WO2006038298A1 - Appareil de production d’eau ozonee - Google Patents
Appareil de production d’eau ozonee Download PDFInfo
- Publication number
- WO2006038298A1 WO2006038298A1 PCT/JP2004/014821 JP2004014821W WO2006038298A1 WO 2006038298 A1 WO2006038298 A1 WO 2006038298A1 JP 2004014821 W JP2004014821 W JP 2004014821W WO 2006038298 A1 WO2006038298 A1 WO 2006038298A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ozone
- water
- gas
- ozone gas
- tube
- Prior art date
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 179
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 140
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 238000004090 dissolution Methods 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims description 34
- 239000002994 raw material Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 9
- 230000004323 axial length Effects 0.000 claims description 5
- 239000012530 fluid Substances 0.000 abstract description 5
- 239000007789 gas Substances 0.000 description 88
- 238000000034 method Methods 0.000 description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 230000003068 static effect Effects 0.000 description 10
- 239000008213 purified water Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- -1 polytetrafluoroethylene tetrafluoroethylene Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 241000238366 Cephalopoda Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000011978 dissolution method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000008215 water for injection Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/10—Preparation of ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
- B01F23/2326—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles adding the flowing main component by suction means, e.g. using an ejector
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
- B01F23/23761—Aerating, i.e. introducing oxygen containing gas in liquids
- B01F23/237612—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
- B01F23/23761—Aerating, i.e. introducing oxygen containing gas in liquids
- B01F23/237613—Ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
- B01F25/4338—Mixers with a succession of converging-diverging cross-sections, i.e. undulating cross-section
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
- C02F2201/782—Ozone generators
Definitions
- the present invention relates to an ozone water production apparatus that generates ozone water by bringing ozone gas into contact with raw material water, and more specifically, a gas-liquid dissolving portion that dissolves ozone gas in water and a recess formed in the inner surface.
- the present invention relates to an ozone water production apparatus composed of tubes in which protrusions and convex portions are alternately formed.
- Ozone (a chemical formula 03) is known to have a strong acid squid and is extremely effective for sterilization and deodorization.
- ozone water produced by dissolving in water.
- Ozone water is used as washing water for hand-washing in the medical and food fields, and is used for sterilization and washing of medical equipment, food production equipment, dishes, and the like.
- ozone is not only persistent but also has the effect of decomposing and detoxifying harmful organic substances like other disinfectants and oxidants such as chlorine, sodium hypochlorite, and hydrogen peroxide. The scope of use is expected to further expand in the future as problems become more serious.
- Ozone water is produced by bringing ozone gas produced by an ozone gas generator into contact with water and dissolving it.
- the silent discharge method is a method in which ozone gas is generated by causing discharge while flowing an oxygen-containing gas between a pair of electrodes arranged in a parallel plate shape or a coaxial cylindrical shape.
- an ozone gas generator using the silent discharge method for example, a double dielectric tube is covered with a solid dielectric tube, and an electrolyte solution or water is sealed between the discharge tube and the solid dielectric tube.
- the electrolysis method consists of a pair of electrodes with an electrolyte membrane sandwiched in water! A direct voltage is applied across the two electrodes to cause electrolysis of water, and at the same time oxygen is added to the oxygen generation side.
- This is a method of generating ozone.
- Examples of ozone gas generators based on electrolysis include solid polymer electrolyte diaphragms.
- a pair of electrodes of an anode and a cathode provided with the water supply part in contact with the electrode surface is disposed, and a water guide part for replenishing water is connected to the water supply part (see Patent Document 2) .
- An ozone water production apparatus usually includes the ozone gas generator as described above and a gas-liquid dissolving part for dissolving ozone gas generated by the ozone gas generator in raw water.
- the gas-liquid dissolving part include a publishing method in which ozone gas is blown from the bottom of the water tank, a ejector method in which a narrow part is provided in a part of the raw water piping, and ozone gas is blown into it, and a pump.
- the ejector method is advantageous in terms of cost and size because the configuration of the apparatus can be simplified.
- a static mixer is constructed by connecting a plurality of spirally rotating blades in a pipe. When two or more fluids flow through the inside of the noise, More than seed fluid is divided and mixed by the presence of a plurality of blades and stirred and mixed.
