WO2006121100A1 - メタクリル酸製造用触媒の製造方法 - Google Patents
メタクリル酸製造用触媒の製造方法 Download PDFInfo
- Publication number
- WO2006121100A1 WO2006121100A1 PCT/JP2006/309452 JP2006309452W WO2006121100A1 WO 2006121100 A1 WO2006121100 A1 WO 2006121100A1 JP 2006309452 W JP2006309452 W JP 2006309452W WO 2006121100 A1 WO2006121100 A1 WO 2006121100A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- producing
- antimony
- methacrylic acid
- slurry
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 83
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000002002 slurry Substances 0.000 claims abstract description 36
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 26
- 239000000843 powder Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000000465 moulding Methods 0.000 claims abstract description 19
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 15
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 15
- 239000011733 molybdenum Substances 0.000 claims abstract description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 14
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 14
- 239000011574 phosphorus Substances 0.000 claims abstract description 14
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 13
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 13
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 29
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims description 19
- 239000004480 active ingredient Substances 0.000 claims description 17
- 238000001354 calcination Methods 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 13
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- 230000003197 catalytic effect Effects 0.000 claims description 11
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000010304 firing Methods 0.000 abstract description 14
- 239000008187 granular material Substances 0.000 description 33
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000002253 acid Substances 0.000 description 17
- 239000007789 gas Substances 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 238000005259 measurement Methods 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 239000011964 heteropoly acid Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 235000011007 phosphoric acid Nutrition 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229960004643 cupric oxide Drugs 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229940076286 cupric acetate Drugs 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
- 239000005695 Ammonium acetate Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000019257 ammonium acetate Nutrition 0.000 description 2
- 229940043376 ammonium acetate Drugs 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- UIJPVZABWOBESM-UHFFFAOYSA-N [V].[Ru] Chemical compound [V].[Ru] UIJPVZABWOBESM-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- -1 cesium compound Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- RFKZUAOAYVHBOY-UHFFFAOYSA-M copper(1+);acetate Chemical compound [Cu+].CC([O-])=O RFKZUAOAYVHBOY-UHFFFAOYSA-M 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002036 drum drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012210 heat-resistant fiber Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- ROVRDARYJMRLLE-UHFFFAOYSA-N oxo(oxomolybdeniooxy)molybdenum Chemical compound O=[Mo]O[Mo]=O ROVRDARYJMRLLE-UHFFFAOYSA-N 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000013076 target substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Definitions
- the present invention uses a heteropolyacid catalyst having high activity, high selectivity, and sufficient mechanical strength to convert methacroleic acid, isobutyraldehyde or isobutyric acid into gas phase catalytic acid.
- the present invention relates to a method for producing a catalyst for production.
- catalysts have been proposed as a catalyst used for producing methacrylic acid by gas phase catalytic oxidation of methacrolein, isobutyraldehyde or isobutyric acid. Most of these catalysts are mainly composed of molybdenum and phosphorus, and have a structure of heteropolyacid and Z or a salt thereof. Heteropolyacid catalysts have problems such as poor moldability and low mechanical strength of the molded catalyst.
- Patent Document 1 proposes a method of mixing and molding heat-resistant fibers such as ceramic fibers as a strength improver.
- Patent Document 2 proposes a method in which an oxide precursor and an oxide are mixed and molded in a catalyst containing molybdenum and phosphorus as essential components.
- Patent Document 1 Japanese Patent Publication No. 2-36296
- Patent Document 2 Japanese Patent Application Laid-Open No. 2004-351297
- the mechanical strength is not sufficient as an industrial catalyst, and the yield during production is poor due to the poor moldability. There is a problem that the manufacturing cost is increased. Further, if the mechanical strength is weak, the active component may be peeled off when the catalyst is filled in the reaction tube, and the required performance may not be obtained, so further improvement is required. ing. [0005] Further, the performance of the currently proposed catalyst for producing methacrylic acid is known as a reaction similar to the gas phase catalytic acid-catalyzed reaction of methacrolein, isobutyraldehyde or isobutyric acid.
