TW201030109A

TW201030109A - Treated textile material for use in aquatic environments

Treated textile material for use in aquatic environments Download PDF

Info

Publication number: TW201030109A
Authority: TW; Taiwan
Prior art keywords: acid; weight; substituted; group; textile material
Prior art date: 2008-11-04

Application number

TW098137427A

Other languages

English (en)

Chinese (zh)

Inventor

Ulrich Karl

Original Assignee

Basf Se

Priority date

2008-11-04

Filing date

2009-11-04

Publication date

2010-08-16

2009-11-04 Application filed by Basf Se filed Critical Basf Se

2010-08-16 Publication of TW201030109A publication Critical patent/TW201030109A/zh

Links

239000000463 material Substances 0.000 title claims abstract description 70
239000004753 textile Substances 0.000 title claims abstract description 56
239000000178 monomer Substances 0.000 claims abstract description 77
239000003139 biocide Substances 0.000 claims abstract description 57
239000000203 mixture Substances 0.000 claims abstract description 49
239000002519 antifouling agent Substances 0.000 claims abstract description 46
239000011230 binding agent Substances 0.000 claims abstract description 45
125000003118 aryl group Chemical group 0.000 claims abstract description 34
230000003373 anti-fouling effect Effects 0.000 claims abstract description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
125000005442 diisocyanate group Chemical group 0.000 claims abstract description 20
239000000654 additive Substances 0.000 claims abstract description 10
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 9
238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 9
239000005056 polyisocyanate Substances 0.000 claims abstract description 8
229920001228 polyisocyanate Polymers 0.000 claims abstract description 8
239000005977 Ethylene Substances 0.000 claims abstract description 7
239000003125 aqueous solvent Substances 0.000 claims abstract description 7
125000002947 alkylene group Chemical group 0.000 claims abstract description 6
238000006243 chemical reaction Methods 0.000 claims abstract description 6
229920000582 polyisocyanurate Polymers 0.000 claims abstract description 6
239000011495 polyisocyanurate Substances 0.000 claims abstract description 6
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims abstract description 5
239000011877 solvent mixture Substances 0.000 claims abstract description 3
-1 (dithianon) (2 , 3-dicyano-1,4-dithia-indene) Chemical compound 0.000 claims description 145
230000003115 biocidal effect Effects 0.000 claims description 47
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 42
229920005596 polymer binder Polymers 0.000 claims description 31
239000002491 polymer binding agent Substances 0.000 claims description 31
125000000217 alkyl group Chemical group 0.000 claims description 30
238000000034 method Methods 0.000 claims description 30
239000002253 acid Substances 0.000 claims description 27
239000003795 chemical substances by application Substances 0.000 claims description 24
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 24
229910052751 metal Inorganic materials 0.000 claims description 22
239000002184 metal Substances 0.000 claims description 22
150000003839 salts Chemical class 0.000 claims description 21
239000000853 adhesive Substances 0.000 claims description 13
230000001070 adhesive effect Effects 0.000 claims description 12
238000009360 aquaculture Methods 0.000 claims description 11
244000144974 aquaculture Species 0.000 claims description 11
239000000052 vinegar Substances 0.000 claims description 11
235000021419 vinegar Nutrition 0.000 claims description 11
239000010949 copper Substances 0.000 claims description 10
239000002917 insecticide Substances 0.000 claims description 10
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 9
229910052802 copper Inorganic materials 0.000 claims description 9
239000000126 substance Substances 0.000 claims description 9
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
239000003522 acrylic cement Substances 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 8
150000002148 esters Chemical class 0.000 claims description 7
150000003254 radicals Chemical class 0.000 claims description 7
GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical class C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 claims description 6
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 6
241001465754 Metazoa Species 0.000 claims description 6
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 6
DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
238000006116 polymerization reaction Methods 0.000 claims description 6
229920000098 polyolefin Polymers 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
239000011701 zinc Substances 0.000 claims description 6
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 5
229910052725 zinc Inorganic materials 0.000 claims description 5
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 4
239000004305 biphenyl Substances 0.000 claims description 4
