WO2007081015A1 - Element chauffant, procede pour produire cet element chauffant, et appareil d'incision associe - Google Patents

Element chauffant, procede pour produire cet element chauffant, et appareil d'incision associe Download PDF

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Publication number
WO2007081015A1
WO2007081015A1 PCT/JP2007/050442 JP2007050442W WO2007081015A1 WO 2007081015 A1 WO2007081015 A1 WO 2007081015A1 JP 2007050442 W JP2007050442 W JP 2007050442W WO 2007081015 A1 WO2007081015 A1 WO 2007081015A1
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WO
WIPO (PCT)
Prior art keywords
heating element
heating
cutting
section
heat generating
Prior art date
Application number
PCT/JP2007/050442
Other languages
English (en)
Japanese (ja)
Inventor
Toshihiro Dodo
Original Assignee
Mycoal Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mycoal Co., Ltd. filed Critical Mycoal Co., Ltd.
Publication of WO2007081015A1 publication Critical patent/WO2007081015A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
    • A61F7/02—Compresses or poultices for effecting heating or cooling
    • A61F7/03—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction
    • A61F7/032—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction using oxygen from the air, e.g. pocket-stoves

Definitions

  • Heating element Heating element manufacturing method and cutting installation device
  • the section of the heat generating element which is a heat generating element
  • the section of the heat generating element is provided with staggered cuts and is elastic, and the flexibility does not change before, during, and after the heat generation. Conforms well with the shape, efficiently transfers the heat of the heating element to the body, maintains stable heat generation characteristics, has excellent thermal effect, and causes redness, medical treatment, etc. even after long use.
  • the present invention relates to a heating element, a heat generating element, a stretchable heating element, a heating element manufacturing method, and a cutting installation device.
  • Conventional warmers are used by wrapping raw materials that generate heat (eg, iron powder, activated carbon, vermiculite, salt, superabsorbent resin) in a porous film or a nonwoven fabric alone or in a composite. Yes. It is used as a warmer that can be applied to the body with adhesive strength if necessary. Cairo has one heat generating part that heats a large area, and several heat generating parts cover that area.
  • heat eg, iron powder, activated carbon, vermiculite, salt, superabsorbent resin
  • a porous film, a non-woven fabric or other fiber material for protecting the skin or improving the contact with the skin is used as a packaging material. It has excellent properties and elasticity.
  • the heating element is attached to an extensible or elastic support, and the extensibility or elasticity of the support is then reduced. To compensate for stretchability or stretchability.
  • the heating element itself did not exhibit extensibility or stretchability 3;
  • Patent Document 1 Japanese Utility Model Publication No. 6-61222
  • a heating element comprising a single heat generating part, which has been commercially available in the past, does not follow a curved surface that lacks flexibility and does not have elasticity, ie, a force to move away from the fixed part, Because the force to peel off the heating part works, there was a problem that even if pasted, it would fall apart
  • the flat bag body thermal packaging body is half-cut, or the flat bag thermal packaging body is preliminarily placed in each thermal packaging body.
  • an object of the present invention is to provide a heating element, a method of manufacturing a heating element, and a manufacturing apparatus that are provided with extensibility or stretchability capable of mass production at low cost.
  • the heating element of the present invention is the heating element according to claim 1, wherein two or more divided heating parts are provided at intervals with the dividing part being a seal part as an interval.
  • a heat-generating composition formed from a heat-generating composition that generates heat upon contact with oxygen, and the segmented heat generating portions are provided in stripes, and one of at least one of the segmented portions.
  • the part has a cut.
  • the invention according to claim 2 is characterized in that, in the heating element according to claim 1, a connecting portion between the notches is shorter than the notches.
  • the invention according to claim 3 is the heating element according to claim 1 or 2, wherein the cuts are provided alternately.
  • the present invention according to claim 4 is the heating element according to any one of claims 1 to 3, wherein the exothermic composition molded body is a non-extensible part of the support via an adhesive. It is characterized in that it is provided in a stripe shape.
  • the present invention described in claim 5 is characterized in that, in the heating element according to claims 1 to 4, the section is provided so as to intersect, and the notch is provided in the intersecting region. To do.
  • the present invention according to claim 6 is characterized in that in the heating element according to claim 5, a through-hole capable of being deformed in the extending direction of the dividing portion is provided in the intersecting region.
  • the method for producing a heating element of the present invention comprises, as described in claim 7, a divided heating part having a heating composition and a sorting part being a seal part without the heating composition
  • the heating element is a method of manufacturing a heating element in which at least a part of the dividing portion is cut in a heating element formed in a concavo-convex shape by providing two or more dividing heating portions through the dividing portion.
  • a groove capable of accommodating the convex portion of the heating element is formed between the cutting roll provided with the cutting blade and the receiving roll, the heating element is passed between the two rolls, and the sectioning is performed.
  • a notch is provided in the part.
  • the present invention described in claim 8 is a method for manufacturing a heating element according to claim 7.
  • the cutting blade has at least one direction selected from a direction parallel to the axis of the cutting roll formed in a cylindrical shape, a direction perpendicular to the axis, and a direction inclined to the axis. And at least a part other than the divided heat generating portion, the connecting portion and the incision having the incising force are arranged adjacent to each other and different from each other.
  • the present invention according to claim 9 is the method of manufacturing a heating element according to claim 7 or 8, wherein the cutting blade is parallel to an axis of the cutting roll formed in a cylindrical shape. And provided in at least one direction selected from a direction perpendicular to the axis and a direction inclined with respect to the axis, and adjacent to at least a part other than the divided heat generating part and a notch that also has a cutting force. It is characterized by being arranged alternately.
  • the present invention according to claim 10 is the method of manufacturing a heating element according to any one of claims 7 to 9, wherein the notch by the cutting blade is divided into two or more times for the heating element. It is characterized by providing.
  • a continuous heating section in which a plurality of section heating section heating elements composed of the plurality of section heating sections are continuous.
  • the first step of manufacturing the heating element heating element and the continuous segment heating element heating element are transferred while penetrating at least part of the area other than the segment heating element of each segment heating element heating element.
  • the cutting installation device of the present invention comprises, as set forth in claim 12, a section heat generating portion having a heat generating composition and a section heating section having no heat generating composition, and the section heat generating section.
  • the cutting portion is a cutting installation device in which a cut is made in at least a part of the partitioning portion, and one or more cuttings are made It has a cutting roll having a blade and a receiving socket corresponding to it, and can store the convex body so that the convex body of the heating element in which at least one of the rolls is formed in a concave-convex shape is not affected by the cutting.
  • the present invention according to claim 13 is the cutting installation device according to claim 12, wherein the cutting blade is parallel to the axis of the cutting roll formed in a cylindrical shape, and to the axis. And at least one direction selected from a vertical direction and an inclination direction with respect to the axis.
  • the present invention described in claim 14 is the cutting installation device according to claim 12 or claim 13, wherein the cutting blade is provided on a blade provided with a notch or on the roll with a gap. It is at least one selected from blades and is characterized in that it forms a notch penetrating through the joint.
  • the present invention described in claim 15 is characterized in that, in the cutting installation device according to claim 14, the cutting blades are arranged adjacent to each other in a different manner.
  • the cutting installation device according to claim 16 is the cutting installation device according to any one of claims 12 to 15, wherein the receiving roll has a blade receiving tool provided on the cutting roll.
  • the present invention described in claim 17 is the incision installation device according to any one of claims 12 to 16, wherein the receiving roll has a receiving blade corresponding to the cutting blade.
  • the present invention according to claim 18 is the cutting installation device according to any one of claims 12 to 17, wherein the forming angle of the blade provided on the cutting roll is set to 0 with respect to the radial direction of the roller. Tilt in the circumferential direction at an angle of ⁇ 45 °.
  • the present invention according to claim 19 is characterized in that in the incision installation device according to any one of claims 12 to 18, the apparatus has a displacement means for displacing at least one of the incision roll and the receiving roll.
  • the exothermic composition is composed of a heat generating composition that generates heat when in contact with oxygen.
  • it contains a molded body, and further, the divided heat generating portions are provided in a stripe shape, and at least one portion of the region of the divided portion has a cut formed by a connecting portion and a cut formed therethrough.
  • the heating element has four or more divided heat generating portions configured as a plurality of divided heat generating portions.
  • the heating element is a heating element in which a plurality of segment heating parts are provided at intervals with a partition part as a seal part as an interval, and at least one part of the area of the partition part is configured by a notch penetrating the connecting part. It is preferable that the notch penetrated from the connecting portion is long and is a perforated notch.
  • the heating element is a heating element in which a plurality of segment heating parts are provided at intervals with a partition part as a seal part as an interval, and at least one part of the area of the partition part is configured by a notch penetrating the connecting part. And the cuts are reciprocal! Mistake! It is preferable that it is a notch.
  • the heating element is provided such that the exothermic composition molded body is provided in a stripe shape on a non-stretchable portion of the support via an adhesive (such as an adhesive).
  • the heating element has one or more crossing areas that reach the other side opposite to the heating element from the one side of the heating element and intersect, and at least one or more crossing areas. It is preferable that a notch composed of a connecting part and a notch penetrated is provided in each of a pair of dividing parts sharing the same.
  • the heating element is provided with a through hole that is deformed in at least one of the intersecting directions in at least one intersecting region of the intersecting region, wherein the notches are alternate notches. Preferred.
  • the heating element preferably has a minimum bending resistance of 100 mm or less. Moreover, it is preferable that the heating element is provided with fixing means on at least a part of the exposed portion of the heating element.
  • the fixing means is preferably an adhesive layer.
  • the change in the minimum bending resistance of the heating element before and after the heating element is preferably 30% or less.
  • the manufacturing method of the heating element of the present invention is a kind of a concavo-convex sheet-like body in which a plurality of convex bodies are provided at intervals with a concave body as an interval. It consists of a classification part that is a seal part that does not have an object. Between the adjacent heating sections, the section heating section is a convex body, the section other than the section heating section is a concave body, and the section heating section heating body composed of a plurality of section heating sections is strip-shaped.
  • Convex section storage section that uses continuous heating elements that are continuously connected, has a cutting tool with a cutting blade and a receiving roll corresponding to it, and at least one roll is not affected by the cutting blade And having a function of intermittently providing a notch penetrating at least a part of the recess by passing the concavo-convex sheet-like body between both rolls.
  • a segment heating part heating element is inserted into the continuous body segment heating part heating element by the cutting roll blade on the continuous segment heating part heating element as it advances while being transported. Less than At least a part, preferred to provide a notch cuts and penetrates a connecting portion provided alternately, the depressed regions is concave body.
  • a plurality of finite-length cutting blades are oriented parallel to each other along the cylindrical surface of the rotating body that is the cutting roll.
  • the cutting blade is a cutting roll that is a cutting roll that is fixed so that adjacent blades are in a zigzag position in a direction perpendicular to the direction of the blade. At least a part of the area other than the section heating section of each section heating section heating element while inserting and transporting the section section heating section heating section.
  • the manufacturing method of a heat generating body is the advancing direction of the said continuous body division
  • the manufacturing method of the heating element includes a blade provided on a cutting roll that rotates in the TD direction, which is a traveling direction of the continuous segment heating unit, and the segment heating unit of the continuous segment heating unit. It is preferable to provide a large number of cuts in which connecting portions and cuts are alternately provided in at least a part of the region other than the above.
  • the manufacturing method of the heating element is other than the section heating section of the continuous section section heating section heating element.
  • the heating element manufacturing method has block-shaped cutting blades provided in two or more directions in at least a part of the region other than the segment heating section of the continuous segment heating section. It is preferable to use an incision roll and provide incisions in which cuts penetrating the connecting portions and penetrating in two or more directions are provided alternately.
  • the cuts are staggered cuts.
  • the method for manufacturing a heating element is characterized in that the cut is a perforated cut.
  • the heating element manufacturing method is a method of manufacturing a heating element provided with a single notch using the heating element manufacturing method, and a divided heating part having a heating composition and a seal part having no heating composition.
  • the section is a space between the section heat generating section and the adjacent section heat generating section, and the section heating section heating element composed of a plurality of section heat generating sections is continuously connected in a strip shape.
  • the incision installation device is an incision installation device for providing an incision in a concave body of a concavo-convex sheet-like body in which a plurality of convex bodies are provided at intervals with a concave body as an interval.
  • Convex body storage section that has a cutting roll having a blade and a receiving roll corresponding to the cutting roll, and at least one of the rolls allows the convex body of the concavo-convex sheet-like body to be ejected by storage so that the cutting blade does not affect the convex body.
  • Concave and convex sheet between both rolls It is preferable to have a function of providing cuts in which cuts penetrating the connecting portions and through are alternately provided in at least a part of the concave body by passing the shaped body.
  • the cutting installation device has the cutting roll blades arranged as follows: 1. Placed along the circumferential direction (MD direction) 2. Axial direction (longitudinal direction, TD direction, lateral direction) 3. Arrangement provided along at least one direction between the circumferential direction and the axial direction, three kinds of arrangement forces to be preferred It was preferable that the arrangement was provided with at least one arrangement selected. Good.
  • the incision setting device is a block-like blade in which the blades of the incision roll are provided in two or more directions in a plurality of directions, and the connecting portions and the incisions penetrating in two or more directions are provided alternately. It is preferred that the cuts made can be provided.
  • the incision setting device has a function of alternately providing a notch penetrating with the connecting portion of the incision roll, 1. a cutting blade having a notch in the notching blade, and 2. a spacing between the cutting blades on the roll. It is preferable that the cutting force is at least one selected.
  • a plurality of finite length cutting blades orient the blade directions parallel to each other along the cylindrical surface of the cutting roll, and the cutting blades In a perpendicular direction, it is preferable that the notch and the spacing force are at least one kind of space in which the adjacent blades are fixed so that the adjacent blades are in a zigzag position.
  • the receiving roll has a receiving blade corresponding to the cutting blade of the cutting roll.
  • a cutting installation apparatus has the receiving device of the blade of a cutting roll.
  • the blade holder of the cutting roll is at least one selected from a gas injection port such as a processing concave portion, a convex portion, a sponge body, a rubber body, a plastic body, a brush-like object, and compressed air. I prefer to be there.
  • the cutting installation device inclines the forming angle of the blade of the cutting roll in the MD (traveling) direction at an angle of 0 to 45 ° with respect to the roller radius normal line of the blade.
  • the cutting installation device is a cutting device that makes a cut in contact with the uneven sheet body.
  • a receiving roll having a cutting roll, a receiving roll that receives the belt-shaped body abutted against the cutting roll, and a recess that receives the cutting roll when the cutting roll penetrates the concavo-convex sheet, and the cutting roll Displacement means (elevating device, expander) for displacing the receiving roll to the first position and the second position not forming the notch, the cutting roll and the receiving roll at the first position
  • the cutting roll and the receiving roll are guided to a predetermined position by means for fixing the cutting roll and the receiving roll to the displacement means (gap adjusting plate) and the blade of the rotary blade of the cutting roll so that the cutting roll is received in the recess, At least one of the cutting roll and the receiving roll is guided to a predetermined position where the blade and the recess are fitted according to the displacing means. It is preferred that and a guide means that.
  • the cutting installation device has an optical detection device arranged between the roll of the cutting installation device and the next process cut roll, and at least in an emergency, the operation of the cutting installation device is stopped at least by the output signal of the optical detection device.
  • the notch installation device is composed of a divided heat generating portion in which the uneven sheet-like body has a heat generating composition and a divided portion that is a seal portion not having a heat generating composition, and the divided portion is a divided heat generating portion and its adjacent section.
  • the section heating section is a convex body, the section other than the section heating section is a concave body, and the section heating section heating element composed of a plurality of section heating sections is continuously connected in a strip shape. It is preferable that the heating element is a continuous segmented heating element.
  • the cutting installation device forms at least one or more sets of alternating cuts in a plan view in a section of the heating element that is the concave body of the uneven sheet-like body.
  • the cutting installation device forms at least one perforation in a plan view in the section of the heating element that is the concave body of the uneven sheet-like body. ,.
  • the first cutting blade having a long blade is provided with a surface having a concave portion (groove) that is softer than the first cutting blade through the concave-convex sheet.
  • a recess corresponding to the first cutting blade is formed on the surface of the receiving roll, while a notch is formed in the recess of the uneven sheet-like body.
  • the second cutting blade whose blade is shorter than the first cutting blade is pressed against the surface of the receiving roll on which the concave portion is formed through the concave and convex sheet-like body, and the concave portion of the concave-convex sheet-like body.
  • a notch forming method characterized in that an incision is formed in is preferable.
  • the heating element of the present invention is provided with staggered cuts at least in a part of the section, it can be expanded and contracted in at least one direction even though it is a single heating element. It is easy to handle because it has a structure that is extremely easy to bend only in one direction compared to the other direction.
  • the heating element of the present invention is used as a thermal patch
  • the heating element, that is, the thermal patch is formed to be easily stretchable or stretchable, bent, or bendable.
  • the thermal patch is prevented from peeling off and adhesion to the outer skin is improved, and the curved part of the human body such as the shoulder or arm is used.
  • it has the effect of developing the thermal effect of the event and the therapeutic effect of the affected area.
  • the heating element of the present invention has a minimum bending resistance of the heating element of 100 mm or less, and the change in the minimum bending resistance of the heating element before and after the heat generation is 30% or less. Since it is typically 0%, the flexibility remains almost the same even after the beginning and end of use, and the adhesion to the curved surface is good.
  • the thermal patch of the present invention has stretchability and flexibility and can bend, the thermal patch can be further bent and stretched at curved parts such as joints such as elbows and knees, and stretchable parts.
  • curved parts such as joints such as elbows and knees, and stretchable parts.
  • Adhesiveness to the outer skin that can not be peeled off to the skin, and the required thermal effect and therapeutic effect on the affected area are exhibited at the curved and elastic parts such as the joints such as elbows and knees, and at the flexion and extension parts
  • the notch installation device of the present invention uses a roll having a convex body storage part (section heating part storage part), when installing a notch in an uneven sheet, the convex part is not Since it is protected, it is possible to easily make cuts in areas other than the convex part without damaging the convex part.
  • a section heating part heating element that is an example of an uneven sheet-like body
  • a convex part Is a segmented heat generating part
  • the concave part is a part other than the segmented heat generating part or a region around the heating element.
  • the incision installation device of the present invention divides the cutting blade provided on the roll of the incision installation device including the ambiroll type and the Z or fitting type so as to come to a desired position, that is, on the section. Therefore, it is possible to accurately cut the section without damaging the section heating section of the section heating element.
  • the incision installation apparatus of the present invention uses an anvil tool having a protruding convex part or a processed concave part, and only each section of the heating element is in contact with the convex part on the anvil roll, Since the blade is in contact with only the dividing portion on the convex portion, the divided heat generating portion of the uneven heat generating portion (concave sheet-like body) is a concave portion between the convex portions. It can be accommodated in the section (convex body housing section), and the uneven heating section with unevenness is stabilized, so that the partition section (concave body) can be accurately cut.
  • the method for manufacturing a heating element having a cut according to the present invention can provide a cut with high accuracy by using the above-described cutting installation device, and can provide a good cut with few defects (mutual or different cut). And a heating element having a Z or perforated notch, etc.) can be obtained at high speed with high efficiency, long-term stability, and high yield.
  • FIG. 1 (a) is a plan view showing an example of a heating element of the present invention.
  • (B) A sectional view taken along the line AA.
  • FIG. 2 is a plan view showing another example of the heating element of the present invention.
  • FIG. 3 is a plan view showing another example of the heating element of the present invention.
  • FIG. 4 (a) is a plan view showing another example of the heating element of the present invention.
  • (B) It is sectional drawing which follows the BB line.
  • FIG. 5 is a plan view showing another example of the heating element of the present invention.
  • FIG. 6 (a) is a plan view showing another example of the heating element of the present invention. (B) It is sectional drawing which follows CC line.
  • FIG. 7 is a plan view showing another example of the heating element of the present invention.
  • FIG. 8 is a plan view showing another example of the heating element of the present invention.
  • FIG. 9 is a plan view showing another example of the heating element of the present invention.
  • FIG. 10 is a plan view showing another example of the heating element of the present invention.
  • FIG. 11 is a plan view showing another example of the heating element of the present invention.
  • FIG. 12 is a plan view showing another example of the heating element of the present invention.
  • FIG. 13 (a) is a plan view showing another example of the heating element of the present invention.
  • (B) It is sectional drawing which follows the DD line.
  • FIG. 14 is a plan view showing another example of the heating element of the present invention.
  • FIG. 15 is a plan view showing another example of the heating element of the present invention.
  • FIG. 16 is a plan view showing another example of the heating element of the present invention.
  • FIG. 17 is a plan view showing another example of the heating element of the present invention.
  • FIG. 18 is a plan view showing another example of the heating element of the present invention.
  • FIG. 19 is a plan view showing another example of the heating element of the present invention.
  • FIG. 20 is a plan view showing another example of the heating element of the present invention.
  • FIG. 21 is a plan view showing another example of the heating element of the present invention.
  • FIG. 22 is a plan view showing another example of the heating element of the present invention.
  • FIG. 23 is a plan view showing another example of the heating element of the present invention.
  • FIG. 24 is a plan view showing another example of the heating element of the present invention.
  • FIG. 25 is a plan view showing another example of the heating element of the present invention.
  • FIG. 26] (a) to (1) are plan views showing an example of the notches of the present invention.
  • FIG. 27] (a) to (f) are plan views showing examples of perforated cuts of the present invention.
  • FIG. 28 (a) to (r) are plan views showing an example of a through hole of the present invention.
  • FIG. 29 (a) and (b) are plan views of examples showing the corresponding positions of the blade of the upper roll and the convex portion of the ambi roll of the present invention.
  • FIG. 31 (a) is a sectional view taken along the line Z—Z in FIG. 29.
  • (B) It is sectional drawing of another example which shows the corresponding position of the blade of the upper roll of this invention, and the convex part of an amyl roller.
  • (C) It is sectional drawing of another example which shows the corresponding position of the blade of an upper roll of this invention, and an ambi roll without a convex part.
  • FIG. 32 is a partial enlarged view showing a processing state in which staggered cuts are installed in the heating element in the example of FIG. 29.
  • FIG. 33 (a) is a plan view showing a relationship between staggered notches of the heating element and the section heating unit in the example of FIG. 29.
  • FIG. 30 is a plan view showing a state where the heating element in the example of FIG. 29 is pulled in a direction orthogonal to the alternate cuts.
  • FIG. 34 (a) A plan view of a cutting installation device as an example of the present invention (b) A side view (c) A drawing showing a cutting result
  • FIG. 35 (a) is a perspective view showing another example of the cutting roll of the present invention.
  • (B) It is a perspective view which shows another example of the cutting roll of this invention.
  • (C) It is sectional drawing which shows another example of the cutting roll of this invention.
  • FIG. 36 (a) is a cross-sectional view showing another example of the cutting installation device of the present invention.
  • (B) It is sectional drawing which shows another example of the cutting installation apparatus of this invention.
  • FIG. 37 is a partially enlarged view showing a processing state in which alternate notches are placed in the heating element section in another example of the notch setting device of the present invention.
  • FIG. 39 (a) is a partial sectional view showing another example of the receiving roll of the present invention.
  • B It is a partial cross section figure which shows the processing state which installs the alternate notch
  • C is a front view of an incision roll with an uneven pattern.
  • D is a front view of a receiving roll with an uneven pattern.
  • (E) is a front view of an indented roll with an uneven pattern.
  • (F) is a front view of a receiving roll with an uneven pattern.
  • G is a front view of a receiving roll having a plain smooth surface.
  • H)-(n) is a top view of an example of an uneven
  • FIG. 40 (a) is a partial sectional view showing another example of the receiving roll of the present invention.
  • (B) It is a partial cross section figure which shows another example of the receiving roll of this invention.
  • (C) It is a partial cross section figure which shows another example of the receiving roll of this invention.
  • (a) is a perspective view showing another example of the cutting installation device of the present invention.
  • (B) (c) off It is explanatory drawing which shows the pattern of a cutting blade.
  • FIG. 42 is a plan view showing a cut formed by the cut roll of FIG. 41 (a).
  • FIG. 43 is a plan view showing another cut.
  • FIG. 44 is a plan view showing a cut by another example of the cut installing device of the present invention. ⁇ 45] It is a front view showing another example of the cutting installation device of the present invention.
  • FIG. 46 is a sectional view taken along line FF.
  • FIG. 47 (a) is a front view showing another example of the cutting installation device of the present invention. (b)-(d) It is a front view which shows an example of the other cutting blade of another example of the cutting installation apparatus of this invention.
  • FIG. 48 (a) is a front view showing another example of the cutting installation device of the present invention.
  • (B) It is a partial front view which shows another example of the cutting installation apparatus of this invention.
  • (C) It is a partial front view which shows another example of the notch
  • FIG. 49 (a) is a cross-sectional view showing another example of the cutting installation device of the present invention. (b)-(e) It is a partial front view of the gap adjustment plate vicinity of the same apparatus.
  • FIG. 50 is a sectional view showing another example of the cutting installation device of the present invention (a).
  • (B) It is sectional drawing which shows an example of the cutting roll with a heater of this invention.
  • FIG. 51 is an explanatory diagram of an example of an apparatus for manufacturing a heating element with a cut according to the present invention.
  • FIG. 52 (a) is a plan view showing an example of a state of alternate installation and cut to a continuous heating element by the manufacturing apparatus for a heating element with a cut in FIG. 55.
  • FIG. 56 is a plan view showing an example of a heating element manufactured by the manufacturing apparatus for a heating element with a cut in FIG.
  • FIG. 53 (a) is a plan view showing another example of a state where the cut-in installation cover is alternately inserted into the continuous heating element by the manufacturing apparatus for the heating element with a cut in FIG. 55.
  • FIG. 56 is a plan view showing another example of a heating element manufactured by the manufacturing apparatus for a heating element with a cut in FIG.
  • FIG. 54 is an explanatory diagram of another example of the production apparatus for a heating element with a cut according to the present invention.
  • FIG. 55 is a plan view showing an example of the cutting installation processing state of the alternate V in the continuous heating element by the manufacturing apparatus for the heating element with the notch shown in FIG. 55.
  • FIG. 56 Mutual application to a continuous heating element by another manufacturing apparatus for a heating element with notches of the present invention.
  • FIG. 57 is a plan view showing an example of the outer shape of the notched heating element of the present invention. Explanation of symbols
  • Heating device oil tank, etc.
  • Cooling means (circulating water cooling system, etc.)
  • the heating element of the present invention is provided with two or more, more preferably three or more, more preferably four or more, a plurality of section heating sections provided with intervals between the section sections that are seal sections.
  • the segment heating part contains a heating composition molded body composed of a heating composition that generates heat in contact with oxygen, and the segment heating part is provided in a stripe shape, and A heating element having a notch composed of a connecting part and a notch penetrating at least in one part of the area of the sectioning part, and the section heating part is composed of four or more section heating parts
  • Penetration cutting force It is a heating element that has a cut that is configured, and the cut is a perforated cut that is longer than the connecting portion, and a plurality of sections with the partitioning portion that is the seal portion as an interval.
  • the heating unit In the heating element the heating unit is provided have your interval, the part of the region of at least the grouping portion has a notch consisting of notches through the connecting portion, said incisions each other! Mistake!
  • the heating composition molded body is a heating element provided in a stripe shape on an inextensible support through an adhesive, and the section is not stretchable It is possible to generate heat with elasticity by providing at least one part of the area of the above-mentioned division part with a notch that has a notch that also has a cutting force penetrating through the connecting part.
