WO2007139118A1 - ヒートシール可能な包装紙及びヒートシール包装体 - Google Patents
ヒートシール可能な包装紙及びヒートシール包装体 Download PDFInfo
- Publication number
- WO2007139118A1 WO2007139118A1 PCT/JP2007/060925 JP2007060925W WO2007139118A1 WO 2007139118 A1 WO2007139118 A1 WO 2007139118A1 JP 2007060925 W JP2007060925 W JP 2007060925W WO 2007139118 A1 WO2007139118 A1 WO 2007139118A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- paper
- heat
- thermoplastic resin
- fiber
- weight
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/02—Wrappers or flexible covers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/67—Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material
- B65D85/671—Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material wound in flat spiral form
- B65D85/672—Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material wound in flat spiral form on cores
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/20—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Definitions
- the present invention relates to a heat-sealable wrapping paper and a heat-seal package.
- roll paper products such as toilet paper rolls and kitchen paper rolls are generally sold to consumers as a group (for example, Patent Document 1, 2).
- each product is generally packaged by a thermoplastic resin film 10 such as a polyethylene film in a state where a plurality of products are stacked as shown in FIGS.
- a thermoplastic resin film 10 such as a polyethylene film
- wrapping film 10 according to the outer shape of packaging object 11 as shown in the figure, wrapping and heat sealing the overlapping part of the film, gusset packaging, pillow packaging, etc. are used.
- a handle 12 made of the same material as the packaging material is attached to the outer surface of the packaging by heat sealing.
- thermoplastic resin film In such a packaging material using a thermoplastic resin film, there is a problem that there is a risk of breaking at the heat-sealed portion, or when a thick film is used to avoid this, the cost increases. Furthermore, from the viewpoint of resource recycling, the use of a thermoplastic resin film has the drawback that it is difficult to reuse the material.
- a packaging material in which a thermoplastic resin layer is laminated on one side of a paper base material has been proposed (see Patent Document 3).
- Such a packaging material is a very preferable packaging material in that it has a texture as paper, is waterproof, and can be heat-sealed. There was a problem that heat sealing could not be performed and the packaging form was limited.
- Patent Document 1 JIT No. 3010719
- Patent Document 2 JP 2005-153959 A
- Patent Document 3 Japanese Patent Application Laid-Open No. 63-12410
- the main problem of the present invention is that it has a texture as paper! And is waterproof, and can be heat-sealed on both the front and back sides, and is torn when held in the hand. It is to provide wrapping paper that suppresses the above.
- a heat-sealable wrapping paper that is a mixed paper made of norp fiber and thermoplastic resin fiber.
- thermoplastic resin a waterproof layer made of thermoplastic resin is laminated on only one side of the mixed paper.
- the main feature of the present invention is that a waterproof layer made of thermoplastic resin is laminated on one side of the mixed paper, or a sizing agent, a water repellent, etc. are added to the mixed paper to provide waterproofing and mixed paper.
- a waterproof layer made of thermoplastic resin is laminated on one side of the mixed paper, or a sizing agent, a water repellent, etc. are added to the mixed paper to provide waterproofing and mixed paper.
- the rice paper weight in the mixed paper is 25-55 gZm 2 .
- the content ratio of pulp fibers in the mixed paper is 50 to 75% by weight, and the content ratio of thermoplastic resin fibers in the mixed paper is 50 to 25% by weight, according to any one of claims 1 to 3.
- the blend ratio within the range described in this section, it will be excellent in a well-balanced manner in all of waterproofness, heat sealability, rupture strength, prevention of tearing when held in the hand and appropriateness of the carpenter. .
- a heat-sealed package characterized in that a target sealing portion is sealed by heat sealing in a state of wrapping an article.
- thermoplastic resin fiber is a composite fiber having a core-sheath structure in which the core is polypropylene and the sheath is polypropylene having a melting point lower than that of the core.
