MX367637B - Copolimeros de etileno, pelicula y proceso de polimerizacion. - Google Patents
Copolimeros de etileno, pelicula y proceso de polimerizacion.Info
- Publication number
- MX367637B MX367637B MX2014014715A MX2014014715A MX367637B MX 367637 B MX367637 B MX 367637B MX 2014014715 A MX2014014715 A MX 2014014715A MX 2014014715 A MX2014014715 A MX 2014014715A MX 367637 B MX367637 B MX 367637B
- Authority
- MX
- Mexico
- Prior art keywords
- copolymers
- polymerization process
- tref
- ethylene copolymers
- film
- Prior art date
Links
- 229920001038 ethylene copolymer Polymers 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000010828 elution Methods 0.000 abstract 1
- 238000005194 fractionation Methods 0.000 abstract 1
- QLNAVQRIWDRPHA-UHFFFAOYSA-N iminophosphane Chemical compound P=N QLNAVQRIWDRPHA-UHFFFAOYSA-N 0.000 abstract 1
- 230000000630 rising effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Se dan a conocer copolímeros de etileno que tienen una relación de flujo de fusión relativamente alta y un perfil multimodal en un diagrama de fraccionamiento de elución por elevación de temperatura (TREF). Los copolímeros se pueden formar en una película que tiene buenos valores de resistencia al impacto por dardo y buenas propiedades de rigidez bajo presiones disminuidas de la extrusora.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2780508 CA2780508A1 (en) | 2012-06-21 | 2012-06-21 | Polyethylene composition, film and polymerization process |
| CA2798855A CA2798855C (en) | 2012-06-21 | 2012-12-14 | Ethylene copolymers having reverse comonomer incorporation |
| PCT/CA2013/000498 WO2013188950A1 (en) | 2012-06-21 | 2013-05-24 | Ethylene copolymers, film and polymerization process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014014715A MX2014014715A (es) | 2015-03-04 |
| MX367637B true MX367637B (es) | 2019-08-29 |
Family
ID=49767962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014014715A MX367637B (es) | 2012-06-21 | 2013-05-24 | Copolimeros de etileno, pelicula y proceso de polimerizacion. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US9079991B2 (es) |
| EP (1) | EP2864369B1 (es) |
| JP (1) | JP6211073B2 (es) |
| KR (1) | KR102104302B1 (es) |
| CN (1) | CN104470955B (es) |
| BR (1) | BR112014031920B1 (es) |
| CA (1) | CA2798855C (es) |
| ES (1) | ES2712684T3 (es) |
| MX (1) | MX367637B (es) |
| WO (1) | WO2013188950A1 (es) |
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| NO2931763T3 (es) * | 2012-12-14 | 2018-06-30 | ||
| CN104822716B (zh) | 2012-12-21 | 2017-11-14 | 埃克森美孚化学专利公司 | 具有改进的加工性的支化聚乙烯及由其制成的高抗撕裂性膜 |
| CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
| US9181369B2 (en) | 2013-03-11 | 2015-11-10 | Chevron Phillips Chemical Company Lp | Polymer films having improved heat sealing properties |
| ES2632549T3 (es) * | 2013-03-28 | 2017-09-14 | Dow Global Technologies Llc | Composición de interpolímero de etileno/alfa-olefina |
| CA2820501C (en) | 2013-06-27 | 2021-01-26 | Nova Chemicals Corporation | Synthesis of phosphinimide coordination compounds |
| KR101657680B1 (ko) | 2013-09-30 | 2016-09-19 | 주식회사 엘지화학 | 폴리올레핀 |
| US9181370B2 (en) | 2013-11-06 | 2015-11-10 | Chevron Phillips Chemical Company Lp | Low density polyolefin resins with low molecular weight and high molecular weight components, and films made therefrom |
| KR101549209B1 (ko) * | 2013-11-18 | 2015-09-02 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| US10253121B2 (en) * | 2014-02-11 | 2019-04-09 | Univation Technologies, Llc | Method of producing polyethylene and polyethylene thereof |
| TWI557140B (zh) * | 2014-08-19 | 2016-11-11 | 努發化工(國際)公司 | 使用單活性中心催化劑產生之乙烯共聚物 |
| KR101617870B1 (ko) | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| US9441063B2 (en) * | 2014-10-09 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports |
| CA2871463A1 (en) * | 2014-11-19 | 2016-05-19 | Nova Chemicals Corporation | Passivated supports: catalyst, process and product |
| KR101747396B1 (ko) * | 2014-12-15 | 2017-06-14 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| CA2874344C (en) | 2014-12-15 | 2021-08-31 | Nova Chemicals Corporation | Spheroidal catalyst for olefin polymerization |
| US10494462B2 (en) | 2015-04-23 | 2019-12-03 | Univation Technologies, Llc | Polyethylene copolymers having a particular comonomer distribution |
| CA2900772C (en) * | 2015-08-20 | 2022-07-12 | Nova Chemicals Corporation | Method for altering melt flow ratio of ethylene polymers |
| CN107922527A (zh) | 2015-08-31 | 2018-04-17 | 埃克森美孚化学专利公司 | 用于聚烯烃反应的具有悬垂烯烃的铝烷基 |
| US10676547B2 (en) | 2015-08-31 | 2020-06-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins on clays |
| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| US9982067B2 (en) | 2015-09-24 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports |
| US10414887B2 (en) | 2015-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
| US9994657B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US10000593B2 (en) | 2015-10-02 | 2018-06-19 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| US9982076B2 (en) | 2015-10-02 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Supported bis phenolate transition metals complexes, production and use thereof |
| US9994658B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
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|---|---|
| EP2864369A1 (en) | 2015-04-29 |
| BR112014031920A2 (pt) | 2017-06-27 |
| CA2798855A1 (en) | 2013-12-21 |
| CA2798855C (en) | 2021-01-26 |
| ES2712684T3 (es) | 2019-05-14 |
| US20130345377A1 (en) | 2013-12-26 |
| JP2015520276A (ja) | 2015-07-16 |
| CN104470955A (zh) | 2015-03-25 |
| KR102104302B1 (ko) | 2020-04-27 |
| EP2864369B1 (en) | 2018-12-05 |
| BR112014031920B1 (pt) | 2021-04-20 |
| US9382394B2 (en) | 2016-07-05 |
| EP2864369A4 (en) | 2016-03-30 |
| WO2013188950A1 (en) | 2013-12-27 |
| CN104470955B (zh) | 2016-08-24 |
| MX2014014715A (es) | 2015-03-04 |
| US20150252159A1 (en) | 2015-09-10 |
| KR20150027235A (ko) | 2015-03-11 |
| US9079991B2 (en) | 2015-07-14 |
| JP6211073B2 (ja) | 2017-10-11 |
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