water, which offers the advantage of being recyclable, low cost and high heat capacity.
- the container (4) is a double bottom structure, so that a chamber is formed through which water can circulate (see figure 6).
- the container has a cold water inlet (20) and a hot water outlet (21).
- the holes (20), (21) are preferably formed at one of the ends of the container, and more preferably, at the front end.
- the container (4) has a longitudinal division (22) formed inside the chamber, said division (22) projects from the front end of the container (4) but is finished off before the rear end. This division (22) allows the water that penetrates through the inlet orifice (20) to follow a path similar to a "U" (see figure 7) and then exits through the orifice (21).
- the water can be circulated inside the chamber of the container by other means, for example, with an internal pipe, a coil or any other element that allows water to travel to cool, however the use of the vertical division (22) for its simplicity and efficiency.
- the water that enters the containers (4) comes from a cooler (23) that sends the cold water to a first cold water distributor (24), said distributor (24) in turn It has connected hoses (25) that transport cold water to the containers (4) through the inlet holes (20).
- the hot water leaves the outlet orifices (21) through second hoses (26) that transport the water to a second distributor (27) that returns the hot water to the cooling equipment (23).
- the hoses (25), (26) are preferably made of a heat-resistant material, since they are connected at all times to the containers and will also be introduced into the oven during the discharge stage To the molds. Similarly, the hoses (25), (26) must be made of a flexible material that allows them to engage the rotation and displacement of the containers (4).
- the containers are made of stainless steel covered with non-stick material or other release material, chromed iron, carbon steel, aluminum or any other high temperature resistant material.
- the position of the molds is as shown in Figure 4, so that two of them are on the horizontal axis and the remaining two on the vertical axis.
- the spider has two positions for feeding the molds, said positions are determined by the rotation transmitted by the arrow (13). In a first position, two molds are fed simultaneously, for example, those found on the horizontal axis, by introducing two containers (4). Then a 90 ° rotation is carried out to the plate for the feeding of the two remaining molds. Subsequently the spider turns 180 ° by means of the arrow (30) to position the molds of the rear plate (3 ') in front of the gates. The loading operation is repeated as was done with the first plate (3), for the remaining molds. The procedure is repeated to form each of the layers that the product requires.
- An important advantage of the present invention is that since the container (4) is cold, there is no adhesion of residues to the walls of the container, avoiding contamination of the subsequent layers.
- a pressurized air cleaning system is also necessary to remove particles from the previous discharge and the container is ready for another load. Compressed air is applied to the containers when they leave the oven.
- the cleaning system of the containers is preferably placed in the support of the feeding system, below the containers. It consists of a fan-type venturi system to cover most of the container. Instead, any device with air movement can be used. When it is desired to clean the containers they are turned down to receive the compressed air. Preferably, the disposal of the containers is received in some container.
- the weighing and dosing system of the thermoplastic material that is proposed for the preferred mode is already known. It consists of one or more vacuum cleaners (10), each vacuum cleaner (10) is connected to a hopper (11) and a gravimetric balance (12) which has electronic level indicators. The discharge to the containers (4) is by an opening system. The vacuum cleaner (10) absorbs the plastic material from a silo (not shown in the figures) and transfers it to the hopper (11). The gravimetric balance (12) by electronic means sends a signal to the hopper (11) to stop feeding according to the weight for which the balance is programmed.
- three hoppers, three vacuum cleaners and three scales will be used.
- the system is configured so that, during the preparation of the first layer, a single balance (12) feeds all the containers of the first material to be used.
- the second hopper will be used and so on.
- the feeding to the containers can be done manually, by pneumatic, hydraulic means, among others.
- the system of the present invention has an oven control panel (40) and a power control panel (41), both of which are computerized systems.
- the power control panel works by coordinates. Both the feeding system and the oven control system are synchronized to feed the material.
- the system of the present invention also has a support device for feeders and a support for arms and vessels.
- the movement of the molds inside the oven can be carried out in various ways, for example, in the form of a carousel.
