WO2006059811A1 - Composition de produit lessiviel ameliorant l'agrement au toucher du tissu et procede de fabrication - Google Patents
Composition de produit lessiviel ameliorant l'agrement au toucher du tissu et procede de fabrication Download PDFInfo
- Publication number
- WO2006059811A1 WO2006059811A1 PCT/KR2004/003123 KR2004003123W WO2006059811A1 WO 2006059811 A1 WO2006059811 A1 WO 2006059811A1 KR 2004003123 W KR2004003123 W KR 2004003123W WO 2006059811 A1 WO2006059811 A1 WO 2006059811A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid
- composition
- laundry detergent
- weight
- parts
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 105
- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- 150000007524 organic acids Chemical class 0.000 claims abstract description 55
- 230000002378 acidificating effect Effects 0.000 claims abstract description 27
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 18
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- -1 silica compound Chemical class 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 230000003472 neutralizing effect Effects 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 229940117927 ethylene oxide Drugs 0.000 claims description 4
- 239000006166 lysate Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- LPTWEDZIPSKWDG-UHFFFAOYSA-N benzenesulfonic acid;dodecane Chemical compound OS(=O)(=O)C1=CC=CC=C1.CCCCCCCCCCCC LPTWEDZIPSKWDG-UHFFFAOYSA-N 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 150000003377 silicon compounds Chemical class 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 2
- JBNHKYQZNSPSOR-UHFFFAOYSA-N 4-(carboxymethylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOCC(O)=O JBNHKYQZNSPSOR-UHFFFAOYSA-N 0.000 claims description 2
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 claims description 2
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 235000013922 glutamic acid Nutrition 0.000 claims description 2
- 239000004220 glutamic acid Substances 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims 2
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 claims 1
- 239000000843 powder Substances 0.000 abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 21
- 238000004900 laundering Methods 0.000 abstract description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 18
- 239000004744 fabric Substances 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- 229910021536 Zeolite Inorganic materials 0.000 description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 13
- 239000010457 zeolite Substances 0.000 description 13
- 238000006386 neutralization reaction Methods 0.000 description 12
- 238000003860 storage Methods 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 108090000790 Enzymes Proteins 0.000 description 9
- 102000004190 Enzymes Human genes 0.000 description 9
- 229940088598 enzyme Drugs 0.000 description 9
- 235000017550 sodium carbonate Nutrition 0.000 description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 7
- 239000008233 hard water Substances 0.000 description 7
- 238000013508 migration Methods 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000001461 cytolytic effect Effects 0.000 description 3
- 239000007850 fluorescent dye Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000019646 color tone Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000002366 lipolytic effect Effects 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 102100038509 E3 ubiquitin-protein ligase ARIH1 Human genes 0.000 description 1
- 101000808922 Homo sapiens E3 ubiquitin-protein ligase ARIH1 Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- AJJJMKBOIAWMBE-UHFFFAOYSA-N acetic acid;propane-1,3-diamine Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCCN AJJJMKBOIAWMBE-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- PMPJQLCPEQFEJW-HPKCLRQXSA-L disodium;2-[(e)-2-[4-[4-[(e)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical group [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-HPKCLRQXSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229940080260 iminodisuccinate Drugs 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Definitions
- the present invention relates to a composition of laundry detergent capable of
- detergents generally include a water softener such as zeolite and so on.
- the water softener such as zeolite and so on.
- iminodisuccinate was used to prevent clothes from being discolored by removing heavy
- Korea Patent No. 1993-0003152 discloses a tablet type of detergent
- detergent compositions including a large amount of basic materials such as alkaline
- caking was formed by neutralization reaction due to various causes if acidic
- a powder detergent is generally manufactured by preparing slurry
- powder detergent may be preferably used for washing since it has an excellent solubility
- the powder detergent was manufactured by preparing salt of alkyl benzene
- low-density detergent having apparent density of 0.6 g/ml or less since it has very high density.
