WO2008133054A1 - 樹脂組成物、及びプリプレグ - Google Patents

樹脂組成物、及びプリプレグ Download PDF

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Publication number
WO2008133054A1
WO2008133054A1 PCT/JP2008/057194 JP2008057194W WO2008133054A1 WO 2008133054 A1 WO2008133054 A1 WO 2008133054A1 JP 2008057194 W JP2008057194 W JP 2008057194W WO 2008133054 A1 WO2008133054 A1 WO 2008133054A1
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WIPO (PCT)
Prior art keywords
thermoplastic resin
mass
resin particle
particle diameter
average particle
Prior art date
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PCT/JP2008/057194
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English (en)
French (fr)
Inventor
Yasuyuki Yokoe
Toru Kaneko
Hiroshi Numata
Takeshi Shimada
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Toho Tenax Co., Ltd.
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Publication date
Application filed by Toho Tenax Co., Ltd. filed Critical Toho Tenax Co., Ltd.
Priority to US12/594,278 priority Critical patent/US8211537B2/en
Priority to CA 2683073 priority patent/CA2683073A1/en
Priority to JP2009511785A priority patent/JPWO2008133054A1/ja
Priority to EP20080740291 priority patent/EP2138522A1/en
Publication of WO2008133054A1 publication Critical patent/WO2008133054A1/ja

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/504Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/241Preventing premature crosslinking by physical separation of components, e.g. encapsulation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/249948Fiber is precoated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/24995Two or more layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/24995Two or more layers
    • Y10T428/249952At least one thermosetting synthetic polymeric material layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2938Coating on discrete and individual rods, strands or filaments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31515As intermediate layer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

 本発明により、成分〔A〕エポキシ樹脂100質量部と、成分〔B〕熱可塑性樹脂粒子41~80質量部と、成分〔C〕コート剤によりマイクロカプセル化されたジアミノジフェニルスルフォンであってジアミノジフェニルスルフォンとして20~50質量部とを必須成分として含み、 成分〔B〕の熱可塑性樹脂粒子が、少なくとも平均粒径1~50μmの熱可塑性樹脂粒子〔B1〕と、平均粒径2~100μmの熱可塑性樹脂粒子〔B2〕とを質量比で3:1~1:3含み、且つ熱可塑性樹脂粒子〔B1〕の平均粒径D1に対する熱可塑性樹脂粒子〔B2〕の平均粒径D2の比D2/D1が2以上である樹脂組成物、該組成物を用いて製造するプリプレグが開示される。
PCT/JP2008/057194 2007-04-13 2008-04-11 樹脂組成物、及びプリプレグ WO2008133054A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/594,278 US8211537B2 (en) 2007-04-13 2008-04-11 Resin composition, and prepreg
CA 2683073 CA2683073A1 (en) 2007-04-13 2008-04-11 Resin composition, and prepreg
JP2009511785A JPWO2008133054A1 (ja) 2007-04-13 2008-04-11 樹脂組成物、及びプリプレグ
EP20080740291 EP2138522A1 (en) 2007-04-13 2008-04-11 Resin composition, and prepreg

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007106594 2007-04-13
JP2007-106594 2007-04-13

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WO2008133054A1 true WO2008133054A1 (ja) 2008-11-06

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US (1) US8211537B2 (ja)
EP (1) EP2138522A1 (ja)
JP (1) JPWO2008133054A1 (ja)
CA (1) CA2683073A1 (ja)
WO (1) WO2008133054A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010055811A1 (ja) * 2008-11-13 2010-05-20 東邦テナックス株式会社 熱硬化性樹脂組成物とそれを用いたプリプレグ
JP2010144118A (ja) * 2008-12-22 2010-07-01 Toho Tenax Co Ltd プリプレグとその製造方法
JP2012528224A (ja) * 2009-05-29 2012-11-12 サイテク・テクノロジー・コーポレーシヨン 層間強化用のエンジニアリングされた架橋結合された熱可塑性粒子
JPWO2013015299A1 (ja) * 2011-07-27 2015-02-23 東レ株式会社 プリプレグおよび繊維強化複合材料
JP2016160367A (ja) * 2015-03-03 2016-09-05 東レ株式会社 樹脂フィルムおよびその製造方法
KR101832017B1 (ko) 2010-11-09 2018-04-04 사이텍 테크놀러지 코포레이션 2차 강인화를 위한 융화성 캐리어
JPWO2018066600A1 (ja) * 2016-10-04 2018-10-04 三菱ケミカル株式会社 プリプレグ、プリプレグ積層体、および繊維強化複合材料

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EP2781539A1 (en) * 2013-03-19 2014-09-24 Siemens Aktiengesellschaft Fibre reinforced plastic composite, method of manufacturing thereof, plastic composite starting material for manufacturing the fibre reinforced plastic composite, and component of a wind turbine comprising the fibre reinforced plastic composite
US10077385B2 (en) * 2016-02-12 2018-09-18 Fuji Electric Co., Ltd. Resin composition and electronic component
JP6447557B2 (ja) * 2016-03-24 2019-01-09 日亜化学工業株式会社 発光装置の製造方法
US10677238B2 (en) 2017-11-08 2020-06-09 Ingersoll-Rand Industrial U.S., Inc. Filled resin layer separated pump housing
CN110183824A (zh) * 2019-07-09 2019-08-30 南通德泰新材料科技有限公司 一种导热绝缘环氧树脂层压复合材料及其制备方法和应用
CN113277824B (zh) * 2021-03-11 2022-06-14 湖南大学 一种无机胶浸渍碳纤维的固化方法

