WO2009150745A1 - 吸水速乾性織編物 - Google Patents
吸水速乾性織編物 Download PDFInfo
- Publication number
- WO2009150745A1 WO2009150745A1 PCT/JP2008/060875 JP2008060875W WO2009150745A1 WO 2009150745 A1 WO2009150745 A1 WO 2009150745A1 JP 2008060875 W JP2008060875 W JP 2008060875W WO 2009150745 A1 WO2009150745 A1 WO 2009150745A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- knitted fabric
- water
- sheath
- woven
- streak
- Prior art date
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/12—Hygroscopic; Water retaining
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/60—Moisture handling or wicking function
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3065—Including strand which is of specific structural definition
- Y10T442/3089—Cross-sectional configuration of strand material is specified
- Y10T442/3098—Cross-sectional configuration varies longitudinaly along the strand
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/425—Including strand which is of specific structural definition
- Y10T442/431—Cross-sectional configuration of strand material is specified
Definitions
- the present invention relates to a woven or knitted fabric containing polyester fibers and excellent in water absorption and quick drying.
- the cloth for clothing used for sports clothes, underwear, etc. Especially when worn, the cloth feels sticky when the entire cloth gets wet due to sweat, or sweat due to poor drying. Since there is a feeling of cooling later and an unpleasant feeling is felt, improvement in comfort at the time of wearing is demanded.
- JP 2005-200809 A discloses a method for imparting a hydrophilic agent to a fiber having a large number of streak-like pores oriented in the fiber axis direction on the fiber surface.
- this method has a problem that although water absorption is improved, water absorption performance is lowered by washing.
- the performance of the hydrophilic agent is greatly deteriorated by high-temperature washing, and a texture with a firm feeling cannot be obtained due to the influence of the hydrophilic agent application.
- polyester woven and dyed products are washed not only at home, but also at high temperatures in Europe and the United States, and at high temperatures as represented by linen supplies.
- a dyed product that exhibits sufficient water absorption, excellent water absorption and quick drying performance, and has a soft and firm feel, and excellent dyeing fastness.
- An object of the present invention is to provide a woven or knitted fabric containing polyester fibers and having excellent water absorption and quick drying. In particular, it is excellent in the durability of water absorption and quick-drying performance by high-temperature washing, maintains a soft and soft texture, has excellent dyeing fastness, and has a good feeling of wear, and dyed water absorption speed.
- An object is to provide a method for producing a dry woven or knitted fabric.
- the inventor of the present invention has a specific amount of polyethylene glycol in the sheath portion of the polyester fiber in the woven or knitted fabric including the polyester fiber having a sheath core structure with an irregular cross section having one or more recesses. It is found that an excellent water-absorbing quick-drying woven or knitted fabric can be obtained by forming specific streak grooves along the fiber axis direction of the polyester fiber surface by subjecting to alkali weight reduction treatment under specific conditions. It came to make this invention.
- the present invention is as follows.
- a water-absorbing quick-drying woven or knitted fabric comprising 20 wt% or more of a sheath-core polyester fiber that satisfies the following requirements (1) to (4): (1) A modified cross-section fiber having one or more recesses in a single yarn cross section. (2) The sheath contains polyethylene glycol and the sheath / core weight ratio is 20/80 to 50/50.
- the amount of polyethylene glycol in the sheath-core polyester fiber is 0.1 to 1.0 wt%.
- a long streak groove A and a short streak groove B are mixed along the fiber axis direction, the length of the streak groove A is 30 ⁇ m or more, and the length of the streak groove B is 15 ⁇ m or less. It is.
- a woven or knitted fabric containing at least 20 wt% of sheath-core polyester fiber satisfying the following (5) to (7) is reduced by 2 to 15% at a temperature of 100 ° C. or lower using an alkaline aqueous solution containing alkylbenzyldimethylammonium chloride.
- a modified cross-section fiber having one or more recesses in a single yarn cross section contains 0.4 to 4.0 wt% of polyethylene glycol.
- the sheath / core weight ratio is 20/80 to 50/50.
- the present invention is a water-absorbing quick-drying woven or knitted fabric comprising a sheath-core type polyester fiber having an odd-shaped cross section having one or more recesses and a sheath-core structure, and containing a specific amount of polyethylene glycol in the sheath portion of the sheath-core type polyester fiber And a water-absorbing quick-drying woven or knitted fabric in which specific streak-like grooves parallel to the fiber axis direction are formed on the surface of the sheath-core polyester fiber by performing an alkali weight loss treatment under specific conditions.
- the water-absorbing quick-drying woven or knitted fabric of the present invention does not particularly use a hydrophilic agent such as a known hydrophilic polyester resin, hydrophilic polyamide resin, hydrophilic polyurethane resin or hydrophilic polyacrylic resin in the dyeing process. Even in this case, excellent water-absorbing quick-drying property and washing durability can be obtained.
- a hydrophilic agent such as a known hydrophilic polyester resin, hydrophilic polyamide resin, hydrophilic polyurethane resin or hydrophilic polyacrylic resin in the dyeing process. Even in this case, excellent water-absorbing quick-drying property and washing durability can be obtained.
- the strip-shaped groove A having an elongated shape is effective, and in order to exert this effect to the maximum, the stripe-shaped groove A is formed in the recess of the concave portion on the surface of the single yarn or in the vicinity thereof. Preferably it is present. Due to this presence, the effect of quickly sucking and transporting moisture (pumping effect) is exhibited as if it were an action of a spider.
- the short streak-like grooves B are present around the recesses, so that the moisture can be quickly diffused and spread throughout the knitted and knitted fabric as if it were an action of a capillary tube. To do. In order to exhibit the above-described effect more effectively, it is preferable that 20 or more streak-like grooves B are formed on average in a length of 30 ⁇ m in the fiber axis direction.
- the sheath of the sheath-core polyester fiber contains polyethylene glycol that is incompatible with polyester, and the number average molecular weight of polyethylene glycol is preferably 4000 to 50000.
- the sheath-core polyester fiber has an atypical cross section having one or more recesses in the single yarn cross section, and the sheath It is essential that the weight ratio of the part / core part is 20/80 to 50/50. This further enhances the synergistic effect of the single yarn shape having one or more recesses and the streaky grooves A and B of the surface layer, and has excellent water absorption that has never been achieved without the addition of a hydrophilizing agent. Quick drying performance and washing durability can be exhibited.
- the polyester fiber refers to a fiber composed of a polymer in which at least 90 mol% is ethylene terephthalate. Therefore, the fiber which consists of a polyethylene terephthalate in which the total amount of another acid component and / or glycol component contained in the range of 10 mol% or less is included as a 3rd component.
- the third component includes polyethylene glycol, adipic acid, isophthalic acid, isophthalic acid containing a sulfonic acid metal salt, and the like.
- Polyester fibers also include trimethyl phosphate, triethyl phosphate, tributyl phosphate, triphenyl phosphate, trimethyl phosphite, triethyl phosphite, triphenyl phosphite, phosphoric acid, phosphorous acid, etc. to improve hue and heat resistance May be added in a range of 0.001 to 2 wt%, preferably 0.02 to 1 wt% with respect to the polyester fiber.
