WO2008029499A1 - Composition de nettoyant pour la peau - Google Patents

Composition de nettoyant pour la peau Download PDF

Info

Publication number
WO2008029499A1
WO2008029499A1 PCT/JP2007/000900 JP2007000900W WO2008029499A1 WO 2008029499 A1 WO2008029499 A1 WO 2008029499A1 JP 2007000900 W JP2007000900 W JP 2007000900W WO 2008029499 A1 WO2008029499 A1 WO 2008029499A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
particles
mass
soluble
disintegrating
Prior art date
Application number
PCT/JP2007/000900
Other languages
English (en)
Japanese (ja)
Inventor
Masaaki Moriyama
Noriyuki Tanaka
Keiko Matsuo
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corporation filed Critical Kao Corporation
Publication of WO2008029499A1 publication Critical patent/WO2008029499A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/022—Powders; Compacted Powders
    • A61K8/0225—Granulated powders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0275—Containing agglomerated particulates
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants

Definitions

  • the present invention relates to a skin cleanser composition.
  • a detergent composition containing particles is useful for removing old keratin and removing dirt that has entered pores.
  • a comfortable massage can be obtained by appropriate physical stimulation of the particles.
  • disintegrating particles are used from the viewpoint of safety, for example, disintegrating particles in which primary particles at least partially water-insoluble are aggregated, Disintegrating particles that disintegrate in a water-soluble salt-containing aqueous solution due to a decrease in the concentration of water-soluble salts (Patent Document 1) are known.
  • an active ingredient when blended in cosmetics, it is generally dissolved or dispersed uniformly in the system, but it is expected to obtain a high effect if it can be applied locally.
  • Patent Document 1 Japanese Patent Laid-Open No. 2 00 _ 6 3 8 9 9
  • Patent Document 2 Japanese Patent Laid-Open No. 5-8 5 7 7
  • An object of the present invention is to provide a skin cleanser composition that can provide a high effect of an active ingredient and that is tactilely and visually grainy.
  • the inventors of the present invention can obtain a high effect of the active ingredient by containing the active ingredient and / or the color pigment in the disintegrating particles and containing the water-soluble salt or the polyhydric alcohol at a high concentration. Further, it has been found that a skin cleanser composition having a clear grain feel can be obtained with the coloring pigment.
  • the present invention provides the following components (A), (B), (C) and (D):
  • the skin cleansing composition containing this is provided.
  • the skin cleanser composition of the present invention contains an active ingredient and / or a coloring material stably in the disintegrating particles, provides a high effect of the active ingredient, and the colored disintegrating particles are composed of It can be clearly confirmed by visual observation that it is contained in the product, and it has a clear grain feeling due to the colored pigment. Furthermore, the base of the cleaning composition has no color transfer and can contain particles of any color.
  • the disintegrating particles of the component (A) used in the present invention may be water-insoluble primary particles only, or those in which water-insoluble primary particles and water-soluble primary particles are aggregated, water-insoluble primary particles only, or water. It is preferable that insoluble primary particles and water-soluble primary particles are aggregated by a water-soluble binder. These primary particles may be organic particles or inorganic particles.
  • water-insoluble means that when 1 part by mass of the target particle is dissolved in 99 parts by mass of water at 25 ° C., the solubility is less than 50% by mass. "" Means that the solubility under the same conditions is 50% by mass or more. The solubility is calculated from the solid content in the filtrate obtained by filtering the aqueous solution with a filter paper (No. 2). As the water-soluble primary particles, those having a solubility of 90% by mass or more are preferable.
  • Water-insoluble organic primary particles include polyethylene, polypropylene, polyamide, polyethylene terephthalate, polystyrene, polyurethane and their cross-linked products, poly (meth) sodium acrylate, poly (meth) acrylate ester And other crosslinked polymers, and synthetic polymers such as rubbers such as ethylene rubber, propylene rubber, styrene-butadiene rubber, butadiene rubber, and silicone rubber, and crosslinked products thereof; cellulose and its derivatives, chitosan and its Derivatives, corn starch, starch, natural polymers such as fruit shells and derivatives thereof.
