WO2009051025A1 - 含リン化合物と含イオウ化合物の触媒 - Google Patents
含リン化合物と含イオウ化合物の触媒 Download PDFInfo
- Publication number
- WO2009051025A1 WO2009051025A1 PCT/JP2008/068110 JP2008068110W WO2009051025A1 WO 2009051025 A1 WO2009051025 A1 WO 2009051025A1 JP 2008068110 W JP2008068110 W JP 2008068110W WO 2009051025 A1 WO2009051025 A1 WO 2009051025A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- containing compound
- acid
- catalyst
- hni
- phosphorus
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- -1 hydrogenated phosphinic acid ester Chemical class 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 abstract 1
- 150000003008 phosphonic acid esters Chemical class 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4015—Esters of acyclic unsaturated acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
本発明は、水素化ホスホン酸エステル、水素化ホスフィン酸エステル又は二置換ホスフィンオキシドを出発原料とし、安価な触媒を用いて、アルケニルリン化合物を製造する方法を提供することを目的とする。[HNi(PR1R2R3)2]+X-または[HNi(R1R2P(CH2)xPR4R5)]+X-で示される錯体化合物(ここで、R1、R2、R3、R4およびR5は、それぞれ独立して、置換されたまたは置換されていない炭化水素基であり、Xはヒドリド供与体である酸(たとえば、無機酸または有機酸)の陰イオンであり、xは正の整数である。)。
Priority Applications (1)
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---|---|---|---|
JP2009538051A JP5388856B2 (ja) | 2007-10-18 | 2008-10-03 | 含リン化合物と含イオウ化合物の触媒 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007271860 | 2007-10-18 | ||
JP2007-271860 | 2007-10-18 |
Publications (1)
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WO2009051025A1 true WO2009051025A1 (ja) | 2009-04-23 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/068110 WO2009051025A1 (ja) | 2007-10-18 | 2008-10-03 | 含リン化合物と含イオウ化合物の触媒 |
Country Status (2)
Country | Link |
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JP (1) | JP5388856B2 (ja) |
WO (1) | WO2009051025A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014087752A (ja) * | 2012-10-30 | 2014-05-15 | Toray Eng Co Ltd | マイクロリアクタシステムとそれを用いた化合物製造方法およびアルケニルリン化合物の製造方法 |
WO2017043552A1 (ja) * | 2015-09-11 | 2017-03-16 | 丸善石油化学株式会社 | アルケニルリン化合物の製造方法 |
WO2019170710A3 (en) * | 2018-03-07 | 2019-10-24 | Forschungsverbund Berlin E.V. | Chemoselective thiol-conjugation with alkene or alkyne-phosphonothiolates and -phosphonates |
CN113179642A (zh) * | 2019-11-27 | 2021-07-27 | 丸善石油化学株式会社 | 烯基磷化合物的制造方法 |
CN114181251A (zh) * | 2020-09-15 | 2022-03-15 | 中国石油化工股份有限公司 | 一种烯基膦酸化合物及其合成方法和应用 |
CN114181250A (zh) * | 2020-09-15 | 2022-03-15 | 中国石油化工股份有限公司 | 一种烯基膦化合物及其制备方法 |
WO2022172906A1 (ja) * | 2021-02-09 | 2022-08-18 | 丸善石油化学株式会社 | リン化合物の精製方法および再利用方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022172905A1 (ja) * | 2021-02-09 | 2022-08-18 | 丸善石油化学株式会社 | アルケニルリン化合物の製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3836395B2 (ja) * | 2002-05-17 | 2006-10-25 | 独立行政法人科学技術振興機構 | アルケニルリン化合物の製造方法 |
JP3951024B2 (ja) * | 2003-08-26 | 2007-08-01 | 独立行政法人産業技術総合研究所 | 有機硫黄化合物の製造方法 |
JP3836459B2 (ja) * | 2003-09-03 | 2006-10-25 | 独立行政法人科学技術振興機構 | アルケニルホスホン酸エステルの製造方法 |
JP3836460B2 (ja) * | 2003-09-03 | 2006-10-25 | 独立行政法人科学技術振興機構 | アルケニルリン化合物を製造する方法 |
JP4314366B2 (ja) * | 2004-02-18 | 2009-08-12 | 独立行政法人産業技術総合研究所 | 含リンブタジエン化合物の製造方法 |
JP4517078B2 (ja) * | 2005-08-30 | 2010-08-04 | 独立行政法人産業技術総合研究所 | 新規ビスホスフィノイル化合物、その製造方法及びそれを有効成分とした医薬 |
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2008
- 2008-10-03 WO PCT/JP2008/068110 patent/WO2009051025A1/ja active Application Filing
- 2008-10-03 JP JP2009538051A patent/JP5388856B2/ja active Active
Non-Patent Citations (2)
Title |
---|
CRESTANI, M. G. ET AL.: "o-Borane Coordinated to Nickel(0) and Some Related Nickel(II) Trihydride Complexes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 127, no. 51, 2005, pages 18066 - 18073 * |
HAN, L-B. ET AL.: "Efficient and Selective Nickel-Catalyzed Addition of H-P(O) and H-S Bonds to Alkynes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, no. 16, 2004, pages 5080 - 5081 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014087752A (ja) * | 2012-10-30 | 2014-05-15 | Toray Eng Co Ltd | マイクロリアクタシステムとそれを用いた化合物製造方法およびアルケニルリン化合物の製造方法 |
WO2017043552A1 (ja) * | 2015-09-11 | 2017-03-16 | 丸善石油化学株式会社 | アルケニルリン化合物の製造方法 |
JPWO2017043552A1 (ja) * | 2015-09-11 | 2018-06-28 | 丸善石油化学株式会社 | アルケニルリン化合物の製造方法 |
US10479809B2 (en) | 2015-09-11 | 2019-11-19 | Maruzen Petrochemical Co., Ltd. | Method for producing alkenyl phosphorus compound |
WO2019170710A3 (en) * | 2018-03-07 | 2019-10-24 | Forschungsverbund Berlin E.V. | Chemoselective thiol-conjugation with alkene or alkyne-phosphonothiolates and -phosphonates |
CN112088168A (zh) * | 2018-03-07 | 2020-12-15 | 柏林合作研究学会 | 与烯烃-或炔烃-硫代膦酸酯和-膦酸酯的化学选择性巯基偶联 |
CN113179642A (zh) * | 2019-11-27 | 2021-07-27 | 丸善石油化学株式会社 | 烯基磷化合物的制造方法 |
CN114181251A (zh) * | 2020-09-15 | 2022-03-15 | 中国石油化工股份有限公司 | 一种烯基膦酸化合物及其合成方法和应用 |
CN114181250A (zh) * | 2020-09-15 | 2022-03-15 | 中国石油化工股份有限公司 | 一种烯基膦化合物及其制备方法 |
WO2022172906A1 (ja) * | 2021-02-09 | 2022-08-18 | 丸善石油化学株式会社 | リン化合物の精製方法および再利用方法 |
Also Published As
Publication number | Publication date |
---|---|
JP5388856B2 (ja) | 2014-01-15 |
JPWO2009051025A1 (ja) | 2011-03-03 |
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