WO2008108438A1 - 耐熱性、耐久性、離型性、及び防汚性シランカップリング剤、並びにそれらの化合物の製造方法 - Google Patents

耐熱性、耐久性、離型性、及び防汚性シランカップリング剤、並びにそれらの化合物の製造方法 Download PDF

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Publication number
WO2008108438A1
WO2008108438A1 PCT/JP2008/054074 JP2008054074W WO2008108438A1 WO 2008108438 A1 WO2008108438 A1 WO 2008108438A1 JP 2008054074 W JP2008054074 W JP 2008054074W WO 2008108438 A1 WO2008108438 A1 WO 2008108438A1
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WO
WIPO (PCT)
Prior art keywords
coupling agents
silane coupling
releasability
durability
heat resistance
Prior art date
Application number
PCT/JP2008/054074
Other languages
English (en)
French (fr)
Inventor
Norio Yoshino
Original Assignee
Tokyo University Of Science Educational Foundation Administrative Organization
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo University Of Science Educational Foundation Administrative Organization filed Critical Tokyo University Of Science Educational Foundation Administrative Organization
Priority to JP2009502622A priority Critical patent/JP4487037B2/ja
Priority to EP08721494A priority patent/EP2133354A4/en
Priority to CN2008800069673A priority patent/CN101646682B/zh
Priority to US12/529,772 priority patent/US8420212B2/en
Publication of WO2008108438A1 publication Critical patent/WO2008108438A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/76—Hydrophobic and oleophobic coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/261—In terms of molecular thickness or light wave length
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31609—Particulate metal or metal compound-containing
    • Y10T428/31612—As silicone, silane or siloxane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

Abstract

　３５０°C以上の雰囲気に４時間以上曝露しても接触角の低下が見られないほどの耐熱性、耐久性、離型性、及び防汚性を有するシランカップリング剤を提供する。　下記一般式（１）で表されるビフェニルアルキル基を有するシランカップリング剤は、３５０°C以上の雰囲気に４時間以上曝露しても、これら化合物による改質表面の接触角の低下が見られないというほどの優れた耐熱性、耐久性、離型性、及び防汚性を有するものであり、格別の効果と有用性を有する。 ［式（１）中、ＲｆはＦ（ＣＦ２）ｎのペルフルオロアルキル基を示し、ｎは１～１４の整数、好ましくは１～１２の整数、より好ましくは４～１２の整数、さらに好ましくは４～１０の整数を示す。］
PCT/JP2008/054074 2007-03-06 2008-03-06 耐熱性、耐久性、離型性、及び防汚性シランカップリング剤、並びにそれらの化合物の製造方法 WO2008108438A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2009502622A JP4487037B2 (ja) 2007-03-06 2008-03-06 耐熱性、耐久性、離型性、及び防汚性シランカップリング剤、並びにそれらの化合物の製造方法
EP08721494A EP2133354A4 (en) 2007-03-06 2008-03-06 SILANE COUPLING AGENTS HAVING HEAT RESISTANCE, SUSTAINABILITY, RELEASE AND ANTIFOULING PROPERTIES, METHOD FOR THE PRODUCTION OF THESE COMPOUNDS
CN2008800069673A CN101646682B (zh) 2007-03-06 2008-03-06 耐热性、耐久性、脱模性和防污性硅烷偶联剂及其制造方法
US12/529,772 US8420212B2 (en) 2007-03-06 2008-03-06 Silane coupling agents with heat resistance, durability, releasability and antifouling property, and process for producing these compounds

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007055975 2007-03-06
JP2007-055975 2007-03-06

Publications (1)

Publication Number Publication Date
WO2008108438A1 true WO2008108438A1 (ja) 2008-09-12

Family

ID=39738305

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/054074 WO2008108438A1 (ja) 2007-03-06 2008-03-06 耐熱性、耐久性、離型性、及び防汚性シランカップリング剤、並びにそれらの化合物の製造方法

Country Status (5)

Country Link
US (1) US8420212B2 (ja)
EP (1) EP2133354A4 (ja)
JP (1) JP4487037B2 (ja)
CN (1) CN101646682B (ja)
WO (1) WO2008108438A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011021100A (ja) * 2009-07-15 2011-02-03 Nippon Soken Inc デポジット付着防止材料および燃料噴射弁
JP2011184304A (ja) * 2010-03-04 2011-09-22 Tokyo Univ Of Science シランカップリング剤及びその製造方法
JP2011187510A (ja) * 2010-03-04 2011-09-22 Tokyo Univ Of Science 金属微細構造体及びその製造方法並びに樹脂成形物の製造方法
WO2016052262A1 (ja) * 2014-09-30 2016-04-07 ユニマテック株式会社 含フッ素アルキルシラン化合物およびその製造法
WO2016052263A1 (ja) * 2014-09-30 2016-04-07 ユニマテック株式会社 ポリフルオロアルキルアリル化合物およびその製造法
US9637644B2 (en) 2011-01-10 2017-05-02 Samsung Electronics Co., Ltd. Composition for coating film to prevent conspicuous fingerprints, coating film to prevent conspicuous fingerprints using the composition, and article having the coating film

