WO2010148652A1 - Composition de diesel et procédé pour l'amélioration de la stabilité d'un biodiesel à l'oxydation - Google Patents

Composition de diesel et procédé pour l'amélioration de la stabilité d'un biodiesel à l'oxydation Download PDF

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WO2010148652A1
WO2010148652A1 PCT/CN2010/000950 CN2010000950W WO2010148652A1 WO 2010148652 A1 WO2010148652 A1 WO 2010148652A1 CN 2010000950 W CN2010000950 W CN 2010000950W WO 2010148652 A1 WO2010148652 A1 WO 2010148652A1
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Prior art keywords
diesel
diesel fuel
biodiesel
substituted
phenyl
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PCT/CN2010/000950
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English (en)
Chinese (zh)
Inventor
蔺建民
张永光
张建荣
李航
李率
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中国石油化工股份有限公司
中国石油化工股份有限公司石油化工科学研究院
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Priority claimed from CN 200910087970 external-priority patent/CN101928614B/zh
Priority claimed from CN 200910089959 external-priority patent/CN101987980B/zh
Priority claimed from CN200910090512.0A external-priority patent/CN101993744B/zh
Priority claimed from CN 200910090511 external-priority patent/CN101993743B/zh
Application filed by 中国石油化工股份有限公司, 中国石油化工股份有限公司石油化工科学研究院 filed Critical 中国石油化工股份有限公司
Priority to US13/380,334 priority Critical patent/US20120124896A1/en
Priority to EP10791159.6A priority patent/EP2447344B1/fr
Priority to ES10791159T priority patent/ES2749879T3/es
Priority to BRPI1012681-3A priority patent/BRPI1012681B1/pt
Publication of WO2010148652A1 publication Critical patent/WO2010148652A1/fr

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Definitions

  • Biodiesel B 0 Fatty acids (Fa yAcd ehy E e ) are oil crops such as soybeans and rapeseed, and oils such as Phyllostachys pubescens, oils and plants of engineering oils, oils and fats of aquatic plants, oils and fats, catering and other raw materials (ethanol). The exchange is reversed, yes biofuel.
  • Biodiesel has three major types of renewable and safe, and my adjustment, energy security and comprehensive management are very significant. However, China's solid oil is currently solid, oil reserves are very limited, and a large amount of oil is caused by the safety of our solid energy. Therefore, the research and development of biodiesel is inherently important.
  • Taishou Zhou Petroleum Diesel ie, the usual diesel fuel is also powered by biodiesel
  • special petroleum diesel oil and non-compounds such as compounds and nitrides are insoluble in the oxidation of oxygen in the form of oxygen.
  • the use of insoluble particles to fuel generated in petroleum diesel storage causes the blockage of the fuel system components, resulting in incomplete combustion or even formation in the nozzle.
  • Biodiesel has the same oxidation stability as petroleum diesel oil and diesel. The most performance is the stability of biodiesel blended fuel compared to petroleum diesel.
  • the above issues can be resolved or .
  • the way is to oxidize the oxygen in the biodiesel and aging the damage.
  • the other is to stabilize the blended fuel of petroleum diesel or biodiesel to improve the stability of the blended fuel. Stabilization can be terminated, weakened, or oxidized by various families to inhibit oil exchange and improve its stability.
  • C 1742072A liters of a method for improving the storage stability of biodiesel includes a solution containing 15-60 by weight of a solution of biodiesel dissolved in biodiesel to stabilized biodiesel until a solution of biodiesel is used, 24 - Toluene to 0.005-2 by weight.
  • the purpose of the present invention is to overcome the above-mentioned existing wood oxygen consumption and the stability improvement of the biodiesel-containing blended fuel, and provide a diesel fuel composition with improved oxidation stability or qualitative properties of biodiesel and improved biodiesel oxidation stability. Sexual approach.
  • the present invention provides a diesel fuel composition
  • a diesel fuel composition comprising a base diesel fuel and an additive composition
  • the diesel fuel comprising a biodiesel additive composition comprising a and b a oxygen
  • b is or polykoto or a derivative.
  • the method for improving the oxidation stability of biodiesel includes, in the diesel containing biodiesel, adding, among them, the additive composition provided by the present invention.
  • the diesel fuel composition has good oxidation stability, and the a oxidizing effect of the a seven groups of b is better than that of the sheep.
