WO2010052153A1 - Treated textile material for use in aquatic environments - Google Patents

Treated textile material for use in aquatic environments Download PDF

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Publication number
WO2010052153A1
WO2010052153A1 PCT/EP2009/064132 EP2009064132W WO2010052153A1 WO 2010052153 A1 WO2010052153 A1 WO 2010052153A1 EP 2009064132 W EP2009064132 W EP 2009064132W WO 2010052153 A1 WO2010052153 A1 WO 2010052153A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
substituted
monomers
binder
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2009/064132
Other languages
English (en)
French (fr)
Inventor
Ulrich Karl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to RU2011122531/05A priority Critical patent/RU2011122531A/ru
Priority to AU2009312901A priority patent/AU2009312901A1/en
Priority to CN2009801535167A priority patent/CN102272376A/zh
Priority to DK09740336.4T priority patent/DK2352876T3/da
Priority to US13/127,645 priority patent/US20110217348A1/en
Priority to JP2011533703A priority patent/JP2012507637A/ja
Priority to EP09740336A priority patent/EP2352876B1/en
Priority to CA2742231A priority patent/CA2742231A1/en
Priority to ES09740336T priority patent/ES2398685T3/es
Publication of WO2010052153A1 publication Critical patent/WO2010052153A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1625—Non-macromolecular compounds organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms

Definitions

  • the density of the polymeric binder (A) is in the range from 0.89 to 0,99 g/cm 3 , preferably 0.89 to 0.96 g/cm 3 , determined in accordance with DIN 53479.
  • Initiators which can be used for the free-radical polymerization are the typical free- radical initiators such as organic peroxides, oxygen or azo compounds, for example. Mixtures of two or more free-radical initiators are suitable as well. Examples have been disclosed in WO 2007/009909, page 9, line 10 to page 10, line 16.
  • R 9 , R 10 , R 11 and R 12 are independently H, d- to Cio-alkyl which is linear or branched, for example, methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, sec-butyl, tert-butyl, n- pentyl, i-pentyl, sec-pentyl, neo-pentyl, 1 ,2-dimethylpropyl, i-amyl, n-hexyl, i-hexyl, sec- hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl and n-decyl; preferably R 9 , R 10 , R 11 and R 12 are selected from the group consisting of H, d- to C 4 -alkyl, which may be linear or branched, for
  • vat dyes are known to a person skilled in the art.
  • Typical disperse and cationic dyestuffs are known to the person skilled in the art.
  • the antifouling agent as a final product so that it can be readily used by the end-user for the process according to the present invention.
  • the impregnated textile material is optionally fi- nally cured and/or fixated.
  • the curing process is in general carried out at a temperature which may be higher than the drying temperature.
  • Preferred temperatures for curing are 60 to 170 0 C, preferably 70 to 170 0 C, more preferably 80 to 150 0 C. Drying and curing can be advantageously be performed during one single process, e.g. in stenters with different compartments which can be heated to different temperatures. If a reactive crosslinking agent is used temperatures may be lower, e.g. 30 to 130 0 C, preferably 30 to 100 0 C.
  • a typical amount of the polymeric binder (b) is from 0.1 to 25 % by weight (dry weight) of the (dry) weight of the fabric or netting.
  • the weight ratio between antifouling biocide and binder (b) should approximately be constant, i.e. the higher the amount of antifouling biocide the higher the amount of binder (b).
  • Preferred amounts of binder (b) are from 0.5 to 20 % by weight, more preferably 1 to 20 % by weight of the (dry) weight of the fabric or netting.
  • the treated textile material of the invention for application in an aquatic environment preferably comprises at least one antifouling biocide selected from diuron, picolinafen, lrgarol 1051 , 2,4,5,6-tetrachloro isophthalonitrile, 4,5-dichloro-2-octyl-3-(2H)- isothiazolin-3-one (DCOIT), 2-(thiocyanomethylthio)benzothiazole, (thiocyano- methylthio)benzothiazole, N-cyclohexyldiazeniumdioxide copper or potassium salt (CuHDO, KHDO), 2-mercapto-benzothiazole, zinc or copper pyrithione, metal dithio- carbamates, e.g.
  • Biofouling is caused by various organisms including
  • actinia sina anemones like metridium sp.
  • Table 1 lists the nets according to the invention prepared according to this procedure. Table 1

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Toxicology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
PCT/EP2009/064132 2008-11-04 2009-10-27 Treated textile material for use in aquatic environments Ceased WO2010052153A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
RU2011122531/05A RU2011122531A (ru) 2008-11-04 2009-10-27 Обработанный текстильный материал для применения в водных средах
AU2009312901A AU2009312901A1 (en) 2008-11-04 2009-10-27 Treated textile material for use in aquatic environments
CN2009801535167A CN102272376A (zh) 2008-11-04 2009-10-27 用于水生环境的经处理的纺织材料
DK09740336.4T DK2352876T3 (da) 2008-11-04 2009-10-27 Behandlet tekstilmateriale til anvendelse i vandige miljøer
US13/127,645 US20110217348A1 (en) 2008-11-04 2009-10-27 Treated textile material for use in aquatic environments
JP2011533703A JP2012507637A (ja) 2008-11-04 2009-10-27 水域環境中で使用するための処理された繊維材料
EP09740336A EP2352876B1 (en) 2008-11-04 2009-10-27 Treated textile material for use in aquatic environments
CA2742231A CA2742231A1 (en) 2008-11-04 2009-10-27 Treated textile material for use in aquatic environments
ES09740336T ES2398685T3 (es) 2008-11-04 2009-10-27 Material textil tratado para el uso en ambientes acuáticos

