WO2006038708A1 - 伸びと穴拡げ性に優れた高強度薄鋼板およびその製造方法 - Google Patents
伸びと穴拡げ性に優れた高強度薄鋼板およびその製造方法 Download PDFInfo
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- WO2006038708A1 WO2006038708A1 PCT/JP2005/018724 JP2005018724W WO2006038708A1 WO 2006038708 A1 WO2006038708 A1 WO 2006038708A1 JP 2005018724 W JP2005018724 W JP 2005018724W WO 2006038708 A1 WO2006038708 A1 WO 2006038708A1
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- Prior art keywords
- elongation
- steel sheet
- strength
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- thin steel
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 66
- 239000010959 steel Substances 0.000 title claims abstract description 66
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 46
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 24
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims description 41
- 238000001816 cooling Methods 0.000 claims description 32
- 238000000137 annealing Methods 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 17
- 230000009466 transformation Effects 0.000 claims description 14
- 238000005097 cold rolling Methods 0.000 claims description 5
- 238000013461 design Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 238000001953 recrystallisation Methods 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 238000005554 pickling Methods 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 2
- 229910001734 painite Inorganic materials 0.000 claims 1
- 229910001563 bainite Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 230000000717 retained effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 23
- 238000005496 tempering Methods 0.000 description 10
- 230000007423 decrease Effects 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 8
- 238000007747 plating Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000010953 base metal Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000005728 strengthening Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 239000010960 cold rolled steel Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 229910001562 pearlite Inorganic materials 0.000 description 2
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B3/02—Rolling special iron alloys, e.g. stainless steel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/041—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing involving a particular fabrication or treatment of ingot or slab
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0426—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0436—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
- C21D8/0473—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the present invention relates to a high-strength thin steel sheet excellent in elongation and hole expansibility and a method for producing the same.
- the processing method is often performed by simple stamping or bending from the conventional drawing using a sheet presser, especially when the bending ridgeline is a curved line such as an arc.
- the end face of the steel plate is elongated, and the flange is stretched.
- An object of the present invention is to solve the above-described prior art and realize a high-strength thin steel sheet excellent in elongation and hole expansibility and a manufacturing method thereof on an industrial scale.
- the present inventors are to realize a high-strength thin steel sheet that exhibits the above performance at a tensile strength of 500 MPa or more and a manufacturing method thereof on an industrial scale.
- the tensile strength and Si and A1 have a specific relationship to avoid deterioration of chemical conversion treatment and adhesiveness while ensuring an appropriate ferrite area ratio, and Mg, REM
- the steel sheet and its manufacturing method have been found to improve unprecedented press formability by controlling inclusions such as precipitates contained inside by adding Ca to improve local formability. .
- V 0.005 to 1% Ti: 0.002 to 1%, Nb: 0.002 to 1%, Cr: 0.005 to 2%, Mo: 0.005 to 1%, B: 0.0002 to 0.1% , Mg: 0.0005 to 0.01%, REM: 0.0005 to 0.01%, Ca: 0.0005 to 0.01%, or one or more types, characterized by being excellent in elongation and hole expansibility described in (1) Strength thin steel sheet.
- TS target value is the strength design value of steel plate, the unit is MPa, [A1] is the mass of A1
- ferrite is an area ratio 1 Tempered martensite of 0 to 85%, residual austenite of 1 to 10% by volume, and area ratio of 10% to 60% and the balance should have a metal structure of Painai.
- the greatest feature of the structure of the high-strength thin steel sheet according to the present invention is that a metal assembly including ferrite, residual austenite, tempered martensite, and bainite in a well-balanced manner by performing the necessary heat treatment after the annealing and quenching process.
- a weave By obtaining a weave, a material with extremely stable ductility and hole expandability can be obtained.
