WO2006066291A1 - Cellulosischer formkörper und verfahren zu seiner herstellung - Google Patents
Cellulosischer formkörper und verfahren zu seiner herstellung Download PDFInfo
- Publication number
- WO2006066291A1 WO2006066291A1 PCT/AT2005/000488 AT2005000488W WO2006066291A1 WO 2006066291 A1 WO2006066291 A1 WO 2006066291A1 AT 2005000488 W AT2005000488 W AT 2005000488W WO 2006066291 A1 WO2006066291 A1 WO 2006066291A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- microcapsules
- shaped body
- cellulose
- viscose
- body according
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
Definitions
- the present invention relates to a cellulosic molding, in particular a cellulose fiber, and a process for their preparation.
- Cellulosic shaped bodies, in particular fibers, are produced today essentially according to two methods:
- viscose an alkaline cellulose xanthate solution is spun into one or more regeneration baths.
- viscose Depending on the exact composition of spinning solution ("viscose") and regeneration baths one speaks of viscose or modal fibers.
- the two groups are classified by the BISFA (The International Bureau for the Standardization of Man Made Fibers) as generic terms.
- amine oxide process or "lyocell process”.
- Both methods also involve the production of other shaped articles, e.g. Films, membranes, etc. possible.
- micro-capsules as carriers of various drugs in a variety of fields to make products consisting of a base and substances which are incompatible with this base material and / or whose release is to be controlled.
- milk capsules are mostly used in the finishing of fibers and textiles in order to subsequently fix active ingredients to the (finished) fibers and textiles.
- EP-A 1 359 247 A1 the entrapped active ingredients can be released by diffusion or mechanical or chemical stress.
- microcapsules are not permanently bound to the fibers and are removed by repeated washings.
- US Pat. No. 3,852,401 describes a process for producing synthetic fibers from various synthetic polymers (but not viscose fibers) containing microencapsulated fiber-modifying substances. In this process, the microcapsules are prepared in situ in the spinning solution.
- US Pat. No. 3,852,401 points out that separate preparation of the milk capsules and mixing of the microcapsules into the spinning solution of the synthetic polymers leads to problems, since the microcapsules form larger aggregates as a result of the change in the dispersion medium, which can not be comminuted again.
- EP 0 306 202 B1 also describes, with regard to synthetic polymers but not viscose fibers, a process for incorporating milk capsules containing heat storage substances.
- EP 1 367 152 A1 describes a process of producing fibers and nonwoven fabrics made therefrom from thermoplastic materials incorporating fragrances into milk capsules.
- EP 0 687 313 describes a method of hollow spheres with a diameter of less than 1.5 ⁇ m in cellulose fibers. These beads contain no modifying substance, but serve themselves as matting agents.
- JP 2-154007 describes the preparation of regenerated cellulose fibers in which microcapsules with fragrances are integrated. Specifically described is the production of fibers by the Kupferoxidammonium- method.
- This object is achieved with a cellulosic molding containing a modifying substance in microencapsulated form.
- a molded article incorporating the microcapsules with the modifying substance can be produced. within the cellulosic matrix of the shaped body.
- microcapsules can be incorporated up to a content of 30% by weight, based on molding.
- microcapsules are used which have a size of 10 microns or less. This is significantly smaller than the microcapsules used according to JP 2-154007 in Kupferoxidammoniak- method.
- the microencapsulated modifying substance is preferably selected from the group consisting of flame retardants, heat storage substances, fragrances, dyes, cosmetic Active ingredients and therapeutic agents selected.
- flame retardants eg so-called phase change materials
- flame retardants eg red phosphorus
- the shaped body according to the invention is preferably in the form of a fiber, in particular in the form of a viscose fiber or lyocell fiber.
- the process for producing the shaped body according to the invention comprises shaping a spinning solution of the cellulose or a cellulose derivative and is characterized in that the spinning solution and / or a precursor of the spinning solution microcapsules containing the modifying substance are added.
- the spinning solution is preferably a viscose or a solution of cellulose in an aqueous tertiary amine oxide.
- precursors of the spinning solution are the starting materials or intermediates in the above-outlined viscose or Lyo cell compiler to understand, ie in the case of the viscose, for example, the cellulosic starting material, the alkali cellulose or cellulose xanthogenate prior to dissolution or in the case of Lyocell compilers the cellulosic starting material, the aqueous amine oxide used or an aqueous suspension of the cellulose in the amine oxide before solution preparation.
- microcapsules are preferably added in the form of an aqueous suspension.
- Example (a) Into a ready-to-spin viscose for the production of modal fibers was stirred a 10% aqueous microcapsule suspension (RT35vis2, Aero company, containing a phase change material) in a concentration of 10% by weight (microcapsules based on cellulose) (example (a)) resp ., added continuously just before the spin filtration (Example (b)).
- RT35vis2 10% aqueous microcapsule suspension
- Aero company Aero company
- Viscose fibers were prepared by methods known per se and their strength was measured. During the spinning process, no increase in pressure could be detected before or after spin filtration. The melting enthalpy of the incorporated phase change material was determined on the finished, dried fibers by means of DSC (Differential Scanning Calorimetry).
