WO2009017185A1 - 中空糸炭素膜及びその製造方法 - Google Patents

中空糸炭素膜及びその製造方法 Download PDF

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Publication number
WO2009017185A1
WO2009017185A1 PCT/JP2008/063731 JP2008063731W WO2009017185A1 WO 2009017185 A1 WO2009017185 A1 WO 2009017185A1 JP 2008063731 W JP2008063731 W JP 2008063731W WO 2009017185 A1 WO2009017185 A1 WO 2009017185A1
Authority
WO
WIPO (PCT)
Prior art keywords
hollow fiber
carbon membrane
fiber carbon
repeating unit
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/063731
Other languages
English (en)
French (fr)
Inventor
Miki Yoshimune
Kenji Haraya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
National Institute of Advanced Industrial Science and Technology AIST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Institute of Advanced Industrial Science and Technology AIST filed Critical National Institute of Advanced Industrial Science and Technology AIST
Priority to CN2008800253883A priority Critical patent/CN101754796B/zh
Priority to US12/671,003 priority patent/US8303690B2/en
Publication of WO2009017185A1 publication Critical patent/WO2009017185A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B01D63/021—Manufacturing thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B01D69/081—Hollow fibre membranes characterised by the fibre diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/521—Aliphatic polyethers
    • B01D71/5211—Polyethylene glycol or polyethyleneoxide
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/34—Core-skin structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/24—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/24—Mechanical properties, e.g. strength

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Inorganic Fibers (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

　気体分離性能に優れた特質を有するとともに、破損しにくい柔軟性を持つ、実用性の高い中空糸炭素膜を提供するものであって、実質的に下記の（ａ）及び（ｂ） （式中、Ｒ１１～Ｒ１２は各々独立して、水素原子、スルホン基を示す。ただし、Ｒ１１～Ｒ１２が共に水素原子であることはない。）で表される繰り返し単位からなり、その繰り返し単位（ｂ）の（ａ＋ｂ）に対する割合Ａ（％）は１５％＜Ａ＜６０％であるポリフェニレンオキシド誘導体を中空糸状に形成した後に焼成して得られる炭化物からなり、その外径が０．０８～０．２５ｍｍの範囲にある中空糸炭素膜。
PCT/JP2008/063731 2007-08-02 2008-07-31 中空糸炭素膜及びその製造方法 Ceased WO2009017185A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2008800253883A CN101754796B (zh) 2007-08-02 2008-07-31 中空纤维碳膜及其制造方法
US12/671,003 US8303690B2 (en) 2007-08-02 2008-07-31 Hollow fiber carbon membrane and method for production thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-201865 2007-08-02
JP2007201865A JP5339324B2 (ja) 2007-08-02 2007-08-02 中空糸炭素膜とその製造方法

Publications (1)

Publication Number Publication Date
WO2009017185A1 true WO2009017185A1 (ja) 2009-02-05

Family

ID=40304413

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/063731 Ceased WO2009017185A1 (ja) 2007-08-02 2008-07-31 中空糸炭素膜及びその製造方法

Country Status (4)

Country Link
US (1) US8303690B2 (ja)
JP (1) JP5339324B2 (ja)
CN (1) CN101754796B (ja)
WO (1) WO2009017185A1 (ja)

