Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
  • A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
  • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
  • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
  • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
  • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
  • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
  • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
  • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
  • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
  • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Definitions

• the present invention concerns a novel method to reduce spray drift during the application of agricultural chemicals by incorporating a self-emulsifiable ester into the liquid to be sprayed.
• Agricultural spraying by economical and available technologies uses hydraulic spray nozzles that inherently produce a wide spectrum of spray droplet sizes.
• the potential for these spray droplets to drift from the initial, desired site of application is found to be a function of droplet size, with smaller droplets having a higher propensity for off-target movement.
• Significant research efforts, involving numerous field trials, wind tunnel tests and subsequent generation of predictive math models have led to a greatly enhanced understanding of the relationship between spray droplet size and potential for off-target drift.
• High molecular weight, water-soluble polymers are currently added to spray compositions as a tank mix to increase droplet size and thereby reduce drift (see, for example, WO 2008/101818 A2 and U.S. 6,214,771 Bl).
• high molecular weight, water- soluble polymers are not entirely satisfactory because they are expensive to use at the concentrations required to substantially increase droplet size.
• many commercially available drift retardants typically do not work with many aerially applied herbicide tank mixtures, due to pump shear, wind shear and other performance issues, which are more pronounced in high speed aerial application conditions. See Hewitt, AJ. (2003) Drift Control Adjuvants in Spray Applications: Performance and Regulatory Aspects. Proc. Third Latin American Symposium on Agricultural Adjuvants, Sao Paulo, Brazil.
• the present invention concerns a method to reduce spray drift during the application of a pesticide which comprises incorporating into the pesticidal spray from 0.01 to 5 percent vol/vol of a self- emulsifiable ester or mixture thereof.
• the reduction in spray drift may result from a variety of factors including a reduction in the production of fine spray droplets ( ⁇ 175 ⁇ in diameter) and an increase in the volume median diameter (VMD) of the spray droplets.
• VMD volume median diameter
• Another embodiment of the invention is a premix formulation which comprises from 1 to 90 weight percent of a pesticide, and from 0.05 to 30 weight percent of a self- emulsifiable ester.
• the premix formulation is preferably a solution, emulsion , suspension, wettable or soluble powder, or water-dispersible or water-soluble granule formulation.
• the method to reduce spray drift applies to the application of any pesticide or crop protection agent including herbicides, fungicides and insecticides.
• herbicides particularly preferred herbicides to which this method applies include cyhalofop-butyl, haloxyfop, penoxsulam, flumetsulam, cloransulam-methyl, florasulam, pyroxsulam, diclosulam, fluroxypyr, clopyralid, acetochlor, triclopyr, isoxaben, 2,4-D, MCPA, dicamba, MSMA, oxyfluorfen, oryzalin, trifluralin, benfluralin, ethalfluralin, aminopyralid, atrazine, picloram, tebuthiuron, pendimethalin, propanil, propyzamide, glyphosate and glufosinate.
• Particularly preferred insecticides to which this method applies include organophosphates such as chlorpyrifos, MACs such as halofenozide, methoxyfenozide and tebufenozide, pyrethroids such as g ⁇ mm ⁇ -cyhalothrin and deltamethrin, and biopesticides such as spinosad and spinetoram.
• organophosphates such as chlorpyrifos
• MACs such as halofenozide, methoxyfenozide and tebufenozide
• pyrethroids such as g ⁇ mm ⁇ -cyhalothrin and deltamethrin
• biopesticides such as spinosad and spinetoram.
• Particularly preferred fungicides to which this method applies include mancozeb,
• the present invention is particularly useful for the application of herbicides, most particularly with herbicides that are subject to restricted applications around sensitive crops which have not been modified to be tolerant of them, such as 2,4-D, dicamba, glyphosate and glufosinate.
• Self-emulsifiable esters used in the present invention are characterized as molecules that combine oil (hydrophobic), hydrophilic nonionic, and, optionally, anionic functionality in a single molecule that can form uniform stable emulsions in an aqueous phase. Contrary to conventional emulsions in which one or more oils would be blended with one or more surfactants (emulsifiers), no such additives are necessary for the emulsion disclosed in the present invention. Uniform, stable aqueous emulsions can be formed with these SEEs without the use of additional emulsifiers or oils by little to moderate agitation of the SEE and water mixture.