- microcapsules based on cellulose stirred.
- the microcapsules contain dyes or dye precursors and / or perfumes.
- Viscose fibers were prepared by methods known per se and their strength was measured. During the spinning process, no increase in pressure could be detected before or after spinning filtration.
- a 30% aqueous microcapsule suspension (type: LD-dev, Aero company) in concentrations of 5-30% by weight (microcapsules based on cellulose) was metered continuously into the spinning pump and by means of downstream homogenizer mixed.
- the microcapsules contain dyes.
- Viscose fibers were prepared by methods known per se and their strength was measured. During the spinning process, no increase in pressure could be detected before or after spinning filtration.
- microcapsules could be demonstrated on the one hand by electron microscopy images, and on the microcapsules with incorporated dyes also directly by light microscopic images.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05812757A EP1828448A1 (de) | 2004-12-23 | 2005-12-05 | Cellulosischer formkörper und verfahren zu seiner herstellung |
US11/820,425 US20080032128A1 (en) | 2004-12-23 | 2007-06-19 | Cellulosic moulded body and process for its manufacture |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0216204A AT501252B1 (de) | 2004-12-23 | 2004-12-23 | Cellulosischer formkörper und verfahren zu seiner herstellung |
ATA2162/2004 | 2004-12-23 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/820,425 Continuation US20080032128A1 (en) | 2004-12-23 | 2007-06-19 | Cellulosic moulded body and process for its manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006066291A1 true WO2006066291A1 (de) | 2006-06-29 |
Family
ID=35846878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2005/000488 WO2006066291A1 (de) | 2004-12-23 | 2005-12-05 | Cellulosischer formkörper und verfahren zu seiner herstellung |
Country Status (5)
Country | Link |
---|---|
US (1) | US20080032128A1 (de) |
EP (1) | EP1828448A1 (de) |
CN (1) | CN101094942A (de) |
AT (1) | AT501252B1 (de) |
WO (1) | WO2006066291A1 (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006046358B3 (de) * | 2006-09-28 | 2007-11-29 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von funktionellen cellulosischen Formkörpern |
EP2041361A1 (de) * | 2006-07-04 | 2009-04-01 | Outlast Technologies, Inc. | Stabile suspensionen mit mikrokapseln und verfahren zu ihrer herstellung |
DE102007054702A1 (de) | 2007-11-14 | 2009-05-20 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von cellulosischen Formkörpern, cellulosischer Formkörper und dessen Verwendung |
US9434869B2 (en) | 2001-09-21 | 2016-09-06 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
CN111455487A (zh) * | 2020-04-27 | 2020-07-28 | 宁波市纤维检验所 | 一种相变调温纤维及其制备方法 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT510909B1 (de) | 2010-12-20 | 2013-04-15 | Chemiefaser Lenzing Ag | Flammgehemmte cellulosische man-made-fasern |
CN102691132B (zh) * | 2011-03-23 | 2016-02-10 | 湖州珠力纳米材料科技开发有限公司 | 微胶囊型芦荟共混再生纤维素纤维与其制备方法 |
US9279192B2 (en) | 2014-07-29 | 2016-03-08 | Dow Corning Corporation | Method for manufacturing SiC wafer fit for integration with power device manufacturing technology |
CN106012075B (zh) * | 2016-07-28 | 2019-02-22 | 天津工业大学 | 一种高强粘胶纤维及其制备方法 |
CN106929931B (zh) * | 2017-03-24 | 2020-05-12 | 青岛邦特生态纺织科技有限公司 | 一种含板蓝根提取物的粘胶纤维及其制备方法 |
CN110184666B (zh) * | 2019-06-20 | 2021-11-16 | 宜宾屏山辉瑞油脂有限公司 | 阻燃纤维素纤维的制造方法及制造过程中使用的喷丝头 |
Citations (4)
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JPH02154007A (ja) * | 1988-12-01 | 1990-06-13 | Asahi Chem Ind Co Ltd | 香りを有する再生セルロース繊維 |
US5298035A (en) * | 1991-12-27 | 1994-03-29 | Og Kabushiki Kaisha | Process for preparing thermosensitive fibrous structure |
US20040126555A1 (en) * | 2001-09-21 | 2004-07-01 | Hartmann Mark Henry | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
WO2005024102A1 (de) * | 2003-08-30 | 2005-03-17 | Thüringisches Institut Für Textil - Und Kunststoff - Forschung E.V. | Formkörper, insbesondere fasern und deren flächengebilde, mit thermoregulativen eigenschaften |
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JPS5022613B1 (de) * | 1971-06-29 | 1975-08-01 | ||
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JPS5232996A (en) * | 1975-09-09 | 1977-03-12 | Bridgestone Corp | Process for preparing polyurethanes based on polydienes |
JPS54136917A (en) * | 1978-04-14 | 1979-10-24 | Mitsubishi Paper Mills Ltd | Selffcoloring fibrous sheet containing capsules |