- the seal strength is not always sufficient. The reason for this is considered to be that the strength of polyethylene itself is expressed as it is and the sealing strength is low as long as polyethylene is used for the sheath as a binder even if a composite fiber having low strength of polyethylene itself is used.
- a core-sheath structure in which the core is polypropylene and the sheath is polypropylene having a melting point lower than that of the core.
- the strength of the polypropylene itself is higher than that of polyethylene and the bond strength between the polypropylene of the sheath and the polypropylene of the core is high, so even if the polypropylene of the sheath melts, it will still melt.
- bonding adheresion
- the package By providing a waterproof layer of thermoplastic resin on the inner surface side of the package, the package can be waterproofed.
- it is a laminated paper when opened, so it is paper-like. It is difficult to say that the viewpoint power of appearance is always preferable.
- the use of a sizing agent in the external application can provide the same water repellency or waterproofness as when a waterproof layer is provided.
- the alkyl ketene dimer (AKD) exhibits excellent water repellency or waterproofness in the blended composition of the mixed paper of the present invention as compared with other sizing agents, as shown in Examples described later. .
- the present invention if necessary, it has a texture as paper and exhibits water repellency or waterproofness, and furthermore, heat sealing is possible on both the front and back sides, and when held in the hand. Advantages such as deterring the breakage of
- FIG. 1 is a cross-sectional view of a wrapping paper according to the present invention.
- FIG. 2 is a perspective view of a toilet paper roll product.
- FIG. 3 is a perspective view of another product.
- FIG. 1 shows a cross section of a heat-sealable wrapping paper 1 according to the present invention.
- This wrapping paper 1 has a mixed paper layer 2 and, if necessary, a waterproof layer 3 laminated (laminated) only on one side thereof. have.
- the mixed paper layer 2 is formed by mixing pulp fibers and thermoplastic resin fibers.
- NLPP unbleached kraft pulp
- NBKP craftwood bleached kraft pulp
- LBKP hardwood bleached kraft pulp
- BCTMP combine chemi-thermometer-calp pulp
- TMP thermo mecha-cal pulp
- GP crushed wood pulp
- the sheath is a composite fiber having a core-sheath structure in which the sheath has a lower melting point than the core.
- the melting point of the core in the strong PP / PP composite fiber is 150-170 ° C, the melting point of the sheath is preferably 120-140 ° C, and the temperature difference between the melting points is 25-40 ° C. Desirable for workability with heat sealing machine!
- the mixing ratio of both fibers can be determined as appropriate.
- the pulp fiber is more than 50 to 75% by weight (especially 50 to 65% by weight), the thermoplastic resin fiber is less than 50 to 25% by weight (particularly less than 50 35% by weight) is preferred.
- the proportion of thermoplastic resin fiber is too small, heat sealability becomes poor, and when the proportion of pulp fiber is too small, the texture as paper becomes poor, or when it cannot be disposed of as paper There is. From this point of view, wrapping paper 1 (even if it contains a waterproof layer) is preferable because it makes it possible to dispose of paper as waste if it contains more than 50% by weight of pulp fiber.
- vinylon fibers can be mixed to improve the (rupture) strength of the mixed paper.
- the upper limit of the blending rate of vinylon fibers is preferably 7% by weight.
- the thermoplastic resin fiber preferably has a fineness of 0.5 to LOdtex and a fiber length of 2 to 30 mm. If the degree is less than 0.5 dtex, the adhesive strength is insufficient and sufficient paper strength cannot be obtained. Even if it exceeds lOdtex, the number of fibers per unit weight is reduced and the adhesive strength is low. The paper strength is not sufficient. If the fiber length is less than 2 mm, the adhesive strength is insufficient. If the fiber length is more than 30 mm, the dispersibility in water deteriorates and the paper strength decreases. A more preferable range of the fineness is 1 to 8 dtex, and a more preferable range of the fiber length is 3 to 20 mm. In addition, a olefin-based synthetic pulp which is not a cut fiber can be used.