  • b can be regarded as oxygen, which can greatly enhance the oxygen. Therefore, it is highly desirable to reduce the amount of the same oxidative stability requirement in the biodiesel composition, especially if it is particularly expensive or a toxic or corrosive. Particularly
  • the diesel fuel composition contains a, b and . Due to the same, the diesel provided by this. Hugh way
  • the diesel fuel composition provided in this product can be added in a larger scale, for example, the diesel content can be 50-100 ppm.
  • the weight ratio of b a can be 0.01-100 1 0.0250:1 step 0.05-10:1 step 0.25:1
  • a Oxygen can be at least one of a substituted, substituted, substituted, substituted.
  • the substituted waist includes, but is not limited to, the following or polyphenyl-a-phenyl-- (anti-aging)
  • substituted phenyl group is phenyl-a-, phenyl-, or oxyphenyl a or more. Especially phenyl-.
  • the replacement pocket is not limited to the following or more
  • a mixture of bases which may be, octyl, or in the form of a solid Pe wa company name Pe oe oxA- Sh solid aoa poychem company name Wyox ADP ADP-X, solid Va deb company name Age e SaUe Age e Sa e S Age e epa Age e Oe oya Company name Poy e A oxda 445, and oxygen in T53.
  • Substituted oxylation and mixtures thereof especially carbon atoms in the 4-10 same group and mixtures such as 44-octyl, 44-octyl, 44-, 44-, octyl (octyl and octyl) Of the mixture), octyl, or oxygen in T534 or more.
  • the substituted oxygen may be a hydrogen atom in (-) or a hydrogen atom in the poly, or, or, an oxy group or a substituted one may be a hydrogen atom substituted or a substitution.
  • the hydrogen atom may be the same as or different from each other, and the substitution may be the same or different. That is to say, the substituted oxygen can be substituted by sheep, substituted by sheep, replaced by sheep, replaced by sheep.
  • Substituted oxygen of Hugh includes but is not limited to one or more of the following
  • the substituted oxygen therein includes but is not limited to
  • Phenyl - anti-old (anti-aging AP, anti-aging A)
  • the multi-lumbar force has the one shown in (A)
  • R each having a carbon atom of 1 to 30 carbon atoms or having a carbon atom of carbon, , , or an oxy group, a nitro group, an oxy group, an amino group, or an amino group; a carbon atom of the oxy, nitro, oxy, or amino group of 130, a carbon atom of 1 to 30, a molecule derived from carbon, , , , , oxy, nitro, oxy, or amino Replace, or.
  • the combined oxygen or oxygen or oxygen is in the same range of 1-30.
  • More waists include - -13-, - 13-, - cattle -13-. Only 2 (CH2)x8 ten 6
  • R 2 R13 R14 R 5 R16 each standing, carbon atom 1-30, X8 0 to 10 integer y3 y4 0 to 5 integer
  • R13 hydrogen R2 or R13 can be R14 or R15.
  • x2 is an integer of 24, an integer of y 1-8, an example of R or a carbon atom of 1 to 30, diethylene, ethylene, ethylene, ethylene, Ethylene, ethylene, propylene, propylene, propylene, propylene, propylene, propylene, propylene, propylene, -(3-)- or or R, , , , , octyl, , ten, twelve, ten, sixteen, ten, twenty, twenty twenty, two, twenty, two, two, twelve, ten, ten, ten, ten, ten, twenty, nine, nine, ten, benzene A, phenyl or a lot of or
  • Examples of integers of the force, carbon atom 1-24 or ( ) X gene x3 0-5 include -2-amino) or -().
  • integers of x4 010 of the RR carbon atom 1-24 include -dimethyl-13-, -diethyl 13, -13, -dimethyl 14-butane, -diethyl-14-butane, -dimethyl 16 Or CN 3 A5 wherein x6 is an integer from 1 to 10.
  • Poly-2-aminoCN 2
  • Aliphatic groups can be either saturated or unsaturated, including , , , .
  • this is meant to mean a straight or a normally 2 to 30 carbon atom of 2 6 carbon atoms.
  • Examples can be, 1-, 1- -2-, -, - -2-, - -3-, 1-, 1- -2-, 1 -3-, 1- -4-, 3- - - , 1 - - - -2- , 1- 1- -3- , 2- -1- -3- , 1- , 1- 2 , 1- -3- , 1 4 , 1- 5 , 3 1 , 4- - 1-, 1- 1- 2, 4 1 2 , 1- -1- -3-, 2- -1- -3-, etc.