- a stationary mixer for example, a first blade member formed in a spiral shape by rotating 180 ° clockwise in a spiral shape inside a cylindrical member through which a fluid such as gas or liquid flows, A second blade member that is formed by rotating 180 ° in a clockwise direction is disposed, and a hole is provided at the boundary between the first blade member and the second blade member to form a plurality of fluid passages.
- a static mixer By adopting such a static mixer, the mixing efficiency of ozone gas and raw water can be improved.
- Patent Document 1 Japanese Patent Laid-Open No. 2003-206108
- Patent Document 2 JP-A-7-157301
- Patent Document 3 Registered Utility Model No. 3100194
- Patent Document 4 Japanese Patent No. 33392692
- the present invention has an object to provide an ozone water production apparatus that can be manufactured at low cost while having a gas-liquid mixing performance comparable to an ozone water production apparatus that employs a static mixer. is there.
- the means adopted by the invention according to claim 1 is an ozone water production apparatus for generating ozone water by dissolving ozone gas in raw water, in the ozone gas generation section.
- An aspirator for contacting the generated ozone gas and raw water, and a tube force connected to the aspirator and having recesses and protrusions alternately formed on the inner surface, and the inside of the tube is filled with ozone gas and raw water.
- a gas-liquid dissolving part that dissolves ozone gas in the raw material water by flowing.
- ozone gas and raw material water are caused to flow into the inside of the tube, which is a gas-liquid dissolving part, via the aspirator, and the ozone gas and raw material water flow in the tube.
- the ozone gas is dissolved in the raw material water by colliding with the concave and convex portions to form a turbulent state.
- the tube has a plurality of recesses and projections alternately formed on the inner surface, each formed in a spiral shape in the axial length direction.
- the tube is formed of a material having at least an inner surface of which has ozone resistance, according to claim 1 or 2. Ozone water production device.
- the gas-liquid dissolving part connected to the aspirator is formed from a tube in which concave parts and convex parts are alternately formed on the inner surface.
- the ozone gas and raw material water contacted by the aspirator flow in the tube, they are resisted by the concave and convex portions and become turbulent, so that the ozone gas can be dissolved in the raw water at a high concentration. It becomes.
- the gas-liquid dissolving part can be created at low cost, an ozone water production apparatus having excellent ozone gas solubility can be provided at low cost.
- a plurality of recesses and projections formed on the inner surface of the tube are provided. Since the ozone gas and the raw material water are more likely to form a turbulent flow state by being continuously formed in a spiral shape in the axial direction, the ozone gas dissolution efficiency can be further improved.
- the inner surface of the tube is formed of a material having ozone resistance, the corrosion deterioration caused by the contact with ozone gas is less likely to occur. This can be prevented and the frequency of maintenance can be reduced, so the running cost can be kept low.
- the ozone water production apparatus includes an ozone gas generation unit, an aspirator, a gas-liquid dissolution unit, and a gas-liquid separation unit.
- An existing ozone gas generator can be used for the ozone gas generating section. For example, a discharge is generated while an oxygen-containing gas flows between a pair of electrodes arranged in a parallel plate shape or a coaxial cylindrical shape. Silent discharge type ozone gas generator that generates ozone gas through a pair of electrodes with an electrolyte membrane sandwiched in water, and a DC voltage is applied between the two electrodes to cause electrical decomposition of the water. An electrolytic ozone gas generator that generates ozone simultaneously with oxygen can be used on the generation side.
- the aspirator is for bringing the raw material water into contact with the ozone gas generated in the ozone gas generation section. That is, the aspirator is connected to raw water supply means such as waterworks and ozone gas generator.
- the ozone gas generated in the ozone gas generating section can be introduced into the aspirator by the negative pressure generated in the aspirator as the raw water passes through the aspirator and brought into contact with the raw water.
- tap water is filtered to remove impurities such as iron trough, organic matter, and chlorine, or pure water using reverse osmosis membrane (RO membrane) from tap water. It is preferable to use water from which impurities have been removed, such as pure water purified by a vessel, distilled water commercially available for medical use, sterilized purified water, and water for injection.
- impurities such as iron trough, organic matter, and chlorine
- RO membrane reverse osmosis membrane
- the gas-liquid dissolving section is for generating ozone water by dissolving ozone gas brought into contact with raw material water in the aspirator in the raw water.
