WO2010057887A1 - Fixateurs capillaires en gel transparent - Google Patents

Fixateurs capillaires en gel transparent Download PDF

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Publication number
WO2010057887A1
WO2010057887A1 PCT/EP2009/065325 EP2009065325W WO2010057887A1 WO 2010057887 A1 WO2010057887 A1 WO 2010057887A1 EP 2009065325 W EP2009065325 W EP 2009065325W WO 2010057887 A1 WO2010057887 A1 WO 2010057887A1
Authority
WO
WIPO (PCT)
Prior art keywords
gel composition
pvoh
weight
clear hair
hair gel
Prior art date
Application number
PCT/EP2009/065325
Other languages
English (en)
Inventor
Michael T. Philbin
Stephanie M. Murphy
Original Assignee
Akzo Nobel N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel N.V. filed Critical Akzo Nobel N.V.
Priority to BRPI0916120A priority Critical patent/BRPI0916120A2/pt
Priority to EP09756721.8A priority patent/EP2355792B1/fr
Priority to US13/128,423 priority patent/US8354098B2/en
Priority to JP2011543769A priority patent/JP2012509358A/ja
Priority to CN2009801458476A priority patent/CN102215814A/zh
Publication of WO2010057887A1 publication Critical patent/WO2010057887A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • One approach to increase the clarity in gelled products is to reduce the molecular weight of the polymeric material, as it is well know that lower molecular weight provides better clarity in both solution and gel.
  • the drawback to low molecular weight is that the polymers are less able to provide good physical properties once the liquid has dried. Properties such as curl strength (stiffness) and humidity resistance will suffer as the molecular weight of the polymer system is lowered.
  • the styling gel must leave the hair looking natural and resist flaking and peeling while being worn. Flaking would provide the appearance of dandruff on ones clothing and would be highly undesirable. Peeling would provide the hair with an unnatural and dull look.
  • the blends of PVOH and PVF of the current invention have been shown to provide excellent hold, as measured by curl compression and humidity resistance. Surprisingly these blends are very resistant to flaking and peeling and provide the hair a natural look.
  • the instant invention comprises a blend of one or more grades of polyvinyl alcohol, polyvinyl formamide and water.
  • the PVOH provides humidity resistance while the PVF provides a high level of clarity, resistance to flake and good curl compression.
  • Polyvinyl Alcohol is commercially available from a number of different sources, one being Celanese Chemicals (1601 West LBJ Freeway, Dallas TX) which offers a wide variety of grades.
  • Grades of PVOH differ by molecular weight and degree of hydrolysis. Molecular weight is expressed in terms of viscosity and comes in low (3- 5 mPas), medium (15-35 mPas), and high (above 50 mPas). In one embodiment of this invention the molecular weight is either low or medium. In another embodiment the molecular weight is low.
  • PVOH Polyvinyl alcohol is derived from polyvinyl acetate by alkaline hydrolysis of the ester groups, thus the term degree of hydrolysis. Therefore a PVOH with a degree of hydrolysis of 88% means there are still 12 % acetate groups on the polymer. The degree of hydrolysis also changes the properties of the PVOH.
  • PVOH is available in five different grades, low hydrolysis (78-85%), partially hydrolyzed (87-89%), intermediate hydrolyzed (90-97%), fully hydrolyzed (98-99%) and super hydrolyzed (greater than 99%).
  • low hydrolysis 78-85%
  • partially hydrolyzed 87-89%
  • intermediate hydrolyzed 90-97%
  • fully hydrolyzed 98-99%
  • super hydrolyzed greater than 99%.
  • the PVOH will be between partially hydrolyzed to fully hydrolyzed (87 to 99%). In another embodiment the PVOH will be partially hydrolyzed.
  • PVF Polyvinyl formamide
  • Process of making PVF is described in detail in US patent 5,977,274 to Leblanc et al. and is incorporated herein by reference.
  • Other publications that describe various aspects of the synthesis of PVF are US patent 6,541 ,573 and US
  • the molecular weight of the PVOH will be between 100,000 and 300,000 daltons as measured by Gel Permeation Chromatography.
  • clarity is any level of turbidity less than 20 at 3% polymer solids dissolved in water with 0.6% Carbopol as the thickener which has been neutralized with AMP (see experimental section below for details).
  • the test is conducted by passing a beam of light through a hair gel formulation and measuring the percentage of light loss.
  • NTU nephelometric turbidity units, a measure of turbidity
  • the hair gel is said to be clear.
  • the turbidity of a clear hair gel is less than 15 NTU.
  • Curl compression is a test to see the amount of stiffness in a swatch of hair 15 centimeters long. The hair is treated with the styling gel and then rolled into a tight curl. The force required to compress the curl 30% of its original diameter is measured. The value is normalized to a standard K90 sample and reported as a percent of standard. This standardization is to take into account variations in handling, hair quality and other variables. It is desirable for the curl compression to be as high as possible, but at least similar to the standard. In one embodiment of this invention, the curl compression is 0.8 (80%) or greater than the K90 sample. In a second embodiment the curl compression is 0.9 (90%) or greater that the K90 standard.
