WO2006038615A1 - エアゾール容器の流量レギュレータユニット,エアゾール容器の流量レギュレータ機構およびエアゾール式製品 - Google Patents
エアゾール容器の流量レギュレータユニット,エアゾール容器の流量レギュレータ機構およびエアゾール式製品 Download PDFInfo
- Publication number
- WO2006038615A1 WO2006038615A1 PCT/JP2005/018348 JP2005018348W WO2006038615A1 WO 2006038615 A1 WO2006038615 A1 WO 2006038615A1 JP 2005018348 W JP2005018348 W JP 2005018348W WO 2006038615 A1 WO2006038615 A1 WO 2006038615A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- flow rate
- passage
- contents
- rate regulator
- space
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/44—Valves specially adapted therefor; Regulating devices
Definitions
- Aerosol container flow rate regulator unit Aerosol container flow rate regulator unit, aerosol container flow rate regulator mechanism and aerosol products
- the present invention relates to a flow rate regulator unit for an aerosol container in which contents are injected into an external space by the action of a discharge gas (compressed gas, liquid gas).
- a discharge gas compressed gas, liquid gas
- the content of the aerosol container that opens and closes according to the operation of the user It is intended for the flow rate regulator unit that is installed between the housing for the stem provided with the hole for the passage and the passage part downstream thereof, and the suction pipe for the container contents.
- a flow rate regulator mechanism that connects an air compression area for moving the flow rate stabilizing member that changes the content passage space inside the housing and an external space via an air passage formed in the stem, etc.
- the flow rate regulator unit and the flow rate regulator mechanism are used, for example, when the pressure of the compressed gas inside the container body is high at the initial stage of use or when the pressure inside the container body is reduced by subsequent use. Even in such a case, the content injection amount per unit time to the external space does not fluctuate significantly.
- the amount of injection of the contents will vary.
- a flow rate regulator that suppresses the change in the content injection amount associated with the pressure drop of the gas discharged from the aerosol container is incorporated in the operation button itself or the nosing itself, or on the content inflow side of the suction pipe. Some are attached (see Patent Documents 1 and 2).
- Patent Document 1 Japanese Patent Laid-Open No. 2004-42980
- Patent Document 2 Japanese Patent Laid-Open No. 2002-347863
- the present invention is a unit structure in which the flow rate regulator for further improvement is a unit structure independent of the original components (operation buttons, housing, etc.) of the aerosol container, and the suction pipe is attached to the housing inlet side. It can be attached to the part, ie, the contents passage after that (unlike the suction pipe) can be deformed or bent.
- the present invention simplifies the work for assembling the regulator, such as attaching a unit-type flow rate regulator between the nosing and the suction pipe, and the contents controlled by the flow rate regulator.
- the purpose of this is to provide a stable injection of the contents of the container through the internal passage areas of the housing, stem, and operation buttons that are free from deformation and bending.
- the air compression area for moving the flow stabilizing member that changes the content passage space inside the housing and the external space are communicated with each other, whereby the air accompanying the movement of the flow stabilizing member The purpose is to reliably avoid the compression problem and make the flow regulator mechanism itself compact.
- Aerosol container force by the action of the gas to be released
- the contents passage hole which is opened and closed according to the user's operation of the aerosol container and
- a flow rate regulator unit (for example, a flow rate regulator unit 10 to be described later) used by being attached between (for example, a housing 41 described later) and a suction pipe (for example, a suction pipe 42 to be described later) for the container contents. , 20, 30)
- the contents inflow side cylindrical part to which the suction pipe is attached (for example, cylindrical hanging parts 11a, 21a, 37a described later),
- a contents outflow side cylindrical portion (for example, an extended portion 12c, 26a, 31a described later) attached to a cylindrical portion (for example, a small diameter portion 41a described later) of the housing,
- a passage space from the content inflow side cylindrical portion to the content outflow side cylindrical portion (for example, between the suction pipe 42 and the groove 16a in FIG. 2—the inner peripheral surface of the cylinder 11 and the inner cylinder 12 Space area between the outer peripheral surface of the inner surface of the piston 13-the upper inlet portion of the lateral hole 12a A-groove portion 12b- space area between the flow control valve 14 and the lower lid 16 6;
- a part of the passage space of the contents for example, an upper inlet portion described later
- A, lower inlet part B, inlet part C a part of the passage space of the contents
- a flow stabilizing member for example, a flow regulating valve 14, 24, 34 described later
- An elastic member for example, coil springs 15, 25, 35 described later for applying the predetermined urging force to the flow rate stabilizing member
- suction pipe is attached to the content inflow side cylindrical portion of the flow rate regulator unit of (1), and the content outflow side cylindrical portion is connected to the suction pipe corresponding cylinder of the housing. Attached to the shape,
- An aerosol container flow rate regulator mechanism is used.