- a cobalt compound such as cobalt acetate and cobalt formate, a commercially available fluorescent whitening agent, and the like are added as a color inhibitor in a range of 0.0001 to 0.1 wt% with respect to the polyester fiber. Also good.
- the sheath-core polyester fiber is a modified cross-section fiber having one or more recesses, and the weight ratio of the sheath / core is 20/80 to 50/50.
- the weight ratio of the sheath / core is 20/80 to 50/50, it is preferable for forming the elongated streak-like groove (strip-like groove A, streak-like groove B) continuous in the recess or around the recess. .
- the pumping effect related to moisture transport is enhanced.
- the weight ratio of the sheath portion / core portion is within the above range, a decrease in the yarn strength due to the alkali weight loss treatment is suppressed.
- the sheath / core weight ratio is smaller than 20/80, the spinning yield will be poor and the dispersion of polyethylene glycol in the polyester will be poor. It becomes difficult to obtain long continuous streak-like grooves.
- the weight ratio of the sheath part / core part exceeds 50/50, the decrease in the raw yarn strength due to the alkali weight loss treatment increases, and the burst strength of the woven or knitted fabric decreases.
- the sheath / core weight ratio is preferably 25/75 to 40/60.
- a plurality of streak-like grooves A and streak-like grooves B are formed on the fiber surface along the fiber axis direction by subjecting the sheath-core type polyester fiber having an irregular cross section having one or more recesses to an alkali weight reduction treatment.
- the sheath part contains polyethylene glycol incompatible with polyester.
- the polyethylene glycol used preferably has a number average molecular weight of 4,000 to 50,000, more preferably a number average molecular weight of 6,000 to 30,000. If the number average molecular weight is less than 4000, the kneadability with the polyester is too good, and there is a tendency that it is difficult to take a streak-like dispersion state in the polyester matrix. There is a tendency for the formation of long, continuous streak grooves to be insufficient. On the other hand, when the number average molecular weight exceeds 50,000, the melt viscosity is high, so that it is difficult to melt and add to the polyester, and the yarn-making property tends to be poor.
- the polyethylene glycol content in the sheath is preferably 0.4 to 4.0 wt%.
- the recess or the streak groove is sufficiently formed in the periphery thereof by the alkali weight reduction treatment, so that excellent water absorption quick drying performance and washing durability can be obtained.
- the sheath-core type polyester fiber having a different cross-sectional shape having at least one can be spun at a good yield, and a textured feel fiber can be obtained.
- the content of polyethylene glycol is preferably in the range of 0.1 to 1.0 wt%, more preferably 0.2 to 0.9 wt%, with respect to the sheath-core polyester fiber.
- the method for mixing polyethylene glycol with polyester is not particularly limited, and any conventionally known method such as mixing at the polymerization stage, chip blending, melt kneading, etc. can be employed.
- a long streak groove A and a short streak groove B are mixed along the fiber axis direction.
- the streak-like groove B has a length of 15 ⁇ m or less, preferably 10 ⁇ m or less.
- the streak-like groove B preferably has a P of 50 or less, more preferably 20 to 50, and is preferably formed in an average of 20 or more in a length of 30 ⁇ m in the fiber axis direction. The range is preferably 20 to 100.
- a sheath-core type polyester fiber having a modified cross section containing polyethylene glycol in the sheath and having one or more recesses in the single yarn cross section will be described later. It is important to reduce the amount by 2 to 15% by alkali weight reduction treatment.
- the formation state of the streak groove can be controlled by the conditions of alkali weight loss treatment, the structure of the atypical cross section, the weight ratio of the sheath / core, the type and amount of polyethylene glycol contained in the sheath.
- a hydrolysis accelerator having a high affinity for polyester fibers is used as an auxiliary agent during the alkali weight reduction treatment, long streak grooves A are mainly formed in the recesses and short streak grooves B are formed around the recesses. This tendency becomes remarkable.
- the weight loss rate by the alkali weight reduction treatment is less than 2%, not only the length of the continuous long streak groove A formed around the recess or the periphery of the recess becomes less than 30 ⁇ m, but P becomes less than 75, and the absorbed moisture In addition, since a predetermined number of short streak grooves B are not formed, the water diffusibility is poor and the water absorption and quick drying performance is lowered.
- the long streak groove A and the short streak groove B both have a large groove width and a specific surface area as described in the examples.
- the water retention capacity is increased and the diffusibility of the absorbed water is deteriorated.
- the water retaining ability is high, there is a problem that when washing is actually performed, the spin-off dewatering rate is deteriorated and the drying speed is slow in the dewatering after washing.
- FIG. 1 shows the relationship between the specific surface area and the water-absorbing quick-drying property based on the example of the present invention.
- the specific surface area has an appropriate range, and the specific surface area is preferably in the range of 0.3 to 0.6 m 2 / g, more preferably 0.4 to 0.5 m 2 / g.
- the specific surface area is in the above range, excellent dehydration quick-drying properties are obtained, and the effects of the present invention are effectively exhibited.
- the alkali concentration, alkylbenzyldimethylammonium chloride concentration, treatment temperature, treatment time, etc. in the alkali weight loss treatment are appropriately selected. Is possible. Specifically, in the alkali reduction treatment, the alkali concentration is 2 to 8 g / liter, the alkylbenzyldimethylammonium chloride concentration is 0.25 to 2 g / liter, the treatment temperature is 90 to 100 ° C., and the treatment time is 5 to 40 minutes. preferable.
- the shape of the streak-like groove A and the streak-like groove B is within the range defined in the present invention, excellent water-absorbing quick-drying property and washing durability can be obtained.
- water-absorbing and quick-drying laundry durability not only the durability in home laundry that is washed with warm water from room temperature, but also high-temperature laundry that is performed at 80 ° C high-temperature laundry and linen supply as is done in European and American homes Excellent durability.
- the water drop disappearance time after washing 30 times at 80 ° C. is preferably 10 seconds or less, more preferably 5 seconds or less.
- the water-absorbing drying property after washing 30 times at 80 ° C. is preferably 20 minutes or less, more preferably 18 minutes or less.
- the water-absorbing diffusion area after washing 30 times at 80 ° C. is 10 cm 2 or more, more preferably 12 cm 2 or more.
- the water absorption drying property and the washing durability thereof are improved.
- the reason is that the streak-like grooves are not present over the entire fiber surface, but are present in the recesses or the periphery of the recesses, so that the fiber surface is excellent in abrasion resistance.
- both the streak-like grooves B are not fibrillated and the shape of the streak-like grooves is maintained without being damaged.
- the single yarn of the sheath-core type polyester fiber has a modified cross-sectional shape having one or more recesses.
- the irregular cross-sectional shape may be a polygonal shape such as an L shape, a T shape, a W shape, an M shape, a V shape, an X shape, a Y shape, a cross shape, or an eight leaf shape, or an irregular shape.
- the thread may have slits or fine holes with an angle.
- the number of recesses is, for example, 2 for the T type, 3 for the W type, and 4 for the X type.
- the fiber has an atypical cross-sectional shape having one or more recesses, the recesses and protrusions of the fiber cross section are entangled and the fibers are easily joined to each other. It is formed and exhibits the effect of improving water absorption and water conductivity by vigorous capillary action.