- a method for producing a catalyst for methacrylic acid production characterized in that the mixture obtained by drying and then calcining a mixture obtained by mixing the dry powder obtained in the above and a compound containing antimony, and molding the mixture,
- a method for producing a catalyst for methacrylic acid production characterized by calcining the obtained dry powder and molding a mixture obtained by mixing the calcined powder and a compound containing antimony, (4) The method for producing a catalyst according to any one of (1) to (3) above, wherein the calcination temperature is 200 to 450 ° C,
- Process power for molding powder after firing One of the above (1) to (4), characterized in that it is a process of coating on an inert carrier using S binder to form a coated catalyst.
- a method for producing the catalyst described in item 1 is a method for producing the catalyst described in item 1,
- a catalyst having high activity, high selectivity, high mechanical strength comprising molybdenum, phosphorus, vanadium, cesium, ammonia, copper, and antimony as essential components.
- the production method of the present invention comprises an aqueous solution containing a compound containing an active component of a catalyst (molybdenum, phosphorus, vanadium, cesium, ammonia, copper and antimony; hereinafter referred to as essential components); It includes a step of preparing an aqueous dispersion (hereinafter referred to as “slurry together”), baking the dried powder obtained (hereinafter referred to as “pre-baking”), and then molding. It becomes. It should be noted that a firing step (main firing) may be provided after the molding step.
- the compound containing an active ingredient in preparing the slurry is
- a metal element other than essential components may be further contained as an active component.
- Metal elements other than essential components include arsenic, silver, manganese, zinc, aluminum Group power consisting of nickel, cerium, thorium, potassium, rubidium, etc., and one or more selected from the group consisting of nickel, cerium, chromium, rhenium, bismuth, tungsten, iron, conoleto .
- the active ingredient-containing compound is used in an atomic ratio such that vanadium is usually 0.1 or more and 6 or less, preferably 0.3 or more and 2.0 or less, with respect to molybdenum 10.
- Lin is usually 0.5 or more and 6 or less, preferably 0.7 or more and 2.0 or less
- cesium is usually 0.01 or more and 4.0 or less, preferably 0.1 or more and 2.0 or less
- ammonia (Usually contained as an ammonium group) is usually 0.1 or more and 10.0 or less, preferably 0.5 or more and 5.0 or less
- antimony is usually 0.01 or more and 5 or less, preferably 0. 05 or more and 2.0 or less.
- the types of other active ingredients to be used and the use ratio thereof are appropriately determined according to the use conditions of the catalyst so that a catalyst exhibiting optimum performance can be obtained.
- the atomic ratio (composition) of the catalyst described in the present invention is the value at the raw material charging stage, excluding oxygen.
- examples of the active ingredient-containing compound used for catalyst preparation include chlorides, sulfates, nitrates, oxides or acetates of active ingredient elements.
- Specific examples of preferred compounds include nitrates such as potassium nitrate and cobalt nitrate, molybdenum oxides, vanadium pentoxide, antimony trioxide, cerium oxide, zinc oxide, and acid oxides such as germanium oxide, orthophosphoric acid, Examples thereof include acids (or salts thereof) such as phosphoric acid, boric acid, aluminum phosphate or 12 tandulinic acid.
- cesium acetate or cesium hydroxide and cesium weak acid salt as the cesium compound
- ammonium acetate or ammonium hydroxide as the ammonium compound
- copper acetate cuprous acetate, cupric acetate, basic copper acetate or cupric oxide, preferably cupric acetate
- copper oxide cuprous oxide, cupric oxide
- active ingredient-containing compounds may be used alone or in combination of two or more. The slurry can be obtained by uniformly mixing each active ingredient-containing compound and water.
- the order of addition of the active ingredient-containing compound when preparing the slurry is that the compound containing molybdenum, vanadium, phosphorus and, if necessary, other metal elements is sufficiently dissolved, and then the cesium-containing compound and the ammonia-containing compound are contained. It is preferable to add a compound and a copper-containing compound.
- an antimony-containing compound when adding an antimony-containing compound during slurry preparation, it is preferably added last among the essential active ingredient-containing compounds, but more preferably after obtaining a slurry containing an active ingredient other than the antimony-containing compound.
- the powder is then dried and mixed with the antimony-containing compound and then fired, or the powder is fired and then the antimony-containing compound is mixed.
