WO2009041269A1 - 導電性高分子電極の製造方法及びそれを備えた色素増感太陽電池 - Google Patents

導電性高分子電極の製造方法及びそれを備えた色素増感太陽電池 Download PDF

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Publication number
WO2009041269A1
WO2009041269A1 PCT/JP2008/066343 JP2008066343W WO2009041269A1 WO 2009041269 A1 WO2009041269 A1 WO 2009041269A1 JP 2008066343 W JP2008066343 W JP 2008066343W WO 2009041269 A1 WO2009041269 A1 WO 2009041269A1
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WO
WIPO (PCT)
Prior art keywords
electroconductive polymer
polymer electrode
electrode
dye
solar cell
Prior art date
Application number
PCT/JP2008/066343
Other languages
English (en)
French (fr)
Inventor
Yasuteru Saito
Masashi Nakayama
Original Assignee
Dai-Ichi Kogyo Seiyaku Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai-Ichi Kogyo Seiyaku Co., Ltd. filed Critical Dai-Ichi Kogyo Seiyaku Co., Ltd.
Priority to EP08833326A priority Critical patent/EP2192650A4/en
Priority to KR1020107003565A priority patent/KR101177188B1/ko
Priority to JP2009534266A priority patent/JP5215314B2/ja
Priority to AU2008305115A priority patent/AU2008305115B2/en
Priority to US12/677,071 priority patent/US8377504B2/en
Priority to CN200880103876A priority patent/CN101821898A/zh
Publication of WO2009041269A1 publication Critical patent/WO2009041269A1/ja

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/43—Chemical oxidative coupling reactions, e.g. with FeCl3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90—Applications
    • C08G2261/91—Photovoltaic applications
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
    • H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/10—Transparent electrodes, e.g. using graphene
    • H10K2102/101—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO]
    • H10K2102/102—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO] comprising tin oxides, e.g. fluorine-doped SnO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H10K85/1135—Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Hybrid Cells (AREA)
  • Photovoltaic Devices (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

導電性、触媒性能に優れ、かつパターニングが容易であり、塗布溶液の使用効率が高く、簡便に、再現性、生産性よく製造することができる導電性高分子電極の製造方法、及びこれを用いた変換効率等に優れた色素増感太陽電池を提供する。すなわち、電極基体上に、導電性高分子のモノマー、酸化剤、重合制御剤として下記一般式（１）で表されるピロリドン化合物を含む溶液を電極基体上に塗布したのち、酸化重合により前記モノマーを重合させることで導電性高分子電極を形成する手法を用いる。 【化１】 （式（１）中、Ｒ１はアルキル基又はアリール基を示す。）
PCT/JP2008/066343 2007-09-26 2008-09-10 導電性高分子電極の製造方法及びそれを備えた色素増感太陽電池 WO2009041269A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP08833326A EP2192650A4 (en) 2007-09-26 2008-09-10 METHOD FOR PRODUCING AN ELECTRICALLY CONDUCTIVE POLYMER ELECTRODE AND COLOR-SENSITIZED SOLAR CELL WITH THE ELECTRICALLY CONDUCTIVE POLYMER ELECTRODE
KR1020107003565A KR101177188B1 (ko) 2007-09-26 2008-09-10 도전성 고분자 전극의 제조 방법과 이를 구비한 색소 증감 태양전지
JP2009534266A JP5215314B2 (ja) 2007-09-26 2008-09-10 導電性高分子電極の製造方法及びそれを備えた色素増感太陽電池
AU2008305115A AU2008305115B2 (en) 2007-09-26 2008-09-10 Process for producing electroconductive polymer electrode and dye-sensitized solar cell comprising the electroconductive polymer electrode
US12/677,071 US8377504B2 (en) 2007-09-26 2008-09-10 Method for producing electroconductive polymer electrode, and dye-sensitized solar cell equipped with the same
CN200880103876A CN101821898A (zh) 2007-09-26 2008-09-10 导电性高分子电极的制造方法及具有该电极的色素敏化太阳能电池

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-249346 2007-09-26
JP2007249346 2007-09-26

Publications (1)

Publication Number Publication Date
WO2009041269A1 true WO2009041269A1 (ja) 2009-04-02

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PCT/JP2008/066343 WO2009041269A1 (ja) 2007-09-26 2008-09-10 導電性高分子電極の製造方法及びそれを備えた色素増感太陽電池

Country Status (8)