- the detergent was conducted within shorter processing time by spraying steam and water
- the present invention is designed to solve the problems of the prior
- laundry detergent capable of swiftly softening hard water and improving touch feel of
- the present invention provides a composition of laundry
- detergent including: (a) 0.1 to 15 parts by weight of an acidic form of water-soluble
- the present invention provides a method for manufacturing a composition of laundry detergent dried by heat generated by neutralizing an acid component with a
- step (S2) added to the mixer; and (S4) mixing the coated organic acid prepared
- the present invention is based on a surprising fact that, if a water-soluble
- organic acid capable of including calcium and/or magnesium ions present in hard water
- the touch feel of clothes may be significantly improved due to low possibility that the
- the present invention is also a water softener itself remains in clothes after laundering.
- the present invention is also a water softener itself remains in clothes after laundering.
- the organic acid of the detergent composition can be prevented from being in
- alkaline substances such as alkaline builder and others generally included
- the organic acid for example an ability of including ions can be maintained during its storage.
- the present invention is also based on the fact that neutralization reaction of acid
- the detergent composition can be used to manufacture a powder detergent.
- the detergent composition can be used to manufacture a powder detergent.
- powder detergent and preferably a low-density powder detergent can be manufactured using bubbles generated by the gas formed in the particle by means of the neutralization reaction.
- the present invention provides a composition of laundry detergent capable of
- touch fell means a feeling that persons feel when
- the touch feel may be
- composition of laundry detergent of the present invention includes (a) 0.1 to
- form of water-soluble polymer may be at least one compound selected from the group
- the acidic form of water-soluble polymer has an advantage that particles of the powder detergent are formed by
- physical properties of the polymer can maintain the shape of the particle when its
- water-soluble polymer preferably has a pH value of 1 to 3.
- composition of laundry detergent of the preset invention includes (b) 5
- the anionic surfactant plays a role of
- Anionic surfactants generally used in compositions of laundry
- detergent may be used as the anionic surfactant of the present invention.
- anionic surfactant of the present invention.
- ethoxylated sulfate and mixtures thereof may be used as the anionic surfactant.
- the powder detergent may be preferably used as the anionic surfactant.
- contents included in the composition may be suitably adjusted within the
- composition of laundry detergent of the present invention includes (c)
- bicarbonate bicarbonate of soda
- sodium sulfate sulfate of soda
- mixtures thereof may be used as the alkaline builder.
- the alkaline builder generally used in
- the powder detergent may reduce the possibility of generating the color-migration in
- the alkaline builder plays a role of
- density of the powder detergent may
- density of the produced composition of laundry detergent may be varied depending on
- anionic surfactant and the alkaline substance such as the alkaline builder, as described
- composition of laundry detergent of the present invention includes (d) 0.5 to 20 parts by weight of an organic acid coated so that it can be separated from the
- composition of laundry detergent of the present invention is a composition of laundry detergent of the present invention
- organic acid which has an ability to include ions and is easily dissolved in
- insoluble zeolite generally used as the water softener.
- the organic acid used in the composition of the present invention is water-soluble, and therefore it shows very low possibility that calcium carbonate and others remain in clothes after
- citric acid anhydrous citric acid
- 1,3-propylenediamine tetraacetic acid succinic acid, fumaric acid, maleic acid,
- O-carboxymethyloxysuccinic acid, tartaric acid, glutamic acid and so on may be used as tartaric acid, glutamic acid and so on.
- the organic acid included is included
- organic acid is not suitably separated from the alkaline components, the organic acid
- composition of laundry detergent may be improved during its storage if the separated organic acid is used in the composition, and therefore washability of the composition of
- laundry detergent may be maintained during its storage.
- composition of laundry detergent is acidic components from the basic components.
- the composition of laundry detergent is acidic components from the basic components.