- the slurry is preferably heated to a temperature at which the compound containing molybdenum, phosphorus, vanadium, and, if necessary, other metal elements can be sufficiently dissolved.
- the temperature at which the cesium-containing compound and the ammonia-containing compound are added is usually 0 to 35 ° C, preferably 10 to 30 ° C. Therefore, it is preferable to cool to 10 to 30 ° C.
- the amount of water used in the slurry is not particularly limited as long as it is capable of completely dissolving the total amount of the compound to be used or can be mixed uniformly. It is. Usually, it is about 200 to 2000 parts by mass with respect to 100 parts by mass of the total mass of the compound for slurry preparation. The amount of water may be large, but if it is too large, the energy cost of the drying process becomes high, and there are many disadvantages such as the case where it cannot be completely dried.
- the slurry obtained above is dried to obtain a dry powder.
- the drying method is not particularly limited as long as the slurry can be completely dried. Examples thereof include drum drying, freeze drying, spray drying, and evaporation to dryness. Among these, in the present invention, spray drying is particularly preferable because the slurry state force can be dried into powders or granules in a short time.
- the drying temperature of spray drying varies depending on the slurry concentration, liquid feeding speed, etc., but the temperature at the outlet of the dryer is generally 70 to 150 ° C. Moreover, it is preferable to dry so that the average particle diameter of the dried slurry obtained at this time becomes 30 to 700 ⁇ m.
- Pre-baking Preliminary firing of the obtained dry powder significantly improves the moldability, the shape of the molded catalyst, and the mechanical strength.
- the preliminary firing atmosphere may be an air stream or an inert gas stream such as nitrogen, but industrially, an air stream is preferred.
- the pre-baking temperature is 200 to 400 ° C, preferably 250 to 380 ° C, more preferably 290 to 310 ° C. Even if pre-calcined at a temperature lower than 200 ° C, the effect on moldability tends to be reduced, and if it exceeds 400 ° C, the catalyst performance may be adversely affected.
- the pre-baking time is preferably 3 to 12 hours, more preferably 5 to LO time. Although it can be fired for more than 12 hours, it is difficult to obtain the appropriate effect.
- the present inventors generally do not use the heteropolyacid partially neutralized salt such as the catalyst in the case where the slurry is only dried. This structure is called a Keggin-type structure when heated, and I believe that this transition may lead to improved moldability.
- the obtained pre-fired granule is molded as follows, but it is preferable to mix molding aids such as silica gel, diatomaceous earth, alumina powder and the like to improve workability.
- molding adjuvant is 1-30 mass parts normally with respect to 100 mass parts of prebaked granule.
- inorganic fibers such as ceramic fibers and whiskers that are inert to the catalyst component as necessary.
- fibers that react with catalyst components such as potassium titanate whiskers and basic magnesium carbonate whiskers are not preferred.
- the amount of these fibers used is usually 1 to 30 parts by mass with respect to 100 parts by mass of the pre-fired granules.
- the pre-fired granule obtained as described above or a mixture obtained by mixing this with a molding aid and a strength-improving material has a columnar shape, a tablet, a ring shape in order to reduce the pressure loss of the reaction gas. It is molded into a spherical shape and used. Among these, it is particularly preferable to coat the inert carrier with pre-calcined granules or a mixture to obtain a coated catalyst since improvement in selectivity and removal of reaction heat can be expected.
- the rolling step is preferably the rolling granulation method described below.
- a disk is rotated at high speed in an apparatus having a flat or uneven disk at the bottom in a fixed container.
- the carrier in the container is vigorously agitated by repeated rotation and revolution, and the binder and the pre-fired granule or mixture are added thereto to coat the carrier with the pre-fired granule or mixture. .
- the binder can be added by 1) pre-mixing the pre-baked granules or mixture 2) adding the pre-baked granules or mixture to the fixed container at the same time, 3) placing the pre-baked granules or mixture in the fixed container 4) Add before adding the pre-baked granule or mixture into the fixed container, 5) Divide the pre-baked granule or mixture and the binder, respectively, and combine 2) to 4) as appropriate.
