WO2007073863A1 - Verfahren und vorrichtung zum stranggiessen von stahl-vorprofilen, insbesondere doppel-t-vorprofilen - Google Patents
Verfahren und vorrichtung zum stranggiessen von stahl-vorprofilen, insbesondere doppel-t-vorprofilen Download PDFInfo
- Publication number
- WO2007073863A1 WO2007073863A1 PCT/EP2006/011972 EP2006011972W WO2007073863A1 WO 2007073863 A1 WO2007073863 A1 WO 2007073863A1 EP 2006011972 W EP2006011972 W EP 2006011972W WO 2007073863 A1 WO2007073863 A1 WO 2007073863A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mold
- web part
- pole
- flange parts
- strand
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/0406—Moulds with special profile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
- B22D11/11—Treating the molten metal
- B22D11/114—Treating the molten metal by using agitating or vibrating means
- B22D11/115—Treating the molten metal by using agitating or vibrating means by using magnetic fields
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/122—Accessories for subsequent treating or working cast stock in situ using magnetic fields
Definitions
- the invention relates to a method for the continuous casting of steel pre-profiles, in particular double-T pre-profiles according to the preamble of claim 1 and a device for performing the method.
- Steel preliminary profiles represent primary material for producing rolled steel profile carriers in I 1 H 1 U and Z cross-sectional shape, as well as special sheet piling profiles.
- a process for the continuous casting of such preliminary profiles is disclosed, for example, in EP-B-1 419 021.
- the continuous casting of pre-profiles was introduced industrially in the 1970s and has become increasingly important in the course of the general trend towards so-called near-dimensional casting.
- the preliminary profiles are usually cast in a double-T cross-sectional shape, the molten steel being introduced essentially vertically into a so-called "dog-bone" continuous mold, the mold cavity cross section of which is composed of two flange parts and a web part.
- the preliminary mold strand is made from the mold with a liquid core fed to a strand guide with secondary cooling devices.
- the continuous casting of double-T pre-profiles presents some problems, especially when it comes to pre-profiles with a relatively thin web part, when high-strength special steel grades (CaSi or AI- soothes and micro-alloyed steels with V, Nb, etc.) can be cast, or during rapid casting.
- high-strength special steel grades CaSi or AI- soothes and micro-alloyed steels with V, Nb, etc.
- the liquid steel is introduced into the mold via only one pour, usually asymmetrically at the transition between the web part and one of the flange parts.
- the present invention has for its object to propose a method of the type mentioned and to provide an apparatus for performing the method with which steel pre-profiles, which have two flange parts and a web part, can be produced with improved quality, even if the pre-profile has a relatively thin web part and / or special steel grades are to be cast. Furthermore, depending on the dimensions or the steel quality of the preliminary section strand, it should be possible to choose a symmetrical or asymmetrical steel feed with one or with two open or closed gates into the mold.
- the liquid core of the pre-profile strand is set into stirring movements transverse to the continuous casting direction using electromagnetically induced forces in the region of the flange parts and / or the web part and the liquid steel in the sump of the pre-profile strand is exchanged between the flange parts and the web part by the stirring movements , the flow and temperature conditions in the liquid steel sump within the pre-profile strand shell can be actively influenced and the following effects can be brought about:
- Fig. 2 a mold in cross section with a second embodiment of an electromagnetic stirrer
- Fig. 3 - 6 a third embodiment of an electromagnetic
- FIG. 11 + 12 a mold with two stirrers in another embodiment, with different pole shoe circuits
- FIG. 13 a side view of the stirrer according to FIG. 10
- FIG. 14 a further exemplary embodiment of a mold with an electromagnetic stirrer and
- FIG. 15 shows an electrical diagram for the stirrer according to FIG. 14.
- FIG. 1 schematically shows a mold 1 or its horizontal mold cavity cross section, which is composed of two flange parts 2, 3 and a web part 4.