- stage of cleaning the containers (4) with compressed air can be carried out either at the moment when the containers leave the oven, or just before placing the material coming from the hopper.
- the product resulting from this process has all the advantages of rotomoulded articles in the oven, since homogeneity of the thickness of the walls is preserved, achieving high quality articles.
- the resulting product has improved attributes and lower manufacturing costs.
- Another advantage is the low energy cost compared to the processes that require extracting the molds of the oven for a new load, or other processes where the oven is opened to manually enter the load of the material to be melted, since each opening of the oven implies losses of heat energy Consequently, the process is also more economical and environmentally friendly.
- the product resulting from the process is a three-layer tank, wherein the outer layer is of a solid polyethylene based material, the intermediate layer is of a polyethylene based foaming and the inner layer of a polyethylene based antibacterial material.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Moulding By Coating Moulds (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Processing Of Solid Wastes (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR112012021237-0A BR112012021237B1 (pt) | 2010-02-23 | 2010-02-23 | aparelho de rotomoldagem e método para produzir artigos de plástico por meio da técnica de moldagem rotacional |
AU2010346962A AU2010346962B2 (en) | 2010-02-23 | 2010-02-23 | Rotational molding method and apparatus |
DE112010005292.1T DE112010005292B4 (de) | 2010-02-23 | 2010-02-23 | Verfahren und Vorrichtung zum Rotationsformen |
MX2012009314A MX345815B (es) | 2010-02-23 | 2010-02-23 | Metodo y aparato para moldeo rotacional. |
CN201080066141.3A CN102858509B (zh) | 2010-02-23 | 2010-02-23 | 旋转模塑方法及设备 |
PCT/IB2010/000336 WO2011104573A1 (es) | 2010-02-23 | 2010-02-23 | Metodo y aparato para moldeo rotacional |
US13/580,907 US9533435B2 (en) | 2010-02-23 | 2010-02-23 | Rotational molding method and apparatus |
UY0001033235A UY33235A (es) | 2010-02-23 | 2011-02-18 | Metodo y aparato para moldeo rotacional |
ARP110100516A AR079770A1 (es) | 2010-02-23 | 2011-02-18 | Metodos y aparato para moldeo rotacional |
SM201200043T SMP201200043B (it) | 2010-02-23 | 2012-09-20 | Metodo e apparato per stampaggio rotazionale |
HK13102495.1A HK1175438A1 (en) | 2010-02-23 | 2013-02-27 | Rotational molding method and apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2010/000336 WO2011104573A1 (es) | 2010-02-23 | 2010-02-23 | Metodo y aparato para moldeo rotacional |
Publications (1)
Publication Number | Publication Date |
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WO2011104573A1 true WO2011104573A1 (es) | 2011-09-01 |
Family
ID=44212278
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2010/000336 WO2011104573A1 (es) | 2010-02-23 | 2010-02-23 | Metodo y aparato para moldeo rotacional |
Country Status (11)
Country | Link |
---|---|
US (1) | US9533435B2 (es) |
CN (1) | CN102858509B (es) |
AR (1) | AR079770A1 (es) |
AU (1) | AU2010346962B2 (es) |
BR (1) | BR112012021237B1 (es) |
DE (1) | DE112010005292B4 (es) |
HK (1) | HK1175438A1 (es) |
MX (1) | MX345815B (es) |
SM (1) | SMP201200043B (es) |
UY (1) | UY33235A (es) |
WO (1) | WO2011104573A1 (es) |