- the shape of the irregular cross section of the single yarn may be one having a flatness of 1.1 to 5 and having one or more recesses, or the opening angle of the recesses in the corrugated flat cross section Preferably have at least one recess of 60 to 160 degrees.
- a W-shaped flat cross section having three concave portions in which the flatness of the single yarn is 2 to 5 and the opening angle of the concave portion is in the range of 100 to 150 degrees is also preferable from the surface of the hand.
- An example of a W-shaped flat cross section is shown in FIG.
- the thickness of the three sheaths of the recess may be not only uniform as shown in FIG. 2 but also non-uniform.
- the concave portion tends to be thinner in the sheath than other places, and when the concave portion is relatively thin, continuous elongated stripe-like grooves such as stripe-like grooves A and stripe-like grooves B are formed more. Easy to be.
- the cross-sectional shape of the single yarn is W-type
- the flatness of the single yarn is as large as 3 to 5, and it is easy to obtain a texture with a soft feeling as defined in the present invention.
- the cross-sectional shape is W-type
- the specific surface area is large, so the efficiency of the alkali weight reduction treatment is increased, and the streak-like grooves A and streak-like grooves B are easily formed around the recesses.
- the streak-like groove A and the streak-like groove B are preferably formed in all three of the recesses, but if they are present in at least one recess, the object of the present invention is sufficiently achieved.
- the fineness of the sheath-core polyester fiber used in the present invention is not particularly limited, but the total fineness is preferably 30 to 250 dtex.
- the form of the fiber may be long fiber or short fiber, and may be uniform or thick in the length direction.
- Examples of the form of the yarn from which the fiber is processed include, for example, spun yarn such as ring spun yarn, open-end spun yarn, air jet spun yarn, sweet twisted yarn to strongly twisted yarn, false twisted yarn (POY drawn false twisted yarn) Air injection processed yarn, indented processed yarn, knitted knitted yarn, and the like.
- the woven or knitted fabric of the present invention contains 20% by weight or more of sheath-core polyester fiber. If the sheath-core polyester fiber is less than 20%, the washing durability of the water-absorbing quick-drying performance is deteriorated.
- the woven or knitted fabric made of 100% sheath-core polyester fiber has excellent water absorption and diffusibility, but there is a problem that sebum stains when worn, stains such as hand stains, stains when washing, etc. are likely to occur. Since the water holding power as a whole of the woven or knitted fabric becomes high, the water absorption and drying speed after washing decreases, and a soft and firm texture cannot be obtained.
- the upper limit of the content of the sheath-core type polyester fiber is preferably 60 wt% or less from the viewpoint of washing durability with water absorption and quick drying performance, drying speed in practical washing, cost, texture, and the like.
- it does not specifically limit as another fiber mixed with the sheath core type polyester fiber used for this invention For example, it is possible to mix a non-sheath core type polyester fiber, spandex, polyamide, a cellulose fiber, etc.
- Non-sheath core type polyester fibers that can be used in combination include polyester multi yarn, high strength polyester yarn, easily dyeable polyester fiber, polytrimethylene terephthalate fiber, etc. It can be preferably used.
- high-strength polyester yarns and polytrimethylene terephthalate fibers are particularly preferable mixed materials because the weight reduction rate due to alkali is extremely slow. This is because when these fibers are mixed, streak-like grooves can be preferentially formed on the surface of the sheath-core type polyester fiber used in the present invention by the alkali weight loss treatment.
- the form of the mixed article of the sheath-core type polyester fiber and other fibers may be a yarn form or a woven or knitted form.
- Examples of yarn forms include blended yarn (blended cotton, fleece blended, sliver blended, core yarn, silo span, silofill, hollow spindle, etc.), entangled blended yarn, twisted yarn, design twisted yarn, covering (single, double), composite temporary Examples include twisting (simultaneous false twisting, first twist false twisting), elongation difference false twisting, phase difference false twisting, mixed fiber after false twisting, and two-feed (simultaneous feed or feed difference) air injection machining.
- the form of the woven or knitted fabric there is a general knitting knitting.
- a method in which the fibers are aligned and fed a double knitted fabric (for example, a double circular knitting machine, a double flat knitting) Machine, a double raschel warp knitting machine), and a method of supplying yarns by feeding or aligning the fibers on the front surface and / or back surface.
- a double knitted fabric for example, a double circular knitting machine, a double flat knitting) Machine, a double raschel warp knitting machine
- a method of supplying yarns by feeding or aligning the fibers on the front surface and / or back surface In the cross weaving, one fiber is used as a warp, the other fiber is used as a weft, or one to three warps and / or wefts are alternately arranged with warp and weft.
- the woven or knitted fabric containing the sheath-core polyester fiber is reduced with a weight loss rate of 2 to 15% using an alkaline aqueous solution.
- Alkali weight loss treatment may be performed before or after the steps such as scouring, relaxing, and presetting. In the alkali weight loss treatment, hanging weight loss and batch weight loss using a liquid dyeing machine are preferable.
- the present invention it is important to form streak-like grooves at a reduced rate only on the fiber surface of the sheath-core type polyester fiber in order to obtain a firm feeling. If the weight loss rate due to the alkali weight loss treatment is too high, the amount of polyester fiber to be mixed is greatly reduced, and a crater-like groove is formed on the fiber surface, resulting in a decrease in tear strength and burst strength as a fabric, water absorption quick drying performance However, the durability to washing is not improved, and a firm texture is not obtained.
- a low-concentration aqueous alkali solution such as sodium hydroxide or potassium hydroxide in order to keep the weight loss rate of the mixed polyester fibers small.
- a low concentration alkaline aqueous solution treatment with an alkaline aqueous solution containing alkylbenzyldimethylammonium chloride is performed. It is important to.
- Alkylbenzyldimethylammonium chloride acts as a phase transfer catalyst and binds to a hydrophilic alkali agent such as sodium hydroxide to accelerate the hydrolysis reaction of the polyester fiber.
- Alkylbenzyldimethylammonium chloride has a high affinity for polyester fibers, and the binding agent with an alkali agent is particularly attracted to the recesses of the recesses, so that the reaction around the recesses is selectively promoted.
- Long streak-like grooves A are easily formed around the periphery, and short streak-like grooves B are easily formed around the recesses.
- the weight loss rate in the alkali weight loss treatment can be easily controlled in the range of 2% to 15%, and the streak groove A and streak groove B can be easily formed. it can. Further, since it is possible to perform alkali weight reduction treatment at a low alkali concentration, the polyester fiber to be mixed is not excessively reduced, so that a woven or knitted fabric with a soft and firm feel can be obtained.
- alkylbenzyldimethylammonium chloride a compound having an alkyl group of C12 to C18 can be used.
- Specific examples of the compound having a C12 lauryl group include DYK-1125 (manufactured by Yushi Co., Ltd.).
- Specific examples of the compound having a C18 stearyl group include DXK-10N (one company, Yushi Co., Ltd.). Manufactured).