- the mold 1 is intended for the continuous casting of double-T pre-profiles. Liquid steel is introduced essentially vertically into this continuous mold, in which a strand crust forms, and from which a pre-profile strand with a liquid core is fed to a strand guide with secondary cooling devices.
- the liquid core of the pre-profile strand is preferably in the area of the mold 1 or directly at the outlet from the mold 1 by means of an electromagnetic stirrer 10 using electromagnetically induced forces by means of 3-phase current in stirring movements transverse to the continuous casting direction offset and thereby the liquid steel in the sump of the preliminary section strand exchanged between the flange parts 2, 3 and the web part 4.
- the stirrer 10 shown in FIG. 1 has an annular, closed yoke 11, which surrounds the mold 1 at a certain height, with six magnetic poles in the form of pole pieces 12 to 17, each pole piece being surrounded by an electromagnetic coil 19.
- the pole pieces 12 to 17 are distributed unevenly on the circumference of the yoke 11, such that one pole piece 12, 13 each on the flange parts 2, 3 and two pole pieces 14, 15; 16, 17 are aligned from both sides with the web part 4.
- the stirrer 10 or, in this example, the rotary stirrer works on the principle of a 6-pole asynchronous motor, in which a traveling field can be generated with the aid of 3-phase current.
- the correct wiring of the poles is important in order to generate a linearly moving or rotating field or linear or rotating currents.
- the mold 1 is again surrounded in a certain and preferably adjustable height range by an electromagnetic stirrer 20 with an annular, closed yoke 21, on the circumference of which again six pole shoes 22 to 27 are distributed non-uniformly , with the difference that all six pole shoes 22 to 27 are essentially aligned for linear flows in the web part 4.
- the mold 1 is each assigned an electromagnetic stirrer 30, which has a closed yoke 31 surrounding the mold 1 and formed as a rectangular frame, the long sides of which each have three pole shoes 34, 35 distributed over the mold width. 36 and 37, 38, 39 are assigned, and the narrow sides of which are each provided with a center pole shoe 32, 33 aligned frontally on the flange parts 2, 3.
- the stirrer 30 can be operated both as a rotary stirrer and as a linear stirrer, depending on the pole connection, ie depending on which pole shoes and with which phase sequence (cf. phase designation U, V, W; U 1 , V, W) are energized.
- Fig. 4 also shows a circuit for a linear operation (center pole shoes 32, 33 switched off in the flange area), with phase sequence U, V, W on both long sides, so that there is a flow in the web part 4 (2x3-pole linear operation, in the same direction).
- This pole connection is preferably used with an asymmetrically arranged sprue 47 in the flange part 2 or 3.
- center pole shoes 32, 33 are live in the flange area, but the middle of the three pole shoes 34, 35, 36; 37, 38, 39, which are assigned to the two long sides, switched off (pole shoes 35, 38 without current). Rotation fields are thus generated in the flange areas (2x3-pole rotation mode).
- the direction of rotation of the rotation fields in the two flange parts 2, 3 is the same, which also results in a flow in the web part 4, which, however, is less efficient than in linear operation Fig. 3.
- This pole connection is preferably used when the sprue 48 is arranged symmetrically in the web part 4.
- the stirrer 30 can also be used to generate rotation fields with opposite directions of rotation in the flange parts 2, 3.
- This pole connection is preferably used in the case of two symmetrically arranged inlets 45, 46 in the flange parts 2, 3.
- FIG. 7 and 8 show a variant in which the mold 1 has two electromagnetic stirrers 40, 40 ′ or two in the width direction of the mold 1 on its circumference separate yokes 41, 41 ', each with three pole pieces 42, 43, 44; 42 ', 43', 44 ', each yoke 41, 41' having a center pole shoe 42, 42 'which is frontally aligned with the respective flange part 2, 3 and two pole shoes 43, 44 which are directed onto the flange part 2, 3 from both sides ; 43 ', 44' is provided.