  • the " " may be either saturated or unsaturated or included.
  • diene, diene, diene, diene, etc. diene, diene, etc.
  • diene, diene, etc. more diene.
  • any of the functions or substitutions derived from any of the sheep's aromatic forests such as phenyl, substituted phenyloctyl, phenylethyl, oxyphenylnitrophenyl, oxycarbophenyl, etc., and The aromatic examples, , , , and so on.
  • this substitution includes a 3 8 unsaturated atom containing 3 8 unsaturation containing dyed atoms.
  • a gene having 1 to 30 carbon atoms which may be derived from carbon, -O-C, , oxy, nitro, oxy, or amino. This refers to atoms, atoms, atoms, atoms, etc., atoms, atoms, atoms, and more atoms.
  • the "oxy" group has a straight or 18 carbon atom of its 1 30 carbon atom.
  • This " has a straight or a 1 30 carbon atom with 1 18 carbon atoms. example , , ,
  • This " has a straight or 1 1 carbon atom of 1 18 carbon atoms. example , , , ,
  • the " " is formed by the removal of the oxygen atom from the upper “ “. 1 30 carbon atoms 1 24 carbon atoms.
  • the derivative is a carbon atom of 640, a carbon atom of 6 to 40, and a carbon atom of 6 to 40.
  • the step is a reverse of a carbon atom of 6-40 fatty acids, a carbon atom of 6-40, a carbon atom of 6-40, or a fatty acid.
  • the opposite means fatty acids, fats, The opposite of or in the fatty acid.
  • the upper side can be used as the b or the compound can be used as the b.
  • the main component of the mixture does not usually contain some unreacted raw materials and other anti-
  • This compound can be obtained, or it can be obtained by the inverse of each class.
  • the ratio shown by B or B shown by A is more than 1: (0.5-2). Inversely, or equal or slightly equal to the case shown in B, or B2, as shown by element A, with b: 1-2)
  • R carbon atoms are 6-40, and carbon atoms are 8-36. This "" replaces the aliphatic, and the substitutions.
  • Aliphatic groups can be either saturated or unsaturated or . That is, B may be a fatty acid, an aromatic, a substituted aromatic fatty acid, and may be a meta- or a multi-component binary.
  • It may be mixed or mixed with various vegetable oil fatty acids, soybean oil, peanut oil, rapeseed, medium and many, preferably at room temperature, linen,
  • fatty acid C6 ⁇ C40 fatty acid, , , , , , , , , , , , , , , , , , Or Acidic Hugh), , , , Linen, , , , , Soybean Oil, Peanut Oil, Rapeseed, Sesame Oil,
  • the R carbon atom 15 , , or B2 is a B acid B compound and a mixture thereof, especially B2 biodiesel.
  • Step b contains the lower compound or C C C C C C C C C C C C C C C C C C C ,
  • the multi-derivative can be the reciprocal of the upper poly-C-C6. More reciprocal than the wood already in the field, its main replacement Or the ratio of the substitution of the excess includes the ratio of C-C6 which can be more than 1: 0.1-10), 1: 0.25, and 1: 0.3-3, instead of hexane, toluene, xylene, etc.
  • the temperature of the water splitting is 80-150C, and the opposite is no longer 30 to 10. Or in an aqueous solution of or in an aqueous solution of C-C6, , , , , , or . It can be in the form of a solution or more.
  • the derivative may be a carbon atom containing 6-34 molecules.
  • the conversion of (C) is more than 1: (0.5-2), and the substitution of C6-C30 contained in the molecule is binary or medium or .
  • the reverse refers to the reverse of fatty acids, fats, fatty acids or more decomposition. On the reverse, it can be used directly as the b.
  • the main component of the mixture usually contains nearly some unreacted raw materials and other counter-
  • the binary substituted by C6-C30 in the present invention may be a C6-C30 substituted unsubstituted, di- or di- or C-C30-substituted C6-C30 substituted C(C) , or , in the dimethyl or C6-C30 substituted, may be substituted with C6-C30 or binary or
  • Part of the fat is the intermediate in the binary or medium carbon, and the carbon is not reversed.
  • C6-C30 substituted succinic acid B3 is shown by C6-C30 substituted B4
  • Substitutions include aliphatic, and substituted.