  • polyethylene, polyamide, polystyrene, poly (meth) acrylic acid sodium, poly (meth) acrylic acid ester, cellulose and derivatives thereof, corn starch, starch, and the like are preferable, and in particular, cone starch, cellulose, and derivatives thereof.
  • poly (meth) acrylic acid means both “polyacrylic acid” and “polymethacrylic acid”.
  • Water-insoluble inorganic primary particles include bentonite, talc, my strength, force ore, sepiolite, silica, calcium carbonate, titanium oxide, anhydrous silicic acid, hydroxy calcium apatite, and pearls. Quality and so on. Among them, bentonite, talc, my strength, kaolin, silica and the like are preferably used.
  • the shape of these water-insoluble primary particles is not particularly limited, and may be a spherical shape, a substantially spherical shape, or an irregular shape by pulverization or the like, or a hollow or porous particle may be used. . These water-insoluble primary particles may be used alone or in combination of two or more.
  • Water-soluble organic primary particles include polyvinyl alcohol and its derivatives, poly (meth) acrylic acid alkali salts, (meth) acrylic acid / (meth) acrylic.
  • Synthetic polymers such as alkali salt of acid ester copolymer, alkali salt of acrylic acid / maleic acid copolymer, polyvinylpyrrolidone; methylcellulose, ethyl cellulose, sodium carboxymethylcellulose, hydroxyalkyl cellulose, modified starch ( Hydroxyalkyl-modified starch, phosphate ester-modified starch, etc.), sugars such as sucrose and lactose; natural polymers such as seaweeds and proteins.
  • the water-soluble inorganic primary particles include sodium chloride, chloride chloride, magnesium chloride, and other chlorides; sodium sulfate, sulfate, lithium sulfate, sulfate, such as aluminum sulfate; sodium carbonate, And carbonates such as sodium hydrogen carbonate.
  • sodium chloride commercially available salt, highly purified salt, natural salt, etc. can be used.
  • inorganic particles such as sodium chloride, potassium chloride, magnesium chloride and sodium carbonate are preferred.
  • the shape of these water-soluble primary particles is not limited, and may be used alone or in combination of two or more.
  • An enclosure is preferred.
  • the average particle size of these primary particles is preferably 1 to 7 Om, and in particular, 5 to 7 Om is preferable in view of granulation.
  • the average particle size of the primary particles is within this range, it is preferable from the viewpoint of discomfort and washability of the primary particles when the disintegrating particles are disintegrated by the washing process of the object to be cleaned and rinse water or tears.
  • the active ingredient contained in the disintegrating particles may be either water-insoluble or water-soluble, and is not particularly limited as long as it is used in cosmetics.
  • a water-insoluble sebum-absorbing ingredient for example, a water-insoluble sebum-absorbing ingredient , Moisturizers, astringents, bactericides, UV absorbers, whitening agents, anti-inflammatory agents and the like.
  • water-insoluble sebum-absorbing ingredients include iron oxide, bengara, and zirconium oxide. Conium, aluminum oxide, bentonite with an average particle size of less than 1 m, force ore, silica, talc, my power, etc., zinc oxide, charcoal, “Trefill E—500”, “Trefill E_500” ”(Toray, manufactured by Dow Koning Co., Ltd.), etc.
  • moisturizers include amino acids such as L-arginine, alanine and glycine, lipids having moisturizing properties such as betaine, pyrrolidone carboxylic acid, ceramide and phospholipid, aloe, hypericum, okra Plant extracts having a moisturizing effect, natural products such as yogurt and honey, and extracts and fractions thereof.
  • amino acids such as L-arginine, alanine and glycine
  • lipids having moisturizing properties such as betaine, pyrrolidone carboxylic acid, ceramide and phospholipid, aloe, hypericum
  • okra Plant extracts having a moisturizing effect natural products such as yogurt and honey, and extracts and fractions thereof.
  • Examples of the astringent include metal oxides such as zinc oxide and magnesium oxide, aluminum hydroxychloride, and tannic acid.
  • bactericides examples include trichlorohydroxydiphenyl ether (tricksan sun), isopropylmethylphenol, trichlorocarbanilide, sanisoyl, hexaclonal fen, resorcin, crystal violet, base chloride Nzetonium, benzalkonium chloride, chlorhexidine gluconate and the like and their derivatives.