• SEEs include, but are not limited to, the following: (1) trimer acid based self-emulsifiable esters produced by the polymerization of oleic and linoleic acids having a C 54 lipophilic backbone and an ester portion of the molecule containing both nonionic and anionic surfactant functionality (see, for example, U.S.
• Patents 5,688,750 and 5,707,945 commercially available under the trademark Priolube products from Croda Uniqema, Inc); (2) esters prepared by esterification of ethoxylated trimethylolpropane by fatty acids and dicarboxylic acid anhydrides (see, for example, WO1990/005714); (3) esters derived from high molecular weight dibasic acids, polyoxyalkylene glycols and monofunctional aliphatic alcohols (see, for example, U.S.
• Patent 3,912,642 self emulsifying ester compounds prepared by reacting an ethoxylated trimethylol propane with a carboxylic acid or a reactive derivative thereof, such as an anhydride, as disclosed in U.S. Patent 5,219,479; (5) succinate triglyceride oil derived from maleating triglyceride oil from a plant or land animal (see, for example, WO 2005/071050 Al) commercially available as the trademark VEG-ESTER products of Lubrizol, Inc.; (6) ethoxylated fatty acid esters (see, for example, WO 1996/022109); (7) alkoxylate esters prepared by reacting an alcohol with ethylene oxide and propylene oxide and/or butylene oxide and capping the resulting alkoxylate with an alkanoic or aromatic acid as disclosed in U.S.
• the self-emulsifiable esters can be incorporated into the pesticidal spray by being tank-mixed directly with the diluted pesticidal formulation or by being provided as a pre-mix with the pesticidal formulation prior to dilution to the final spray volume.
• the self- emulsifiable ester is incorporated at a concentration from 0.01 to 5 volume percent of the final spray volume, preferably from 0.05 to 1.0 volume percent of the final spray volume, and most preferably from 0.05 to 0.2 volume percent of the final spray volume.
• the present method reduces off-target movement of the pesticide spray in both aerial and ground applications.
• the optimum droplet size depends on the application for which the composition is used. If droplets are too large, there will be less coverage by the spray; i.e, large droplets will land in certain areas while areas in between will receive little or no spray composition.
• the maximum acceptable droplet size may depend on the amount of composition being applied per unit area and the need for uniformity in spray coverage. Smaller droplets provide more even coverage, but are more prone to drift during spraying. If it is particularly windy during spraying, larger droplets may be preferred, whereas on a calmer day smaller droplets may be preferred.
• the spray droplet size may also depend on the spray apparatus; e.g., nozzle size and configuration.
• One skilled in the art will readily be able to adjust the percentage of surfactant and/or polymer in the composition to provide the desired droplet size for a given apparatus, application, and condition.
• the median diameter of the plurality of spray droplets is increased above that of a spray composition without said self-emulsifiable ester.
• the present invention also embraces premix formulations comprising from 1 to 90 weight percent, preferably from 5 to 70 weight percent, and most preferably from 20 to 60 weight percent of a pesticide and from 0.05 to 30 weight percent, preferably from 1.0 to 20 weight percent, and most preferably from 1.0 to 10 weight percent of a self-emulsifiable ester.
• the composition of the present invention may contain a surfactant.
• the surfactants can be anionic, cationic or nonionic in character.
• Typical surfactants include salts of alkyl sulfates, such as diethanolammonium lauryl sulfate; alkylarylsulfonate salts, such as calcium dodecylbenzenesulfonate; alkyl and/or arylalkylphenol-alkylene oxide addition products, such as nonylphenol-Ci8 ethoxylate; alcohol-alkylene oxide addition products, such as tridecyl alcohol-Ci6 ethoxylate; soaps, such as sodium stearate; alkylnaphthalenesulfonate salts, such as sodium dibutylnaphthalenesulfonate; dialkyl esters of sulfosuccinate salts, such as sodium di(2-ethylhexyl) sulfosuccinate; sorbito
• the present invention also embraces formulations in combination with one or more additional compatible ingredients.