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08168285 2008-11-04
EP08168285.8 2008-11-04

Publications (1)

Publication Number Publication Date
WO2010052153A1 true WO2010052153A1 (en) 2010-05-14

Family

ID=41490487

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/064132 Ceased WO2010052153A1 (en) 2008-11-04 2009-10-27 Treated textile material for use in aquatic environments

Country Status (13)

Country Link
US (1) US20110217348A1 (https=)
EP (1) EP2352876B1 (https=)
JP (1) JP2012507637A (https=)
KR (1) KR20110093863A (https=)
CN (1) CN102272376A (https=)
AU (1) AU2009312901A1 (https=)
CA (1) CA2742231A1 (https=)
CL (1) CL2011001003A1 (https=)
DK (1) DK2352876T3 (https=)
ES (1) ES2398685T3 (https=)
RU (1) RU2011122531A (https=)
TW (1) TW201030109A (https=)
WO (1) WO2010052153A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016093719A1 (en) * 2014-12-12 2016-06-16 Instituto Superior Técnico Functionalization process for biocide immobilization in polymer matrices
WO2023036491A1 (en) 2021-09-07 2023-03-16 Dsm Ip Assets. B.V. Net for fish farming, method of making and use thereof

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DE202012100443U1 (de) * 2012-02-09 2012-02-28 Wenko-Wenselaar Gmbh & Co. Kg Duschvorhang mit Antibewuchs-Ausrüstung
CN104211637A (zh) * 2013-06-25 2014-12-17 四川大学 含三苯基吡啶和叔丁基的芳香二胺及其制备方法
US9758692B2 (en) * 2014-07-25 2017-09-12 Tommie Copper Ip, Inc. Article with reactive metals bound to its surface and method of application
JP6578745B2 (ja) * 2015-05-29 2019-09-25 住友化学株式会社 水中に生息する有害生物防除用樹脂製剤
CN105365323A (zh) * 2015-12-11 2016-03-02 桐乡市玉溪针织有限公司 高透湿防水面料
CN107474617A (zh) * 2017-07-15 2017-12-15 佛山实瑞先导材料研究院（普通合伙） 一种水性环保抗菌防污涂料
GB201718899D0 (en) * 2017-11-15 2017-12-27 Jotun As Antifouling coating composition
CN108084070B (zh) * 2017-12-14 2020-04-14 浙江海洋大学 一种硫代亚磺酸酯类化合物的制备及其在防污涂料中的应用
CN114775162B (zh) * 2022-04-13 2023-06-06 中国水产科学研究院东海水产研究所 一种矩形深远海养殖分隔网的制备方法
CN116970617A (zh) * 2023-09-25 2023-10-31 烟台大学 红条毛肤石鳖ArWz-1基因在重金属污染中的应用
CN120205138B (zh) * 2025-05-28 2025-08-19 武汉理工大学三亚科教创新园 一种铜单原子纳米酶及其制备方法和海洋抗污损应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19644224A1 (de) * 1996-10-24 1998-04-30 Bayer Ag Antifoulingbeschichtung
US5990043A (en) * 1993-12-21 1999-11-23 Bayer Aktiengesellschaft Anti-fouling compositions
WO2006128870A2 (en) * 2005-06-03 2006-12-07 Basf Aktiengesellschaft Composition for the impregnation of fibers, fabrics and nettings imparting a protective activity against pests
WO2008151984A1 (en) * 2007-06-12 2008-12-18 Basf Se Aqueous formulation and process for the impregnation of non-living-materials imparting a protective activity against pests

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2188938B (en) * 1985-12-27 1990-03-21 Nippon Oils & Fats Co Ltd Antifouling coating composition comprising a polymer having siloxane and/or alkylsilyl groups
US6267079B1 (en) * 1999-08-26 2001-07-31 Lisa A. Eby Fish cage
GB0330023D0 (en) * 2003-12-24 2004-01-28 Basf Ag Microbicidal compositions
DE102005034215A1 (de) * 2005-07-19 2007-01-25 Basf Ag Verfahren zur Beschichtung von Oberflächen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5990043A (en) * 1993-12-21 1999-11-23 Bayer Aktiengesellschaft Anti-fouling compositions
DE19644224A1 (de) * 1996-10-24 1998-04-30 Bayer Ag Antifoulingbeschichtung
WO2006128870A2 (en) * 2005-06-03 2006-12-07 Basf Aktiengesellschaft Composition for the impregnation of fibers, fabrics and nettings imparting a protective activity against pests
WO2008151984A1 (en) * 2007-06-12 2008-12-18 Basf Se Aqueous formulation and process for the impregnation of non-living-materials imparting a protective activity against pests

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016093719A1 (en) * 2014-12-12 2016-06-16 Instituto Superior Técnico Functionalization process for biocide immobilization in polymer matrices
WO2023036491A1 (en) 2021-09-07 2023-03-16 Dsm Ip Assets. B.V. Net for fish farming, method of making and use thereof

Also Published As

Publication number Publication date
ES2398685T3 (es) 2013-03-21
AU2009312901A1 (en) 2010-05-14
TW201030109A (en) 2010-08-16
CL2011001003A1 (es) 2011-09-16
DK2352876T3 (da) 2013-03-04
JP2012507637A (ja) 2012-03-29
KR20110093863A (ko) 2011-08-18
CN102272376A (zh) 2011-12-07
CA2742231A1 (en) 2010-05-14
EP2352876A1 (en) 2011-08-10
EP2352876B1 (en) 2012-12-12
RU2011122531A (ru) 2012-12-20
US20110217348A1 (en) 2011-09-08

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