WO2010075410A8 - Générateur d'hydrogène avec catalyseur d'aérogel - Google Patents

Générateur d'hydrogène avec catalyseur d'aérogel Download PDF

Info

Publication number
WO2010075410A8
WO2010075410A8 PCT/US2009/069239 US2009069239W WO2010075410A8 WO 2010075410 A8 WO2010075410 A8 WO 2010075410A8 US 2009069239 W US2009069239 W US 2009069239W WO 2010075410 A8 WO2010075410 A8 WO 2010075410A8
Authority
WO
WIPO (PCT)
Prior art keywords
metal borohydride
component
aerogel catalyst
reaction chamber
fuel component
Prior art date
Application number
PCT/US2009/069239
Other languages
English (en)
Other versions
WO2010075410A1 (fr
Inventor
Michael Curello
Constance Stepan
Original Assignee
Societe Bic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to KR1020167001101A priority Critical patent/KR101852135B1/ko
Priority to RU2011124794/07A priority patent/RU2011124794A/ru
Priority to MX2011006742A priority patent/MX2011006742A/es
Priority to BRPI0923395A priority patent/BRPI0923395A2/pt
Priority to CN200980152040.5A priority patent/CN102265443B/zh
Priority to US13/132,827 priority patent/US8821834B2/en
Application filed by Societe Bic filed Critical Societe Bic
Priority to JP2011543645A priority patent/JP5781940B2/ja
Priority to EP09835773.4A priority patent/EP2382682A4/fr
Priority to CA2746895A priority patent/CA2746895C/fr
Publication of WO2010075410A1 publication Critical patent/WO2010075410A1/fr
Priority to ZA2011/04431A priority patent/ZA201104431B/en
Publication of WO2010075410A8 publication Critical patent/WO2010075410A8/fr

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Catalysts (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

Abstract

La présente invention concerne un appareil de production de gaz hydrogène (10) comprenant les éléments suivants : (1) un réservoir (100) comportant un composant aqueux (110), (2) un compartiment de combustible (200) comprenant un composant combustible de borohydrure de métal solide (210), et (3) une chambre de réaction (300) comprenant un catalyseur aérogel (310). Un premier passage de fluide introduit le composant aqueux dans le compartiment de combustible où le composant de combustible de borohydrure de métal solide est dissous dans un composant de combustible de borohydrure de métal liquide (210'). Un second passage de fluide introduit le composant de combustible de borohydrure de métal liquide dans la chambre de réaction pour produire un gaz hydrogène au moyen d'une réaction d'oxydation hydrure-eau qui est accélérée par le catalyseur aérogel. La température et/ou la pression de la chambre de réaction sont déterminées pour maintenir l'eau dans le sous-produit de borate sensiblement dans la phase liquide, afin de minimiser la précipitation du sous-produit de borate.
PCT/US2009/069239 2008-12-23 2009-12-22 Générateur d'hydrogène avec catalyseur d'aérogel WO2010075410A1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
RU2011124794/07A RU2011124794A (ru) 2008-12-23 2009-12-22 Генератор водорода с аэрогелевым катализатором
MX2011006742A MX2011006742A (es) 2008-12-23 2009-12-22 Generador de hidrogeno con catalizador en aerogel.
BRPI0923395A BRPI0923395A2 (pt) 2008-12-23 2009-12-22 Método para controlar uma reação entre um combustível aquoso de hidreto metálico e um catalisador para produzir hidrogênio e gerador de gás
CN200980152040.5A CN102265443B (zh) 2008-12-23 2009-12-22 利用气凝胶催化剂的氢气发生器
US13/132,827 US8821834B2 (en) 2008-12-23 2009-12-22 Hydrogen generator with aerogel catalyst
KR1020167001101A KR101852135B1 (ko) 2008-12-23 2009-12-22 에어로겔 촉매를 구비한 수소발생기
JP2011543645A JP5781940B2 (ja) 2008-12-23 2009-12-22 エアロゲル触媒を伴う水素発生装置
EP09835773.4A EP2382682A4 (fr) 2008-12-23 2009-12-22 Générateur d'hydrogène avec catalyseur d'aérogel
CA2746895A CA2746895C (fr) 2008-12-23 2009-12-22 Generateur d'hydrogene avec catalyseur d'aerogel
ZA2011/04431A ZA201104431B (en) 2008-12-23 2011-06-14 Hydrogen generator with aerogel catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14031308P 2008-12-23 2008-12-23
US61/140,313 2008-12-23

Publications (2)