  • the body is a heating element that is a notch of scissors, and the heating composition molded body is a heating element provided in a stripe shape on an inextensible support through an adhesive, and the section is not stretchable It is possible to generate heat with elasticity by providing at least one part of the area of the above-mentioned division part with a notch that has a notch that also has a cutting force penetrating through the connecting part.
  • Incision and connecting portion force The distance between the formed incision body and the adjacent incision body and the distance between the incision group and the infeed failure incision are not limited and are determined as desired. In the present specification, a preferred example will be described.
  • the heating elements having different and different notches are deformed substantially reversibly in the short direction, which is a direction orthogonal to the mutual and different! /, Notches. Nevertheless, the heating element can be expanded and contracted in the short direction.
  • the heating element having alternating cuts and through holes of the present invention has substantially the same cuts and through holes in the longitudinal direction and the short direction, which are orthogonal to the alternate cuts. Since it is reversibly deformed, the heating element can be deformed in the longitudinal direction and the lateral direction, that is, can be expanded and contracted, although it is a single heating element. Also, the hand-breakable microphone of the present invention. A heating element with a perforated cut can be used according to the situation because the heating element can be separated into two at the perforated cut.
  • a heating element with multiple perforations is easily small!
  • a plurality of heating elements can be made and applied to a plurality of small areas with respect to the human body, etc., this leads to an improvement in medical effects.
  • the heating element of the present invention is preferably provided with fixing means on at least a part of the exposed portion of the heating element.
  • fixing means is an adhesive layer, the functionality of a transdermal drug or the like is provided. It is preferable to contain the substance.
  • the heating element of the present invention is also useful as a patch for poultice.
  • the heating element of the present invention is a segment heating part heating element.
  • the heating element according to the present invention consists of a heating element that contains a heat-generating composition molded body and a dividing part that does not contain a heat-generating composition molded body. Is a heating element having a heat generating portion provided with an interval. At least a part of the heating element has air permeability.
  • the heating element of the present invention usually has a difference in height between the section heating section and the section section, and both surfaces are uneven.
  • the segment heating element is composed of a segment heating unit and a segmenting unit, the size of the heating element itself is not limited, and the number of segment heating units and segmenting units can be increased. Therefore, the size of the heating element itself can be increased as much as possible while maintaining the flexibility and other characteristics of the heating element itself.
  • the thickness can be manufactured from ultra-thin to thick. Therefore, the heating element provided with the cut according to the present invention is also a segment heating part heating element.
  • the divided heat generating portion is a heat generating member that houses the exothermic composition molded body, wherein the divided portion is a seal portion, and the divided heat generating portion is provided with an interval between the divided portions.
  • the shape of the heating element and the shape of the section heating part are not necessarily the same.
  • the heating element and the Z or section heating part may be provided with corners in a substantially arc shape (R shape), and the corners may be curved or curved.
  • the section of the heating element is a sealing part, and the sealing part is heat sealed as long as it is sealed, pressure-bonded with an adhesive, acrylic or acetic acid base.
  • An example is an adhesive seal using a non-adhesive agent. Usually a heat seal is used.
  • the shape of the exothermic composition molded body or the divided heat generating portion may be any shape, but may be a planar shape such as a circle, an ellipse, a football shape, a triangle, a square, a rectangle, a hexagon, a polygon, a house shape, a flower shape, A ring shape etc. are mentioned as an example.
  • disk shape In three-dimensional shape, disk shape, pyramid shape, spherical shape, cube shape, polygonal pyramid shape, cone shape, frustum shape, spherical shape, parallelepiped shape, cylindrical shape, rectangular parallelepiped shape, polyhedron shape, ellipsoid shape, Semi-cylindrical shape, semi-elliptical cylinder shape, bowl shape, cylinder shape, elliptic cylinder shape, etc. are listed as examples of i.
  • the corners may be provided in a substantially arc shape (R shape), the corners may be curved or curved, or the center may have a recess.
  • a region corresponding to a corner such as an exothermic composition molded body, a heat generating portion, a segmented heat generating portion, a heat generating body, a seal portion, a through hole, a concave portion, or a convex portion is substantially arc-shaped (R). May be provided.
  • the radius of curvature of the substantially arc shape is not limited, but is preferably 0.1 mm to 20. Ocm, more preferably 0.3 mm to 10. Ocm, and still more preferably. 0. lmm to 5. Ocm, more preferably 0. lmm to 20. Omm, more preferably 0.1 mm to: LO. Omm, more preferably 0. lmm ⁇ 5.Omm, more preferably 0.3mm ⁇ 5.Omm, more preferably 0.3mn! ⁇ 3. Omm, more preferably 0.5mm ⁇ 2. Omm.
  • the same characteristics and standards are applied to the heating element and the heating element, except for the characteristic only by the notch and the size and shape only by the notch.
  • the heating element of the present invention has an uneven surface on both sides, and is flexible before, during, and after the end of heating, that is, before, during, and after use.
  • the present invention relates to a heating element for warming a possible human body and a method of using the same.
  • air (with a segmented portion where the exothermic composition molded body having a exothermic composition molded body obtained by molding a moldable surplus water exothermic composition that generates heat in contact with oxygen by a molding method is a seal portion,
  • a heating element having a heat generating part provided at an interval, comprising iron powder and carbon components.
  • Exothermic reaction that does not function as a barrier layer, immediately after manufacture, is not stored in a breathable storage bag, and has a temperature increase of 5 ° C or more within 5 minutes after being placed in air at 20 ° C without wind
  • the exothermic composition molded body obtained by molding the moldable surplus water exothermic composition by the molding method is laminated on the base material and further coated with a coating material, and the peripheral portion of the exothermic composition molded body
  • the length of the heat generating part is 5mm to 300mm, the width is lmm to less than 25mm, and the height is 0.5mn!
  • the ratio of (length Z width) is 2.0 ⁇ 60
  • the width of the section is 0.1 ⁇ : LOOmm
  • the above four or more section heating parts are separated from each other
  • at least one of the base material and the covering material is air permeable (oxygen permeable)
  • the surface A is air permeable
  • the A, B Are both convex and concave surfaces formed by a convex section heating section and a concave (flat) section section
  • the heating element has a minimum bending resistance of 100 mm or less, and a minimum bending resistance ratio
  • the ratio is 60 or less, it does not bend easily except in the direction with the minimum bending resistance, it has a direction for ease of bending, and it has a structure that is extremely easy to bend only in one direction compared to the other direction.
  • a heating element as another example of the present invention is a double-sided concave heating element having a minimum low bending resistance ratio of 100 or less.
  • the heating element of the present invention includes both the case where the appearance of the heating element is uneven on both sides and the case where the heating composition molded body is uneven on both sides due to holes, etc.
  • the appearance of the heating element becomes uneven on both sides when a nonuniform force is applied to the surface of the heating element. That is, a portion of the packaging material sinks into the hole, resulting in unevenness.
  • the heating element has a pressure-sensitive adhesive layer on the air-permeable side of the heating element, and the pressure-sensitive adhesive layer is mainly (1) a type that is provided in the section heating section, (2) a type that is provided in the section, (3) Ward A heating element of the type that is in direct contact with any of the types of skin provided in the partial heating section and the section
  • the heating element has a pressure-sensitive adhesive layer on the non-breathable surface of the heating element, and the pressure-sensitive adhesive layer is mainly (4) a type that is provided in the section heating unit, and (5) a type that is provided in the section. (6) There is a type of heating element that is in direct contact with the skin of any type provided in the section heating section and the sectioning section. It is preferable that the fixing means can be removed.
  • the pressure-sensitive adhesive of the present invention is a pressure-sensitive adhesive.
  • the packaging material on the side touching the body of the heating element of the present invention can be obtained by adding a functional substance to the adhesive layer.
  • the heat generating portion of the present invention is provided in a stripe shape (strip shape) at intervals. But striped (stripe) (Provided in parallel lines). It is preferable that one stripe (streaks) is composed of one section heating part.
  • one stripe may be composed of two or more divided heat generating portions and one or more divided portions.
  • T is T ⁇ 2 X S, preferably ⁇ 2.5 X S.
  • ⁇ is ⁇ , preferably ⁇ 0.5 ⁇ .
  • One example is the arrangement of streaks composed of segmented heat generating parts in parallel stripes (vertical stripes, horizontal stripes, diagonal stripes, vertical wave stripes, horizontal wave stripes, diagonal wave stripes, etc.).
  • the minimum bending resistance of the heating element of the present invention is usually 100 mm or less, preferably 1 to 100 mm, more preferably 1 to 80 mm, still more preferably 1 to 50 mm, and even more preferably.
  • Preferably it is 5-50 mm, More preferably, it is 5-40 mm, More preferably, it is 5-30 mm, More preferably, it is 5-20 mm.
  • the minimum bending resistance of the heating element of the present invention is usually 60 or less, preferably 50 or less, more preferably 1 to 50, still more preferably 1 to 40, and further Preferably 1-30 More preferably, it is 1-20, More preferably, it is 1-10.
  • the minimum bending resistance ratio of the heating element of the present invention is usually 100 or less, preferably 1 to: LOO, more preferably 2 to: LOO, and still more preferably 2 to 90. More preferably 2 to 70, still more preferably 2 to 60, still more preferably 2 to 50, still more preferably 2 to 40, still more preferably 2 to 30, and still more preferably. 2 to 20, more preferably 2 to 10.
  • the change in the minimum bending resistance before and after the heat generation of the heating element of the present invention is Usually, it is 30% or less, preferably 0 to 30%, more preferably 0 to 20%, still more preferably 0 to 10%, still more preferably 0 to 5%, still more preferably 0. %.
  • the size of the section heating section and the section section can be various sizes, and the length and width can be long, short, wide and narrow, and they can be combined.
  • Various stripe-shaped heating sections can be used.
  • a perforation that can be cut off by hand is provided in the section of the heating element of the present invention so that the heating element can be divided into several parts when used.
  • the size of the section heat generating portion or the heat generating composition molded body is not limited, but preferable sizes are as follows.
  • the shape is preferably a rectangle or a rectangle-like shape.
  • the width is usually 1 mm or more and less than 25 mm, preferably lmn! ⁇ 24mm, more preferably lmn! ⁇ 23mm, more preferably lmm ⁇ 23mm, more preferably lmn! ⁇ 20mm, more preferably 3mn! ⁇ 20mm, more preferably 5mm ⁇ 15mm, more preferably 5mn! ⁇ 10mm.
  • the length is usually 5 mm to 300 mm, preferably 5 mm to 200 mm, more preferably 5 mm to 100 mm, more preferably 20 mm to 150 mm, and even more preferably 30 mm to: L OOmm is there.
  • the ratio of (length Z width) is usually 2.0 to 60, more preferably 2.1 to 60, even more preferably ⁇ 2. 2. 1 to 50, and more preferably ⁇ or 2 5 to 50, more preferably 2.5 to 2.5, more preferably 2.5 to 25, more preferably 2.5 to 25, still more preferably 2.5 to 20 and even more preferred. It is 3-20.
  • the height is usually 0. lmn! ⁇ 10mm, preferably 0.3mm ⁇ 10mm, more preferably lmn! ⁇ 10mm, more preferably 2mm ⁇ : LOmm.
  • the heat generating composition molded body which is the heat generating composition molded body occupation area The volume ratio between the volumetric product and the volume of the exothermic part that is the exothermic composition storage area is usually 0.6 to 1, preferably 0.7 to 1, more preferably 0.8 to 1. More preferably, it is 0.9 to 1.
  • the width of the section is not limited as long as the section heat generating section can be provided at intervals, but is usually 0.1 lmn! ⁇ 100mm, preferably 0. lmn! 80 mm, more preferably 0.1 mm to 60 mm, still more preferably 0.1 mm to 50 mm, still more preferably 0.3 mm to 50 mm, still more preferably 0.3 mm to 40 mm, and further Preferably 0.5mn! ⁇ 30mm, more preferably lmm ⁇ 30mm, more preferably lmn! ⁇ 20mm, more preferably 3mm ⁇ : LOmm.
  • the total area of the divided heat generating portions is not limited, but preferably the total area of the divided heat generating portions is 50 to 85% with respect to the entire surface of the heat generating surface of the heating element, and more preferably. 50-70%.
  • the shape of the segmented heat generating portion includes a continuous stripe shape and a discontinuous stripe shape as shown in FIGS.
  • the width of the section In order to have a partial stimulating element in many places and to expect a comfortable thermotherapy, it is preferable to set the width of the section to 3.5 to: LOmm. It is preferable to set the ratio of the width of the partition and the width of the partition part (air layer part) to 1: 1 to 3: 1.
  • the ratio of the width of the section heating section and the section section is not limited, but the range is 1: 1 to 3: 1. It is preferable that The same thermal effect as in the case of a single heating part on the entire surface can be obtained, and the wearability is sufficient, and redness and the like can be more effectively prevented. In other words, it is possible to practically secure the adhesive strength 'thermal effect, suppress heat accumulation, further improve the effect of preventing redness, etc., and suppress the retention of sweat. As a result, it is possible to more effectively prevent stuffiness and peeling of the sheet.
  • the heating element of the present invention can be arranged in various shapes according to the use in which all the section heating sections and their intervals (section sections) do not have to be the same size.
  • the section heat generating portion may be formed by making the density in the central portion rougher than the outer peripheral portion of the sheet surface.
  • the exothermic composition part molded body means both the exothermic composition part molded body and the exothermic composition compressed body which is a compressed exothermic composition molded body.
  • the outer shape of the heating element of the present invention is not limited, in FIG. 57, (a) is a flat shape, (b) is an eye mask shape, (c) is a bowl shape, (d) (E) is rounded rectangle, (f) is rectangular, (g) is rounded square, (h) is square, (j) is oval, (j) is boomerang, (k) is (1) is a star shape, (m) is a leaf shape, (n) is a leaf shape, (o) is a nose shape, (p) is a lantern shape, (q) is a lantern shape, (r) For example, a foot shape is shown as an example. The airfoil is suitable around the neck and shoulders. The straight line in the figure is the one in which the cutting force in FIG. 26 or 27 is also arbitrarily selected.
  • Perforation perforated cut
  • V-notched perforated perforated with V-notch
  • V A heating element provided with notches or through-holes such as staggered notches with notches, or crossed regions shown in FIG. 28, and provided with at least incisions and through-holes that can be deformed in the extending direction of the section, or any combination thereof. Included in the outer shape of the heating element.
  • the shape of the heating element described in the present specification includes a shape obtained by modifying the described shape as a basic shape. Other notches such as U notch and I notch may be used instead of V notch.
  • the segmented heat generating part including the exothermic composition molded body and the segmented part which is a seal part not including the exothermic composition are spaced apart, and in particular, the segmented heat generating part is striped.
  • the details of the effect of suppressing the redness and the numbness by the formation of the film are not clear, but the present inventor estimates as follows.
  • Hyperthermia treatment aims to promote circulation and relieve stiff shoulders and muscle pain by supplying heat to the affected area and warming it.
  • a heating element formed with a single exothermic part is left on the affected part for a long time, heat storage occurs, and if the skin surface temperature exceeds a certain critical temperature (about 42-43 ° C), blood As it becomes difficult to flow, the cooling effect of the blood flow is reduced and heat storage is further increased, resulting in redness treatment.
  • the skin temperature may become a critical temperature or more when the temperature of the heating element rises.
  • the skin temperature may become a critical temperature or more when the temperature of the heating element rises.
  • the heat generating part is formed in a stripe shape using the segmented heat generating part, so that the heat supply from the heat generating part is less than the part where the heat supply is large (the segmented heat generating part).
  • the sorting parts serve as air passages that allow the air layer part to communicate with the outside. For this reason, excess ripening that causes heat storage is dissipated to the outside through this air passage, so heat storage can be suppressed within the surface of the heating element, and heat generation, medical treatment, etc. can be prevented. By providing this ventilation path, it is considered that excess heat is effectively released.
  • the extensibility of the present invention means that when an external force is applied, the external force is at least in the direction in which the external force is applied. This means that at least a part is longer than the length before the force is applied, and the length after the external force is removed does not matter. Extensibility includes elasticity.
  • the elongation rate is not limited as long as it exceeds 1, but it is preferably 1.005 to 10 although it depends on the application. More preferably, ⁇ MA 1. 01 to 10, more preferably ⁇ or 1.01 to 5, more preferably ⁇ or 1. 01 to 5, more preferably 1. 01 to 3, more preferably 1.01 to 2, more preferably ⁇ or 1.02 to 2, more preferably ⁇ or 1.03 to 2, more preferably ⁇ or 1.04. It is -2, More preferably, it is 1.05-2.
  • the alternate cut usually has a function of imparting extensibility and stretchability.
  • the stretchability of the present invention means that when an external force is applied, it stretches, and when the external force is removed, it becomes shorter than the length when stretched.
  • the degree of shortening is displayed with a shortening rate, there is no limit if the shortening rate exceeds 1, but depending on the application, it is preferably 1.005 to 10 Yes, more preferably ⁇ 1.01 to 10, more preferably ⁇ or 1.01 to 5, more preferably ⁇ 1.01 to 5, more preferably 1. 01 to 3. More preferably, it is 1.01-2, more preferably ⁇ or 1. 02-2, more preferably ⁇ or 1. 03-2, more preferably ⁇ or 1. It is 04-2, More preferably, it is 1.05-2.
  • tensile strength of the extensible or stretchable heating element of the present invention there is no limitation on the tensile strength of the extensible or stretchable heating element of the present invention, but a preferable example is 350 mm or more.
  • the through-cuts that can be deformed in at least one direction include those having a space such as a through hole that is not limited if the cut can be deformed in at least one direction.
  • Figures 26 (a) to (i) show the notches 18 combined with alternating notches and V-notches 21.
  • An example of staggered cuts having a connecting portion 19 and a connecting portion 19 is shown.
  • Examples of the arrangement direction include vertical, horizontal, diagonal, longitudinal, short, and diagonal directions, which are not limited.
  • Figure 26 (c) shows two rows according to the layout rules shown in Figure 26 (a). Similarly, the number of columns (rows) can be increased. The same applies to the other cuts.
  • FIGS. 27A to 27F show an example of a perforated cut having a cut 18 and a connecting portion 19 in combination with a perforated cut or V-notch 21.
  • Examples of the arrangement direction include vertical, horizontal, diagonal, longitudinal, short, and diagonal directions.
  • FIGS. 28 (a) to 28 (r) show examples of through-holes that are provided mainly in the crossing region of the cut and can be deformed in at least one direction in cooperation with the cut. For example, there are no restrictions on the direction in which they are placed, and there are areas that intersect in the vertical, horizontal, diagonal, longitudinal, short, and diagonal directions.
  • the plurality of section heat generating sections 6 are provided at predetermined intervals with the section sections 7 serving as seal sections as an interval, and at least a part of the section sections 7 is provided.
  • an adhesive layer 13 may be provided on at least a part of the exposed portion of the heating element 1.
  • the notch that penetrates may or may not penetrate the separator.
  • a heating element 1 as a thermal patch includes a heating element in which a plurality of section heating sections 6 are spaced apart from each other by a section 7 that is a seal section. 1 and has a basic structure in which the heating element 1 is composed of the heating element 1 having the adhesive layer 13 on the non-breathable surface side, and the notch 15 is provided in at least one section 7. .
  • the heating element 1 of the present invention shown in FIG. 1 (a) includes a plurality of divided heat generating portions 6, in this case, six divided heat generating portions 6 provided in a stripe pattern with a divided portion having a width of 7 mm as an interval.
  • Each section 7 is provided with three rows of cuts staggered at intervals of 1.5 mm, and provided with staggered cuts 15! /. At least a part of the notch 15 between each other and different! / Is in contact with the periphery of the heating element 1.
  • Figure 1 (b) is a cross-sectional view taken along line AA.
  • the pressure-sensitive adhesive layer 13 is formed on one surface of the heating element 1 with styrene, isoprene, or styrene. It is a layer of about 50 ⁇ m thick made of adhesive.
  • the pressure-sensitive adhesive layer 13 was a lidocaine hydrochloride-containing pressure-sensitive adhesive layer coated with lidocaine hydrochloride jelly.
  • the lidocaine hydrochloride content in the entire lidocaine hydrochloride-containing pressure-sensitive adhesive layer was adjusted to 1% by weight.
  • a separator 14 for covering and protecting the surface of the pressure-sensitive adhesive is provided!
  • Breathable packaging material made by bonding nylon nonwoven fabric and porous polyethylene film
  • a polyethylene film 12 having a pressure-sensitive adhesive layer 13 with a separator 14 provided on one side as a base material for a non-breathable packaging material.
  • activated carbon particle size 300 m or less
  • wood flour particle size 150 m or less
  • water-absorbing polymer particle size 300 m or less
  • a formable hydrous exothermic composition having a mobile water value of 11 mixed with 0.5 parts by weight of slaked lime, 0.7 parts by weight of sodium sulfite and 11% saline was used. The forming degree was 10.
  • the air permeability of the covering material 15 was 400 gZm 2 Z24hr according to the wet method.
  • heating element 1 When the heating element 1 is pulled in the longitudinal direction, i.e., substantially perpendicular to the direction of the alternating cuts 15, the alternating cuts 15 are deformed, and the heating element 1 extends in the pulled direction, and when the external force is removed, the alternating cuts are made. 15 returned to its original shape, and heating element 1 was also restored to its original shape. Despite being one heating element, heating element 1 showed extensibility and elasticity in the longitudinal direction. That is, since the alternate cuts 15 in the longitudinal direction, which are orthogonal to the alternate cuts 15, are deformed in a substantially reversible manner, the heating element 1 is used as a heating element 1 even though it is a single heating element. Can be deformed in the longitudinal direction, that is, can be expanded and contracted.
  • thermo patch a commercially available heating element having one heating part was used. It was confirmed that this heating element (thermal patch) 1 was not stretchable or stretchable at all.
  • thermo patch A heating element (thermal patch) was prepared in the same manner as in the above example, except that the heating element 1 without the staggered cuts 15 in the section 7 was formed instead of the above example, that is, the cuts 15 of the staggered differences were not formed. Got one.
  • This exothermic body (thermal patch) was found to have no extensibility and elasticity.
  • the example is divided into six divided heat generating parts 6, and each divided part 7 has a different cut 15 so that the heat generating element itself is one heat generating element. Since it has stretchability, the heating element (thermal patch) 1 can easily stretch, bend and bend.
  • the heating element (thermal patch) 1 of Comparative Example 1 is formed of one heating element having one heating part force without the alternate notches 15, and therefore has no stretchability. Therefore, when this kind of heating element (thermal patch) 1 was applied to the elbow and used, all nine testers had a heating element (thermal patch). It peels off during use due to the restoring force of 1 and has poor adhesion to the outer skin. I appealed.
  • the heating element (thermal patch) 1 of Comparative Example 2 is formed of a single heating element having no alternate cuts 15 and therefore has no elasticity but is flexible.
  • the heating element (thermal patch) 1 was applied to the elbow and used, all nine testers evaluated the heating element (thermal patch) 1 between Example and Comparative Example 1.
  • the heating element (thermal patch) 1 of the example had good adhesion to the outer skin, and 6 out of 9 testers complained that the elbow was not damaged, Of the remaining three testers, two testers complained that the pain was reduced and the pharmacological effect was excellent!
  • the heating element (thermal patch) 1 of Comparative Example 1 is easy to peel off and has poor adhesion to the outer skin, and there is a variation in the temperature of the application site. He complained that there was almost no pharmacological effect.
  • thermo patch 1 of Comparative Example 2 is formed of a single heating element without alternating cuts, it has no elasticity but is flexible.
  • the exothermic body (thermal patch) 1 was applied to the elbow and used, all nine testers evaluated the exothermic body of Example and Comparative Example 1 (thermal patch).
  • the temperature change of the skin (elbow) part was measured with a data collector using four thermothermocouples attached to the skin (elbow) side and stuck to the skin (elbow) side.
  • the force in the example ranged from 41 to 42.5 ° C.
  • the comparative example ranged from 36 to 42.3 ° C, and the temperature variation was large. It was recognized that
  • the minimum bending resistance of the heating element of Example 1 is 30 mm or less, the heating element of Comparative Example 1 is not flexible and the bending resistance cannot be measured, and the minimum bending resistance of the heating element of Comparative Example 2 is not possible.
  • the change in the minimum bending resistance of the heating element before and after the heat generation is 0% for the heating elements of Example 1 and Comparative Example 2, and before and after the heating There was no change in flexibility.
  • the heating element (thermal patch) 1 of the present invention has six segment heating parts 6 spaced apart by a predetermined interval, in this case, each segment heating part 6 is spaced by 7 mm.
  • the width of the partition 7 located at the center is 12 mm, and 5 sets of cuts are formed alternately at intervals of 1.5 mm in the center. 3 rows of cuts at 5mm intervals Therefore, the joints such as the elbows and knees, the shoulders and arms, etc., and the curved and stretched parts of the human body, and the bent and stretched parts are followed, and the tension force is stretched during use. It feels uncomfortable because it feels uncomfortable and has good usability, and since it does not peel during use, it is recognized that it exhibits excellent thermal effects and therapeutic effects on the affected area.
  • the heating element (thermal patch) 1 of the present invention can be used only in the winter to simply supply heat to the human body and to be able to spend comfortably, with symptoms such as local stiffness, colic and coldness.
  • symptoms such as local stiffness, colic and coldness.
  • it is used for diseases such as stiff shoulders, muscle pain, and back pain, and a therapeutic effect by heat can be sufficiently expected.
  • FIG. 2 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • This heating element (thermal patch) 1 is a rectangular heating element, and five heating elements are arranged in the longitudinal direction. Are divided at predetermined intervals, and the width of each section 7 is equal to 7 mm, each of which has four rows of staggered notches 15 with 1.5 mm spacing and 3 column force. Further, it has a basic structure in which an adhesive layer 13 is provided with a separator 14 on the non-breathable side. Each different cut 15 is in contact with the periphery of the heating element 1.
  • FIG. 3 is a modification of the heating element (thermal patch) 1 shown in FIG. 1.
  • the section heating section 6 whose central section 7 is wider than the other section 7 is shown in FIG. Except that there are 8 cuts 15 in the middle section 7 that consist of 5 rows only, and that is different! /, Except for! /,
  • the heating element (thermal patch) shown in Fig. 1 1 Since this is the same as the above, it is omitted to avoid redundant explanation.
  • Each alternate cut 15 is in contact with the periphery of the heating element 1.
  • Fig. 4 (a) shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • the heating composition molded body 4 of the heating element 1 in Fig. 1 is replaced with the heating composition molding.
  • the heating element 1 is the same as the heating element 1 in Fig. 1 except that it is fixed to the polyethylene film with an adhesive instead of the sheet-shaped heating sheet 5 made of a paper-making heating sheet containing water and sodium chloride.
  • Figure 4 (b) is a cross-sectional view of BB.
  • FIG. 5 shows another example of the heating element (thermal patch) 1 according to the present invention, and this heating element (thermal patch) was formed by bonding a nylon nonwoven fabric and a polyethylene porous film.
  • Each section 7 is provided with alternate notches 15 in which three rows of incisions are alternately formed, and a mesh-like ventilation provided by the melt blow method on the breathable side. It has a basic structure provided with an adhesive layer. When storing, the mesh-like breathable pressure-sensitive adhesive layer side is covered with a separator, sealed in a non-breathable storage bag (outer bag), and stored. At least some of the alternating cuts 15 are in contact with the peripheral portion of the heating element 1.