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JP4911417B2 (ja) * 2009-05-20 2012-04-04 独立行政法人産業技術総合研究所 金属イオンを導入した中空糸炭素膜及びそれを用いたアルコール水溶液の脱水方法
JP2011177695A (ja) * 2010-03-04 2011-09-15 Toyobo Co Ltd 浸透気化膜の製造方法、浸透気化膜および有機溶剤回収システム
WO2011136002A1 (ja) * 2010-04-26 2011-11-03 大陽日酸株式会社 気体分離装置の運転方法
JP5557328B2 (ja) * 2010-10-07 2014-07-23 Ｎｏｋ株式会社 中空糸炭素膜の製造方法
CN103370123A (zh) * 2011-02-02 2013-10-23 Nok株式会社 用于碳膜的成膜原液及使用其制备碳中空纤维膜的方法
JP5853529B2 (ja) * 2011-09-20 2016-02-09 東洋紡株式会社 中空糸炭素膜およびその製造方法
JP5853530B2 (ja) * 2011-09-20 2016-02-09 東洋紡株式会社 中空糸炭素膜、分離膜モジュールおよび中空糸炭素膜の製造方法
JP5966298B2 (ja) * 2011-09-28 2016-08-10 東洋紡株式会社 中空糸炭素膜の製造方法
JP5906674B2 (ja) * 2011-11-02 2016-04-20 東洋紡株式会社 中空糸炭素膜およびその製造方法
JP6237234B2 (ja) 2012-05-30 2017-11-29 東レ株式会社 二酸化炭素分離膜
JP2014133219A (ja) * 2013-01-11 2014-07-24 Ngk Insulators Ltd ガス除去装置およびそれを用いたガス除去方法
ES2499117B1 (es) * 2013-02-25 2015-08-11 Porous Fibers, S.L. Proceso de fabricacion de membranas de microfibras huecas y membranas asi obtenidas
JP5708684B2 (ja) * 2013-02-27 2015-04-30 Nok株式会社 中空糸状炭素膜の製造方法
JPWO2014196601A1 (ja) * 2013-06-05 2017-02-23 Ｊｘエネルギー株式会社 炭素膜及び炭素膜の製造方法
GB2519959A (en) * 2013-11-01 2015-05-13 Airbus Operations Ltd Dehumidifier
MX395453B (es) 2014-07-24 2025-03-25 Toray Industries Película de carbono para separación de fluidos, módulo de película de separación de fluidos y método para producir película de carbono para separación de fluidos.
JP6379995B2 (ja) * 2014-10-24 2018-08-29 Nok株式会社 炭素膜用製膜原液およびこれを用いた中空糸炭素膜の製造方法
WO2016067900A1 (ja) 2014-10-30 2016-05-06 Nok株式会社 炭素膜用製膜原液およびこれを用いた炭素中空糸膜の製造方法
US10086337B2 (en) 2014-11-30 2018-10-02 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Composite carbon molecular sieve membranes having anti-substructure collapse particles loaded in a core thereof
US10150086B2 (en) 2014-12-12 2018-12-11 Nok Corporation Method for producing a carbon hollow fiber membrane
WO2016158183A1 (ja) * 2015-03-27 2016-10-06 国立研究開発法人産業技術総合研究所 中空糸炭素膜の製造方法及び分離膜モジュール
JP6493872B2 (ja) * 2015-03-27 2019-04-03 Ｊｘｔｇエネルギー株式会社 中空糸炭素膜の製造方法、分離膜モジュール、並びに膜分離器
JP2016185895A (ja) * 2015-03-27 2016-10-27 Ｊｘエネルギー株式会社 水素製造システム
JP6643223B2 (ja) * 2016-12-28 2020-02-12 日立造船株式会社 ガス分離膜の品質評価方法とその評価装置
CN111315467A (zh) * 2017-07-14 2020-06-19 哈里发科学技术大学 磁场下的气体膜分离
CA3101592A1 (en) 2018-06-05 2019-12-12 Toray Industries, Inc. Separation membrane
JP6914575B2 (ja) * 2019-06-06 2021-08-04 ユニチカ株式会社 中空糸膜、該中空糸膜モジュール、加湿ユニット、エアドライヤー、該中空糸膜の製膜原液及び該中空糸膜の製造方法
CN112023713B (zh) * 2020-07-21 2021-07-06 东华大学 一种吸附和降解微塑料的双功能碳纤维膜及其制备方法
JP2024520736A (ja) * 2020-12-21 2024-05-24 エスエイチピーピー グローバル テクノロジーズ べスローテン フェンノートシャップ スルホン化ポリ（フェニレンエーテル）コポリマーの炭化により得られる選択透過性膜

Citations (3)

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JP2626837B2 (ja) * 1990-11-27 1997-07-02 宇部興産株式会社 非対称性中空糸炭素膜の製法
JP2673846B2 (ja) * 1992-02-07 1997-11-05 宇部興産株式会社 非対称性中空糸炭素膜及びその製法
JP2006231095A (ja) * 2005-02-21 2006-09-07 National Institute Of Advanced Industrial & Technology 炭化膜及びその製造法

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KR101196867B1 (ko) * 2007-10-12 2012-11-01 내셔날 인스티튜트 오브 어드밴스드 인더스트리얼 사이언스 앤드 테크놀로지 가스 정제 방법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2626837B2 (ja) * 1990-11-27 1997-07-02 宇部興産株式会社 非対称性中空糸炭素膜の製法
JP2673846B2 (ja) * 1992-02-07 1997-11-05 宇部興産株式会社 非対称性中空糸炭素膜及びその製法
JP2006231095A (ja) * 2005-02-21 2006-09-07 National Institute Of Advanced Industrial & Technology 炭化膜及びその製造法

Also Published As

Publication number Publication date
US20100212503A1 (en) 2010-08-26
US8303690B2 (en) 2012-11-06
CN101754796B (zh) 2012-11-28
JP2009034614A (ja) 2009-02-19
JP5339324B2 (ja) 2013-11-13
CN101754796A (zh) 2010-06-23

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