- a method of adding the whole amount can be arbitrarily adopted.
- the pre-fired granule or mixture is added to the fixed container wall, and the pre-fired granule or mixture is not agglomerated and added using an auto feeder or the like so that a predetermined amount is supported on the carrier. I prefer to adjust the speed.
- the binder is not particularly limited as long as it is at least one liquid selected from the group consisting of water and Z or an organic compound having a boiling point of 150 ° C or less at 1 atm. However, drying after coating is not limited. In view of the above, an organic compound having a boiling point of 150 ° C. or lower is preferable.
- Specific examples of binders other than water include alcohols such as methanol, ethanol, propanols and butanols, preferably alcohols having 1 to 4 carbon atoms, ethers such as ethyl ether, butyl ether or dioxane, ethyl acetate or butyl acetate.
- binders examples thereof include ketones such as esters, acetone or methyl ethyl ketone, and aqueous solutions thereof. Ethanol is particularly preferable.
- ethanol Z water 10 ZO to OZlO (mass ratio), preferably 10ZO to lZ9 (mass ratio) is preferable.
- the amount of these binders used is usually 10 to 60 parts by mass, preferably 15 to 40 parts by mass with respect to 100 parts by mass of the dry powder.
- the force to coat the pre-baked granules or the mixture on the carrier in this way is usually about 3 to 15 mm in diameter.
- the coated catalyst obtained as described above can be directly used as a catalyst for a gas phase catalytic acid-oxidation reaction.
- catalyst activity may be improved, which is preferable.
- the firing temperature is usually 100 to 450 ° C, preferably 270 to 420 ° C, and the firing time is 1 to 20 hours.
- the firing is usually performed in an air atmosphere, it may be performed in an inert gas atmosphere such as nitrogen, or after the firing in an inert gas atmosphere, if necessary, the air atmosphere may be further increased. Bake under the air.
- the catalyst obtained as described above (hereinafter referred to as the catalyst of the present invention) is used for the production of methacrylic acid by gas-phase catalytic oxidation of methacrolein, isobutyraldehyde or isobutyric acid.
- molecular oxygen or a molecular oxygen-containing gas is used for the gas phase catalytic oxidation reaction.
- the molar ratio of molecular oxygen to methacrolein is preferably in the range of 0.5 to 20, particularly preferably in the range of 1 to LO.
- water is preferably added to the raw material gas in a molar ratio of 1 to 20 with respect to methacrolein.
- the raw material gas may contain oxygen and, if necessary, water (usually included as water vapor), a gas inert to the reaction such as nitrogen, carbon dioxide, saturated hydrocarbon, and the like.
- a gas obtained by acidifying isobutylene, tertiary butanol and methyl tertiary butyl ether may be supplied as it is.
- the reaction temperature in the gas phase catalytic oxidation reaction is usually 200 to 400 ° C, preferably 250 to 360.
- C the supply amount of the raw material gas in the space velocity (SV), usually 100 ⁇ 6000hr _1, preferably 3 00 ⁇ 3000hr _1.
- the catalytic acid-acid reaction can be performed under pressure or under reduced pressure, but generally a pressure around atmospheric pressure is suitable.
- the obtained coated catalyst was charged into a cylindrical rotary machine having a radius of 14 cm and having a single baffle plate inside, and rotated at 23 rpm for 10 minutes. Thereafter, the peeled powder was removed by sieving, and the remaining amount was measured to be 49.82 g.
- the percentage of the exfoliated powder was 0.36% of the total, and this value is expressed as the degree of wear and is shown in Table 1 together with the shape of the catalyst.
- Example 1 except that the pre-baking temperature was 290 ° C., a catalyst was prepared in the same manner as in Example 1, and methacroleic acid reaction and strength measurement were performed. The results are shown in Table 1.
- Example 1 except that the pre-baking temperature was set to 270 ° C., a catalyst was prepared in the same manner as in Example 1, and methacroleic acid reaction and strength measurement were performed. The results are shown in Table 1.
- Example 1 except that the pre-baking temperature was 250 ° C., a catalyst was prepared in the same manner as in Example 1, and methacroleic acid reaction and strength measurement were performed. The results are shown in Table 1.
