WO2008149676A1 - 防汚加工剤組成物およびその製造方法ならびに加工物品 - Google Patents

防汚加工剤組成物およびその製造方法ならびに加工物品 Download PDF

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Publication number
WO2008149676A1
WO2008149676A1 PCT/JP2008/059381 JP2008059381W WO2008149676A1 WO 2008149676 A1 WO2008149676 A1 WO 2008149676A1 JP 2008059381 W JP2008059381 W JP 2008059381W WO 2008149676 A1 WO2008149676 A1 WO 2008149676A1
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WIPO (PCT)
Prior art keywords
same
stain
agent composition
proofing agent
mass
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Application number
PCT/JP2008/059381
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English (en)
French (fr)
Inventor
Hiroyuki Hara
Shuichiro Sugimoto
Takao Hirono
Takashige Maekawa
Original Assignee
Asahi Glass Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Company, Limited filed Critical Asahi Glass Company, Limited
Priority to JP2009517777A priority Critical patent/JP5310550B2/ja
Priority to CA002686440A priority patent/CA2686440A1/en
Priority to KR1020097020338A priority patent/KR101431298B1/ko
Priority to EP08753058A priority patent/EP2149591B1/en
Priority to AT08753058T priority patent/ATE531778T1/de
Priority to ES08753058T priority patent/ES2373352T3/es
Priority to CN2008800179796A priority patent/CN101679835B/zh
Publication of WO2008149676A1 publication Critical patent/WO2008149676A1/ja
Priority to US12/626,739 priority patent/US8598291B2/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1637—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/22—Materials not provided for elsewhere for dust-laying or dust-absorbing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/27—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of alkylpolyalkylene glycol esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

　短鎖のペルフルオロアルキル基を用いたフッ素系の防汚加工剤組成物であって、揮発性の有機溶剤をほとんど含まない水分散液の形態とすることができ、良好な汚れ除去性（ＳＲ性）を有する防汚加工剤組成物を提供する。 　炭素数１～６のペルフルオロアルキル基を有する重合単位（ａ’）の３０～７０質量％と、アルキレンオキシド鎖を有する重合単位（ｂ’）の２０～６９質量％と、アミノ基を有する重合単位（ｃ’）の１～１０質量％を含み、主鎖末端にアニオン性基を有する含フッ素共重合体を含有することを特徴とする防汚加工剤組成物。
PCT/JP2008/059381 2007-05-30 2008-05-21 防汚加工剤組成物およびその製造方法ならびに加工物品 WO2008149676A1 (ja)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2009517777A JP5310550B2 (ja) 2007-05-30 2008-05-21 防汚加工剤組成物およびその製造方法ならびに加工物品
CA002686440A CA2686440A1 (en) 2007-05-30 2008-05-21 Antifouling composition, method for its production and article treated therewith
KR1020097020338A KR101431298B1 (ko) 2007-05-30 2008-05-21 방오 가공제 조성물 및 그 제조 방법 그리고 가공물품
EP08753058A EP2149591B1 (en) 2007-05-30 2008-05-21 Stain-proofing agent composition, method for producing the same and article processed with the same
AT08753058T ATE531778T1 (de) 2007-05-30 2008-05-21 Zusammensetzung für ein schmutzabweisendes mittel,verfahren zur herstellung und damit bearbeiteter artikel
ES08753058T ES2373352T3 (es) 2007-05-30 2008-05-21 Composición con agente de impermeabilización de manchas, método para producir la misma y artículo procesado con la misma.
CN2008800179796A CN101679835B (zh) 2007-05-30 2008-05-21 防污加工剂组合物及其制造方法及加工物品
US12/626,739 US8598291B2 (en) 2007-05-30 2009-11-27 Antifouling composition, method for its production and article treated therewith

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007143463 2007-05-30
JP2007-143463 2007-05-30

Related Child Applications (1)

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US12/626,739 Continuation US8598291B2 (en) 2007-05-30 2009-11-27 Antifouling composition, method for its production and article treated therewith

Publications (1)

Publication Number Publication Date
WO2008149676A1 true WO2008149676A1 (ja) 2008-12-11

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PCT/JP2008/059381 WO2008149676A1 (ja) 2007-05-30 2008-05-21 防汚加工剤組成物およびその製造方法ならびに加工物品

Country Status (10)

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US (1) US8598291B2 (ja)
EP (1) EP2149591B1 (ja)
JP (1) JP5310550B2 (ja)
KR (1) KR101431298B1 (ja)
CN (1) CN101679835B (ja)
AT (1) ATE531778T1 (ja)
CA (1) CA2686440A1 (ja)
ES (1) ES2373352T3 (ja)
TW (1) TWI448479B (ja)
WO (1) WO2008149676A1 (ja)

