WO2007146686A3 - Pellicule antireflet durable - Google Patents

Pellicule antireflet durable Download PDF

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Publication number
WO2007146686A3
WO2007146686A3 PCT/US2007/070465 US2007070465W WO2007146686A3 WO 2007146686 A3 WO2007146686 A3 WO 2007146686A3 US 2007070465 W US2007070465 W US 2007070465W WO 2007146686 A3 WO2007146686 A3 WO 2007146686A3
Authority
WO
WIPO (PCT)
Prior art keywords
inorganic nanoparticles
surface modified
modified inorganic
refractive index
antireflective film
Prior art date
Application number
PCT/US2007/070465
Other languages
English (en)
Other versions
WO2007146686A2 (fr
Inventor
Christopher B. Walker Jr.
Marc D. Radcliffe
Thomas P. Klun
Lan H. Liu
Richard J. Pokorny
William D. Coggio
Chuntao Cao
Mark J. Pellerite
Paul C. Kelley
Robert J. Fleming
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Priority to CN2007800219229A priority Critical patent/CN101809465B/zh
Priority to US12/304,505 priority patent/US8137801B2/en
Priority to KR1020087030336A priority patent/KR101375897B1/ko
Priority to EP07798145A priority patent/EP2033020A2/fr
Priority to JP2009515567A priority patent/JP2009540391A/ja
Publication of WO2007146686A2 publication Critical patent/WO2007146686A2/fr
Publication of WO2007146686A3 publication Critical patent/WO2007146686A3/fr
Priority to US13/365,313 priority patent/US8343624B2/en
Priority to US13/690,064 priority patent/US8470439B2/en

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/111Anti-reflection coatings using layers comprising organic materials
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256Heavy metal or aluminum or compound thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264Up to 3 mils
    • Y10T428/2651 mil or less
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31935Ester, halide or nitrile of addition polymer

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

La présente invention concerne des pellicules antireflets comportant une couche de surface comprenant le produit de réaction d'une composition polymérisable à faible indice de réfraction comprenant au moins un matériau polymérisable à radicaux libres fluorés et des nanoparticules inorganiques modifiées en surface. Une couche à fort indice de réfraction est couplée à la couche à faible indice de réfraction. Dans un mode de réalisation, la couche à fort indice de réfraction comprend des nanoparticules inorganiques modifiées en surface dispersées dans un matériau organique réticulé. La pellicule antireflet est de préférence durable, présentant un voilage inférieur à 1,0% après avoir été frottée 25 fois avec une laine de fer au moyen d'un mandrin de 3,2 cm et d'une masse de 1000 grammes.
PCT/US2007/070465 2006-06-13 2007-06-06 Pellicule antireflet durable WO2007146686A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN2007800219229A CN101809465B (zh) 2006-06-13 2007-06-06 耐久性抗反射膜
US12/304,505 US8137801B2 (en) 2006-06-13 2007-06-06 Durable antireflective film
KR1020087030336A KR101375897B1 (ko) 2006-06-13 2007-06-06 내구성 반사방지 필름
EP07798145A EP2033020A2 (fr) 2006-06-13 2007-06-06 Pellicule antireflet durable
JP2009515567A JP2009540391A (ja) 2006-06-13 2007-06-06 耐久性の高い反射防止フィルム
US13/365,313 US8343624B2 (en) 2006-06-13 2012-02-03 Durable antireflective film
US13/690,064 US8470439B2 (en) 2006-06-13 2012-11-30 Durable antireflective film

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US42378106A 2006-06-13 2006-06-13
US11/423,781 2006-06-13
US11/427,055 2006-06-28
US11/427,055 US20070286994A1 (en) 2006-06-13 2006-06-28 Durable antireflective film

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
US11/427,055 Continuation-In-Part US20070286994A1 (en) 2006-06-13 2006-06-28 Durable antireflective film
US11/427,055 Continuation US20070286994A1 (en) 2006-06-13 2006-06-28 Durable antireflective film

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/304,505 A-371-Of-International US8137801B2 (en) 2006-06-13 2007-06-06 Durable antireflective film
US13/365,313 Continuation US8343624B2 (en) 2006-06-13 2012-02-03 Durable antireflective film

Publications (2)

Publication Number Publication Date
WO2007146686A2 WO2007146686A2 (fr) 2007-12-21
WO2007146686A3 true WO2007146686A3 (fr) 2010-05-27

Family

ID=38577920

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/070465 WO2007146686A2 (fr) 2006-06-13 2007-06-06 Pellicule antireflet durable

Country Status (7)

Country Link
US (3) US20070286994A1 (fr)
EP (1) EP2033020A2 (fr)
JP (1) JP2009540391A (fr)
KR (1) KR101375897B1 (fr)
CN (1) CN101809465B (fr)
TW (1) TWI393632B (fr)
WO (1) WO2007146686A2 (fr)

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US8470439B2 (en) 2013-06-25
US20130088782A1 (en) 2013-04-11
TW200808541A (en) 2008-02-16
US20070286994A1 (en) 2007-12-13
US8137801B2 (en) 2012-03-20
TWI393632B (zh) 2013-04-21
EP2033020A2 (fr) 2009-03-11
WO2007146686A2 (fr) 2007-12-21
CN101809465B (zh) 2013-04-10
JP2009540391A (ja) 2009-11-19
CN101809465A (zh) 2010-08-18
KR101375897B1 (ko) 2014-03-18
KR20090018951A (ko) 2009-02-24
US20100232021A1 (en) 2010-09-16

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