- the use concentration of alkylbenzyldimethylammonium chloride is preferably in the range of 0.25 to 2.0 g / liter. If the concentration used is less than 0.25 g / liter, the intended elongated continuous streak groove may not be formed in the recess of the recess or its periphery, and there is variation in the formation of the streak groove between the single yarns. Large, it is difficult to obtain the streak-like groove A and the streak-like groove B defined in the present invention, so that there is a tendency that the washing durability of the water absorption quick-drying performance becomes insufficient. On the other hand, when the use concentration is higher than 2.0 g / liter, the hydrolysis reaction is excessively promoted, and it tends to be difficult to control to a desired weight loss rate.
- the concentration of the alkaline aqueous solution is 2 to 8 g / liter because the weight loss rate can be easily controlled.
- the treatment temperature is 100 ° C. or lower, preferably 95 ° C., and the treatment time is preferably in the range of 5 to 60 minutes.
- the range of the weight loss rate in the alkali weight loss treatment is 2 to 15%.
- the weight loss rate is less than 2%, the formation of the streak groove is insufficient, the streak groove A and the streak groove B defined in the present invention cannot be obtained, and the washing durability of the water absorption quick-drying performance is insufficient. It becomes.
- the weight loss rate exceeds 10%
- the width of the streak groove becomes large
- the water retention power increases, and the water absorption and quick drying performance tends to decrease.
- the weight loss rate exceeds 15%, fibrillation due to single yarn breakage and accompanying deterioration in the appearance quality of the knitted or knitted fabric and reduction in bursting strength may occur, resulting in not only a firm feeling but also a stain. There is also a problem that is easily attached.
- the polyester knitted fabric has good water absorption quick-drying performance and washing durability, and has a soft and firm feel. It becomes possible to grant.
- the dyeing conditions for dyeing polyester fibers with disperse dyes are usually applicable.
- Types of dyeing assistants and their concentrations, dyeing pH, dyeing bath ratio, dyeing time, etc. May be set as appropriate in consideration of the type of article to be dyed, the dyeing apparatus used, and the dyeing method.
- azo disperse dyes represented by benzeneazo (monoazo, disazo, naphthaleneazo) and heterocyclic azo (thiazoleazo, benzothiazoleazo, quinolineazo, pyridoneazo, imidazoleazo, thiophenazo, etc.) It is preferable for improving color reproducibility and dyeing fastness.
- a disperse dye having a diffusion index of 3.0 or more because color variation among dyeing batches is reduced.
- the dyeing temperature is preferably 135 ° C. or lower, and the dyeing operation can be carried out by either a batch method or a continuous method using an apparatus such as a wins, a jigger, a beam dyeing machine or a liquid dyeing machine. In addition to dip dyeing, it can also be dyed by a padding dyeing method or a printing method.
- a reducing agent sodium hydrosulfite and thiourea dioxide are preferable, and as the alkali agent used in combination, an alkali metal hydroxide such as sodium hydroxide and an alkali metal carbonate such as sodium carbonate can be preferably used.
- finishing may be performed according to a conventional method, but a preferable result is obtained when the final set temperature is set at 160 ° C. or lower.
- any of those usually used for polyester fibers can be used, but among them, core-corona type fine particles composed of styrene-PEG 4000 (particle size distribution: 90 to 200 nm). Can be preferably used because it covers the entire surface of the sheath-core polyester fiber used in the present invention and further enhances the hygroscopicity and water absorption.
- the woven or knitted fabric dyed in this way has a soft and firm texture, exhibits excellent water-absorbing quick-drying properties and washing durability, and is excellent in wearing comfort and fastness performance. It is good. Specifically, a dyed woven or knitted fabric with a sweat alkali fastness of 3 or more in JIS-L-0848 A method and high commercial value can be obtained.
- the water-absorbing quick-drying woven or knitted fabric of the present invention contains a sheath-core type polyester fiber having specific streak-like grooves A and streak-like grooves B, so that when it is worn as a garment, it does not become sticky and feels smooth. As a result, the evaporation of sweat is promoted to dry quickly, so that excellent wearing comfort is obtained, and the water-absorbing quick-drying property is excellent in durability by washing, and is retained even after repeated washing at high temperature.
- the lysate was centrifuged and the supernatant was measured.
- the content rate was calculated
- Washing method The knitted and knitted fabric was subjected to 30 times using an aqua dry washing machine (manufactured by Electroux-Wascator), with a cycle according to the following conditions set as one wash. Washing conditions: Synthetic detergent (Kao Attack) 2g / liter, bath ratio 1:20, washed at 80 ° C for 30 minutes and dehydrated, then washed at 40 ° C for 5 minutes and then dehydrated. It was washed with water at 10 ° C. for 10 minutes, dehydrated, and dried at 70 ° C. for 30 minutes.
- Water-absorbing diffusion area A woven or knitted fabric is attached to a 15 cm diameter embroidery round frame, and 0.1 ml of a water-soluble blue dye solution (containing 0.005 wt% of CI Acid Blue 62) is dropped on the surface of the woven or knitted fabric.
- the water-absorbing diffusion area that spreads after 3 minutes. Obtained from the following equation.
- Water absorption diffusion area (cm 2 ) [vertical diameter (cm) ⁇ horizontal diameter (cm)] ⁇ ⁇ ⁇ 4 Measurement was performed 5 times for each sample, and the water absorption and diffusion area was determined from the average of 5 times.
- Examples 1 to 3 4 wt% polyethylene glycol with a number average molecular weight of 20000 is contained in the sheath portion with respect to polyethylene terephthalate A containing 2.0 wt% titanium oxide and having an intrinsic viscosity [ ⁇ ] of 0.60 (measured in orthochlorophenol at 1 wt%).
- Polyethylene terephthalate A was used for the core.
- both were extruded using two extruders so that the sheath / core weight ratio was 30/70, and the spinning temperature (spin head temperature) 290 was obtained from a nozzle having 36 spinning holes perforated in a W shape.
- Extrusion was performed at a temperature of 2000 ° C. and a spinning speed of 2000 m / min.
- the filament is heated with a first drawing roll at 90 ° C., heat set with a second drawing roll at 130 ° C., and drawn so that the elongation becomes 30 to 40%.
- a stretched yarn of 84 dtex / 36 filaments having a letter-shaped cross section was obtained (3 recesses, 130 ° opening angle inside recess, flatness 3.5, strength 3.7 cN / dtex, elongation 38%).
- the obtained sheath-core polyester yarn having a W-shaped cross section was false twisted by a conventional method using a two-heater false twister to obtain false twisted yarn.
- a smooth knitted fabric was prepared under normal knitting conditions with a 28 gauge, 33 inch knitting machine. .
- the mixture ratio of the sheath-core type polyester fiber was 39.1 wt%, and the basis weight was 210 g / m 2 .
- This knitted fabric was scoured at 80 ° C. and pre-set at 190 ° C., and then the treatment time was adjusted to the weight loss rate shown in Table 1-1 under the conditions shown below. The alkali weight loss treatment was performed.
