WO2011014022A3 - Composé métallocène, composition de catalyseur le contenant, et polymères oléfiniques produits à l'aide de celui-ci - Google Patents

Composé métallocène, composition de catalyseur le contenant, et polymères oléfiniques produits à l'aide de celui-ci Download PDF

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Publication number
WO2011014022A3
WO2011014022A3 PCT/KR2010/004991 KR2010004991W WO2011014022A3 WO 2011014022 A3 WO2011014022 A3 WO 2011014022A3 KR 2010004991 W KR2010004991 W KR 2010004991W WO 2011014022 A3 WO2011014022 A3 WO 2011014022A3
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WO
WIPO (PCT)
Prior art keywords
same
metallocene compound
olefinic polymers
catalyst composition
produced
Prior art date
Application number
PCT/KR2010/004991
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English (en)
Korean (ko)
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WO2011014022A2 (fr
Inventor
이용호
전만성
이기수
권헌용
조민석
박종상
조준희
김현국
송은경
김선경
홍대식
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to EP10804735.8A priority Critical patent/EP2460809B1/fr
Priority to US13/386,620 priority patent/US8692009B2/en
Priority to CN201080043648.7A priority patent/CN102574885B/zh
Priority to SG2012005880A priority patent/SG178126A1/en
Priority to JP2012522765A priority patent/JP5712213B2/ja
Publication of WO2011014022A2 publication Critical patent/WO2011014022A2/fr
Publication of WO2011014022A3 publication Critical patent/WO2011014022A3/fr
Priority to US14/077,896 priority patent/US9221922B2/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un nouveau composé métallocène, une composition de catalyseur le contenant, et des polymères oléfiniques produits à l'aide de celui-ci. Le composé métallocène selon l'invention et la composition de catalyseur le contenant peuvent être utilisés lors de la production de polymères oléfiniques, ont de remarquables propriétés de copolymérisation, et peuvent produire des polymères oléfiniques de masse moléculaire élevée. En particulier, lorsque le composé métallocène selon l'invention est employé, des copolymères séquencés hautement thermorésistants peuvent être produits, ainsi que des polymères oléfiniques présentant un point de fusion (Tm) élevé même si l'on augmente la teneur en comonomère lors de la production du polymère oléfinique.
PCT/KR2010/004991 2009-07-31 2010-07-29 Composé métallocène, composition de catalyseur le contenant, et polymères oléfiniques produits à l'aide de celui-ci WO2011014022A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP10804735.8A EP2460809B1 (fr) 2009-07-31 2010-07-29 Composé métallocène, composition de catalyseur le contenant, et polymères oléfiniques produits à l'aide de celui-ci
US13/386,620 US8692009B2 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same
CN201080043648.7A CN102574885B (zh) 2009-07-31 2010-07-29 茂金属化合物、包含该茂金属化合物的催化剂组合物和使用该催化剂组合物制备的烯烃聚合物
SG2012005880A SG178126A1 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same
JP2012522765A JP5712213B2 (ja) 2009-07-31 2010-07-29 メタロセン化合物、これを含む触媒組成物、およびこれを利用して製造されたオレフィン系重合体
US14/077,896 US9221922B2 (en) 2009-07-31 2013-11-12 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20090070574 2009-07-31
KR10-2009-0070574 2009-07-31
KR10-2010-0072934 2010-07-28
KR1020100072934A KR101154507B1 (ko) 2009-07-31 2010-07-28 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/386,620 A-371-Of-International US8692009B2 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same
US14/077,896 Continuation US9221922B2 (en) 2009-07-31 2013-11-12 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same

Publications (2)

Publication Number Publication Date
WO2011014022A2 WO2011014022A2 (fr) 2011-02-03
WO2011014022A3 true WO2011014022A3 (fr) 2011-06-16

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Application Number Title Priority Date Filing Date
PCT/KR2010/004991 WO2011014022A2 (fr) 2009-07-31 2010-07-29 Composé métallocène, composition de catalyseur le contenant, et polymères oléfiniques produits à l'aide de celui-ci

Country Status (7)

Country Link
US (2) US8692009B2 (fr)
EP (1) EP2460809B1 (fr)
JP (1) JP5712213B2 (fr)
KR (1) KR101154507B1 (fr)
CN (1) CN102574885B (fr)
SG (1) SG178126A1 (fr)
WO (1) WO2011014022A2 (fr)

