WO2006133677A1 - Alkalistabile sol-gel-bechichtung - Google Patents
Alkalistabile sol-gel-bechichtung Download PDFInfo
- Publication number
- WO2006133677A1 WO2006133677A1 PCT/DE2006/001002 DE2006001002W WO2006133677A1 WO 2006133677 A1 WO2006133677 A1 WO 2006133677A1 DE 2006001002 W DE2006001002 W DE 2006001002W WO 2006133677 A1 WO2006133677 A1 WO 2006133677A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- alkali
- alkoxides
- coating according
- stable
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
Definitions
- the invention relates to an alkali-stable sol-gel coating, to a process for producing an alkali-stable sol-gel coating and to the use thereof.
- DE 40 25 215 C2 describes the preparation of alkali-stable abrasion-resistant coatings. It describes the preparation of coating materials via the reaction of silanes containing non-hydrolyzable primary, secondary and / or tertiary amino groups with organic epoxides.
- the coating solutions must have at least one component with amino groups on the nonhydrolyzable part and a component with at least two epoxy groups.
- the alkali resistance in the dishwasher test (stored for 2 h in 3% solution of Somat) showed no shift change.
- siloxane KatZWasser Intermediate Silanol Cat
- the siloxane bond hydrolyzes in the alkaline medium under the catalytic influence of hydroxide ions to silanols. As a result, the inorganic polymer network and thus the coating is destroyed.
- the object of the invention is therefore to provide an alkali-stable sol-gel coating.
- condensation catalyst based on a.) secondary or tertiary bases (for example amino, mercaptosilanes) and / or b.) Lewis acids as metal alkoxides such as aluminum alkoxides,
- sol-gel systems based on silanes without organically functional side chain (MTEOS and higher-chain alkylsilanes to C30, TEOS) by condensation catalysts based on
- secondary or tertiary bases e.g., amino, mercaptosilanes
- tertiary bases e.g., amino, mercaptosilanes
- Lewis acids such as aluminum alkoxides, zirconium alkoxides, titanium alkoxides have significantly improved alkali stability, i. that even with 200 to 300 dishwasher cycles no failure is given.
- the required drying temperature of the coatings can be significantly reduced, for example transparent coatings can be produced which are used in drying Temperatures between 60 and 8O 0 C already good to very good adhesion and abrasion resistance on PVC, polycarbonate or other common plastics show. Depending on the application, the thickness of the applied layers is between 0.01 ⁇ m and 20 ⁇ m.
- the curing catalysts can either be added directly at the beginning of the sol-gel synthesis, or they can be added subsequently to the final coating solution.
- pot-life-resistant multicomponent coatings for example 2-component systems with binder and curing component.
- pigments or fillers can also be dispersed as desired.
- customary paint additives for example Byk additive for surface development / leveling or substrate wetting, pigment wetting
- paint practice as required.
- a development of the invention is that the coating with a solvent, in particular with water, to a solids content of more than 0.05 wt .-% and less than 20 wt .-% is diluted.
- a part of the alkoxysilanes is fluorinated or contains a hydrophilic side chain, in particular polyether.
- the metal alkoxides are preferably aluminum and zirconium alkoxides.
- the bases are silanes with a secondary amino group.
- the coating contains nanoparticles, in particular SiO 2 nanoparticles.
- the silane is hydrolyzed with the addition of acid and immediately after the hydrolysis up to Ih hydrolysis time, the catalyst is added. It is envisaged that the coating is carried out by rolling, flooding, spray painting, electrostatic spraying, spin coating, dipping or wiping.
- An embodiment of the invention is that the curing of the coating at room temperature (RT) to 1.200 0 C takes place.
- the coating is applied as a primer or as a thin layer with up to 3 micron layer thickness on the object to be coated.
- the coating according to the invention as a primer for hydrophobic coatings or photocatalytically active particles, Antikalk füren on chrome surfaces, stainless steel surfaces, PVC or polyester.
- the coating according to the invention as a base system for Antif ⁇ ngerprint-, photocatalytic, anti-scale coatings, matting agents, color pigments, leveling agents, for the impregnation of textiles, leather, paper or as a binder or additive for paint systems or polymers within the scope of the invention.