- Alkali Sodium hydroxide; 4 g / liter Laurylbenzyldimethylammonium chloride: DYK-1125 (manufactured by Yushi Kogyo Co., Ltd.); 1.2 g / liter bath ratio; 1:40 Processing temperature: 95 ° C
- Dye Dianix Blue S-2R (Dystar); 1.5% omf Auxiliary agent: Nikka Sun Salt RM-340 (manufactured by Nikka Chemical Co., Ltd.); 0.5 g / liter Acetic acid: 0.5 cc / liter Sodium acetate: 1 g / liter Bath ratio; 1:25 Dyeing temperature and time: 130 ° C, 30 minutes
- the dyeing residual liquid is discharged from the dyeing machine, water is added to the dyeing machine, the temperature is raised to 80 ° C., the following chemicals are added thereto, and a reducing cleaning bath having the following concentration is prepared, Reduction cleaning was performed at 80 ° C. for 20 minutes.
- the dyed product was rinsed with warm water and water, dehydrated and dried, and then set by dry heat at 130 ° C. for 45 seconds to finish.
- Table 1-2 shows the evaluation results of water droplet disappearance time, water absorption diffusion area, water absorption drying property, texture, and sweat alkali fastness of the finished dyed knitted fabric.
- Table 1-1 shows the shapes of the streak-like groove A and streak-like groove B on the surface of the sheath-core polyester fiber when the obtained dyed knitted fabric is observed with an electron microscope at a magnification of 1800 times.
- Comparative Examples 1 to 3 As Comparative Example 1, the knitted fabric of Example 1 was dyed and finished under the same conditions as in Example 1 without performing the alkali weight loss treatment.
- Comparative Example 2 instead of the sheath-core type polyester fiber, 84 decitex / 36 filament polyester fiber having W-shaped cross section (trade name; Technofine, concave opening angle 130 degrees, flatness 3) 0.0 semi-dial yarn), a smooth knitted fabric is prepared, alkali weight reduction treatment is performed so that the weight loss rate is 9.9%, and water-soluble polyester resin [SR-1000 (manufactured by Takamatsu Yushi)] is used at the time of dyeing. It dye
- an 84 dtex / 36 filament sheath core yarn with a round cross-sectional shape was prepared by the same spinning method as in Example 1 using the same polymer as in Example 1.
- the sheath core weight ratio at this time was 30/70.
- the obtained raw yarn was false twisted in the same manner as in Example 1.
- Smooth knitting was performed using the obtained false twisted yarn and false twisted yarn made of 84 dtex / 72-filament polyester fiber (full yarn), and the weight was reduced by 5.9% in the same manner as in Example 1. Thereafter, it was dyed and finished under the same conditions.
- Table 1-2 shows the evaluation results of water droplet disappearance time, water absorption diffusion area, water absorption drying property, texture, and sweat alkali fastness of each of the obtained dyed products.
- Table 1-1 shows the shape of the streak-like grooves A and B when observed with an electron microscope at a magnification of 1800 times.
- the dyed knitted fabrics obtained in Examples 1, 2, and 3 of the present invention were faster in water absorption and washed than the dyed knitted fabrics obtained in Comparative Examples 1, 2, and 3. It can be seen that it is a dyed knitted fabric with excellent durability and a soft and firm feel, and has a high commercial value.
- polyethylene glycol having a number average molecular weight of 15000 is contained in the sheath portion with respect to polyethylene terephthalate A containing 2.0 wt% titanium oxide and having an intrinsic viscosity [ ⁇ ] of 0.60 (measured in orthochlorophenol at 1 wt%).
- Both are extruded using two extruders so that the sheath / core weight ratio becomes 40/60, and is spun at a spinning temperature (spin head temperature) 290 from a nozzle having 36 spinning holes perforated in a W shape.
- the extrusion was performed at a temperature of 2000 ° C. and a spinning speed of 2000 m / min.
- the filament is heated with a first drawing roll at 90 ° C., heat set with a second drawing roll at 130 ° C., and drawn so that the elongation becomes 30 to 40%.
- a drawn yarn of 84 dtex / 36 filaments having a letter-shaped cross section was obtained (3 recesses, 130 ° opening angle inside recess, flatness 3.6, strength 3.7 cN / dtex, elongation 37%).
- the obtained false twisted yarn, a false twisted yarn of 84 dtex / 24 filament polyester yarn (semi-dal), and a false twisted yarn of 84 dtex / 36 filament polytrimethylene terephthalate fiber (Asahi Kasei Fibers Co., Ltd.) was used to prepare a smooth knitted fabric on a 28 gauge, 33 inch knitting machine.
- the mixture ratio of the sheath-core type polyester fiber was 38.4 wt%, and the basis weight was 240 g / m 2 .
- the knitted fabric was scoured at 80 ° C. and pre-set at 190 ° C., and then the treatment time was adjusted under the same conditions as in Example 1 so that the weight loss rate shown in Table 2-1 was obtained.
- the alkali weight loss treatment was performed with a flow dyeing machine.
- the polyethylene glycol content of the obtained knitted fabric was as shown in Table 2-1.
- dyeing and reduction washing were performed under the same conditions as in Example 1, and the dyed product was rinsed, then dehydrated and dried, and then subjected to dry heat setting at 130 ° C. for 45 seconds to finish.
- Table 2-1 shows the shape of the streak groove A and streak groove B on the surface of the sheath-core polyester fiber when the obtained dyed knitted fabric is observed with an electron microscope at a magnification of 1800 times.
- Table 2-2 shows the evaluation results of the water drop disappearance time, water absorption drying property, water absorption diffusion area, texture, and sweat alkali fastness of the obtained dyed knitted fabric.
- Comparative Example 4 As Comparative Example 4, the knitted fabric of Example 2 was dyed and finished under the same conditions without performing the alkali weight loss treatment.
- Table 2-2 shows the evaluation results of water drop disappearance time, water absorption diffusion area, water absorption drying property, texture, and sweat alkali fastness of the obtained dyed product.
- the dyed knitted fabric obtained in Examples 4, 5, and 6 of the present invention is superior in water-absorbing quick-drying property and its washing durability as compared with the dyed knitted fabric obtained in Comparative Example 4. It can be seen that this is a dyed knitted fabric that is excellent in wearing comfort, has a soft and firm feel, and has a high commercial value.
- Examples 7 and 8 4 wt% of polyethylene glycol having a number average molecular weight of 6000 is contained in the sheath portion of polyethylene terephthalate A containing 2.0 wt% of titanium oxide and having an intrinsic viscosity [ ⁇ ] of 0.60 (measured in orthochlorophenol at 1 wt%).
- % A polymer obtained by blending 50% by weight of polyester B copolymerized (polyethylene glycol content in the sheath part is 2.0% by weight), and polyethylene terephthalate A was used for the core part.
- both were extruded using two extruders so that the sheath / core weight ratio was 25/75, and the spinning temperature (spin head temperature) 290 was obtained from a nozzle having 36 spinning holes perforated in a W shape.
- Extrusion was performed at a temperature of 2000 ° C. and a spinning speed of 2000 m / min.
- the filament is heated with a first drawing roll at 90 ° C., heat set with a second drawing roll at 130 ° C., and drawn so that the elongation becomes 30 to 40%.
- a stretched yarn of 84 dtex / 36 filaments having a letter-shaped cross section was obtained (3 recesses, 130 ° opening angle inside recess, flatness 3.3, strength 3.3 cN / dtex, elongation 36%).