  • Aliphatic groups can be either saturated or unsaturated.
  • Typical can be used as a C6-C30 substitution.
  • the binary can be Ding, Ding, Twelve Ding, Thirteen Ding, Ten Ding, Fifteen Ding, Sixteen Ding, Ding Or D, D, D, D, D, D, D, D, D, E
  • Typical C6-C30 substitutions that can be used as the localization can be , , twelve, thirteen, ten, fifteen, ten,
  • C6-C30 The methods substituted by C6-C30 are either unpolymerized in the wood phase of the art, or substituted by chlorination. Hugh can be found in 33 673 S3676089 and S 72892.
  • Substituted ( ) can be obtained, or can be used
  • the various methods have been prepared, for example, by phase-substituted water or water vapor hydrolysis. Hydrolyzed Hugh and Operation has been used in this field of wood. Field wood, no longer here. And the anti-object Mobbi has. The East said that the reverse temperature is about 10 C.) The anti-heating of the main body of the waist is high (15 C or so) and the waist is the main force. And / or more
  • the additive provided contains c, c which may be reversed or combined with gold or gold or gold or gold.
  • the weight ratio can be 1:0-1, a. Weight ratio 1:0.01-1, step
  • the derivative may be fat or formed in the fat Mannich or .
  • (T) can be water - - water and / or - diethyl.
  • Sour It may be - in di-dihydrate-12-, -dihydrate-12-, -dihydrate-12-, -dihydrate-propylene. Yuan Examples of the derivatives thereof and the derivatives thereof may be, or, ( ), horses, and the like and derivatives thereof.
  • fat formed fat Mannich reverse (except for the trade name T551), and the combination of multiple and its fat, or fat (ie, polyacids, derivatives) or .
  • the additives provided in this section may contain other additions, streams, hexagrams, anti-corruption, etc.
  • Each of the sheep of the additive composition provided herein can be uniformly mixed with each of the constituent compositions. It can be mixed directly or in the presence of a mixture.
  • F 14-dioxane
  • hydrogen F
  • dimethyl D O in or .
  • It may also be ⁇ , especially toluene, xylene, oil and mixtures thereof, which may be biodiesel and fat.
  • the diesel fuel provided by this can add this
  • diesel can be biodiesel.
  • Biodiesel refers to the exchange of low-carbon fatty acids, ie, fats and oils, which are produced by low-carbon C C5 fat exchange.
  • the exchange counter can be any method of biodiesel exchange with or without the low-carbon exchange of fats and oils, such as catalytic, catalytic, catalytic, and the like. Hugh can refer to C 1473907A DE3444893 C 1472280A C 142993C C 115g1C C 594504A et al.
  • oils and fats are generally the same in the art, and the main component is fatty acid glycerin.
  • Normal temperature rest or normal resting fat .
  • Vegetable oil can be herbal oil or woody vegetable oil peanut oil, corn oil, rapeseed, soybean oil, safflower, flax, coconut, almond oil, walnut, sesame oil, sesame oil, (Ta O ), sunflower, van, , berberine, soil plant mallow, and other plants. Oils can be, ducks, sheep, butter, and so on.
  • diesel may also contain other diesel oil, other diesel oil, diesel fuel, synthetic diesel, hydrogenated biodiesel, oxygenated diesel compounds or biodiesel.
  • petroleum diesel refers to various processes such as crude oil (petroleum) kerosene, catalytic, catalytic reforming, hydrogenification, and other devices.
  • - Synthetic diesel is mainly GT diesel (Ga To q d) or CT diesel produced by natural or raw material - (FT) synthesis method (Coa To q d can be BT diesel omas To q produced by plant synthesis method).
  • - Synthetic diesel is essentially free of sulfur and is a very fuel. But biodiesel is greatly improved, but the combined oxidation stability is likely to cross. Therefore, biodiesel fuels also require oxygen.
  • Biodiesel is also the second generation of biodiesel, which is derived from the hydrogen and chemical reaction of vegetable oils and fats.
  • the main components of the reversed biodiesel are 16 high and low in content.
  • the use of diesel fuel or combination can greatly reduce diesel emissions.
  • Oxygenated diesel combination refers to a mixture of oxygenates or oxygenates that can meet the regulatory requirements for each diesel fuel.
  • CC fat, -C fat, ethanol, propanol, , , , , , Ten carbon, Laurel and their gods get off.