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JP2014503027A (ja) * 2011-01-27 2014-02-06 エルジー・ケム・リミテッド オレフィンブロック共重合体
US9000115B2 (en) * 2011-01-27 2015-04-07 Lg Chem, Ltd. Olefin block copolymers and production methods thereof
WO2012102572A2 (fr) * 2011-01-27 2012-08-02 주식회사 엘지화학 Copolymère séquencé d'oléfine
KR101503002B1 (ko) * 2011-01-28 2015-04-01 주식회사 엘지화학 메탈로센 화합물 및 이를 이용하여 제조되는 올레핀계 중합체
EP2760895A4 (fr) * 2011-09-30 2015-07-22 Exxonmobil Chem Patents Inc Modulation dynamique de catalyseurs à métallocène
WO2013168928A1 (fr) 2012-05-08 2013-11-14 주식회사 엘지화학 Composé ansa-métallocène et procédé de préparation de catalyseur supporté l'utilisant
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
KR101623485B1 (ko) * 2013-08-01 2016-05-23 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101650092B1 (ko) * 2013-08-01 2016-08-22 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101644113B1 (ko) 2013-10-18 2016-07-29 주식회사 엘지화학 혼성 담지 메탈로센 촉매
KR101631700B1 (ko) 2013-10-18 2016-06-17 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법
KR101549209B1 (ko) 2013-11-18 2015-09-02 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
KR101705340B1 (ko) * 2014-06-03 2017-02-09 주식회사 엘지화학 폴리올레핀의 제조 방법 및 이로부터 제조된 폴리올레핀
KR101666170B1 (ko) * 2014-06-18 2016-10-13 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 폴리올레핀의 제조방법
KR101617870B1 (ko) * 2014-09-05 2016-05-03 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
KR101685664B1 (ko) * 2014-09-05 2016-12-12 주식회사 엘지화학 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101761394B1 (ko) * 2014-09-30 2017-07-25 주식회사 엘지화학 섬유 제조용 폴리올레핀 중합체의 제조방법
EP3056524B1 (fr) 2014-10-13 2021-09-22 LG Chem, Ltd. Copolymère d'éthylène/1-butène présentant d'excellente processabilité et résistance à la fissuration sous contrainte environnementale
WO2016060445A1 (fr) * 2014-10-13 2016-04-21 주식회사 엘지화학 Copolymère d'éthylène/1-hexène ou d'éthylène/1-butène présentant d'excellentes propriétés de travail et résistance à la fissuration sous contrainte environnementale
KR101747396B1 (ko) * 2014-12-15 2017-06-14 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
CN106661072B (zh) 2015-01-28 2021-03-12 Lg化学株式会社 金属茂化合物、包含其的催化剂组合物以及使用其制备基于烯烃的聚合物的方法
CN106536534B (zh) 2015-01-28 2021-03-12 Lg化学株式会社 金属茂化合物、包含其的催化剂组合物以及使用其制备聚烯烃的方法
KR101891638B1 (ko) 2015-04-15 2018-08-24 주식회사 엘지화학 가공성이 우수한 에틸렌/알파-올레핀 공중합체 공중합체
KR101768194B1 (ko) 2015-05-15 2017-08-16 주식회사 엘지화학 촉매 조성물 및 이를 이용한 폴리올레핀의 제조방법
KR20160134464A (ko) 2015-05-15 2016-11-23 주식회사 엘지화학 혼성 담지 촉매계, 및 이를 이용한 폴리올레핀의 제조방법
US10513474B2 (en) 2015-05-15 2019-12-24 Lg Chem, Ltd. Catalyst composition and method of preparing polyolefin using the same
KR101790672B1 (ko) 2015-08-24 2017-10-26 주식회사 엘지화학 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법
WO2018122134A1 (fr) 2016-12-29 2018-07-05 Borealis Ag Catalyseurs
WO2019179959A1 (fr) 2018-03-19 2019-09-26 Borealis Ag Catalyseurs pour la polymérisation d'oléfines
US11643427B2 (en) 2018-06-28 2023-05-09 Borealis Ag Catalysts
BR112022010356A2 (pt) * 2019-12-04 2022-08-16 Borealis Ag Mantas leves sopradas em fusão com propriedades de barreira aprimoradas

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Publication number Publication date
JP5712213B2 (ja) 2015-05-07
US9221922B2 (en) 2015-12-29
EP2460809B1 (fr) 2015-06-17
US20120123078A1 (en) 2012-05-17
JP2013500331A (ja) 2013-01-07
US20140066288A1 (en) 2014-03-06
SG178126A1 (en) 2012-03-29
KR101154507B1 (ko) 2012-06-13
CN102574885A (zh) 2012-07-11
KR20110013286A (ko) 2011-02-09
CN102574885B (zh) 2014-12-31
EP2460809A4 (fr) 2014-09-03
EP2460809A2 (fr) 2012-06-06
US8692009B2 (en) 2014-04-08
WO2011014022A2 (fr) 2011-02-03

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