  • Examples of the ultraviolet absorber include benzoic acid-based ultraviolet absorbers such as paraaminobenzoic acid, glyceryl paraaminobenzoic acid, octyldimethylbenzoic acid, etc .; , Salicylic acid UV absorbers such as phenyl salicylate and p-isopropanol vinyl salicylate; octylcinnamate, ethyl _ 4- Sopropyl cinnamate, methyl 1,2,4-diisopropyl cinnamate, 2 _ethylhexyl _ p-methycin cinnamate, 2 _ hexyl hexyl — cyano _ S-phenyl cinnamate, glyceryl mono 1 _ethyl Cinnamic acid-based ultraviolet absorbers such as hexanol diparamethoxycinnamate, 3-hydroxy_4-sodium methoxyc
  • whitening agents include L-ascorbic acid and its derivatives, hydroquinone derivatives, placenta extract and ellagic acid and its derivatives, force mitsu, tea, earthen ground, kudzu, clove, licorice, aloe, altea, rose mariichi
  • plant extracts such as
  • Anti-inflammatory agents include, for example, indomethacin, methyl salicylate, diclofenac sodium, flufenamic acid, bufuexamac, ibuprofen, zaltoprofen, naproxen, flurbiprofen, flurbiprofen axetyl, fenbufen, mefenamic acid, piroxicam, Xycam, tenoxicam, fuerbinac, tocolletinate, hydrocortisone, prednisolone, methylprednisolone, betamethasone, dexamethasone, triamsilonone, triamsilononeacetonide, flumethasone, fluocononide, beclomethasone, fluocinorone, fluocinorone Steroidal or non-sterolic compounds such as tazone, clobetasone, clobetasol, and the like And derivatives thereof.
  • One or more active ingredients can be used, and can be blended in an appropriate amount in consideration of circumstances such as the concentration of the active ingredient, the strength of the required effect, appearance, feeling of use, and economy.
  • the amount is not uniquely limited, but generally it is preferably contained in the collapsible particles in an amount of 0.001 to 10% by mass.
  • the active ingredient in the present invention, by incorporating an active ingredient into the disintegrating particles, The active ingredient can be applied to the skin at a high concentration.
  • examples of the color pigment contained in the disintegrating particles include inorganic pigments such as iron oxide (Bengara), yellow iron oxide, black iron oxide, carbon black, titanium dioxide, ultramarine blue, and bitumen; Organic pigments such as red 2 0 1, red 2 0 2, red 2 2 6, yellow 4 0 1, blue 4 0 4; red 1 0 4, red 2 3 0, yellow 4, Examples include lake pigments such as yellow No. 5 and blue No. 1.
  • inorganic pigments such as iron oxide (Bengara), yellow iron oxide, black iron oxide, carbon black, titanium dioxide, ultramarine blue, and bitumen
  • Organic pigments such as red 2 0 1, red 2 0 2, red 2 2 6, yellow 4 0 1, blue 4 0 4
  • red 1 0 4, red 2 3 0, yellow 4 examples include lake pigments such as yellow No. 5 and blue No. 1.
  • One or more color pigments can be used, and can be combined in an appropriate amount depending on the color and appearance of the particles, and the content is not particularly limited, but generally in the collapsible particles. It is preferably contained in an amount of 0.1 to 10% by mass.
  • An active ingredient and a color pigment can be used in combination.
  • the disintegrating particles are preferably those in which the primary particles, the active ingredient and / or the color pigment are aggregated in a water-soluble binder.
  • water-soluble binders are those that dissolve in a water-soluble salt or polyhydric alcohol aqueous solution when the water-soluble salt or polyhydric alcohol concentration decreases, and precipitate when the water-soluble salt or polyhydric alcohol concentration increases.
  • polyvinyl alcohol and its derivatives (itaconic acid-modified polyvinyl alcohol, sulfonic acid-modified polyvinyl alcohol, maleic acid-modified polyvinyl alcohol, etc.), poly (meth) acrylic acid alkali salt, (meth) acrylic acid / (meta ) Alkali salts of acrylic ester copolymers, alkali salts of acrylic acid / maleic acid copolymers, synthetic polymers such as polyvinylpyrrolidone; methyl cellulose, ethyl cellulose, sodium carboxymethyl cellulose, hydroxyalkyl cellulose, starch derivatives, etc.
  • Half of Synthetic polymers natural polymers such as starch, seaweeds, plant mucilage, and proteins.
  • polyvinyl alcohol and derivatives thereof, sodium carboxymethyl cellulose, and hydroxyalkyl cellulose are preferable, and polyvinyl alcohol and derivatives thereof are particularly preferable.
  • the water-soluble primary particles and the water-soluble binder 1 may use the same type of material or different materials.