- C is an important element for strengthening steel and improving hardenability It is indispensable to obtain a composite organization consisting of ferrite, martensite, and bainai. TS ⁇ 500MPa and 0.03% or more is required to obtain a tempered martensite that is advantageous for local formability. On the other hand, when the content increases, iron-based carbides such as cementite are likely to be coarsened and local formability is deteriorated, and the hardness increase after welding is markedly limited to 0.25%. To do.
- Si is a preferable element for increasing the strength without decreasing the workability of the steel.
- it if it is less than 0.4%, it becomes easy to form a pearlite structure that is harmful to the hole expandability, and the solid solution strengthening ability of the ferrite decreases, resulting in a large hardness difference between the formed structures.
- the lower limit is set to 0.4% because it causes deterioration of expansibility. If it exceeds 2.0%, the ferritic solid solution strengthening ability will increase, resulting in a decrease in cold rollability and a decrease in chemical conversion treatment due to the Si oxide formed on the steel sheet surface.
- the upper limit is 2.0% because plating adhesion and weldability are also reduced.
- Mn is an element that delays the formation of carbides and is an effective element for the formation of ferritic soot, in addition to the need to be added to ensure strength. If it is less than 0.8%, the strength is not satisfactory, and the ferrite is not sufficiently formed and the ductility deteriorates. If it exceeds 3.1%, the martensite will be excessive, resulting in an increase in strength and deterioration of ductility and workability, so 3.1% is the upper limit.
- S is a harmful element because it remains as sulfide inclusions such as MnS.
- the higher the strength of the base metal the more conspicuous the effect is. It should be suppressed to 0.02% or less when the tensile strength is 500 MPa or more.
- T i is added, precipitation occurs as a soot sulfide, so it is somewhat relaxed.
- Al is an element necessary for deoxidation of steel, but if it exceeds 2.0%, inclusions such as alumina increase and workability is impaired, so 2.0% is made the upper limit. In order to improve ductility, addition of 0.2% or more is preferable.
- N exceeds 0.01%, the aging and workability of the base metal deteriorate, so 0.01% is made the upper limit.
- TS target value is the strength design value of steel plate, unit is MPa, [Al] is Al mass%, [Si] is Si mass%
- addition amount of A1 and Si is (0.0012X [TS target value]-0.29) / 3 or less, it is not sufficient to improve the ductility, and if it is 1.0 or more, the chemical conversion processability and the adhesiveness of the adhesive deteriorate.
- V can be added in the range of 0.005 to 1% for the purpose of improving the strength.
- Ti is an element effective in reducing harmful MnS by forming ⁇ -based sulfides with the purpose of improving strength and having relatively little effect on local formability. It also has the effect of suppressing the coarsening of the weld metal structure and making it difficult to become brittle. To achieve these effects, less than 0.002% is insufficient, so 0.002% is set as the lower limit. However, when added in excess, coarse and square TiN increases and local formability deteriorates, as well as stable carbide is formed, and the C concentration in the austenite cocoon decreases during the production of the base material. The desired hardened structure cannot be obtained, and it is difficult to secure the tensile strength, so 1.0% is made the upper limit.
- Nb is an element effective for improving the strength and forming fine carbides that suppress the softening of the heat affected zone. If it is less than 0.002%, the effect of suppressing the softening of the weld heat affected zone is sufficient. Since it cannot be obtained, the lower limit is 0.002%. On the other hand, if added in excess, the machinability of the base material decreases due to an increase in carbides, so 1.0% is made the upper limit.
- Cr can also be added as a strengthening element, but if it is less than 0.005%, no effect is obtained, and if it exceeds 2%, ductility and chemical conversion properties deteriorate, so the range is 0.005% to 2%.
- Mo is an element that is effective in securing strength and hardenability, and makes it easy to obtain a bainitic structure.
- it has the effect of suppressing the softening of the weld heat affected zone, and it is thought that the effect is enhanced by coexistence with Nb, etc., and the effect is insufficient at less than 0.005%, and the lower limit is 0.005%.