  • the high humidity curl retention relates to the humidity resistance of a swatch of hair 25 centimeters long.
  • the hair is treated with the styling gel, rolled and then suspended from one end.
  • the hair is subjected to a constant relative humidity of 90% (at a temperature of 21 0 C) for 24 hours and the length is measured and reported as a percent of the original swatch.
  • the curl retention would be as close to the initial as possible to provide the wearer a sag resistant hair style regardless of the weather conditions.
  • the high humidity curl retention is greater than 50%.
  • the high humidity curl retention is greater than 70%.
  • the high humidity curl retention is greater than 90%.
  • the flake test is a measurement of how much styling gel is fluffed off a sample of hair with a controlled combing and then expressed as a percentage of the control (K90). In one embodiment the flake will be less than the standard (100%). In a second embodiment of this invention the flake will be less than 80% of the standard.
  • the polymeric fixative is defined as a mixture of polyvinyl formamide and one or more grades of polyvinyl alcohol.
  • the ratio of PVOH to PVF in the polymer fixative will range from 20 to 80% PVOH and 20 to 80% PVF.
  • the ratio of PVOH to PVF in the polymer fixative will range from 40 to 70% PVOH and 30 to 60% PVF.
  • blends of more than one grade of PVOH can be used.
  • blends of low molecular weight PVOH with medium molecular weight or fully hydrolyzed PVOH with partially hydrolyzed PVOH offers the formulator options to obtain variations in properties as needed for individual hair styling gells.
  • this invention a blend of low molecular weight, partially hydrolyzed
  • PVOH with a medium molecular weight with a partially hydrolyzed PVOH is used at a ratio of from 1 to 1 to 4 to 1.
  • the hair fixative formulations of this invention comprise an amount of the hair fixative polymer which is effective to impart hair fixative properties to the gels. Where the level of polymer is too high, the gels and films formed therefrom exhibit unacceptable haziness. Where the level of polymer is too low, properties such as stiffness and humidity resistance are adversely affected.
  • the gels comprise from about 0.5 to about 15 weight percent of the polymer (based on the total weight of the gel). In another embodiment the fixative polymer is present from about 1 to 10 weight percent. In a third embodiment the fixative polymer is present at 2 to 7 weight percent of the gel.
  • the gels comprise from 0.05 to about 1 weight percent of the gelling agent. In one embodiment, the gelling agent is present at 0. 1 to 0.6 weight percent based on the total weight of the hair fixative gel.
  • gelling agents examples include synthetic polymers such as the acrylic- based Carbopol® series of thickeners available from B. F. Goodrich, Cleveland, Ohio and associative thickeners such as AculynTM, available from Rohm & Haas,
  • exemplary gelling agents include, cellulosic thickeners, such as derivatized hydroxyethyl cellulose and methyl cellulose, starch-based thickeners, such as acetylated starch, and naturally occurring gums, such as agar, algin, gum arabic, guar gum and xanthan gum.
  • the gelling agent will be Carbomer.
  • the gelling agent is Carbopol 940 or 908.
  • Carbomer is a polymer of acrylic acid which has some level of cross-linking. Depending on the grade, the level of cross-linking will vary. Additional monomer(s) can also be added during the polymerization to provide other properties and various grades.
  • the acid groups In order for the Carbomer to function as a gelling agent the acid groups must be neutralized with a base such as hydroxide or amine.
  • the neutralizing agents are chosen from the list of triethanolamine (TEA), 2-animo-2-methyl-1-propanol (AMP), ammonia and sodium hydroxide.
  • the neutralizing agent is TEA or AMP.
  • the neutralizing agent is AMP.
  • ingredients can be added to the clear hair gel formulation that will affect the look of the gel, but will not have any significant impact on the properties defined above.
  • the ingredients are, but not limited to, colorants, fragrances, fillers, pigments, conditioners and other actives.
  • compatibility of these other ingredients with the styling polymers and gelling agent will ultimately affect the clarity of the final formulation, therefore care must be taken to insure a clear product by careful choice of ingredients.
  • Celvol 523 87-89% hydrolyzed, viscosity at 4% solids, 20 0 C is 23.0-27.0 cPs Celvol 325: 98-99% hydrolyzed, viscosity at 4% solids, 20 0 C is 28.0-32.0 cPs Celvol 203: 87-89% hydrolyzed, viscosity at 4% solids, 20 0 C is 3.5-4.5 cPs Carbomer from Lubrizol (formerly Noveon) Carbopol 980: crosslinked polyacrylate