- a tube having a concave part and a convex part formed on the inner surface is used for the gas-liquid dissolving part.
- the shape of the inner surface include those formed in a bellows shape, and those in which a concave portion and a convex portion each form a spiral in the axial length direction, and among these, a spiral shape is ozone gas. It is especially preferred because it is easy to form a turbulent state without any retention of raw material water.
- the inner diameter of the tube is not particularly limited, and may be adjusted according to the flow rate of the raw material water. Further, the length of the tube is not particularly limited, but it is preferable to set it within the range of 50 mm-1 OOOmm. This is because if the length is shorter than 50 mm, ozone water having a sufficient ozone concentration cannot be obtained, and if it is longer than 1000 mm, no more ozone water concentration can be obtained.
- At least the inner surface of the tube is preferably formed of a material having ozone resistance. This is because the inner surface is made of a material having ozone resistance, which causes corrosion deterioration of the tube.
- the material having ozone resistance include fluorine resin such as polytetrafluoroethylene tetrafluoroethylene resin, pure titanium, ceramic, glass, etc., and the entire tube may be formed of these materials. The surface can be coated with these materials.
- the ozone water production apparatus is provided with a gas-liquid separation unit that separates excess ozone gas that has not been dissolved in water, while storing ozone water generated in the gas-liquid dissolution unit. Good.
- the surplus ozone gas separated in the gas-liquid separation unit is decomposed into oxygen through an ozone gas processing unit connected to the gas-liquid separation unit, and discharged to the outside.
- ozone gas treatment methods include activated carbon decomposition method, catalyst method, thermal decomposition method, etc., and existing ozone gas treatment equipment using these methods can be used.
- FIG. 1 shows a schematic diagram of an ozone water production apparatus 100 according to this embodiment.
- the ozone water production apparatus 100 has an ozone gas generation unit 110, an aspirator 120, a spiral tube 130 as a gas-liquid dissolution unit, a gas-liquid separation unit 140, an ozone gas treatment unit 150, and an ozone water output unit 160. is doing.
- the ozone gas generation unit 110 is connected to an oxygen cylinder (not shown), and an alternating high voltage is generated while flowing an oxygen gas supplied from the oxygen cylinder between a pair of electrodes arranged in a parallel plate shape.
- a silent discharge type that generates ozone gas when applied is adopted.
- This ozone gas generation part is connected to the aspirator 120, and the generated ozone gas flows into the aspirator 120.
- the aspirator 120 is connected to the water supply via a filtration filter (not shown), and is connected to the ozone gas generation unit 110.
- the ozone gas is sucked by the negative pressure generated when purified water flows into the aspirator 120 and mixed with purified water.
- the aspirator 120 is connected to a spiral tube 130 described in detail below, and ozone gas and purified water mixed in the aspirator 120 flow out toward the spiral tube 130.
- FIG. 2 shows a snoral tube 130 as a gas-liquid mixing unit disposed in the ozone water production apparatus according to the present embodiment.
- the snow tube 130 has a plurality of recesses 131 and protrusions 132 alternately formed on the inner surface thereof, and the plurality of recesses 131 and protrusions 132 are each continuous in the axial length direction. Formed into a spiral structure.
- the spiral tube 130 is resistant to ozone. Made of PTFE (polytetrafluoroethylene tetrafluoroethylene)! RU
- the inner diameter and length of the spiral tube 130 are set to 10 mm and 150 mm, respectively.
- a mixed liquid of ozone gas and purified water flowing out from the aspirator 120 passes through the spiral tube 130.
- the mixed solution of ozone gas and purified water collides with the concave portion 131 and the convex portion 132 in the spiral tube 130, and rotates in a spiral to become a turbulent state.
- the mixed liquid becomes a turbulent state, so that the ozone gas can be efficiently dissolved in the purified water.
- the gas-liquid separation unit 140 separates the ozone water generated in the spiral tube 130 from the surplus ozone gas that has not been dissolved in the purified water, and stores the ozone water.
- the gas-liquid separation part 140 is divided into two chambers, an ozone water inflow part 142 and an ozone water storage part 143, by a partition wall 141 suspended from the inner bottom surface. Excess ozone gas and ozone water flow into the ozone water inflow section 142 connected to the spiral tube 130.