- the upper limit is 1%.
- B is an element that improves the hardenability of steel and has the effect of suppressing the softening by suppressing the C diffusion in the weld heat affected zone through the interaction with C. Addition of more than 0002% is required. On the other hand, if added in excess, not only the workability of the base metal is lowered, but also the steel becomes brittle and the hot workability is lowered, so the upper limit is 0.1%.
- Mg is combined with oxygen to form an oxide by this addition, but this is a composite of MgO or MgO containing A 1 2 0 3 , S i 0 2 , MnO, T i 2 0 3, etc. The compound is considered to precipitate very finely.
- REM is considered to be an element that has the same effect as Mg. Although it has not been fully confirmed, it is considered an element that can be expected to improve hole expansion and stretch flangeability due to the effect of suppressing cracks due to the formation of fine oxides. Since this is sufficient, the lower limit is set to 0.0005%. On the other hand, addition over 0.01% not only saturates the amount of improvement for the added amount, but also deteriorates the cleanliness of the steel and deteriorates the hole expandability and stretch flangeability. The upper limit is%.
- Ca has the effect of improving the local formability of the base metal by controlling the morphology (spheroidization) of sulfide inclusions. However, if less than 0.0005%, the effect is insufficient. % Is the lower limit. Addition of excessive amount not only saturates the effect, but also causes an adverse effect (local formability deterioration) due to an increase in inclusions, so the upper limit is set to 0.0 1%.
- the reason why the steel sheet structure is a composite structure of ferrite, residual austenite, tempered martensite, and bainite is In addition, this is to obtain a steel sheet having excellent elongation and hole expandability.
- Ferrite refers to polygonal feral ⁇ and pay feral ⁇ .
- the greatest feature in the metal structure of the high-strength thin steel sheet is that the steel has a tempered martensite in an area ratio of 10% to 60%. This tempered martensite is obtained by heat treatment in which the martensite cocoon produced during the cooling process of annealing is kept at 150 to 400 ° C for 1 to 20 minutes after cooling below the martensite transformation temperature, and further from the above holding temperature.
- tempered into a tempered martensite structure by holding for 1 to 100 seconds at a high temperature of 50 to 300 ° C and below 500 ° C.
- the area ratio of the tempered martensite is less than 10%, the hardness difference between the structures becomes too large and the hole expansion rate is not improved, whereas when it exceeds 60%, the steel sheet strength is too low.
- the ratio of elongation and hole expansion is remarkably improved by the presence of a well-balanced steel plate with 10 to 85% ferritite and 1 to 10% residual austenite in volume ratio. it is conceivable that. If the ferrite area ratio is less than 10%, sufficient elongation cannot be secured.
- the strength is insufficient, which is not preferable.
- residual austenite of 1% or more remains, and when the residual austenite volume ratio exceeds 10%, the residual austenite is transformed into martensite by processing. At times, at the interface between the martensite phase and the surrounding phase, a poise and many dislocations are generated, hydrogen accumulates in such a place, and the delayed fracture characteristics are inferior.
- Hot finish rolling in the temperature range of 800-950 ° C, and roll up to 700 ° C or less to make a hot rolled steel sheet. If the hot rolling finish temperature is less than 800 ° C, the grains become mixed and the workability of the base metal is lowered. Above 950 ° C, austenite grains become coarse and the desired micro structure cannot be obtained.
- a lower coiling temperature can suppress the formation of partite structure, but considering the cooling load, it is preferably in the range of 400 to 600 ° C.
- the cold rolling ratio is preferably 30 to 80% in terms of rolling load and material.
- the annealing temperature is important for ensuring the predetermined strength and heat resistance of the high-strength steel sheet, and is preferably 600 ° C to Ac 3 + 50 ° C. If the temperature is less than 600 ° C, sufficient recrystallization is not performed, and it is difficult to stably obtain the workability of the base material itself. On the other hand, if it exceeds Ac 3 +50 ° C, the austenite grain size becomes coarse, ferrite formation is suppressed, and it becomes difficult to obtain a desired microstructure. In order to obtain a microstructure defined in the present invention, a method by continuous annealing is preferable.