  • Example 1 High Viscosity Polyvinyl Alcohol Cook (Celvol 325 or Celvol 523, Celanese)
  • a one liter 3-neck round bottom flask was equipped with a condenser, temperature probe, heating mantle, and overhead stirrer.
  • Deionized water 450.0 grams was added to the flask and the stir rate was set at 350 rpm.
  • Polyvinyl alcohol (50.0 grams) was added slowly to the flask to make a 10% solids solution. The polyvinyl alcohol was cooked out at 90 0 C for 30 minutes. The final solution was cooled to 40 0 C before being discharged from the flask.
  • Example 3 Gel Formulation (tertiary blend)
  • Part A - Polymer solution A 250 milliliter beaker was equipped with a paddle bladed overhead stirrer. Deionized water (32.2 grams) was added to the beaker and the stir rate was set at 350 rpm. Polyvinyl formamide (0.5 grams, 100% solids) was added to the beaker and allowed to stir until fully dissolved. Low viscosity polyvinyl alcohol (Celvol 203, 4.2 grams, 30% solids), medium viscosity polyvinyl alcohol (Celvol 523, 12.6 grams, 10% solids), DMDM Hydantoin (Glydant Plus Liquid, 0.5 grams) and 2-amino-2- methyl-1-propanol (AMP-95, 0.5 grams) were added to the beaker.
  • Deionized water 32.2 grams
  • Polyvinyl formamide 0.5 grams, 100% solids
  • Low viscosity polyvinyl alcohol (Celvol 203, 4.2 grams, 30% solids)
  • Part B - Carbomer solution Carbomer (Carbopol 980, 30.0 grams of 2% solution) and deionized water (20.0 grams) were added to a 100 milliliter beaker equipped with a magnetic stirrer. A stir plate was used to mix the solution at 400 rpm until homogeneous.
  • Tubidity of the hair gels was determined using a Hach (Loveland, CO) Model 2100N turbidimeter by placing a 3OmL vial containing the hair gel in the sample compartment of the turbidimeter. Note that the hair gel sample needs to be free of any air bubbles to get an accurate reading. Table 2 - Turbidity Measurements
  • results reported in table 2 above show the actual value obtained in column 2 and the expected value in column 3.
  • the expected is a weighted average from the samples in 1 through 4.
  • the synergy, or loss of turbidity, is shown in column 4. A positive number means the sample became less turbid or clearer than would have been expected from the weighted average.
  • the swatches are tested the next day using a Diastron MTT 160 miniature tensile tester with a Curl Compression jig available from the manufacturer of the instrument (Diastron Ltd. Andover, Hampshire, England). Each rolled hair swatch is placed in the curl compression jig and tested.
  • the Diastron MTT 160 miniature tensile tester compresses the rolled hair swatch 30% of it's diameter at a rate of 20mm/min.
  • the force, in gram force is the 30% curl compression for the sample being tested.
  • the 30% curl compression for the five 6 inch swatches is then recorded and an average is determined based on these five swatches.
  • a PVP K90 hair gel is run each time a series of hair gels is evaluated.
  • a PVP K90 normalized 30% curl compression value is determined by the following formula. PVP K90
  • Normalized Curl Compression average 30% curl compression for hair gel sample average 30% curl compression for PVP K90 hair gel sample
  • Procedure 1 Wet each swatch first with water, and comb through swatch 2-3 times with a fine tooth comb to remove tangles. Squeeze excess water from swatches by squeezing them between a thumb and forefinger.
  • Digital images of the hair were captured using an Optronics (Goleta, CA) Microfire digital camera interfaced with an Olympus (Center Valley, PA) SZX10 Stereomicroscope at a magnification of 1 with a 10x objective. Five digital images were taken per hair swatch.
  • the digital images were analyzed for flake using Microsuite Analytical Suite 2.6 (Olympus Soft Imaging Solutions GmbH, Munster, Germany). Images were first converted to gray scale, then the grayscale range was adjusted so that all the flake particles were captured. The software then calculated the amount flake (by the grayscale range selected) relative to the area of the entire image. The amount of flake for each hair gel sample is the average 10 images (5 images on 2 hair swatches)
  • a PVP K90 hair gel is run each time a series of hair gels is evaluated.
  • a normalized PVP/K90 flake value is determined by the following formula.
  • PVP K90 Normalized Flake average %flake for hair gel sample average % flake for PVP K90 hair gel sample
  • the results in table 4 above shown the actual measured values obtained for each sample.
  • the expected value in column 3 represents a weighted average from each of the ingredients.
  • the synergy value represents the decrease in flake when PVOH and PVF are blended together. The lower the flake value the more desirable the formulation.
  • Procedure 1 Wet hair swatch and comb through 2-3 times to remove snarls.
  • the high humidity curl retention is calculated by the following formula:
  • L length of hair fully extended
  • L 0 initial curl length
  • L t curl length at a given time t.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
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Abstract

