WO2010044761A1 - Process for producing artificial leather - Google Patents

Process for producing artificial leather Download PDF

Info

Publication number
WO2010044761A1
WO2010044761A1 PCT/TR2009/000123 TR2009000123W WO2010044761A1 WO 2010044761 A1 WO2010044761 A1 WO 2010044761A1 TR 2009000123 W TR2009000123 W TR 2009000123W WO 2010044761 A1 WO2010044761 A1 WO 2010044761A1
Authority
WO
WIPO (PCT)
Prior art keywords
porous
artificial leather
spongy
coating
layer
Prior art date
Application number
PCT/TR2009/000123
Other languages
English (en)
French (fr)
Inventor
Rafet Tukek
Original Assignee
Flokser Tekstil Sanayi Ve Ticaret A.S.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flokser Tekstil Sanayi Ve Ticaret A.S. filed Critical Flokser Tekstil Sanayi Ve Ticaret A.S.
Publication of WO2010044761A1 publication Critical patent/WO2010044761A1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC

Definitions

  • This invention is related to a kind of artificial leather that is particularly produced to be used in furniture, shoes, bag, clothing and accessories sector and the production method developed for the said kind of artificial leather; with the usage of this production method developed through this invention, the artificial leather obtained through using the intermediate product (layer) acquired by churning water based polyurethane and/or acrylic, latex, dye and other auxiliary chemicals in a newly developed foam machinery with the help of air in order to give them a porous structure exhibits very similar characteristics to natural leather thanks to its porous (spongy) pattern and corrugated surface view.
  • This production technique consists of two basic steps.
  • semi finished product (intermediate product) is obtained by applying polyurethane on the textile texture (woven, knitted, nonwowen, etc.) for creating porous structure to be used (as the details will be provided in 1.1) as the texture for in the second step.
  • the semi finished product (intermediate product) that is obtained by applying porous polyurethane onto the textile texture is exposed the coating process (as details will be provided in 1.2)
  • this carrier paper with chemicals comes to the 3 rd coating blade (2.7) and is once again coated with polyurethane, solvent and other auxiliary chemicals within the required thickness and weight (by grams) through the 3 rd coating blade (2.7).
  • the semi finished texture ' product (intermediate product) obtained through the coagulated production process applied to the paper with chemicals is adhered in the texture unit (2.8) and dried in the 3 rd furnace (2.9).
  • the product is obtained through separation of the texture and the patterned carrier paper at the exit of the cooling cylinders (2.10) of the machinery. Nevertheless, this production method causes contamination of both the air and the soil with 90 % solvent, DMF, in the coating polyurethane, thus damages the ecological system.
  • Patterned carrier paper in the coating machinery is coated with polyurethane and/or polyvinyl chloride, solvent and other auxiliary chemicals through the 1 st coating blade (3.3) within the required thickness and weight (by grams). Then, it is dried in the 1 st furnace (3.4).
  • This carrier paper with chemicals after the drying process, comes to the 2 nd coating blade (3.5) and is once again coated with polyvinyl chloride and other auxiliary chemicals within the required thickness and weight (by grams).
  • this carrier paper with chemicals comes to the 3 rd coating blade (3.7) and is once again coated with polyvinyl chloride and other auxiliary chemicals within the required thickness and weight (by grams) through the 3 rd coating blade (2.7).
  • textile texture (woven, knitted, nonwoven, etc.) is adhered to the paper with chemicals in the texture unit (3.8) and dried in the 3 rd furnace (3.9).
  • the product is obtained through separation of the texture and the patterned carrier paper at the exit of the machinery.