- the average cooling rate is set to 30 ° C / s or less, and 10 ° C / s or less is more preferable. .
- a temperature of 100 to 400 ° C or a martensite transformation point temperature of 400 ° C is preferable.
- the temperature is held at 150 to 400 ° C for 1 to 20 minutes and cooled.
- the martensite is not tempered, the hardness difference between the structures is large, and the bainitic transformation is insufficient, and the prescribed ductility and hole expandability cannot be obtained. If it exceeds 400 ° C, it will be tempered too much and the strength will decrease.
- the upper limit is not more than the martensite transformation point.
- the lower limit it is preferable to set the lower limit to exceed the martensite transformation point.
- tempering or transformation hardly progresses or is incomplete, and the ductility and hole expansion rate do not improve. Over 20 minutes, tempering and transformation are almost complete, so there is no effect even if extended.
- the heating and holding process may be continuous with the continuous annealing line or a separate line, but it may be performed continuously with the continuous annealing equipment or in the overaging furnace of the continuous annealing line. It is preferable in terms of productivity.
- the heating and holding step is the first heating and holding step. After heating and holding at 0 to 400 ° C or less and holding for 1 to 20 minutes, as the second heating and holding process, the temperature is 30 to 300 ° C higher than the holding temperature of the first heating and holding process, and 5 It is desirable to cool it after holding it at 00 ° C or below for 1 to 100 seconds.
- the martensite is not tempered and the hardness difference between the structures increases, and the prescribed ductility and hole expandability are obtained. Absent. If the temperature of the second heating and holding step is higher than the holding temperature of the first heating and holding step + 300 ° C., it is tempered and the strength is lowered, which is not preferable.
- tempering hardly progresses or is incomplete, and the ductility and hole expansion rate do not improve. If it exceeds 100 seconds, tempering is almost complete, so extending it will have no effect.
- the heating and holding step is the first heating and holding step. Hold at 1400 ° C or lower, hold for 1-20 minutes, then cool to below the martensite transformation point, hold for 1 to 100 seconds at 500 ° C or lower, above the end temperature of cooling It is desirable to cool after performing the heating and holding. Tempering martensite can be ensured by ensuring that the temperature in the second heating and holding process is the cooling end temperature when cooling below the martensite transformation point + 50 to 300 ° C and 500 ° C or less. Is preferable.
- the temperature of the second heating and holding step is lower than the cooling end temperature, the martensite is not tempered and the hardness difference between the structures becomes large, and the predetermined ductility and hole expandability cannot be obtained.
- the lower limit of the temperature of the second heating and holding step is more preferably the cooling end temperature + 50 ° C. and the martensite transformation point or higher, and more preferably the cooling end temperature + 300 ° C. If the temperature of the second heating and holding process exceeds 500 ° C, it is tempered too much and the strength decreases, which is preferable. It ’s not.
- tempering hardly progresses or is incomplete, and ductility and hole expansion rate do not improve. If it exceeds 100 seconds, tempering is almost complete, so extending it will have no effect.
- the steel plate may be either a cold rolled steel plate or a plated steel plate.
- the normal plating may be either zinc or aluminum plating.
- Plating may be either melt or electric plating, and may be alloyed after plating or may be multi-layer plating. Further, a steel sheet obtained by subjecting a steel sheet not subjected to plating to film lamination on a laid steel sheet does not depart from the present invention.
- test methods used in the present invention are as follows.
- Tensile properties Evaluated by conducting a tensile test perpendicular to the rolling direction of JIS No. 5 tensile test piece
- Ferai wrinkle area ratio Ferrite is observed with nital etching. Ferai wrinkle area ratio is quantified with nital etching.