- the ozone water storage unit 143 stores ozone water from which excess ozone gas has been removed at the ozone water inflow unit 142, and is connected to an ozone water output unit 160 that outputs ozone water to the outside. .
- the ozone water inflow section 142 and the ozone water storage section 143 communicate with each other upward.
- Excess ozone gas that has not been dissolved in the ozone water flowing into the ozone water inflow portion 142 from the spiral tube 130 is separated from the ozone water as bubbles at the ozone water inflow portion, and the excess ozone gas is removed.
- the ozone water is stored in the ozone water storage unit 143.
- the stored ozone water is output to the outside by an operation of a switch (not shown) from the ozone water output unit 160.
- surplus ozone gas separated from the ozone water flows into the ozone gas processing unit 150.
- the ozone gas processing unit 150 in this embodiment employs a so-called catalytic method using manganese dioxide as a catalyst.
- the ozone gas that has come into contact with manganese dioxide in the ozone gas processing unit 150 is converted into oxygen and released to the outside.
- Table 1 shows the measurement results.
- the measurement conditions were: water supply volume and water supply pressure of 3.5 LZmin and 0.15 MPa, oxygen supply volume and delivery pressure, respectively.
- lL / min, 0.15Mpa, supply ozone gas concentration and supply ozone gas were 80gZNm3, 8g / ozone water discharge and water temperature respectively 3.5L / min, 25 ° C, and ozone water Sampling was performed in three batches, and each ozone gas concentration was measured to obtain an average value.
- Comparative Example 1 a straight tube having an inner diameter of 10 mm and a length of 150 mm was used as the gas-liquid dissolving part, and in Comparative Example 2, a straight tube having an inner diameter of 10 mm and a length of 1000 mm was used as the gas-liquid dissolving part. In Comparative Example 3, a static mixer was used for the gas-liquid dissolving part.
- the average value of the ozone gas concentration in this example was 1.39 ppm higher than that of Comparative Example 1 and 1.42 ppm higher than that of Comparative Example 2.
- the value was equal to or greater. From this test result, it was confirmed that the ozone water production apparatus 100 according to the present example using the spiral tube 130 as the gas-liquid dissolving part had excellent ozone gas dissolving performance.
- the ozone water production apparatus 100 employs the spiral tube 130 as the gas-liquid dissolution unit, thereby providing an ozone water production apparatus having ozone gas dissolution efficiency comparable to that of a conventional static mixer. 100 can be offered at low cost.
- the gas-liquid dissolving part connected to the aspirator has recesses and protrusions alternately formed on the inner surface.
- FIG. 1 is a schematic block diagram of an ozone water production apparatus according to the present embodiment.
- FIG. 2 is a partially cutaway plan view of a spiral tube as a gas-liquid dissolving part constituting the ozone water production apparatus according to the present embodiment.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2004800441780A CN101052460A (zh) | 2004-10-07 | 2004-10-07 | 臭氧水制造装置 |
JP2006539118A JPWO2006038298A1 (ja) | 2004-10-07 | 2004-10-07 | オゾン水製造装置 |
PCT/JP2004/014821 WO2006038298A1 (fr) | 2004-10-07 | 2004-10-07 | Appareil de production d’eau ozonee |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2004/014821 WO2006038298A1 (fr) | 2004-10-07 | 2004-10-07 | Appareil de production d’eau ozonee |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006038298A1 true WO2006038298A1 (fr) | 2006-04-13 |
Family
ID=36142388