- the of the present invention includes a coated organic acid so that the coated organic acid
- the present invention relates to the composition of
- laundry detergent including the organic acid modified and handled so that it can be in
- coated organic acid is more preferably 3-50 urn, considering the storage stability and the
- Silica compound, porous starch lysate, polyvinylpyrrolidone, carboxymethylcellulose and so on may be used as the coating material for coating the
- the detergent has an excellent flowability of particles and
- porous starch lysate has an advantage that it is not
- the silica compound is used as the coating material, it preferably has a specific gravity
- the organic acid may be any organic acid.
- the organic acid may be any organic acid.
- coated organic acid of the present invention may be any organic acid of the present invention.
- the coated organic acid of the present invention may be any organic acid of the present invention.
- Hydrophilic materials such as non-ionic surfactant, polyethyleneglycol, etc.
- hydrophobic materials such as silicon compound, fatty acid, etc. may be used for
- the binder component Preferably, at least one material selected from the group consisting of:
- composition of laundry detergent of the present invention may further comprise
- the non-ionic surfactant include 5 to 20 parts by weight of a non-ionic surfactant.
- the non-ionic surfactant include 5 to 20 parts by weight of a non-ionic surfactant.
- the non-ionic surfactant has a content of 5 to 20 parts by weight since its manufacturability may be reduced at
- Non-ionic surfactants used in laundry detergent compositions may be any suitable surfactants used in laundry detergent compositions.
- alkyl ether coconut diethanolamide, fatty acid alkanolamine, amine oxide, alkyl
- polyglucoside methyl polyethylene alkyl ether, sugar ether, etc.
- composition of laundry detergent of the present invention may include
- the water-insoluble water softener in order to aid to formulate powder detergent
- the zeolite is preferably used at a minimum content since the remnant of the zeolite
- composition of laundry detergent of the present invention may further comprise
- the other additives may include a proteolytic enzyme
- protease for removing contaminant proteins
- lipolytic enzyme for removing contaminant proteins
- lipolytic enzyme lipase
- a carbohydrolytic enzyme for removing contaminant foods
- a cellulolytic enzyme for removing fluff of
- Each of the proteolytic enzyme, the lipolytic enzyme, the carbohydrolytic enzyme and the cellulolytic enzyme preferably has a content of 0.01 to 1 parts by weight, the
- fluorescent dye preferably has a content of 0.1 to 1 parts by weight, and the migration
- inhibitor preferably has a content of 0.5 to 5 parts by weight.
- the present invention also provides a manufacturing method capable of
- composition of laundry detergent and preferably a method capable of
- low density means that apparent density
- the present invention uses a principle that the powder detergent is manufactured by implementing granulization of the powder detergent in the neutralization reaction of
- the pores have an advantage of improving the solubility (especially, solubility in cold water) since they prevent the residuals from remaining in
- composition of laundry detergent that is, because the counter-flow spray dryer, the
- Citric acid was used as organic acid to prepare coated organic acid.
- the coated organic acid was prepared from Citric acid.
- organic acid was manufactured by mixing 90 kg of citric acid anhydrous with 4 kg of
- polydimethylsiloxane which is the silicon compound used as the binder component, in
- the mixer for about 1 hour, followed by adding and mixing 6 kg of silica as the coating component.
- compositions were manufactured by the conventional method including step of mixing
- fluorescent dye is Tinopal CBS-X (Ciba Specialty Chemicals).