  • the number of coating blades at this stage may be increased or decreased, as requested.
  • the porous (spongy) structure is ensured with the use of a chemical, which is called azodicarbonamide, added into the PVC (polyvinyl chloride).
  • azodicarbonamide a chemical, which is called azodicarbonamide
  • PVC polyvinyl chloride
  • the artificial leather which is produced using this production method, causes contamination of the air through evaporation of the azodicarbonamid during the drying process, as well as contamination of the ecological system by the dangerous components contained in PVC (polyvinyl chloride), plasticizers and other auxiliary chemicals.
  • PVC polyvinyl chloride
  • the artificial leather developed by this invention is produced by using the intermediate product
  • this method gains the artificial leather produced by the said method with the characteristics having natural leather texture and outlook that is different from the known artificial leathers.
  • FIGURE 1 Production Process for the Polyurethane Semi Finished Product Required for Creation of a Porous (Spongy) Layer (Coagulation Production Process) (the Known Technique)
  • FIGURE 2 Production Process of the Semi Finished Product Produced with Porous (Spongy) Layer (Coagulated Product) through Polyurethane Coating (the Known Technique)
  • FIGURE 3 Production Process for the Products with Porous (Spongy) Layer by Coating Textile Textures with PU (polyurethane) and PVC (polyvinyl chloride) (the
  • FIGURE 4 Production of Semi Finished Product (Intermediate Product) Obtained Using Water Based Chemicals Churned with Air
  • FIGURE 5 Polyurethane Coating of the Semi Finished Product (Intermediate Product) with Semi Finished Porous Layer Obtained Using Water Based Chemicals Churned with Air
  • FIGURE 6 Cross Section of the Foam Machine Definition of the Elements (Features/ Components/Parts) on the Figures
  • the mixture which is prepared with water based polyurethane and/or acrylic, latex, dye and other auxiliary chemicals put into the mixing chamber (6) within the unit, is taken into the foam machine (11) through internal suction pump (7). Air is pumped to this mixture within the foam machine (11), in required amounts, from the internal air pump (8), and it is churned through mixing by the mixer (9). This churned mixture is, then, sent to the dipping tank (4.3) or Semi Finished Product Production Scraping Blades (4.5 or 4.7), whichever is preferred, through the drain pump (10). After the churned mixture is used for dipping or coating with at least one blade onto the textile texture (woven, knitted, nonwoven, etc.) and dried, we acquire the water based semi finished product (intermediate product) (4.10) required for coating procedure.
  • cooling cylinders (4.9) start working to cool the water based semi finished product (4.10) coming out of the 2 nd furnace (4.8) hot, and prevent potential problems in hot winding.
  • the patterned carrier paper (5.1) is coated with water or solvent based polyurethane and other auxiliary chemicals in preferred thickness and weight in grams through the polyurethane coating production 1 st coating blade (5.3), and the polyurethane coating production is dried in the 1 st furnace (5.4).
  • the carrier paper with chemicals leaves the polyurethane coating production 2 nd furnace (5.6) after completion of the drying procedure, comes to the polyurethane coating production 3 rd furnace (5.7), and is coated with water or solvent based polyurethane and other auxiliary chemicals in preferred thickness and weight in grams.
  • This coating procedure is done with at least one blade.
  • the drying procedures can also be realized in one or more furnaces according to the number of blades used.
  • the patterned carrier paper (5.1) is adhered through the texture unit (5.8) to the semi finished product (intermediate product) (4.10) with water based porous layer obtained through production with water based chemicals, and dried in polyurethane coating production 3 rd furnace (5.9).