- a waterproofing layer is not provided by the thermoplastic resin layer
- the type of sizing agent and water repellent is not limited.
- examples of sizing agents include alkyl ketene dimers, sizing agents such as styrene acrylic resin and rosin, olefin fin water repellents, and fluorine water repellents.
- Alkyl ketene dimers are particularly suitable.
- the water-repellent effect is high due to the small amount of coating.
- the addition amount of the sizing agent is preferably 2 to LO weight% with respect to the total fibers.
- silicone-based, acrylic-based, urethane-based, ester-based, oil-based fats or monomers can be used. More specific examples include paraffin-based nuts and natural waxes. Wax emulsion obtained by emulsifying wax such as polyamide; Synthetic resin such as polyamide resin and polyamine resin; Fluorine resin such as polytetrafluoroethylene and polychloroethylene; polymethylhydrogen siloxane and polydimethylsiloxane And the like.
- paper strength agents and yield improvers can be added as necessary.
- paper strength agents and yield improvers include polyacrylamide resin, polyamide epoxy hydrin resin, polyethyleneimine and its derivatives, polyethylene oxide, polyamine, polyamide, polyamide polyamine and its derivatives, cationic and amphoteric Starch, oxidized starch, carboxymethylated starch, plant gum, organic compounds such as polybulal alcohol, and sulfate band Inorganic compounds such as alumina sol, colloidal silica and bentonite are used in appropriate combination.
- a filler examples include talc, kaolin, calcined kaolin, clay, diatomaceous earth, heavy calcium carbonate, magnesium carbonate, aluminum hydroxide, titanium dioxide, magnesium sulfate.
- mineral fillers such as silica, aluminosilicate, bentonite, etc.
- organic synthetic fillers such as polystyrene particles, urea formalin resin particles, and the like can be appropriately selected and used in combination.
- paper additive aids such as dyes, pH adjusters, slime control agents, antifoaming agents, and stickers can be used as appropriate according to the intended use.
- the waterproof layer 3 provided if necessary is a water-impermeable layer made of a thermoplastic resin such as PE, PP, and PET.
- the material of the waterproof layer 3 is preferably the same as that of the thermoplastic resin fiber in the mixed paper layer 2, but can be different.
- the thickness 3t is not particularly limited, but is preferably 6 m or more. Desirably, it is 6 to 20 / ⁇ ⁇ . If it is less than 6 m, the waterproof property is poor, and if it exceeds 20 / z m, there is a problem that it is waterproof but is not easily torn when opening the wrapping paper.
- basis weight is preferably from 25 ⁇ 55gZm 2. If the weight is less than 25 gZm 2 , the strength will be insufficient and the product may be broken when holding the packaged product. On the other hand, if it is greater than 55 g / m 2 , the existing thermoplastic resin film packaging equipment cannot be used, and even if it can be used, the heat seal temperature is increased and the processing speed is lowered, resulting in poor operability. There is a case. In other words, if the weight is too low, the strength will be insufficient, and if the weight is too high, it will be difficult to use existing thermoplastic resin film packaging equipment.
- the lower limit is the strength required for a packaging bag, and if it exceeds the upper limit, opening becomes difficult and the cost of packaging paper increases.
- the wrapping paper 1 composed of force
- the waterproof layer 3 surface to waterproof layer 3 surface, waterproof layer 3 surface to mixed paper layer 2 surface, and mixed paper layer 2 surface to mixed paper layer 2 surface wrinkle ⁇
- good heat sealability is exhibited.
- the packaging form the above-mentioned caramel packaging, gusset packaging, pillow packaging, etc. can be adopted.
- Pulp fibers used (NUKP (unbleached kraft pulp)), thermoplastic fibers (composite fiber: core with a core (polypropylene (melting point: 165 ° C)) and sheath with polypropylene (melting point: 132 ° C) core-sheath composite fiber ( PPZPP composite fibers))
- specific examples of sizing agents and water repellents are listed in Tables 1 and 2.