- a 2x3-pole rotation operation can again be accomplished or rotation fields can be generated in the flange regions 2, 3, which in turn have the same direction of rotation (FIG. 7) or the opposite direction of rotation (FIG. 8) exhibit.
- a symmetrical gate is indicated at 48.
- FIGS. 10 to 12 also offer similar advantages, in which the mold 1 in turn is assigned two electromagnetic stirrers 50, 50 '(FIGS. 10 and 13) or 60, 60' (FIGS. 11 and 12) on its circumference which, however, do not have yokes 51, 51 'or 61, 61' separated from one another in the wide but in the thick direction of the mold 1.
- Each yoke is each with three pole pieces 52, 53, 54; 52 ', 53', 54 'and 62, 63, 64; 62 ', 63', 64 ".
- the three pole shoes 52, 53, 54; 52 ', 53', 54 ' each distributed over the entire width of the preliminary profile and two of them (pole shoes 52, 54; 52', 54 ') laterally directed towards the flange parts 2, 3, and the middle pole shoe 53, 53' extends up to to the bridge part 4.
- all three pole shoes 62, 63, 64; 62 ', 63', 64 'of the respective stirrer 60, 60' only distributed over the web and protrude to the web part 4.
- 45, 46 two symmetrical inlets are shown.
- the stirrers 50, 50 'and 60, 60' are operated as linear stirrers, with opposing flows (FIGS. 10 and 11) or a co-flowing flow (FIG. 12) being able to be generated in the web part 4.
- the setting is made depending on the casting and / or product parameters.
- FIG. 14 shows an electromagnetic stirrer 70 with an 8-pole structure, constructed similarly to the stirrer 30 according to FIGS. 3 to 6 (with a yoke 71 designed as a rectangular frame, the long sides of which each have three pole shoes 74 distributed over the mold width , 75, 76; 77, 78, 79 and the narrow sides thereof are each provided with a center pole shoe 72, 73 aligned frontally on the flange parts 2, 3).
- this version does not choose between rotary and linear operation by switching off two of the eight poles, but simultaneously linear fields in the web part 4 are used using a 1x6-pole linear stirrer (pole shoes 74, 75, 76; 77, 78, 79 ) and fields of rotation in the flange parts 2, 3 using 2x3-pole rotary stirrers (pole shoes 74, 72, 77 and 76, 73, 79).
- FIG. 15 shows an electrical diagram of the stirrer 70 with this 8-pole structure or this 8-pole system, in which the linear fields are generated simultaneously by means of a 1x6-pole linear stirrer and the rotation fields are used using these 2x3-pole rotation stirrers .
- This electromagnetic stirrer 70 is supplied by the network, for example with three-phase current 50 Hz, by means of lines 81, 82, the lines 81, 82 each leading to a frequency converter 83, 84. These frequency converters 83, 84 are connected to a converter control 85 and the individual phases are set by this to a predetermined frequency.
- the control 85 has the task of coordinating the frequencies of the two converters with one another, in order on the one hand to match those in the web and in the transition region to the synchronize the stirring movements generated by both flange parts. In addition, it should prevent the occurrence of beat phenomena at slightly different frequencies of the two stirrers. A beat would lead to one and the other poles being under full load at the same time, which would result in a very uneven network load.
- the individual phases U, V, W of one converter 84 or the phases Ui, V-i, Wi of the other converter 83 are connected to the pole shoes 74, 75, 76; 77, 78, 79 wound coils.
- Phases U, V, W lead to the coils IT, 78 ', 79' in the pole pieces 77, 78, 79 in the bridge part and further to the coils 76 ', 75', 74 'of the pole pieces 76, 75, which are arranged symmetrically to them.
- 74 wherein the connecting lines from the coils 77 ', 79' are crossed to the coils 76 ', 74' (connected in series). The lines are led from these coils to star point 87.
- the same is provided for phases U 1 , V 1 , W 1 , but this is not explained in detail.