- the obtained sheath-core polyester having a W-shaped cross section was false twisted by a conventional method using a two-heater false twister to obtain false twisted yarn.
- the mixed rate of the sheath core type polyester fiber was 39.1 wt% on a 28 gauge, 33 inch knitting machine. The knitting conditions were adjusted so that a smooth knitted fabric was prepared. The basis weight of this knitted fabric was 220 g / m 2 .
- This knitted fabric was scoured at 80 ° C. and pre-set at 190 ° C., and then the treatment time was adjusted so that the weight loss rate shown in Table 3-1 was obtained in the same manner as in Example 1.
- the alkali weight loss treatment was performed with a dyeing machine.
- the polyethylene glycol content of each knitted fabric obtained was as shown in Table 3-1. Next, dyeing and reduction washing were performed under the same conditions as in Example 1, and the dyed knitted fabric was rinsed, then dehydrated and dried, and then set by dry heat at 130 ° C. for 45 seconds to finish.
- Table 3-1 shows the shape of the streak-like grooves on the surface of the sheath-core polyester fiber when each of the obtained dyed knitted fabrics is observed with an electron microscope at a magnification of 1800 times.
- Table 3-2 shows the evaluation results of the water drop disappearance time, water absorption diffusion area, water absorption drying property, texture, and sweat alkali fastness of each dyed knitted fabric obtained.
- Comparative Example 5 As Comparative Example 5, the knitted fabric of Example 3 was dyed and finished under the same conditions without performing the alkali weight loss treatment.
- Table 3-2 shows the evaluation results of water drop disappearance time, water absorption diffusion area, water absorption drying property, texture, and sweat alkali fastness of the obtained dyed product.
- the dyed knitted fabrics obtained in Examples 7 and 8 of the present invention are superior to the dyed knitted fabric obtained in Comparative Example 5 in water-absorbing quick-drying and washing durability. Moreover, it can be seen that this is a dyed knitted fabric having a soft and firm feeling and a high commercial value.
- the water-absorbing quick-drying woven or knitted fabric of the present invention has excellent drying properties, has no stickiness or chilliness even when the entire fabric is wet by sweat, and has excellent comfort when worn, such as sports clothing, underwear, etc. Can be suitably used.
Abstract
Description
(1)単糸断面に凹部を一個以上有する異型断面繊維である。
(2)鞘部にポリエチレングリコールを含有し、鞘部/芯部の重量比が20/80~50/50である。
(4)繊維軸方向に沿って、長い筋状溝Aと短い筋状溝Bが混在しており、筋状溝Aの長さが30μm以上であり、筋状溝Bの長さが15μm以下である。
ただし、Pは、溝の幅に対する長さの比であり、P=[長さ]/[幅]で表される。
3.鞘部にポリエチレングリコールを0.4~4.0wt%含むことを特徴とする上記1または2に記載の吸水速乾性織編物。
ただし、Pは、溝の幅に対する長さの比であり、P=[長さ]/[幅]で表される。
6.親水化剤を含まないことを特徴とする上記1~5のいずれかに記載の吸水速乾性織編物。
8.異型断面がW型であることを特徴とする上記1~7のいずれかに記載の吸水速乾性織編物。
10.織編物を80℃で30回洗濯後、吸水速乾性が20分以下であることを特徴とする上記1~9のいずれかに記載の吸水速乾性織編物。
(6)鞘部にポリエチレングリコールを0.4~4.0wt%含む。
(7)鞘部/芯部の重量比が20/80~50/50である。
本発明は、凹部を1個以上有する異型断面で且つ鞘芯構造を有する鞘芯型ポリエステル繊維を含む吸水速乾性織編物であり、鞘芯型ポリエステル繊維の鞘部に特定量のポリエチレングリコールを含有させ、特定の条件でアルカリ減量処理することで、鞘芯型ポリエステル繊維表面に、繊維軸方向に平行な特定の筋状溝を形成させた吸水速乾性織編物である。
この様に、汗をかいたときの快適性を向上させるためには、すばやく水分を吸い取って輸送する機能と、吸い取った水分をすばやく拡散させる機能という、2つの機能が同時に必要である。
従って、第三成分として、他の酸成分及び又はグリコール成分の合計量が10モル%以下の範囲で含有されたポリエチレンテレフタレートからなる繊維を包含する。例えば、第三成分としては、ポリエチレングリコール、アジピン酸、イソフタル酸、スルホン酸金属塩を含有するイソフタル酸などが挙げられる。
本発明において、ポリエチレングリコールをポリエステルと混合する方法には特に制限はなく、重合段階での混合、チップブレンド、溶融混練等、従来公知の任意の方法が採用できる。
本発明の吸水速乾性織編物において、80℃で30回洗濯後の吸水乾燥性は20分以下であることが好ましく、より好ましくは18分以下である。
本発明に用いる鞘芯型ポリエステル繊維と混用する他の繊維としては、特に限定されないが、例えば、非鞘芯型のポリエステル繊維、スパンデックス、ポリアミド、セルロース繊維等を混用することが可能である。
b 長辺
S1 筋状溝A
S2 筋状溝B
扁平度は、単糸の横断面の外接長方形の長辺bと短辺aの比で表され、次式により算出した(図2参照)。
扁平度=(長辺b)/(短辺a)
BET比表面積測定器(Mountech社製)を用い、単糸の比表面積を5回測定し、その平均値を求めた。
走査型電子顕微鏡(日立製作所製、形式S-3500N)を用いて、試料の鞘芯型ポリエステル繊維の表面を1800倍に拡大し、適宜に5ヶ所写真撮影し、スケールゲージをもとに、凹部及び凹部周辺の筋状溝の幅、長さ及び数を測定し、長さに対する幅の割合(P)、及び、繊維長30μm当りの数(個)を算出して、5ヶ所の平均値を求めた。
編地を洗濯した後、室温で24時間乾燥し、鞘芯型ポリエステル繊維を取り出し、繊維中のポリエチレングリコールの含有率を1H-NMR法により測定した。
測定装置、条件は以下の通りである。
測定装置 :日本電子社製 JNM-LA400