- Example 1 except that the pre-baking temperature was 380 ° C., a catalyst was prepared in the same manner as in Example 1, and methacroleic acid reaction and strength measurement were performed. The results are shown in Table 1.
- Example 2 320 g of the granule after the drying step and 22.7 g of antimony trioxide antimony were pre-baked.
- a catalyst was prepared in the same manner as in Example 2 except that it was mixed before synthesis, and methacrolein oxidation reaction and strength measurement were performed. The results are shown in Table 1.
- Example 2 the same method as in Example 2 except that the strength-improving material (ceramic fiber) added during coating molding was 10 g and the spherical porous alumina support (particle size 3.5 mm) was 335 g.
- a catalyst was prepared and subjected to methacroleic acid reaction and strength measurement. The results are shown in Table 1.
- Example 1 a catalyst was prepared in the same manner as in Example 1 except that pre-calcination was not performed, and methacrolein oxidation reaction and strength measurement were performed. The results are shown in Table 1.
- 320g of granules were calcined at 290 ° C for 5 hours under air flow to obtain pre-calcined granules.
- 45 g of a strength improving material (ceramic fiber) was uniformly mixed, and 300 g of a spherical porous alumina support (particle size: 3.5 mm) was coated and molded using a 90 mass% aqueous ethanol solution as a binder.
- the obtained molded product was subjected to main calcination at 310 ° C. for 5 hours under air flow to obtain a target coated catalyst.
- Comparative Example 2 the methacrolein oxidation reaction and the strength measurement were performed in the same manner as in Comparative Example 2 except that pre-baking was not enough. The results are shown in Table 1.
- Example 2 From Example 2 and Example 6, it can be seen that the same effect can be obtained by adding antimony trioxide antimony before or after the preliminary calcination, and that the catalyst performance is almost equivalent. .
- a catalyst that does not use some of the essential components in the catalyst of the present invention as an active component may improve the friability by pre-calcination, but the performance may be greatly reduced.
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Description
Claims
Priority Applications (6)
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BRPI0609231-4A BRPI0609231A2 (pt) | 2005-05-12 | 2006-05-11 | método para manufaturação de catalisador para uso na produção de ácido metacrìlico |
KR1020077025709A KR101223589B1 (ko) | 2005-05-12 | 2006-05-11 | 메타크릴산 제조용 촉매의 제조방법 |
CA002608130A CA2608130A1 (en) | 2005-05-12 | 2006-05-11 | Method for preparing catalyst for production of methacrylic acid |
EP06746261A EP1880761A4 (en) | 2005-05-12 | 2006-05-11 | PROCESS FOR PREPARING A CATALYST FOR THE PRODUCTION OF METHACRYLIC ACID |
US11/919,911 US8017547B2 (en) | 2005-05-12 | 2006-05-11 | Method for manufacturing catalyst for use in production of methacrylic acid |
US13/155,863 US8148291B2 (en) | 2005-05-12 | 2011-06-08 | Method for manufacturing catalyst for use in production of methacrylic acid |
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JP2005-140037 | 2005-05-12 | ||
JP2005140037A JP2006314923A (ja) | 2005-05-12 | 2005-05-12 | メタクリル酸製造用触媒の製造方法 |
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US11/919,911 A-371-Of-International US8017547B2 (en) | 2005-05-12 | 2006-05-11 | Method for manufacturing catalyst for use in production of methacrylic acid |