- a horizontal passage 61a) and a content passage portion downstream thereof for example, an annular passage described later.
- a flow rate regulator mechanism used inside a housing (for example, a lower housing portion 51 and an upper housing portion 52 described later) with respect to a stem (for example, a stem 61 described later) provided with a passage 61b),
- Space area for passage from the content inflow portion of the housing for example, a vertical hole 5 la described later
- the content passage hole for example, the vertical groove 51a—the groove 51 next to the rib 51b—the horizontal hole 53 in FIG. 8
- An elastic member for example, a coil spring 57 described later for applying the predetermined urging force to the flow rate stabilizing member
- An air compression space area for moving the flow rate stabilizing member for example, an air upper space area 58, an air lower space area 59 described later
- An air passage portion (for example, an upstream air passage 61c described later) formed at least in the stem to communicate the moving air compression space with an external space;
- an operation button for example, an operation button 60 to be described later
- an external air passage air passage portion for example, a downstream air passage 60b described later
- the present invention is directed to a flow rate regulator unit and a flow rate regulator mechanism of an aerosol container having such a constitutional force, and is equipped with this flow rate regulator mechanism to discharge gas and contents inside the container.
- the contained aerosol type products are also covered.
- the present invention has a unit structure in which the flow rate regulator is attached and fixed to the suction pipe mounting portion and the suction pipe on the housing inlet side of the aerosol container as described above. Assembling work of the flow rate regulator can be simplified, and the suction pipe that may be deformed or bent is removed from the passage to the flow hole of the flow rate regulator. Therefore, stable injection of the container contents can be achieved.
- FIG. 1 is an explanatory view showing a flow rate regulator mechanism (part 1, still mode). (Example 1)
- FIG. 2 is an explanatory view showing a specific timing state (when the upper inlet portion A is opened) in the flow rate regulator mechanism of FIG. (Example 1)
- FIG. 3 is an explanatory view showing a flow rate regulator mechanism (part 2, stationary mode). (Example 2)
- FIG. 4 is an explanatory view showing a specific timing state (when the lower inlet portion B is opened) in the flow rate regulator mechanism of FIG. 3. (Example 2)
- FIG. 5 is an explanatory view showing a flow rate regulator mechanism (part 3, still mode). (Example 3)
- FIG. 6 is an explanatory view showing a specific timing state (when the inlet portion C is opened) in the flow rate regulator mechanism of FIG. (Example 3)
- FIG. 5 is an explanatory view showing a flow rate regulator mechanism (part 3, still mode). (Example 4)
- FIG. 8 shows a specific timing condition (inlet part D in the flow rate regulator mechanism of Fig. 7.
- a bottomed cylindrical upper receiving portion that is held between the annular flange and the outer bottom surface of the upper housing portion 52 and accommodates and guides a flow rate adjusting valve 56 described later.
- Coil spring for a flow regulator that is arranged between the ceiling surface of the upper receiving part 54 and the concave part on the upper surface of the flow control valve 56 and urges the flow control valve downward.
- Operation buttons 60a A passage for jetting contents extending in the longitudinal direction
- Coil spring for content injection disposed between the bottom surface of the upper housing portion 52 and the step portion of the stem 61 and biasing the stem upward
- the first main feature of the present invention is that a flow regulator is connected to a discharge head (operation button), a stem, a housing, and a suction unit, which are essential components of an aerosol container.
