WO2006111315A1 - Protected carbon steel pipe for fire tube heat exchange devices, particularly boilers - Google Patents

Protected carbon steel pipe for fire tube heat exchange devices, particularly boilers Download PDF

Info

Publication number
WO2006111315A1
WO2006111315A1 PCT/EP2006/003381 EP2006003381W WO2006111315A1 WO 2006111315 A1 WO2006111315 A1 WO 2006111315A1 EP 2006003381 W EP2006003381 W EP 2006003381W WO 2006111315 A1 WO2006111315 A1 WO 2006111315A1
Authority
WO
WIPO (PCT)
Prior art keywords
corrosion
resistant material
pipe according
pipe
ribs
Prior art date
Application number
PCT/EP2006/003381
Other languages
English (en)
French (fr)
Inventor
Giovanni Jahier
Original Assignee
Unical Ag S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from ITMN20050023 external-priority patent/ITMN20050023A1/it
Priority claimed from ITMN20060012 external-priority patent/ITMN20060012A1/it
Application filed by Unical Ag S.P.A. filed Critical Unical Ag S.P.A.
Priority to US11/887,638 priority Critical patent/US20090266529A1/en
Priority to CA002603454A priority patent/CA2603454A1/en
Priority to EP06724287A priority patent/EP1872080A1/de
Priority to EA200702265A priority patent/EA011432B1/ru
Publication of WO2006111315A1 publication Critical patent/WO2006111315A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00Tubular elements; Assemblies of tubular elements
    • F28F1/02Tubular elements of cross-section which is non-circular
    • F28F1/022Tubular elements of cross-section which is non-circular with multiple channels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00Tubular elements; Assemblies of tubular elements
    • F28F1/003Multiple wall conduits, e.g. for leak detection
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00Tubular elements; Assemblies of tubular elements
    • F28F1/10Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
    • F28F1/40Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only inside the tubular element
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/06Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F28F19/06Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2215/00Fins
    • F28F2215/10Secondary fins, e.g. projections or recesses on main fins