Publication Number Publication Date
WO2010075410A1 WO2010075410A1 (fr) 2010-07-01
WO2010075410A8 true WO2010075410A8 (fr) 2011-06-16

Family

ID=42288122

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/069239 WO2010075410A1 (fr) 2008-12-23 2009-12-22 Générateur d'hydrogène avec catalyseur d'aérogel

Country Status (11)

Country Link
US (1) US8821834B2 (fr)
EP (1) EP2382682A4 (fr)
JP (1) JP5781940B2 (fr)
KR (2) KR101649386B1 (fr)
CN (1) CN102265443B (fr)
BR (1) BRPI0923395A2 (fr)
CA (1) CA2746895C (fr)
MX (1) MX2011006742A (fr)
RU (1) RU2011124794A (fr)
WO (1) WO2010075410A1 (fr)
ZA (1) ZA201104431B (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8636826B2 (en) 2009-11-03 2014-01-28 Societe Bic Hydrogen membrane separator
US8986404B2 (en) 2009-11-03 2015-03-24 Societe Bic Gas generator with starter mechanism and catalyst shield
CN103477488A (zh) 2011-02-11 2013-12-25 法商Bic公司 燃料电池系统
CN103062619B (zh) * 2012-12-21 2016-04-13 张建洲 一种机动车加氢站系统
US9577273B2 (en) 2013-03-15 2017-02-21 Intelligent Energy Limited Fluidic interface module for a fuel cell system
US10193169B2 (en) 2013-03-15 2019-01-29 Intelligent Energy Limited Fluidic interface module for a fuel cell system
US9680171B2 (en) 2013-03-15 2017-06-13 Intelligent Energy Limited Methods for operating a fuel cell system
WO2015050601A2 (fr) * 2013-07-01 2015-04-09 United Technologies Corporation Efficacité fonctionnelle apu améliorée
US9876240B2 (en) 2014-04-07 2018-01-23 Intelligent Energy Limited Multi-functional fuel cable
SE540539C2 (en) * 2016-01-05 2018-09-25 Myfc Ab Fuel cartridge
US10892505B1 (en) * 2016-08-26 2021-01-12 Hrl Laboratories, Llc Power management system utilizing metastable hydrogen carrier and method of operating the same
JP6869799B2 (ja) * 2017-04-28 2021-05-12 株式会社デイトナ 水素ガス生成装置 並びにこれを適用した内燃機関 並びにこの内燃機関を駆動源とする発電機
FR3077815B1 (fr) 2018-02-13 2021-01-08 Apollon Solar Dispositif portable de production d'hydrogene, et son utilisation
US20210155476A1 (en) 2018-04-17 2021-05-27 Electriq-Global Energy Solutions Ltd. Batch systems and methods for hydrogen gas extraction from a liquid hydrogen carrier
KR102120818B1 (ko) * 2018-07-26 2020-06-09 한국화학연구원 자동 압력조절 기체 발생 장치
CN114229794A (zh) * 2021-12-28 2022-03-25 东方电气集团东方锅炉股份有限公司 一种固定式氢化镁水解自动控制装置及方法
EP4299508A1 (fr) * 2022-06-28 2024-01-03 E.M.I GmbH Système d'approvisionnement en énergie
CN116161617A (zh) * 2023-02-21 2023-05-26 上海氢栖科技有限公司 一种制氢装置及氢能电源