- a discharge head operation button
- a stem a stem
- a housing a housing
- a suction unit which are essential components of an aerosol container.
- it is provided in the form of a unit that is externally attached between the housing and the suction pipe rather than being formed inside the pipe.
- the second main feature (see Fig. 7 and Fig. 8) is that the air compression area for moving the flow stabilizing member that changes the content passage space by movement based on the gas pressure inside the container and a predetermined elastic force. And communicating with external space.
- the flow regulator units 10, 20, 30 and the flow regulator mechanism 50 (excluding coil springs 15, 25, 35, 57, 62 and stem gasket 64, annular lano 65, mounting cap 66 are excluded. )
- Each component, and the nozzle 41, suction pipe 41, suction pipe 42, etc., are made of plastic such as polypropylene, polyethylene, polyacetanol, nylon, polybutylene terephthalate.
- the coil springs 15, 25, 35, 57, 62 are made of stainless steel or plastic.
- the stem gasket 64 and the annular rubber 65 are made of acrylo-tolyl butadiene rubber (NBR), butyl rubber (IIR), and other rubber seals.
- the material of the mounting cap 66 is tinplate or aluminum material.
- any elastic member such as various types of springs and plate panels may be used in place of the coin springs 15, 25, 35, 57, 62!
- both the compressed gas and the liquid gas are used as the contents discharge gas.
- the compressed gas is used for the sake of convenience of explanation. To do.
- the inner cylinder 12 of the flow rate regulator unit 10 of Figs. 1 and 2 is formed with an extending portion 12c for fitting into the small diameter portion 41a of the existing housing 41. Further, the cylinder 11 that forms the content passage with the inner cylinder is provided with a cylindrical hanging part 1 la for attaching the existing suction pipe 42.
- the inner cylinder 12 accommodates a piston 13 biased downward by a coil spring 15, a flow rate adjusting valve 14 fitted and integrated with the piston, and the like.
- the inner space of the container body (not shown) and the suction pipe 42 "between the grooves 16a—between the inner peripheral surface of the cylinder 11 and the outer peripheral surface of the inner cylinder 12"
- the upper inlet portion A is set to a substantially closed state or a narrow state by the flow rate adjusting valve 14.
- the timing of transition from Fig. 1 to Fig. 2 (the total time of the upper inlet portion A in the substantially closed state) is mainly determined by the biasing force of the coil spring 15, which is a constant, and vice versa.
- the transition timing from Fig. 2 to Fig. 1 (the total open time of upper inlet part A) is based on the gas pressure!
- the substantially closed state time width tl (duration in FIG. 1) per vertical movement of the upper inlet portion A is a substantially constant value based on the urging force of the coil spring 15, while
- the open state time duration t2 (duration in Fig. 2) per cycle becomes shorter as the gas pressure inside the container body is higher.
- the substantially closed state time width tl when shifting to the wide state of 2 also acts on the lower surface portion 14b of the flow rate adjusting valve 14 until then, and the pressure corresponding to the urging force of the coil spring 15 corresponds. Since it is related to the time span to drop to the predetermined value, the higher the pressure (gas pressure inside the container), the longer.
- the flow rate regulator unit 20 shown in Figs. 3 and 4 is provided with a connecting member 26 for fitting the cylinder 21, the sheath 22 and the like into the small diameter portion 41a of the housing 41. It has been.
- the cylinder 21 is provided with a cylindrical hanging portion 21a for attaching the suction pipe 42, and the sheath-like portion 22 is fitted with the piston 23 biased upward by the coil spring 25 and this.
- the flow control valve 24 in the state is accommodated.
- the content passage hole of the stem (not shown) following this passage space area is closed with a well-known stem gasket, and the pressure in the passage space area is the same as that in the container (atmospheric pressure). It is also a force that is at high pressure. That is, this high pressure acts on the upper surface 23a of the piston 23, and pushes down the piston and the flow rate adjusting valve 24 against the urging force of the coil spring 25.