- a proteolytic enzyme is Savinase 12.0T (Novozymes)
- a cellulolytic enzyme is
- the coated organic acid was mixed with soda ash, and then it was evaluated whether or not caking
- the soda ash is a representative alkaline substance amongst the
- the soda ash powder were mixed at a ratio of 1 :3, namely 100 g of the coated organic
- thermohygrostat with 60% relative
- composition of laundry detergent of the present invention is stable in
- Kawabata system such as KOSHI (Stiffness), SHARI (Crispness), FUKURAMI
- Kawabata System is generally relevant to the value measured by the actual consumers
- present invention shows a low possibility that the water-insoluble substance such as zeolite, etc. remains in clothes, or calcium carbonate is attached to clothes, and also has
- the washing conditions are identical to those of the evaluation of the touch feel
- thermohygrostat 25 ° C , 20 % RH
- R s represents surface reflectivity of the soiled fabrics
- composition of laundry detergent according to the present invention is useful to have very low possibility that calcium carbonate and others remain in clothes after laundering since the softening rate of hard water is highly
- composition of laundry detergent according to the present invention is stable, and
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007544248A JP2008521995A (ja) | 2004-11-30 | 2004-11-30 | 衣類の肌触りを向上させることができる粉末洗剤組成物及びその製造方法 |
EP04822503A EP1828362A4 (fr) | 2004-11-30 | 2004-11-30 | Composition de produit lessiviel ameliorant l'agrement au toucher du tissu et procede de fabrication |
PCT/KR2004/003123 WO2006059811A1 (fr) | 2004-11-30 | 2004-11-30 | Composition de produit lessiviel ameliorant l'agrement au toucher du tissu et procede de fabrication |
CNA2004800445156A CN101068912A (zh) | 2004-11-30 | 2004-11-30 | 改善衣物触感的洗衣洗涤剂组合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/KR2004/003123 WO2006059811A1 (fr) | 2004-11-30 | 2004-11-30 | Composition de produit lessiviel ameliorant l'agrement au toucher du tissu et procede de fabrication |
Publications (1)
Publication Number | Publication Date |
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WO2006059811A1 true WO2006059811A1 (fr) | 2006-06-08 |
Family
ID=36565227
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/KR2004/003123 WO2006059811A1 (fr) | 2004-11-30 | 2004-11-30 | Composition de produit lessiviel ameliorant l'agrement au toucher du tissu et procede de fabrication |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1828362A4 (fr) |
JP (1) | JP2008521995A (fr) |
CN (1) | CN101068912A (fr) |
WO (1) | WO2006059811A1 (fr) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2105277A1 (fr) * | 2008-03-25 | 2009-09-30 | Granula Polymer GmbH | Produit de nettoyage pour dispositifs de traitement de matière synthétique ou de fabrication de matière synthétique, son utilisation, son procédé de fabrication et procédé de nettoyage |
JP2010519377A (ja) * | 2007-02-21 | 2010-06-03 | エルジー ハウスホールド アンド ヘルスケア リミテッド | 酸性の水溶性高分子を含む粉末洗剤粒子及びその製造方法 |
WO2010133829A1 (fr) * | 2009-05-20 | 2010-11-25 | Reckitt Benckiser N.V. | Particules de polycarboxylate cristallin enrobees |
WO2011076769A1 (fr) * | 2009-12-24 | 2011-06-30 | Akzo Nobel Chemicals International B.V. | Particules revêtues d'un agent chélatant à base de n,n-diacétate d'acide glutamique |
CN103865680A (zh) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | 柔软洗衣粉 |
KR20150100548A (ko) * | 2014-02-25 | 2015-09-02 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
WO2015130084A1 (fr) * | 2014-02-25 | 2015-09-03 | 주식회사 엘지생활건강 | Composition pour adoucissant de tissus |
WO2015130085A1 (fr) * | 2014-02-25 | 2015-09-03 | 주식회사 엘지생활건강 | Composition pour assouplissant pour textile |