Cette invention concerne l'utilisation d'un mélange simple de formamide polyvinyle et d'un ou plusieurs alcools polyvinyliques en tant que système de polymère fixateur dans une composition capillaire en gel transparent. L'interaction du système de polymère et de l'agent de gélification fournit une clarté meilleure que 20 NTU (unité de turbidité néphélémétrique) et d'autres propriétés physiques telles qu'une bonne compression des boucles, une bonne résistance à l'humidité élevée et une bonne résistance au décollement.
PCT/EP2009/065325 2008-11-18 2009-11-17 Fixateurs capillaires en gel transparent WO2010057887A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0916120A BRPI0916120A2 (pt) 2008-11-18 2009-11-17 "composição de gel capilar transparente, e, sistema fixador capilar polimérico"
EP09756721.8A EP2355792B1 (fr) 2008-11-18 2009-11-17 Gels capillaires qui sont claires
US13/128,423 US8354098B2 (en) 2008-11-18 2009-11-17 Clear hair gel fixatives
JP2011543769A JP2012509358A (ja) 2008-11-18 2009-11-17 透明なヘアゲル固定剤
CN2009801458476A CN102215814A (zh) 2008-11-18 2009-11-17 透明的发胶固定剂

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US11566808P 2008-11-18 2008-11-18
US61/115,668 2008-11-18
EP09154321.5 2009-03-04
EP09154321A EP2226067A1 (fr) 2009-03-04 2009-03-04 Gels capillaires qui sont claires

Publications (1)

Publication Number Publication Date
WO2010057887A1 true WO2010057887A1 (fr) 2010-05-27

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PCT/EP2009/065325 WO2010057887A1 (fr) 2008-11-18 2009-11-17 Fixateurs capillaires en gel transparent

Country Status (6)

Country Link
US (1) US8354098B2 (fr)
EP (2) EP2226067A1 (fr)
JP (1) JP2012509358A (fr)
CN (1) CN102215814A (fr)
BR (1) BRPI0916120A2 (fr)
WO (1) WO2010057887A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3742163B1 (fr) * 2019-05-20 2022-09-28 L'oreal Procédé de mesure de compression et de douceur de cheveux
EP4168457A1 (fr) 2020-06-18 2023-04-26 Nutrition & Biosciences USA 4, Inc. Éthers de poly-alpha-1,6-glucane cationiques et compositions les comprenant
CN117616054A (zh) 2021-07-13 2024-02-27 营养与生物科学美国4公司 阳离子葡聚糖酯衍生物
WO2023081341A1 (fr) 2021-11-05 2023-05-11 Nutrition & Biosciences USA 4, Inc. Compositions comprenant un dérivé d'alpha-1,6-glucane cationique et un alpha-1,3-glucane
WO2023114942A1 (fr) 2021-12-16 2023-06-22 Nutrition & Biosciences USA 4, Inc. Compositions comprenant des éthers d'alpha-glucane cationiques dans des solvants organiques polaires aqueux
WO2024015769A1 (fr) 2022-07-11 2024-01-18 Nutrition & Biosciences USA 4, Inc. Dérivés amphiphiles d'ester de glucane
WO2024081773A1 (fr) 2022-10-14 2024-04-18 Nutrition & Biosciences USA 4, Inc. Compositions comprenant de l'eau, un éther d'alpha-1,6-glucane cationique et un solvant organique
WO2024097166A1 (fr) 2022-11-02 2024-05-10 Nutrition & Biosciences USA 4, Inc. Compositions comprenant de la gomme de xanthane et de l'alpha-1,3-glucane cristallin