- the time until the piston is lowered to the extent that the piston is lowered against the urging force of the coil spring 25 is short when the gas pressure inside the container is high, and becomes longer as the gas pressure decreases. In this way, the content discharge amount is stabilized against changes in the gas pressure inside the container.
- the time width when the inlet portion B in FIG. 3 shifts to the wide state in FIG. 4 is such that the pressure that has been applied to the upper surface 23a of the piston 23 corresponds to the biasing force of the coil spring 25. Since it is related to the time width to drop to a predetermined value, it becomes longer as the pressure is higher.
- the ratio of the inlet portion B occupying the wide state of Fig. 4 per unit time (the ratio of the time during which the contents can pass) is made smaller than when the pressure is low. This ensures that the content flow rate per unit time released to the external space is stable regardless of changes in gas pressure!
- the cylinder 31 of the flow rate regulator unit 30 in Figs. 5 and 6 is provided with an extending portion 31a for fitting into the small diameter portion 41a of the housing 41.
- the cylinder 31 is provided with a joint 37 for attaching the suction pipe 42, and the piston 33 urged downward by the coil spring 35, the flow rate adjusting valve 34, and the flow rate adjusting valve.
- a bush 36 and the like that form an inlet portion C are accommodated between the two.
- the ratio of the inlet portion C occupying the wide state in FIG. 6 per unit time (the ratio of the time during which the contents can pass) is made smaller than when the pressure is low. In this way, the content flow rate per unit time released to the external space is stabilized against changes in gas pressure.
- the upper space 58 for the air inside the housing and its own volume changes in accordance with the movement of the "piston 55 + flow rate adjustment valve 56" for the flow rate regulator.
- the lower air space 59 is communicated with the external space by the upstream air passage 6 lc of the stem 61 and the downstream air passage 60 b of the operation button 60.
- the upstream air passage 61c may be formed so that the output side thereof opens to the outer peripheral surface of the stem between the mounting cap 66 and the operation button 60. In this case, the downstream air passage 60b of the operation button 60 is not necessary.
- the upstream air passage is a dedicated air passage different from the content injection passage.
- the flow rate regulator mechanism 50 is roughly
- 'Ha a horizontal hole 61a and an annular passage 61b for passing contents from the buffer space 63 to the injection passage 60a, and an upstream air passage 61c from the upper air space 58 to the downstream air passage 60b.
- the reverse skirt-like part 55a of the piston 55 and the lower skirt-like part 56a of the flow regulating valve 56 are the inner circumferences of the lower receiving part 53 (other than the lateral hole 53a for the flow regulator), respectively.
- the tip of the upper skirt-like portion 56b of the flow regulating valve 56 is in close contact with the inner peripheral surface of the upper receiving portion 54.
- the so-called air storage space of the upper air space 58, the internal passage 55b, and the lower air space 59 is dedicated to the air sealed from the content injection passage (see FIG. 8).
- the passage communicates with the external space.
- the inlet portion D in the content injection passage is set to a substantially closed state or a narrow state by the flow rate adjusting valve 56.
- the entrance D is opened and the state shifts to the closed state.
- the ratio of the inlet portion D occupying the wide state in Fig. 8 per unit time (the ratio of the time during which the contents can pass) is smaller than when the pressure is low. By doing so, the content flow rate per unit time released to the external space is stabilized against changes in gas pressure.
- the contents of the container include various properties such as liquid, foam (foam), paste, jewel, and powder.
- Aerosol products to which the present invention is applied include cleaning agents, cleaning agents, antiperspirants, cooling agents, muscle anti-inflammatory agents, hair styling agents, hair treatment agents, hair dyes, hair restorers, cosmetics, and shavings.
- adhesives and lubricants are various applications such as adhesives and lubricants.
- the contents stored in the container main body are, for example, a powdery substance, an oil component, an alcohol, a surfactant, a polymer compound, and an active ingredient according to each application.
- metal salt powder inorganic powder, rosin powder or the like is used.
