WO2010143317A1 - Composition antibactérienne, fibre de polyester antibactérienne et procédé pour la fabrication d'une fibre de polyester antibactérienne - Google Patents

Composition antibactérienne, fibre de polyester antibactérienne et procédé pour la fabrication d'une fibre de polyester antibactérienne Download PDF

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Publication number
WO2010143317A1
WO2010143317A1 PCT/JP2009/064460 JP2009064460W WO2010143317A1 WO 2010143317 A1 WO2010143317 A1 WO 2010143317A1 JP 2009064460 W JP2009064460 W JP 2009064460W WO 2010143317 A1 WO2010143317 A1 WO 2010143317A1
Authority
WO
WIPO (PCT)
Prior art keywords
antibacterial
parts
glycol
antibacterial composition
composition
Prior art date
Application number
PCT/JP2009/064460
Other languages
English (en)
Japanese (ja)
Inventor
前田　浩司
Original Assignee
互応化学工業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 互応化学工業株式会社 filed Critical 互応化学工業株式会社
Priority to JP2011518198A priority Critical patent/JP5498492B2/ja
Publication of WO2010143317A1 publication Critical patent/WO2010143317A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/015—Biocides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5271—Polyesters; Polycarbonates; Alkyd resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

Definitions

  • antibacterial agents silver antibacterial agents
  • amine-based antibacterial agents have been widely used for fibers used in clothing and the like, but silver-based antibacterial agents have been used in consideration of health.
  • a method of performing antibacterial treatment on a substrate such as a fiber using a silver antibacterial agent a method of attaching or penetrating an aqueous dispersion obtained by dispersing a silver antibacterial agent in water, etc. Can be considered.
  • the antibacterial treatment using such an aqueous dispersion is excellent in occupational safety and environmental conservation.
  • the polyester resin can be obtained by a known polyester production method.
  • a direct esterification reaction using a carboxylic acid and a glycol or an ester exchange reaction between an ester-forming derivative of a carboxylic acid and a glycol may be used as a first-stage reaction, and the reaction product may be produced by a second-stage reaction. it can.
  • the transesterification reaction between a dicarboxylic acid diester and a glycol which is the most common method, is used as a first-stage reaction, and a production method consisting of a second-stage reaction in which this reaction product is polycondensed is used.
  • a production method consisting of a second-stage reaction in which this reaction product is polycondensed is used.
  • dicarboxylic acid diester and glycol are added to the reaction vessel, and the temperature is gradually raised to 150 to 250 ° C. under an atmospheric pressure in an inert gas atmosphere such as nitrogen gas.
  • the polyester resin thus obtained exhibits good water dispersibility by forming a segment derived from polyalkylene glycol in the molecular chain.
  • the antibacterial property can be imparted to the base material by subjecting the base material to antibacterial treatment using this antibacterial composition.
  • antibacterial treatment is performed by preparing an aqueous dispersion containing the antibacterial composition and applying the aqueous dispersion to various substrates. Is possible. For this reason, it is excellent in the occupational safety and environmental conservation at the time of performing the antibacterial treatment of the substrate.
  • the antibacterial composition contains a silver-based antibacterial agent, yellowing of the substrate to be treated is less likely to occur, and even if the antibacterial composition is exposed to high temperatures and pressures, Yellowing of the material or the like can be suppressed.
  • the ratio of the polyalkylene glycol used to the polyester resin in the antibacterial composition and the ratio of the content of the silver antibacterial agent to the antibacterial composition are as shown in Table 1.
  • the ratio of the polyalkylene glycol used to the polyester resin in the antibacterial composition and the ratio of the content of the silver antibacterial agent to the antibacterial composition are as shown in Table 2.
  • the ratio of the polyalkylene glycol used to the polyester resin in the antibacterial composition and the ratio of the content of the silver antibacterial agent to the antibacterial composition are as shown in Table 2.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

L'invention porte sur une composition antibactérienne qui présente une bonne aptitude à la dispersion dans l'eau et qui permet de réduire considérablement l'apparition du jaunissement d'une matière de base, ou autre, qui est soumise à un traitement antibactérien. La composition antibactérienne comporte une résine polyester et un agent antibactérien contenant de l'argent, la résine polyester étant obtenue par la réaction entre des composants polymérisables comportant un composant acide téréphtalique et/ou un composant acide isophtalique comme composant acide carboxylique et au moins un polyalkylèneglycol comme composant glycol. Dans la composition antibactérienne, la résine polyester possède un segment issu du polyalkylèneglycol. Par conséquent, la composition antibactérienne présente une excellente aptitude à la dispersion dans l'eau et une dispersion aqueuse contenant la composition antibactérienne peut être facilement préparée. En outre, lorsqu'un traitement antibactérien d'une matière de base, ou autre, est effectué à l'aide de la composition antibactérienne, le jaunissement de la matière de base, ou autre, peut être considérablement réduit.
PCT/JP2009/064460 2009-06-12 2009-08-18 Composition antibactérienne, fibre de polyester antibactérienne et procédé pour la fabrication d'une fibre de polyester antibactérienne WO2010143317A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2011518198A JP5498492B2 (ja) 2009-06-12 2009-08-18 抗菌性組成物、抗菌性ポリエステル系繊維、及び抗菌性ポリエステル系繊維の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2009140758 2009-06-12
JP2009-140758 2009-06-12