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0879590A2 (fr) * 1997-04-10 1998-11-25 National Starch and Chemical Investment Holding Corporation Compositions pour le traitement des cheveux contenant une N-vinyl acétamide polymerique et méthodes pour le traitement des cheveux
US20020048603A1 (en) * 2001-12-07 2002-04-25 Fred Burmeister Hydrogel composition
WO2005002532A2 (fr) * 2003-07-04 2005-01-13 Basf Aktiengesellschaft Agent cosmetique contenant au moins un copolymere soluble dans l'eau, comportant des unites d'amide d'acide (meth)acrylique
EP1313432B1 (fr) * 2000-08-22 2005-03-09 Basf Aktiengesellschaft Utilisation de copolymeres greffes a motifs n-vinylamine et/ou n-vinylamide a chaine ouverte dans des formulations cosmetiques
EP1646663B1 (fr) * 2003-07-14 2007-01-24 Basf Aktiengesellschaft Dispersion polymere aqueuse et son utilisation en cosmetique

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3519701A (en) * 1966-07-11 1970-07-07 Union Carbide Corp Polyvinyl esters and derivatives therefrom
DE3128478A1 (de) 1981-07-18 1983-02-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von linearen, basischen polymerisaten
LU86430A1 (fr) * 1986-05-16 1987-12-16 Oreal Utilisation d'alcool polyvinylique partiellement acetyle comme agent de moussage dans les compositions sous forme d'aerosols
JPH01231934A (ja) * 1988-03-10 1989-09-18 Lion Corp マイクロカプセルの製造方法
US5977274A (en) 1998-03-09 1999-11-02 National Starch And Chemical Investment Holding Corporation Method for making polymers from N-vinyl formamide monomer
DE19836992A1 (de) 1998-08-14 2000-02-17 Basf Ag Verfahren zur Eliminierung von Formamid aus N-Vinylformamideinheiten enthaltenden Polymerisaten
JP4104790B2 (ja) * 1999-08-10 2008-06-18 日本エヌエスシー株式会社 化粧料
DE10127104A1 (de) * 2001-06-02 2002-12-05 Wella Ag Zweiphasiges Haargel
JP2003095893A (ja) * 2001-09-27 2003-04-03 Mitsubishi Chemicals Corp 整髪料組成物

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0879590A2 (fr) * 1997-04-10 1998-11-25 National Starch and Chemical Investment Holding Corporation Compositions pour le traitement des cheveux contenant une N-vinyl acétamide polymerique et méthodes pour le traitement des cheveux
EP1313432B1 (fr) * 2000-08-22 2005-03-09 Basf Aktiengesellschaft Utilisation de copolymeres greffes a motifs n-vinylamine et/ou n-vinylamide a chaine ouverte dans des formulations cosmetiques
US20020048603A1 (en) * 2001-12-07 2002-04-25 Fred Burmeister Hydrogel composition
WO2005002532A2 (fr) * 2003-07-04 2005-01-13 Basf Aktiengesellschaft Agent cosmetique contenant au moins un copolymere soluble dans l'eau, comportant des unites d'amide d'acide (meth)acrylique
EP1646663B1 (fr) * 2003-07-14 2007-01-24 Basf Aktiengesellschaft Dispersion polymere aqueuse et son utilisation en cosmetique

Also Published As

Publication number Publication date
JP2012509358A (ja) 2012-04-19
EP2355792A1 (fr) 2011-08-17
EP2226067A1 (fr) 2010-09-08
US8354098B2 (en) 2013-01-15
EP2355792B1 (fr) 2016-08-24
US20110217256A1 (en) 2011-09-08
BRPI0916120A2 (pt) 2015-11-03
CN102215814A (zh) 2011-10-12

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