WO2009013149A3 - Verfahren zur herstellung von chelatharzen - Google Patents

Verfahren zur herstellung von chelatharzen Download PDF

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Publication number
WO2009013149A3
WO2009013149A3 PCT/EP2008/059055 EP2008059055W WO2009013149A3 WO 2009013149 A3 WO2009013149 A3 WO 2009013149A3 EP 2008059055 W EP2008059055 W EP 2008059055W WO 2009013149 A3 WO2009013149 A3 WO 2009013149A3
Authority
WO
WIPO (PCT)
Prior art keywords
chelate resins
aminomethyl
groups
producing
producing chelate
Prior art date
Application number
PCT/EP2008/059055
Other languages
English (en)
French (fr)
Other versions
WO2009013149A2 (de
Inventor
Reinhold Klipper
Michael Schelhaas
Original Assignee
Lanxess Deutschland Gmbh
Reinhold Klipper
Michael Schelhaas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland Gmbh, Reinhold Klipper, Michael Schelhaas filed Critical Lanxess Deutschland Gmbh
Priority to CN200880100118.4A priority Critical patent/CN101754809B/zh
Priority to EP08786056A priority patent/EP2173486A2/de
Priority to US12/669,968 priority patent/US8506818B2/en
Publication of WO2009013149A2 publication Critical patent/WO2009013149A2/de
Publication of WO2009013149A3 publication Critical patent/WO2009013149A3/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • B01J13/06Making microcapsules or microballoons by phase separation
    • B01J13/10Complex coacervation, i.e. interaction of oppositely charged particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/64Heavy metals or compounds thereof, e.g. mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/12Macromolecular compounds
    • B01J41/14Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/90Chelants
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/683Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006Wet processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Water Supply & Treatment (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

Gegenstand der vorliegenden Erfindung ist ein Verfahren zur Herstellung neuer Chelatharze auf Basis vernetzter Perlpolymerisate ausgehend von (Meth)acrylverbindungen mit Aminomethylgruppen und/oder Aminomethylstickstoffheterocyclengruppen als funktionelle Gruppen, die eine hohe Aufnahmekapazität für Schwermetalle und eine schnelle Kinetik besitzen.
PCT/EP2008/059055 2007-07-23 2008-07-11 Verfahren zur herstellung von chelatharzen WO2009013149A2 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN200880100118.4A CN101754809B (zh) 2007-07-23 2008-07-11 螯合树脂的生产方法
EP08786056A EP2173486A2 (de) 2007-07-23 2008-07-11 Verfahren zur herstellung von chelatharzen
US12/669,968 US8506818B2 (en) 2007-07-23 2008-07-11 Method for producing chelate resins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007034732.6 2007-07-23
DE200710034732 DE102007034732A1 (de) 2007-07-23 2007-07-23 Verfahren zur Herstellung von Chelatharzen

Publications (2)

Publication Number Publication Date
WO2009013149A2 WO2009013149A2 (de) 2009-01-29
WO2009013149A3 true WO2009013149A3 (de) 2009-07-16

Family

ID=40157187

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/059055 WO2009013149A2 (de) 2007-07-23 2008-07-11 Verfahren zur herstellung von chelatharzen

Country Status (5)

Country Link
US (1) US8506818B2 (de)
EP (1) EP2173486A2 (de)
CN (1) CN101754809B (de)
DE (1) DE102007034732A1 (de)
WO (1) WO2009013149A2 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009047848A1 (de) * 2009-09-30 2011-03-31 Lanxess Deutschland Gmbh Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen
EP2330137B1 (de) * 2009-12-04 2013-06-26 LANXESS Deutschland GmbH Methylenaminoethylsulfonsäure-Chelatharze
CA2736680C (en) * 2010-04-30 2014-06-03 Dow Global Technologies, Llc Process for the recovery of gold using macroporous resins
CN102020745B (zh) * 2010-11-05 2013-04-24 山东鲁抗立科药物化学有限公司 一种丙烯酸系脱色树脂及其制备方法
CN102161757B (zh) * 2011-03-08 2015-07-01 上海树脂厂有限公司 提钒专用树脂及其制备方法
CN102476851B (zh) * 2011-10-20 2013-01-23 常州亚环环保科技有限公司 一种处理含镉废水的复合除镉剂及其应用方法
CN102489227B (zh) * 2011-11-15 2013-10-30 中国科学院化学研究所 功能树脂负载型金属纳米粒子的制备方法
EP2606973A1 (de) * 2011-12-22 2013-06-26 LANXESS Deutschland GmbH Thiolgruppenhaltiges Acrylatharz
US9309363B2 (en) 2012-03-30 2016-04-12 Rohm And Haas Company Product and method for making uniform spherical, acrylic polymeric beads
US20150210789A1 (en) * 2012-07-30 2015-07-30 Polymerium, Llc Polymeric Chelation System
DE102013105177A1 (de) 2013-05-21 2014-11-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Gewinnung metallischer Anteile sowie von metallabgereichertem Material aus metallhaltigen Materialien
CN107032448A (zh) * 2016-12-03 2017-08-11 华莉君 一种含铅工业废水的处理方法
CN207384199U (zh) 2017-04-12 2018-05-22 科沃斯机器人股份有限公司 手持式吸尘器
CN109317116B (zh) * 2018-09-26 2021-08-31 中国工程物理研究院核物理与化学研究所 一种复合树脂及其制备方法和对硝酸介质中钯的回收方法
RU2695065C1 (ru) * 2018-12-29 2019-07-19 АО "Аксион - Редкие и Драгоценные Металлы" Способ получения сорбента для извлечения ионов золота
CN110003376B (zh) * 2019-03-11 2021-09-28 西安蓝晓科技新材料股份有限公司 一种从含镍溶液中制备硫酸镍的螯合树脂制备方法
CN113754824A (zh) * 2021-09-10 2021-12-07 核工业北京化工冶金研究院 一种甲基吡啶树脂及其制备方法和应用
CN116573705B (zh) * 2023-03-28 2024-01-26 南京大学 一种铝材酸抛光废液回收再利用工艺
CN116239717B (zh) * 2023-05-12 2023-07-18 天津南开和成科技有限公司 一种用于曼尼希反应的功能树脂及其制备方法、应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4317887A (en) * 1976-07-25 1982-03-02 Yeda Research And Development Co. Ltd. Metal complexing polymers
JPS6011231A (ja) * 1983-06-28 1985-01-21 Sumitomo Chem Co Ltd ウランの回収法
US20050004240A1 (en) * 2001-12-17 2005-01-06 Bayer Ag Monodisperse anion exchangers

