WO2007040096A1 - Liquide de traitement pour ameliorer la formabilite de materiau d'alliage d'aluminium - Google Patents

Liquide de traitement pour ameliorer la formabilite de materiau d'alliage d'aluminium Download PDF

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Publication number
WO2007040096A1
WO2007040096A1 PCT/JP2006/319059 JP2006319059W WO2007040096A1 WO 2007040096 A1 WO2007040096 A1 WO 2007040096A1 JP 2006319059 W JP2006319059 W JP 2006319059W WO 2007040096 A1 WO2007040096 A1 WO 2007040096A1
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WO
WIPO (PCT)
Prior art keywords
aluminum alloy
alloy material
treatment liquid
improving
water
Prior art date
Application number
PCT/JP2006/319059
Other languages
English (en)
Japanese (ja)
Inventor
Masao Komai
Koh Yoshioka
Original Assignee
Toyo Kohan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Kohan Co., Ltd. filed Critical Toyo Kohan Co., Ltd.
Priority to JP2006534522A priority Critical patent/JPWO2007040096A1/ja
Publication of WO2007040096A1 publication Critical patent/WO2007040096A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/18—Ethers, e.g. epoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/22—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/28—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/40—Lubricating compositions characterised by the base-material being a macromolecular compound containing nitrogen
    • C10M107/44—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/105—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles

Definitions

  • the present invention relates to a treatment liquid for improving the formability of an aluminum alloy sheet used for improving the formability of an aluminum alloy material.
  • Patent Document 1 JP 2003-105364 A
  • the present invention relates to an aluminum alloy plate forming processability improving process that exhibits an excellent lubricating effect when forming an aluminum alloy material coated on the surface of an aluminum alloy material and drying to form a film.
  • the purpose is to provide a liquid.
  • the treatment liquid for improving moldability of the aluminum alloy material of the present invention is modified with water-soluble urethane resin, water-soluble polyester resin, water-soluble acrylic resin, water-soluble epoxy resin, or these organic resins.
  • the aluminum alloy material forming cacheability improving treatment liquid comprises a silane coupling agent and colloidal silica.
  • the treatment liquid for improving the formability of the aluminum alloy material as described above (Claim 1 or 2)!
  • the aluminum alloy material forming processability improving treatment solution contains a heat resistance imparting agent (Claim 3), and
  • the heat resistance imparting agent is a siloxane compound (Claim 4).
  • a water-soluble urethane resin or a water-soluble polyester resin is preferably a water-soluble or water-dispersible resin.
  • the addition percentage of the organic resin is desirably in the range of 20 to 85% by weight. If it is less than 20% by weight, the formed organic resin film is undesirably easily damaged by processing. If it exceeds 85% by weight, there is no problem in characteristics, but it is not economical.
  • the processing temperature of the aluminum alloy material is preferably used at a temperature exceeding 150 ° C., it is preferable to use an organic resin having excellent heat resistance.
  • These resins may be used by coating the resin alone on the surface of the aluminum alloy material or the surface of the forming tool, and drying to form a film. Improves corrosion resistance when remaining on the surface of aluminum alloy material as a protective coating
  • the following substances may be used in the resin solution.
  • Silane coupling agents are classified according to the type of functional group such as bur, epoxy, styryl, methacryloxy, attaryloxy, amino, ureido, propyl propyl, mercapto and isocyanate. All can be used effectively.
  • the silane coupling agent has excellent binding properties, that is, adhesiveness to almost all of the resins.
  • epoxy-based silane coupling agent KBM403 is excellent in bonding with urethane and epoxy-based resins
  • amino-based silane coupling agent KBM903 is excellent in bonding with acrylic-based resins. Excellent adhesion.
  • the silane coupling agent is preferably contained in the resin film at 5% by weight or less, more preferably 1% by weight or less. Even if the content exceeds 5% by weight, the effect of improving the adhesion is saturated and the cost becomes not advantageous.
  • the inclusion of colloidal silica in the resin film increases the hardness of the resin film, thereby improving the scratch resistance of the aluminum alloy material and improving the corrosion resistance. It is preferable that the colloidal silica is contained at 50% by weight or less in the resin film. When the content exceeds 50% by weight, the resin film becomes too hard, and the processability of the resin film deteriorates, and when forming an aluminum alloy material having a resin film formed on the surface, the resin film is formed. Cracks are likely to occur.
  • Lubricants include higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, calcium salts of these higher fatty acids, aluminum salts, zinc salts, barium salts, magnesium salts, higher fatty acid esters thereof, Polyolefin waxes such as polyethylene wax and polypropylene wax, fluorinated waxes such as polytetrafluoroethylene, polytetrafluoroethylene, polyvinylidene fluoride and polyfluoride butyl, graphite, molybdenum disulfide, boron nitrile An inorganic powder such as an id can be used. These lubricants are preferably contained in the organic resin film at 20% by weight or less. When the content exceeds 20% by weight, the adhesiveness deteriorates even during the molding of the organic resin film on the magnesium
  • metal alkoxides include boron, aluminum, titanium, vanadium, manganese, iron, cobalt, copper, yttrium, zirconium, niobium, lanthanum, cerium, tantalum, and tungsten alkoxides. Can be preferably used. These metal alkoxides are preferably contained in the organic resin film at 10% by weight or less. When the content exceeds 10% by weight, the formability of the aluminum alloy material for forming work in which an organic resin film is formed on the aluminum alloy material is lowered.
  • the above silane coupling agent, colloidal silica, lubricant, and metal alkoxide are each contained alone as one kind in the organic resin film, and / or may be contained in two or more kinds.
  • the organic resin obtained as described above is applied to the surface of an aluminum alloy material and dried to form an organic resin film.
  • the thickness of the organic resin film is preferably 0.1 to 50; ⁇ ⁇ as the thickness after drying, and more preferably 1 to LO m.
  • the aluminum alloy material to which the treatment liquid for improving the moldability of the aluminum alloy material of the present invention is applied is, in particular, pure aluminum not containing an alloy element, or IS standard 1000 series, 2000 Aluminum alloy of any type, 3000 series, 5000 series, 6000 series, and 7000 series can be applied to any extruded material, cutting material, hot rolled material, etc. It can also be applied to difficult-to-cure materials such as magnesium alloys, titanium alloys, and stainless steel.
  • the treatment liquid for improving the moldability of the aluminum alloy material of the present invention is applied when the aluminum alloy material is subjected to a forming process such as drawing, forging, rolling, or press forging.
  • a forming process such as drawing, forging, rolling, or press forging.
  • the treatment liquid for improving the moldability of the aluminum alloy material according to the present invention is applied to the surface of the aluminum alloy material and dried to be used for these forming processes, the conventionally used lubricating oil or molybdenum disulfide molybdenum Suitable for molding without using solid lubricant such as can do.
  • the treatment liquid for improving the formability of the aluminum alloy material of the present invention is applicable to the case of forming at a cold working temperature, but particularly at a warm working temperature of 200 to 350 ° C.
  • Forming can be performed with a high degree of processing, and can be applied particularly favorably.
  • the organic resin film is decomposed and discolored or cracks are generated in the film, which deteriorates the appearance and makes it difficult to improve the drawing ratio. Therefore, by adding a heat resistance-imparting agent to the organic resin film that only improves the heat resistance of the organic resin alone, it can be used in a warm working temperature range of 200-350 ° C or lower.
  • the temperature can be lowered in a temperature range of 350 ° C or lower, and there is an advantage that unnecessary heat treatment is unnecessary. Of course, needless to say, it is not necessary to apply lubricant during molding.
  • a heat-resistant resin such as polyimide or a siloxane compound.
  • the siloxane compound include polymers and monomers of organosiloxanes such as dimethylsiloxane, jetylsiloxane, methylethylsiloxane, diphenylsiloxane, and methylphenylsiloxane, or polyalkyleneoxide groups, hydroxyl groups in these organosiloxane molecules.
  • An amide group, a carboxyl group, a sulfone group, and an amino group, those having one or more substituents of two or more are preferably used.
  • These heat resistance imparting agents are preferably contained in the organic resin film at 5 to 80% by weight, more preferably 10 to 60% by weight. In this way, by including a heat resistance imparting agent in the organic resin film, the aluminum alloy material for forming is heated to a warm working temperature range of 200 to 350 ° C., and a molding case is formed at a high degree of processing. Can be It becomes ability.
  • the heat resistance imparting agent may be contained alone in the organic resin, but may be contained in combination with one or more of the above silane coupling agent, colloidal silica, and lubricant. Good.
  • a coating solution for improving the moldability of the aluminum alloy material of the present invention is applied onto the surface of the aluminum alloy material and dried on the organic resin film obtained by drying. It is also possible to apply.
  • an aluminum alloy molded body may be formed by molding a coating material that has been pre-coated on the organic resin film formed on the aluminum alloy material for forming force as described above. .
  • the organic resin film is dissolved and removed using an alkaline solution, or removed using a shot blasting method in which abrasive particles are sprayed onto the surface, and an anodizing treatment or a surface treatment such as staking. Processing can also be performed.
  • the water-soluble rosin solution shown in Table 1 contains a silane coupling agent, colloidal silica, a lubricant, a metal alkoxide, and a heat resistance imparting agent in the contents shown in Table 1, and the aluminum shown in sample numbers 1 to 13 An alloy material forming processability improving treatment liquid was prepared.
  • an aluminum alloy material for forming force on both sides of an aluminum alloy plate (JIS 50 52 HI 9) with a thickness of 0.6 mm, for improving the forming force strength of aluminum alloy materials shown in Table Nos. 1 to 13 in Table 1.
  • the aluminum alloy material for forming shown in sample numbers 1 to 13 was subjected to drawing under the following conditions, and the limit drawing ratio was obtained. .
  • the processing temperature was the same for the die and the blank holder, and only the punch was at room temperature. ⁇ Punch shoulder R>
  • Lubricating oil and lubricant are not used for drawing of aluminum alloy materials for forming force indicated by sample numbers 1-13
  • sample No. 14 of the comparative example obtained by applying a commercially available plastic cask oil G3080 (manufactured by Nippon Tool Oil Co., Ltd.) to both sides of the above aluminum alloy material, and an aluminum alloy material
  • a sample having a fluororesin film with a thickness of 50 ⁇ m on both sides was drawn under the same conditions as Sample No. 15 of the comparative example, and the limit drawing ratio was determined.
  • the processing temperature is low, the workability is extremely inferior, and drawing is difficult. Drawing was performed only when the holder temperature was 200 ° C or higher.
  • the die temperature and blank holder temperature are 350 ° C, the fluorine resin film is severely damaged and difficult to draw. Therefore, drawing was performed only when the die temperature and blank holder temperature were 150-300 ° C.
  • F resin Fluorine resin ⁇ 7 rem 50 / m
  • an aluminum alloy for molding is formed by coating the aluminum alloy material with the treatment solution for improving the molding caloricity of the aluminum alloy material according to the present invention and coating it with an organic resin.
  • Alloy material has excellent workability, and significantly superior workability compared to the comparative example (sample No. 14) in which lubricating oil is applied to a conventional aluminum alloy plate and drawn. Indicates. Furthermore, since it has the best workability in the past, it was used mainly in research and development, and when compared with a comparative example (sample No. 15) using an expensive fluorocoagulant film as a lubricant, it was equivalent or better.
  • the aluminum alloy material forming processability improving liquid of the present invention is applied and dried. Therefore, the superiority of the molding method is clear. Furthermore, when a heat resistance imparting agent is included in the organic resin, drawing can be performed at a high temperature up to 350 ° C. When drawing at such a high temperature, the drawing ratio is as high as 4.0. It can be formed into an aluminum alloy molded body (drawn container) at a degree of processing.
  • An aluminum alloy material for forming which is formed by coating the surface of an aluminum alloy material with an organic resin obtained by applying the aluminum alloy material forming cacheability improving treatment liquid of the present invention and drying it. Can be molded with a high degree of processing. Especially when an organic resin contains a heat-resistance imparting agent such as a siloxane compound, it is excellent in the warm processing temperature range of 200 to 350 ° C. It has an excellent lubricating effect, and is used for automobile parts such as hoods, trunk lids, doors and fenders, small exterior cases for portable electronic devices such as mopile communication devices and laptop computers, travel suitcases, and attachments for storing documents. It can be suitably applied to a container such as a large case such as a case, and particularly to an aluminum alloy molded body such as a drawn container that is drawn at a high working degree with a drawing ratio of 4.0 or less.
  • a container such as a large case such as a case
  • an aluminum alloy molded body such as a drawn container that is drawn at