Definitions

  • the present invention relates to a protected carbon steel pipe for fire tube heat exchange devices, particularly boilers.
  • fire tube heat exchange devices which provide pipes designed to convey flue gases generated by combustion in appropriate furnaces, such pipes being provided within a vessel which contains the fluid to be heated; among such devices, boilers for generating hot water or another heat transfer fluid are particularly important.
  • the pipes comprised within said devices are made of carbon steel in order to ensure optimum quality of the welded joints between the pipes and the structures of the devices, which are also made of carbon steel; however, in the case of devices, such as for example condensing boilers, in which the water vapor contained in the flue gases condenses inside the flue gas conveyance pipes, condensation forms which attacks strongly by corrosion the wall of the pipes.
  • Pipes of the described type are not typical only of boilers, but can be present also in other devices of industrial thermal cycles, such as for example condensers, economizers and heat exchangers. Disclosure of the Invention
  • the aim of the present invention is to provide a carbon steel pipe adapted to convey flue gases which is entirely protected against the danger of corrosion caused by condensation and further ensures high efficiency in the transmission of heat from the flue gases to the fluid, and in particular to the water, to be heated.
  • Figure 1 is a longitudinal sectional view of a fire tube boiler with a pipe according to the present invention
  • Figure 2 is a partial sectional view, taken along the line II-II of Figure l ;
  • FIG. 3 to 25 show the same sectional view according to variations. Ways of carrying out the Invention
  • the reference numeral 1 generally designates a fire tube boiler with a burner 2, a furnace 3, a flue gas reversal chamber 4a, a vessel 5 which contains the water to be heated with couplings 5a, 5b respectively for inflow and outflow, pipes 6 designed to convey the gases generated by combustion in the furnace which arrive from the reversal chamber 4a and are sent to the output chamber 4b according to the arrows shown in figure 1.
  • the boiler 1 is of the type known as condensing boiler, and therefore the water vapor contained in the flue gases condenses therein as they flow within the pipes such as 6; the structure of said boiler is made of carbon steel.
  • An important characteristic of the invention consists in that the pipe 6 is made of carbon steel and comprises internally, bonded thereto, a layer 7 made of a corrosion-resistant material, such as aluminum or stainless steel.
  • the layer 7 is present along the entire length of the pipe 6, but it should be clearly noted that such layer might be provided only in the part of the pipe toward the outlet of the flue gases.
  • An embodiment of the pipe according to the invention is shown in
  • the carbon steel pipe 8 comprises, bonded thereto, a layer 9 made of corrosion-resistant material and accommodates internally a coaxial sleeve 10, which is closed by at least one plug 10a, likewise made of corrosion- resistant material.
  • An interspace 11 for conveying the flue gases in a reduced cross- section is thus provided: the consequent increase in speed effectively helps to increase heat exchange between the flue gases and the water to be heated.
  • a further increased efficiency of said exchange occurs in the variation of Figure 4, in which a carbon steel pipe 12 has, bonded thereto, a layer 13 of corrosion-resistant material, and a sleeve 14, closed by a plug 14a, has ribs 14b which extend monolithically from it and which, by entering an interspace 15 through which the flue gases flow, make contact with the layer 13, transmitting thereto, and ultimately to the water to be heated, heat by conduction.
  • An identical situation occurs in the variations of Figures 5, 6, 7, and
  • FIG. 9 provides, bonded to a carbon steel pipe 20, a first layer 21 made of corrosion-resistant material, and a second layer 22, also made of corrosion-resistant material, which provides ribs 22a adapted to make contact, by entering an interspace 23 through which the flue gases flow, with a sleeve 24 closed by a plug 24a, thus providing a situation which is similar to the one described earlier.
  • Figures 14 to 18 replicate the constructive embodiments shown in Figures 9 to 13, with the only difference related to the fact that there is just one layer made of corrosion-resistant material bonded to the carbon steel pipe: thus, for example, the variation of Figure 14 provides, bonded to a carbon steel pipe 25, only a layer 26 made of corrosion-resistant material, which is provided with a ribs 26a which make contact with a sleeve 27.
  • Figure 19 illustrates an embodiment in which a first layer 29, made of corrosion-resistant material, and a second layer 30, also made of corrosion- resistant material, are bonded to a carbon steel pipe 28; ribs 30a protrude from said second layer and are alternated with ribs 31a which protrude from a sleeve 31 , leaving spaces 32 between said ribs for the flow of the flue gases: ribs 31a extend until they make contact with the layer 30 in the presence of references 31b which ensure correct positioning.
  • a variation of the embodiment of Figure 19 is shown in Figure 20: the only difference is the absence of the layer 29 bonded to a carbon steel pipe 33, and therefore only a layer 34 made of corrosion-resistant material and provided with the ribs as described above, is present.
  • the variation shown in Figure 21 comprises, bonded to a carbon steel pipe 35, a layer 36 made of corrosion-resistant material, which is provided with variously shaped ribs 36a arranged alternately with respect to variously shaped ribs 37a which protrude from a sleeve 37 and are adapted to make contact in the presence of references 37b with the wall of the layer 36.
  • the reference numeral 38 designates a carbon steel pipe, which comprises internally two flue gas conveyance modules, designated generally by the reference numerals 39 and 40 respectively, which are delimited by a closed wall made of corrosion-resistant material.
  • the wall of the module 39 comprises a portion 41, which is bonded to the wall of the pipe 38 substantially along half of the circumferential extension thereof, and a straight portion 42, which extends transversely, and likewise the wall of the module 40 comprises a portion 43 bonded to the wall of the pipe 38 and a straight portion 44; the straight portions 42 and 44 are in mutual contact.
  • the described configuration allows to obtain the dual result of protecting the wall of the pipe 38 against contact with the flue gases, and this is done by the portions 41 and 43 of the walls of the modules, and of providing an intense transmission of heat from the flue gases to the water contained in the boiler which strikes the outer surface of the pipe 38, determined by the presence of the portions 42 and 44 of said walls which make contact with the flue gases at the region where said flue gases have a particularly high temperature.
  • Figure 23 illustrates another variation of the invention, which provides, inside the pipe 38, six flue gas conveyance modules which are substantially shaped like wedges and are designated respectively by the reference numerals 45, 46, 47, 48, 49, 50.
  • the walls of the module which are made of corrosion-resistant material, are identical and comprise an arc-like portion, 45a for the module 45, bonded to the wall of the pipe 38, and two straight portions 45b, 45c for said module, which protrude from the ends of said arc-like portion toward the axis of said pipe; the straight portions of the individual modules are in mutual contact.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Geometry (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Laminated Bodies (AREA)
  • Incineration Of Waste (AREA)
PCT/EP2006/003381 2005-04-18 2006-04-12 Protected carbon steel pipe for fire tube heat exchange devices, particularly boilers WO2006111315A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US11/887,638 US20090266529A1 (en) 2005-04-18 2006-04-12 Protected Carbon Steel Pipe for Fire Tube Heat Exchange Devices, Particularly Boilers
CA002603454A CA2603454A1 (en) 2005-04-18 2006-04-12 Protected carbon steel pipe for fire tube heat exchange devices, particularly boilers
EP06724287A EP1872080A1 (de) 2005-04-18 2006-04-12 Geschütztes kohlenstoffstahlrohr für feuerrohrwärmetauschvorrichtungen, insbesondere kessel
EA200702265A EA011432B1 (ru) 2005-04-18 2006-04-12 Защищенная труба из углеродистой стали для жаротрубных теплообменных устройств, в частности для котлов