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5419040B2 (ja) * 2008-09-05 2014-02-19 学校法人東京理科大学 転写構造体の製造方法及びそれに用いる母型
CN113666956B (zh) * 2021-08-25 2023-04-25 上海橡实化学有限公司 一种水杨醛亚胺硅烷偶联剂及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09315923A (ja) 1996-05-29 1997-12-09 Norio Yoshino 歯の表面改質剤およびそれを用いた歯表面の改質方法
JPH10265242A (ja) 1997-03-24 1998-10-06 Showa Alum Corp 透明はっ水皮膜およびその製造方法
JP2000342602A (ja) 1999-06-04 2000-12-12 Agency Of Ind Science & Technol 汚濁物質付着抑制材およびその製造方法
JP2004107274A (ja) 2002-09-19 2004-04-08 Norio Yoshino 耐熱性シランカップリング剤、およびそれらの化合物の製造方法
JP2008063594A (ja) * 2006-09-05 2008-03-21 T & K:Kk 含フッ素薄膜および該含フッ素薄膜を有する基材の製造方法

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JP2000169483A (ja) 1998-12-02 2000-06-20 Daikin Ind Ltd 親水・疎水の両基を有する表面処理剤
CN100396751C (zh) * 2005-06-21 2008-06-25 广州市白云化工实业有限公司 一种有机硅氟防水剂及其制备方法
JP2007238567A (ja) 2006-03-10 2007-09-20 Tokyo Univ Of Science シランカップリング剤、歯科用コンポジットレジン、及びこのシランカップリング剤を含む歯科用プライマー
JP2008266313A (ja) 2007-03-26 2008-11-06 Asahi Glass Co Ltd 新規なフルオロアダマンタン誘導体、その製造方法、および組成物
JP2009132637A (ja) 2007-11-29 2009-06-18 Tokyo Univ Of Science エポキシ基含有ビフェニル化合物およびその製造方法、並びに表面改質剤、接着助剤および接着剤

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09315923A (ja) 1996-05-29 1997-12-09 Norio Yoshino 歯の表面改質剤およびそれを用いた歯表面の改質方法
JPH10265242A (ja) 1997-03-24 1998-10-06 Showa Alum Corp 透明はっ水皮膜およびその製造方法
JP2000342602A (ja) 1999-06-04 2000-12-12 Agency Of Ind Science & Technol 汚濁物質付着抑制材およびその製造方法
JP2004107274A (ja) 2002-09-19 2004-04-08 Norio Yoshino 耐熱性シランカップリング剤、およびそれらの化合物の製造方法
JP2008063594A (ja) * 2006-09-05 2008-03-21 T & K:Kk 含フッ素薄膜および該含フッ素薄膜を有する基材の製造方法

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"3rd section, Development and Performance Advances of Fluorine-Containing Coating Agent", JOHOKIKO CO., article "Development of Water-Repellent, Hydrophilic, Antifouling Agent and Control of Coating and Wettability", pages: 108 - 121
JOURNAL OF FLUORINE CHEMISTRY, vol. 127, 2006, pages 1058 - 1065
See also references of EP2133354A4

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011021100A (ja) * 2009-07-15 2011-02-03 Nippon Soken Inc デポジット付着防止材料および燃料噴射弁
JP2011184304A (ja) * 2010-03-04 2011-09-22 Tokyo Univ Of Science シランカップリング剤及びその製造方法
JP2011187510A (ja) * 2010-03-04 2011-09-22 Tokyo Univ Of Science 金属微細構造体及びその製造方法並びに樹脂成形物の製造方法
US10809423B2 (en) 2011-01-10 2020-10-20 Samsung Electronics Co., Ltd. Composition for coating film to prevent conspicuous fingerprints, coating film to prevent conspicuous fingerprints using the composition, and article having the coating film
KR101800743B1 (ko) * 2011-01-10 2017-11-24 삼성전자주식회사 지문 돋보임 방지 피막용 조성물, 상기 조성물을 이용한 지문 돋보임 방지 피막, 및 상기 피막을 포함하는 물품
US9637644B2 (en) 2011-01-10 2017-05-02 Samsung Electronics Co., Ltd. Composition for coating film to prevent conspicuous fingerprints, coating film to prevent conspicuous fingerprints using the composition, and article having the coating film
KR20170063654A (ko) 2014-09-30 2017-06-08 유니마테크 가부시키가이샤 폴리플루오로알킬알릴 화합물 및 그 제조법
KR20170066379A (ko) 2014-09-30 2017-06-14 유니마테크 가부시키가이샤 함불소 알킬실레인 화합물 및 그 제조법
WO2016052263A1 (ja) * 2014-09-30 2016-04-07 ユニマテック株式会社 ポリフルオロアルキルアリル化合物およびその製造法
US10125154B2 (en) 2014-09-30 2018-11-13 Unimatec Co., Ltd. Fluorine-containing alkylsilane compound, and method for producing the same
US10125069B2 (en) 2014-09-30 2018-11-13 Unimatec Co., Ltd. Polyfluoroalkyl allyl compound and method for producing the same
US10131598B2 (en) 2014-09-30 2018-11-20 Nok Corporation Polyfluoroalkyl allyl compound and method for producing the same
WO2016052262A1 (ja) * 2014-09-30 2016-04-07 ユニマテック株式会社 含フッ素アルキルシラン化合物およびその製造法
KR102444487B1 (ko) 2014-09-30 2022-09-19 유니마테크 가부시키가이샤 함불소 알킬실레인 화합물 및 그 제조법

Also Published As

Publication number Publication date
US8420212B2 (en) 2013-04-16
CN101646682A (zh) 2010-02-10
EP2133354A4 (en) 2012-02-08
JP4487037B2 (ja) 2010-06-23
US20100119848A1 (en) 2010-05-13
EP2133354A1 (en) 2009-12-16
CN101646682B (zh) 2012-07-04
JPWO2008108438A1 (ja) 2010-06-17

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