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL81827C (de) 1952-04-14
US4382124B1 (en) 1958-07-18 1994-10-04 Rohm & Haas Process for preparing macroreticular resins, copolymers and products of said process
DD99587A1 (de) 1972-10-23 1973-08-20
US4031038A (en) 1975-06-16 1977-06-21 The Dow Chemical Company Water insoluble chelate exchange resins having a crosslinked polymer matrix and pendant thereto a plurality of methyleneaminopyridine groups
DE3031737A1 (de) 1980-08-22 1982-04-01 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von perlpolymerisaten einheitlicher teilchengroesse
CA1166413A (en) 1980-10-30 1984-05-01 Edward E. Timm Process and apparatus for preparing uniform size polymer beads
US4419245A (en) 1982-06-30 1983-12-06 Rohm And Haas Company Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer
DE4020943A1 (de) 1990-06-30 1992-01-02 Bayer Ag Verfahren zur herstellung von anionenaustausch-harzen vom poly(meth)-acrylamid-typ
EP0481603A1 (de) * 1990-10-15 1992-04-22 The Dow Chemical Company Trennung von organischen schwachen Säuren von Flüssigkeitsmischungen
US5141965A (en) * 1991-03-28 1992-08-25 The Dow Chemical Company Resins having improved exchange kinetics
US5231115A (en) 1991-12-19 1993-07-27 The Dow Chemical Company Seeded porous copolymers and ion-exchange resins prepared therefrom
EP1078937B1 (de) * 1999-08-27 2007-08-15 Lanxess Deutschland GmbH Verfahren zur Herstellung von monodispersen, vernetzten Perlpolymerisaten mit Thioharnstoffgruppen und ihre Verwendung zur Adsorption von Metallverbindungen
EP1078690B1 (de) 1999-08-27 2011-10-12 LANXESS Deutschland GmbH Verfahren zur Herstellung von monodispersen Ionenaustauschern mit chelatisierenden Gruppen
TW200406429A (en) * 2002-05-08 2004-05-01 Hitachi Chemical Co Ltd Foamed styrene resin granules, hollow granules and shaped products
DE102004006115A1 (de) * 2004-02-06 2005-08-25 Bayer Chemicals Ag Verfahren zur Herstellung von monodispersen acrylhaltigen Perlpolymerisaten
DE102006004953A1 (de) * 2006-02-01 2007-08-02 Lanxess Deutschland Gmbh Chelatharze in der Metallgewinnung
DE102007020688A1 (de) * 2007-05-03 2008-11-06 Lanxess Deutschland Gmbh Konditionierung von Ionenaustauschern zur Adsorption von Oxoanionen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4317887A (en) * 1976-07-25 1982-03-02 Yeda Research And Development Co. Ltd. Metal complexing polymers
JPS6011231A (ja) * 1983-06-28 1985-01-21 Sumitomo Chem Co Ltd ウランの回収法
US20050004240A1 (en) * 2001-12-17 2005-01-06 Bayer Ag Monodisperse anion exchangers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HIRAYAMA, N. ET AL: "Ion chromatography using a charged complex anion-exchange group", ANALYTICA CHIMICA ACTA , 409(1-2), 17-26 CODEN: ACACAM; ISSN: 0003-2670, 2000, XP002526164 *

Also Published As

Publication number Publication date
DE102007034732A1 (de) 2009-01-29
EP2173486A2 (de) 2010-04-14
CN101754809B (zh) 2014-02-26
US20100252506A1 (en) 2010-10-07
US8506818B2 (en) 2013-08-13
CN101754809A (zh) 2010-06-23
WO2009013149A2 (de) 2009-01-29

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