- the sample is polished (alumina finish), immersed in a corrosive liquid (mixed solution of pure water, sodium pyrosulfite, ethyl alcohol, and picric acid) for 10 seconds, polished again, washed with water, and the sample is washed. Dry with cold air. After drying, the tissue of the sample was multiplied by 1000, and the area of 100 H m X 100 I m was measured with a Luzex device to determine the area percentage of the ferrite. In each table, this area ratio of ferrite was expressed as ferrite area%.
- the tempered martensite area ratio is quantified by repeller etching.
- the sample is polished (alumina finish) and then immersed in a corrosive solution (pure water, sodium bisulphite, ethyl alcohol, and picric acid) for 10 seconds. After soaking, grind again, rinse with water and dry the sample with cold air. After drying, the area of 100 II m x 100 m area was measured with a Luzex apparatus at 1000 times the texture of the sample and the area% of tempered martensite was determined. In each table, this tempered martensite area ratio is expressed as tempered martensite area%.
- Residual austenite volume ratio On the surface that has been chemically polished to a thickness of 1/4 from the surface layer of the specimen plate, (2 0 0), (2 1 0) Residual austenite was quantified from the (2 0 0), (2 2 0), and (3 1 1) area strengths of the stenite and used as the residual austenite volume fraction. A residual austenite volume fraction of 1-10% or more was considered good. In each table, this residual austenite volume fraction is expressed as the residual volume.
- Table 3 shows the test results of the comparative example of experiment number [8] shown in Table 2 of Example 1. Further, the test Wa results of the experiment number [2] of the present invention are shown in Table 4, and the experiment number
- Table 6 shows [6] and Table 6 shows the experiment number [9].
- the test results of Example 2 are shown in Table 7.
- Example 1 As a comparative example, when the experiment number [8] similar to the conventional operating conditions is compared with the experiment number [2] [6] [9] of the present invention example, the hole expansion rate is higher in the present invention example. When the elongation shows a good value, the force is high.
- Example 2 Furthermore, when the tempering conditions were changed and compared, in Experiment Nos. [4] and [7] with a high tempering temperature, the strength was greatly reduced, and the elongation was rather lowered. The decrease in growth is thought to be due to the occurrence of a pair light. Experiment No. [1] [2] [5] [6] ⁇ 9] The present invention showed good results.
- the present invention it is possible to provide a high-strength thin steel sheet excellent in elongation and hole expansibility used for automobile parts and the like, and a manufacturing method thereof, and its industrial value is extremely large.
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Abstract
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Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
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CA2582409A CA2582409C (en) | 2004-10-06 | 2005-10-05 | High strength thin-gauge steel sheet excellent in elongation and hole expandability and method of production of same |
EP13189987.4A EP2690191B1 (en) | 2004-10-06 | 2005-10-05 | A method of production of high strength thin-gauge steel sheet excellent in elongation and hole expandability |