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3133837A (en) 1959-12-31 1964-05-19 Electric Storage Battery Co Fuel cell system
US4072514A (en) 1971-04-20 1978-02-07 Suzuki Masahiro Magnesium composites and mixtures for hydrogen generation and method for manufacture thereof
US3787186A (en) 1972-02-02 1974-01-22 Us Navy Calcium hydride gas generator
GB1399041A (en) 1972-02-16 1975-06-25 Siemens Ag Process and apparatus for use in the heterogeneous decompo sition of liquids
DE2306896A1 (de) 1973-02-13 1974-08-29 Licentia Gmbh Fluessigkeitszersetzeranlage mit einem zersetzer, einem fluessigkeitstank und einem puffer- und kondensatgefaess
DE2521090C3 (de) 1975-05-12 1978-06-08 Siemens Ag, 1000 Berlin Und 8000 Muenchen Verfahren und Vorrichtung zur Erzeugung von Wasserstoff
US4054423A (en) 1975-07-21 1977-10-18 Blenman Orman L Variable pressure fuel generator and method
US4650660A (en) 1985-08-02 1987-03-17 The Boeing Company Method for feeding solids to a controlled environment
US5202195A (en) 1990-12-14 1993-04-13 International Fuel Cells Corporation Method of and arrangement for replenishing hydrogen consumed by a fuel cell device
US5244640A (en) 1991-05-13 1993-09-14 Crawford J Harvey Gas generator and pressure/reaction regulator for use therewith
JPH0694003B2 (ja) 1991-07-02 1994-11-24 株式会社コロイドリサーチ 触媒担持アルミナ系多孔質材の製造方法
DE19513292C1 (de) * 1995-04-07 1996-08-22 Siemens Ag Brennstoffzelle
US5648052A (en) 1995-05-30 1997-07-15 Martin Marietta Corporation Liquid monopropellant gas generator
IL134131A (en) * 1997-07-22 2005-08-31 Black Light Power Inc Inorganic hydrogen compounds, separation methods and fuel applications
JP3136336B2 (ja) 1997-09-05 2001-02-19 工業技術院長 メタンのｃｏ２改質方法及びこの方法に用いる高耐熱性アルミナエアロゲル担持金属触媒の製造方法
US6018091A (en) 1998-06-08 2000-01-25 Quantum Marketing Corporation Methods for thermally degrading unwanted substances using particular metal compositions
US6274093B1 (en) 1998-08-06 2001-08-14 Ball Aerospace & Technologies Corp. Self-regulating hydrogen generator
JP2001031401A (ja) 1999-07-21 2001-02-06 Kiriu Mach Mfg Co Ltd 水素ガスの製造方法
US6506360B1 (en) 1999-07-28 2003-01-14 Erling Reidar Andersen Method for producing hydrogen
US6534033B1 (en) * 2000-01-07 2003-03-18 Millennium Cell, Inc. System for hydrogen generation
CA2308514A1 (fr) * 2000-05-12 2001-11-12 Mcgill University Methode de production d'hydrogene pour des applications de pile a combustible et un systeme de production d'hydrogene
US6686079B2 (en) * 2000-05-17 2004-02-03 Schlumberger Technology Corporation Fuel cell for downhole power systems
US6582676B2 (en) 2000-08-14 2003-06-24 The University Of British Columbia Hydrogen generation from water split reaction
US6932847B2 (en) 2001-07-06 2005-08-23 Millennium Cell, Inc. Portable hydrogen generator
US7316718B2 (en) 2001-07-11 2008-01-08 Millennium Cell, Inc. Differential pressure-driven borohydride based generator
US7198761B2 (en) * 2001-12-10 2007-04-03 Daimlerchrysler Corporation Vehicle hydrogen fuel system
US6746496B1 (en) * 2002-01-15 2004-06-08 Sandia Corporation Compact solid source of hydrogen gas
JP2003221201A (ja) 2002-01-30 2003-08-05 Honda Motor Co Ltd 水素発生装置
JP2003221202A (ja) 2002-01-30 2003-08-05 Honda Motor Co Ltd 水素発生装置
US7282073B2 (en) * 2002-04-02 2007-10-16 Millennium Cell, Inc. Method and system for generating hydrogen by dispensing solid and liquid fuel components
JP2004161554A (ja) * 2002-11-14 2004-06-10 Honda Motor Co Ltd 水素を必要とする機器への水素供給方法
JP4276854B2 (ja) 2003-01-30 2009-06-10 ウチヤ・サーモスタット株式会社 水素発生材料、水素発生方法及び水素発生装置
US7105033B2 (en) * 2003-02-05 2006-09-12 Millennium Cell, Inc. Hydrogen gas generation system
JP2004358697A (ja) 2003-06-02 2004-12-24 Denso Corp 樹脂製品の製造方法
US7674540B2 (en) 2003-10-06 2010-03-09 Societe Bic Fuel cartridges for fuel cells and methods for making same
CN1291784C (zh) * 2004-04-22 2006-12-27 复旦大学 一种甲醇水蒸汽重整制氢用的铜基催化剂及其制备方法
US20060071088A1 (en) * 2004-10-05 2006-04-06 Paul Adams Fuel cartridge with an environmentally sensitive valve
WO2006081402A2 (fr) 2005-01-28 2006-08-03 Millennium Cell, Inc. Systemes et procedes de regulation de la generation d'hydrogene
US7666386B2 (en) 2005-02-08 2010-02-23 Lynntech Power Systems, Ltd. Solid chemical hydride dispenser for generating hydrogen gas
EP1867603A4 (fr) 2005-03-25 2008-10-08 Hitachi Maxell Materiau generateur d'hydrogene, procede de production dudit materiau et procede de production d'hydrogene
US7309479B2 (en) * 2005-06-29 2007-12-18 Samsung Engineering Co., Ltd. Cobalt oxide catalysts
US8215342B2 (en) 2005-09-30 2012-07-10 Societé BIC Hydrogen supplies and related methods
US20070271844A1 (en) 2006-04-12 2007-11-29 Mohring Richard M Hydrogen fuel cartridge and methods for hydrogen generation
WO2007120872A2 (fr) 2006-04-13 2007-10-25 Millennium Cell, Inc. Appareil et procédé de cycle de purge de pile à combustible
JP2007326742A (ja) 2006-06-08 2007-12-20 Hitachi Maxell Ltd 水素製造方法
US20090047185A1 (en) 2007-03-06 2009-02-19 Fennimore Keith A Hydrogen generation systems
CN100503425C (zh) 2007-03-20 2009-06-24 中山大学 催化剂分解硼氢化钠制氢的方法