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JP6428609B2 (ja) * | 2013-05-10 | 2018-11-28 | 日本電気株式会社 | 二次電池用電解液および二次電池 |
CN104139478B (zh) * | 2014-06-27 | 2017-02-22 | 大连船舶重工集团有限公司 | 一种基于快速管件内壁滚塑设备的工艺方法 |
EP3183104A1 (en) * | 2014-08-22 | 2017-06-28 | 3M Innovative Properties Company | Method and composition including thermoplastic particles and hollow microspheres and articles made from them |
US10243234B2 (en) * | 2014-10-24 | 2019-03-26 | Nec Corporation | Secondary battery |
CN105729697B (zh) * | 2016-02-29 | 2019-04-26 | 浙江海洋学院 | 一种滚塑游艇的铸造上件 |
US9802340B1 (en) | 2016-09-12 | 2017-10-31 | Kenneth S. Anderson | Method and fixture for molding a tank with an embedded ring |
CN106827566B (zh) * | 2016-12-28 | 2018-12-28 | 重庆瑞霆塑胶有限公司 | 中空塑胶的制作方法 |
CN206520155U (zh) * | 2017-01-25 | 2017-09-26 | 得意精密电子(苏州)有限公司 | 注塑机装置和气压支承机构 |
CN108454009B (zh) * | 2018-03-07 | 2023-11-10 | 东莞市荣昌盛航空科技有限公司 | 一种节能环保塑料加工机 |
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WO2008131555A2 (en) * | 2007-05-01 | 2008-11-06 | University Of Ontario Institute Of Technology | Extrusion assisted rotational foam molding process |
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US6409493B1 (en) | 2000-03-20 | 2002-06-25 | Textron Automotive Company, Inc. | Double-cast slush molding method and apparatus |
CN2908117Y (zh) * | 2006-05-19 | 2007-06-06 | 慈溪市德顺容器有限公司 | 一种滚塑机 |
CA2689253A1 (en) | 2007-04-30 | 2008-11-06 | Charles Caulder Bree | Rotationally moulded products and moulds |
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2010
- 2010-02-23 BR BR112012021237-0A patent/BR112012021237B1/pt not_active IP Right Cessation
- 2010-02-23 DE DE112010005292.1T patent/DE112010005292B4/de not_active Expired - Fee Related
- 2010-02-23 US US13/580,907 patent/US9533435B2/en not_active Expired - Fee Related
- 2010-02-23 WO PCT/IB2010/000336 patent/WO2011104573A1/es active Application Filing
- 2010-02-23 MX MX2012009314A patent/MX345815B/es active IP Right Grant
- 2010-02-23 AU AU2010346962A patent/AU2010346962B2/en not_active Ceased
- 2010-02-23 CN CN201080066141.3A patent/CN102858509B/zh not_active Expired - Fee Related
-
2011
- 2011-02-18 AR ARP110100516A patent/AR079770A1/es not_active Application Discontinuation
- 2011-02-18 UY UY0001033235A patent/UY33235A/es unknown
-
2012
- 2012-09-20 SM SM201200043T patent/SMP201200043B/it unknown
-
2013
- 2013-02-27 HK HK13102495.1A patent/HK1175438A1/xx not_active IP Right Cessation
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US20060088622A1 (en) * | 2004-10-22 | 2006-04-27 | Claudia Persico | Device and mold for rotational molding of plastic materials |
WO2008131555A2 (en) * | 2007-05-01 | 2008-11-06 | University Of Ontario Institute Of Technology | Extrusion assisted rotational foam molding process |
Also Published As
Publication number | Publication date |
---|---|
CN102858509B (zh) | 2014-12-03 |
AU2010346962B2 (en) | 2014-01-09 |
AU2010346962A1 (en) | 2012-10-11 |
SMP201200043B (it) | 2013-01-14 |
MX2012009314A (es) | 2012-09-07 |
UY33235A (es) | 2011-06-30 |
DE112010005292T5 (de) | 2013-03-07 |
MX345815B (es) | 2017-02-17 |
BR112012021237A2 (pt) | 2016-05-17 |
US20130026684A1 (en) | 2013-01-31 |
DE112010005292B4 (de) | 2016-06-16 |
SMAP201200043A (it) | 2012-10-31 |
US9533435B2 (en) | 2017-01-03 |
BR112012021237B1 (pt) | 2019-10-29 |
HK1175438A1 (en) | 2013-07-05 |
CN102858509A (zh) | 2013-01-02 |
AR079770A1 (es) | 2012-02-22 |
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