- the heat seal strength was 170 ° C, which is close to the seal temperature when packaging PE film, and the seal time was 3 seconds.
- the test piece width of the seal strength measurement was 25 mm, and the peel strength was measured with a tensilon.
- heat-sealability when the paper surfaces of the wrapping paper are sealed with a heat sealer and the sealing part is peeled off, the wrapping paper breaks.
- Burst strength CFIS P 81 12) was also measured, and those with a burst strength of 0, 90kgfZcm 2 or more were marked with ⁇ , and those with less than that were marked with X.
- the range of burst strength is preferably 0, 90-1.95 kgfZcm 2 .
- Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 US tsubo (g / m 2 ) 30 50 30 60 30
- Thermoplastic resin sleep 33% 49% 33% 48% 48% Ingredients: Core «PP / PP PP PP PP PP PP / PP PP / PP
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
- Packages (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020087032003A KR101335471B1 (ko) | 2006-05-31 | 2007-05-29 | 히트실 가능한 포장지 및 히트실 포장체 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-152840 | 2006-05-31 | ||
JP2006152840 | 2006-05-31 | ||
JP2006-234629 | 2006-08-30 | ||
JP2006234629A JP5015530B2 (ja) | 2006-05-31 | 2006-08-30 | ヒートシール包装体 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007139118A1 true WO2007139118A1 (ja) | 2007-12-06 |
Family
ID=38778637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/060925 WO2007139118A1 (ja) | 2006-05-31 | 2007-05-29 | ヒートシール可能な包装紙及びヒートシール包装体 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP5015530B2 (ja) |
KR (1) | KR101335471B1 (ja) |
WO (1) | WO2007139118A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110344280A (zh) * | 2018-04-04 | 2019-10-18 | 特种东海制纸株式会社 | 纸 |
CN115056561A (zh) * | 2022-07-01 | 2022-09-16 | 浙江仙鹿新材料有限公司 | 一种防水型抗拉竹浆包装纸生产工艺 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012062102A (ja) * | 2010-09-17 | 2012-03-29 | Fretek:Kk | 食品鮮度保持具 |
JP2015160321A (ja) * | 2014-02-26 | 2015-09-07 | セイコーエプソン株式会社 | 接着紙及び接着紙の製造方法 |
JP2021054436A (ja) * | 2019-09-27 | 2021-04-08 | 日本製紙クレシア株式会社 | ロール製品包装体 |
JP7470500B2 (ja) * | 2019-09-30 | 2024-04-18 | 日本製紙クレシア株式会社 | 包装体 |
JP7470501B2 (ja) * | 2019-09-30 | 2024-04-18 | 日本製紙クレシア株式会社 | 包装体 |
JP2021155066A (ja) * | 2020-03-26 | 2021-10-07 | 大王製紙株式会社 | ロール紙製品の包装紙及び包装体 |
JP2021172415A (ja) * | 2020-04-30 | 2021-11-01 | 日本製紙クレシア株式会社 | トイレットロール包装体 |
JP7436307B2 (ja) * | 2020-06-30 | 2024-02-21 | 日本製紙クレシア株式会社 | 紙製品用包装体 |
JP7436308B2 (ja) * | 2020-07-02 | 2024-02-21 | 日本製紙クレシア株式会社 | 紙製品用包装体 |
JP2022127724A (ja) * | 2021-02-22 | 2022-09-01 | 大王製紙株式会社 | 包装袋、包装袋の製造方法、及びシート包装体 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61220840A (ja) * | 1985-03-28 | 1986-10-01 | 共同印刷株式会社 | 押出チユ−ブ |