EP05793806.0A EP1808505B1 (en) | 2004-10-06 | 2005-10-05 | Cold rolled high strength thin-gauge steel sheet excellent in elongation and hole expandibility |
ES05793806T ES2712142T3 (es) | 2004-10-06 | 2005-10-05 | Lámina de acero de calibre fino de alta resistencia laminada en frío excelente en elongación y capacidad de expansión de agujeros |
US11/663,581 US20080000555A1 (en) | 2004-10-06 | 2005-10-05 | High Strength Thin-Gauge Steel Sheet Excellent in Elongation and Hole Expandability and Method of Production of Same |
PL05793806T PL1808505T3 (pl) | 2004-10-06 | 2005-10-05 | Blacha stalowa cienka walcowana na zimno o dużej wytrzymałości oraz doskonałym wydłużeniu i podatności na powiększenie otworu |
CN2005800342050A CN101035921B (zh) | 2004-10-06 | 2005-10-05 | 延伸率和扩孔性优良的高强度薄钢板及其制造方法 |
PL13189987T PL2690191T3 (pl) | 2004-10-06 | 2005-10-05 | Sposób wytwarzania blachy stalowej cienkiej o dużej wytrzymałości oraz doskonałym wydłużeniu i podatności na powiększanie otworu |
US12/583,846 US8137487B2 (en) | 2004-10-06 | 2009-08-27 | Method of production of high strength thin-gauge steel sheet excellent in elongation and hole expandability |
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JP2004293990A JP4445365B2 (ja) | 2004-10-06 | 2004-10-06 | 伸びと穴拡げ性に優れた高強度薄鋼板の製造方法 |
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US11/663,581 A-371-Of-International US20080000555A1 (en) | 2004-10-06 | 2005-10-05 | High Strength Thin-Gauge Steel Sheet Excellent in Elongation and Hole Expandability and Method of Production of Same |
US12/583,846 Division US8137487B2 (en) | 2004-10-06 | 2009-08-27 | Method of production of high strength thin-gauge steel sheet excellent in elongation and hole expandability |
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EP (2) | EP2690191B1 (ja) |
JP (1) | JP4445365B2 (ja) |
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CN (2) | CN101851730A (ja) |
CA (1) | CA2582409C (ja) |
ES (2) | ES2712142T3 (ja) |
PL (2) | PL2690191T3 (ja) |
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CN115003841A (zh) * | 2020-01-31 | 2022-09-02 | 杰富意钢铁株式会社 | 钢板、部件及它们的制造方法 |
WO2021172298A1 (ja) * | 2020-02-28 | 2021-09-02 | Jfeスチール株式会社 | 鋼板、部材及びそれらの製造方法 |
JP7006848B1 (ja) * | 2020-02-28 | 2022-01-24 | Jfeスチール株式会社 | 鋼板、部材及びそれらの製造方法 |
JP7006849B1 (ja) * | 2020-02-28 | 2022-01-24 | Jfeスチール株式会社 | 鋼板、部材及びそれらの製造方法 |
JP7020594B2 (ja) | 2020-02-28 | 2022-02-16 | Jfeスチール株式会社 | 鋼板、部材及びそれらの製造方法 |
JPWO2021172297A1 (ja) * | 2020-02-28 | 2021-09-02 | ||
WO2021172299A1 (ja) * | 2020-02-28 | 2021-09-02 | Jfeスチール株式会社 | 鋼板、部材及びそれらの製造方法 |
WO2021172297A1 (ja) * | 2020-02-28 | 2021-09-02 | Jfeスチール株式会社 | 鋼板、部材及びそれらの製造方法 |
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US20080000555A1 (en) | 2008-01-03 |
US8137487B2 (en) | 2012-03-20 |
EP1808505B1 (en) | 2018-11-28 |
EP1808505A1 (en) | 2007-07-18 |
EP2690191A2 (en) | 2014-01-29 |
US20090314395A1 (en) | 2009-12-24 |
TW200615387A (en) | 2006-05-16 |
ES2712177T3 (es) | 2019-05-09 |
CA2582409C (en) | 2012-02-07 |
CN101035921A (zh) | 2007-09-12 |
CN101035921B (zh) | 2012-07-04 |
TWI305232B (en) | 2009-01-11 |
PL1808505T3 (pl) | 2019-05-31 |
EP2690191A3 (en) | 2017-03-01 |
JP2006104532A (ja) | 2006-04-20 |
ES2712142T3 (es) | 2019-05-09 |
KR20070061859A (ko) | 2007-06-14 |
PL2690191T3 (pl) | 2019-05-31 |
EP1808505A4 (en) | 2012-04-25 |
CA2582409A1 (en) | 2006-04-13 |
EP2690191B1 (en) | 2018-11-28 |
JP4445365B2 (ja) | 2010-04-07 |
CN101851730A (zh) | 2010-10-06 |
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