- the phase W 1 is conducted to the coil 72 'and further to the opposite coil 73' and further to a star circuit 88.
- Flange parts rotating and / or linear moving fields in the web part can be generated for the targeted achievement of flows in the liquid sump.
- Tube molds are shown schematically in the figures. Instead of tubular molds, however, all mold constructions suitable for preliminary profiles, such as block or plate molds etc., can be operated with the method according to the invention or can be used with the device according to the invention.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2633026A CA2633026C (en) | 2005-12-24 | 2006-12-13 | Method and device for the continuous casting of preliminary steel sections, in particular preliminary i-sections |
KR1020087015544A KR101332209B1 (ko) | 2005-12-24 | 2006-12-13 | 예비 형강, 특히 예비 이중 t 형강을 연속 주조하기 위한방법 및 그 장치 |
CN2006800489806A CN101346200B (zh) | 2005-12-24 | 2006-12-13 | 用于连铸粗制钢型材尤其是双t形粗制型材的方法和装置 |
BRPI0620623-9A BRPI0620623A2 (pt) | 2005-12-24 | 2006-12-13 | processo e dispositivo para o lingotamento contìnuo de perfis de aço, particularmente perfis de duplo t |
JP2008546200A JP5308826B2 (ja) | 2005-12-24 | 2006-12-13 | 鋼予備形材、特にi型予備形材の連続鋳造方法および装置 |
US12/140,135 US8109320B2 (en) | 2005-12-24 | 2008-06-16 | Method and apparatus for the continuous casting of preliminary steel sections |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05028469A EP1815925B1 (de) | 2005-12-24 | 2005-12-24 | Verfahren und Vorrichtung zum Stranggiessen Doppel-T-Vorprofilen |
EP05028469.4 | 2005-12-24 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/140,135 Continuation US8109320B2 (en) | 2005-12-24 | 2008-06-16 | Method and apparatus for the continuous casting of preliminary steel sections |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007073863A1 true WO2007073863A1 (de) | 2007-07-05 |
Family
ID=35809633
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2006/011972 WO2007073863A1 (de) | 2005-12-24 | 2006-12-13 | Verfahren und vorrichtung zum stranggiessen von stahl-vorprofilen, insbesondere doppel-t-vorprofilen |
Country Status (16)
Country | Link |
---|---|
US (1) | US8109320B2 (de) |
EP (1) | EP1815925B1 (de) |
JP (1) | JP5308826B2 (de) |
KR (1) | KR101332209B1 (de) |
CN (1) | CN101346200B (de) |
AR (1) | AR056855A1 (de) |
AT (1) | ATE517706T1 (de) |
BR (1) | BRPI0620623A2 (de) |
CA (1) | CA2633026C (de) |
ES (1) | ES2371168T3 (de) |
MY (1) | MY163903A (de) |
RU (1) | RU2419509C2 (de) |
TW (1) | TWI406720B (de) |
UA (1) | UA91104C2 (de) |
WO (1) | WO2007073863A1 (de) |
ZA (1) | ZA200803923B (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017162418A1 (de) * | 2016-03-21 | 2017-09-28 | Primetals Technologies Austria GmbH | Einen metallstrang partiell umgreifende rührspule |
CN108526424A (zh) * | 2018-04-09 | 2018-09-14 | 上海大学 | 一种双频电磁搅拌的磁场发生器 |