  • FIG. 6 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • This heating element (thermal patch) 1 has a striped segment heating part (width) in the longitudinal direction. (8mm) 15 pieces of heat generated by 6 rows of 6 pieces of heat generators, which are provided in 4 rows at 6mm equally spaced 7mm across the center piece 7
  • the heating element 1 having the portion 6 has a width of 11 mm at the center of the longitudinal portion 7 located at the center in the longitudinal direction, and is formed in five rows of staggered cuts 15 at 1.5 mm intervals in the center. Yes.
  • the width of the section in the short direction is 10mm.
  • There are 5 rows of notches 15 in the middle of the wide section in the longitudinal direction. At least a part of the notch 15 is in contact with the periphery of the heating element 1.
  • Figure 6 (b) is a cross-sectional view of CC.
  • the pressure-sensitive adhesive layer 13 is composed of a SIS-based pressure-sensitive adhesive.
  • a non-breathable packaging material comprising a breathable packaging material obtained by bonding a nylon nonwoven fabric 10 and a polyethylene porous film 11 to a covering material 9, and a polyethylene film 12 having a pressure-sensitive adhesive layer 13 with a separator 14 provided on one side.
  • a breathable packaging material obtained by bonding a nylon nonwoven fabric 10 and a polyethylene porous film 11 to a covering material 9, and a polyethylene film 12 having a pressure-sensitive adhesive layer 13 with a separator 14 provided on one side.
  • the base material 8 and as the moldable surplus water heating composition 3
  • iron powder particle size 300 m or less
  • activated carbon particle size 300 m or less
  • wood powder grain (Diameter 150 m or less) 2.
  • the air permeability of the covering material 9 was 400 gZm 2 Z24hr of moisture permeability according to the Risch method.
  • a punching die having two rows of four holes on both sides of the center interval with a predetermined interval therebetween is provided.
  • 15 exothermic composition molded bodies 4 were laminated on the polyethylene film 12 surface of the base material, and the covering material was covered so that the polyethylene film 12 surfaces were superposed on each other, Fever Heat-generating body with pressure-sensitive adhesive layer 13 with separator 14 having 15 divided heat-generating parts 6 in eight rows of stripes by heat-sealing the peripheral part of composition molded body 4 and the peripheral part of heating element 1 Got one.
  • staggered notches 15 having 5 rows of force were formed at the center of the 11 mm wide section 7 located at the center at intervals of 1.5 mm to obtain heating elements 1 with staggered notches.
  • the minimum bending resistance of the heating element in this example is 50 mm or less, and the change in the minimum bending resistance of the heating element before and after the heating is 0%, which is flexible before and after heating. There was no change in sex.
  • FIG. 7 is a modification of the heating element (thermal patch) 1 shown in FIG. 6.
  • the heating element (thermal patch) 1 shown in FIG. 6 is the same as the heating element 1 except that the central section 7 is provided with three rows of notches 15 which are different from each other. At least a part of the alternating cuts 15 is in contact with the outermost end portion around the heating element 1.
  • Fig. 8 is a modification of the heating element (thermal patch) 1 shown in Fig. 7.
  • the notch 15 of the difference of 3 rows in the central section 7 is 1 row. Except for! /, It is the same as the heating element (thermal patch) 1 shown in FIG. At least some of the alternating cuts 15 are in contact with the periphery of the heating element 1.
  • Fig. 9 is a modification of the heating element (thermal patch) 1 shown in Fig. 7.
  • each section is provided with three rows of notches 15 each of which is divided into three rows, and different! /, Except for seven rows of cuts 15 each other, the same as the heating element (thermal patch) 1 shown in FIG. At least a part of the notch 15 is in contact with the outermost edge of the periphery of the heating element 1.
  • FIG. 10 is a modification of the heating element (thermal patch) 1 shown in FIG. 9.
  • the heating element (heat patch) 1 is composed of 16 divided heating parts 6, which are different from each other provided in the sorting part 7.
  • 9 is the same as the heating element (thermal patch) 1 shown in FIG. 9 except that the notch 15 does not reach the periphery of the heating element 1.
  • FIG. 11 is a modification of the heating element (thermal patch) 1 shown in FIG. 9, and in this case, the outermost end of the periphery of the heating element 1 of each staggered cut 15 provided in the section 7.
  • 9 is the same as the heating element (thermal patch) 1 shown in FIG. 9 except that the V notch 21 is provided and each staggered cut 15 is in contact with the V notch 21.
  • FIG. 12 is a modification of the heating element (thermal patch) 1 shown in FIG. 9, and in this case, the outermost end of the periphery of the heating element 1 of each staggered cut 15 provided in the section 7. 9 is the same as the heating element (thermal patch) 1 shown in FIG.
  • the heating element 1 can be deformed in the longitudinal direction despite being one heating element, that is, Can expand and contract.
  • FIG. 13 is a modification of the heating element (thermal patch) 1 shown in FIG. 6, and is a heating element 1 that does not have an adhesive layer.
  • the heating element 1 is configured such that the striped segment heating portions 6 are provided in four rows at equal intervals across the central segment 7 in the short direction, and the strip-shaped segment heating units 6 Is a heating element with 16 divided heat generating parts 6 composed of two divided heat generating parts 6 and is alternately divided into a wide divided part 7 in the center in the short side direction and a divided part 7 substantially orthogonal thereto.
  • at least a part of the notch 15 has a notch cut into each other. At least a part of the notch 15 is in contact with the peripheral part of the heating element 1 at least.
  • Fig. 13 (b) is a cross-sectional view of DD.
  • FIG. 14 is a modification of the heating element 1 shown in FIG. 13.
  • the heating element 1 thermal patch
  • the heating element 1 has the adhesive layer 14, and all the dividing portions 7 have three rows of force.
  • at least a part of the alternate cuts 15 has a cut cut in each. Further, at least a part of the alternate cuts 15 is in contact with the peripheral part of the heating element 1. Except for the pressure-sensitive adhesive layer and the notch, it is the same as the heat generator 1 shown in FIG.
  • FIG. 15 is a modification of the heating element (thermal patch) 1 shown in FIG. 14.
  • a circular through hole 22 is provided in the intersecting region of the central partition 7 and intersects. In the region, it is the same as the heating element (thermal patch) 1 shown in FIG. 13 except that at least some of the alternating cuts 15 have cuts cut into the circular through holes 22 respectively.
  • FIG. 16 is a modification of the heating element (thermal patch) 1 shown in FIG. 14.
  • circular through holes 22 are provided in the intersecting region of the central partition 7 and intersect.
  • the alternate cuts 15 are the same as the heating element (thermal patch) 1 shown in FIG. 13 except that the notches 15 do not contact the circular through holes 22.
  • the heating element 1 Since the notches 15 that are different from each other in the long and short directions, which are orthogonal to the alternate notches 15, deform substantially reversibly, the heating element 1 is in the longitudinal direction despite being one heating element. It can be deformed in the short direction, that is, it can expand and contract.
  • FIG. 17 is a modification of the heating element (thermal patch) 1 shown in FIG. 14.
  • circular through holes 22 are provided in the intersecting regions of all the divided portions, and in the intersecting regions, However, it is the same as the heating element (thermal patch) 1 shown in FIG. 14 except that at least some of the alternating cuts 15 have cuts cut into the circular through holes 22 respectively. Since the notch 15 and the through hole 22 are reversibly deformed in the longitudinal direction and the short direction, which are perpendicular to the notch 15 of the difference V, they are deformed substantially reversibly.
  • the heating element 1 can be deformed in the longitudinal direction and the lateral direction, that is, can be expanded and contracted.
  • FIG. 18 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • the heating element (thermal patch) 1 is a saddle-shaped heating element with constricted sides on the center. 1 is a heating element 1 having six strip heating sections 6 arranged in three rows at equal intervals, with a strip-shaped section heating section 6 in the short direction and sandwiching a wide section section 7 in the center. Three rows of staggered cuts 15 are provided at the center of each section 7 where the width of each section 7 is wider than the other sections 7. The different notches 15 are in contact with the periphery of the heating element 1.
  • the base material, the covering material, the molded composition molded body 4 and the like are the same as the heating element 1 in FIG. Since the alternate cuts 15 in the longitudinal direction, which are orthogonal to the alternate cuts 15, deform substantially reversibly, the heating element 1 can be deformed in the longitudinal direction despite the fact that it is a single heating element. it can.
  • FIG. 19 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • This heating element (thermal patch) 1 is a broad bean-shaped heating element 1 in the short direction.
  • a strip-shaped segment heating section 6 is provided in three rows at equal intervals across a central wide section 7 and is a heating element 1 having six segment heating sections 6, where the center section 7 has a different width.
  • Sectioning section of each section Three rows of staggered cuts 15 are provided in the central portion of 7 and both ends of the heating element 1 are arranged in parallel with the other 15!
  • a notch 15 is provided! The notch 15 is in contact with the outermost edge of the periphery of the heating element 1.
  • the heating element 1 Since the notches 15 that are different from each other in the longitudinal direction, which are orthogonal to the notches 15 of each other, are substantially reversibly deformed, the heating element 1 remains in the longitudinal direction even though it is a single heating element. It can be deformed, that is, it can expand and contract.
  • FIG. 20 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • This heating element (thermal patch) 1 is a broad bean-shaped heating element 1 in the short direction.
  • the striped segment heat generating section 6 is provided in three rows at equal intervals across the wide central partition section 7, and the striped segment heat generating section 6 is composed of two segment heat generating sections 6.
  • all the dividing parts 7 are provided with staggered cuts 15, and both end regions of the heating element 1 are also parallel to other different cuts 15. There are 15 cuts that are different from each other.
  • the notch 15 In the region where each section 7 intersects with the section 7 that is substantially orthogonal to it, at least a part of the notch 15 has a notch in the respective part, and the notch 15 is the periphery of the heating element 1. It is in contact with the part. Since the notches 15 in the longitudinal direction and in the short direction, which are orthogonal to the alternating notches 15, are substantially reversibly deformed, the heating element 1 is It can be deformed in the longitudinal direction and the short direction, that is, can be expanded and contracted.
  • FIG. 21 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • the heating element (thermal patch) 1 has three rows of staggered cuts in a cross shape and an X shape.
  • Each of the different cuts 15 intersects at the center of the heating element 1, and at least a part of the cuts 15 that are different from each other in the intersecting area are cut into the respective cuts.
  • Eight section heating parts 6 are provided, surrounded by alternate cuts 15 on the two sides.
  • the notch 15 is provided so as to intersect with the cross shape and the X shape.
  • the heating element 1 can be deformed vertically (short direction), horizontally (longitudinal direction), and diagonally (diagonal direction), that is, can be expanded and contracted. Other than the above, it is the same as the heating element 1 in FIG.
  • FIG. 22 shows a modification of the heating element (thermal patch) 1.
  • the central section is crossed.
  • a circular through hole 22 is provided in the area to be inserted, and in the intersecting area, as shown in FIG. 21, except that at least some of the alternating cuts 15 have cuts cut into the circular through holes 22, respectively.
  • the heating element 1 can be deformed in the long side direction and the short side direction, that is, can be expanded and contracted.
  • FIG. 23 shows another embodiment of the heating element (thermal patch) 1 according to the present invention, and this heating element (thermal patch) 1 is a divided heating part sandwiching the central dividing part 7.
  • 6 is a heating element 1 having two divided heat generating parts 6, and the middle section 7 is provided with five rows of staggered cuts 15. At least some of the alternating cuts 15 are in contact with the periphery of the heating element 1. Since the alternate cuts 15 in the longitudinal direction, which is a direction orthogonal to the alternate cuts 15, are substantially reversibly deformed, the heat generator 1 can expand and contract in the longitudinal direction even though it is a single heating element.
  • FIG. 24 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • the heating element (thermal patch) 1 has a striped segment heating part 6 in the short direction.
  • a heating element 1 having sixteen segmented heating units 6 provided at equal intervals and having a striped segmented heating unit 6 composed of two segmented heating units 6. All sections 7 are provided with perforated cuts 23 that can be cut by hand. The perforated cut 23 that can be cut by hand is in contact with the outermost end of the heating element 1.
  • This heating element 1 can be used as a single heating element, but it can also be used as a maximum of 16 heating elements by cutting the perforated cuts.
  • FIG. 25 shows another embodiment of the heating element (thermal patch) 1 according to the present invention.
  • This heating element (thermal patch) 1 is a saddle-shaped heating element with constricted sides at the center. 1 is a heating element having six segment heating parts 6 arranged in three rows at equal intervals across a wide section 7 in the middle, with a strip-shaped segment heating part 6 in the short direction.
  • a perforated cut 23 that can be cut by hand is provided in the central section 7 where the width of the section 7 is wider than the other sections 7.
  • the perforated cut 27 that can be cut by hand is in contact with the periphery of the heating element.
  • the heating element described in FIGS. 1 to 25 has a minimum bending resistance of 100 mm or less.
  • the change in the minimum bending resistance of the heating element before and after the heat generation is 30% or less, substantially 0%, maintaining the flexibility and virtually no change in flexibility. I helped.
  • heating element (thermal patch) 1 when the separator is peeled off from these heating elements (thermal patches) 1, and this heating element (thermal patch) 1 is applied to the curved portion of the human body such as the shoulder, waist, and arm, etc. Heating body (thermal patch) 1 is prevented from being peeled off, and adhesion to the outer skin is improved, and the required thermal effect and therapeutic effect on the affected area are applied to the curved part of the human body, such as the shoulders and hips. Can be expressed.
  • these heating elements are stretchable and flexible and can be bent
  • these heating elements can be attached to the joints such as the elbows and knees.
  • the thermal patch 1 has good adhesion to the outer skin that does not peel off during use, and the required thermal effects and affected areas are required for curved and stretchable parts such as joints such as elbows and knees, as well as bending and stretching parts. The therapeutic effect of can be expressed.
  • the heating element of the present invention can be attached to clothes, put in a pocket of clothes, put in a band-like object having a pocket or a pocket of a band-like object, put between folds of a muffler, It can be used in various places by sticking it on a machine or the like, and its use is not limited.
  • the heating element (thermal patch) of the present invention can be directly applied to the outer skin, and when there is a variation in the adhesion to the skin, there will be a temperature variation between the adhesion site and the peeling site.
  • the heating element (thermal patch) of the present invention has good adhesion to the skin as described above, there is no variation in the temperature of the application site, and the usability is also good.
  • the packaging material constituting the covering material of the present invention is not limited as long as it functions as a packaging material for a heating element.
  • non-breathable materials, breathable materials, water-absorbing materials, non-water-absorbing materials, non-stretchable materials, stretchable materials, stretchable materials, non-stretchable materials, foamed materials, non-foamed materials, non-packaging materials examples include heat-sealable materials, heat-sealable materials, and the like, and they can be appropriately used depending on the desired application in desired forms such as films, sheets, nonwoven fabrics, woven fabrics, and laminates thereof.
  • the packaging material used for the heating element according to the present invention may be any packaging material that has been disclosed in the past or is commercially available, or that is used for a well-known disposable body warmer or heating element. It can be appropriately selected and used.
  • the packaging material constituting the base material of the present invention is a molded product such as a film or sheet, a nonwoven fabric, a woven fabric, a knitted fabric, etc., and a non-water absorbent packaging material is a water-absorbing packaging material.
  • a non-water-absorbing packaging material include polyolefins such as polyethylene and polypropylene, polyamides such as polyester and nylon.
  • the water-absorbent packaging material comprises at least one selected from cotton, silk, hemp, wool, polyacrylonitrile-based synthetic fiber, polyamide-based synthetic fiber, polybulal alcohol-based synthetic fiber, acetate fiber, triacetate fiber, and recycled fiber
  • Non-woven fabrics, woven fabrics and knitted fabrics Absorbent packaging materials with a water absorption rate (measurement method: JIS L1096) of 2% or more, and a water absorption rate (measurement method: JIS L1096) selected from the above fibers is 2% or more.
  • Non-woven fabrics or woven fabrics having the water-absorbing fibers as the main component and highly water-absorbing packaging materials can be mentioned.
  • super absorbent packaging material super absorbent polymer powder, zeolite, silica gel, or non-woven fabric holding diatomaceous earth is coated with super absorbent polymer.
  • a non-woven fabric containing fibers using the material of the packaging material a non-woven fabric containing hollow fibers having a large number of micropores on the surface, or a non-woven fabric containing fibers having a large number of cross-sectional or attacking layers
  • An example is a packaging material.
  • the non-adhesive surface packaging material is preferably a soft and flexible material.
  • Suitable materials for the non-adhesive surface packaging material are not limited, but examples include molded film sheets, woven fabrics, knitted fabrics, and non-woven fabrics.
  • Woven fabrics, knitted fabrics, and non-woven fabrics are manufactured through processes such as fiber spinning, spinning, air-based, thermally integrated, wet-type, melt-blowing, etc. Contains air.
  • Examples of the material composition of the non-adhesive packaging material include cotton, polyester, polyethylene, polypropylene, and nylon.
  • the packaging material for the adhesive surface is a soft, flexible, good-feeling, non-irritating packaging material for skin, is a water-absorbing packaging material, or a packaging material that combines these properties.
  • Examples of the packaging material for the adhesive surface include, but are not limited to, molded films and sheets, woven fabrics, knitted fabrics, and nonwoven fabrics.
  • Woven fabrics, knitted fabrics, and non-woven fabrics are manufactured through processes such as fiber spinning, spinning, air-based, thermally integrated, wet-type, melt-blowing, etc. Contains air.
  • the material composition of the adhesive packaging material is cotton, silk, hemp, wool, polyacrylonitrile-based synthetic fiber, polyamide-based synthetic fiber, polybutyl alcohol-based synthetic fiber, acetate fiber, triacetate fiber, and recycled fiber, polyester, polyethylene, Examples include polypropylene and nylon.
  • the air permeable film used in the present invention for example, a porous film using polyethylene, polypropylene, polyfluorinated titanium film or the like is suitably used, and the pore diameter is determined according to the required air permeability.
  • the ventilation rate is designed in relation to the heat generating agent used depending on the required heat generation and temperature.
  • the porous film is a film having fine through-holes having a maximum pore diameter of about 0.001 to 20 m by a methanol bubbling method.
  • a through-hole is provided by extending a synthetic resin film.
  • an inorganic fine powder such as calcium carbonate dispersed in molten polyethylene, polypropylene, etc., then extruded into a film, and the resulting film is further stretched to provide through holes, etc. .
  • a packaging material made of a nonwoven fabric in which fibers are laminated and thermocompression-bonded to control air permeability such as a polyethylene film or a specific air permeability film such as a perforated hole can be used.
  • non-breathable material there is no restriction if it is a material that does not substantially transmit oxygen.
  • Polyolefin such as polyethylene, polypropylene, and polybutadiene, polyvinyl chloride, polyvinylidene chloride, Films and sheets of polyester, polyether, polysulfone, polyamide, etc., and metal and metal compounds such as aluminum oxide and silicon oxide (including metals including semiconductors) laminated on them by vapor deposition, sputtering, etc.
  • the air-permeable adhesive surface has air permeability and is provided with an adhesive layer.
  • the adhesive used for the adhesive layer has the desired adhesive strength, does not cause transfer to the undergarment, does not adversely affect the human body and the environment, and is stored for a long time until it is used as a fever bag Anything can be used as long as it does not change.
  • the surface of the pressure-sensitive adhesive layer is usually covered with a separator or the like so that it does not stick to other objects until it is used.
  • the non-adhesive surface in contact with the skin is configured not to be provided with an adhesive layer.
  • the material can be appropriately set according to desired properties such as touch, thermal conductivity, water absorption against sweat and the like.
  • a single packaging material for a non-breathable film such as a polyethylene film or a polypropylene film, or a packaging material in which a polyethylene film or a polypropylene film is bonded to a non-woven fabric or a woven fabric, and a packaging material obtained by raising the surface of these materials.
  • the non-adhesive surface packaging material is made of a nonwoven fabric or a woven fabric mainly composed of water-absorbing fibers so that sweat is absorbed when perspiration occurs.
  • U which is preferably composed of V-wrapping packaging material.
  • Water-absorbing fibers with a water absorption rate of 2% or more include cotton, silk, hemp, wool, polyacrylonitrile synthetic fibers, polyamide synthetic fibers, polyvinyl alcohol synthetic fibers, acetate fibers, triacetate fibers, recycled fibers, etc. It can be illustrated.
  • a nonwoven fabric excellent in water absorption a nonwoven fabric in which a highly water-absorbing polymer is held on the nonwoven fabric can be used.
  • the nonwoven fabric or woven fabric which has these fibers as a main component is also a thing with a comparatively favorable feeling with respect to skin.
  • hydrophilic nonwoven fabric used in the present invention for example, hydrophilic materials such as rayon, cotton, and pulp, and a mixture and combination thereof are used.
  • the thickness of the nonwoven fabric is not limited. The thickness is preferably about 100 ⁇ m to 1 mm.
  • a highly water-absorbing packaging material with high sweat absorption can also be used as the non-adhesive surface packaging material.
  • a non-woven fabric including a fiber whose surface is coated with a highly water-absorbent resin a non-woven fabric including a hollow fiber having a large number of micropores on its surface, a cross-sectional shape having a large number of attacks or multiple layers, etc.
  • Non-woven fabrics containing fibers that have a capillary action by using It is.
  • a non-adhesive surface packaging material a non-woven fabric in which a water-absorbing inorganic compound is held, or
  • a film can also be used.
  • a nonwoven fabric in which a powder of diatomaceous earth, zeolite, silica gel or the like is held in a nonwoven fabric a film in which a relatively large amount of powder of silica, alumina or the like is held in a synthetic resin such as polyethylene can be used.
  • antibacterial properties can be imparted to the non-adhesive surface packaging material as desired.
  • Antibacterial agents that can be used in the present invention have high safety without affecting the physiological functions of the human body, and do not produce harmful substances even when discarded.
  • Such antibacterial agents include various types such as inorganic, quaternary ammonia, guanidine, phenol, fatty acid ester, and natural products.
  • the antibacterial agent is applied to and impregnated into the nonwoven fabric, woven fabric, film, paper, and other packaging materials by the gravure roll method, dip roll method, etc. It can also be attached by spraying, spreading or printing.
  • the air permeability of the heating element is inhibited when the surface adheres to the skin. Since the heat generation characteristics fluctuate depending on the state, the air permeability of the heating element is normally limited to the air-permeable adhesive surface.
  • the heating element of the present invention does not exclude imparting air permeability to the packaging material on the non-adhesive surface of the heating element.
  • a packaging material that can ensure air permeability even when the non-adhesive surface packaging material is in close contact with the skin is selected, or when the underwear air permeability has unique properties. Considering this, it is possible to make the non-adhesive surface breathable. Further, when a slight variation is allowed in the heat generation characteristics, air permeability can be imparted to the non-adhesive surface.
  • the non-adhesive surface packaging material is also provided with air permeability, normally, the air permeability of the air-permeable adhesive surface is appropriately adjusted according to the amount of air flow.
  • the pressure-sensitive adhesive layer is provided, but it is preferable that the pressure-sensitive adhesive layer is uniformly dispersed on the air-permeable pressure-sensitive adhesive surface so that it can be applied to the underwear efficiently in a small area.
  • the breathable adhesive surface for example, the adhesive is partially printed in advance on the breathable packaging material, or the adhesive is applied to almost the entire surface of the non-breathable packaging material, and then the needle hole is opened to make it breathable. It can be obtained by this method.
  • the air permeability of the air-permeable adhesive surface means air permeability in a state where an adhesive is applied.
  • the air permeability of the heating element of the present invention is not limited as long as heat generation can be maintained on the ventilation surface having the pressure-sensitive adhesive layer and the pressure-sensitive adhesive layer.
  • one method moisture permeability force by (Lyssy method) is preferably 50 ⁇ : LO, 000g / m 2 /2
  • the moisture permeability is less than 50 gZm 2 Z24hr, the amount of heat generated may be reduced, and a sufficient thermal effect may not be obtained. On the other hand, if the moisture permeability exceeds 10,000 gZm 2 Z24hr, the exothermic temperature will increase. This is not preferable because there is a concern that a safety problem may occur.
  • the fixing means is not limited as long as it has a fixing ability capable of fixing the heating element to the required portion.
  • the fixing means is preferably removable.
  • Adhesive layers, key hooks, hook buttons, hook-and-loop fasteners such as berg mouths, magnets, bands, strings, and combinations thereof, which are generally employed as the fixing means, can be arbitrarily used.
  • the adjustment fixing means may be further constituted by a combination of a hook-and-loop fastener and an adhesive layer.
  • the fixing means There are no restrictions on the installation method, installation location, installation pattern, etc. of the fixing means, and it is preferable to provide at least one part of the exposed part of the heating element as appropriate.
  • the separator may be provided with a slit or the like so that it can be easily peeled off.
  • the fixing means of the present invention has been disclosed in the past, is commercially available, or is publicly known. Fixing means (including removable attachment means) used for disposable warmers and heating elements can be selected and used as appropriate.
  • the hook-and-loop fastener is known by trade names such as Velcro (registered trademark), Velcro fastener (registered trademark), Berg mouth fastener, hook and loop tape, and the like. It has a fastening function in combination with a hook that is a male fastener that can be fastened with a female fastener.
  • the pressure-sensitive adhesive layer is composed of a pressure-sensitive adhesive.
  • the pressure-sensitive adhesive is not limited as long as the heating element can be fixed. Conventionally, it is used for chemical warmers, heating elements and poultices, and is used after technical disclosure.
  • a heating element provided so that the adhesive material layer can be attached to and removed from at least one part of the exposed part of the heating element.
  • the adhesive material layer is a means for fixing the heating element to an inner part of the user's clothes, and the B surface of the heating element is placed directly on the user's body.
  • a double-sided uneven heating element that is located on the A surface of the section heating unit and is provided so that the heating element can be removably attached;
  • the pressure-sensitive adhesive layer is provided on each section of one side of the heating element and on both ends of the heating element extending to both ends of the heating element and at least at both ends in the longitudinal direction of the heating element.
  • the pressure-sensitive adhesive layer has a top region of each heating section on one side of the heating element, and extends to both ends of the heating element, and extends to both ends of the heating element and at least both longitudinal ends of the heating element.
  • a heating element that is provided and ventilated mainly from the side surface of the divided heat generating section of the section;
  • the adhesive layer of 2), 3) and 4) fixes the heating element to the inner part of the user's clothes, and the B side of the heating element is placed directly on the user's body.
  • the heating element is provided on the surface A of the section heating part so that the heating element can be detachably attached thereto.
  • An example is a thermal body.
  • At least a part of the pressure-sensitive adhesive layer or the exposed portion of the heating element is composed of a water retention agent, a water-absorbing polymer, a PH adjusting agent, a surfactant, an organic silicon compound, a hydrophobic polymer compound, a pyroelectric compound, and the like. It may contain at least one selected from the additional ingredients consisting of substances, antioxidants, aggregates, fibrous materials, humectants, functional substances or mixtures thereof.
  • the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer is not limited as long as it has an adhesive force necessary to adhere to the skin or clothes.
  • Solvent type aqueous type, emulsion type, hot melt type, reactivity, sensitivity
  • Various forms such as a pressure system, a non-hydrophilic pressure-sensitive adhesive, a mixed pressure-sensitive adhesive, and a hydrophilic pressure-sensitive adhesive (Giel etc.) are used.
  • the pressure-sensitive adhesive layer may be air permeable or non-air permeable. What is necessary is just to select suitably according to a use. As for air permeability, it is only necessary to have air permeability as a whole.