DE3316880A1 (de) * | 1983-05-07 | 1984-11-08 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von hydrolysestabilen pulverfoermigen ammoniumpolyphosphaten |
US4513053A (en) * | 1983-06-13 | 1985-04-23 | Pennwalt Corporation | Encapsulated phase change thermal energy storage materials and process |
US4797160A (en) * | 1984-08-31 | 1989-01-10 | University Of Dayton | Phase change compositions |
US5053446A (en) * | 1985-11-22 | 1991-10-01 | University Of Dayton | Polyolefin composites containing a phase change material |
US4756958A (en) * | 1987-08-31 | 1988-07-12 | Triangle Research And Development Corporation | Fiber with reversible enhanced thermal storage properties and fabrics made therefrom |
US5007478A (en) * | 1989-05-26 | 1991-04-16 | University Of Miami | Microencapsulated phase change material slurry heat sinks |
JP3128882B2 (ja) * | 1990-09-04 | 2001-01-29 | 東レ株式会社 | インターロイキン−6の産生方法 |
NZ239231A (en) * | 1990-10-09 | 1994-07-26 | Matsui Shikiso Kagaku Kogyosho | Process for dyeing textiles with reversible colour changeable particles |
DE4140085A1 (de) * | 1991-12-05 | 1993-06-09 | Basf Ag, 6700 Ludwigshafen, De | Farbstoffpraeparationen von solventfarbstoffen |
US5391583A (en) * | 1992-07-17 | 1995-02-21 | Blount; David H. | Flame-retardant poly (polyisocyanate-organic phosphorus) products |
US5435376A (en) * | 1992-08-17 | 1995-07-25 | Microtek Laboratories, Inc. | Flame resistant microencapsulated phase change materials |
US7220951B2 (en) * | 2004-04-19 | 2007-05-22 | Surgrx, Inc. | Surgical sealing surfaces and methods of use |
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-
2004
- 2004-12-23 AT AT0216204A patent/AT501252B1/de not_active IP Right Cessation
-
2005
- 2005-12-05 WO PCT/AT2005/000488 patent/WO2006066291A1/de active Application Filing
- 2005-12-05 EP EP05812757A patent/EP1828448A1/de not_active Withdrawn
- 2005-12-05 CN CNA2005800441215A patent/CN101094942A/zh active Pending
-
2007
- 2007-06-19 US US11/820,425 patent/US20080032128A1/en not_active Abandoned
Patent Citations (4)
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JPH02154007A (ja) * | 1988-12-01 | 1990-06-13 | Asahi Chem Ind Co Ltd | 香りを有する再生セルロース繊維 |
US5298035A (en) * | 1991-12-27 | 1994-03-29 | Og Kabushiki Kaisha | Process for preparing thermosensitive fibrous structure |
US20040126555A1 (en) * | 2001-09-21 | 2004-07-01 | Hartmann Mark Henry | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
WO2005024102A1 (de) * | 2003-08-30 | 2005-03-17 | Thüringisches Institut Für Textil - Und Kunststoff - Forschung E.V. | Formkörper, insbesondere fasern und deren flächengebilde, mit thermoregulativen eigenschaften |
Non-Patent Citations (1)
Title |
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DATABASE WPI Section Ch Week 199030, Derwent World Patents Index; Class A11, AN 1990-226966, XP002370192 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9434869B2 (en) | 2001-09-21 | 2016-09-06 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
US9920455B2 (en) | 2001-09-21 | 2018-03-20 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
US10208403B2 (en) | 2001-09-21 | 2019-02-19 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
EP2041361A1 (de) * | 2006-07-04 | 2009-04-01 | Outlast Technologies, Inc. | Stabile suspensionen mit mikrokapseln und verfahren zu ihrer herstellung |
EP2041361A4 (de) * | 2006-07-04 | 2012-06-06 | Outlast Technologies Inc | Stabile suspensionen mit mikrokapseln und verfahren zu ihrer herstellung |
DE102006046358B3 (de) * | 2006-09-28 | 2007-11-29 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von funktionellen cellulosischen Formkörpern |
DE102007054702A1 (de) | 2007-11-14 | 2009-05-20 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von cellulosischen Formkörpern, cellulosischer Formkörper und dessen Verwendung |
US9303335B2 (en) | 2007-11-14 | 2016-04-05 | Smartpolymer Gmbh | Process for producing cellulosic shaped articles, cellulosic shaped articles and the use thereof |
DE102007054702B4 (de) | 2007-11-14 | 2018-10-18 | Smartpolymer Gmbh | Verfahren zur Herstellung von cellulosischen Formkörpern, cellulosischer Formkörper und dessen Verwendung |
US10323138B2 (en) | 2007-11-14 | 2019-06-18 | Smartpolymer Gmbh | Process for producing cellulosic shaped articles, cellulosic shaped articles and the use thereof |
CN111455487A (zh) * | 2020-04-27 | 2020-07-28 | 宁波市纤维检验所 | 一种相变调温纤维及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1828448A1 (de) | 2007-09-05 |
US20080032128A1 (en) | 2008-02-07 |
AT501252B1 (de) | 2008-02-15 |
CN101094942A (zh) | 2007-12-26 |
AT501252A1 (de) | 2006-07-15 |
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