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EP2025432B2 (de) * | 2007-07-27 | 2017-08-30 | Concast Ag | Verfahren zur Erzeugung von Stahl-Langprodukten durch Stranggiessen und Walzen |
EP2350697B1 (de) * | 2008-05-23 | 2021-06-30 | Baker Hughes Ventures & Growth LLC | Zuverlässiges bohrloch-datenübertragungssystem |
JP5431438B2 (ja) * | 2011-11-10 | 2014-03-05 | 高橋 謙三 | 攪拌装置付き連続鋳造用鋳型装置 |
CN110434301B (zh) * | 2019-09-20 | 2021-01-15 | 哈尔滨工业大学 | 等外径多型号薄壁合金铸件行波磁场半连铸多级随动型芯设备 |
CN111715859B (zh) * | 2020-07-08 | 2021-09-14 | 燕山大学 | 一种嵌套式线圈结晶器电磁搅拌器 |
CN114505471B (zh) * | 2022-02-22 | 2024-04-23 | 襄阳金耐特机械股份有限公司 | 一种多自由度浇铸机 |
CN114951600B (zh) * | 2022-06-08 | 2023-11-03 | 刘磊 | 铝镁合金变速器多向挤压铸造模具及铸造方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US4867786A (en) * | 1987-05-19 | 1989-09-19 | Sumitomo Metal Industries, Ltd. | Electromagnetic stirring method |
JPH08294746A (ja) * | 1995-04-21 | 1996-11-12 | Nippon Steel Corp | ビームブランク鋳造用鋳型 |
JPH10230349A (ja) * | 1997-02-20 | 1998-09-02 | Yaskawa Electric Corp | 電磁攪拌装置 |
US20030183363A1 (en) * | 2000-07-05 | 2003-10-02 | Anders Lehman | Method and device for controlling stirring in a strand |
EP1419021A1 (de) * | 2001-08-20 | 2004-05-19 | Profilarbed S.A. | Verfahren zum stranggiessen eines stahlvorblocks |
JP2005066613A (ja) * | 2003-08-21 | 2005-03-17 | Yaskawa Electric Corp | 電磁攪拌装置 |
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JPS5236492B2 (de) * | 1972-12-20 | 1977-09-16 | ||
JPS58224050A (ja) * | 1982-06-22 | 1983-12-26 | Nippon Kokan Kk <Nkk> | ビ−ムブランクの連続鋳造方法 |
JPS62207543A (ja) * | 1986-03-05 | 1987-09-11 | Mitsubishi Heavy Ind Ltd | 連続鋳造用電磁撹拌方法 |
JPH0767604B2 (ja) * | 1990-11-30 | 1995-07-26 | 新日本製鐵株式会社 | 連続鋳造用電磁撹拌方法 |
JP3089608B2 (ja) * | 1992-06-22 | 2000-09-18 | 川崎製鉄株式会社 | ビームブランクの連続鋳造方法 |
PT1212159E (pt) * | 1999-08-26 | 2003-10-31 | Concast Standard Ag | Molde de fundicao para o vazamento continuo de aco em barras brutas e formas de barras pre-laminadas. |
JP2001334352A (ja) * | 2000-05-26 | 2001-12-04 | Nippon Steel Corp | ビレット用鋳型内電磁撹拌装置および撹拌方法 |
DE10062440A1 (de) * | 2000-12-14 | 2002-06-20 | Sms Demag Ag | Vorrichtung zum Stranggießen von Metallen, insbesondere von Stahl |
KR100554093B1 (ko) * | 2004-02-04 | 2006-02-22 | 주식회사 나노캐스트코리아 | 반응고 성형장치 |
-
2005
- 2005-12-24 AT AT05028469T patent/ATE517706T1/de active
- 2005-12-24 EP EP05028469A patent/EP1815925B1/de not_active Not-in-force
- 2005-12-24 ES ES05028469T patent/ES2371168T3/es active Active
-
2006
- 2006-12-13 JP JP2008546200A patent/JP5308826B2/ja not_active Expired - Fee Related
- 2006-12-13 BR BRPI0620623-9A patent/BRPI0620623A2/pt not_active Application Discontinuation
- 2006-12-13 KR KR1020087015544A patent/KR101332209B1/ko not_active IP Right Cessation
- 2006-12-13 RU RU2008130521/02A patent/RU2419509C2/ru not_active IP Right Cessation