  • a pressure-sensitive adhesive layer in which the pressure-sensitive adhesive is partially present and there is a part in which the pressure-sensitive adhesive is not present partially, and the entire region is breathable can be given as an example.
  • the method of maintaining the breathability is, for example, by printing the adhesive or transferring the adhesive layer partially.
  • the non-laminated part is used as a ventilation part, and the adhesive is moved in one direction or zigzag while drawing a circle in the shape of a thread.
  • Examples include a method in which the gap between the thread-like adhesives has air permeability or moisture permeability, a method of foaming the adhesive, or a layer formed by a melt blow method.
  • Examples of the adhesive constituting the non-hydrophilic adhesive layer include acrylic, urethane, rubber, silicon, polyisoprene, polyisobutylene, styrene isoprene styrene (SIS), styrene mono
  • SIS styrene isoprene styrene
  • An isoprene-based pressure-sensitive adhesive can be used.
  • an acrylic or SIS system that can be hot-melt processed is preferably used.
  • the hydrophilic pressure-sensitive adhesive constituting the hydrophilic pressure-sensitive adhesive layer is not particularly limited as long as it has a hydrophilic polymer or a water-soluble polymer as a main component and has adhesiveness, and the adhesive is hydrophilic. .
  • hydrophilic polymers such as polyacrylic acid, water-soluble polymers such as sodium polyacrylate polypyrrolidone, carboxymethylcellulose, sodium carboxymethylcellulose, hydroxyethylcellulose, dry aluminum hydroxide and Crosslinking agents such as metal aluminates, soft adhesives such as glycerin and propylene glycol, excipients, hydrophilic adhesives composed mainly of water, (meth) acrylamide, A copolymer of a hydrophilic acrylic monomer such as hydroxyethyl acrylate and a (meth) acrylic acid alkyl ester such as butyl (meth) acrylate or ethyl hexyl (meth) acrylate is used as a protective colloid for butyl (meth ) (Meth) acetates, ethylhexyl (meth) atarylates, etc.
  • water-soluble polymers such as sodium polyacrylate polypyrrolidone, carboxymethylcellulose, sodium carboxymethylcellulose,
  • Wet surface adhesive emulsion type pressure-sensitive adhesive which is a copolymer mixture obtained by polymerizing alkyl rilates and acrylic monomers such as acrylonitrile and acrylic acid, carboxylic acid monomers such as (meth) acrylic acid and butyl acrylate
  • An example is a wet surface adhesive emulsion type pressure-sensitive adhesive which is a copolymer mixture with (meth) acrylic acid alkyl ester such as ethyl ethyl (meth) acrylate.
  • the pressure-sensitive adhesive layer is a hydrophilic pressure-sensitive adhesive layer
  • the moisture permeability of the moisture-proof packaging material is not limited as long as moisture movement can be prevented as long as it does not affect the heat generation performance. in the moisture permeability by law), and preferably, at 2gZm 2 Zday less, more preferably 1. is a 0gZm 2 Zday less, or less and more preferably 0.
  • the moisture-proof packaging material can be used as a base material or a coating material, or can be laminated alone on a base material or a coating material.
  • the moisture-proof packaging material is not limited as long as moisture transfer between the exothermic composition molded body and the hydrophilic pressure-sensitive adhesive layer can be prevented, but a biaxially stretched polypropylene film, a metal vapor-deposited film, a metal Examples include oxide vapor deposition films and metal foil laminate films.
  • the non-air-permeable material can also be used.
  • a packaging material such as a moisture-proof packaging material disclosed in Japanese Patent Application Laid-Open No. 2002-200108 can also be used, and the contents of this description are incorporated in the present invention.
  • a reaction accelerator such as sodium chloride in the heat generating composition is used to adjust the water balance between the heat generating composition and the pressure sensitive adhesive layer.
  • the water-absorbing polymer, etc. in the range of 10 to 40% by weight, preferably 1, 5 to 40% by weight, more preferably 15 to You may adjust in the range of 30 weight%.
  • a pressure-sensitive adhesive having good moisture permeability and low irritation to the skin a water-containing pressure-sensitive adhesive (hydrophilic pressure-sensitive adhesive, Jewel) such as JP-A-10-265373 and JP-A-987173 can be used.
  • 6-145050, JP-A-6-199660, hot-melt-adhesive adhesives are disclosed in JP-A-10-279466 and in JP-A-10-182408.
  • the rubber adhesives described in JP-A-10-279466 and JP-A-10-182408 are emulsions having wet surface adhesion as disclosed in JP-A-2004-263054 and JP-A-2004-263055.
  • the water-based emulsion type pressure-sensitive adhesive having wet surface adhesiveness disclosed in Japanese Patent Application Laid-Open No. 2001-143294 is also useful, and each document is cited and incorporated herein in its entirety.
  • the method, pattern, and shape of the pressure-sensitive adhesive layer may be provided on the entire surface as long as the heating element can be fixed, or may be provided partially or intermittently. Examples include various patterns and shapes such as nets, stripes, dots and bands. A net-like (spider web) pressure-sensitive adhesive layer by the melt blow method is useful.
  • an appropriate method such as a melt-blow method, a curtain spray method, or a gravure method in which a hot-melt type adhesive substance is blown and developed through hot air under heat and melting is used.
  • a method may be used in which an active substance is fiberized or partially coated, and then spread and deposited on a nonwoven fabric or porous film.
  • the covering material In the base material, the covering material, the pressure-sensitive adhesive layer, and the separator constituting the heating element, at least one or a part thereof is a character, a pattern, a symbol, a number, a pattern, a photograph, a picture, a coloring part Any one or more of these may be provided.
  • the installation layer should be determined appropriately.
  • the covering material, the pressure-sensitive adhesive layer, and the separator constituting the heating element each may be any of transparent, opaque, colored, uncolored, and the like.
  • at least one of the layers constituting each material and each layer may be colored in a different color from the other layers.
  • the exothermic composition molded body of the present invention is not limited as long as the exothermic composition molded body can be laminated on a substrate and has a divided heat generating portion.
  • a heat-generating composition molded body formed from a small heat-generating sheet or a sheet-like heat-generating piece can be mentioned.
  • the exothermic composition that can be used in the present invention is not limited as long as the double-sided uneven heating element of the present invention can be produced, but the exothermic composition contains iron powder, a carbon component, a reaction accelerator, and water as essential components, and easily It contains surplus water with a dynamic water value of 0.01 to 13.5, has a moldability of a molding degree of 5 or more, and moisture in the exothermic composition does not function as an air barrier layer.
  • a moldable surplus water exothermic composition that generates heat with a temperature increase of 5 ° C or more within 5 minutes after being left in air at 20 ° C is preferable.
  • the moldable excess water exothermic composition of the present invention includes a molding aid, a water retention agent, a water-absorbing polymer, a hydrogen generation inhibitor, a pH adjuster, an aggregate, and a functional substance.
  • Nonionics such as polyoxyethylene alkyl ethers, zwitterions, ions, cationic surfactants, hydrophobic polymer compounds such as polyethylene and polypropylene, organic silicon compounds such as dimethylsilicone, pyroelectrics Substances, far-infrared emitting materials such as ceramics, negative odor generators such as tourmaline, exothermic aids such as FeC12, metals other than iron such as silicon and aluminum, metal oxides other than iron oxide such as manganese dioxide, hydrochloric acid and Additional components consisting of acidic substances such as maleic acid and acetic acid, fibrous materials such as pulp, fertilizer components such as urea, humectants such as glycerin and D-sorbitol, mold release agents, or mixtures thereof It may contain at least one selected from
  • the component of the exothermic composition of the present invention may be any component of the exothermic composition that has been disclosed in the past, is commercially available, or is used for known disposable warmers or heating elements. You can select and use.
  • the moldable excess water exothermic composition of the present invention can be used with or without a molding aid.
  • the moldability is further enhanced, and the heat generating composition molded body
  • the prevention of collapse of the shape is strengthened, and the shape maintenance of the exothermic composition molded body is strengthened even when moving to the sealing process.
  • the molding aid is 0.001 to 5% by mass with respect to the mass of the iron powder, the exothermic characteristics of the hydrous exothermic yarn and the composition and the exothermic composition molded body are not affected by the molding aid, and the moldability is not included. After forming the surplus water heating composition, it does not remove water such as water absorption, dehydration, water absorption, dewatering, etc., and generates heat in contact with air without adding water or an aqueous solution of a water-soluble component.
  • exotherm with a temperature rise of 5 ° C or more within 5 minutes after being left in air in a 20 ° C environment without wind means that after producing the exothermic composition 24 Immediately after the production of the exothermic composition without leaving an aging period such as standing for a long time, the exothermic composition is placed on a non-water-absorbing material such as a polyethylene film, a polyester film or a sheet in air in a windless environment at 20 ° C. When exotherm is released, the exothermic composition generates heat with a temperature rise of 5 ° C. or more within 5 minutes.
  • a non-water-absorbing material such as a polyethylene film, a polyester film or a sheet in air in a windless environment at 20 ° C.
  • the temperature rise within 5 minutes is preferably 1 ° C or higher, more preferably 5 ° C or higher, still more preferably 10 ° C or higher, more preferably 20 ° C or higher, and more preferably, the temperature rise within 10 minutes is 10 ° C or higher.
  • the method for measuring the temperature rise of the exothermic composition is that the exothermic composition immediately after production or the exothermic composition molded body is used, and there is no wind and the ambient temperature is 20 ⁇ 1 ° C. Measure while still in contact.
  • Using a data collector to measure the exothermic temperature measure the temperature for 10 minutes at a measurement timing of 2 seconds, and measure the temperature at 0 minute, 1 minute, 3 minutes, 5 minutes, 6 minutes, and 7 minutes Then, determine the exotherm at a temperature within 5 minutes.
  • the base material is moved at a constant speed, and the dropping port for dropping the exothermic composition is moved on the base material while moving at the same speed as the base material.
  • the exothermic composition is water-containing, as described above, the exothermic composition, particularly iron powder and air, is produced during the period from the production of the exothermic body until the obtained exothermic body is sealed in an airtight outer bag. Oxidation reaction occurs, and the initial heat generation characteristics of the heat generating composition are improved, so that there is an advantage that a heating element with improved initial heat generation characteristics can be obtained.
  • the amount of excess water in the exothermic composition is defined as a mobile water value.
  • the mobile water value of the moldable excess water exothermic composition of the present invention is preferably not less than 0.01 and not more than 14 It is full, more preferably 0.01-13.5, still more preferably 0.01-13, still more preferably 0.01-12, still more preferably 1-12, still more preferably Is from 2 to 12, more preferably from 3 to 12, more preferably from 4 to 12, still more preferably from 5 to 12, and even more preferably from 5 to L 1.
  • the solid exothermic composition raw material of the moldable excess water exothermic composition of the present invention is a powder, and its particle size is preferably 500 ⁇ m or less, more preferably 425 ⁇ m or less, and further Preferably it is 300 m or less, more preferably 250 / zm or less, more preferably 21 2 ⁇ m or less, more preferably 150 ⁇ m or less, and even more preferably 106 ⁇ m or less. More preferably, it is 90 ⁇ m or less.
  • the particle diameter is a value obtained by displaying the amount passing through the sieve in terms of the sieve opening (diameter of the sieve) ⁇ m.
  • the moldability and shape retention of the moldable excess water exothermic composition are improved as the particle size of the water-insoluble solid component excluding the reaction accelerator, the water-soluble substance and water is smaller.
  • the formability-matched surplus water exothermic composition is not particularly limited, but the carbon component is 1.0 to 50 parts by weight with respect to 100 parts by weight of iron powder, the reaction accelerator.
  • the blending ratio is preferably selected so that it is 1.0 to 50 parts by weight and water is 1.0 to 60 parts by weight.
  • the following composition may be added to the exothermic composition with respect to the iron powder in the following blending ratio.
  • the molding aid and the release agent are each 0.001 to 5 parts by weight, water retention agent 0.01 to 10 parts by weight, water-absorbing polymer 0.01 to 20 parts by weight, pH Conditioner 0.01 to 5 parts by weight, hydrogen generation inhibitor 0.01 to 12 parts by weight, metal other than iron 1.0 to 50 parts by weight, metal oxide other than iron oxide 1.0 to 50 parts by weight, Surfactant 0.01 to 5 parts by weight, hydrophobic high molecular weight compound, aggregate, fibrous material, functional substance, organosilicon compound and pyroelectric substance, respectively 0.01 to 10 parts by weight, moisturizing agent
  • the fertilizer component and the exothermic aid are each preferably 0.01 to 10 parts by weight, and the acidic substance is preferably 0.01 to 1 part by weight.
  • a magnetic substance may be further blended, and the blending ratio may be appropriately determined as desired.
  • This blending ratio can also be applied to a reaction mixture and an exothermic mixture.
  • the mobile water value of the reaction mixture is preferably less than 0.01. Further, the blending ratio that may be further blended with the magnetic material may be appropriately determined as desired.
  • the content of the molding aid is not limited as long as the heat generation performance is not significantly lowered, but is preferably 0.001 to 5 parts by weight, more preferably 0 to 100 parts by weight of the iron powder.
  • 001 to 3 parts by weight more preferably 0.001 to 1 part by weight, still more preferably 0.01 to 1 part by weight, still more preferably 0.01 to 0.5 part by weight. More preferred is 0.01 to 0.2 parts by weight, still more preferred is 0.01 to 0.1 parts by weight, still more preferred is 0.01 to 0.099 parts by weight, still more preferred. Is 0. 01-0. 095 parts by weight.
  • the reaction mixture or exothermic composition is left in the oxidizing gas environment or left to mix, etc.
  • An example is a method for producing an exothermic mixture.
  • the oxidizing gas contact treatment method of the reaction mixture has iron powder, a reaction accelerator and water as essential components, a water content of 0.5 to 20% by weight, and a mobile water value of less than 0.01. The reaction mixture is contacted with oxidizing gas and the temperature rise of the reaction mixture is raised to 1 ° C or higher within 10 minutes.
  • the oxidizing gas contact treatment may be present in a container or in a breathable sheet-like material such as a nonwoven fabric.
  • the acidic gas contact treatment may be either batch type or continuous type under stirring, non-stirring, flowing or non-flowing.
  • the iron powder is not limited! However, pig iron iron powder, atomized iron powder, electrolytic iron powder, reduced iron powder, sponge iron powder, and iron alloy powder thereof can be used as examples. Furthermore, these iron powders It may contain carbon or oxygen, or it may contain more than 50% iron and contain other metals!
  • the type of metal contained as an alloy is not particularly limited as long as the iron component acts as a component of the exothermic composition, but metals such as aluminum, manganese, copper, and silicon, and semiconductors are listed as examples.
  • the metal of the present invention includes a semiconductor.
  • the content of the metal other than iron is usually 0.01 to 50% by weight, preferably 0.1 to 10% by weight, based on the whole iron powder.
  • the thickness of the iron oxide film which is an oxygen-containing film covering the surface of the iron powder, is usually 3 nm or more, preferably 3 nm to 100 m, using the Auger electron spectroscopy.
  • the thickness of the iron oxygen-containing film can exert an effect of promoting the oxidation reaction, and contact with an oxidizing gas such as air causes the oxidation reaction. You can get started right away. If the thickness of the iron oxygen-containing coating is 100 m or more, the heat generation time may be shortened, but it can be used depending on the application.
  • the other is active iron powder having wustite, and the amount of wustite is usually 2 to 50% by weight, preferably 5.01 to 50% by weight, as an X-ray intensity ratio with iron. More preferably, it is from 5.01 to 40% by weight, more preferably from 6 to 40% by weight, still more preferably from 7 to 30% by weight, still more preferably from 7 to 25% by weight. Even if it exceeds 50% by weight, the rise of heat generation is good, but the heat generation duration is shortened. If it is less than 2% by weight, the heat build-up property becomes pure. [0142]
  • the water may be from a suitable source. There are no restrictions on the purity and type.
  • the water content preferably contains 1 to 70% by weight of the exothermic composition.
  • reaction mixture and an exothermic mixture before contact treatment with an oxidizing gas preferably 0.5 to 20% by weight of the reaction mixture or exothermic mixture, more preferably 1 to 20% by weight, still more preferably 3 -20% by weight, more preferably 4-15% by weight.
  • the carbon component is not limited as long as it is a carbonaceous material. Examples thereof include carbon black, graphite, activated carbon and the like.
  • reaction accelerator is not limited as long as it can accelerate the exothermic reaction.
  • inorganic electrolytes such as metal halides such as sodium chloride and potassium salt, metal sulfates such as potassium sulfate, nitrates such as sodium nitrate, acetates such as sodium acetate, and carbonates such as ferrous carbonate As mentioned.
  • metal halides such as sodium chloride and potassium salt
  • metal sulfates such as potassium sulfate
  • nitrates such as sodium nitrate
  • acetates such as sodium acetate
  • carbonates such as ferrous carbonate
  • reaction accelerators are usually used as aqueous solutions, but can also be used in powder form. When used as an aqueous solution of a reaction accelerator, it is treated as a liquid exothermic composition raw material, and there is no restriction on the particle size of the solid raw material for entrusting the preparation of the liquid exothermic composition raw material.
  • the water retention agent is not limited as long as it can retain water. Examples include wood powder, pulp powder, activated carbon, vermiculite, terra balloon, and fossil.
  • the molding aid is a moldability improving agent that improves the moldability of the excess water exothermic composition by a combination with moisture.
  • the molding aid is not limited as long as it is water-soluble or hydrophilic and improves the moldability of the excess water heating composition, but glucose, fructose, sorbitol, maltose, lactose are not limited.
  • Sugars such as sucrose, saccharose, trenorose, pectin, sugar alcohols such as mannitol, sonorebitol, maltitol, erythritol, xylitol, corn starch, wheat starch, rice starch, corn starch, potato starch, dextrin Starch, partially alpha starch, hydroxypropyl starch, carboxymethyl starch, (X-cyclodextrin, 13-cyclodextrin, pullulan and other starches, crystalline cellulose, carboxymethylcellulose, hydroxypropyl cell Loose, low-substituted hydroxypropylcellulose, hydroxypropylmethylcellulose, methinoresenorelose, canoleboxymethylenoresenol
  • the water-absorbing polymer is not particularly limited as long as it has a crosslinked structure and has a water absorption ratio of 3 times or more of ion-exchanged water relative to its own weight. Further, the surface may be cross-linked. Conventional water-absorbing polymers and commercially available ones can also be used. Examples of water-absorbing polymers include poly (meth) acrylic acid cross-linked products, poly (meth) acrylate cross-linked products, and poly (meth) having polyoxyalkylene groups.
  • Cross-linked acrylate ester cross-linked poly (meth) acrylamide, cross-linked copolymer of (meth) acrylate and (meth) acrylamide, co-polymer of (meth) hydroxyalkyl acrylate and (meth) acrylate
  • Polymerized cross-linked products starch-poly (meth) acrylonitrile graft copolymer cans, starch-poly (meth) acrylic acid (salt) graft cross-linked copolymers, polyisobutylene maleic acid (salt) cross-linked polymers, etc. Is an example. These may be used alone or in combination of two or more.
  • the pH adjusting agent is not limited as long as the pH can be adjusted.
  • Alkali metal or Al force There are weak earth salt and hydroxide of alkaline earth metal, Na CO, NaHCO, Na PO, Na HP
  • the hydrogen generation inhibitor is not limited as long as it suppresses the generation of hydrogen.
  • at least one sentence selected from the group consisting of thio compounds, oxidants, alkaline substances, io, antimony, selenium, phosphorus and tellurium also has two or more abilities.
  • the iodo compound is a compound with an alkali metal or an alkaline earth metal, such as a metal sulfate such as calcium sulfate, a metal sulfite such as sodium sulfite, or a metal thiosulfate such as sodium sulfate.
  • a metal sulfate such as calcium sulfate
  • a metal sulfite such as sodium sulfite
  • a metal thiosulfate such as sodium sulfate.
  • the aggregate is not particularly limited as long as it is useful as a filler and is useful for making Z or the exothermic composition porous.
  • Fossil coral coral fossil, weathered reef coral etc.
  • bamboo charcoal Bincho charcoal
  • silica-alumina powder silica-magnesia powder
  • kaolin crystalline cellulose
  • colloidal silica pumice
  • silica gel silica powder
  • my strength powder clay
  • talc Examples include powders and pellets of synthetic resins, foamed synthetic resins such as foamed polyester and polyurethane, algae, alumina, and fiber powder.
  • Examples of the fibrous material include, for example, vegetable fibers (cotton, cabbage, wood pulp, non-wood pulp, peanut protein fiber, corn protein fiber, soybean protein fiber, mannan). Fiber, rubber fiber, hemp, Manila hemp, sisal hemp, New Zealand hemp, Rafu hemp, lion, igusa, straw, etc.), animal fiber (wool, goat hair, mohair, cashmere, alkanoku, Angola, camel, vicuuna , Silk, feathers, down, feather, algin fiber, chitin fiber, casein fiber, etc.) and mineral fibers (asbestos, etc.).
  • Examples of synthetic fibers include semi-synthetic fibers (acetate, triacetate, oxidized acetate).
  • single fibers such as polyolefins such as high density polyethylene, medium density polyethylene, low density polyethylene, polypropylene, polyester, polyvinylidene chloride, starch, polybutyl alcohol or polyacetate butyl, or copolymers or modified products thereof.
  • polyolefins such as high density polyethylene, medium density polyethylene, low density polyethylene, polypropylene, polyester, polyvinylidene chloride, starch, polybutyl alcohol or polyacetate butyl, or copolymers or modified products thereof.
  • Polyolefin and modified polyester are preferably used.
  • Synthetic fibers such as polyolefin having branching are also preferably used because of their good fixability with acid-repellent metals and water retention agents. This These fibers can be used alone or in combination of two or more. These fibers can also be collected and reused.
  • wood pulp and cotton are preferably used from the viewpoints of the oxidizable metal, fixability of the water retention agent, flexibility of the resulting molded sheet, oxygen permeability resulting from the presence of voids, production cost, and the like. It is done.
  • the fibrous material preferably has an average fiber length of 0.1 to 50 mm.
  • the release agent is not limited, but is a lubricating oil composed of mineral oil, synthetic oil, animal and vegetable oil, etc., highly viscous lubricating oil such as grease, natural wax, synthetic wax, silicone oil, Examples thereof include silicon rosin, stearic acid, stearates, and the like.
  • the functional substance may be any substance as long as it has some function such as medicinal effect and aroma.
  • acidic mucopolysaccharides such as alkaloid compounds; , Anthocyanin, vitamin P, kinka, silanol, terminaria, mayus, etc .
  • organic Slimy agents such as iodine compounds, hyperic leather, cedar, mannen wax, ginseng, hyanore mouth-dase; indomethacin, dl-camphor, ketoprofen, shoga extract, pepper extract, methyl salicylate, glycolic salicylate, etc. Pain; fragrances such as lavender, rosemary, citron, jeper, peppermint, eucalyp
  • the percutaneously absorbable drug is not particularly limited as long as it is percutaneously absorbable, and examples thereof include skin stimulants, analgesic anti-inflammatory agents such as salicylic acid and indomethacin, and central nervous system agents.
  • skin stimulants such as salicylic acid and indomethacin
  • analgesic anti-inflammatory agents such as salicylic acid and indomethacin
  • central nervous system agents such as central nervous system agents.
  • humectant examples include polyols such as glycerin, ceramides, collagens and the like.
  • the moisturizing function of the moisturizer is enhanced by the synergistic effect of the moisturizer and heat, and the skin can be moisturized and tensioned.
  • Nop percent examples of anti-inflammatory agents such as indomethacin and methyl salicylate. These poultices also promote transdermal absorption due to a synergistic effect with ripening, and can effectively improve muscle pain, joint pain, low back pain and the like.
  • the method for producing the heating element of the present invention includes laminating the exothermic composition molded body on the base material, covering the covering material, and sealing the peripheral edge of the exothermic composition molded body. It is manufactured by doing.
  • a method for producing a heating element using the moldable excess water heating composition of the present invention comprises producing a heating composition molded body by a mold molding method such as a mold-through molding method or a swallow molding method, It is manufactured by laminating on a base material, covering with a covering material, and sealing the periphery of the exothermic composition molded body.
  • a mold molding method such as a mold-through molding method or a swallow molding method
  • a moldable surplus water exothermic composition with an easy water value of more than 13.5 to 50 or less is formed by molding, a exothermic composition molded body is laminated on the nonwoven fabric, and the nonwoven fabric is further covered, Press with a roll, dry with hot air (nitrogen or air, etc.) at 30 to 200 ° C, cut and laminate the sheet on the base material, cover with the covering material, the peripheral part of the exothermic composition molded body It is manufactured by sealing. Water or a reaction accelerator aqueous solution such as sodium chloride may be added during the process of sealing the periphery of the exothermic composition formed from the exothermic composition that does not contain a reaction accelerator such as sodium chloride after drying with hot air. Oh ,.
  • the mold-through molding method uses a punching die, molds a moldable excess water heating composition, laminates a punching-shaped heating composition molding on a substrate, and generates a heating composition. This is a method for producing a molded article.
  • the punching die is a die having a through hole having a desired shape and thickness.
  • Hollow drum-like strut conveyor using a drum-shaped forming device in which the through-hole is provided on the rotating surface of the rotary body and a strut-conveyor-like rotary body provided with a plurality of struts having the through-hole An example is a shape forming apparatus.
  • a rotary punching die is used, and a molding machine for laminating a die-shaped exothermic composition molded body on a long base material and covering it with a long covering material.
  • a rotary sealer that can seal the section and the periphery of the base material and coating material (heat seal, pressure seal, heat seal, etc.), and around the exothermic composition molded body through the seal
  • An example is a continuous forming method in which the necessary portions of the section and the section are heat sealed and sealed.
  • the squeeze-molding method is a method of forming a heat-generating composition by filling a moldable excess water exothermic composition into a squeeze mold having recesses and laminating the molded exothermic composition compact on a substrate.
  • a punching die is a die having a recess having a desired shape and thickness.
  • An example is a heat generating composition molded body manufacturing apparatus in which a concave portion is provided on the outer surface of a drum-shaped rotating body or a hollow drum-shaped rotating body.
  • a molding machine for laminating a heat-generating composition formed body on a long base material by covering the concave portion with a drum-shaped rotating body and transferring it to the base material, and covering it with a long covering material Using a rotary sealer that can seal the target section and the periphery of the base material and coating material (heat seal, pressure seal, thermocompression seal, etc.), the exothermic composition molded body through the seal device
  • a continuous forming method in which necessary portions of the twill part and the divided part are heat sealed and sealed.
  • the exothermic composition molded body of the present invention generates heat upon contact with air (oxygen), can be stacked on a substrate, can maintain its shape, is covered with a covering material, and has a peripheral edge of the exothermic composition molded body.
  • air oxygen
  • a perforated exothermic sheet or a sheet-like exothermic piece is also used in addition to the exothermic composition molded body obtained by molding the moldable excess water exothermic composition. Can be used. That is,
  • a sheet-like heating piece with holes which is provided with a striped space (including slits) having a width of 0.001 to 50 mm on the sheet-like heating piece and generates heat upon contact with air (oxygen), and its cut processed product
  • the size of the exothermic composition molded body of the above 3) and 4) may be determined according to the desired size of the double-sided uneven heating element.
  • the distance between the exothermic composition molded body space and the space in 3) and 4) applies the width of the same exothermic part.
  • the size of the exothermic composition formed by molding the moldable excess water exothermic composition by molding is applied to the size of the other part.
  • the notch provided in at least one end of the heating sheet and the sheet-shaped heating piece of 3) to 4) may be a straight line or a two-dimensional shape such as a triangle. You can have it.