- the invention also includes the use of the coating according to the invention on household utensils, household appliances, kitchens and sanitary equipment, textiles, in particular pots, pans, housings of all kinds, fittings, covers, moldings, towel holders, paper dispensers, hand dryers, soap dispensers, shower heads, mirror frames, bathtubs. and washbasin closures, shower rods, shower panels, bathroom furniture, slats, PVC profiles (window frames, doors, conservatories), facade elements, shutter boxes, blinds, textiles, in particular technical fabrics, such as awnings, tent roofs and tarpaulins or (clothing) fabrics.
- the invention will be explained below with reference to exemplary embodiments.
- Primer 20.8 g of TEOS are stirred with 14.4 g of 0.1% H 2 SO 4 for 1.5 h (single-phase). Then is diluted with butyl glycol to 1% solids and treated with 1.2 g of N-methylaminopropyltrimethoxysilane.
- the primer On the cleaned chrome surface, the primer is sprayed on first. After 5 minutes (flash off), the functional layer is sprayed on. It is cured at 80 C for 20 minutes.
- the layer shows a clear beading behavior and a contact angle with water of 110 °.
- Kaikabgraphy is greatly facilitated by the coating.
- the coating also shows after two hours of storage in boiling dishwasher (10% Alio solution, pH 11.5) nor a contact angle greater than 100 ° and low adhesion to limescale.
- Primer 20.8 g of TEOS are stirred with 7.2 g of 1% H 2 SO 4 for Ih. Then it is diluted with demi water to 1% solids and treated with 1.4 g of 3-aminopropyltrimethoxysilane.
- the primer is sprayed on first. After 5 minutes (flash off), the functional layer is sprayed on. It is cured for 180 minutes at RT. Results: Compared to water, the layer shows a clear beading behavior and a contact angle with water of 105 °. Kaikabgraphy is greatly facilitated by the coating. Even after one hour of immersion in boiling dishwashing liquor (10% strength Alio solution, pH 11.5), the coating still shows a contact angle greater than 100 ° and low adhesion to limescale.
- the coated stainless steel samples show a clear beading behavior compared to water and a contact angle against water of more than 90 °.
- the coated samples show Antifmge ⁇ rinteigenschaften, ie applied fingerprints leave even after several hours no blue tarnishing traces and are therefore hardly noticeable on the surface.
- the fingerprints can be easily removed with a dry paper or cotton cloth. After boiling in tap water for 8 hours, no change in layer (turbidity, peeling, ...) can be detected. Limestone residues cooked on the surface can easily be removed with an acid surfactant cleaner.
- the samples were boiled for 8 h in dishwasher lye (10% Ali solution, pH 11.5) for the rapid test.
- Example 4 the coated samples were cleaned in a household dishwasher under standard conditions over a period of 300 program cycles. After none of the two test methods, a detachment or attack of the coating can be determined. The above-mentioned anti-fingerprint effect also remains.
- Example 4
- the solution is spray-coated onto PVC plan substrates and to polyester-topcoated metal panels, allowed to flash for 10 minutes and then dried for one hour at 7O 0 C in a convection oven.
- the coatings in each case show good adhesion and water storage stability (24-hour storage in demiwater at RT with subsequent adhesion test without complaint). In the QUV-A test, no yellowing or delamination of the coating can be detected after 500 hours.