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/014821 WO2006038298A1 (fr) | 2004-10-07 | 2004-10-07 | Appareil de production d’eau ozonee |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPWO2006038298A1 (fr) |
CN (1) | CN101052460A (fr) |
WO (1) | WO2006038298A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013523448A (ja) * | 2010-07-15 | 2013-06-17 | コリア・インスティテュート・オブ・マシナリー・アンド・マテリアルズ | 旋回ユニット基盤の微細気泡発生装置 |
US8800969B2 (en) | 2009-02-10 | 2014-08-12 | Diffusaire Ltd | Device and method for dissolving gas into a liquid |
EP3093066A1 (fr) * | 2015-05-05 | 2016-11-16 | Nordson Corporation | Mélangeurs statiques et procédés d'utilisation et de fabrication |
IT202200007652A1 (it) * | 2022-04-19 | 2023-10-19 | Micheletti Eng & Consulting Sagl | Sistema ed impianto per lo spruzzagio di acqua ozonizzata ad alta pressione |
Families Citing this family (6)
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TWI635856B (zh) * | 2017-04-06 | 2018-09-21 | 嘉麗通健康科技有限公司 | 負壓氧療機 |
CN107285417A (zh) * | 2017-08-10 | 2017-10-24 | 深圳市橘井舒泉技术有限公司 | 一种臭氧水机除臭氧机构及臭氧水机 |
SG11202012041PA (en) * | 2018-06-13 | 2021-01-28 | Mitsubishi Electric Corp | Oxidation device, water treatment device, water treatment method, ozone water generation method, and cleaning method |
CN110338732A (zh) * | 2019-05-21 | 2019-10-18 | 珠海格力电器股份有限公司 | 一种洗碗机及洗碗方法 |
CN113576881A (zh) * | 2021-07-27 | 2021-11-02 | 广州生基科技有限公司 | 一种负氧离子水浴装置 |
TWI802019B (zh) * | 2021-09-22 | 2023-05-11 | 品源鑫科技有限公司 | 多層電極套管之高壓水臭氧產生裝置與臭氧泡澡系統 |
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JPS4884954A (fr) * | 1972-02-17 | 1973-11-10 | ||
JP2002095942A (ja) * | 2000-09-22 | 2002-04-02 | Yoshiyuki Sawada | 気体溶解装置 |
JP2002210340A (ja) * | 2001-01-22 | 2002-07-30 | Core Medical Kk | オゾン水製造装置 |
JP2004223441A (ja) * | 2003-01-24 | 2004-08-12 | Toyota Auto Body Co Ltd | オゾン水製造装置 |
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2004
- 2004-10-07 WO PCT/JP2004/014821 patent/WO2006038298A1/fr active Application Filing
- 2004-10-07 CN CNA2004800441780A patent/CN101052460A/zh active Pending
- 2004-10-07 JP JP2006539118A patent/JPWO2006038298A1/ja active Pending
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JPS4884954A (fr) * | 1972-02-17 | 1973-11-10 | ||
JP2002095942A (ja) * | 2000-09-22 | 2002-04-02 | Yoshiyuki Sawada | 気体溶解装置 |
JP2002210340A (ja) * | 2001-01-22 | 2002-07-30 | Core Medical Kk | オゾン水製造装置 |
JP2004223441A (ja) * | 2003-01-24 | 2004-08-12 | Toyota Auto Body Co Ltd | オゾン水製造装置 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8800969B2 (en) | 2009-02-10 | 2014-08-12 | Diffusaire Ltd | Device and method for dissolving gas into a liquid |
JP2013523448A (ja) * | 2010-07-15 | 2013-06-17 | コリア・インスティテュート・オブ・マシナリー・アンド・マテリアルズ | 旋回ユニット基盤の微細気泡発生装置 |
US9061255B2 (en) | 2010-07-15 | 2015-06-23 | Korea Institute Of Machinery & Materials | Rotating unit-based micro-sized bubble generator |
EP3093066A1 (fr) * | 2015-05-05 | 2016-11-16 | Nordson Corporation | Mélangeurs statiques et procédés d'utilisation et de fabrication |
US10092887B2 (en) | 2015-05-05 | 2018-10-09 | Nordson Corporation | Static mixers and methods for using and making the same |
EP3388144A1 (fr) * | 2015-05-05 | 2018-10-17 | Nordson Corporation | Mélangeurs statiques et procédés d'utilisation et de fabrication |
IT202200007652A1 (it) * | 2022-04-19 | 2023-10-19 | Micheletti Eng & Consulting Sagl | Sistema ed impianto per lo spruzzagio di acqua ozonizzata ad alta pressione |
EP4272858A3 (fr) * | 2022-04-19 | 2024-04-17 | Micheletti Engineering & Consulting Sagl | Machine et système de pulvérisation d'eau ozonée sous haute pression |
Also Published As
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JPWO2006038298A1 (ja) | 2008-05-15 |
CN101052460A (zh) | 2007-10-10 |
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