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
ITMN20050023 ITMN20050023A1 (it) 2005-04-18 2005-04-18 Tubo in acciaio al carbonio protetto compreso in caldaia a tubi di fumo
ITMN2005A000023 2005-04-18
ITMN2006A000012 2006-02-22
ITMN20060012 ITMN20060012A1 (it) 2006-02-22 2006-02-22 Tubo in acciaio al carbonio protetto, per apparecchi di scambio termico particolarmente caldaie a tubi di fumo

Publications (1)

Publication Number Publication Date
WO2006111315A1 true WO2006111315A1 (en) 2006-10-26

Family

ID=36581553

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/003381 WO2006111315A1 (en) 2005-04-18 2006-04-12 Protected carbon steel pipe for fire tube heat exchange devices, particularly boilers

Country Status (5)

Country Link
US (1) US20090266529A1 (de)
EP (1) EP1872080A1 (de)
CA (1) CA2603454A1 (de)
EA (1) EA011432B1 (de)
WO (1) WO2006111315A1 (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1936315A1 (de) 2006-12-13 2008-06-25 UNICAL AG S.p.A. Geschütztes Kohlenstoffstahlrohr zur Leitung von Rauchgasen in einer Wärmetauschervorrichtung
US20080296006A1 (en) * 2007-05-31 2008-12-04 Amerifab, Inc. Adjustable heat exchange apparatus and method of use
EP2814910A4 (de) * 2012-02-17 2015-11-11 Ceramatec Inc Erweitertes fischer-tropsch-system
US10871328B2 (en) 2017-01-30 2020-12-22 Amerifab, Inc. Top loading roof for electric arc, metallurgical or refining furnaces and system thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100963423B1 (ko) * 2009-11-12 2010-06-15 현대하이스코 주식회사 하이드로 포밍을 이용한 워터 파이프 제조 방법
US10775040B2 (en) * 2016-12-16 2020-09-15 James Matthew Austin Annular superheating element for firetube boilers
US11703282B2 (en) * 2016-12-22 2023-07-18 Trinity Endeavors, Llc Fire tube

Citations (16)

* Cited by examiner, † Cited by third party
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US1701617A (en) * 1928-05-11 1929-02-12 Mccord Radiator & Mfg Co Metal tubing
FR1146302A (fr) * 1956-03-27 1957-11-08 échangeur de chaleur tubulaire
US2960114A (en) * 1957-04-26 1960-11-15 Bell & Gossett Co Innerfinned heat transfer tubes
US3036818A (en) * 1958-01-29 1962-05-29 Foster Wheeler Francaise Soc Heat exchanger
GB1003013A (en) * 1962-05-28 1965-09-02 Patterson Kelley Co Heat exchange device
US3267564A (en) * 1964-04-23 1966-08-23 Calumet & Hecla Method of producing duplex internally finned tube unit
DE2027507A1 (de) * 1970-05-30 1971-12-09 Licentia Gmbh Düse zur Beschleunigung zweiphasiger Strömungen
US4054174A (en) * 1974-03-18 1977-10-18 The Babcock & Wilcox Company Method of inhibiting deposition of internal corrosion products in tubes
JPS629184A (ja) * 1985-07-04 1987-01-17 Toshiba Corp 熱交換器
FR2697077A1 (fr) * 1992-10-16 1994-04-22 Sofath Dispositif pour améliorer les performances des pompes à chaleur à capteur enterré.
JPH09292062A (ja) * 1996-04-24 1997-11-11 Furukawa Electric Co Ltd:The 耐食性に優れた内面溝付管
US5960835A (en) * 1996-08-06 1999-10-05 Kubota Corporation Cast iron pipe surface-modified for corrosion prevention and method of modifying the cast iron pipe surface for corrosion prevention
WO1999050610A1 (de) * 1998-03-27 1999-10-07 Siemens Aktiengesellschaft Wärmetauscherrohr, verfahren zur herstellung eines wärmetauscherrohrs sowie kondensator
US6006741A (en) * 1998-08-31 1999-12-28 Carrier Corporation Secondary heat exchanger for condensing furnace
US6070657A (en) * 1994-03-24 2000-06-06 Hoval Interliz Ag Heat exchanger tube for heating boilers
WO2000042294A1 (en) * 1999-01-13 2000-07-20 Abb Alstom Power Inc. Material selection and conditioning to avoid brittleness caused by nitriding