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JPS61250021A (ja) 1985-04-30 1986-11-07 Toray Ind Inc プリプレグ用マトリツクス樹脂組成物
JPS6257417A (ja) 1985-09-06 1987-03-13 Toray Ind Inc プリプレグ用エポキシ樹脂組成物
JPS63162732A (ja) 1986-12-25 1988-07-06 Toray Ind Inc プリプレグ
JPH04249544A (ja) 1990-12-28 1992-09-04 Toho Rayon Co Ltd プリプレグ及びその製造方法
JPH07304968A (ja) * 1994-03-15 1995-11-21 Toray Ind Inc マイクロカプセル型硬化剤、その製造法、熱硬化性樹脂組成物、プリプレグおよび繊維強化複合材料
JPH0925393A (ja) * 1995-05-09 1997-01-28 Toray Ind Inc 繊維強化複合材料用エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
JP2001323046A (ja) * 2000-05-16 2001-11-20 Toray Ind Inc 熱硬化性樹脂組成物及びプリプレグ
JP2002212320A (ja) * 2001-01-23 2002-07-31 Toray Ind Inc プリプレグおよび極低温タンク
JP2006291095A (ja) * 2005-04-13 2006-10-26 Yokohama Rubber Co Ltd:The 繊維強化複合材料用エポキシ樹脂組成物
JP2007314753A (ja) * 2006-04-25 2007-12-06 Yokohama Rubber Co Ltd:The 繊維強化複合材料用エポキシ樹脂組成物

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JPS61250021A (ja) 1985-04-30 1986-11-07 Toray Ind Inc プリプレグ用マトリツクス樹脂組成物
JPS6257417A (ja) 1985-09-06 1987-03-13 Toray Ind Inc プリプレグ用エポキシ樹脂組成物
JPS63162732A (ja) 1986-12-25 1988-07-06 Toray Ind Inc プリプレグ
JPH04249544A (ja) 1990-12-28 1992-09-04 Toho Rayon Co Ltd プリプレグ及びその製造方法
JPH07304968A (ja) * 1994-03-15 1995-11-21 Toray Ind Inc マイクロカプセル型硬化剤、その製造法、熱硬化性樹脂組成物、プリプレグおよび繊維強化複合材料
JPH0925393A (ja) * 1995-05-09 1997-01-28 Toray Ind Inc 繊維強化複合材料用エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
JP2001323046A (ja) * 2000-05-16 2001-11-20 Toray Ind Inc 熱硬化性樹脂組成物及びプリプレグ
JP2002212320A (ja) * 2001-01-23 2002-07-31 Toray Ind Inc プリプレグおよび極低温タンク
JP2006291095A (ja) * 2005-04-13 2006-10-26 Yokohama Rubber Co Ltd:The 繊維強化複合材料用エポキシ樹脂組成物
JP2007314753A (ja) * 2006-04-25 2007-12-06 Yokohama Rubber Co Ltd:The 繊維強化複合材料用エポキシ樹脂組成物

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010055811A1 (ja) * 2008-11-13 2010-05-20 東邦テナックス株式会社 熱硬化性樹脂組成物とそれを用いたプリプレグ
EP2366742A1 (en) * 2008-11-13 2011-09-21 Toho Tenax CO., LTD. Thermosetting resin composition and prepreg utilizing same
EP2366742A4 (en) * 2008-11-13 2013-01-02 Toho Tenax Co Ltd THERMOSETTING RESIN COMPOSITION AND PREPREGATION USING THE SAME
JP5469086B2 (ja) * 2008-11-13 2014-04-09 東邦テナックス株式会社 熱硬化性樹脂組成物とそれを用いたプリプレグ
JP2010144118A (ja) * 2008-12-22 2010-07-01 Toho Tenax Co Ltd プリプレグとその製造方法
JP2012528224A (ja) * 2009-05-29 2012-11-12 サイテク・テクノロジー・コーポレーシヨン 層間強化用のエンジニアリングされた架橋結合された熱可塑性粒子
KR101832017B1 (ko) 2010-11-09 2018-04-04 사이텍 테크놀러지 코포레이션 2차 강인화를 위한 융화성 캐리어
JPWO2013015299A1 (ja) * 2011-07-27 2015-02-23 東レ株式会社 プリプレグおよび繊維強化複合材料
KR101911976B1 (ko) * 2011-07-27 2018-10-25 도레이 카부시키가이샤 프리프레그 및 섬유 강화 복합 재료
JP2016160367A (ja) * 2015-03-03 2016-09-05 東レ株式会社 樹脂フィルムおよびその製造方法
JPWO2018066600A1 (ja) * 2016-10-04 2018-10-04 三菱ケミカル株式会社 プリプレグ、プリプレグ積層体、および繊維強化複合材料
US11292883B2 (en) 2016-10-04 2022-04-05 Mitsubishi Chemical Corporation Prepreg, prepreg laminate, and fiber-reinforced composite material

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US8211537B2 (en) 2012-07-03
EP2138522A1 (en) 2009-12-30
CA2683073A1 (en) 2008-11-06
JPWO2008133054A1 (ja) 2010-07-22
US20100183862A1 (en) 2010-07-22

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