Abstract

L'invention concerne un liquide de traitement destiné à améliorer la formabilité de matériaux d'alliage d'aluminium, qui forme un film de revêtement lorsqu'il est appliqué sur la surface d'un matériau d'alliage d'aluminium, puis séché. Ledit film de revêtement recouvrant le matériau d'alliage d'aluminium présente d'excellents effets lubrifiants lorsque ledit matériau d'alliage d'aluminium revêtu est soumis à un processus de formage. Plus précisément, l'invention concerne un liquide de traitement destiné à améliorer la formabilité de matériaux d'alliage d'aluminium, qui contient une résine d'uréthane hydrosoluble, une résine de polyester hydrosoluble, une résine acrylique hydrosoluble, une résine époxyde hydrosoluble, et une ou plusieurs résines obtenue par modification de ces résines organiques. Ledit liquide de traitement peut en outre contenir, outre lesdites résines, un agent de couplage au silane, une silice colloïdale, un lubrifiant, un alcoxyde de métal, un agent conférant une résistance thermique et analogues.
PCT/JP2006/319059 2005-10-03 2006-09-26 Liquide de traitement pour ameliorer la formabilite de materiau d'alliage d'aluminium WO2007040096A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006534522A JPWO2007040096A1 (ja) 2005-10-03 2006-09-26 アルミニウム合金材成形加工性向上用処理液