229910052742 iron Inorganic materials 0.000 claims description 4
150000002576 ketones Chemical class 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 4
FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 claims description 4
YTQQIHUQLOZOJI-UHFFFAOYSA-N 2,3-dihydro-1,2-thiazole Chemical compound C1NSC=C1 YTQQIHUQLOZOJI-UHFFFAOYSA-N 0.000 claims description 3
XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 claims description 3
WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
239000005510 Diuron Substances 0.000 claims description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
239000012964 benzotriazole Substances 0.000 claims description 3
229910052793 cadmium Inorganic materials 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 3
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 3
229930003658 monoterpene Natural products 0.000 claims description 3
229910052759 nickel Inorganic materials 0.000 claims description 3
AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 claims description 3
229960002026 pyrithione Drugs 0.000 claims description 3
XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 claims description 3
125000003107 substituted aryl group Chemical group 0.000 claims description 3
WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 claims description 3
OURODNXVJUWPMZ-UHFFFAOYSA-N 1,2-diphenylanthracene Chemical compound C1=CC=CC=C1C1=CC=C(C=C2C(C=CC=C2)=C2)C2=C1C1=CC=CC=C1 OURODNXVJUWPMZ-UHFFFAOYSA-N 0.000 claims description 2
PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 claims description 2
125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 claims description 2
MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 claims description 2
150000008378 aryl ethers Chemical class 0.000 claims description 2
ZVSKZLHKADLHSD-UHFFFAOYSA-N benzanilide Chemical group C=1C=CC=CC=1C(=O)NC1=CC=CC=C1 ZVSKZLHKADLHSD-UHFFFAOYSA-N 0.000 claims description 2
JYZIHLWOWKMNNX-UHFFFAOYSA-N benzimidazole Chemical compound C1=C[CH]C2=NC=NC2=C1 JYZIHLWOWKMNNX-UHFFFAOYSA-N 0.000 claims description 2
235000010290 biphenyl Nutrition 0.000 claims description 2
239000004202 carbamide Substances 0.000 claims description 2
239000003153 chemical reaction reagent Substances 0.000 claims description 2
MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical class CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 claims description 2
230000001804 emulsifying effect Effects 0.000 claims description 2
150000002596 lactones Chemical class 0.000 claims description 2
239000003120 macrolide antibiotic agent Substances 0.000 claims description 2
150000002773 monoterpene derivatives Chemical class 0.000 claims description 2
125000005609 naphthenate group Chemical group 0.000 claims description 2
150000002923 oximes Chemical group 0.000 claims description 2
230000003071 parasitic effect Effects 0.000 claims description 2
230000000590 parasiticidal effect Effects 0.000 claims description 2
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 2
229920006391 phthalonitrile polymer Polymers 0.000 claims description 2
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
238000009987 spinning Methods 0.000 claims description 2
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 2
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims 2
BYVSMDBDTBXASR-UHFFFAOYSA-N 5,6-dihydro-4h-oxazine Chemical class C1CON=CC1 BYVSMDBDTBXASR-UHFFFAOYSA-N 0.000 claims 2
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 2
WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 claims 2
150000003949 imides Chemical class 0.000 claims 2
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims 1
UPUWMQZUXFAUCJ-UHFFFAOYSA-N 2,5-dihydro-1,2-thiazole Chemical compound C1SNC=C1 UPUWMQZUXFAUCJ-UHFFFAOYSA-N 0.000 claims 1
YDKQAOPJFWRLMP-UHFFFAOYSA-N 2-(sulfanylcarbamoyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1C(=O)NS YDKQAOPJFWRLMP-UHFFFAOYSA-N 0.000 claims 1
SCVJRXQHFJXZFZ-KVQBGUIXSA-N 2-amino-9-[(2r,4s,5r)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-3h-purine-6-thione Chemical compound C1=2NC(N)=NC(=S)C=2N=CN1[C@H]1C[C@H](O)[C@@H](CO)O1 SCVJRXQHFJXZFZ-KVQBGUIXSA-N 0.000 claims 1
CYCRZLRIJWDWCM-UHFFFAOYSA-N 2-aminonaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(N)=CC(=O)C2=C1 CYCRZLRIJWDWCM-UHFFFAOYSA-N 0.000 claims 1
ASSKVPFEZFQQNQ-UHFFFAOYSA-N 2-benzoxazolinone Chemical compound C1=CC=C2OC(O)=NC2=C1 ASSKVPFEZFQQNQ-UHFFFAOYSA-N 0.000 claims 1
229940054266 2-mercaptobenzothiazole Drugs 0.000 claims 1
IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical class O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 claims 1
FNBOXQYFMYXVDU-UHFFFAOYSA-N 3-thiophen-2-yl-1h-indole Chemical compound C1=CSC(C=2C3=CC=CC=C3NC=2)=C1 FNBOXQYFMYXVDU-UHFFFAOYSA-N 0.000 claims 1
NDZFORWVONADMI-UHFFFAOYSA-N 4-phenyl-5h-1,3-thiazol-2-one Chemical class O=C1SCC(C=2C=CC=CC=2)=N1 NDZFORWVONADMI-UHFFFAOYSA-N 0.000 claims 1
RPMWEGXHQSEPPH-UHFFFAOYSA-N 6-ethoxy-1h-indole Chemical compound CCOC1=CC=C2C=CNC2=C1 RPMWEGXHQSEPPH-UHFFFAOYSA-N 0.000 claims 1