Also Published As

Publication number Publication date
KR20160011235A (ko) 2016-01-29
EP2382682A1 (fr) 2011-11-02
CA2746895C (fr) 2015-11-24
RU2011124794A (ru) 2013-01-27
BRPI0923395A2 (pt) 2017-07-11
KR20110112302A (ko) 2011-10-12
JP5781940B2 (ja) 2015-09-24
KR101649386B1 (ko) 2016-08-19
US20110243836A1 (en) 2011-10-06
EP2382682A4 (fr) 2014-07-16
CN102265443A (zh) 2011-11-30
JP2012513372A (ja) 2012-06-14
WO2010075410A1 (fr) 2010-07-01
KR101852135B1 (ko) 2018-04-26
ZA201104431B (en) 2014-11-26
US8821834B2 (en) 2014-09-02
MX2011006742A (es) 2011-07-20
CA2746895A1 (fr) 2010-07-01
CN102265443B (zh) 2016-04-06

Similar Documents

Publication Publication Date Title
WO2010075410A8 (fr) Générateur d'hydrogène avec catalyseur d'aérogel
MX2009005574A (es) Aparato para generar gas hidrogeno, mediante el uso de una composicion para generar gas hidrogeno y composicion para generar gas hidrogeno.
WO2009008330A1 (fr) Appareil de génération de gaz
MY142306A (en) Vapour phase hydrogenation of glycerol
EA201790053A1 (ru) Способ, устройство и топливо для производства водорода
WO2007109036A3 (fr) Compositions de combustible pour des piles à combustible et générateurs de gaz utilisant celles-ci
MX336262B (es) Equipo de adicion de hidrogeno selectivo para fluido aplicable a organismo viviente.
TW200806392A (en) Microcartridge hydrogen generator
WO2006135896A3 (fr) Cartouches de pile a combustible generant de l'hydrogene
EA201100292A1 (ru) Способ сжижения углеродсодержащего материала с получением жидкого углеводорода
EP2109911A4 (fr) Générateurs de gaz hydrogène
WO2006081402A3 (fr) Systemes et procedes de regulation de la generation d'hydrogene
WO2005094335A3 (fr) Systeme de reformation de plasmatron multi-etape a large gamme dynamique
WO2009028143A1 (fr) Elément et procédé de production d'hydrogène gazeux
UA98661C2 (ru) Способ активации катализатора процесса фишера-тропша
IN2014CN04588A (fr)
WO2007078277A3 (fr) Centrale à système de réacteur de conversion du gaz à l'eau à membrane
MY179281A (en) A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio
MY158629A (en) An improved process for hydrogenating alkyl ester(s) in the presence of carbon monoxide
MX2012001205A (es) Procedimiento de reduccion basado en gas de reformacion con emision reducida de nox.
WO2008050350A3 (fr) Procédés et systèmes permettant de produire de l'énergie à partir du dioxyde de carbone
EP2826782A3 (fr) Procédés de production de organohalohydrosilanes
WO2014067664A3 (fr) Procédés et systèmes permettant de réduire des oxydes métalliques
TW200728196A (en) Production of hydrogen from non-cyclic organic substances having multiple alcohol functionality
TW200700310A (en) Production of hydrogen via a base-facilitated reaction of carbon monoxide

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200980152040.5

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09835773

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 13132827

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2746895

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2009835773

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 4395/CHENP/2011

Country of ref document: IN

Ref document number: MX/A/2011/006742

Country of ref document: MX

ENP Entry into the national phase

Ref document number: 2011543645

Country of ref document: JP

Kind code of ref document: A

Ref document number: 20117014397

Country of ref document: KR

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2011124794

Country of ref document: RU

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: PI0923395

Country of ref document: BR

ENP Entry into the national phase

Ref document number: PI0923395

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20110621