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005289482 2005-10-03
JP2005-289482 2005-10-03

Publications (1)

Publication Number Publication Date
WO2007040096A1 true WO2007040096A1 (fr) 2007-04-12

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JP (1) JPWO2007040096A1 (fr)
WO (1) WO2007040096A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015054422A (ja) * 2013-09-11 2015-03-23 株式会社Uacj プレコートアルミニウム合金板及びプレス成型品の製造方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06207189A (ja) * 1992-04-03 1994-07-26 Sky Alum Co Ltd プレス加工用固体潤滑膜塗布アルミニウム板
JPH1088364A (ja) * 1996-09-13 1998-04-07 Sumitomo Light Metal Ind Ltd 脱膜型潤滑処理アルミニウム板およびその製造方法
JPH10114012A (ja) * 1996-10-15 1998-05-06 Sumitomo Metal Ind Ltd 耐キズつき性と脱膜性に優れた表面潤滑処理金属材
JPH1150083A (ja) * 1997-07-30 1999-02-23 Sugimura Kagaku Kogyo Kk 金属塑性加工用潤滑剤
JP2000052485A (ja) * 1998-06-02 2000-02-22 Toyo Kohan Co Ltd 加工性、耐疵付き性および耐食性に優れた表面処理金属板およびその製造方法
JP2004083781A (ja) * 2002-08-28 2004-03-18 Yushiro Chem Ind Co Ltd 金属材料の塑性加工用水系潤滑剤組成物
JP2004338218A (ja) * 2003-05-15 2004-12-02 Mitsubishi Steel Mfg Co Ltd 複合材料及びそれを用いた塑性加工品
JP2006052382A (ja) * 2004-07-15 2006-02-23 Toyo Kohan Co Ltd 金属板成形加工性向上用処理液
JP2006051801A (ja) * 2004-07-15 2006-02-23 Toyo Kohan Co Ltd 成形加工用マグネシウム合金板、マグネシウム合金容器およびマグネシウム合金容器の製造方法
JP2006218523A (ja) * 2005-02-14 2006-08-24 Toyo Kohan Co Ltd 成形加工用マグネシウム合金板の圧延方法および加工方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06207189A (ja) * 1992-04-03 1994-07-26 Sky Alum Co Ltd プレス加工用固体潤滑膜塗布アルミニウム板
JPH1088364A (ja) * 1996-09-13 1998-04-07 Sumitomo Light Metal Ind Ltd 脱膜型潤滑処理アルミニウム板およびその製造方法
JPH10114012A (ja) * 1996-10-15 1998-05-06 Sumitomo Metal Ind Ltd 耐キズつき性と脱膜性に優れた表面潤滑処理金属材
JPH1150083A (ja) * 1997-07-30 1999-02-23 Sugimura Kagaku Kogyo Kk 金属塑性加工用潤滑剤
JP2000052485A (ja) * 1998-06-02 2000-02-22 Toyo Kohan Co Ltd 加工性、耐疵付き性および耐食性に優れた表面処理金属板およびその製造方法
JP2004083781A (ja) * 2002-08-28 2004-03-18 Yushiro Chem Ind Co Ltd 金属材料の塑性加工用水系潤滑剤組成物
JP2004338218A (ja) * 2003-05-15 2004-12-02 Mitsubishi Steel Mfg Co Ltd 複合材料及びそれを用いた塑性加工品
JP2006052382A (ja) * 2004-07-15 2006-02-23 Toyo Kohan Co Ltd 金属板成形加工性向上用処理液
JP2006051801A (ja) * 2004-07-15 2006-02-23 Toyo Kohan Co Ltd 成形加工用マグネシウム合金板、マグネシウム合金容器およびマグネシウム合金容器の製造方法
JP2006218523A (ja) * 2005-02-14 2006-08-24 Toyo Kohan Co Ltd 成形加工用マグネシウム合金板の圧延方法および加工方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015054422A (ja) * 2013-09-11 2015-03-23 株式会社Uacj プレコートアルミニウム合金板及びプレス成型品の製造方法

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