  • the components of the exothermic composition used in conventional warmers and exothermic bodies can be used without particular limitation.
  • the segmented heat generating part using the sheet-like exothermic composition molded body is also a segmented heat generating part provided in a stripe shape.
  • the heat generating sheet is not limited as long as it is a sheet-like material that generates heat upon contact with air (oxygen).
  • Examples of the heat generating sheet include a dispersive heat generating sheet, a papermaking heat generating sheet, and a pressure processing heat generating sheet.
  • the manufacturing method of each sheet of the present invention described above is processing such as cutting, punching, punching Z cutting and the like of the material heat generating sheet and a small width (width is lmm to 30 mm, preferably width is lmm to 25 mm, more preferably width is lmn! 24. 5mm) production of the sheet is preferred.
  • the manufacturing method of a raw material sheet can use a well-known manufacturing method. For example, W096Z11654 and JP-A-2003-102761, WO00Z13626 and the like can be cited as examples. Also space (including Installation of the slit) is limited can be used Nag known methods, mechanical cutting method or a laser (l Aser) by cutting method such as a guillotine cutter or cutting roll is found as an example.
  • the dispersive exothermic sheet is not limited as long as the exothermic composition is dispersed and retained in a non-woven fabric or other packaging material having a porosity, and processed into a sheet-like exothermic body.
  • Oxidizable metal powder Carbon component, powder raw material exothermic composition containing water retention agent as essential components is dispersed in the nonwoven fabric, and then an aqueous solution of reaction accelerator such as electrolyte is added, and contact with air (oxygen) generates heat. This is an exothermic sheet.
  • the paper-making exothermic sheet is not limited as long as the exothermic composition is processed into a sheet-like heating element by a paper-making method.
  • the oxidizable metal powder such as iron powder, carbon component, water retention agent,
  • a paper sheet made from a slurry-like raw material exothermic composition containing fiber and water as essential components by papermaking is dried with hot air at 90 to 200 ° C, and a reaction accelerator such as an electrolyte or an aqueous solution thereof is added to air (oxygen).
  • a heat-generating sheet that generates heat upon contact with () may be mentioned.
  • the pressure-processable exothermic sheet is not limited as long as the exothermic composition is processed into a sheet-like heating element by the pressure-processing method, but the following 1) and 2) are given as examples. It is done.
  • components of the moldable excess water exothermic composition can be used.
  • ethanol, propylene glycol, glycerin and the like are preferable as the alcohol.
  • the cross-linking agent causes cross-linking between the water-absorbing polymers, cross-linking between the second polymers, cross-linking between the water-absorbing polymer and the second polymer, and a cross-linking reaction between these polymers.
  • at least one cross-linking agent that promotes cross-linking is preferable among the ones that intervene between these polymers to cause crosslinking. Examples include ethylene glycol diglycidyl ether and methylene bisacrylamide.
  • Oxidizable metal powder such as iron powder, carbon component, molding aid, reaction accelerator and water are essential components.
  • the water-containing exothermic composition containing 1 to 15% by weight, preferably 3 to 15% by weight of the molding aid with respect to the total amount and having an easy water value of less than 0.01 is applied with a predetermined pressure. Integrated heat generation sheet.
  • water-absorbing polymers such as wood powder, hydrogen generation inhibitors such as sodium sulfite, pH regulators such as slaked lime, etc. that have been publicly disclosed. Can be appropriately selected and used.
  • a heat-generating sheet When a pressure-processed heat generating sheet is made into a sheet by the pressure processing method, a heat-generating sheet, a sheet-shaped heating piece, or a holed mold can be used depending on the size of the mold hole. A heating piece can be manufactured.
  • the pressure processing method is not limited as long as it is a method in which a exothermic composition is put into a mold cavity and pressed in a mold and the exothermic composition is compressed and molded.
  • Exothermic composition Is placed in a cylindrical mold and pressed to form.
  • the pressure and pressurizing time are not limited as long as they can be molded, but the pressure is preferably 100 to 9000 kgZcm 2 and the time is preferably 0.01 to 30 seconds.
  • the exothermic composition is rolled at a predetermined pressure using a roller to form a sheet-like heating element.
  • a heat generating composition is placed in a mold hole having a recess or a through hole having a desired shape, and a deformable flexible roll such as a balloon roll or a roll having a protrusion that can be inserted into the mold hole. Pressing with a heating means such as a belt or the like with a heat generating composition in the mold cavity, the heat generating composition is compressed and molded.
  • the heat treatment conditions in this case are not limited, but are preferably 50 to 250 ° C. and about 1 to 20 minutes.
  • Exothermic composition molded body molded from moldable excess water exothermic composition by molding and exothermic composition molded body composed of sheet-like heating piece, hole-like heating sheet, hole-like sheet-like heating piece
  • Dispersion-type heating sheets, dispersion-type sheet-like heating pieces, paper-making-type heating sheets, paper-making-type sheet-like heating pieces, pressure-processing-type heating sheets, and pressure-processing-type sheet-like heating pieces are heating sheets. It also includes a laminate obtained by arbitrarily combining packaging materials such as non-woven fabrics.
  • the size of the sheet-like heating piece is not limited, but is preferably the following size.
  • the shape is preferably a rectangle or a rectangle-like shape.
  • the width is preferably lmm to 30mm, more preferably lmn! ⁇ 24.9mm, more preferably lmn! ⁇ 24mm, more preferably lmn! ⁇ 23mm, more preferred lmn! -23 mm, more preferably 1 mm-20 mm, more preferably 3 mm-20 mm, and even more preferably 5 mn! ⁇ 15mm, more preferably 5mn! ⁇ 10 mm.
  • the length is preferably 5 mm to 300 mm, more preferably 5 mm to 200 mm, more preferably 5 mm to 100 mm, more preferably 20 mm to 150 mm, and even more preferably 30 mm to: L OOmm It is.
  • the ratio of (length Z width) is preferably 2.0 to 60, more preferably 2.1 to 60, more preferably 2.1 to 50, and still more preferably 2.1 to 40. More preferably 2.1 to 30, more preferably 2.5 to 25, more preferably 2.5 to 20, and further preferably 3 to 20. It is.
  • the height is preferably from 0.111111 to 10111111, more preferably from 0.3 mm to 10 mm, and even more preferably 0.5 mn! ⁇ 10mm, more preferably lmm ⁇ : L Omm, more preferably 2mn! ⁇ 1 Omm.
  • the size of the sheet-like heating piece with holes may be determined according to the size of the double-sided uneven heating element and the size of the dividing portion.
  • the width of the space is not limited as long as flexibility can be secured, but is usually 0.001 mn! ⁇ 50mm, preferably 0. Olmn! -50 mm, more preferably 0.1 mm to 50 mm, and even more preferably 0.3 mn! ⁇ 50mm, more preferably 0.3mm ⁇ 50mm, still more preferably 0.3mn! ⁇ 40mm, more preferably 0.5mn! ⁇ 3 Omm, more preferably lmn! ⁇ 30mm, more preferably lmn! ⁇ 20mm, more preferably 3mm ⁇ : LOmm.
  • the width of the section is not limited as long as flexibility can be secured, but is usually 0.1 lmn! -50 mm, preferably 0.3 mm to 50 mm, more preferably 0.3 mm to 50 mm, and even more preferably 0.3 mn! ⁇ 40mm, more preferably 0.5mn! ⁇ 30mm, more preferably lmn! ⁇ 30mm, more preferably lmn! ⁇ 20mm, even better It is 3 to 10mm.
  • the size of the heat generating sheet with holes may be determined according to the size of the double-sided uneven heating element.
  • the width of the space is not limited as long as flexibility can be secured, but is usually 0.001 mn! ⁇ 50mm, preferably 0. Olmn! -50 mm, more preferably 0.1 mm to 50 mm, and even more preferably 0.3 mn! -50 mm, more preferably 0.3 mm to 40 mm, and even more preferably 0.5 mn! ⁇ 30mm, more preferably lmm ⁇ 30mm, more preferably lmm ⁇ 20mm, more preferably 3mn! ⁇ 10mm
  • the total area of the heat generating regions other than the space is not limited, but preferably, the total area of the divided heat generating portions is 50 to 85% with respect to the entire heat generating surface of the heating element, More preferably, it is 50 to 70%. Within this range, heat storage can be suppressed and redness, medical treatment, etc. can be more effectively prevented.
  • the shape of the segmented heat generating portion includes a continuous stripe shape and a discontinuous stripe shape as shown in FIGS.
  • the width of the section In order to have a partial stimulating element in many places and to expect comfortable thermotherapy, it is preferable to set the width of the section to 3.5 to: LOmm. It is preferable to set the ratio of the width of the partition and the width of the partition part (air layer part) to 1: 1 to 3: 1.
  • the ratio of the width of the section heating section to the section section (air layer section) is preferably 1: 1 to 3: 1.
  • the ratio of the width of the section heating section to the section section is preferably 1: 1 to 3: 1.
  • the nonwoven fabric (b) is laminated on the lower surface of the nonwoven fabric (a) having a large number of voids, and the exothermic composition powder and the mature melt adhesive powder are sprayed on the upper surface of the nonwoven fabric (a), and the nonwoven fabric ( c) After the stacking, a sheet-like product is formed by heating and compressing with a heating compressor, and then impregnated with water or an aqueous inorganic electrolyte solution. Three-layer nonwoven fabric-dispersed heat-generating sheet cut to size, 2) After water is attached to the lower surface of the nonwoven fabric having a large number of voids, the heat generating composition powder is spread and held on the upper surface of the nonwoven fabric.
  • Two-layer nonwoven fabric dispersion type that is obtained by superposing and compressing another nonwoven fabric having a large number of voids on the upper surface of this nonwoven fabric and then spraying water or an aqueous electrolyte solution or cutting it into a desired size.
  • a heat generating sheet is an example.
  • the three-layer nonwoven fabric dispersed heat generating sheet will be described.
  • the three-layer nonwoven fabric heating sheet of the distributed heating sheet is
  • the nonwoven fabric (b) is superimposed on the lower surface of the nonwoven fabric (a) having a large number of voids, and the nonwoven fabric (c) is superimposed on the upper surface of the nonwoven fabric (a).
  • the exothermic composition powder and the hot-melt adhesive powder are held between the non-woven fabric (a) and the non-woven fabric (c), and the non-woven fabric (a) and the non-woven fabric (c) are bonded by water compression by a heat compressor. Or a heating sheet impregnated with an aqueous inorganic electrolyte solution,
  • the heat generating composition powder and the hot-melt adhesive powder are held in the gap between the nonwoven fabric (a) and the nonwoven fabric (c) and between the laminate of the nonwoven fabric (a) and the nonwoven fabric (c).
  • the exothermic composition powder and the hot-melt adhesive powder are held in the non-woven fabric, and at least one surface is bonded to the other non-woven fabric in contact with the non-woven fabric by heat compression of a heating compressor, and impregnated with water or an aqueous inorganic electrolyte solution
  • the exothermic sheet formed is mentioned as an example.
  • the hot melt adhesive powder is made of ionomer, ethylene 'butyl acetate copolymer, polyethylene, homopolymer of thermoplastic resin such as polypropylene, polymer blend of these thermoplastic resin, and mature plastic resin. It is preferable that it is at least one selected from the group consisting of hot melt as a base polymer.
  • the softening point of the hot melt adhesive powder is preferably 40 to 200 ° C.
  • the amount of hot melt adhesive powder added is 0.1 to 20 per 100 parts by weight of oxidizable metal powder. It is preferably 0 parts by weight.
  • the particle size of the hot-melt adhesive powder is preferably 0.2 to 2 mm in diameter. It is preferable that the heating compressor has an emboss on at least one of the compression surfaces.
  • Non-woven fabric (a), non-woven fabric (b), and non-woven fabric (c) It is preferable that the main component is at least one selected from the group consisting of 1S, cotton, hemp, rayon and acetate.
  • the non-woven fabric is a non-woven fabric having a large number of voids, and among the exothermic composition raw materials that generate heat upon contact with air, a mixture of those used in powder form (hereinafter referred to as exothermic composition powder) is used.
  • exothermic composition powder a mixture of those used in powder form
  • known non-woven fabrics can be used because they can be held in voids and have high water retention and flexibility. It is preferable to have a concave and convex surface constituted by the embossed surface of the compression roll on the compression surface of the nonwoven fabric.
  • the exothermic composition powder may contain iron powder and a carbon component as essential components, and may contain at least one of the components of the moldable excess water exothermic composition.
  • the two-layer nonwoven fabric-dispersed exothermic sheet has a plurality of voids, the first nonwoven fabric with water attached to the lower surface, and the heat generated by being dispersed from the upper surface of the nonwoven fabric and held in the voids inside the nonwoven fabric. And a sheet-like product formed by compressing the nonwoven fabric with a mold compressor. It is a heat generating sheet in which a product is impregnated with water or an aqueous inorganic electrolyte solution.
  • the two-layer nonwoven fabric dispersive exothermic sheet has a plurality of non-woven fabrics stacked on top of each other with water adhesion or water adhesion and compressive force, so that the exothermic composition is held in at least one non-woven fabric void.
  • first nonwoven is composed mainly pulp, cotton, hemp, the fiber selected rayon force, porosity from 60 to 99.5%, a thickness of 0. 5 to 25 mm, basis weight is 5 ⁇ 200GZm 2 It is preferable.
  • the exothermic composition powder is sprayed on the upper surface and held in the voids, and then the second nonwoven fabric on the upper surface of the first nonwoven fabric.
  • An example is a heat-generating sheet in which a nonwoven fabric is laminated and compressed with a mold compressor and impregnated with water or an aqueous inorganic electrolyte solution.
  • the amount of water to be deposited is 10-200gZm 2 ! /.
  • a method for producing the two-layer nonwoven fabric dispersed heat generating sheet a known production method can be used. It is preferable to have a concavo-convex surface constituted by the embossed surface of the compression roll on the compression surface of the nonwoven fabric.
  • the components of the exothermic composition can be used in a dispersion type exothermic sheet, a papermaking type exothermic sheet, and a pressure-compression type exothermic sheet.
  • the hot-melt adhesive powder is the same as the three-layer nonwoven fabric-dispersed heat generating sheet.
  • the papermaking exothermic sheet is made by making an intermediate molded body from a raw material composition containing at least iron powder, carbon component, fibrous material and water in a papermaking process, and then heating and drying the intermediate molded body at 60 to 300 ° C. Further, a heat generating sheet in which an electrolyte (a reaction accelerator such as sodium chloride) or an aqueous solution thereof is added and contained (impregnated) into the intermediate molded body by spray coating or spraying is preferable.
  • an electrolyte a reaction accelerator such as sodium chloride
  • an aqueous solution thereof is added and contained (impregnated) into the intermediate molded body by spray coating or spraying is preferable.
  • the heat generating sheet is a heat generating composition molded body that generates heat upon contact with air (oxygen).
  • the raw material composition is at least iron powder, carbon component, reaction accelerator (inorganic electrolyte), thermoplastic fiber, and water, and the raw material composition is paper-made, and the obtained intermediate molded body is 90 to 300 °. After heating and drying with C, the intermediate molded body is added with a reaction accelerator (inorganic electrolyte) or an aqueous solution thereof (impregnated) by spray coating or spraying, and the mature plastic fibers are fused inside.
  • the papermaking heat generating sheet preferably contains 50% by weight or more of components other than the fibrous material, such as iron powder, carbon component, and fibrous material.
  • the raw material composition may contain at least one component of the moldable excess water heating composition.
  • the amount of the oxidizable metal such as iron powder in the component obtained by removing the electrolyte from the papermaking heat generating sheet is preferably 10 to 95% by weight.
  • a flocculant may be added to the papermaking heat generating sheet.
  • Additives can be added without particular limitation.
  • the addition amount of the additive can be appropriately set according to the additive to be added.
  • the density of the papermaking heat generating sheet is preferably 0.6 to 3. OgZcm 3 .
  • the papermaking exothermic sheet preferably has a moisture content (weight moisture content, the same shall apply hereinafter) of 10 to 80%.
  • the flocculant examples include inorganic coagulants such as sulfate bands, polysalts and aluminum; clay minerals such as bentonite; diacids such as colloidal silica or hydrates thereof; Examples thereof include magnesium silicate and the molding aid. Besides these combinations, these flocculants can be used alone or in combination of two or more.
  • the amount of the flocculant added is preferably 0.01 to 5% by weight based on the solid content of the raw material composition.
  • the concentration of the raw material composition is preferably 0.05 to 10% by weight, more preferably 0.1 to 2% by weight.
  • a known papermaking method such as a short net paper machine can be used as a papermaking method for forming the papermaking sheet by papermaking the raw material composition.
  • the paper sheet is dehydrated until the water content (weight water content, the same shall apply hereinafter) is 70% or less from the viewpoint of maintaining the form after paper making (shape retention) and maintaining the mechanical strength. It is more preferable to dehydrate until 60% or less.
  • the moisture content of the papermaking sheet after drying is preferably 20% or less, more preferably 10% or less.
  • excellent long-term storage stability for example, even when temporarily stored in a wound roll state, etc., heat generation performance in which moisture does not easily move in the thickness direction of the roll, Excellent in that it can supply a uniform product in mechanical strength!
  • the water content is adjusted according to necessity, It can be stabilized to form a papermaking type heat generating sheet. If necessary, the paper-making heat generating sheet and the paper-making sheet can be processed into a predetermined size by performing processes such as trimming and laminating two or more sheets.
  • the pressure-processable exothermic sheet is a mixture of an exothermic composition containing iron powder, a carbon component, a reaction accelerator, and water as essential components with a water-absorbing polymer and a second polymer other than Z or a water-absorbing polymer.
  • An exothermic sheet in which either a crosslinking agent or a plasticizer is added and a predetermined pressure is applied to the exothermic sheet is preferred.
  • components of the moldable excess water exothermic composition can be used.
  • ethanol, propylene glycol, glycerin and the like are preferable as the alcohol.
  • the cross-linking agent causes cross-linking between the water-absorbing polymers, cross-linking between the second polymers, cross-linking between the water-absorbing polymer and the second polymer, and a cross-linking reaction between these polymers.
  • at least one cross-linking agent that promotes cross-linking is preferable among the ones that intervene between these polymers to cause crosslinking. Examples include ethylene glycol diglycidyl ether and methylene bisacrylamide.
  • a heat-generating sheet with holes in which a stripe-shaped space is provided in a heat-generating sheet such as the distributed heat-generating sheet, the paper-making heat-generating sheet, and the pressure-processed heat-generating sheet is a plurality of striped space portions in the heat-generating sheet.
  • the length of the part is preferably 5 mm to 200 mm, the width is preferably 1 mm to less than 25 mm, and the height is preferably 0.5 mn!
  • the ratio of (length Z width) is preferably 2.1 to 30 and the width of the space is not limited, but the width of the space is preferably l to 30mm,
  • the separate heat generating parts are separated from each other, and are formed in a stripe shape in at least one direction by the stripe-shaped space, and are easy to bend in one direction. Only has a structure that is easy to bend.
  • the heat generating sheet with holes there is provided a heat generating sheet with holes in which the striped space of the heat generating sheet with holes has a cutout at least at one end of the heat generating sheet with holes on the extension line of the stripe. As an example.
  • the exothermic composition molded body is laminated on a substrate, covered with a coating material, and the peripheral edge and Z or space of the exothermic composition molded body are heat-sealed to form a heating element.
  • the sheet-like heating piece with holes is a sheet-like heating piece in which a striped space is provided in a sheet-like heating piece such as the dispersion-type sheet-like heating piece, the paper-making sheet-like heating piece, and the pressure-working-type heating sheet piece. It is a heat-generating composition molded body which is a heat-generating piece or a cut processed product thereof.
  • the ratio of the length, width, height, (length Z width) of the segmented heat generating portion, which is the region between the space portions, is not limited, but the length force of the segmented heat generating portion is preferably 5 mn! ⁇ 200mm, width is preferably lmm or more and less than ⁇ 25mm, height is preferably 0.5mn! ⁇ 10mm, and the ratio of (length Z width) is preferably 2.1 ⁇ 30,
  • the width of the space portion is not limited, but the width of the space portion is preferably 1 to 30 mm, and the plurality of divided heat generating portions are separated from each other, and are striped in at least one direction by the stripe-shaped space portion. It is formed and has a structure that is easy to bend in one direction and has a structure that is easy to bend in only one direction compared to other directions.
  • the exothermic composition molded body is laminated on a substrate, covered with a coating material, and the peripheral edge and Z or space of the exothermic composition molded body are heat-sealed to form a heating element.
  • the method for producing a heating element of the present invention (a heating element before cutting) is formed by laminating a heating composition molded body on a substrate, covering with a covering material, and sealing the peripheral edge of the heating composition molded body. This is a method for producing a heating element.
  • a sheet-like heating piece such as the dispersion-type sheet-like heating piece and the paper-making type sheet-like heating piece is used as a heating assembly molded body, and the heating composition molding is laminated on a substrate, and a covering material is covered.
  • a method for producing a heating element by laminating a thermal composition molding on a substrate, covering with a covering material, and sealing the peripheral edge of the heating composition molding,
  • a sheet-like heating piece with a hole having a stripe-shaped space is used as a heating assembly molded body, the heating composition molding is laminated on a base material, and a covering material is placed over the periphery of the heating composition molding.
  • the heating yarn and the molded article may be laminated and fixed on a base material through a fixing layer made of an adhesive or an adhesive. ⁇ .
  • the mobile water value is a value indicating the amount of surplus water that can move out of the exothermic composition in the water present in the exothermic composition. This easy water value will be explained.
  • a non-water-absorbing 70 / zm polyethylene film is placed so as to cover the hole, and further, a thickness of 5 mm X a length of 150 mm X Place a stainless steel plate with a width of 150 mm and hold for 5 minutes. Then, the filter paper is taken out, and the soaking locus of water or aqueous solution is read in mm units as the distance from the circumferential portion that is the edge of the hole of the hollow cylinder to the soaking tip along the radial line. Similarly, the distance is read from each line to obtain a total of 8 values.
  • Each of the 8 values (a, b, c, d, e, f, g, h) read is taken as the measured moisture value.
  • the arithmetic mean of the 8 measured moisture values is the moisture value (mm) of the sample.
  • the moisture content for measuring the true moisture value is the blended moisture content of the exothermic composition or the like corresponding to the weight of the exothermic composition or the like having an inner diameter of 20 mm and a height of 8 mm, and only water corresponding to the moisture content is used. Measure in the same way with, and calculate the same as the true moisture value (mm).
  • the moisture content for measuring the true moisture value is determined by determining the moisture content of the exothermic composition from the moisture content measurement using an infrared moisture meter for the exothermic yarn and composition. Based on this, the amount of water necessary for measurement is calculated, and the true water value is measured and calculated from the amount of water.
  • the exothermic composition having a mobile water value of 0.01 or more and less than 14 is placed a non-water-absorbing 70 / zm polyethylene film so as to cover the hole, and further, a thickness of 5 mm X a length of 150 mm If a windshield is put on instead of placing a stainless steel flat plate with an X width of 150 mm, the heat generating composition of the present invention undergoes an exothermic reaction during measurement, making measurement impossible.
  • the exothermic composition being moldable means that the exothermic composition has a molding degree of 5 or more.
  • the degree of molding refers to the shape of the exothermic composition molded body, which is a molded body of the exothermic composition in the shape of the punched hole by mold-through molding using a punching die having a punched hole, after being separated from the mold. Maintain the maximum length of 300 ⁇ at the peripheral edge of the exothermic composition molded body that the maximum length exceeds 800 m!
  • the moldability of the exothermic composition is numerically expressed by the number of pieces of the exothermic composition molded body of up to 800 m.
  • a stainless steel mold (with 60mm x 40mm in the center is treated to 5 corners (substantially arc-shaped, radius of curvature 5mm), and the upper part of the punched hole (heat generation composition)
  • the corners on the four sides of the product inlet) are 1 radius r (substantially arcuate, with a radius of curvature of 1 mm), and the corners on the four sides of the lower part of the punch hole (exit of the heated yarn and the molded product) are 3 radius r.
  • a plate with a thickness of 2mm x length 200mm x width 200mm with a punch hole provided in a substantially arc shape and a radius of curvature of 3mm, with the outer surface of the mold and each wall surface of the punch hole made smooth.
  • the smooth surface is not limited as long as it is smooth.
  • Force Surface roughness Ra force is preferably 10 ⁇ m or less, more preferably 4 ⁇ m or less, and further preferably 2 ⁇ m or less.
  • the magnet covers an area that is larger than the area (40 mm) of the maximum cross section with respect to the direction of travel of the punching hole of the mold, and the area in the vicinity thereof.
  • a stainless steel plate with a thickness of lmm x length 200mm x width 200mm is placed on the endless belt of the measuring device, and a polyethylene plate with a thickness of 70 ⁇ m x length 200mm x width 200mm is placed on the stainless steel plate. Place the stainless steel mold.
  • a molding degree of 1 means that the maximum length is 300 ⁇ , provided that there is no broken piece of the exothermic composition molded body whose maximum length exceeds 800 ⁇ m! There are 9 or more pieces of broken pieces of ⁇ 800 m exothermic yarn and molded product.
  • a forming degree of 2 means that there are 8 pieces of broken pieces of heat-generating yarn and molded product with a maximum length of 300 m to 800 m.
  • a forming degree of 3 means that there are seven pieces of broken pieces of heat-generating yarns and molded articles with a maximum length of 300 m to 800 m.
  • the forming power is the 6 pieces of broken pieces of heat-generating yarn and molded product with a maximum length of 300 m to 800 m.
  • a forming degree of 5 means that there are 5 pieces of exothermic yarn and molded product of maximum length 300 m to 800 m.
  • a forming degree of 6 means that there are four pieces of broken pieces of heat-generating yarns and molded articles with a maximum length of 300 m to 800 m.
  • a forming degree of 7 means that there are three pieces of broken pieces of heat-generating yarn and molded product with a maximum length of 300 m to 800 m.
  • a forming degree of 8 means that there are two pieces of broken pieces of exothermic yarn and molded product with a maximum length of 300 m to 800 m.
  • a forming degree of 9 means that there is one broken piece of heat-generating yarn and molded product with a maximum length of 300 m to 800 m.
  • a forming degree of 10 means a maximum length of 300 ⁇ ! There are 0 pieces of broken pieces of exothermic yarn and molded product of ⁇ 800 m.
  • the degree of molding representing the moldability of the moldable excess water exothermic composition of the present invention is preferably 5 or more, more preferably 7 or more, still more preferably 9 or more, and even more preferably 10. .
  • a forming degree of 5 or higher is set to a level or higher.
  • the degree of molding is 5 or more, a seal that can withstand practical use is provided at the periphery of the exothermic composition molded body sandwiched between the base material and the covering material after molding.
  • a exothermic composition molded body can be prepared by a mold molding method such as die-through molding or squeeze molding.
  • the exothermic composition molded body is covered with at least the coating material, and the shape is maintained until the seal part is formed between the base material and the coating material. Sealing is possible at the peripheral part, and since the loose sesame is not scattered in the sealing part, which is a broken piece of the exothermic composition, it can be sealed without being broken. The presence of sesame will cause a seal failure.
  • the perforation at the section of the heating element is not used to improve the bendability of the section. This includes things that have been cut intermittently and those that have been cut intermittently to the extent that they can be cut off by hand. This perforation may be provided in all the division parts, or may be provided partially.