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 1
KCLPXPUTKVWUCP-UHFFFAOYSA-N B.C1=CC=CC=C1C1=CC=NC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 Chemical compound B.C1=CC=CC=C1C1=CC=NC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 KCLPXPUTKVWUCP-UHFFFAOYSA-N 0.000 claims 1
FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 claims 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
239000005747 Chlorothalonil Substances 0.000 claims 1
101100447665 Mus musculus Gas2 gene Proteins 0.000 claims 1
PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 1
240000004460 Tanacetum coccineum Species 0.000 claims 1
ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 claims 1
239000000556 agonist Substances 0.000 claims 1
150000001408 amides Chemical class 0.000 claims 1
CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims 1
XDUPUJNNHFTMQS-UHFFFAOYSA-N copper;1-oxidopyridine-2-thione Chemical compound [Cu+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S XDUPUJNNHFTMQS-UHFFFAOYSA-N 0.000 claims 1
150000001893 coumarin derivatives Chemical class 0.000 claims 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
RGXWDWUGBIJHDO-UHFFFAOYSA-N decanoic acid ethyl ester Natural products CCCCCCCCCC(=O)OCC RGXWDWUGBIJHDO-UHFFFAOYSA-N 0.000 claims 1
230000007547 defect Effects 0.000 claims 1
WURGXGVFSMYFCG-UHFFFAOYSA-N dichlofluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=CC=C1 WURGXGVFSMYFCG-UHFFFAOYSA-N 0.000 claims 1
RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims 1
150000002240 furans Chemical class 0.000 claims 1
MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims 1
150000002696 manganese Chemical class 0.000 claims 1
150000004702 methyl esters Chemical class 0.000 claims 1
NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims 1
230000001681 protective effect Effects 0.000 claims 1
229940015367 pyrethrum Drugs 0.000 claims 1
150000005846 sugar alcohols Polymers 0.000 claims 1
PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims 1
LNQMAGOUQKHYNT-UHFFFAOYSA-N sulfanylidenemethylidenehydrazine Chemical class NN=C=S LNQMAGOUQKHYNT-UHFFFAOYSA-N 0.000 claims 1
229940124530 sulfonamide Drugs 0.000 claims 1
150000003456 sulfonamides Chemical class 0.000 claims 1
239000012948 isocyanate Substances 0.000 abstract description 16
150000002009 diols Chemical class 0.000 abstract description 12
150000002513 isocyanates Chemical class 0.000 abstract description 11
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract description 11
229920005862 polyol Polymers 0.000 abstract description 7
150000003077 polyols Chemical class 0.000 abstract description 7
239000004814 polyurethane Substances 0.000 abstract description 6
229920002635 polyurethane Polymers 0.000 abstract description 6
229920005822 acrylic binder Polymers 0.000 abstract description 5
238000002360 preparation method Methods 0.000 abstract description 5
150000001735 carboxylic acids Chemical class 0.000 abstract description 2
150000001991 dicarboxylic acids Chemical class 0.000 abstract description 2
125000001153 fluoro group Chemical group F* 0.000 abstract description 2
125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
125000000732 arylene group Chemical group 0.000 abstract 1
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239000004744 fabric Substances 0.000 description 48
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 27
229910052739 hydrogen Inorganic materials 0.000 description 23
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 22
239000000049 pigment Substances 0.000 description 21
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238000001035 drying Methods 0.000 description 19
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 17
238000001723 curing Methods 0.000 description 15
239000002904 solvent Substances 0.000 description 15
125000004432 carbon atom Chemical group C* 0.000 description 14
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 14
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241000238366 Cephalopoda Species 0.000 description 12
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KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
239000006185 dispersion Substances 0.000 description 12
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 11
230000008569 process Effects 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
150000001412 amines Chemical class 0.000 description 9
239000002585 base Substances 0.000 description 9
239000000835 fiber Substances 0.000 description 9
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 9
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 9
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 8
125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 8
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 8
239000007788 liquid Substances 0.000 description 8
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150000001298 alcohols Chemical class 0.000 description 7
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