WO2009031523A1 - 温度応答性高分子、およびこれを用いた温度応答性ファイバーおよび不織布、並びにその製造方法 - Google Patents

温度応答性高分子、およびこれを用いた温度応答性ファイバーおよび不織布、並びにその製造方法 Download PDF

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Publication number
WO2009031523A1
WO2009031523A1 PCT/JP2008/065740 JP2008065740W WO2009031523A1 WO 2009031523 A1 WO2009031523 A1 WO 2009031523A1 JP 2008065740 W JP2008065740 W JP 2008065740W WO 2009031523 A1 WO2009031523 A1 WO 2009031523A1
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WIPO (PCT)
Prior art keywords
temperature
sensitive
woven fabric
sensitive polymer
fiber
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PCT/JP2008/065740
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English (en)
French (fr)
Inventor
Yusuke Hara
Hu Yan
Hidenori Okuzaki
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University Of Yamanashi
Tokyo Electron Limited
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Application filed by University Of Yamanashi, Tokyo Electron Limited filed Critical University Of Yamanashi
Publication of WO2009031523A1 publication Critical patent/WO2009031523A1/ja

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/0007—Electro-spinning
    • D01D5/0015—Electro-spinning characterised by the initial state of the material
    • D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
    • D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

　複雑な工程を用いずに、明瞭な温度応答性を備えた温度応答性高分子、及び温度応答性高分子からなる温度応答性高分子ファイバーおよび不織布、その製造方法を提供する。 　温度によって水溶性が変化する温度応答性高分子であって、前記高分子は、温度応答性モノマーと、疎水性モノマーとの共重合体からなる。前記温度応答性高分子は、温度応答性モノマーと疎水性モノマーとの比が、50モル％：50モル％から99.9モル％対0.1モル％の組成比で構成されている。
PCT/JP2008/065740 2007-09-03 2008-09-02 温度応答性高分子、およびこれを用いた温度応答性ファイバーおよび不織布、並びにその製造方法 WO2009031523A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007228385A JP2009057522A (ja) 2007-09-03 2007-09-03 温度応答性高分子、およびこれを用いた温度応答性ファイバーおよび不織布、並びにその製造方法
JP2007-228385 2007-09-03

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WO2009031523A1 true WO2009031523A1 (ja) 2009-03-12

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WO (1) WO2009031523A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103074733A (zh) * 2012-12-31 2013-05-01 东华大学 一种静电纺制备温敏性半乳糖乙烯酯纳米载药纤维膜的方法
CN103173933A (zh) * 2013-04-12 2013-06-26 东华大学 一种葡萄糖乙烯酯/异丙基丙烯酰胺共聚物纳米纤维膜的制备方法
WO2014109379A1 (ja) * 2013-01-11 2014-07-17 独立行政法人物質・材料研究機構 自己発熱性及び生理活性物質放出性を有するナノファイバー、その製造方法並びに自己発熱性及び生理活性物質放出機能性不織布
JPWO2013027668A1 (ja) * 2011-08-19 2015-03-19 国立大学法人九州大学 イオン濃度勾配発生システム、装置、方法、及び、温度応答性電解質材料
CN104928851A (zh) * 2015-06-24 2015-09-23 东华大学 载银纳米粒子温度刺激响应性杂化纳米纤维膜的制备方法
CN111962290A (zh) * 2020-08-19 2020-11-20 上海理工大学 一种新型温敏性PNIPAAm-CNT-PNMA纤维水凝胶及制备方法
CN115216852A (zh) * 2021-04-15 2022-10-21 财团法人纺织产业综合研究所 感温调湿纤维及其制备方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
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CA2872597C (en) * 2012-05-15 2018-01-23 Mantrose-Haeuser Co., Inc. Seaweed-based food packaging coating
CN105637130B (zh) * 2013-10-17 2019-07-19 日产化学工业株式会社 感光性纤维及其制造方法
KR101994024B1 (ko) 2015-04-22 2019-06-27 닛산 가가쿠 가부시키가이샤 감광성 섬유 및 섬유 패턴의 형성 방법
CN104911819B (zh) * 2015-06-16 2017-06-06 东华大学 一种载贵金属纳米棒温度刺激响应性纳米纤维膜的制备方法

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JPS62141110A (ja) * 1985-12-11 1987-06-24 Canon Inc ゲル繊維の製造方法
JPS63101407A (ja) * 1986-10-20 1988-05-06 Kanegafuchi Chem Ind Co Ltd 耐熱性樹脂
JPS63101406A (ja) * 1986-10-20 1988-05-06 Kanegafuchi Chem Ind Co Ltd 耐熱性樹脂
JPH02196806A (ja) * 1988-10-27 1990-08-03 Mitsui Toatsu Chem Inc 粒子状重合体の製造方法
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JPH04298559A (ja) * 1991-03-27 1992-10-22 Kohjin Co Ltd 一時保護膜の処理方法
JPH05170803A (ja) * 1991-12-25 1993-07-09 Kohjin Co Ltd 合成エマルジョン樹脂の製造方法
JPH06233809A (ja) * 1993-02-08 1994-08-23 Shizu Kubota 創傷被覆材
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2013027668A1 (ja) * 2011-08-19 2015-03-19 国立大学法人九州大学 イオン濃度勾配発生システム、装置、方法、及び、温度応答性電解質材料
US10137409B2 (en) 2011-08-19 2018-11-27 Kyushu University, National University Corporation System, device and method for generating ion concentration gradient, and temperature-responsive electrolyte material
US10300432B2 (en) 2011-08-19 2019-05-28 Kyushu University, National University Corporation System, device, and method for producing ion concentration gradient, and temperature-responsive electrolyte material
US10695714B2 (en) 2011-08-19 2020-06-30 Kyushu University, National University Corporation System, device, and method for producing ion concentration gradient, and temperature-responsive electrolyte material
CN103074733A (zh) * 2012-12-31 2013-05-01 东华大学 一种静电纺制备温敏性半乳糖乙烯酯纳米载药纤维膜的方法
WO2014109379A1 (ja) * 2013-01-11 2014-07-17 独立行政法人物質・材料研究機構 自己発熱性及び生理活性物質放出性を有するナノファイバー、その製造方法並びに自己発熱性及び生理活性物質放出機能性不織布
JP5867839B2 (ja) * 2013-01-11 2016-02-24 国立研究開発法人物質・材料研究機構 自己発熱性及び生理活性物質放出性を有するナノファイバー、その製造方法並びに自己発熱性及び生理活性物質放出機能性不織布
CN103173933A (zh) * 2013-04-12 2013-06-26 东华大学 一种葡萄糖乙烯酯/异丙基丙烯酰胺共聚物纳米纤维膜的制备方法
CN104928851A (zh) * 2015-06-24 2015-09-23 东华大学 载银纳米粒子温度刺激响应性杂化纳米纤维膜的制备方法
CN111962290A (zh) * 2020-08-19 2020-11-20 上海理工大学 一种新型温敏性PNIPAAm-CNT-PNMA纤维水凝胶及制备方法
CN115216852A (zh) * 2021-04-15 2022-10-21 财团法人纺织产业综合研究所 感温调湿纤维及其制备方法

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