• additional ingredients may include, for example, one or more other pesticides, dyes, and any other additional ingredients providing functional utility, such as, for example, stabilizers, fragrances, viscosity-lowering additives, and freeze-point depressants.
• the premix formulation is preferably a solution, emulsion , suspension, wettable or soluble powder, or water-dispersible or water-soluble granule formulation.
• the aqueous spray solution was made by adding 1 mL of the each formulation to 99 mL of deionized water to make a l%v/v dilution.
• the spray solution was then sprayed through a TeeJet 8002 flat fan nozzle at 40psi (276 kilopascal (kPa)) and the droplet size was measured by using a Sympatec Helos particle sizer.
• the measurements were made with the tip of the nozzle at either 6 or 12 inches (15.24 or 30.48 centimeters (cm)) from the measurement zone of the particle sizer. The results are reported in Table 2 (6 inches; 15.24 cm) and Table 3 (12 inches; 30.48 cm).
• the driftable fines with droplet size less than 175 ⁇ m by the spray composition of the present invention are largely reduced.
• the present invention efficiently reduces driftable fine droplets by narrowing the drop size distribution profile without significantly increasing the large droplets, thus with minimal effect on spray coverage and quality.
• Example 1 Compositions 6 Inches (15.24 cm) from Nozzle.
• Example 1 Compositions 12 Inches (30.48 cm) from Nozzle.
• Example 2 Compositions 12 Inches (30.48 cm) from Nozzle.
• aqueous spray solutions of each were made by adding 2 ml of each of the formulations to 98 ml of deionized water to make 2% v/v dilutions. The solutions were then sprayed following the same procedure and settings as described in Example 1, with the spray nozzle 12 inches (30.48 cm) from particle sizer measurement zone.
• Table 6 The results are shown in Table 6. As can be seen from these results, the present invention does effectively reduce the driftable fine droplets by narrowing the drop size distribution profile without significantly increasing the large droplets, thus having minimal effect on spray coverage and quality.
• Example 5 The solutions were then sprayed following the same procedure and settings as described in Example 1, with the spray nozzle 12 inches (30.48 cm) from particle sizer measurement zone. The results are shown in Table 5. As can be seen from these results, the present invention does effectively reduce the driftable fine droplets by altering the drop size distribution profile without significantly increasing the large droplets, thus having minimal effect on spray coverage and quality.

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• Life Sciences & Earth Sciences (AREA)
• Health & Medical Sciences (AREA)
• General Health & Medical Sciences (AREA)
• Zoology (AREA)
• Engineering & Computer Science (AREA)
• Dentistry (AREA)
• Wood Science & Technology (AREA)
• Environmental Sciences (AREA)
• Plant Pathology (AREA)
• Pest Control & Pesticides (AREA)
• Agronomy & Crop Science (AREA)
• Toxicology (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)
• Catching Or Destruction (AREA)

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• 2009
  • 2009-10-29 AR ARP090104172A patent/AR075294A1/es active IP Right Grant
  • 2009-10-30 JP JP2011534804A patent/JP5653926B2/ja active Active
  • 2009-10-30 CA CA2739700A patent/CA2739700C/en active Active
  • 2009-10-30 MX MX2011004586A patent/MX2011004586A/es unknown
  • 2009-10-30 US US12/609,404 patent/US20100113275A1/en not_active Abandoned
  • 2009-10-30 CN CN2009801416581A patent/CN102186340A/zh active Pending
  • 2009-10-30 EP EP09744579.5A patent/EP2348836B1/en active Active
  • 2009-10-30 CN CN201510397552.5A patent/CN104996417A/zh active Pending
  • 2009-10-30 WO PCT/US2009/062734 patent/WO2010051435A2/en not_active Ceased
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• 2011
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  • 2011-04-14 CO CO11046642A patent/CO6361858A2/es active IP Right Grant
• 2014
  • 2014-07-29 JP JP2014153686A patent/JP5728114B2/ja active Active
• 2016
  • 2016-06-09 US US15/177,410 patent/US11172679B2/en active Active

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