- the coating exhibits good UV weatherability and can be used e.g. be used as a barrier layer system for the application of a photocatalytically active titanium oxide self-cleaning layer. Will be in o.g. Example 4 instead of N-butylaminolpropyltrimethoxysilane a propyltrimethoxysilane used, so at least curing temperatures of 130 ° C are necessary to achieve similar good mechanical and chemical resistance on the plastic substrates.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06742406A EP1891176A1 (de) | 2005-06-15 | 2006-06-12 | Alkalistabile sol-gel-bechichtung |
CA002611868A CA2611868A1 (en) | 2005-06-15 | 2006-06-12 | Alkali-stable sol-gel coating |
JP2008516118A JP2008543994A (ja) | 2005-06-15 | 2006-06-12 | アルカリ耐性ゾル−ゲルコーティング |
US11/922,297 US20090238986A1 (en) | 2005-06-15 | 2006-06-12 | Alkali-Resistant Sol-Gel Coating |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005027789A DE102005027789A1 (de) | 2005-06-15 | 2005-06-15 | Alkalistabile Sol-Gel-Beschichtung |
DE102005027789.6 | 2005-06-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006133677A1 true WO2006133677A1 (de) | 2006-12-21 |
Family
ID=36954911
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2006/001002 WO2006133677A1 (de) | 2005-06-15 | 2006-06-12 | Alkalistabile sol-gel-bechichtung |
Country Status (8)
Country | Link |
---|---|
US (1) | US20090238986A1 (de) |
EP (1) | EP1891176A1 (de) |
JP (1) | JP2008543994A (de) |
KR (1) | KR20080022577A (de) |
CN (1) | CN101218317A (de) |
CA (1) | CA2611868A1 (de) |
DE (1) | DE102005027789A1 (de) |
WO (1) | WO2006133677A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008155453A1 (en) * | 2007-06-20 | 2008-12-24 | Valtion Teknillinen Tutkimuskeskus | Coating and method for producing same |
DE102011077021A1 (de) * | 2011-06-07 | 2012-12-13 | Schaeffler Technologies AG & Co. KG | Beschichtungsverfahren für ein Kolben- oder Lager-Bauteil |
US8399575B2 (en) | 2007-09-03 | 2013-03-19 | Wacker Chemie Ag | Crosslinkable materials based on organosilicon compounds |
EP3290487A4 (de) * | 2015-04-30 | 2019-01-09 | Lintec Corporation | Bewuchshemmende zusammensetzung, bewuchshemmende folie und verfahren zur herstellung einer bewuchshemmenden folie |
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DE102007034633A1 (de) † | 2007-04-05 | 2009-01-29 | Nano-X Gmbh | Beschichtungsmaterial mit einer katalytischen Aktivität und Verwendung des Beschichtungsmaterials |
DE102007016946A1 (de) * | 2007-04-05 | 2008-10-09 | Nano-X Gmbh | Beschichtungsmaterial mit einer katalytischen Aktivität und Verwendung des Beschichtungsmaterials |
WO2009059798A2 (en) * | 2007-11-08 | 2009-05-14 | Corus Uk Limited | A method for producing a coating on a metal substrate and a coating produced thereby |
US8709545B2 (en) * | 2009-01-30 | 2014-04-29 | The Boeing Company | Hybrid coatings and associated methods of application |
DE102009008144A1 (de) * | 2009-02-09 | 2010-08-19 | Nano-X Gmbh | Verfahren zur Herstellung von Alkali- und Erdalkalilegierungen und Verwendung der Alkali- und Erdalkalilegierungen |
CN101775124B (zh) * | 2010-02-11 | 2012-07-25 | 东华大学 | 耐磨抗刮稳定透明聚酯涂料基体的制备方法 |
CN104395327B (zh) * | 2012-07-05 | 2017-06-23 | 日本曹达株式会社 | 有机硅化合物、使用其的薄膜形成用组合物以及有机薄膜 |
CN105531337B (zh) | 2013-09-16 | 2020-01-10 | 霍尼韦尔国际公司 | 含氟聚硅氧烷涂料 |
JP5724021B1 (ja) * | 2014-06-25 | 2015-05-27 | アイシン軽金属株式会社 | 高耐アルカリ性アルミニウム部材及びその製造方法 |
ES2597749B1 (es) * | 2015-07-20 | 2017-12-26 | Bsh Electrodomésticos España, S.A. | Componente de aparato doméstico que comprende un elemento base con un recubrimiento funcional |
US10128388B2 (en) | 2015-11-17 | 2018-11-13 | King Fahd University Of Petroleum And Minerals | Methods for treating a polycarbonate glass surface and forming directed hierarchical nanopatterning and increasing hydrophobicity |
JP6662001B2 (ja) * | 2015-11-27 | 2020-03-11 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質とその製造方法、被覆液の製造方法 |
KR101640727B1 (ko) * | 2016-02-04 | 2016-07-18 | 세진산업 (주) | 내화학성 및 방수성이 우수한 맥반석 판재의 제조방법 |
FR3061724B1 (fr) | 2017-01-06 | 2021-07-16 | Commissariat Energie Atomique | Procede de revetement de materiaux textiles |