試料濃度 :5.0重量/vol%
測定温度 :25℃
化学シフト基準:tetramethylsilane(TMS)を0ppmとした。
積算回数 :256回
待ち時間 :2.9秒
尚、含有率は、ポリエチレングリコールのメチレン基シグナルを用いて求め、サンプル毎に測定を3回行い、その平均値を求めた。
織編物を、アクアドライ洗濯機(Electroux-Wascator製)を用い、下記条件によるサイクルを洗濯1回とし、30回行った。
洗濯条件:合成洗剤(花王製アタック)2g/リットル、浴比1:20で、80℃で30分洗濯を行い脱水した後、次いで、40℃にて水洗を5分行い脱水後、さらに、40℃にて水洗を10分行い脱水後、70℃で30分乾燥させた。
JIS-L-1097 滴下法に従って水滴消失時間を評価した。サンプル毎に5回測定を行い、平均水滴消失時間を求めた。尚、このときの水滴1滴の平均量は0.039mlであった。
織編物(10cm角)を水で十分に濡らし、脱水機にて2000rpmで1分間脱水した後、織編物の重量を測定し、水分量を算出し、次いで、温度20℃で相対湿度65%の環境下で、織編物の水分量が2%(乾いたと感じる水分量)となるまでの時間(分)を測定した。
織編物を直径15cmの刺繍用丸枠に取り付け、織編物表面に水溶性青染料溶液(C.I.アシッドブルー62を0.005wt%含有)を0.1ml滴下し、3分後に濡れ拡がった吸水拡散面積を。次式より求める。
吸水拡散面積(cm2)=[縦の直径(cm)×横の直径(cm)]×π÷4
サンプル毎に測定を5回行い、5回の平均から吸水拡散面積を求めた。
検査者(30人)によって評価した。混用染色品を10回洗濯した後、織編物の感触を、次の基準で相対評価した。
○(良好):ソフトであり、コシ感がよい
△(普通):ソフトであるが、コシ感は普通
×(不良):ソフトであるが、コシ感がない
染色品について、JIS-L-0848-A法に準じ、汗アルカリ人工汗液を用いて評価した。試験片の変褪色と添付白布片の汚染の程度を、それぞれ変褪色用グレースケール、汚染用グレースケールと比較して判定した。
鞘部に、酸化チタン2.0wt%含有し、固有粘度 [η] が0.60(オルソクロロフェノール中、1wt%で測定)のポリエチレンテレフタレートAに対して、数平均分子量20000のポリエチレングリコールを4wt%共重合したポリエステルBを50wt%ブレンド(鞘部でのポリエチレングリコール含有率は2.0wt%)したポリマーを用いた。芯部にはポリエチレンテレフタレートAを用いた。
アルカリ:水酸化ナトリウム;4g/リットル
ラウリルベンジルジメチルアンモニウムクロライド:DYK-1125(一方社油脂工業製);1.2g/リットル
浴比; 1:40
処理温度:95℃
得られた各編地のポリエチレングリコール含有率の測定結果を表1-1に示す。
次に下記の染色条件で染色した。
染料:ダイアニックス ブルー S-2R(ダイスター社製);1.5%omf
助剤:ニッカサンソルト RM-340(日華化学(株)製);0.5g/リットル
酢酸:0.5cc/リットル
酢酸ナトリウム:1g/リットル
浴比; 1:25
染色温度、時間: 130℃、30分
苛性ソーダ-:2g/リットル
ビスノールUP-10(一方社油脂工業(株)製):0.5g/リットル
浴比; 1:25
得られた染色編地を、電子顕微鏡にて1800倍の倍率にて観察したときの、鞘芯型ポリエステル繊維表面の筋状溝A、筋状溝Bの形状を表1-1に示す。
比較例1として、実施例1の編地を、アルカリ減量処理を施さずに実施例1と同様の条件にて染色し仕上げた。
比較例1~3についても、実施例1と同様に電子顕微鏡にて1800倍の倍率にて観察したときの筋状溝A,Bの形状を表1-1に示す。
鞘部に、酸化チタン2.0wt%含有し、固有粘度[η]が0.60(オルソクロロフェノール中、1wt%で測定)のポリエチレンテレフタレートAに対して、数平均分子量15000のポリエチレングリコールを4wt%共重合したポリエステルBを55wt%ブレンド(鞘部でのポリエチレングリコール含有率は2.2wt%)したポリマーを用い、芯部にはポリエチレンテレフタレートAを用いた。
次に、実施例1と同様の条件で染色、還元洗浄を行い、染色物をすすぎ洗いした後、脱水、乾燥後、130℃で45秒間の乾熱セットを行い、仕上げた。
また、得られた染色編地の水滴消失時間、吸水乾燥性、吸水拡散面積、風合、汗アルカリ堅牢度の評価結果を表2-2に示す。
比較例4として、実施例2の編地を、アルカリ減量処理を施さずに同様の条件にて染色し、仕上げた。得られた染色品の水滴消失時間、吸水拡散面積、吸水乾燥性、風合、汗アルカリ堅牢度の評価結果を表2-2に示す。
鞘部に、酸化チタン2.0wt%含有し、固有粘度[η]が0.60(オルソクロロフェノール中、1wt%で測定)のポリエチレンテレフタレートAに対して、数平均分子量6000のポリエチレングリコールを4wt%共重合したポリエステルBを50wt%ブレンド(鞘部でのポリエチレングリコール含有率は2.0wt%)したポリマーを用い、芯部にはポリエチレンテレフタレートAを用いた。
次に、実施例1と同様の条件で染色、還元洗浄を行い、染色編地をすすぎ洗いした後、脱水、乾燥後、130℃で45秒間の乾熱セットを行い、仕上げた。
また、得られた各染色編地の水滴消失時間、吸水拡散面積、吸水乾燥性、風合、汗アルカリ堅牢度の評価結果を表3-2に示す。
比較例5として、実施例3の編地を、アルカリ減量処理を施さずに同様の条件にて染色し、仕上げた。得られた染色品の水滴消失時間、吸水拡散面積、吸水乾燥性、風合、汗アルカリ堅牢度の評価結果を表3-2に示す。
Claims (12)
- 下記(1)~(4)の要件を満足する鞘芯型ポリエステル繊維を20wt%以上含むことを特徴とする吸水速乾性織編物。
(1)単糸断面に凹部を一個以上有する異型断面繊維である。
(2)鞘部にポリエチレングリコールを含有し、鞘部/芯部の重量比が20/80~50/50である。
(3)鞘芯型ポリエステル繊維中におけるポリエチレングリコールの量が0.1~1.0wt%である。
(4)繊維軸方向に沿って、長い筋状溝Aと短い筋状溝Bが混在しており、筋状溝Aの長さが30μm以上であり、筋状溝Bの長さが15μm以下である。
ただし、Pは、溝の幅に対する長さの比であり、P=[長さ]/[幅]で表される。 - ポリエチレングリコールの数平均分子量が4000~50000であることを特徴とする請求項1に記載の吸水速乾性織編物。
- 鞘部にポリエチレングリコールを0.4~4.0wt%含むことを特徴とする請求項1または2に記載の吸水速乾性織編物。
- 筋状溝AのPが75以上であり、筋状溝BのPが50未満である請求項1~3のいずれかに記載の吸水速乾性織編物。
ただし、Pは、溝の幅に対する長さの比であり、P=[長さ]/[幅]で表される。 - 筋状溝Aが、凹部あるいは凹部周辺に形成されていることを特徴とする請求項1~4のいずれかに記載の吸水速乾性織編物。
- 親水化剤を含まないことを特徴とする請求項1~5のいずれかに記載の吸水速乾性織編物。
- 筋状溝Bが、繊維軸方向の長さ30μm中に平均20個以上形成されていることを特徴とする請求項1~6のいずれかに記載の吸水速乾性織編物。
- 異型断面がW型であることを特徴とする請求項1~7のいずれかに記載の吸水速乾性織編物。
- 織編物を80℃で30回洗濯後、滴下法による水滴消失時間が10秒以下であることを特徴とする請求項1~8のいずれかに記載の吸水速乾性織編物。
- 織編物を80℃で30回洗濯後、吸水速乾性が20分以下であることを特徴とする請求項1~9のいずれかに記載の吸水速乾性織編物。
- 織編物を80℃で30回洗濯後、吸水拡散面積が10cm2以上であることを特徴とする請求項1~10のいずれかに記載の吸水速乾性織編物。
- 下記(5)~(7)を満足する鞘芯型ポリエステル繊維を20wt%以上含む織編物を、アルキルベンジルジメチルアンモニウムクロライドを含んだアルカリ水溶液を用いて、100℃以下の温度で2~15%減量処理した後、酸処理し、次いで染色することを特徴とする染色された吸水速乾性織編物の製造方法。
(5)単糸断面に凹部を一個以上有する異型断面繊維である。
(6)鞘部にポリエチレングリコールを0.4~4.0wt%含む。
(7)鞘部/芯部の重量比が20/80~50/50である。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200880129786XA CN102066626A (zh) | 2008-06-13 | 2008-06-13 | 吸水速干性编织物 |
PCT/JP2008/060875 WO2009150745A1 (ja) | 2008-06-13 | 2008-06-13 | 吸水速乾性織編物 |
JP2010516696A JP5074590B2 (ja) | 2008-06-13 | 2008-06-13 | 吸水速乾性織編物 |