WO2015130088A1 (fr) * | 2014-02-25 | 2015-09-03 | 주식회사 엘지생활건강 | Composition pour adoucissant de tissus |
KR101776681B1 (ko) | 2014-02-25 | 2017-09-08 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
KR101809786B1 (ko) * | 2014-02-25 | 2017-12-18 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
US11878077B2 (en) | 2019-03-19 | 2024-01-23 | The Procter & Gamble Company | Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6629220B2 (ja) * | 2014-02-25 | 2020-01-15 | エルジー ハウスホールド アンド ヘルスケア リミテッド | 繊維柔軟剤組成物 |
JP6817065B2 (ja) * | 2014-02-25 | 2021-01-20 | エルジー ハウスホールド アンド ヘルスケア リミテッド | 繊維柔軟剤組成物 |
JP6817067B2 (ja) * | 2014-02-25 | 2021-01-20 | エルジー ハウスホールド アンド ヘルスケア リミテッド | 繊維柔軟剤組成物 |
EP3712238A1 (fr) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Procédé de fabrication d'un article fibreux de dose unitaire soluble dans l'eau |
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- 2004-11-30 CN CNA2004800445156A patent/CN101068912A/zh active Pending
- 2004-11-30 WO PCT/KR2004/003123 patent/WO2006059811A1/fr active Application Filing
- 2004-11-30 JP JP2007544248A patent/JP2008521995A/ja active Pending
- 2004-11-30 EP EP04822503A patent/EP1828362A4/fr not_active Withdrawn
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US5753460A (en) * | 1993-10-08 | 1998-05-19 | Novo Nordisk A/S | Amylase variants |
US6031132A (en) * | 1997-12-18 | 2000-02-29 | Nippon Shokubai Co., Ltd. | Amide-group-containing polyacetal and its production process and use |
US6534466B2 (en) * | 1999-01-08 | 2003-03-18 | Genencor International, Inc. | Low-density compositions and particulates including same |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010519377A (ja) * | 2007-02-21 | 2010-06-03 | エルジー ハウスホールド アンド ヘルスケア リミテッド | 酸性の水溶性高分子を含む粉末洗剤粒子及びその製造方法 |
EP2105277A1 (fr) * | 2008-03-25 | 2009-09-30 | Granula Polymer GmbH | Produit de nettoyage pour dispositifs de traitement de matière synthétique ou de fabrication de matière synthétique, son utilisation, son procédé de fabrication et procédé de nettoyage |
WO2010133829A1 (fr) * | 2009-05-20 | 2010-11-25 | Reckitt Benckiser N.V. | Particules de polycarboxylate cristallin enrobees |
WO2011076769A1 (fr) * | 2009-12-24 | 2011-06-30 | Akzo Nobel Chemicals International B.V. | Particules revêtues d'un agent chélatant à base de n,n-diacétate d'acide glutamique |
US9096820B2 (en) | 2009-12-24 | 2015-08-04 | Akzo Nobel Chemicals International B.V. | Coated particles of a glumatic acid N,N-diacetate chelating agent |
CN103865680A (zh) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | 柔软洗衣粉 |
KR20150100548A (ko) * | 2014-02-25 | 2015-09-02 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
WO2015130084A1 (fr) * | 2014-02-25 | 2015-09-03 | 주식회사 엘지생활건강 | Composition pour adoucissant de tissus |
WO2015130085A1 (fr) * | 2014-02-25 | 2015-09-03 | 주식회사 엘지생활건강 | Composition pour assouplissant pour textile |
WO2015130088A1 (fr) * | 2014-02-25 | 2015-09-03 | 주식회사 엘지생활건강 | Composition pour adoucissant de tissus |
KR101776681B1 (ko) | 2014-02-25 | 2017-09-08 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
KR101809786B1 (ko) * | 2014-02-25 | 2017-12-18 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
KR102123613B1 (ko) | 2014-02-25 | 2020-06-17 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
US11878077B2 (en) | 2019-03-19 | 2024-01-23 | The Procter & Gamble Company | Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures |
Also Published As
Publication number | Publication date |
---|---|
EP1828362A1 (fr) | 2007-09-05 |
JP2008521995A (ja) | 2008-06-26 |
EP1828362A4 (fr) | 2009-12-16 |
CN101068912A (zh) | 2007-11-07 |
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