ES2682687B1 (es) * | 2017-03-21 | 2019-08-12 | Bsh Electrodomesticos Espana Sa | Método para recubrir un elemento base para un componente de aparato doméstico, y componente de aparato doméstico |
CN110054986A (zh) * | 2018-01-19 | 2019-07-26 | 四川铁创科技有限公司 | 一种高铁隧道排水暗管用防钙盐沉积涂料及其制备方法 |
WO2020165032A1 (en) * | 2019-02-13 | 2020-08-20 | Chemetall Gmbh | Improved method for applying silane-based coatings on solid surfaces, in particular on metal surfaces |
GB202104385D0 (en) * | 2020-11-27 | 2021-05-12 | Milliery Manuel | A sol-gel coating to give coated substrates barrier properties and method of applications thereof |
WO2022139220A1 (ko) * | 2020-12-23 | 2022-06-30 | 주식회사 엘지화학 | 광학 적층체 및 이를 포함하는 플렉서블 디스플레이 장치 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0471301A2 (de) * | 1990-08-09 | 1992-02-19 | Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. | Verfahren zur Herstellung eines alkalistabilen und abriebbeständigen Überzugs und Lack zur Verwendung in diesem Verfahren |
EP1484372A1 (de) * | 2003-06-05 | 2004-12-08 | Cofresco Frischhalteprodukte GmbH & Co. KG | Beschichtungsmaterial, Beschichtung und Aluminiumfolie |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3925901C1 (de) * | 1989-08-04 | 1990-11-29 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | |
DE10151264A1 (de) * | 2001-10-17 | 2003-04-30 | Degussa | Aminoalkylalkoxysiloxanhaltige Gemische, deren Herstellung und deren Verwendung |
DE10212523A1 (de) * | 2002-03-21 | 2003-10-02 | Degussa | Lufttrocknende, silanhaltige Beschichtungsmittel |
DE10227759A1 (de) * | 2002-06-21 | 2004-01-22 | Koenig & Bauer Ag | Verfahren zum Behandeln der Mantelflächen von Druckzylindern |
DE10320765A1 (de) * | 2003-05-09 | 2004-11-25 | Degussa Ag | Mittel zur Beschichtung von Metallen zum Schutz vor Korrosion |
DE10321799A1 (de) * | 2003-05-14 | 2004-12-16 | Röhm GmbH & Co. KG | Beschichtungsmittel und Kunststoffkörper mit Antigraffiti-Wirkung sowie Verfahren zur Herstellung |
-
2005
- 2005-06-15 DE DE102005027789A patent/DE102005027789A1/de not_active Ceased
-
2006
- 2006-06-12 EP EP06742406A patent/EP1891176A1/de not_active Withdrawn
- 2006-06-12 CN CNA2006800247667A patent/CN101218317A/zh active Pending
- 2006-06-12 CA CA002611868A patent/CA2611868A1/en not_active Abandoned
- 2006-06-12 WO PCT/DE2006/001002 patent/WO2006133677A1/de active Application Filing
- 2006-06-12 US US11/922,297 patent/US20090238986A1/en not_active Abandoned
- 2006-06-12 KR KR1020087001043A patent/KR20080022577A/ko not_active Application Discontinuation
- 2006-06-12 JP JP2008516118A patent/JP2008543994A/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0471301A2 (de) * | 1990-08-09 | 1992-02-19 | Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. | Verfahren zur Herstellung eines alkalistabilen und abriebbeständigen Überzugs und Lack zur Verwendung in diesem Verfahren |
EP1484372A1 (de) * | 2003-06-05 | 2004-12-08 | Cofresco Frischhalteprodukte GmbH & Co. KG | Beschichtungsmaterial, Beschichtung und Aluminiumfolie |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008155453A1 (en) * | 2007-06-20 | 2008-12-24 | Valtion Teknillinen Tutkimuskeskus | Coating and method for producing same |
US8399575B2 (en) | 2007-09-03 | 2013-03-19 | Wacker Chemie Ag | Crosslinkable materials based on organosilicon compounds |
DE102011077021A1 (de) * | 2011-06-07 | 2012-12-13 | Schaeffler Technologies AG & Co. KG | Beschichtungsverfahren für ein Kolben- oder Lager-Bauteil |
EP3290487A4 (de) * | 2015-04-30 | 2019-01-09 | Lintec Corporation | Bewuchshemmende zusammensetzung, bewuchshemmende folie und verfahren zur herstellung einer bewuchshemmenden folie |
Also Published As
Publication number | Publication date |
---|---|
US20090238986A1 (en) | 2009-09-24 |
CA2611868A1 (en) | 2006-12-21 |
CN101218317A (zh) | 2008-07-09 |
JP2008543994A (ja) | 2008-12-04 |
EP1891176A1 (de) | 2008-02-27 |
DE102005027789A1 (de) | 2006-12-21 |
KR20080022577A (ko) | 2008-03-11 |
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