Publications (1)

Publication Number Publication Date
WO2010143317A1 true WO2010143317A1 (fr) 2010-12-16

Family

ID=43308581

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2009/064460 WO2010143317A1 (fr) 2009-06-12 2009-08-18 Composition antibactérienne, fibre de polyester antibactérienne et procédé pour la fabrication d'une fibre de polyester antibactérienne

Country Status (2)

Country Link
JP (1) JP5498492B2 (fr)
WO (1) WO2010143317A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014503032A (ja) * 2011-01-17 2014-02-06 イーストマン ケミカル カンパニー 芳香族−脂肪族ポリエステルと抗菌性添加剤とのブレンドにおけるヘイズの低減
JP2016108299A (ja) * 2014-12-10 2016-06-20 竹本油脂株式会社 農薬活性成分放出制御剤及び徐放性農薬組成物
WO2019176654A1 (fr) * 2018-03-12 2019-09-19 東レ株式会社 Structure en fibres de polyester
JP2023007326A (ja) * 2021-06-30 2023-01-18 南亞塑膠工業股▲分▼有限公司 抗菌・防カビのポリエステル材料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5039756B1 (fr) * 1966-12-28 1975-12-19
JPS62195037A (ja) * 1986-02-20 1987-08-27 Kanebo Ltd 抗菌性を有するポリエステル系成形体
JPH06279657A (ja) * 1993-03-24 1994-10-04 Teijin Ltd ポリエステル組成物および繊維
JPH07238421A (ja) * 1994-02-21 1995-09-12 Teijin Ltd 抗菌性ポリエステル繊維の製造方法
WO2001032975A1 (fr) * 1999-11-04 2001-05-10 Teijin Limited Fibres en polyester a fonctionnalite conferee, structure etablie a partir de ces fibres et procede de fabrication correspondant
JP2007031857A (ja) * 2005-07-25 2007-02-08 Taiko:Kk 繊維製品の抗菌処理方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5546856B2 (fr) * 1973-08-15 1980-11-26

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5039756B1 (fr) * 1966-12-28 1975-12-19
JPS62195037A (ja) * 1986-02-20 1987-08-27 Kanebo Ltd 抗菌性を有するポリエステル系成形体
JPH06279657A (ja) * 1993-03-24 1994-10-04 Teijin Ltd ポリエステル組成物および繊維
JPH07238421A (ja) * 1994-02-21 1995-09-12 Teijin Ltd 抗菌性ポリエステル繊維の製造方法
WO2001032975A1 (fr) * 1999-11-04 2001-05-10 Teijin Limited Fibres en polyester a fonctionnalite conferee, structure etablie a partir de ces fibres et procede de fabrication correspondant
JP2007031857A (ja) * 2005-07-25 2007-02-08 Taiko:Kk 繊維製品の抗菌処理方法

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014503032A (ja) * 2011-01-17 2014-02-06 イーストマン ケミカル カンパニー 芳香族−脂肪族ポリエステルと抗菌性添加剤とのブレンドにおけるヘイズの低減
JP2016108299A (ja) * 2014-12-10 2016-06-20 竹本油脂株式会社 農薬活性成分放出制御剤及び徐放性農薬組成物
WO2019176654A1 (fr) * 2018-03-12 2019-09-19 東レ株式会社 Structure en fibres de polyester
JPWO2019176654A1 (ja) * 2018-03-12 2021-01-14 東レ株式会社 ポリエステル系繊維構造物
JP2023007326A (ja) * 2021-06-30 2023-01-18 南亞塑膠工業股▲分▼有限公司 抗菌・防カビのポリエステル材料
JP7414788B2 (ja) 2021-06-30 2024-01-16 南亞塑膠工業股▲分▼有限公司 抗菌・防カビのポリエステル材料
US11968980B2 (en) 2021-06-30 2024-04-30 Nan Ya Plastics Corporation Antibacterial and antifungal polyester material

Also Published As

Publication number Publication date
JP5498492B2 (ja) 2014-05-21
JPWO2010143317A1 (ja) 2012-11-22

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