WO2011070446A1 - Formule désodorisante - Google Patents

Formule désodorisante Download PDF

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Publication number
WO2011070446A1
WO2011070446A1 PCT/IB2010/003451 IB2010003451W WO2011070446A1 WO 2011070446 A1 WO2011070446 A1 WO 2011070446A1 IB 2010003451 W IB2010003451 W IB 2010003451W WO 2011070446 A1 WO2011070446 A1 WO 2011070446A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
sulfur
deodorizing
formulation according
component
Prior art date
Application number
PCT/IB2010/003451
Other languages
German (de)
English (en)
Inventor
Robert Wuest
Original Assignee
Biothys S.A. (Societe Anonyme)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biothys S.A. (Societe Anonyme) filed Critical Biothys S.A. (Societe Anonyme)
Priority to EP10814658A priority Critical patent/EP2509642A1/fr
Publication of WO2011070446A1 publication Critical patent/WO2011070446A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions

Definitions

  • the invention relates to a deodorizing formulation, in particular for a mixture of bitumen and sulfur, which contains active, odor-reducing agents and a diluent, and to processes for the preparation of a composition based on sulfur, which can be used for odor reduction.
  • bitumen processing can be carried out at lower temperatures in the range of 130 to 150 ° C.
  • US-A-3,960,585 and WO 2005/059016 disclose that the formation of hydrogen sulfide upon heating a mixture of asphalt and sulfur can be suppressed by the addition of free radical-forming inhibitors and / or redox catalysts. However, these additives are not sufficiently effective.
  • the invention therefore an object of the invention to suppress or at least reduce this odor nuisance in mixtures of bitumen and sulfur.
  • a deodorizing formulation according to claim 1 comprising active agents and at least one diluent, the active agents comprising the following components:
  • the active agents consist of the following components:
  • EP-A 1 235 768 and WO 2009/019 041 describe processes for reducing the odor of bitumen in which odor-reducing formulations are mixed into liquid bitumen, which in particular contain certain carboxylic acid esters or certain aldehydes.
  • the foul-smelling volatiles of bitumen consist essentially of organic sulfur and nitrogen compounds, while in the present case especially hydrogen sulphide and sulfur dioxide must be eliminated.
  • the bitumen / sulfur mixture preferably contains minor amounts of sulfur, in particular 20 to 40 wt.%.
  • the deodorizing formulation of active agents and diluents is preferably incorporated into the bitumen / sulfur mixture in amounts of from 50 to 1000 ppm, in particular from 100 to 500 ppm, the formulation preferably being from 5 to 50% by weight and in particular from 10 to 40% by weight of active agents and from 95 to 50% by weight, in particular from 90 to 60% by weight, of diluent.
  • Component A is preferably benzyl salicylate, but other alkyl salicylates having 1 to 8 carbon atoms in the alkyl radical are also suitable, for example methyl salicylate.
  • Benzylsalicylate has the great advantage that it is extremely high due to its very high boiling point low vapor pressure, so that the deodorizing formulation remains effective in the mixture of bitumen and sulfur for a long time, eg several months.
  • Component B is preferably heptanal or dodecanal.
  • the further aldehydes of component C are preferably selected from:
  • the alcohols of component D are preferably naturally occurring alcohols selected from:
  • Limonene (1-methyl-4-prop-1-en-2-ylcyclohexene C] 0 Hi 6 ).
  • the optional ketones of component F are preferably selected from:
  • Benzophenone butyl methyl ketone and 1,8-cineole.
  • the active agents are used together with a diluent.
  • the deodorizing formulation causes the deodorizing formulation to be in liquid form. At the same time it acts as a mixing agent when mixing the individual components. In addition, it prevents that evaporate at relatively high temperature individual relatively low-boiling components of the active agents.
  • Preferred diluents are mineral oils, ie hydrocarbon middle distillates, such as CATENEX from SHELL, and vegetable oils, such as sunflower oil or mixtures thereof.
  • the present invention further relates to a method according to
  • a deodorant composition based on sulfur and 0.02 to 0.3% by weight of the deodorizing formulation, if appropriate together with 0 to 8% by weight of other additives, is initially used , each based on sulfur produced.
  • Suitable additives are processing aids, for example ethylenebisstearylamide or amyl acetate, and colorants, for example carbon powders. This mixture can then be incorporated at 140 to 170 ° C in liquid bitumen.
  • sulfur based means that sulfur is the essential ingredient of the composition.
  • the first deodorizing agent Preferably, the first deodorizing agent
  • Mixture of sulfur and optionally the processing aid and the colorant to produce and apply the deodorizing formulation on the particles on the surface for example, according to customary in plastics technology by spraying, by tumbling or by compounding.
  • a mixture of active agents was prepared from:
  • a mixture of active agents was prepared from:

Landscapes

  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

L'invention concerne une formule désodorisante, notamment pour un mélange de bitume et de soufre, laquelle formule contient des agents actifs atténuant les odeurs, à base d'esters d'acide salicylique, d'aldéhydes et éventuellement d'alcools, ainsi qu'un diluant. L'invention concerne en outre des procédés de préparation d'une composition désodorisante à base de soufre, laquelle peut être incorporée au bitume en vue d'atténuer les odeurs.
PCT/IB2010/003451 2009-12-08 2010-12-07 Formule désodorisante WO2011070446A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10814658A EP2509642A1 (fr) 2009-12-08 2010-12-07 Formule désodorisante

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09306195A EP2338526A1 (fr) 2009-12-08 2009-12-08 Formule désodorisante
EP09306195.0 2009-12-08

Publications (1)

Publication Number Publication Date
WO2011070446A1 true WO2011070446A1 (fr) 2011-06-16

Family

ID=42209374

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2010/003451 WO2011070446A1 (fr) 2009-12-08 2010-12-07 Formule désodorisante

Country Status (2)

Country Link
EP (2) EP2338526A1 (fr)
WO (1) WO2011070446A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018068728A1 (fr) * 2016-10-12 2018-04-19 Shell Internationale Research Maatschappij B.V. Procédé de réduction d'odeurs de bitume et de crmb
US11274208B2 (en) 2016-10-12 2022-03-15 Shell Oil Company Reducing crumb rubber modified bitumen odors

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960585A (en) 1973-12-17 1976-06-01 Shell Oil Company Reducing H2 S-emission from hot cast sulfur-asphalt mixtures
DE19725920A1 (de) * 1996-06-25 1998-02-05 Heresch & Heresch Umweltengine Verfahren zur Geruchsneutralisation bei Asphaltmischanlagen
EP1235768A1 (fr) 1999-11-16 2002-09-04 Alan Jeffrey Ronyak Composition hydrocarbonee contenant des agents de suppression d'odeur
WO2004045657A1 (fr) * 2002-11-15 2004-06-03 Air & D - Sarl Procede pour desodoriser des installations de grande surface
WO2005059016A1 (fr) 2003-12-10 2005-06-30 Shell Internationale Research Maatschappij B.V. Granules de soufre contenant un suppresseur de h2s
US6987207B1 (en) * 2005-03-03 2006-01-17 Alan Jeffrey Ronyak Hydrocarbonaceous composition
EP1772158A2 (fr) * 2005-10-06 2007-04-11 Air & D- Sarl Procédé du reduction des substances malodorantes dans citernes
WO2009019041A1 (fr) 2007-08-09 2009-02-12 Air & D - Sarl Procédé de réduction de l'odeur du bitume
DE102007062314A1 (de) * 2007-12-21 2009-06-25 Air & D - Sarl Verfahren zum Reduzieren von übelriechenden Substanzen in Tankbehältern

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960585A (en) 1973-12-17 1976-06-01 Shell Oil Company Reducing H2 S-emission from hot cast sulfur-asphalt mixtures
DE19725920A1 (de) * 1996-06-25 1998-02-05 Heresch & Heresch Umweltengine Verfahren zur Geruchsneutralisation bei Asphaltmischanlagen
EP1235768A1 (fr) 1999-11-16 2002-09-04 Alan Jeffrey Ronyak Composition hydrocarbonee contenant des agents de suppression d'odeur
WO2004045657A1 (fr) * 2002-11-15 2004-06-03 Air & D - Sarl Procede pour desodoriser des installations de grande surface
WO2005059016A1 (fr) 2003-12-10 2005-06-30 Shell Internationale Research Maatschappij B.V. Granules de soufre contenant un suppresseur de h2s
US6987207B1 (en) * 2005-03-03 2006-01-17 Alan Jeffrey Ronyak Hydrocarbonaceous composition
EP1772158A2 (fr) * 2005-10-06 2007-04-11 Air & D- Sarl Procédé du reduction des substances malodorantes dans citernes
WO2009019041A1 (fr) 2007-08-09 2009-02-12 Air & D - Sarl Procédé de réduction de l'odeur du bitume
DE102007037534A1 (de) * 2007-08-09 2009-02-12 Air & D - Sarl Verfahren zu Geruchsverminderung bei Bitumen
DE102007062314A1 (de) * 2007-12-21 2009-06-25 Air & D - Sarl Verfahren zum Reduzieren von übelriechenden Substanzen in Tankbehältern

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018068728A1 (fr) * 2016-10-12 2018-04-19 Shell Internationale Research Maatschappij B.V. Procédé de réduction d'odeurs de bitume et de crmb
US11274208B2 (en) 2016-10-12 2022-03-15 Shell Oil Company Reducing crumb rubber modified bitumen odors

Also Published As

Publication number Publication date
EP2338526A1 (fr) 2011-06-29
EP2509642A1 (fr) 2012-10-17

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