  • the water-soluble binder is used in an amount of 0.5 to 30% by mass based on the mass of the primary particles. From the viewpoint of workability at the time of manufacture of the disintegrating point of force particles and disintegrating particles or a skin cleansing composition containing the same.
  • Disintegrating particles are produced by dispersing active ingredients and / or color pigments while mixing with primary particles, and granulating using a water-soluble / inder.
  • rolling granulation For example, while mixing and / or mixing active ingredients and / or color pigments, primary particles, and water-soluble binders, rolling granulation, rolling fluid granulation, fluidized bed granulation, stirring, rolling granulation, melting It can be produced by a granulation method such as granulation, extrusion granulation, spray drying granulation or the like.
  • the disintegrating particles have a characteristic that the disintegration rate increases in a high-concentration water-soluble salt or polyhydric alcohol-containing aqueous solution due to a decrease in the water-soluble salt or polyhydric alcohol concentration. Therefore, when the disintegrating particles are blended in the cleaning composition, the disintegrating particles are stably dispersed without being disintegrated in the cleaning composition, and the water-soluble salt or the large amount in the cleaning process and the rinsing process are dispersed. The collapsible particles disintegrate as the alcohol concentration decreases.
  • the disintegrating properties of the disintegrating particles are that the water-soluble salt concentration is less than 1% by mass, particularly less than 1.5% by mass, or the polyhydric alcohol concentration is 1%. It is preferable to design so that at least a part of the aqueous solution is less than 5% by mass, particularly 10% by mass or less. From the viewpoint of rinsing with rinse water or tears, the water-soluble salt concentration is further 1%. More preferably less than 1.5% by weight, especially less than 1.5% by weight, or more than 60% by volume in an aqueous solution with a polyhydric alcohol concentration of less than 15% by weight, especially less than 10% by weight. . Further, the collapsed particles at this time preferably have an average particle size of 8 Om or less.
  • the average particle size of the disintegrating particles is preferably 70 to 80 Om, more preferably 70 to 60, and particularly preferably 70 to 3600 m.
  • the average particle size of the disintegrating particles is in the range of 70 to 80 Om, it is particularly preferable because the discomfort during use and skin irritation are low.
  • One or more types of disintegrating particles of the component (A) can be used, and 1 to 25% by mass, particularly 2 to 20% by mass in the total composition is used for cleaning and feel. Excel Therefore, it is preferable.
  • examples of the water-soluble salt include water-soluble inorganic salts and water-soluble organic salts, and water-soluble inorganic salts are more preferable.
  • water-soluble inorganic salt examples include chlorides such as sodium chloride, chloride chloride, magnesium chloride; sulfates such as sodium sulfate, sulfate sulfate, magnesium sulfate, and aluminum sulfate; sodium carbonate, sodium hydrogen carbonate And carbonates such as In the case of sodium chloride, commercially available salt, highly purified salt, natural salt, etc. can be used. Of these, sodium chloride, potassium chloride, magnesium chloride, and sodium carbonate are particularly preferably used.
  • the water-soluble salt of component (B) is contained in the entire composition in an amount of 1% by mass or more and less than saturated solubility, and preferably 1.5% by mass or more and less than saturated solubility. Within this range, the disintegrating particles can be contained stably without disintegrating, which is preferable from the viewpoint of disintegrating property and foaming property.
  • the saturated solubility is for water in the skin cleanser composition.
  • examples of the polyhydric alcohol include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, 1, Examples include glycols such as 4-butylene glycol; glycerols such as glycerin and diglycerin; sugar alcohols such as sorbitol, mannitol, xylitol, and maltitol.
  • One or more polyhydric alcohols of component (B) can be used, and the total composition is 15 to 70 mass 0 / &, preferably 15 to 60 mass 0 / &, particularly preferably Is contained in an amount of 20 to 50% by mass. Within this range, the disintegrating particles can be stably contained in the skin cleansing composition without disintegrating.