  • the diesel fuel composition of the diesel biodiesel in the present invention can be directly mixed with the addition of biodiesel and other diesel fuels, or it can be obtained by first adding biodiesel and then combining other diesel fuels. It is also possible to mix the various components of the direct diesel fuel of each of the added materials, or to mix the added materials in advance to obtain a mixture, and to mix the components of the diesel oil or the diesel fuel.
  • the order of mixing of each of the added and biodiesel and other diesel fuels is not particularly limited and may be mixed in each order.
  • the mixed mixture can be disadvantageous in the absence of the composition and the diesel fuel composition in each section, and can be mixed at a temperature.
  • the method for improving the oxidation stability of biodiesel provided by the present invention is added to the diesel fuel containing biodiesel.
  • Each of the 1-6 is in the Ming Dynasty.
  • the ratio is about 1:0.5:0.5).
  • the heat is turned to 12 and the nitrogen is reversed.
  • Nuclear counteraction Direct force b
  • Each 11-15 is used to describe the synthesis of many chemicals.
  • Each 11-15 is used to describe the synthesis of many chemicals.
  • the difference is 28.49 ethylene (0.5 mol) instead of 5679 ethylene (0.3mo), and 108.29 Chengli 159-185 dilution instead of 136.59 Chengli 159-185C dilution. 50 parts by weight of the anti-mixture of the di-diene dip-grain master is obtained, and the anti-mixture is directly used as the force b.
  • compositions of the present invention includes a b-ary fatty acid or a poly-derivative multi-derivative.
  • Ratio bg each 2 Ratio b each 3
  • 18-24 illustrates the various compounds of the present invention, wherein b is a multi-derivative derivative.
  • compositions of the present composition wherein b is a multi-derivative multi-derivative.
  • biodiesel and rapeseed biodiesel used in the following tests are biodiesel and acid oil biodiesel used for biodiesel supplied by Sinopec Shijia Chemical Chemical Co., Ltd.. PetroChina is provided by Fujian Youshang New Energy Co., Ltd. B diesel.
  • Oxidation stability of biodiesel composition of biodiesel-powered diesel fuel 4112:2003 Method (acma) Determination of early non-biodiesel oxidation stability of C using Swiss company's 743 oil oxidative stability determination, wherein The better the oxidizability of the diesel fuel composition, the more the oxidative property of the diesel fuel composition is indicated. It was tested in 58. 5
  • the ratio in the ratio b6 720 29 5 can be seen that a is oxygen, biodiesel oxidation stability is improved, b sheep use no oxygen or the effect is poor. Sheep use a or group b to force the ratio.
  • the biodiesel composition provided herein has a better oxygen stability.
  • a b is cooperative, the oxidation stability of the biodiesel composition is much better than that of the sheep using a and b, so that the a and b can have the same effect.
  • the group, the effect step is enhanced.
  • the resulting biodiesel composition has an enhanced oxygen stability step.
  • a is the oxygen oxidation resistance of oxygen biodiesel has improved, b sheep use no oxygen or the effect is poor, sheep use a or group b to work hard Listed.
  • the biodiesel composition has better oxidation stability and indicates that the oxidation stability of the biodiesel composition is much better than that of the sheep using a and b, so that a and b appear together. The same effect. Group of . The effect step is enhanced.
  • the oxidation stability step of the resulting biodiesel composition is enhanced.
  • a is an oxygen biodiesel oxidation stability has a certain improvement b sheep use in the addition of small biodiesel oxygen does not have the effect or the effect of the biodiesel composition provided Better oxidation stability.
  • the binding effect of a b, the oxidation stability of the biodiesel composition is much better than that of the sheep using a and b, so that a and b have the same effect.
  • biodiesel composition has an enhanced oxygen stability step. 8
  • the number in bg 600 3.7 8 can be seen that a is oxygen, biodiesel oxidation stability is improved, b sheep use no oxygen or oxygen is relatively poor.
  • the biodiesel composition provided has better oxidation. Stability.
  • the oxidation stability of the biodiesel composition is much better than that of the sheep using a and b, so that a and b can have the same effect. Group of . , the fruit step is enhanced.
  • biodiesel used for biodiesel.