US12/991,101 US20110059665A1 (en) | 2008-06-13 | 2008-06-13 | Water-absorbing rapidly dryable woven or knitted fabric |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2008/060875 WO2009150745A1 (ja) | 2008-06-13 | 2008-06-13 | 吸水速乾性織編物 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009150745A1 true WO2009150745A1 (ja) | 2009-12-17 |
Family
ID=41416466
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/060875 WO2009150745A1 (ja) | 2008-06-13 | 2008-06-13 | 吸水速乾性織編物 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20110059665A1 (ja) |
JP (1) | JP5074590B2 (ja) |
CN (1) | CN102066626A (ja) |
WO (1) | WO2009150745A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11649565B2 (en) * | 2019-07-10 | 2023-05-16 | Hyundai Motor Company | Fiber for sound-absorbing material for vehicles and sound-absorbing material for vehicles including the same |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102505252A (zh) * | 2011-09-30 | 2012-06-20 | 常熟市梅李镇宾理服饰制衣厂 | 一种吸水面料 |
CN102519822B (zh) * | 2011-12-01 | 2013-05-01 | 江苏阳光股份有限公司 | 毛织物干燥性能的测试方法 |
CN106757670A (zh) * | 2016-12-20 | 2017-05-31 | 江苏金太阳纺织科技股份有限公司 | 一种抗起球磨毛面料及其制造方法 |
CN112359440A (zh) * | 2020-09-30 | 2021-02-12 | 嘉兴华绰纺织股份有限公司 | 一种吸水性涤纶经编面料生产工艺 |
WO2023116478A1 (zh) * | 2021-12-22 | 2023-06-29 | 军事科学院系统工程研究院军需工程技术研究所 | 一种防黏身单向导湿织物及加工方法 |
CN114232189B (zh) * | 2021-12-22 | 2024-01-26 | 军事科学院系统工程研究院军需工程技术研究所 | 一种防黏身单向导湿织物及加工方法 |
CN116043362B (zh) * | 2022-12-13 | 2024-02-27 | 东华大学 | 一种具有表面凹凸结构的聚合物纤维及其制备方法 |
CN116180266B (zh) * | 2022-12-13 | 2024-02-20 | 东华大学 | 一种吸湿排汗聚酯纤维及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03113070A (ja) * | 1989-09-27 | 1991-05-14 | Kuraray Co Ltd | ポリエステル繊維の製造法 |
JPH111823A (ja) * | 1997-06-11 | 1999-01-06 | Asahi Chem Ind Co Ltd | ポリエステル繊維とその混用布帛染色物 |
-
2008
- 2008-06-13 WO PCT/JP2008/060875 patent/WO2009150745A1/ja active Application Filing
- 2008-06-13 CN CN200880129786XA patent/CN102066626A/zh active Pending
- 2008-06-13 JP JP2010516696A patent/JP5074590B2/ja not_active Expired - Fee Related
- 2008-06-13 US US12/991,101 patent/US20110059665A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03113070A (ja) * | 1989-09-27 | 1991-05-14 | Kuraray Co Ltd | ポリエステル繊維の製造法 |
JPH111823A (ja) * | 1997-06-11 | 1999-01-06 | Asahi Chem Ind Co Ltd | ポリエステル繊維とその混用布帛染色物 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11649565B2 (en) * | 2019-07-10 | 2023-05-16 | Hyundai Motor Company | Fiber for sound-absorbing material for vehicles and sound-absorbing material for vehicles including the same |
Also Published As
Publication number | Publication date |
---|---|
US20110059665A1 (en) | 2011-03-10 |
JPWO2009150745A1 (ja) | 2011-11-10 |
CN102066626A (zh) | 2011-05-18 |
JP5074590B2 (ja) | 2012-11-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5074590B2 (ja) | 吸水速乾性織編物 | |
EP2829643B1 (en) | Polymethylpentene conjugate fiber and fiber structure comprising same | |
CN109477254B (zh) | 由可染性聚烯烃纤维形成的假捻加工丝 | |
CN109715869B (zh) | 聚合物合金纤维及包含其的纤维结构体 | |
JP5658602B2 (ja) | ソフトで抗ピリング性に優れた紡績糸 | |
TWI814764B (zh) | 可染性聚烯烴纖維及包含其之纖維構造體 | |
KR101374774B1 (ko) | 심초형 잠재권축 혼섬사 및 이를 사용한 원단 | |
JP5034412B2 (ja) | ナノファイバーからなる布帛およびその製造方法 | |
JP2010255130A (ja) | 染色された吸水速乾性織編物の製造方法 | |
JP5778400B2 (ja) | 吸水速乾性織物 | |
JP2008150728A (ja) | 吸水速乾性織編物 | |
JP2012077406A (ja) | ポリエステル潜在捲縮加工糸及びその製造方法 | |
JP2019127679A (ja) | 可染性ポリオレフィン芯鞘型複合繊維およびそれからなる繊維構造体 | |
JP5339926B2 (ja) | 衣料用織編物 | |
JP2010255139A (ja) | 吸水拡散性ポリエステル編物 | |
JP4789791B2 (ja) | 吸水速乾性ポリエステル複合繊維及びその製造方法 | |
JP2009144263A (ja) | 吸水速乾性ポリエステル未延伸繊維及びその製造方法 | |
JPH07252744A (ja) | 羊毛/レーヨン混紡織物 | |
JP7172258B2 (ja) | 編地 | |
JP2005048309A (ja) | ポリアミド繊維、ポリアミド織物およびそれよりなる繊維製品 | |
JP2005344219A (ja) | 肌着用編地 | |
JP2001164436A (ja) | ポリエステル混繊糸およびそれを用いた織編物 | |
JP4317082B2 (ja) | レース編地 | |
JPH06330424A (ja) | 混繊糸 | |
JP2001159051A (ja) | 吸水性布帛 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200880129786.X Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08765585 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010516696 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12991101 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 08765585 Country of ref document: EP Kind code of ref document: A1 |