- talc kaolin, aluminum hydroxychloride (aluminum salt), calcium alginate, gold powder, silver powder, mica, carbonate, barium sulfate, cellulose, and mixtures thereof are used.
- oil component silicone oil, palm oil, eucalyptus oil, camellia oil, olive oil, jojoba oil, paraffin oil, myristic acid, palmitic acid, stearic acid, linoleic acid, linolenic acid and the like are used.
- alcohols examples include monovalent lower alcohols such as ethanol, monovalent higher alcohols such as lauryl alcohol, and polyhydric alcohols such as ethylene glycol.
- Surfactants include anionic surfactants such as sodium lauryl sulfate, nonionic surfactants such as polyoxyethylene oleyl ether, amphoteric surfactants such as lauryl dimethylamino betaine acetate, salts Power such as alkyltrimethyl ammonium thione surfactant is used.
- anionic surfactants such as sodium lauryl sulfate
- nonionic surfactants such as polyoxyethylene oleyl ether
- amphoteric surfactants such as lauryl dimethylamino betaine acetate
- salts Power such as alkyltrimethyl ammonium thione surfactant is used.
- As the polymer compound methyl cellulose, gelatin, starch, casein and the like are used.
- Active ingredients according to each application include anti-inflammatory analgesics such as methyl salicylate and indomethacin, antibacterial agents such as sodium benzoate and talesol, insect repellents such as hillesroid and jettilamide, Antiperspirants such as zinc, softeners such as camphor and menthol, anti-asthma drugs such as ephedrine and adrenaline, sweeteners such as sucralose and aspartame, adhesives and paints such as epoxy resin and urethane, noraf-rangeamamine, Use dyes such as aminophenol, fire extinguishing agents such as ammonium dihydrogen phosphate, sodium bicarbonate and potassium.
- analgesics such as methyl salicylate and indomethacin
- antibacterial agents such as sodium benzoate and talesol
- insect repellents such as hillesroid and jettilamide
- Antiperspirants such as zinc
- softeners such as camphor and menthol
- anti-asthma drugs
- suspending agents In addition to the above-mentioned contents, suspending agents, ultraviolet absorbers, emulsifiers, humectants, antioxidants, sequestering agents, and the like can also be used.
- Gases for releasing contents in aerosol-type products include carbon dioxide, nitrogen gas, compressed air, oxygen gas, rare gas, and mixed gases such as these, liquid petroleum gas, dimethyl ether, and fluorocarbon.
- a liquefied gas such as
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- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Nozzles (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/576,620 US20080017672A1 (en) | 2004-10-07 | 2005-10-04 | Flow Rate Regulator Unit For Aerosol Container, Flow Rate Regulator Mechanism For Aerosol Container And Aerosol Type Product |
JP2006539295A JP4471130B2 (ja) | 2004-10-07 | 2005-10-04 | エアゾール容器の流量レギュレータユニット,エアゾール容器の流量レギュレータ機構およびエアゾール式製品 |
EP05790530A EP1818279A4 (en) | 2004-10-07 | 2005-10-04 | FLOW CONTROL UNIT FOR AEROSOL CONTAINER, FLOW CONTROL MECHANISM FOR AEROSOL CONTAINER, AND AEROSOL-LIKE PRODUCT |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004295410 | 2004-10-07 | ||
JP2004-295410 | 2004-10-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006038615A1 true WO2006038615A1 (ja) | 2006-04-13 |
Family