  • the surfactant of component (C) used in the present invention is preferably an anionic surfactant or a nonionic surfactant.
  • anionic surfactants include higher fatty acid salts such as sodium laurate, potassium laurate, and potassium palmitate; potassium lauryl phosphate, sodium lauryl phosphate, arginine lauryl phosphate, myristyl phosphate power, myristyl Alkyl phosphate ester salts such as sodium nomyristyl phosphate, potassium palmitate, sodium palmitate, arginine palmitate, polyoxyethylene (hereinafter referred to as POE) sodium oleylterphosphate, POE stearyl ether phosphate POE alkyl phosphates such as sodium sulfate; alkyl sulfates such as sodium lauryl sulfate and lauryl sulfate; ROE potassium lauryl sulfate, POE sodium lauryl sulfate, POE Uryl sulfate POE alkyl ether sulfate such as triethanolamine; Lauroyl sarcosine sodium,
  • alkyl phosphate esters and POE alkyl ether sulfates are preferred.
  • the nonionic surfactant include POE fatty acid ester, POE alkyl ether, fatty acid POE alkyl ether, POE sorbitan fatty acid ester, POE sorbit fatty acid ester, POE glycerin fatty acid ester, POE hydrogenated castor oil, poly Examples thereof include oxyethylene monopolyoxypropylene alkyl ether, polyglycerin fatty acid ester, fatty acid sucrose ester, alkyl polyglucoside, and sorbit fatty acid ester.
  • POE alkyl ether, POE hydrogenated castor oil, fatty acid sucrose ester, and alkyl polyglucoside are preferable.
  • One or more surfactants can be used, and it is preferably contained in an amount of 1 to 50% by mass, particularly 5 to 40% by mass in the total composition from the viewpoint of cleaning performance and foaming property.
  • the water of component (D) is preferably contained in an amount of 1 to 90% by mass, particularly 20 to 80% by mass in the total composition.
  • the skin cleansing composition of the present invention includes, in addition to the above-mentioned components, components used in ordinary cleaning composition, for example, humectants other than polyhydric alcohols, oil-based components, whitening agents, blood circulation Accelerators, anti-inflammatory agents, bactericides, ultraviolet absorbers, touch improvers, colorants, preservatives, antioxidants, fragrances, and the like can be used as long as the effects of the present invention are not impaired.
  • components used in ordinary cleaning composition for example, humectants other than polyhydric alcohols, oil-based components, whitening agents, blood circulation Accelerators, anti-inflammatory agents, bactericides, ultraviolet absorbers, touch improvers, colorants, preservatives, antioxidants, fragrances, and the like can be used as long as the effects of the present invention are not impaired.
  • the skin cleanser composition of the present invention can be produced by an ordinary method, and can be applied as a facial cleanser, a whole body cleanser or the like.
  • the skin cleansing composition of the present invention is used after being applied to the skin and massaged, and then washed and / or washed away.
  • the disintegrating particles provide a sufficient massage effect, and the disintegrating particles disintegrate in the washing and rinsing processes, so that no skin damage or itching occurs, and the washability is extremely good.
  • Disintegrating particles having the composition shown in Table 1 were produced.
  • the active ingredient, coloring pigment, etc. are added and mixed, and then a predetermined amount of binder is added to perform granulation.
  • collapsible particles (Production Examples 2 to 5) are prepared. )
  • the component (14) is added and dispersed uniformly.
  • Ingredients (12), (13) and (15) dispersed in 8) were added, mixed uniformly, and then cooled to 30 ° C. to obtain the face wash of Examples and Comparative Examples.
  • the appearance of the obtained face wash was visually observed and evaluated according to the following criteria.
  • X The base is colored. Colored grains cannot be confirmed.
  • a face wash having the composition shown in Table 3 was produced in the same manner as in Example 1, and the non-stickiness after face washing was evaluated.
  • component (1 2) and (1 3) is component (1 2)
  • component (1 4) is component (1 3
  • component (1 5) is component (1 4)
  • component ( 1 6) shall be read as component (1 5) respectively.
  • Table 3 The results are also shown in Table 3.
  • Sorbitol # 650 (Sorbit liquid, manufactured by Towa Industrial Co., Ltd.) 30.00 30.00 30.00