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US3735478A (en) * 1971-01-06 1973-05-29 Foster Co Methods for making bi-metallic pipe
US4336958A (en) * 1977-12-12 1982-06-29 John Goetzinger Pipe flange
CA1139923A (en) * 1979-02-28 1983-01-25 Toshio Yoshida Method of producing multiple-wall composite pipes

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1701617A (en) * 1928-05-11 1929-02-12 Mccord Radiator & Mfg Co Metal tubing
FR1146302A (fr) * 1956-03-27 1957-11-08 échangeur de chaleur tubulaire
US2960114A (en) * 1957-04-26 1960-11-15 Bell & Gossett Co Innerfinned heat transfer tubes
US3036818A (en) * 1958-01-29 1962-05-29 Foster Wheeler Francaise Soc Heat exchanger
GB1003013A (en) * 1962-05-28 1965-09-02 Patterson Kelley Co Heat exchange device
US3267564A (en) * 1964-04-23 1966-08-23 Calumet & Hecla Method of producing duplex internally finned tube unit
DE2027507A1 (de) * 1970-05-30 1971-12-09 Licentia Gmbh Düse zur Beschleunigung zweiphasiger Strömungen
US4054174A (en) * 1974-03-18 1977-10-18 The Babcock & Wilcox Company Method of inhibiting deposition of internal corrosion products in tubes
JPS629184A (ja) * 1985-07-04 1987-01-17 Toshiba Corp 熱交換器
FR2697077A1 (fr) * 1992-10-16 1994-04-22 Sofath Dispositif pour améliorer les performances des pompes à chaleur à capteur enterré.
US6070657A (en) * 1994-03-24 2000-06-06 Hoval Interliz Ag Heat exchanger tube for heating boilers
JPH09292062A (ja) * 1996-04-24 1997-11-11 Furukawa Electric Co Ltd:The 耐食性に優れた内面溝付管
US5960835A (en) * 1996-08-06 1999-10-05 Kubota Corporation Cast iron pipe surface-modified for corrosion prevention and method of modifying the cast iron pipe surface for corrosion prevention
WO1999050610A1 (de) * 1998-03-27 1999-10-07 Siemens Aktiengesellschaft Wärmetauscherrohr, verfahren zur herstellung eines wärmetauscherrohrs sowie kondensator
US6006741A (en) * 1998-08-31 1999-12-28 Carrier Corporation Secondary heat exchanger for condensing furnace
WO2000042294A1 (en) * 1999-01-13 2000-07-20 Abb Alstom Power Inc. Material selection and conditioning to avoid brittleness caused by nitriding

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PATENT ABSTRACTS OF JAPAN vol. 011, no. 180 (M - 597) 10 June 1987 (1987-06-10) *
PATENT ABSTRACTS OF JAPAN vol. 1998, no. 03 27 February 1998 (1998-02-27) *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1936315A1 (de) 2006-12-13 2008-06-25 UNICAL AG S.p.A. Geschütztes Kohlenstoffstahlrohr zur Leitung von Rauchgasen in einer Wärmetauschervorrichtung
US20080296006A1 (en) * 2007-05-31 2008-12-04 Amerifab, Inc. Adjustable heat exchange apparatus and method of use
US20180038655A1 (en) * 2007-05-31 2018-02-08 Amerifab, Inc. Adjustable heat exchange apparatus and method of use
US10760854B2 (en) 2007-05-31 2020-09-01 Amerifab, Inc. Adjustable heat exchange apparatus and method of use
EP2814910A4 (de) * 2012-02-17 2015-11-11 Ceramatec Inc Erweitertes fischer-tropsch-system
US10871328B2 (en) 2017-01-30 2020-12-22 Amerifab, Inc. Top loading roof for electric arc, metallurgical or refining furnaces and system thereof

Also Published As

Publication number Publication date
CA2603454A1 (en) 2006-10-26
US20090266529A1 (en) 2009-10-29
EP1872080A1 (de) 2008-01-02
EA200702265A1 (ru) 2008-02-28
EA011432B1 (ru) 2009-02-27

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