JPS63126994A (ja) * | 1986-11-12 | 1988-05-30 | 株式会社 興人 | 通気性ヒ−トシ−ル−用紙 |
JP2000168829A (ja) * | 1998-12-04 | 2000-06-20 | Sumisho Kami Pulp Kk | 衣料品包装材及び衣料品包装用カバー |
JP2005112429A (ja) * | 2003-10-09 | 2005-04-28 | Daio Paper Corp | 食品包装用シート |
-
2006
- 2006-08-30 JP JP2006234629A patent/JP5015530B2/ja not_active Expired - Fee Related
-
2007
- 2007-05-29 KR KR1020087032003A patent/KR101335471B1/ko active IP Right Grant
- 2007-05-29 WO PCT/JP2007/060925 patent/WO2007139118A1/ja active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61220840A (ja) * | 1985-03-28 | 1986-10-01 | 共同印刷株式会社 | 押出チユ−ブ |
JPS63126994A (ja) * | 1986-11-12 | 1988-05-30 | 株式会社 興人 | 通気性ヒ−トシ−ル−用紙 |
JP2000168829A (ja) * | 1998-12-04 | 2000-06-20 | Sumisho Kami Pulp Kk | 衣料品包装材及び衣料品包装用カバー |
JP2005112429A (ja) * | 2003-10-09 | 2005-04-28 | Daio Paper Corp | 食品包装用シート |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110344280A (zh) * | 2018-04-04 | 2019-10-18 | 特种东海制纸株式会社 | 纸 |
CN115056561A (zh) * | 2022-07-01 | 2022-09-16 | 浙江仙鹿新材料有限公司 | 一种防水型抗拉竹浆包装纸生产工艺 |
Also Published As
Publication number | Publication date |
---|---|
KR20090028570A (ko) | 2009-03-18 |
JP5015530B2 (ja) | 2012-08-29 |
KR101335471B1 (ko) | 2013-11-29 |
JP2008007922A (ja) | 2008-01-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2007139118A1 (ja) | ヒートシール可能な包装紙及びヒートシール包装体 | |
JP2008007922A5 (ja) | ||
CN104755388B (zh) | 具有发泡聚合物层的窃启显示拉片式密封件 | |
US20230130087A1 (en) | Paper packaging material with improved resuspendability of cellulosic fibres | |
JP2023058567A (ja) | 開封及び再閉鎖性が改善された吸収性物品パッケージ | |
JP2008155433A (ja) | バリア性を有するヒ−トシ−ル性フィルム | |
TW200942411A (en) | Thermal melting multilayer film | |
CN101454219A (zh) | 能够热封的包装纸和热封包装体 | |
JP2008087785A (ja) | 包装材料 | |
JP6917129B2 (ja) | 紙製容器、および重袋 | |
JP7115055B2 (ja) | 撥液層形成用樹脂組成物、並びに、それを用いた撥液性フィルム、撥液性積層体、包装材及び容器 | |
JP4816073B2 (ja) | 紙容器 | |
JP5249536B2 (ja) | 二重袋包装体用インフレーションフィルムおよび二重袋包装体 | |
JP7214678B2 (ja) | 家庭用ロール紙包装体 | |
JP7470500B2 (ja) | 包装体 | |
JP7481826B2 (ja) | 包装体 | |
JP7470501B2 (ja) | 包装体 | |
CA2539389A1 (en) | Multilayer heat sealant structures, packages and methods of making the same | |
JP2013202980A (ja) | 蓋材 | |
EP2498985B1 (en) | A package for paper sheets | |
CN217951204U (zh) | 一种全撕离型易拉密封垫片 | |
JP7481827B2 (ja) | 包装体 | |
WO2023166989A1 (ja) | 包装袋、及びシート包装体 | |
JP5703904B2 (ja) | 蓋材 | |
JP2007269328A (ja) | 食品包装用シート |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200780019799.7 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07744344 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020087032003 Country of ref document: KR |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 07744344 Country of ref document: EP Kind code of ref document: A1 |