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
PCT/TR2009/000123 2008-10-17 2009-10-05 Process for producing artificial leather WO2010044761A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2008/07824 2008-10-17
TR2008/07824A TR200807824A1 (tr) 2008-10-17 2008-10-17 Gözenekli (süngerimsi) tabaka oluşturma prosesi ve bu prosese göre üretilmiş suni deri.

Publications (1)

Publication Number Publication Date
WO2010044761A1 true WO2010044761A1 (en) 2010-04-22

Family

ID=41720637

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/TR2009/000123 WO2010044761A1 (en) 2008-10-17 2009-10-05 Process for producing artificial leather

Country Status (2)

Country Link
TR (2) TR200807824A1 (tr)
WO (1) WO2010044761A1 (tr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102418284A (zh) * 2011-09-02 2012-04-18 福建宝利特集团有限公司 一种水性聚氨酯合成革贝斯的制备方法
CN103993486A (zh) * 2014-05-26 2014-08-20 合肥市科天化工有限公司 一种水性聚氨酯墙体革的制备方法
WO2021001070A1 (en) 2019-07-02 2021-01-07 Kvadrat A/S Artificial leather product and process for producing same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003004760A1 (en) * 2001-07-06 2003-01-16 C & Et Co.,Ltd Method for manufacturing artificial leather
EP1279762A2 (en) * 2001-07-23 2003-01-29 Koatsu Cloth Co., Ltd. Sheet structure for leather-like material with surface structure and method for manufacturing the same
US20030204942A1 (en) * 2002-03-11 2003-11-06 Wang Ching Tang Artificial leather composite reinforced with ultramicrofiber nonwoven fabric
US20070281147A1 (en) * 2006-06-06 2007-12-06 San Fang Chemical Industry Co., Ltd. Method of producing artificial leather and artificial leather
US20080145613A1 (en) * 2006-12-13 2008-06-19 Chung-Chih Feng Extensible artificial leather and method for making the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003004760A1 (en) * 2001-07-06 2003-01-16 C & Et Co.,Ltd Method for manufacturing artificial leather
EP1279762A2 (en) * 2001-07-23 2003-01-29 Koatsu Cloth Co., Ltd. Sheet structure for leather-like material with surface structure and method for manufacturing the same
US20030204942A1 (en) * 2002-03-11 2003-11-06 Wang Ching Tang Artificial leather composite reinforced with ultramicrofiber nonwoven fabric
US20070281147A1 (en) * 2006-06-06 2007-12-06 San Fang Chemical Industry Co., Ltd. Method of producing artificial leather and artificial leather
US20080145613A1 (en) * 2006-12-13 2008-06-19 Chung-Chih Feng Extensible artificial leather and method for making the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102418284A (zh) * 2011-09-02 2012-04-18 福建宝利特集团有限公司 一种水性聚氨酯合成革贝斯的制备方法
CN103993486A (zh) * 2014-05-26 2014-08-20 合肥市科天化工有限公司 一种水性聚氨酯墙体革的制备方法
WO2021001070A1 (en) 2019-07-02 2021-01-07 Kvadrat A/S Artificial leather product and process for producing same

Also Published As

Publication number Publication date
TR201103546T2 (tr) 2012-02-21
TR200807824A1 (tr) 2010-05-21

Similar Documents

Publication Publication Date Title
CN101545212A (zh) 耐水解合成革及其制造方法
CN102234935B (zh) 防污pu合成革的制造方法
CN103015185B (zh) 耐磨超细纤维绒面革及其制备方法
CN102797167B (zh) 具有定向绒毛效果的超纤绒面革的制备方法
CN104328690A (zh) 一种导热型聚氨酯合成革的生产方法
CN110670374B (zh) 水性超柔服装生态合成革的制备工艺
CN102234937A (zh) 仿头层皮超纤合成革生产工艺
CN85108817A (zh) 织物透湿防水涂料
WO2010044761A1 (en) Process for producing artificial leather
CN105002742A (zh) 环保型阻燃超纤革的制备方法
CN105332288A (zh) 鞋革制作工艺及其配方
CN110670373A (zh) 无氟环保型运动鞋材合成革生产工艺
CN104674564B (zh) 一种无折痕合成革的生产方法
CN1188566C (zh) 作为无衬里的鞋帮的带涂层非织造织物
JPWO2017082273A1 (ja) 人工皮革基材、人工皮革及びその製造方法
CN106319985A (zh) 真空吸制备真皮感超纤材料及制品的制备工艺
CN112301752A (zh) 水性压花服装革制备工艺
CN103572614B (zh) 手球革制作方法
CN1766225A (zh) 染色布帛的制造方法及染色布帛
CN101760969B (zh) 一种牛巴革生产方法
CN105386203A (zh) 易裁剪尼龙商标布及其制备方法
CN107524014A (zh) 用于化妆品粉扑的海绵片及其制造方法
CN114211848B (zh) 一种防水透湿复合布的制备方法
CN108914620A (zh) 一种足球用环保超纤革及其制备方法
SE429559B (sv) Forfarande for framstellning av naturleder med harbeklednad

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09737196

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2011/03546

Country of ref document: TR

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 09737196

Country of ref document: EP

Kind code of ref document: A1