  • the bending resistance indicates rigidity (cone, stiffness) or flexibility, and conforms to the JIS L 1096A method (45 ° cantilever method) except that the heating element itself is used as a sample. Is. That is, one side of the heating element is placed on the scale base line on a smooth horizontal surface with a 45 ° (degree) slope at one end.
  • the heating element is slid gently in the direction of the slope by an appropriate method, and when the center point of one end of the heating element contacts the slope, the position of the other end is read on the scale.
  • the bending resistance is indicated by the length (mm) that the heating element has moved.
  • Each of the five heating elements is measured and the average value is obtained.
  • the heating element containing the heating composition of the heating element must have a moving distance of 5 mm or more and a distance of 20 mm or more in the direction perpendicular to the moving direction.
  • the length of the heating element placed on the horizontal platform is such that the exothermic composition exists! / The area where the heat generating composition exists! / The area where the heat generating composition exists! / It exists and crosses the area linearly.
  • the separator covering the pressure-sensitive adhesive layer of the heating element with a pressure-sensitive adhesive layer is a plastic film having a bending resistance of 30 mm or less, or a plastic film having a thickness of 50 ⁇ m or less, preferably 25 ⁇ m or less.
  • a soft, soft film such as a plastic film that can be lightly manipulated and wrinkled.
  • For one heating element place one surface on a horizontal base and give the bending resistance in each direction with the average value in the vertical and horizontal directions, or in one direction and the direction perpendicular to it. 1 side is placed on a horizontal table and measured in the same manner to obtain each bending resistance. The smallest bending resistance of each value is defined as the minimum bending resistance. 3) As for the bending resistance of the packaging material such as the base material, make a short 100mm x 200mm long test piece and adopt the bending resistance in the longitudinal direction (200mm direction).
  • the change in the minimum bending resistance of the heating element or heating portion in the present invention means that the minimum bending resistance, which is the smallest value of the bending resistance of the heating element or heating portion, is that before the heating element generates heat. This is a change in value that occurs after the end of heat generation.
  • the change in the minimum bending resistance is calculated by the following equation.
  • the obtained heating element is left in air in a 20 ° C environment with no wind to generate heat.When the temperature of the heating element falls below 25 ° C, the end of use is regarded as the end of use. Measure the stiffness against the body in the direction that indicated the minimum stiffness of the heating element before heat generation, and use it as the minimum stiffness of the heating element after the end of heat generation.
  • the minimum bending resistance ratio of the heating element or heating section in the present invention is the minimum bending resistance of the heating element or heating section and the bending resistance ratio with respect to the total length in the direction, and is calculated by the following equation. .
  • the minimum orthogonal bending resistance of the heating element or the heating section means the bending resistance in the direction perpendicular to the direction indicating the minimum bending resistance of the heating element or the heating section and the bending resistance relative to the total length in that direction.
  • the ratio is calculated by the following equation.
  • the minimum bending resistance ratio in the present invention is the minimum bending resistance ratio in the plane orthogonal to the thickness direction of the heating element or heating section, and the minimum bending rigidity ratio in the direction orthogonal to the minimum bending resistance ratio. It is the ratio of the minimum bending resistance to the orthogonal bending resistance, and is calculated from the following equation.
  • Heating elements having segmented heat generating portions provided in the form of stripes in the present invention (pleated heating elements, pleated sheets, pleated heating elements, pleated packs, pleated pads, pleated warmers, thermal pleats, etc.)
  • a heating element with a parallel hexahedron-shaped segmented heating section with streaks spaced apart, and a pressure-sensitive adhesive layer, which maximizes the absolute value of the difference in bending resistance between the two directions perpendicular to each other, are used.
  • the heating element provided and the heating element provided with the adhesive layers spaced apart in stripes are very flexible in one direction and rigid in one direction. It is effective for alleviating symptoms such as back pain and muscle fatigue, especially for menstrual pain. Furthermore, it can be made approximately in the width direction in the width direction of the heating element to make it compact and convenient for storage. If a separator is used, it can be wound if a separator with low bending resistance is used.
  • the body has many secondary curved surfaces, and the shoulders, legs, abdomen, waist, arms, etc. are almost linear in one direction, and the other two directions are Almost curved force is also created. Therefore, the heating element of the present invention that can form a curved surface in one direction is almost linear and the other two directions can form a curved surface. Ideal for symptom relief and treatment.
  • a cut may be provided in at least a part of the region other than the divided heat generating portion of the heat generating element of the present invention.
  • the incision in the present invention means a notch penetrated and penetrated, or a connecting portion force structure.
  • the shape, type and size (length and width, etc.), the shape of each interval, type and size (length and width, etc.), size (length and width, etc.), and combinations of these are arbitrary combinations and arbitrary Can be combined repeatedly.
  • Examples include perforations (perforation cuts), staggered cuts, perforations with V-notches (perforated cuts with V-notches), differences with V-notches, and cuts.
  • the connecting portion between the cuts is shorter than the cut means that the connecting portion is shorter than the cutting portion in the cut made of the cut portion and the t-nail. Further, this need not be the case at the end of the cut.
  • the connecting part is shorter than the cut through.
  • connection portion between the notches is shorter than the notches.
  • the heating element according to 1. Is a heating element according to claim 1, wherein the notch is composed of a connecting portion and a notching portion, and the connecting portion is shorter than the notching portion ''.
  • the end portion of the notch made of is not limited to this.
  • the force related to the distance between the notch and the periphery of the heating element may be shorter than the joint at the end of the notch.
  • At least one end of the at least one cut may or may not be in contact with at least one side of the heating element.
  • the length of the cut through that is in contact may be shorter than that of the joint portion.
  • a V notch may be provided at a contact point between the extending direction of at least one section and at least one side of the heating element.
  • at least one cutting edge may or may not have at least one V notch and a contact.
  • the notches in the present invention are staggered notches and staggered with V notches.
  • the incision is used as a heating means expansion means, expansion / contraction means, separation means, and folding means.
  • staggered cuts are listed as an example of stretching and stretching means, and perforations and cuts that can be cut by hand are longer than joints as separating means!
  • a scissor cut is an example, and a perforation is an example of a folding means.
  • a notch is formed in the middle of the section which is a seal portion between the adjacent section heat generating parts up to one side force of the sectioning part and the other side corresponding thereto.
  • the heating element enables expansion and Z or expansion / contraction between the heat generating sections.
  • a heating element provided with a notch on at least one side corresponding to the section of the heating element of 1) to 3) above,
  • a heating element provided with a notch (V notch, U notch, I notch, etc.) on at least one of the sides corresponding to the section of the heating element,
  • a heating element in which at least a part of the notch contacts (abuts) at least one side of the heating element or at least a part of the notch,
  • At least a part of the notch contacts (abuts) at least one side of the heating element or at least a part of the notch!
  • the change in elongation rate in the present invention is preferably 0-30%, more preferably 0-20. %, More preferably 0 to 10%, and still more preferably 0%.
  • the change in the elongation rate in the present invention is an absolute value of a change in the value of the elongation rate of the heating element or the heat generating portion before and after the heating element is heated.
  • the change in the elongation rate is calculated by the following equation.
  • the obtained heating element is left in air in a 20 ° C environment with no wind to generate heat, and when the temperature of the heating element becomes equal to the environmental temperature, the end of use With respect to the heating element, the elongation rate of the heating element before heat generation is measured, and the elongation rate of the heating element after completion of heat generation is determined.
  • the heating element capable of extending and Z or expanding and contracting may be such that at least a part of the heating element extends and Z or expands and contracts when an external force is applied.
  • a notch is formed in the middle of the partitioning portion which is a seal portion between the adjacent segmenting heat generating portions to the other side corresponding to the one side force.
  • This is a heating element in which each heating section can be divided (separated) by this cutting.
  • a notch is formed in the middle of the partitioning portion which is a seal portion between the adjacent segmenting heat generating portions to the other side corresponding to the one side force. This is a heating element that makes it easy to fold each of the divided heating portions by this cut.
  • the V notch may be replaced with another notch such as a U notch or an I notch.
  • the alternate incision of the present invention consists of notches (or notches) and non-notched joints (or joints) and force, and there are few independent incisions consisting of two or more rows.
  • Two rows in one pair ! different, incision, three rows in one set, different, incision, four rows in one pair, incision or five rows in one set
  • Examples of preferred, different, and incisions include the following.
  • a plurality of cuts are arranged in a staggered pattern.
  • a plurality of cuts are arranged in different directions (eg, right angles) in one direction of cut (longitudinal direction, etc.).
  • the trajectory connecting the three nearest non-incision center points in the incision direction is non-linear (bending A plurality of incisions with three nearest non-incisions satisfying a straight line having an angle that is not 90 ° with respect to the incision direction.
  • Examples of the shape of the cut include a straight line, an ellipse, and a rectangle.
  • a region with a cut is called a cut portion.
  • a linear groove refers to a compressed portion or a thin portion that does not penetrate.
  • the leading edge of the at least one staggered cut may have at least one side of the heating element and a contact.
  • the length, the longest diameter or the longest side of the notch is not limited, but is preferably 1 to 100 mm, more preferably 1 to 50 mm, still more preferably 1.5 to 50 mm, and still more preferably Is 2 to 30 mm, more preferably 5 to 20 mm.
  • the width or shortest diameter or shortest side is not limited, but is preferably more than 0 and 50 mm. More preferably ⁇ is 0.1 to 50 mm, more preferably ⁇ or 0.01 to 30 mm, more preferably ⁇ to 0.01 to 20 mm, and even more preferably ⁇ or 0.1 to 30 mm. 20 mm, more preferably 0.1 to 10 mm, and still more preferably 0.1 to 5 mm. It should be noted that the minimum value of the width of the linear notch is not limited. The maximum value is 50 mm or less, more preferably as described above.
  • the interval between adjacent cuts (cut feed width, W1) in the extension direction of the cut is not limited, but is preferably 0.01 to 20 mm, more preferably 0.01 to: LOmm, even more preferable. Is 0.1 to: LOmm, more preferably 0.1 to 8 mm, and still more preferably 0.1 to 7 mm. More preferably, it is 0.1-5 mm.
  • the interval between adjacent cuts (cut width, W2) in the direction orthogonal to the extension direction of the cut is not limited, but is preferably 0.1 to 20 mm, more preferably 0.1 to 15 mm, and still more preferably. It is 0.1 to 10 mm, more preferably 0.1 to 5 mm, and still more preferably 0.5 to 5 mm.
  • the notch provided in the heating element having the separator may be a notch that penetrates the separator, or may be a notch that does not penetrate the separator.
  • the shape of the cut is not limited.
  • FIG. 26, FIG. 27, and FIG. 28 show examples of planar shapes.
  • a non-stretchable (extensible) heating element can be made into a stretchable (extensible) heating element.
  • the bending resistance can be further reduced.
  • the user decides the shape according to which part of the body is warmed by the heating element, and can be used by dividing the perforated perforation, which can be used in a shape and size suitable for the place of use. It is extremely efficient and convenient. For example, if you want to warm the neck, you can achieve the goal without any bulkiness by dividing it into small and narrow divided heat generating parts.
  • the present invention is smaller in size than the conventional miniature heat generating unit, and compared to the case where the heating element is manufactured or packaged separately, a plurality of small divided heating elements are provided in one large heating element. Is included together! /, Therefore, the manufacturing method is not cut by the conventional method, and the cost is not increased simply by cutting the cut portion. In addition, since packaging can be performed with a large heating element, the packaging cost can be reduced.
  • a heating element with a V-notch and a perforated perforation makes it easier and more reliable for tearing when the hand is cut, and easily and securely separates the segmented heating section. It is possible to improve the product value.
  • the heat generating part (heat generating element) provided with a V-notched perforated perforation provided on the elastic support is easy and reliable to stretch (extensible) when the support is extended. ) It can be used as a heating element, is excellent in design, and increases product value.
  • the notched notched heating element is useful, and the V notch used for alternating notched heating elements and hand-cut perforated heating elements can be replaced with other notches such as U notches and I notches. Moyo.
  • the perforated perforation is a through-cut, and if the hand can be cut, there is no limitation on the distance between the adjacent cut and the adjacent cut.
  • the ability to perform combinations and arbitrary repeated combinations The following are examples.
  • the length of the cut through is preferably 10 ⁇ m to 200 mm, more preferably 10 / ⁇ ⁇ to 50 ⁇ , still more preferably 10 / ⁇ ⁇ to 30 ⁇ , more preferably 10 ⁇ m to 20 mm, more preferably 100 ⁇ m to 20 mm, further preferably 10 ⁇ to 10 ⁇ , and even more preferably 0.5 mn! ⁇ 10 mm, more preferably lm m ⁇ lOmm "&).
  • the length of the interval between the through notch and the adjacent notch is not limited, but is preferably 1 ⁇ m to 10 mm, more preferably 1 ⁇ m to 7 mm, and even more preferably 1 ⁇ m. ⁇ 5mm, more preferably 0. lmn! ⁇ 5mm, more preferably 0. lmn! ⁇ 2mm to.
  • the ratio (A / B) between the length of the cuts (A) and the shortest length (B) between the adjacent cuts is preferably 1 or more, more preferably 1 to 50, still more preferably Is from 5 to 40, more preferably from 10 to 30.
  • the tip of at least one notch of the perforation may have a contact point with at least one side of the heating element.
  • Perforated perforations that can be cut by hand may be provided in the area other than the section heating section with any given interval in the vertical, horizontal, vertical and horizontal directions.
  • the heating element of the present invention is also a stretchable (elongating) heating element in which an arbitrary number of staggered cuts are provided in an arbitrary area other than the section heating part.
  • the shapes of the plurality of cuts penetrating in the thickness direction arranged in a different manner are deformed, so that they can be extended or contracted. It is preferable that the notches of the above and the other are provided in a direction substantially perpendicular to the direction expanded and contracted.
  • the number of cuts, the number of rows of cuts, and the like can be appropriately selected and used.
  • Fig. 26 shows a plan view of an example of the difference in notches.
  • the length, longest diameter or longest side of the notch is not limited, but is preferably 1 to 100 mm, more preferably 1 to 50 mm, and even more preferably 1.5 to 50 mm. More preferably, it is 2-30 mm, More preferably, it is 5-20 mm.
  • the width, the shortest diameter, or the shortest side is not limited, but is preferably more than 0 and 50 mm, more preferably ⁇ or 0.01 to 50 mm, and even more preferably ⁇ or 0.1 to 50 mm, and more preferably. Is 0.1 to 30 mm, more preferably 0.1 to 20 mm, still more preferably 0.1 to 1 Omm, and still more preferably 0.1 to 5 mm.
  • the interval between adjacent cuts in the extension direction of the cut is not limited, but is preferably 0.01 to 20 mm, more preferably 0.01 to 10 mm, and even more preferably. It is 0.1-10 mm, More preferably, it is 0.1-8 mm, More preferably, it is 0.1-7 mm. More preferably, it is 0.1-5 mm.
  • the interval between adjacent cuts (cut width, W2) in the direction orthogonal to the extension direction of the cut is not limited, but is preferably 0.1 to 20 mm, more preferably 0.1 to 15 mm, and still more preferably. It is 0.1 to 10 mm, more preferably 0.1 to 5 mm, and still more preferably 0.5 to 5 mm.
  • An example of the means for disposing the cut is not particularly limited, and examples thereof include use of an extended cutter, a rotary die cutter, a big puncher, and a laser.
  • an epoxy band cutter it is possible to easily cut into thick adhesive tapes and adhesive tapes with double separators.
  • a rotary die cutter continuous work is possible.
  • staggered arrangement means that the notches can be deformed into a mesh shape, etc. so that they can be stretched (stretched) even with packaging materials such as non-stretchable materials and non-stretchable materials.
  • packaging materials such as non-stretchable materials and non-stretchable materials.
  • staggered manner i.e., they are staggered somewhere, and, unlike a net that has been laced with strings, etc., the joints are integrated and expanded by a certain notch length.
  • a mesh can be formed while opening.
  • the heating element with staggered cuts which is the heating element of the present invention, preferably expands and contracts as long as a part of the heating element expands.
  • the elongation rate of the heating element is not limited as long as the elongation rate exceeds 1, but it is preferably 1.005 to 10 depending on the application, and more preferably 1.01 to 10, more preferably ⁇ or 1.01 to 5, further preferably ⁇ or 1.01 to 5, more preferably 1.01 to 3, more preferably 1.01 to 5. 2, more preferably ⁇ or 1.02 to 2, more preferably ⁇ or 1.03 to 2, more preferably ⁇ or 1.04 to 2, more preferably 1.05. ⁇ 2.
  • the extensibility of the present invention means that, when an external force is applied, at least a part is longer than the length before the external force is applied in the direction in which the external force is applied.
  • the length does not matter. Extensibility includes elasticity.
  • the alternate cuts usually have a function of imparting extensibility and / or stretchability.
  • the stretchability of the present invention means that when an external force is applied, the stretch is extended, and when the external force is removed, it becomes shorter than the length at the time of extension. It is.
  • the degree of shortening is displayed with a shortening rate, there is no limit if the shortening rate exceeds 1, but depending on the application, it is preferably 1.005 to 10 Yes, more preferably ⁇ 1.01 to 10, more preferably ⁇ or 1.01 to 5, more preferably ⁇ 1.01 to 5, more preferably 1. 01 to 3. More preferably, it is 1.01-2, more preferably ⁇ or 1. 02-2, more preferably ⁇ or 1. 03-2, more preferably ⁇ or 1. It is 04-2, More preferably, it is 1.05-2.
  • tensile strength of the stretchable or stretchable heating element of the present invention there is no limitation on the tensile strength of the stretchable or stretchable heating element of the present invention, but a preferable example is 3N / 50 mm or more.
  • the stretchable sheet-like material is a film, foam, nonwoven fabric, woven fabric, or a laminate thereof, or a laminate carrying a scrim, which has been given stretchability by an elastomer, and the stretchability.
  • Materials can be used.
  • the heating element of the present invention is 1) a heating element package sealed in an outer bag which is a non-breathable storage bag, or 2) two or more folded and non- Folded heating element package enclosed in an outer bag that is a breathable storage bag or 3) Folded heating element package enclosed in a non-breathable bag (outer bag), folded in two or more with the ventilation surface inside May be stored and transported.
  • the heating element When the heating element is enclosed in an outer bag that is a non-breathable storage bag, at least one part of the exposed part of the heating element is at least one part of the outer bag and a temporary adhesive layer such as a weak adhesive (outer temporary attachment). Layered) and temporarily (outside).
  • a temporary adhesive layer such as a weak adhesive (outer temporary attachment). Layered) and temporarily (outside).
  • At least one part of the exposed part of the heating element is at least one part of the outer bag and a temporary adhesive layer such as a weak adhesive. (Outer temporary wear layer) is temporarily worn (outer temporary wear)!
  • the folded heating element package which is the folded heating element of the present invention is a breathable surface of the heating element.
  • the heating element may be inside or outside, but a heating element that is folded with the air-permeable surface of the heating element inside is preferable.
  • the heating element is folded into two or more with the air-permeable surface inside, and sealed in an air-tight outer bag, thereby saving the air-tight packaging material and reducing the heating element during storage. Prevents deterioration, can be stored stably for a long time, the large-sized heating element is compact, convenient to carry, stable storage in a stable airtight outer bag, easy to use, Manufacturing costs are reduced and transportation is advantageous.
  • the heating element can be prevented from being deteriorated during storage with a small amount of water evaporated in the heating composition.
  • Forming in the present invention means that at least a part of the folded portion comes into contact with the region of the non-folded portion.
  • the width of the section corresponding to the folded part of the heating element is formed to be larger than 0.5 times the sum of the thicknesses of the section heating sections on both sides. That is, if the width of the section to be folded is C, and the height of the section heating section on both sides is H and L, respectively, the ratio between C and (H + L), that is, the folding ratio CZ (H + L) is usually at least 0.5, preferably 0.5 to 10, more preferably ⁇ to 0.55 to 10, more preferably ⁇ to 0.6 to 10, [Preferably ⁇ or 0.7 to 0.7, more preferably ⁇ or 1. 0 to 10, more preferably ⁇ or 1. 2 to 10, more preferably 1.2 to 10. 5, more preferably 1. 2 to 3.
  • the short length is C if the heating section of the heating element is different on one side and the other side. Since the heating element of the present invention is a double-sided uneven heating element in which the section is a recess (flat shape) and the section heating section is a protrusion, the folding ratio (CZ (H + L)) is 0.5 or more 1 It is possible to fold at the dividing section even if it is less than.
  • the narrow (short) width is taken as the width C of the section.
  • the packaging material used for the outer bag which is a non-breathable storage bag, has one or more notches (I notch, U notch, V notch, etc.) formed on the edge of the seal part of the outer bag, It is desirable that the user can easily tear and open the outer bag. Further, the notch forming means for forming the notch may be disposed, for example, on the downstream side of the sealing process by the sealing device.
  • the outer bag which is a non-breathable storage bag, is formed of a non-breathable sheet and covers the periphery of the heating element in an airtight manner by heat sealing or the like, so that the heat-generating composition is formed until the heating element is used.
  • the supply of oxygen to the feature is cut off! /
  • the outer bag you can use a so-called easy peel film that, when sealed, will be in a soft-adhesive state that can be easily peeled off.
  • a known material such as a non-breathable synthetic resin film coated with an easy peel styrene resin or the like can be appropriately used.
  • the outer bag is formed in a shape that is slightly larger than that according to the folded shape of the heating element (here, substantially rectangular).
  • the folded heating element package of the present invention is a heating element stored in a non-breathable bag in a folded or rolled state, and is at least one of the exposed portions of the heating element body (heating element).
  • the part may be temporarily attached to the inner surface of the outer bag, which is a non-breathable storage bag (hereinafter referred to as outer temporary attachment), or temporarily attached to at least a part of the inner surface of the outer bag, which is a non-breathable storage bag. (Hereinafter referred to as outer temporary wear).
  • Outer temporary attachment means that the heating element and the non-breathable storage bag are at least partially in contact with each other via the easily peelable weak adhesive layer. Thereby, the movement of the outer bag of the heating element on the packaging material can be prevented at least until the heating element is folded. There are no restrictions on the number, area, etc. of external garments. In the case of a heating element having a separator, the separator is also handled as a heating element.
  • the outer temporary attachment layer may be provided on the entire surface where there are no restrictions on the installation area or shape, may be provided only in the area necessary for fixing, or may be provided partially or intermittently. Examples include a net shape (spider web shape), a stripe shape, a dot shape, a fiber shape, a strip shape, a rod shape, and various shapes.
  • the pressure-sensitive adhesive layer of the heating element of the present invention is preferably covered with a peelable member until use so as not to directly contact the inner surface of the outer bag.
  • the peelable member should be a thin material having an exfoliating property that allows at least one attachment / detachment to / from the pressure-sensitive adhesive layer.
  • a substrate that has been treated with a release agent is preferred. .
  • Films such as PET (polyesters), sheets, paper, non-woven fabrics, and composite materials thereof are used.
  • silicone-based, fluorine-based, isocyanate-based and the like are preferable. These release agents can be applied to the substrate by a known method.
  • the outer bag may be laminated so long as it is non-breathable.
  • the packaging material of the airtight outer bag that houses the heating element should be substantially impermeable to air (oxygen)!
  • the non-breathable material or a conventionally known packaging material can be used.
  • the hermetic outer bag is formed by sealing around the packaging material so as not to substantially transmit air (oxygen).
  • air oxygen
  • Known sealing methods can be used. Usually, heat sealing is performed.
  • the manufactured heating element is interposed between two non-breathable films or sheets, and the two films or sheets are attached to the heating element at the same time as or after this intervention.
  • An example is a heating element package in which the two films or sheets are sealed in a peripheral portion exceeding the size of the heating element at the same time as or after the punching.
  • the adhesive constituting the re-peelable weak adhesive layer used for external temporary attachment (hereinafter, this adhesive is referred to as "external temporary adhesive") ends the folding operation with weak adhesive strength. Until the heating element If the packaging material can be put on hold, there is no limitation.
  • An example of a removable adhesive that can be used is a weak adhesive.
  • hot-melt adhesives there are hot-melt adhesives, emulsion adhesives, solvent-based adhesives, etc.
  • acrylics that have a high glass transition temperature are preferred, and the ratio of acrylic acid components is increased.
  • rubbers those containing a high melting point tack fire are preferred.
  • a hot melt adhesive particularly a hot melt adhesive (polypropylene adhesive, polyethylene adhesive, ethylene-propylene copolymer adhesive, etc.) is preferable.
  • an elastomer such as a thermoplastic elastomer
  • thermoplastic resin is used as a base polymer.
  • the base polymer may be used alone or in combination.
  • the thermoplastic elastomer of the base polymer in the hot-melt adhesive include styrene / isoprene / styrene block copolymer (SIS), styrene / butadiene / styrene.
  • Block copolymer SBS
  • Styrene-ethylene-ethylene-styrene-styrene block copolymer SEBS
  • Styrene-ethylene-propylene-styrene block copolymer SEPS
  • Styrene-ethylene-ethylene-propylene block copolymer Styrenic thermoplastic elastomers such as SEP) (styrenic block copolymers; for example, styrene-containing block copolymers containing 5% by weight or more of styrene); polyurethane-based thermoplastic elastomers; polyester-based thermoplastic elastomers; polypropylene and EPT ( Ternary ethylene-propylene rubber) And blended thermoplastic elastomers such as polymer blends.
  • the thermoplastic resin of the base polymer in the hot-melt adhesive is, for example, a polyolefin resin, a vinyl acetate resin, a polyester resin, a styrene resin, an acrylic resin, Examples thereof include polyamide-based rosin.
  • the polyolefin resin includes, for example, an ethylene copolymer (for example, ethylene vinyl acetate copolymer (EVA)).
  • Ethylene-acrylic acid copolymer EAA
  • EAA Ethylene-acrylic acid copolymer
  • Ethylene-methacrylic acid copolymer EAA
  • Ethylene-methacrylic acid copolymer Ethylene-acrylic acid copolymer
  • Ethylene (meth) acrylic acid ester copolymers such as methyl copolymers, ethylene methacrylate methacrylate copolymers; ethylene glycol alcohol copolymers, etc.
  • polyethylene low density polyethylene, linear low density polyethylene, meta Polyolefins such as polyethylene, medium density polyethylene, and high density polyethylene
  • polypropylene a- olefin copolymer (ethylene-propylene copolymer, ethylene-butene monocopolymer, propylene-butene copolymer, etc.); polypropylene Examples thereof include modified rosin.
  • acetic acid-based resin examples include poly (vinyl acetate), acetic acid ((meth) acrylic acid) ester copolymer, vinyl acetate vinyl ester copolymer, vinyl acetate maleic acid ester copolymer, and the like. It is done.
  • thermoplastic elastomer particularly, a polyolefin-based thermoplastic elastomer or a styrene-based thermoplastic elastomer
  • adhesives such as emulsion adhesives and solvent-based adhesives, acrylic adhesives, rubber adhesives, polyester adhesives, urethane adhesives, polyamide adhesives, epoxy adhesives, etc.
  • Adhesives such as bulle alkyl ether adhesives, silicone adhesives, fluorine adhesives, etc., and adhesives of each form (for example, emulsion form, solution form, etc.).
  • the adhesive may be a cross-linking agent (for example, a polyisocyanate-based cross-linking agent, an alkyl ether base, or the like depending on the type of the adhesive).
  • a cross-linking agent for example, a polyisocyanate-based cross-linking agent, an alkyl ether base, or the like depending on the type of the adhesive.