Cited By (7)

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Publication number Priority date Publication date Assignee Title
WO2010123042A1 (ja) * 2009-04-23 2010-10-28 旭硝子株式会社 撥水撥油剤組成物、その製造方法および物品の処理方法
WO2010140668A1 (ja) * 2009-06-05 2010-12-09 旭硝子株式会社 撥水撥油剤組成物、その製造方法および物品の処理方法
US20120016070A1 (en) * 2009-03-25 2012-01-19 Daikin Industries Ltd. Surfactant comprising fluorine-containing polymer
US20120149860A1 (en) * 2009-08-20 2012-06-14 Agc Seimi Chemical Co.,Ltd. Fluoroalkyl group-containing n-substituted (meth)acrylamide compound, polymer thereof , and use thereof
WO2019171968A1 (ja) * 2018-03-07 2019-09-12 ナガセケムテックス株式会社 アクリル樹脂およびその製造方法、ならびに金属微粒子分散体
JP2019206769A (ja) * 2018-05-28 2019-12-05 ユニチカトレーディング株式会社 防汚性布帛およびその製造方法
JP2020084012A (ja) * 2018-11-22 2020-06-04 共栄社化学株式会社 コーティング剤用表面改質剤、コーティング剤、及び硬化塗膜

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JP5562018B2 (ja) * 2009-12-10 2014-07-30 株式会社リケン エンジン部品用コーティング組成物及びそれを用いたエンジン部品
IT1402906B1 (it) * 2010-11-30 2013-09-27 Milano Politecnico Rivestimento superficiale con composti perfluorurati come antifouling.
SG11201901465RA (en) 2016-08-25 2019-03-28 Gen Electric Reduced fouling of hydrocarbon oil
WO2021122709A1 (en) * 2019-12-18 2021-06-24 Basf Se Textile coated with malodor reducing polymers
US20210379621A1 (en) * 2020-06-09 2021-12-09 University Of North Texas Fluorinated polymers for corrosion protection of metal

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JPH0243210A (ja) * 1988-06-08 1990-02-13 Bayer Ag ペルフルオロアルキル基を含むコポリマー
JPH05271351A (ja) * 1992-01-22 1993-10-19 Bayer Ag フツ素含有コポリマー類およびそれらから製造した水分散液
JPH05279541A (ja) * 1992-01-22 1993-10-26 Bayer Ag フツ素含有コポリマー類の混合物
JP2777040B2 (ja) 1992-01-22 1998-07-16 バイエル・アクチエンゲゼルシヤフト フツ素含有コポリマー類およびそれらから製造した水分散液
JP3320491B2 (ja) 1993-03-24 2002-09-03 旭硝子株式会社 防汚加工剤
JP3820694B2 (ja) 1997-08-06 2006-09-13 ダイキン工業株式会社 新規共重合体および防汚加工剤
WO2000058416A1 (fr) * 1999-03-29 2000-10-05 Asahi Glass Company, Limited Composition hydrophobe et oleophobe dispersable dans l'eau
JP2004506073A (ja) * 2000-08-07 2004-02-26 アトフィナ 新規なフッ素化コポリマーと、その基材への被覆・含浸剤としての使用と、得られた基材
WO2005100421A1 (ja) * 2004-04-15 2005-10-27 Daikin Industries, Ltd. 含フッ素重合体および処理剤組成物
WO2007007743A1 (ja) * 2005-07-14 2007-01-18 Daikin Industries, Ltd. 含フッ素重合体および汚れ脱離剤
JP2007143463A (ja) 2005-11-28 2007-06-14 Hiroshima Univ 大腸菌を用いたリン酸化反応方法
JP2007333564A (ja) 2006-06-15 2007-12-27 Nec Network & Sensor Systems Ltd 海洋波計測システムおよび海洋波計測方法

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2010110339A1 (ja) * 2009-03-25 2012-10-04 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
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JP2015145511A (ja) * 2009-03-25 2015-08-13 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
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US20100076168A1 (en) 2010-03-25
CA2686440A1 (en) 2008-12-11
KR20100015330A (ko) 2010-02-12
US8598291B2 (en) 2013-12-03
EP2149591B1 (en) 2011-11-02
JPWO2008149676A1 (ja) 2010-08-26
EP2149591A1 (en) 2010-02-03
CN101679835B (zh) 2012-12-26
TW200911852A (en) 2009-03-16
EP2149591A4 (en) 2010-06-30
CN101679835A (zh) 2010-03-24
ATE531778T1 (de) 2011-11-15
TWI448479B (zh) 2014-08-11

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