- 2006-12-13 MY MYPI20081908A patent/MY163903A/en unknown
- 2006-12-13 WO PCT/EP2006/011972 patent/WO2007073863A1/de active Application Filing
- 2006-12-13 CA CA2633026A patent/CA2633026C/en not_active Expired - Fee Related
- 2006-12-13 UA UAA200809668A patent/UA91104C2/ru unknown
- 2006-12-13 CN CN2006800489806A patent/CN101346200B/zh not_active Expired - Fee Related
- 2006-12-18 TW TW095147520A patent/TWI406720B/zh not_active IP Right Cessation
- 2006-12-21 AR ARP060105742A patent/AR056855A1/es active IP Right Grant
-
2008
- 2008-05-08 ZA ZA200803923A patent/ZA200803923B/xx unknown
- 2008-06-16 US US12/140,135 patent/US8109320B2/en not_active Expired - Fee Related
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US4867786A (en) * | 1987-05-19 | 1989-09-19 | Sumitomo Metal Industries, Ltd. | Electromagnetic stirring method |
JPH08294746A (ja) * | 1995-04-21 | 1996-11-12 | Nippon Steel Corp | ビームブランク鋳造用鋳型 |
JPH10230349A (ja) * | 1997-02-20 | 1998-09-02 | Yaskawa Electric Corp | 電磁攪拌装置 |
US20030183363A1 (en) * | 2000-07-05 | 2003-10-02 | Anders Lehman | Method and device for controlling stirring in a strand |
EP1419021A1 (de) * | 2001-08-20 | 2004-05-19 | Profilarbed S.A. | Verfahren zum stranggiessen eines stahlvorblocks |
JP2005066613A (ja) * | 2003-08-21 | 2005-03-17 | Yaskawa Electric Corp | 電磁攪拌装置 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017162418A1 (de) * | 2016-03-21 | 2017-09-28 | Primetals Technologies Austria GmbH | Einen metallstrang partiell umgreifende rührspule |
AT518460A1 (de) * | 2016-03-21 | 2017-10-15 | Primetals Technologies Austria GmbH | Einen Metallstrang partiell umgreifende Rührspule |
AT518460B1 (de) * | 2016-03-21 | 2021-07-15 | Primetals Technologies Austria GmbH | Einen Metallstrang partiell umgreifende Rührspule |
CN108526424A (zh) * | 2018-04-09 | 2018-09-14 | 上海大学 | 一种双频电磁搅拌的磁场发生器 |
CN108526424B (zh) * | 2018-04-09 | 2020-11-24 | 上海大学 | 一种双频电磁搅拌的磁场发生器 |
Also Published As
Publication number | Publication date |
---|---|
AR056855A1 (es) | 2007-10-24 |
TWI406720B (zh) | 2013-09-01 |
US8109320B2 (en) | 2012-02-07 |
KR20080081158A (ko) | 2008-09-08 |
ATE517706T1 (de) | 2011-08-15 |
US20080251231A1 (en) | 2008-10-16 |
EP1815925A1 (de) | 2007-08-08 |
ZA200803923B (en) | 2009-03-25 |
ES2371168T3 (es) | 2011-12-28 |
BRPI0620623A2 (pt) | 2011-11-16 |
CA2633026A1 (en) | 2007-07-05 |
CA2633026C (en) | 2014-03-11 |
MY163903A (en) | 2017-11-15 |
JP5308826B2 (ja) | 2013-10-09 |
RU2419509C2 (ru) | 2011-05-27 |
CN101346200B (zh) | 2011-09-07 |
KR101332209B1 (ko) | 2013-11-25 |
UA91104C2 (ru) | 2010-06-25 |
EP1815925B1 (de) | 2011-07-27 |
RU2008130521A (ru) | 2010-01-27 |
TW200810859A (en) | 2008-03-01 |
JP2009521330A (ja) | 2009-06-04 |
CN101346200A (zh) | 2009-01-14 |
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