  • Melamine compound cross-linking agent, etc. tackifiers (for example, rosin derivative resin, polyterpene resin, petroleum resin, phenol resin, etc.), plasticizers, fillers, anti-aging agents, etc. May be included.
  • the heating element and the packaging material should be adhered until the folding operation is completed.
  • 180 degree peel strength is from 0.001 to 0.9 kgZ25 mm, more preferably from 0.001 to 0.5 kg / 25 mm, more preferably from 0.001 to 0.1 kg / 25 mm, More preferably, it is 0.005 to 0. lkgZ25mm, more preferably 0.1 to: L00gZ25mm, more preferably 0.1 to 50gZ25mm, more preferably 0.1 to 30gZ25mm, More preferably, it is 0.1-25gZ25mm.
  • the coating thickness is not particularly limited, but is preferably 3 mm or less, more preferably ⁇ to 0.1 ⁇ m to 3 mm, and further preferably ⁇ to 0.1 ⁇ m to 2 mm. More preferably, ⁇ or 0.0 .: Lmm, more preferably ⁇ or 0.01 to 500 m, more preferably ⁇ or 0.01 to: LOO / zm, more preferably ⁇ or 0.00. 40 / ⁇ ⁇ , more preferably ⁇ 0.1 to 40 ⁇ m, more preferably ⁇ 0.1 to 30 ⁇ m, more preferably ⁇ 1 to 30 ⁇ m, more preferably It is 5-30 micrometers, More preferably, it is 5-30 micrometers.
  • a known forming method can be employed. Examples thereof include a hot melt coating method and a solution type coating method. Moreover, it can be in any form such as a whole surface, a partial shape, a solid shape, a net shape, a rod shape, a stripe shape, and a polka dot shape.
  • the separator when a separator is provided on the heating element, it is preferable to provide the separator so that it does not peel off the heating element force.
  • the heating element of the present invention is a heating element enclosed in an outer bag which is an airtight storage bag
  • a notch for opening is provided in the seal portion of the outer bag which is an airtight storage bag U, .
  • the notch is provided in a seal portion of the outer bag that is an airtight storage bag without contacting at least the side of the outer bag that is the airtight storage bag.
  • the notch is provided in a region in the seal portion of the outer bag which is an airtight storage bag and at least touches the side of the outer bag which is an airtight storage bag.
  • the notches of the present invention are not limited, but examples include I notches, V notches, U notches and the like.
  • the method of using the heating element of the present invention is such that the section heating section having the heating composition that generates heat upon contact with oxygen in the air is provided with an interval between the section sections where the section heating section is a seal section.
  • a thermal patch that has an adhesive layer on the non-breathable part of the heating element and uses the excellent adhesion to the human body due to the elasticity of the heating element to provide an excellent thermal effect and therapeutic effect on the trunk.
  • the breathable adhesive surface of the heating element has air permeability and an adhesive part, and the non-adhesive surface does not have an adhesive part, and the breathable adhesive surface is pasted on a desired region of the human body, Using the unevenness of the heating element of the present invention, a thermal patch that ensures the breathability of the heating element and provides the excellent thermal effect and thermal treatment effect due to the supply of hot steam to the human body.
  • the air-permeable adhesive surface of the heating element has air permeability and an adhesive part, and the non-adhesive surface does not have an adhesive part.
  • An example is a method of using it as a thermal patch that allows an excellent non-adhesive surface to be brought into direct contact with the skin to obtain an excellent thermal effect or treatment effect on the trunk.
  • the cutting blade of the present invention is not limited as long as it is a blade that forms a joint and a cut, but 1) a cutting blade that is a blade in which notches are provided at predetermined intervals; ) Notched blades, which are blades provided with a plurality of cutting blades at intervals, 3) One-way single blades with blades in the direction, 4) Multiple cutting blades substantially in parallel Blades are provided, and adjacent cutting blades are provided differently, and a parallel double blade or the like is an example.
  • substantially parallel means that the line connecting the centers of the cutting blades may be substantially parallel between adjacent lines.
  • a heating element manufacturing method and manufacturing apparatus will be described. First, a notch installation apparatus for cutting and installing in a section of a heating element will be described.
  • the notch setting device of the present invention is a notch setting device that can easily form a good notch with few defects at high speed and can be operated continuously for a long period of time.
  • the convex body storage section that allows the convex body to be stowed out, and by passing the concave and convex sheet-like body between both rolls, at least one of the concave body is provided.
  • This is an incision installation device having a function of providing incisions in which cut portions through and through portions are alternately provided. Further, the blade of the incision roll is provided along the circumferential direction (in the MD direction). Placement,
  • the blade of the cutting roll is a block-shaped blade provided in two or more directions in a plurality of directions, and a cut is provided in which cutting portions penetrating alternately with connecting portions in two or more directions are provided.
  • a cutting installation device that has a function of alternately providing cuts through which the blades of the cutting roll and the connecting portion pass,
  • the installation device is a notch that is at least one selected from
  • the notch and spacing force is a notch installation device that is a notch roll in which at least one selected space is fixed so that adjacent blades are in a zigzag position, and the receiving roll force notch roll
  • a cutting device having a receiving blade corresponding to the cutting blade of the cutting device, and a cutting device having a receiving device of the receiving roll force cutting roll blade, and the receiving device of the blade of the cutting roll is processed
  • It is a cutting installation device that is at least one of the selected body injection loca such as a concave, convex, sponge, rubber, plastic, brush, and compressed air.
  • the formation angle of the blade of the switch interrupt rolls at an angle of 0 to 45 ° than the blade in the roller radius normal, an incision installation apparatus tilted MD (traveling) direction.
  • a plurality of convex bodies are provided at intervals with the concave bodies as intervals.
  • a segmented heat generating portion heating element is exemplified.
  • the concavo-convex sheet-like body is a segmented heating element heating element
  • the continuous concavo-convex sheet-like body is a continuous section-segmenting heating element.
  • the continuous concavo-convex sheet-like body body and the continuous section-segment heating element are referred to as a heating element.
  • the incision of the present invention is mainly an incision in which connecting portions and penetrating incisions are alternately provided, and examples thereof include staggered incisions and perforated incisions.
  • Examples of the optical detection device of the notch setting device include an optical sensor.
  • Examples of the displacement means of the roll of the notch setting device include an elevating device and an expander.
  • Guide means for guiding the roll to a predetermined position where the blade and recess of the notch setting device are fitted include shaft holes, positioning fixing pins (stoppers), position holes in the cylinder gap adjustment plate, guide cylinders, slide shafts, etc. A combination etc. are mentioned as an example.
  • Examples of the receiving device for the cutting roll blade include a convex portion, a concave portion, and a receiving blade.
  • the roll may be a hollow cylindrical rotating body without limitation as long as it is a rotating body, or a non-hollow solid rotating body.
  • types such as an upper and lower roll type, a left and right roll type, and an inclined roll type are conceivable depending on the facing angle.
  • This type can also be changed to the left / right roll type, the upper / lower roll type, the vertical / left / right roll functions can be changed, and other changes are possible.
  • the surface of the roll does not include the inside of the storage section of the section heating section, the inside of the processing recess, or the blade installation area.
  • the cutting roll and Z or the receiving roll are at least an uneven sheet. It is preferable to provide rounded corners at the portions that come into contact with the body, that is, the corners have a substantially arc shape.
  • a cutting roll has a storage section, a pressing section, and a cutting blade for a divided heat generating section, and a warning is placed on the corner section of the storing section, the corner section of the pressing section, and the end corner section of the roll body.
  • each corner is substantially arc-shaped.
  • the receiving port 1 has a convex heat generating part storage part, a processing concave part and a pressing part, a classification heat generating part storage part corner, a processing concave part corner and a pressing part corner part, and a roll body.
  • R are provided at the end corners, that is, each corner is substantially arcuate.
  • the corner portion of the storing portion of the segmented heat generating portion, the corner portion of the force-generating concave portion, and the corner of the pressing portion which are the corner portions of the cutting roll and Z or receiving roll of the present invention that are in contact with the uneven sheet-like body.
  • the contact surface of each roll is provided by providing a radius r adjacent to the end of the end of the roll body adjacent to the concavo-convex sheet-like body (contacting). It is possible to reliably eliminate the cutting of the packaging material at the end of the corner of the concavo-convex sheet.
  • the radius of curvature is preferably 0.1 to: LOmm, more preferably ⁇ to 0.1 to 5. Omm, and further preferably ⁇ to 0.1 to 3. Omm. Yes, more preferably ⁇ to 0.3-3. Omm, and still more preferably 0.5-2. Omm.
  • the cutting roll and Z or the receiving roll may have a plain flat surface at least in contact with the concavo-convex sheet, but at least selected from the pressing portion and the surface of the roll. Even if you have an uneven pattern on one part of one kind.
  • the pitch which is the distance between the concaves and concaves or the distance between the convexes and the convexes in the concavo-convex pattern, may be any length as long as a notch can be formed, but usually 0.3 to 2 Omm.
  • the thickness is preferably 0.4 to 1.5 mm, more preferably 0.5 to 1. Omm, and still more preferably 0.6 to 0.8 mm.
  • the height of the concavo-convex pattern is not limited as long as it does not hinder cutting, but is usually 0.1 mm to 0.3 mm.
  • a round at the corners of the concave and convex portions of the concave-convex pattern Preferably, it is 0.1 to 1. Omm, more preferably 0.1 to 0.5 mm. More preferably, it is 0.1 to 0.2 mm.
  • End force of the pressing part of the cutting roll and the pressing part of the receiving part of the receiving roll At least one selected type is formed in a substantially arc shape (R is provided at the end part). preferable.
  • At least one selected from the cross-sectional shape of the surface of the cutting roll that contacts the concave-convex sheet and the cross-sectional shape of the surface of the receiving roll that contacts the concave-convex sheet is formed in a concave-convex shape
  • a slitting installation device characterized in that a pattern is provided is preferable.
  • At least one selected from the cross-sectional shape of the surface of the cutting roll in contact with the concavo-convex sheet and the cross-sectional shape of the surface of the receiving roll in contact with the concavo-convex sheet is formed in the concavo-convex shape.
  • the cross-sectional shape of the surface of the cutting roll in contact with the concavo-convex sheet is different from the cross-sectional shape of the surface of the receiving roll in contact with the concavo-convex sheet.
  • a cutting installation device characterized by this is preferred.
  • a heating element incision installation method in which at least both sides are adjacent to a section heating section containing a heating composition and which has one or more section sections that do not store a heating composition;
  • a heating element incision installation method is preferable, in which an incision is provided by the roll in a section that does not contain the exothermic composition.
  • a scoring method for a heating element is preferred, characterized in that a roll having a pattern formed by forming one kind of irregularities is used to cut in the section not containing the heat generating composition by the roll. .
  • heating element cutting installation method of 6. at least selected from the cross-sectional shape of the surface of the cutting roll that comes into contact with the concavo-convex sheet and the cross-sectional shape of the surface of the receiving roll that comes into contact with the concavo-convex sheet
  • a heating element incision installation method is preferred, in which a roll is formed into a flat shape by forming one kind and a cut is provided by the roll in a section not containing the exothermic composition. .
  • the roll is formed in a concavo-convex shape and formed into a pattern and a planar shape, and a pattern in which no pattern is mixed at an arbitrary ratio, and the exothermic composition is not accommodated.
  • the characteristic heat-sink cut installation method is preferred.
  • the cross-sectional shape of the surface of the cutting roll in contact with the concavo-convex sheet is different from the cross-sectional shape of the surface of the receiving roll in contact with the concavo-convex sheet.
  • a heating element incision installation method is preferable, in which an incision is provided by the roll in a section where the exothermic composition is not accommodated using the roll.
  • At least one type of peripheral surface of the peripheral surfaces of both rolls is One part force of at least one part of the heat generating part and the processing concave part. Do not contain the heat generating composition using a roll provided with a groove for discharging air to the opposite side!
  • a notch installation method is preferable, characterized in that an incision is installed in the section by the tool.
  • the heating element manufactured by the cutting installation device of any one of 1 to 5 is also included in the present invention.
  • the present invention also includes a heating element in which a cut is set by any of the above-described cut setting methods 6 to 11.
  • the cutting installation device of the present invention comprises:
  • a notch installation device is provided, wherein a cooling device for cooling at least the peripheral surface of the receiving roll is provided.
  • the blade of the cutting roll has a mechanism for obtaining vibrations of 50 cycles or more in parallel with the blade.
  • An example is a device in which a lifting device is provided on the receiving roll, but the lifting device (pressing mechanism) of the receiving roll is not limited and any device may be used. Also, raise and lower the cutting roll instead of the receiving roll.
  • the direction of movement of the receiving roll or the cutting roll is not limited to the vertical direction, and may be any direction.
  • the receiving roll is pressed against the cutting roll. If you apply force, the cutting roll may be pressed against the receiving roll.
  • the direction of movement of the receiving roll or the cutting roll is not limited to the vertical direction, and may be any direction.
  • the roll has convex and concave portions of the concavo-convex sheet and Z or concave pressing portions.
  • the uneven sheet-like body of the present invention is a sheet having an uneven surface.
  • corrugated sheet-like body which is not providing the notch is called an uneven
  • a structure in which a plurality of concavo-convex sheet-like main bodies are continuously connected in a band shape is referred to as a continuous concavo-convex sheet-like main body.
  • the convex part is a segmented heat generating part and the concave part is a segmented part.
  • the segment heating element according to the present invention corresponds to the concavo-convex sheet-like body, and is a segment heating element segment heating element before being cut and installed.
  • the continuous segment heating element heating element corresponds to a continuous irregular sheet-like body, and the segment heating element and the heating composition having the heating composition are combined. It consists of a section that is not a seal, and the section is the distance between the section heat generating section and the adjacent section heat generating section, and the section heating section heating element consisting of a plurality of section heat generating sections is continuous in a strip shape. It is a divided heat generating part heating element that is continuously connected.
  • the method of providing a cut in the concave portion of the concavo-convex sheet-like body has a cutting tool having a cutting blade and a receiving roll corresponding thereto, and at least one of the rolls has a convex portion of the concavo-convex sheet-like body as the cutting blade. It is installed on the incision roll by operating a notch installation device having a convex part storage part that can be protruded by storing the convex part and inserting a concavo-convex sheet between the rotating rolls.
  • This is a method of providing a through notch in which notches and connecting portions are alternately provided in at least a part of the recess by the provided blade. Depending on the type of blade, various cuts can be provided in the region excluding the convex portion.
  • an example of the cutting installation device of the present invention is such that both rolls 24, 25 are engaged with each other at their end portions 32, 32 and rotate in opposite directions around the axis.
  • Fig. 30 (a) is a cross-sectional view of Z-Z, using a blade 26 with a notch 37 every 180 °.
  • the desired cutting 15 is formed in the continuous body 2.
  • FIG. 30 (b) shows an example of the blade 26 provided with a notch 37 every 120 degrees.
  • the notch setting device of another example of the present invention shown in the cross-sectional views of FIGS. 30 (c) and 30 (d) has no protrusion on the surface of the anvil roll of the notch setting device of FIG. 29. This is an example of using an ambiroll without a convex portion having a flat surface.
  • FIG. 30 (c) The cross-sectional view of Fig. 30 (c) uses a blade 26 with a notch 37 every 180 °.
  • a desired cutting is formed in the heating element.
  • FIG. 30 (d) shows an example of a blade provided with a notch 37 every 120 °.
  • FIG. 31 (a) is a partially enlarged view showing a processing state in which alternate cuts 15 are installed in the heating element in the example of FIG.
  • alternating cutting blades 26 projecting in the radial direction are provided.
  • the blades 26 are all the same height and the cutting edges are aligned on the same circumference.
  • a convex portion 28 is formed at a position where the cutting edges of the alternate cutting blades contact each other, and the position of the divided heat generating portions 6 and 6 is determined so as not to get on the convex portion.
  • a different cut 15 is provided in the heating element sorting section 7 so that it is in the state.
  • the blade 26 has a circular blade shape, and the blade tips of the plurality of blades 26 are provided concentrically and are provided on the cutting roll 24.
  • the blade tips of the plurality of blades 26 are provided concentrically, and a plurality of blades 26 that also serve as a combination force of the plurality of blades 26 are provided on the incision tool 24 at intervals.
  • Fig. 31 (b) is a partially enlarged view of the type in which the cutting blade comes into contact with the convex portion of the receiving roll
  • Fig. 31 (c) is a convex portion with a hole provided with a hole in the convex portion of the receiving roll
  • FIG. 5 is a partially enlarged view of a type in which the cutting blade does not contact the convex portion of the receiving roll.
  • FIG. 32 is a plan view in which five sets of staggered cuts 15 having three rows of force are provided in the installation pattern of staggered cuts 15 in the heating element in the example of FIG.
  • FIG. 33 (a) shows an example of Fig. 29, in which all the dividing portions 7 of one heating element 1 having five rows of dividing portions 7 are provided with alternate notches 15 comprising notches 19 and connecting portions 18.
  • FIG. 6 is a partial plan view showing the relationship between alternate notches 15 of the heating element 1 and the sectional heating part 6.
  • FIG. 33 (b) shows a deformed state of the portion of FIG. 33 (a) when stretched in the longitudinal direction, which is a direction orthogonal to the cutting direction of the heating element 1 provided with alternate cuts 15.
  • the meshes corresponding to the length of the cuts 19 are formed by the alternating cuts 15 using the joints 18 as knots. Deform to form.
  • the substantially alternate notches 15 shown in Fig. 33 (a) are restored.
  • the heating element 1 has elasticity in the longitudinal direction, which is the direction orthogonal to the cutting installation direction.
  • FIG. 6 is a cross-sectional view showing a cutting roll of a cutting installation device that provides different cuttings 15 in the TD direction with respect to the device that provides the cutting force.
  • the cutting blade extending in the TD direction is provided with a plurality of notches 27 having a desired length at desired intervals.
  • FIG. 34 (b) is a cross-sectional view taken along line E-E of the cutting roll 24, and different cutting blades 37 having three rows of force are provided.
  • the anvil roll is provided with convex portions projecting in the radial direction so as to face the blades on the surface of the anvil roll, and is provided at a predetermined interval. .
  • FIG. 34 (c) is a plan view showing a part of an example of three rows of staggered cuts 15 provided in the section 7 in the TD direction of the heating element in the cut setting device of the present invention. .
  • the cutting blade 37 is in contact with the convex portion on the receiving roll, which is a force anvil roll, only in the section 7 of the heating element, so that the section heating section 6 is located at the center of the roll. It is housed in the section heat generating section housing section 32 adjacent to the convex section, and only the section section 7 is supported by the convex section, so that the cut installation is performed. As a result, defects that are difficult to process were easily eliminated.
  • this example shows a heating element (continuous segment heating element heating element body) and a device for processing a cut and a joint on a section of a segment heating element heating element
  • the present invention It is not limited to these cutting processes.
  • the shape, position, size, number, number of sets, etc. of the blades and projections to be cut are determined according to the shape of the desired heating element, section heating section generator, section heating section and section.
  • FIG. 35 (a) is a perspective view of an example of a cutting roll used in the cutting installation device of the present invention, and is provided with five sets of a plurality of divided heat generating portion storage portions 32 and cutting blades 36.
  • the cut blades 36 are provided with a cutout 27, and the cutouts 27 of the adjacent cut blades 36 are combined so that they are not aligned with each other in the coaxial direction. This makes it possible to install a notch 15 that is different from each other.
  • FIG. 35 (b) is a perspective view of an example of the cutting roll 29 having the divided heat generating portion storage section 32 and each cutting blade 36 provided in the direction of the axis 52 of the roll.
  • the cutting blades 36 adjacent to each other in the direction of the axis 52 are arranged in a circumferential direction so that they are combined in a different manner. This makes it possible to set up notches 15 that are different from each other.
  • Fig. 35 (c) has a section heating section storage section 32, and the incision angle ( ⁇ ) of the incision blade 37 is cut and the roll radius normal force of the infeed roll 29 is tilted in the traveling direction at an angle of 0 to 45 °.
  • ⁇ incision angle
  • Fig. 35 (a) shows a cutting roll 29 for installing a plurality of alternating cuts 15 in the MD direction, which is the traveling direction of the heating element
  • Fig. 35 (b) shows the progression of the heating element.
  • This is a notch roll 29 for installing two sets of notches 15 in the TD direction perpendicular to the MD direction.
  • the cutting blades 35 in each set are fixed in a zigzag position. Further, when making a horizontal cut as in the present application, it may not be sufficient to allow the heating element to penetrate the blade with a tension of just vertical, in which case the roll of at least one of the rolls 29 and 30 is not suitable. This is particularly effective because a convex portion is provided at the end portion, and both ears, which are the end portions of the heating element, can be gripped and applied with a lateral tension.
  • FIG. 36 shows a front view of another example of the cutting installation device of the present invention.
  • a cutting roll 29 provided with cutting blades 35 in the circumferential direction and a receiving roll 30 corresponding to the cutting roll 29 are arranged with a receiving roll 30 having a processing recess 43 at a position facing the cutting blade 29.
  • the first guide roll and the second guide roll are arranged on both sides of the receiving roll 30, and the optical detection device 48 is arranged between the cut roll 29 and the first guide roll.
  • This incision setting device is an example of an apparatus for forming a notch in the vertical direction (MD direction) in a heating element (continuous concavo-convex sheet main body).
  • the cutting roll 29 is an assembly in which round blades 35 having a plurality of arcuate cutting edges are arranged in parallel at a predetermined pitch with a gap on the shaft 52.
  • the receiving roll 30 is a cutting roll 29. And, for example, rotate around the axis at the same peripheral speed.
  • a force recess 43 is provided corresponding to the section of the heating element.
  • the processing recess 43 is provided so as to correspond to the position where the cutting edge of the round blade 35 of the cutting roll 29 abuts the heating element, the heating element is pressed around the processing recess, and the notch 15 is provided in the section 7. .
  • the receiving roll 30 is pressed against the cutting roll 29 by an elevating device having a pressing mechanism.
  • the heating element is guided by the guide roll and travels between the cutting roll 29 and the receiving roll 30 along the outer peripheral surface of the receiving roll 30. Then, a cut is formed in the section 7 of the heating element at the contact portion between the arcuate cutting edge with the notch of the round blade 35 and the heating element. Further, from the optical detector 48 arranged between the cutting roll 29 and the first guide roll, the round blade 35 provided on the cutting roll 29 penetrates the heating element and is exposed above the heating element. It is possible to confirm that the incision installation process has been carried out reliably by using the above or by sensing the image of the incision 15.
  • Examples of the optical detection device 48 include an optical sensor and a CCD camera.
  • the length of the cutting blade 35 in the circumferential direction is set to the reference length of the convex portion or the cutting by the detecting device 48.
  • the distance between the blades as the reference length of the concave portion, it is possible to confirm the state of the cutting installation process into the heating element.
  • the cutting blade 35 is missing and cutting installation processing is not possible Since the distance between the cutting blades 35, that is, the length of the recess is longer than the reference length, it can be detected that the predetermined cutting is not performed. Next, when the cutting blade is in a normal state but the heating element has not been cut and installed, the cutting 18 is detected by detecting that the length of the cutting 18 is longer than the reference length. It's done normally! /, That can be confirmed.
  • the material and thickness of the packaging material (including the separator) constituting the heating element to be cut and installed are not particularly limited, and may be any material that can be continuously processed. Then, when the defective part of the cutting installation process is confirmed, the defective part can be removed by inputting the data of the defective part, and post-processing such as cutting and bag making can be performed.
  • the cuts to be processed are not limited to straight lines, but may be of various shapes, and it is also possible to process a plurality of two or more than one. This applies to all of this specification.
  • the optical detection device 48 may be a defective incision detection sensor, and when a defective incision occurs, the incision installation device is stopped by the output signal of the sensor so that the defective incision does not continue. wear.
  • FIG. 36 (b) shows a cross-sectional view of another example of the cutting installation device of the present invention.
  • the cutting roll 29 is arranged on the lower side, the receiving roll 30 is arranged on the upper side, and the pinch roll 51 is used.
  • FIG. 37 shows another example of the incision apparatus of the present invention, in which the segment heating section 6 of the heating element is stored in the segment heating section storage section 32, and the blade 35 of the cutting roll 29 is the section 7 of the heating element.
  • FIG. 3 is an enlarged cross-sectional view of a state where a notch is placed in contact with
  • the cutting roll 29 has a divided heat generating portion storage portion 32, and has pressing portions 34 on both sides of the outermost blade of the cutting blade 35 having three cutting edges.
  • the convex part 33 Z with a hole of the receiving roll 30 has a pressing part 34, and a section heating part storage part 32 is provided adjacent thereto.
  • the heat generating member comes into contact with the cutting roll 29 and the receiving roll 30 at the pressing portion 34 of the cutting roll 29 and the pressing portion 34 of the receiving roll 30!
  • Fig. 38 is a cross-sectional view of another example of the cutting installation device of the present invention.
  • This cutting installation device is an example of a device that forms a vertical (MD) cut in a heating element.
  • the cutting roll 29 is provided with six divided heat generating portion storage portions 32 on the peripheral surface, and five sets of cutting blades 35 sandwiching the divided heat generating portion storage portion 32.
  • pressing portions 34 which are adjacent to the blade 35 and are pressed on the outer surface of the outermost round blade and receive the heating element against the roll 30.
  • the cutting blade 36 is a round blade having a plurality of arc-shaped cutting blades 35 and notches provided at predetermined intervals at the tip, as shown in FIG.
  • the notches are arranged so that they are not aligned in a straight line with respect to the axial direction of the roll, and a set of three cutting blades, and three cutting blades 35 are arranged in parallel at a predetermined pitch.
  • each group of cutting blades 35 is changed to one cutting blade 35, it becomes a cutting roll for forming perforations.
  • the receiving roll 30 rotates around the axis at the same peripheral speed as the cutting roll 29.
  • the receiving roll 30 is provided with a processing recess 43 and a pressing portion 34 adjacent to the processing recess 43.
  • the holding part 34 forms the outer peripheral surface of the receiving roll 30.
  • the outer peripheral surface of the receiving roll 30 does not include the inner surface of the processing recess 43.
  • the machining recess 43 is provided so as to correspond to the position where the cutting edge of the round blade 35 of the cutting roll 29 abuts the section of the heating element.
  • Both ends of the cutting roll 29 and the receiving roll 30 are holding parts 34 for pressing the heating element against the rolls 29 and 30.
  • the receiving roll 30 is pressed against the cutting roll 29 by an elevating mechanism that is also a pressing mechanism.
  • the heating element 1 (continuous segment heating element body) is tensioned in the vertical direction (MD direction) due to the pulling force by a pinch roll or the like.
  • the heating element 1 is held on the upper periphery of the processing recess 43 by the frictional force caused by the contact between the pressing portion 34 of the receiving roll 30 and the heating element 1. .
  • both ends of the heating element 1 are pressed by the pressing portions 34, the movement of the heating element 1 in the lateral direction is restricted. With the heating element 1 held in this way, the arcuate cutting edge force of the blade 35 of the cutting roll abuts against the section 7 of the heating element 1 and pushes the section 7.
  • lateral tension (TD direction) is generated in the heating element 1. This The force acts so that the cutting edge of the blade 35 can easily penetrate the sorting portion 7. At this time, since the processing recess 43 is present, the cutting edge of the cutting roll 29 is received by the processing recess 43 and does not contact the receiving hole 30.
  • the heating element 1 when a longitudinal cut is formed in the heating element 1, the heating element 1 is tensioned in the MD direction, that is, in the longitudinal direction. Movement to is restricted. As a result, the heating element 1 is held in a state of being stretched over the pressing portion 34 adjacent to the processing recess 43 of the receiving roll 30.