Country Link
US (1) US8377504B2 (ja)
EP (1) EP2192650A4 (ja)
JP (1) JP5215314B2 (ja)
KR (1) KR101177188B1 (ja)
CN (1) CN101821898A (ja)
AU (1) AU2008305115B2 (ja)
TW (1) TWI424601B (ja)
WO (1) WO2009041269A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011222604A (ja) * 2010-04-06 2011-11-04 Tayca Corp 導電性高分子製造用酸化剤兼ドーパント溶液、導電性高分子、それを固体電解質として用いた固体電解コンデンサおよびその製造方法
JP2013020789A (ja) * 2011-07-11 2013-01-31 Japan Carlit Co Ltd:The 色素増感太陽電池用電解液およびそれを用いた色素増感太陽電池
JP2013164974A (ja) * 2012-02-10 2013-08-22 Toppan Printing Co Ltd 固体高分子形燃料電池用膜・電極接合体の製造方法、固体高分子形燃料電池用膜・電極接合体の製造装置、固体高分子形燃料電池
JP2014154498A (ja) * 2013-02-13 2014-08-25 Nsk Ltd 光電変換素子
JP6035662B1 (ja) * 2016-04-05 2016-11-30 エーアイシルク株式会社 導電性高分子導電体の製造方法及び製造装置

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TWI394285B (zh) * 2009-06-08 2013-04-21 Univ Tatung 光電轉換裝置及其製法
US9378859B2 (en) 2010-08-20 2016-06-28 Rhodia Operations Polymer compositions, polymer films, polymer gels, polymer foams, and electronic devices containing such films, gels and foams
KR101073118B1 (ko) * 2010-10-25 2011-10-12 연세대학교 산학협력단 광전극의 제조방법 및 이에 의하여 제조한 광전극을 포함하는 태양전지
JP2012209243A (ja) * 2011-03-17 2012-10-25 Rohm Co Ltd 色素増感太陽電池
US9512029B2 (en) 2012-05-31 2016-12-06 Corning Incorporated Cover glass article
WO2014091809A1 (ja) * 2012-12-14 2014-06-19 積水化学工業株式会社 電極基板及び色素増感太陽電池
KR20140146006A (ko) * 2013-06-14 2014-12-24 주식회사 엘지화학 유기태양전지 및 이의 제조방법
TWI548723B (zh) * 2014-10-14 2016-09-11 瑞化股份有限公司 一種導電線路圖案化的蝕刻劑與利用蝕刻劑進行導電線路圖案化的製程
JP6686244B2 (ja) * 2015-03-17 2020-04-22 国立大学法人東北大学 電極素子及び電極の生産方法、並びに、当該電極を用いる測定システムの作製
CN107222821B (zh) * 2017-06-09 2019-09-17 京东方科技集团股份有限公司 复合电极、使用其的声学传感器及制造方法
CN110444396B (zh) * 2018-05-02 2022-02-11 钰邦科技股份有限公司 用于提升结构强度的卷绕式电容器组件及其制造方法
TWI675389B (zh) * 2018-05-02 2019-10-21 鈺邦科技股份有限公司 用於提升結構強度的捲繞式電容器組件及其製造方法
CN112670483B (zh) * 2020-12-25 2022-07-05 合肥国轩高科动力能源有限公司 正极片、正极极板及固态电池
CN114464338B (zh) * 2021-11-29 2024-06-28 无锡帝科电子材料股份有限公司 一种太阳能电池正面导电银浆及其制备方法

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JPH09507334A (ja) 1993-02-03 1997-07-22 エコール ポリテクニーク フェデラル ドゥ ローザンヌ 光電気化学電池及びこの電池用の電解液
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THE 72ND MEETING OF ELECTROCHEMICAL SOCIETY OF JAPAN, 2005, pages 471

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011222604A (ja) * 2010-04-06 2011-11-04 Tayca Corp 導電性高分子製造用酸化剤兼ドーパント溶液、導電性高分子、それを固体電解質として用いた固体電解コンデンサおよびその製造方法
JP2013020789A (ja) * 2011-07-11 2013-01-31 Japan Carlit Co Ltd:The 色素増感太陽電池用電解液およびそれを用いた色素増感太陽電池
JP2013164974A (ja) * 2012-02-10 2013-08-22 Toppan Printing Co Ltd 固体高分子形燃料電池用膜・電極接合体の製造方法、固体高分子形燃料電池用膜・電極接合体の製造装置、固体高分子形燃料電池
JP2014154498A (ja) * 2013-02-13 2014-08-25 Nsk Ltd 光電変換素子
JP6035662B1 (ja) * 2016-04-05 2016-11-30 エーアイシルク株式会社 導電性高分子導電体の製造方法及び製造装置
JP2017185449A (ja) * 2016-04-05 2017-10-12 エーアイシルク株式会社 導電性高分子導電体の製造方法及び製造装置

Also Published As

Publication number Publication date
EP2192650A1 (en) 2010-06-02
TWI424601B (zh) 2014-01-21
TW200915641A (en) 2009-04-01
US20110000527A1 (en) 2011-01-06
JPWO2009041269A1 (ja) 2011-01-20
US8377504B2 (en) 2013-02-19
JP5215314B2 (ja) 2013-06-19
AU2008305115B2 (en) 2011-12-08
KR20100044218A (ko) 2010-04-29
AU2008305115A1 (en) 2009-04-02
EP2192650A4 (en) 2011-07-06
CN101821898A (zh) 2010-09-01
KR101177188B1 (ko) 2012-08-24

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