US13/155,863 Division US8148291B2 (en) | 2005-05-12 | 2011-06-08 | Method for manufacturing catalyst for use in production of methacrylic acid |
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EP (2) | EP1880761A4 (ja) |
JP (1) | JP2006314923A (ja) |
KR (1) | KR101223589B1 (ja) |
CN (1) | CN101175569A (ja) |
BR (1) | BRPI0609231A2 (ja) |
CA (1) | CA2608130A1 (ja) |
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JP5574434B2 (ja) * | 2008-11-06 | 2014-08-20 | 日本化薬株式会社 | メタクリル酸の製造方法及びメタクリル酸製造用触媒 |
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JP4756890B2 (ja) * | 2005-03-29 | 2011-08-24 | 日本化薬株式会社 | メタクリル酸製造用触媒及びその製造方法 |
JP2006314923A (ja) * | 2005-05-12 | 2006-11-24 | Nippon Kayaku Co Ltd | メタクリル酸製造用触媒の製造方法 |
JP4848813B2 (ja) * | 2006-03-29 | 2011-12-28 | 住友化学株式会社 | メタクリル酸製造用触媒の製造方法及びメタクリル酸の製造方法。 |
KR100982831B1 (ko) | 2007-03-26 | 2010-09-16 | 주식회사 엘지화학 | 헤테로폴리산계 촉매의 제조방법 |
JP5570142B2 (ja) * | 2009-05-26 | 2014-08-13 | 日本化薬株式会社 | メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法 |
EP2508256A4 (en) | 2009-11-30 | 2013-07-10 | Nippon Kayaku Kk | METHOD FOR PRODUCING A CATALYST FOR USE IN THE PREPARATION OF METHACRYLIC ACID AND METHACRYLIC ACID METHOD OF PREPARING THEREOF |
JP2012110806A (ja) * | 2010-11-22 | 2012-06-14 | Nippon Kayaku Co Ltd | メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法 |
WO2015053269A1 (ja) | 2013-10-10 | 2015-04-16 | 日本化薬株式会社 | 不飽和カルボン酸の製造方法、及び担持触媒 |
WO2018150797A1 (ja) * | 2017-02-17 | 2018-08-23 | 三菱ケミカル株式会社 | メタクリル酸製造用触媒、メタクリル酸製造用触媒前駆体、およびそれらの製造方法、メタクリル酸の製造方法、並びにメタクリル酸エステルの製造方法 |
CN112439442B (zh) * | 2019-09-05 | 2023-08-11 | 中石油吉林化工工程有限公司 | 一种丙烯氧化制丙烯醛的催化剂制备方法 |
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2005
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2006
- 2006-05-10 MY MYPI2012005079A patent/MY157329A/en unknown
- 2006-05-10 MY MYPI20062144A patent/MY148862A/en unknown
- 2006-05-11 US US11/919,911 patent/US8017547B2/en not_active Expired - Fee Related
- 2006-05-11 EP EP06746261A patent/EP1880761A4/en not_active Withdrawn
- 2006-05-11 BR BRPI0609231-4A patent/BRPI0609231A2/pt not_active IP Right Cessation
- 2006-05-11 CN CNA2006800163159A patent/CN101175569A/zh active Pending
- 2006-05-11 KR KR1020077025709A patent/KR101223589B1/ko not_active IP Right Cessation
- 2006-05-11 CA CA002608130A patent/CA2608130A1/en not_active Abandoned
- 2006-05-11 WO PCT/JP2006/309452 patent/WO2006121100A1/ja active Application Filing
- 2006-05-11 EP EP12185643A patent/EP2540393A1/en not_active Ceased
- 2006-05-12 TW TW095116946A patent/TWI394615B/zh not_active IP Right Cessation
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2011
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JP5574434B2 (ja) * | 2008-11-06 | 2014-08-20 | 日本化薬株式会社 | メタクリル酸の製造方法及びメタクリル酸製造用触媒 |
Also Published As
Publication number | Publication date |
---|---|
EP1880761A1 (en) | 2008-01-23 |
EP1880761A4 (en) | 2012-04-04 |
TWI394615B (zh) | 2013-05-01 |
US8148291B2 (en) | 2012-04-03 |
KR20080005535A (ko) | 2008-01-14 |
CA2608130A1 (en) | 2006-11-16 |
US8017547B2 (en) | 2011-09-13 |
JP2006314923A (ja) | 2006-11-24 |
BRPI0609231A2 (pt) | 2010-03-09 |
MY148862A (en) | 2013-06-14 |
US20110237829A1 (en) | 2011-09-29 |
MY157329A (en) | 2016-05-31 |
EP2540393A1 (en) | 2013-01-02 |
US20090036707A1 (en) | 2009-02-05 |
KR101223589B1 (ko) | 2013-01-17 |
CN101175569A (zh) | 2008-05-07 |
TW200704439A (en) | 2007-02-01 |
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