WO2009051025A1 - 含リン化合物と含イオウ化合物の触媒 - Google Patents

含リン化合物と含イオウ化合物の触媒 Download PDF

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Publication number
WO2009051025A1
WO2009051025A1 PCT/JP2008/068110 JP2008068110W WO2009051025A1 WO 2009051025 A1 WO2009051025 A1 WO 2009051025A1 JP 2008068110 W JP2008068110 W JP 2008068110W WO 2009051025 A1 WO2009051025 A1 WO 2009051025A1
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WO
WIPO (PCT)
Prior art keywords
containing compound
acid
catalyst
hni
phosphorus
Prior art date
Application number
PCT/JP2008/068110
Other languages
English (en)
French (fr)
Inventor
Li-Biao Han
Hiroyoshi Fujino
Yuta Saga
Kouji Kitagaki
Kaoru Hasegawa
Original Assignee
Katayama Chemical Industries Co., Ltd.
National Institute Of Advanced Industrial Science And Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Katayama Chemical Industries Co., Ltd., National Institute Of Advanced Industrial Science And Technology filed Critical Katayama Chemical Industries Co., Ltd.
Priority to JP2009538051A priority Critical patent/JP5388856B2/ja
Publication of WO2009051025A1 publication Critical patent/WO2009051025A1/ja

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4003Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4015Esters of acyclic unsaturated acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121Metal hydrides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/847Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

本発明は、水素化ホスホン酸エステル、水素化ホスフィン酸エステル又は二置換ホスフィンオキシドを出発原料とし、安価な触媒を用いて、アルケニルリン化合物を製造する方法を提供することを目的とする。[HNi(PR1R2R3)2]+X-または[HNi(R1R2P(CH2)xPR4R5)]+X-で示される錯体化合物(ここで、R1、R2、R3、R4およびR5は、それぞれ独立して、置換されたまたは置換されていない炭化水素基であり、Xはヒドリド供与体である酸(たとえば、無機酸または有機酸)の陰イオンであり、xは正の整数である。)。
PCT/JP2008/068110 2007-10-18 2008-10-03 含リン化合物と含イオウ化合物の触媒 WO2009051025A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009538051A JP5388856B2 (ja) 2007-10-18 2008-10-03 含リン化合物と含イオウ化合物の触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007271860 2007-10-18
JP2007-271860 2007-10-18

Publications (1)

Publication Number Publication Date
WO2009051025A1 true WO2009051025A1 (ja) 2009-04-23

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ID=40567295

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PCT/JP2008/068110 WO2009051025A1 (ja) 2007-10-18 2008-10-03 含リン化合物と含イオウ化合物の触媒

Country Status (2)

Country Link
JP (1) JP5388856B2 (ja)
WO (1) WO2009051025A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014087752A (ja) * 2012-10-30 2014-05-15 Toray Eng Co Ltd マイクロリアクタシステムとそれを用いた化合物製造方法およびアルケニルリン化合物の製造方法
WO2017043552A1 (ja) * 2015-09-11 2017-03-16 丸善石油化学株式会社 アルケニルリン化合物の製造方法
WO2019170710A3 (en) * 2018-03-07 2019-10-24 Forschungsverbund Berlin E.V. Chemoselective thiol-conjugation with alkene or alkyne-phosphonothiolates and -phosphonates
CN113179642A (zh) * 2019-11-27 2021-07-27 丸善石油化学株式会社 烯基磷化合物的制造方法
CN114181251A (zh) * 2020-09-15 2022-03-15 中国石油化工股份有限公司 一种烯基膦酸化合物及其合成方法和应用
CN114181250A (zh) * 2020-09-15 2022-03-15 中国石油化工股份有限公司 一种烯基膦化合物及其制备方法
WO2022172906A1 (ja) * 2021-02-09 2022-08-18 丸善石油化学株式会社 リン化合物の精製方法および再利用方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022172905A1 (ja) * 2021-02-09 2022-08-18 丸善石油化学株式会社 アルケニルリン化合物の製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3836395B2 (ja) * 2002-05-17 2006-10-25 独立行政法人科学技術振興機構 アルケニルリン化合物の製造方法
JP3951024B2 (ja) * 2003-08-26 2007-08-01 独立行政法人産業技術総合研究所 有機硫黄化合物の製造方法
JP3836459B2 (ja) * 2003-09-03 2006-10-25 独立行政法人科学技術振興機構 アルケニルホスホン酸エステルの製造方法
JP3836460B2 (ja) * 2003-09-03 2006-10-25 独立行政法人科学技術振興機構 アルケニルリン化合物を製造する方法
JP4314366B2 (ja) * 2004-02-18 2009-08-12 独立行政法人産業技術総合研究所 含リンブタジエン化合物の製造方法
JP4517078B2 (ja) * 2005-08-30 2010-08-04 独立行政法人産業技術総合研究所 新規ビスホスフィノイル化合物、その製造方法及びそれを有効成分とした医薬

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CRESTANI, M. G. ET AL.: "o-Borane Coordinated to Nickel(0) and Some Related Nickel(II) Trihydride Complexes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 127, no. 51, 2005, pages 18066 - 18073 *
HAN, L-B. ET AL.: "Efficient and Selective Nickel-Catalyzed Addition of H-P(O) and H-S Bonds to Alkynes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, no. 16, 2004, pages 5080 - 5081 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014087752A (ja) * 2012-10-30 2014-05-15 Toray Eng Co Ltd マイクロリアクタシステムとそれを用いた化合物製造方法およびアルケニルリン化合物の製造方法
WO2017043552A1 (ja) * 2015-09-11 2017-03-16 丸善石油化学株式会社 アルケニルリン化合物の製造方法
JPWO2017043552A1 (ja) * 2015-09-11 2018-06-28 丸善石油化学株式会社 アルケニルリン化合物の製造方法
US10479809B2 (en) 2015-09-11 2019-11-19 Maruzen Petrochemical Co., Ltd. Method for producing alkenyl phosphorus compound
WO2019170710A3 (en) * 2018-03-07 2019-10-24 Forschungsverbund Berlin E.V. Chemoselective thiol-conjugation with alkene or alkyne-phosphonothiolates and -phosphonates
CN112088168A (zh) * 2018-03-07 2020-12-15 柏林合作研究学会 与烯烃-或炔烃-硫代膦酸酯和-膦酸酯的化学选择性巯基偶联
CN113179642A (zh) * 2019-11-27 2021-07-27 丸善石油化学株式会社 烯基磷化合物的制造方法
CN114181251A (zh) * 2020-09-15 2022-03-15 中国石油化工股份有限公司 一种烯基膦酸化合物及其合成方法和应用
CN114181250A (zh) * 2020-09-15 2022-03-15 中国石油化工股份有限公司 一种烯基膦化合物及其制备方法
WO2022172906A1 (ja) * 2021-02-09 2022-08-18 丸善石油化学株式会社 リン化合物の精製方法および再利用方法

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JP5388856B2 (ja) 2014-01-15
JPWO2009051025A1 (ja) 2011-03-03

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