ID=36142688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/018348 WO2006038615A1 (ja) | 2004-10-07 | 2005-10-04 | エアゾール容器の流量レギュレータユニット,エアゾール容器の流量レギュレータ機構およびエアゾール式製品 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20080017672A1 (ja) |
EP (1) | EP1818279A4 (ja) |
JP (1) | JP4471130B2 (ja) |
WO (1) | WO2006038615A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009273990A (ja) * | 2008-05-13 | 2009-11-26 | Thales:Kk | マイクロバブル発生用ノズル |
JP2014118183A (ja) * | 2012-12-17 | 2014-06-30 | Daiwa Can Co Ltd | 噴霧容器 |
JP2020058961A (ja) * | 2018-10-05 | 2020-04-16 | ヤマトプロテック株式会社 | 防犯スプレー |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1949971B1 (en) * | 2005-09-26 | 2019-08-07 | Mitani Valve Co., Ltd. | Flow rate regulator unit and aerosol-type product with the same |
CN103097261B (zh) * | 2010-09-09 | 2014-11-19 | 三谷阀门有限公司 | 执行器倒立定量喷射机构以及具备该执行器倒立定量喷射机构的喷雾式制品 |
US20180354254A1 (en) * | 2015-11-23 | 2018-12-13 | Koenig & Bauer Ag | Device for processing substrates |
KR101790878B1 (ko) | 2016-06-01 | 2017-10-26 | 김창곤 | 나선형 유동 경로를 갖는 레귤레이터 및 이를 갖는 휴대형 화장수 분사장치 |
EP4240536A1 (en) | 2020-11-09 | 2023-09-13 | Rust-Oleum Corporation | Locking spray nozzle |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08108112A (ja) * | 1994-10-13 | 1996-04-30 | Mitani Valve:Kk | エアゾ−ル容器の流量調整構造 |
EP0916596A1 (en) | 1997-11-07 | 1999-05-19 | Toyo Aerosol Industry Co., Ltd. | Flow controller for pressurized aerosol container |
JP2002347863A (ja) | 2001-05-29 | 2002-12-04 | Mitani Valve Co Ltd | エアゾール容器用流量調整弁 |
JP2004042980A (ja) * | 2002-07-12 | 2004-02-12 | Mitani Valve Co Ltd | エアゾール容器用の流量調整機構およびこれを備えたエアゾール式製品 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1603971A (en) * | 1978-05-30 | 1981-12-02 | Metal Box Co Ltd | Aerosol valves and housings therefor |
CA1279042C (en) * | 1986-02-11 | 1991-01-15 | Bespak Plc | Gas pressurised dispensing containers |
JP2968944B2 (ja) * | 1996-03-19 | 1999-11-02 | 東洋エアゾール工業株式会社 | エアゾール容器用バルブ装置 |
-
2005
- 2005-10-04 US US11/576,620 patent/US20080017672A1/en not_active Abandoned
- 2005-10-04 JP JP2006539295A patent/JP4471130B2/ja not_active Expired - Fee Related
- 2005-10-04 EP EP05790530A patent/EP1818279A4/en not_active Withdrawn
- 2005-10-04 WO PCT/JP2005/018348 patent/WO2006038615A1/ja active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08108112A (ja) * | 1994-10-13 | 1996-04-30 | Mitani Valve:Kk | エアゾ−ル容器の流量調整構造 |
EP0916596A1 (en) | 1997-11-07 | 1999-05-19 | Toyo Aerosol Industry Co., Ltd. | Flow controller for pressurized aerosol container |
JP2002347863A (ja) | 2001-05-29 | 2002-12-04 | Mitani Valve Co Ltd | エアゾール容器用流量調整弁 |
JP2004042980A (ja) * | 2002-07-12 | 2004-02-12 | Mitani Valve Co Ltd | エアゾール容器用の流量調整機構およびこれを備えたエアゾール式製品 |
Non-Patent Citations (1)
Title |
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See also references of EP1818279A4 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009273990A (ja) * | 2008-05-13 | 2009-11-26 | Thales:Kk | マイクロバブル発生用ノズル |
JP2014118183A (ja) * | 2012-12-17 | 2014-06-30 | Daiwa Can Co Ltd | 噴霧容器 |
JP2020058961A (ja) * | 2018-10-05 | 2020-04-16 | ヤマトプロテック株式会社 | 防犯スプレー |
Also Published As
Publication number | Publication date |
---|---|
JPWO2006038615A1 (ja) | 2008-05-15 |
EP1818279A4 (en) | 2008-07-23 |
EP1818279A1 (en) | 2007-08-15 |
US20080017672A1 (en) | 2008-01-24 |
JP4471130B2 (ja) | 2010-06-02 |
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