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition de nettoyant pour la peau qui peut exercer l'effet de son ingrédient actif de façon hautement efficace et qui présente une sensation granulaire sensible fournie par un pigment colorant contenu dans celle-ci. La composition de nettoyant pour la peau comprend les composants suivants (A), (B), (C) et (D) : (A) des particules dégradables obtenues par la dispersion d'un ingrédient actif et/ou d'un pigment colorant tout en mélangeant avec des particules primaires et en agglutinant le produit résultant à l'aide d'un liant soluble dans l'eau ; (B) un sel soluble dans l'eau en une quantité non inférieure à 1 % en masse et inférieure à la solubilité saturée de celui-ci, ou un alcool polyvalent en une quantité de 15 à 70 % en masse ; (C) un agent tensioactif ; et (D) de l'eau.
PCT/JP2007/000900 2006-08-29 2007-08-24 Composition de nettoyant pour la peau WO2008029499A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006232819 2006-08-29
JP2006-232819 2006-08-29

Publications (1)

Publication Number Publication Date
WO2008029499A1 true WO2008029499A1 (fr) 2008-03-13

Family

ID=39156945

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/000900 WO2008029499A1 (fr) 2006-08-29 2007-08-24 Composition de nettoyant pour la peau

Country Status (2)

Country Link
TW (1) TW200817042A (fr)
WO (1) WO2008029499A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012233057A (ja) * 2011-04-28 2012-11-29 Suzuki Yushi Kogyo Kk 生分解性スクラブ剤及び皮膚洗浄剤
CN112402290A (zh) * 2020-10-28 2021-02-26 广州博峰化工科技有限公司 磨砂粒子基料、磨砂粒子及其制备和应用
EP4066903A4 (fr) * 2019-11-25 2024-01-03 Kao Corporation Agent nettoyant pour la peau

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6318013B2 (ja) * 2013-06-13 2018-04-25 花王株式会社 洗浄剤組成物
JP7370214B2 (ja) * 2018-12-12 2023-10-27 花王株式会社 塩感応性粒子

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01190616A (ja) * 1988-01-25 1989-07-31 Kobayashi Kose Co Ltd 易崩壊性顆粒配合化粧料
JPH04198116A (ja) * 1990-11-29 1992-07-17 Mikimoto Pharmaceut Co Ltd スクラブ洗浄料
JPH05221826A (ja) * 1992-02-17 1993-08-31 Beiersdorf Ag 皮膚洗浄料
JP2000302630A (ja) * 1999-04-20 2000-10-31 Nippon Starch Chemical Co Ltd スクラブ剤およびその製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01190616A (ja) * 1988-01-25 1989-07-31 Kobayashi Kose Co Ltd 易崩壊性顆粒配合化粧料
JPH04198116A (ja) * 1990-11-29 1992-07-17 Mikimoto Pharmaceut Co Ltd スクラブ洗浄料
JPH05221826A (ja) * 1992-02-17 1993-08-31 Beiersdorf Ag 皮膚洗浄料
JP2000302630A (ja) * 1999-04-20 2000-10-31 Nippon Starch Chemical Co Ltd スクラブ剤およびその製造方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012233057A (ja) * 2011-04-28 2012-11-29 Suzuki Yushi Kogyo Kk 生分解性スクラブ剤及び皮膚洗浄剤
EP4066903A4 (fr) * 2019-11-25 2024-01-03 Kao Corporation Agent nettoyant pour la peau
CN112402290A (zh) * 2020-10-28 2021-02-26 广州博峰化工科技有限公司 磨砂粒子基料、磨砂粒子及其制备和应用

Also Published As

Publication number Publication date
TW200817042A (en) 2008-04-16

Similar Documents

Publication Publication Date Title
JP2008081496A (ja) 皮膚洗浄剤組成物
JP3511455B2 (ja) 化粧料
JP6318013B2 (ja) 洗浄剤組成物
WO1997036571A1 (fr) Agent ameliorant le teint de la peau
WO2008029499A1 (fr) Composition de nettoyant pour la peau
JP6050666B2 (ja) 洗浄剤組成物
JP2000143434A (ja) 粉末性の化粧料及び／又は皮膚科学的ロ―ション、並びにその使用
JP2022000465A (ja) 発泡性皮膚外用剤
US7795195B2 (en) Gel cosmetic composition comprising disintegrable particles, a polyol, a thickening polymer and water
JP5294591B2 (ja) ゲル状化粧料
JP2002020739A (ja) 発熱性粒子
ES2347168T3 (es) Composicion de detergente.
JPH03123732A (ja) マッサージ料
JP5680496B2 (ja) 温感洗浄剤
JP2006083140A (ja) 皮膚洗浄剤組成物
JP2000191510A (ja) 皮膚洗浄剤組成物
JP2000063899A (ja) 崩壊性粒子
JP2012106972A (ja) カルボキシルエチルセルロース含有ゲル状化粧料
JP3032531B1 (ja) 化粧料
WO2002056860A1 (fr) Compositions nettoyantes
WO2020121958A1 (fr) Particules sensibles au sel
JP2020094032A (ja) 塩感応性粒子
JP2001199876A (ja) 皮膚洗浄料
JP2001233722A (ja) 化粧料
JP7502860B2 (ja) 洗浄剤組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07790385

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

NENP Non-entry into the national phase

Ref country code: RU

122 Ep: pct application non-entry in european phase

Ref document number: 07790385

Country of ref document: EP

Kind code of ref document: A1