  • the divided heat generating portion 6 which is a convex portion is stored in the divided heat generating portion storing portion 32, the contact of the cutting edge with the divided heat generating portion 6 is protected. Further, since the processing recess 43 is present, the cutting edge does not contact the receiving roll 30. Therefore, long-term continuous operation is possible in which the life of the receiving roll 30 is extremely long.
  • Fig. 39 (a) is a partial cross-sectional view of another example of the receiving roll 30 of the cutting installation device 28 of the present invention.
  • the processing recess 43 has a rectangular cross section.
  • the processing recess 43 has a rectangular cross-section, a trapezoidal cross-section, a semicircle, and the cross-sectional shape is not limited.
  • a processing recess 43 having a cross-sectional shape such as a cross-section can be used.
  • FIG. 38 (b) is a cross-sectional view of FF.
  • FIG. 38 (c) is a cross-sectional view of another embodiment of the cutting installation device 28 according to the present invention.
  • the surface circumferential force is a receiving socket manufactured by a member softer than the blade of the cutting roll such as rubber. Is used.
  • This receiving roll 30 has a divided heat generating portion storage portion 32, a force spring recess portion 42, and a holding portion 34, and a corner portion 47 of the divided heat generating portion storage portion 32, a corner portion 47 of the processing recessed portion 43, and a holding portion 34.
  • R are provided at the corner 47 of the roll and the corner 47 of both ends 46 and 46 of the roll body. That is, each corner 47 is substantially arc-shaped. It is.
  • the surfaces of the pressing part 34 and the rolls 29 and 30 may be plain and flat, but it is preferable that at least one part of the pressing part 24 is provided with an uneven pattern.
  • the surfaces of the rolls 29 and 30 do not include the inside of the compartment heat generating portion storage portion 32 and the inside of the force recess 43.
  • FIG. 39 (b) shows another example in which the notch 16 is provided in the section 7 by the notch roll 29 and the receiving roll 30 of the notch setting device 28 of the present invention, and has six section heat generating parts 6.
  • FIG. 6 is a partial cross-sectional view of a state in which longitudinal notches 16 are installed in five section portions 7 of a continuous body 8 in which the section heating element bodies 2 are connected. Each section heating section 6 is stored in the section heating section storage section 32, a part of the section section 7 is pressed by the holding section 34, and the notch 19 is nested in a predetermined section section 7 area by the blade 35 of the cutting roll 29. is set up. The end of the continuous main body 8 is pressed against both ends 46 and 46 of both rolls by the pressing part 47.
  • This cutting roll 29 has a section heating section storage section 32, both ends 46 and 46 of the roll body 46, a holding section 47 and a cutting blade 35, and a corner section 47 of the section heating section storage section 32 and both ends 46 of the roll body 46. 46 are provided at the corners 47 of the holding part 34. That is, each corner 47 is substantially arc-shaped.
  • the receiving roll 30 has a divided heat generating portion storage portion 32 and a processing concave portion 43 with a holding portion 34.
  • the corner portion 47 of each holding portion 34, the end portions 46 and 46 of the roll body 47, and the corner portion 47. has been established. That is, each corner is substantially arc-shaped.
  • the surface of the holding part 34 and the rolls 29 and 30 may be plain and flat, but the surface force of the holding part 34 and the rolls 29 and 30 is provided with an uneven pattern on at least one selected part. Also good.
  • the surfaces of the rolls 29 and 30 do not include the inside of the divided heat generating portion storage portion 32, the inside of the processing recess 43, and the blade installation area.
  • FIG. 39 (c) is a front view of the cutting roll 29 with a concavo-convex pattern.
  • FIG. 39 (d) is a front view of the receiving roll 30 with an uneven pattern.
  • FIG. 39 (e) is a front view of the incision roll 29 having a concavo-convex pattern on both ends 46, 46 of the roll.
  • FIG. 39 (f) is a front view of the receiving roll 30 having a concavo-convex pattern on both ends 46, 46 of the roll.
  • FIG. 39 (g) is a front view of the receiving roll 30 having a plain flat surface.
  • FIG. 41 (a) another example of the cutting installation device of the present invention includes a cutting roll 24 and a receiving roll 25, and the cutting roll 24 is provided in two or more directions in a plurality of directions.
  • This is a notch setting device for providing notches in which block-shaped cutting blades 27 are provided, receiving roll 25 is an ambi roll, and in which two or more directions are alternately provided with connecting portions and notches penetrating therethrough.
  • a heating element is obtained in which is provided in at least a part of the region other than the divided heating part of the heating element.
  • the pressing part is provided at both ends of the cutting roll, the receiving roll may be the same.
  • Fig. 41 (b) is an explanatory view showing a notch pattern corresponding to the very thick line and the thick line in the block-shaped cutting blade 27 of Fig. 41 (a).
  • Fig. 44 shows a cross-sectional view of a pair of horizontally long steel rolls as another example of the cutting installation device.
  • the notch setting device 28 is a notch setting device 28 having a plurality of divided heat generating portion storage portions 32, and can be engaged with each other and rotated.
  • the roll 30 has a receiving blade 41, and the cutting blade 40 and the receiving blade 41, which are formed by the cutting blade 40 and the receiving blade 41, are arranged on the roll at regular intervals so that the notch 1 6 is not installed in the section heating section 6.
  • the peripheral edge of the cutting blade circumferential surface 44 is used as a cutting blade, and a notch 39, which is an intermittent recess, is formed on a part of the opposing circumferential surface of the cutting blades 40 adjacent to each other.
  • a notch 39 that is an intermittent recess is formed in a part of the surface, the continuous body 8 is inserted into the fitting part 42 of the cutting blade and the receiving blade, and at least in a region other than the section heating part 6 of the continuous body 8 Part of the fitting part 42 ⁇ ⁇ 42 between the cutting blade and the receiving blade It is a notch installation device 28 that alternately forms the notches 17 and the connecting portions 18 along the same.
  • FIG. 45 is a sectional view taken along line GG.
  • FIG. 46 is a cross-sectional view of a pair of horizontally long steel rolls, which is another example of the cutting installation device 28.
  • the rolls 29 and 30 are provided with fitting portions 42 between the cutting blade and the receiving blade at a desired interval.
  • Holding parts 34 are provided at both ends of the rolls 29 and 30 so that both ears of the continuous body 8 are pressed down and the divided heat generating part is accommodated between the cutting blade and the fitting part 42 of the receiving blade.
  • the blade 41 is squeezed by a moderate depth.
  • a cutting blade is formed on the peripheral edge of the circumferential surface 45 of the cutting blade in the rolls 29 and 30.
  • the cutting blades 40 of the rolls 29 and 30 each have a notch 39 which is an intermittent recess formed on a part of the circumferential surface of the cutting blade 40 adjacent to each other, and the length of the cutting blade 40 (the end of the notch). To the edge of the adjacent notch) and the length of the notch 39 can be molded and set arbitrarily.
  • the notch 19 and the connecting part 18 are the length of the cutting edge 35Z of the cutting part 35 of the rolls 29 and 30 and the fitting part 42 of the receiving blade (the shortest distance from the end of the notch to the end of the adjacent notch) and the notch.
  • Set by length of 39 As an example, the length of the cutting edge 35Z is about 10 mm, the length of the notch 39 is about 3 mm, and the like.
  • the distance between one row of cuts 15 constituted by the cuts 19 and the connecting portions 18 and the adjacent row of cuts 15 is set by the width of the fitting portion 42 between the cut blade and the receiving blade.
  • the distance between one set of cuts 15 made up of one or more rows of cuts 15 provided in one section and another set of cuts 15 provided in another adjacent section is determined by cutting 15 It can be set to a desired interval according to the conditions to be established (distance between the division parts 7 etc.) The
  • the notch 39 may be set at an arbitrary angle such as every 45 ° or 120 °, which is an example in which the notch 42 is provided every 180 °.
  • the notch 39 is provided in one axial direction of each cutting blade 40 and each receiving blade 41.
  • FIG. 47 (a) shows the cutting installation device of the present invention.
  • It has a cutting roll 29 and a receiving roll 30, and holding parts 34 that support both ends of the continuous body 8 at both ends of the receiving roll 30 (or both ends of the continuous body when multiple heating elements are connected). It is the same as the fourth incision setting device 28 except that a separate heat generating portion storage portion 32 is further provided adjacent to the fitting portion 42 of each incision blade and the receiving blade of the incision roll 29.
  • the receiving heat 30 or both of the rolls 29 and 30 may be provided with the same type of divided heat generating part storage part 32.
  • Fig. 47 (b) shows the cutting blade 40 of the cutting roll 29 having a notch 42 and a cutting blade 35Z, and the receiving roll 30 has a receiving blade 41 fitted to the cutting blade 40 of the cutting roll 29.
  • 41 is fitted and rotated, one notch 15 consisting of notch 19 and connecting portion 18 is formed.
  • Fig. 47 (c) forms two notches 15.
  • At least one of the cutting blade 40 and the receiving blade 41 has a cutout 39, and three cuts 16 are formed.
  • the notch 39 is provided over the entire horizontal width direction of every other cutting blade 40,
  • the notch 39 may be provided at an appropriate angle ⁇ over the entire width direction of the cutting blade 40.
  • the above relationship also applies to cutting blades having other notches in this specification.
  • FIG. 47 (a) is a front view of another example of the cutting installation device with a detachable clutch of the present invention.
  • This incision installation device with clutch is divided heat generation by belt 60 such as timing belt.
  • belt 60 such as timing belt.
  • a detachable clutch 58 (hereinafter referred to as a clutch) used as a mechanism for maintaining the state of both rolls 29 and 30 is provided between a gear 56 and a gear 56 that is driven synchronously by a gear (not shown) of a drive source. It is.
  • Fig. 47 (a) is an example of a driving method for both rolls 29 and 30.
  • the cutting roll 29 and the receiving roll 30 are not in contact with each other, but the gear 55 of the cutting roll 29 and the gear 55 of the receiving slot 1 are connected by the benolet 60! 30 is driven.
  • both rolls 29 and 30 stop. Even if the clutch 60 is disengaged to stop both rolls 29 and 30, once the clutch 60 is reengaged, the clutch 60 can be engaged only at one point. The phase of the incision position with respect to is kept accurate.
  • the shaft 53 of the incision ronole 29 is connected to the benolet 60 by the joint 78 and is connected to the shaft 52Z having the gear 55.
  • FIG. 47 (b) shows that the driving force transmitted from the driving unit is transmitted from the gear 56 by the gear 55 Z by the meshing and rotated by the shaft 52 of the receiving roll 29.
  • FIG. 4 is a partial front view of an example in which both rolls 29 and 30 are synchronized in a meshing manner.
  • Fig. 47 (c) is a front partial view of an example in which the driving force of the driving unit force is also transmitted to the respective gear wheels 55 through the gear 59, and both rolls 29 and 30 are synchronized. is there.
  • the cutting roll uses shafts 53 and 52Z with joint 78.
  • the lifting device and the stopper are omitted.
  • FIG. 48 (a) is another example of the incision installation device of the present invention, which illustrates the movement of the roll 29 by the elevating device 61 by performing synchronization with the drive source force in the chain 59.
  • the shafts 52, 52 are constituted by a cutting roll 29 having a section heat generating part storage section in parallel, and a receiving roll 30 having a force recess 43 and a section heat generating section storage section 32.
  • the cutting roll 29 is pressed by a lifting device 61 such as an air cylinder toward a receiving roll 30 whose axial position is fixed.
  • a blade that forms a notch in the heating element when deployed on the peripheral surface of the cutting roll 29 is provided.
  • the surface is flat.
  • the driving force from the driving source to the gears 56, 56 fixed to the shaft 53 and the rolls 29, 30 is transmitted to the cutting roll 29 and the receiving roll 30 through the chain 59, respectively. While synchronizing, it is synchronizing with apparatuses other than the cutting installation apparatus.
  • FIG. 48 (d) is an enlarged front view of the gap adjusting plate 63 portion.
  • a configuration in which the gap adjusting plate 63 is pushed in the axial direction of the rolls 29 and 30 so as to obtain a predetermined gap is a preferred example.
  • the push-in configuration includes a push-in configuration with a spring and a push-in configuration with a screw such as a bolt Z nut type.
  • the hardness of the two rolls in this example is preferably the same as this example when the hardness of the surface of the receiving roll 30 or the inner surface of the processed recess 43 is higher than the hardness of the blade 35 of the cutting roll 29.
  • the cutting roll 29 and the receiving roll 30 use gears to rotate in opposite directions, and the heating element Rotate each with an independent motor to synchronize with the feed rate.
  • a notch is formed in the heating element due to the action of the force to be cut and the influence of the distortion generated in the vicinity.
  • the receiving roll 30 is preferably grooved with a polymer material such as rubber or plastic, which is a low-grade material, in order to reduce wear of the cutting edge of the expensive rotary blade 35.
  • the mechanism for transmitting the driving force of the driving source force to the roll synchronously is that the cutting roller 29 side having the divided heat generating part storage portion 32 has a gear 59 on the driving source side and a gear 55 on the cutting roll 30 side by a chain 59.
  • the chain 59 is stretched by the adjusting gear 57.
  • a gear 56 on the drive source side and a gear 55 on the receiving roll 30 side are connected by a chain 59.
  • a gear 55 is fixed to the shaft 52 on the cutting roll 29, and a gear 55 is also fixed to the shaft 52 on the receiving roll 30.
  • the cutting roll 30 is provided with a lifting device 61.
  • the lifting device 61 also serves as a pressing mechanism.
  • the lifting device 61 is an air cylinder that lifts and lowers the roll 29.
  • the cutting roll 29 can be separated from the receiving roll 30, and the cutting roll 29 can be received close to the rolling roll 30.
  • the heating element When the heating element is first introduced between the receiving roll 30 and the cutting roll 29, it is easier to introduce the heating element 30 and the cutting roll 29 apart from each other.
  • a packaging material made of thermoplastic resin is used as the packaging material for the heating element, when the cutting blade 35 of the cutting roll 29 is heated, the receiving roll 30 and the cutting roll 29 must be separated from each other. I must. Otherwise, the heating element cannot be introduced. Therefore, the elevating device 61 can receive the cutting roll 29 so that it can be separated from the roll 30! /.
  • the support 67 of the receiving roll 30 is provided with a detachable sliding clearance adjusting plate 64 at a predetermined location.
  • the guide cylinder 66 can be moved along the column 67 by the lifting device 61 while being pressed against the receiving roll 30 and guided by the positioning pin 62 and the gap adjusting plate hole 64.
  • the blade 55 of the cutting roll 29 is aligned with the processing recess 43 of the receiving roll 30.
  • the cutting roll 29 and the receiving roll 30 are provided with positioning pins 62 and 62, respectively, and can be stored in the gap adjusting plate 63 with the rotational positions of the rolls 29 and 30 being set to predetermined positions.
  • the gap adjustment that also serves as a relative alignment between the cutting roll 29 and the receiving roll 30 so that the blade 35 of the cutting roll 29 is received in the machining recess 43 of the receiving roll 30.
  • a plate 63 and positioning pins 62 are provided. Therefore, when the cutting roll 29 and the receiving roll 30 are brought close to each other, the cutting blade 35 is always received by the force recess 43 and does not contact the bottom of the processing recess 43, so that the cutting blade 35 is damaged.
  • Figure 48 (b) shows a mechanism that synchronizes the driving force from the driving source and transmits it to the cutting roll 29, and the gear 56 on the driving source side and the gear 55 on the cutting roll 29 side are connected by a chain 59 and adjusted.
  • FIG. 5 is a side view showing a state where a chain 59 is stretched by a gear 57.
  • FIG. 48 (c) is a side view showing the state of the gears 55 and 56, the adjusting gear 57 and the chain 59 in a state where the cutting roll 29 is separated from the receiving roll 30.
  • FIG. 48 (c) is a side view showing the state of the gears 55 and 56, the adjusting gear 57 and the chain 59 in a state where the cutting roll 29 is separated from the receiving roll 30.
  • the cutting roll 29 is provided with an elevating device 61 and is movable, but conversely, the cutting roll 29 is fixed to the column 67 and the receiving roll 30 is fixed to the column.
  • the structure may be fixed to a guide tube 66 provided at 67, and a structure in which the receiving roll 30 is pushed up by the lifting device 61, that is, it may be lifted and lowered.
  • the clearance adjustment plate 63, positioning pin 62, etc. may be modified so that they can be accommodated.
  • the cutting roll 29 and the receiving roll 30 may be interchanged.
  • Fig. 48 (e) includes a cutting roll 29 and a receiving roll 30 whose rotation axes are parallel to each other.
  • the receiving roll 30 is pressed against a cutting roll 29 having a fixed axial position by a movable support member 28 such as an expander.
  • the separation mechanism of the cutting roll 29 and the receiving roll 30 including alignment in the cutting installation device of the present invention can be applied to other mechanisms as long as the function of the cutting installation device is maintained.
  • the format is arbitrary.
  • Examples of the operating mechanism that presses and moves the roll support member with a movable structure include a type that protrudes a rod etc. outside the cylinder according to the rotation of the motor, and a type that uses a force disk that rotates by the motor. It is done.
  • the mechanism for transmitting the driving force from the driving source to the roll in synchronism is the force that shows the mechanism in which the gear 56 on the driving source side and the gear 55 on the cutting roll 29 side are connected by a chain 59 in this example.
  • a power source such as an independent motor with synchronization may be used.
  • Fig. 49 (a) is another example of the incision installation device of the present invention, in which the incision blade 35 of the incision roll 29 having the divided exothermic part storage part 32 is set to an appropriate temperature equal to or higher than the melting start temperature of the heating element packaging material.
  • the receiving roll 30 having the processing concave portion 43 and the divided heat generating portion accommodating portion 32 is cooled and rotated.
  • the cutting blade 35 of the cutting roll 29 has a heater 77 in a heating device 73 such as a heating tank provided below. Heated silicone oil 75
  • the lower part is immersed in a bath and the cutting blade 35 is heated and rotated to an appropriate temperature that is equal to or higher than the melting start temperature of the heating element packaging material, and the receiving roll 30 cools the water tank provided below.
  • the lower part is immersed in water 76 in the apparatus 74, and the receiving roll 30 is cooled and rotated.
  • the water 76 adhering to the receiving roll 30 is wiped off with a cloth or sponge to prevent scattering and adhesion to the heating element.
  • cooling means such as a water circulation type cooling device which cools water, in a water tank.
  • the cooling device 74 include a cooling air device and a cooler other than the cooling water tank that is not limited.
  • the silicon oil 75 adhering to the cutting blade 55 is wiped off with a cloth or sponge to prevent scattering and adhesion to the heating element.
  • FIG. 49 (b) shows an example of the cutting roll 29 having the electric heater 77 installed in a hole provided inside the cutting roll 29.
  • the material of the low hardness constituting the surface of the receiving roll is not limited, but a polymer substance is preferable.
  • Elastomer Plastics capable of some degree of elastic deformation
  • Elastomers can be selected with appropriate hardness and are easy to manufacture.
  • the receiving roll is provided with a moisture wiping device after cooling until it contacts the heating element of the continuous heating element. May be.
  • a round blade is provided on the shaft, or when a plurality of blades are combined at a predetermined parallel pitch, an intermittent notch is provided with a notch on the outer periphery of the round blade (a notch is provided at the edge of the blade). It is preferable to provide small blades on the outer periphery at intervals (a method in which the outer periphery of the blade is divided to cut an axial groove and a strip-shaped blade is implanted in the groove).
  • the cutting roll is provided with long blades along the axial direction, or by combining multiple blades with a predetermined parallel pitch, intermittent cutting can be provided with long blades (notches on the blade tip).
  • a small blade along the axial direction (a method of dividing the outer periphery of the blade to cut an axial groove and implanting a strip-shaped blade in this), and a plurality of parallel blades at a predetermined parallel pitch. It is preferable to combine blades.
  • a plurality of sets of the blades may be provided at a predetermined interval.
  • the cutting blade may be heated by at least one of 1) heating from the inside of the roll, for example, heating by a heater, 2) radiation from the outside, or 3) heating by an oil bath.
  • any heating means can be used as long as the cutting blade can be heated above the melting point of the packaging material constituting the heating element. At this time, cool the receiving roll.
  • Cooling of the receiving roll is possible with any cooling method such as internal cooling method, external air cooling method, or external water cooling method of the receiving roll.
  • the method of cooling by blowing air to the outside is the simplest and most practical. It is.
  • cooling liquid for the roll water is usually used, and the lower half of the roll is immersed in a water tank.
  • a moisture wiping device may be provided after the receiving roll is cooled and before it contacts the heating element.
  • the packaging material that constitutes the heating element of the continuous segmented heating element will not melt too much, and melted grease will adhere when the blade comes off, making it difficult to form an appropriate cut.
  • the deterioration of the surface of the slug receiving roll due to heat is also reduced.
  • incision installation device and the incision installation device described in the present specification have been described by taking the case of using an alternate incision installation device as an example. Can be used for cutting installation equipment. In addition, continuous cutting without a joint can be installed.
  • the method for producing a heating element of the present invention is a kind of uneven sheet-like body, and consists of a divided heating part having a heating composition and a sorting part being a seal part without a heating composition.
  • the segment heating unit is a convex object, and other than the segment heating unit is a concave object, and the segment heating consisting of a plurality of segment heating units
  • Part Uses a continuous segment heating part heating element in which the heating elements are continuously connected in a strip shape, and has a cutting roll having a cutting blade and a receiving roll corresponding thereto, and at least one of the rolls is not affected by the cutting blade.
  • Concavities and convexities having a function of providing intermittent cuts through at least a part of the concave portions by passing the concave and convex sheet members between both rolls.
  • Sheet cutting The continuous section heating element is inserted between both rotating rolls of the device, and the cutting is made on the continuous section heating section heating element by contacting with the rotating body while moving and moving. Recesses other than the section heating section of each section heating section heating element by the blade of the roll.
  • the method for producing a heating element with a notch comprises a section between a segment heating section having a heating composition and a section heating section, and a section that is a seal section having no heating composition,
  • a third step of cutting each of the generated heating elements by cutting to manufacture a heating element, and a third step of manufacturing the heating elements by cutting each heating element provided with a cut This is a heating element manufacturing method for manufacturing a heating element provided with a notch penetrating by placing a third step after the second step, and the notch installation processing in the second step is used to cut multiple rows of cuts 1 It is a process of installing multiple sets of cuts as a set, and is a method of manufacturing a heating element in which multiple sets of cuts in each set are divided into two or more cutting forces, and the cuts are staggered This is a method for manufacturing a heating element that is a cut, and a method for manufacturing a heating element in which the notch is a perforated cut.
  • a heating element with a single notch can be manufactured.
  • a method for installing a notch using the notch setting device is also included in the method for manufacturing a heating element of the present invention.
  • the heating element manufacturing apparatus shown in FIG. 50 manufactures a heating element having a heating part in which a plurality of section heating parts are provided with intervals as a sealing part, and cuts by making alternate cuts.
  • This is a manufacturing device for a heating element with a notch.
  • the exothermic composition 3 is supplied as the exothermic composition molded body 4 onto the base material 8 from the device 50 through the through-hole 49, and then the covering material 9 supplied from the covering material supply roll 55 is covered, and the seal roll 56 is covered.
  • the peripheral portion of the exothermic composition molded body 4 and the peripheral portion of the exothermic composition molded body S are heat sealed. Next, it is supplied to a staggered incision installation device 57 composed of one unit, a staggered incision with three rows of force is formed in the sorting part, and then it is supplied to a cut roll 59 and cut into a heating element. Obtain the heating element 1 with staggered notches shown in the plan view of b).

Abstract

L'invention concerne un élément chauffant présentant des incisions formées, de manière alternée, dans une matière non extensible ou dans une matière non étirable, ou dans une zone non extensible, de sorte à pouvoir changer spatialement, lors de la réception d'une force extérieure. Cet élément chauffant, auquel on a conféré extensibilité ou étirabilité, peut être produit en masse, à faible coût. L'invention concerne un procédé et un appareil permettant de produire cet élément chauffant. Cet élément chauffant (1) comprend au moins deux parties chauffantes séparées (6) séparées l'une de l'autre par des parties de séparation (7) servant de parties d'étanchéité. L'invention est caractérisée en ce que les parties chauffantes séparées (6) contiennent une composition chauffante moulée (4) constituée d'une composition chauffante qui génère de la chaleur, lors de sa mise en contact avec de l'oxygène, les parties chauffantes séparées (6) étant disposées selon un agencement de bandes formant rayures, et en ce qu'au moins certaines parties de séparations (7) présente des incisions (15).
PCT/JP2007/050442 2006-01-13 2007-01-15 Element chauffant, procede pour produire cet element chauffant, et appareil d'incision associe WO2007081015A1 (fr)

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JP2006006818A JP2009082157A (ja) 2006-01-13 2006-01-13 発熱体、発熱体製造方法及び切り込み設置装置
JP2006-006818 2006-01-13

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WO2007081015A1 true WO2007081015A1 (fr) 2007-07-19

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
JP2009089754A (ja) * 2007-10-04 2009-04-30 Japan Pionics Co Ltd 発熱シート及び発熱シート袋
CN114850004A (zh) * 2022-06-02 2022-08-05 东莞市坚华机械有限公司 一种回字形烤箱

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011027436A1 (fr) * 2009-09-02 2011-03-10 マイコール株式会社 Matériau générateur de chaleur et procédé pour produire un matériau générateur de chaleur
KR102138912B1 (ko) * 2013-06-11 2020-07-31 이성재 다용도 핫팩
JP7469001B2 (ja) 2019-06-28 2024-04-16 花王株式会社 複合シートの製造方法及び製造装置並びに複合シートの検査方法

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JPS52123882U (fr) * 1976-03-17 1977-09-20
JPH0570525U (ja) * 1992-03-06 1993-09-24 譲二 大島 医療用保温具
JPH079771U (ja) * 1993-07-16 1995-02-10 丈夫 加藤 包装用クッションネット袋
JPH11512954A (ja) * 1996-06-27 1999-11-09 ザ、プロクター、エンド、ギャンブル、カンパニー 共通の接着部および酸素透過性面を有する温熱パッド
JP2002018985A (ja) * 2000-07-10 2002-01-22 Masaya Matsuda 合成樹脂製包装用容器における開蓋用ミシン目の形成装置
JP2005304613A (ja) * 2004-04-19 2005-11-04 Toa Kiko Kk 使い捨てカイロ、その製造方法及び製造装置

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JPS52123882U (fr) * 1976-03-17 1977-09-20
JPH0570525U (ja) * 1992-03-06 1993-09-24 譲二 大島 医療用保温具
JPH079771U (ja) * 1993-07-16 1995-02-10 丈夫 加藤 包装用クッションネット袋
JPH11512954A (ja) * 1996-06-27 1999-11-09 ザ、プロクター、エンド、ギャンブル、カンパニー 共通の接着部および酸素透過性面を有する温熱パッド
JP2002018985A (ja) * 2000-07-10 2002-01-22 Masaya Matsuda 合成樹脂製包装用容器における開蓋用ミシン目の形成装置
JP2005304613A (ja) * 2004-04-19 2005-11-04 Toa Kiko Kk 使い捨てカイロ、その製造方法及び製造装置

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009089754A (ja) * 2007-10-04 2009-04-30 Japan Pionics Co Ltd 発熱シート及び発熱シート袋
CN114850004A (zh) * 2022-06-02 2022-08-05 东莞市坚华机械有限公司 一种回字形烤箱

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