  • the S/175 method measures the stability of the various combinations of diesel fuel compositions (sheep mg/m) and their stability. The greater the value, the more stable it is. The smaller the stability, the better the stability. The test results are in 10 13 . 1
  • Petroleum diesel 50 0.5 petroleum diesel 7.2 8.8 biodiesel 14 200 50 . 5
  • Biodiesel fuel oil with a weight of 60 mg/kg 20 is blended according to a ratio of 15 85 to calculate the blending fuel content.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Lubricants (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L'invention porte sur une composition de diesel contenant un diesel de base et une composition d'additif. Le diesel de base contient du biodiesel. La composition d'additif contient les composants a et b. Le composant a est un antioxydant amine aromatique. Le composant b est une ou plusieurs polyamines ou des dérivés de celles-ci. La composition de diesel a une meilleure stabilité à l'oxydation. L'invention porte également sur un procédé pour l'amélioration de la stabilité d'un biodiesel à l'oxydation.
PCT/CN2010/000950 2009-06-26 2010-06-25 Composition de diesel et procédé pour l'amélioration de la stabilité d'un biodiesel à l'oxydation WO2010148652A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US13/380,334 US20120124896A1 (en) 2009-06-26 2010-06-25 Diesel Composition and Method of Increasing Biodiesel Oxidation Stability
EP10791159.6A EP2447344B1 (fr) 2009-06-26 2010-06-25 Composition de diesel et procédé pour l'amélioration de la stabilité d'un biodiesel à l'oxydation
ES10791159T ES2749879T3 (es) 2009-06-26 2010-06-25 Composición de diésel y proceso para mejorar la estabilidad a la oxidación de biodiésel
BRPI1012681-3A BRPI1012681B1 (pt) 2009-06-26 2010-06-25 Composição de diesel e método de aumentar a estabilidade de oxidação de biodiesel

Applications Claiming Priority (8)

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CN 200910087970 CN101928614B (zh) 2009-06-26 2009-06-26 一种柴油组合物和提高生物柴油氧化安定性的方法
CN200910087970.9 2009-06-26
CN 200910089959 CN101987980B (zh) 2009-07-30 2009-07-30 添加剂组合物和柴油组合物及提高生物柴油氧化安定性的方法
CN200910089959.6 2009-07-30
CN200910090512.0 2009-08-19
CN200910090512.0A CN101993744B (zh) 2009-08-19 2009-08-19 生物柴油组合物及提高生物柴油氧化安定性的方法
CN200910090511.6 2009-08-19
CN 200910090511 CN101993743B (zh) 2009-08-19 2009-08-19 添加剂组合物和柴油组合物及提高生物柴油氧化安定性的方法

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US10517849B2 (en) 2016-10-26 2019-12-31 Constellation Pharmaceuticals, Inc. LSD1 inhibitors and medical uses thereof
US10526287B2 (en) 2015-04-23 2020-01-07 Constellation Pharmaceuticals, Inc. LSD1 inhibitors and uses thereof
CN115920969A (zh) * 2022-12-05 2023-04-07 中国人民解放军军事科学院系统工程研究院 一种Salen金属配体固载催化剂、其制备方法和应用

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US20150368576A1 (en) * 2014-06-18 2015-12-24 Shell Oil Company Fischer tropsch derived diesel fuel formulation
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US10526287B2 (en) 2015-04-23 2020-01-07 Constellation Pharmaceuticals, Inc. LSD1 inhibitors and uses thereof
US10517849B2 (en) 2016-10-26 2019-12-31 Constellation Pharmaceuticals, Inc. LSD1 inhibitors and medical uses thereof
US11013718B2 (en) 2016-10-26 2021-05-25 Constellation Pharmaceuticals, Inc. LSD1 inhibitors and medical uses thereof
US11547695B2 (en) 2016-10-26 2023-01-10 Constellation Pharmaceuticals, Inc. LSD1 inhibitors and medical uses thereof
CN115920969A (zh) * 2022-12-05 2023-04-07 中国人民解放军军事科学院系统工程研究院 一种Salen金属配体固载催化剂、其制备方法和应用
CN115920969B (zh) * 2022-12-05 2023-12-29 中国人民解放军军事科学院系统工程研究院 一种Salen金属配体固载催化剂、其制备方法和应用

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EP2447344A4 (fr) 2013-10-30
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US20120124896A1 (en) 2012-05-24
BRPI1012681A2 (pt) 2016-03-29
ES2749879T3 (es) 2020-03-24
BRPI1012681B1 (pt) 2019-03-26

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