WO2006033353A1 - 導電性ローラ - Google Patents
導電性ローラ Download PDFInfo
- Publication number
- WO2006033353A1 WO2006033353A1 PCT/JP2005/017386 JP2005017386W WO2006033353A1 WO 2006033353 A1 WO2006033353 A1 WO 2006033353A1 JP 2005017386 W JP2005017386 W JP 2005017386W WO 2006033353 A1 WO2006033353 A1 WO 2006033353A1
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- WO
- WIPO (PCT)
- Prior art keywords
- coating layer
- shaft member
- layer
- elastic
- coating
- Prior art date
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/02—Apparatus for electrographic processes using a charge pattern for laying down a uniform charge, e.g. for sensitising; Corona discharge devices
- G03G15/0208—Apparatus for electrographic processes using a charge pattern for laying down a uniform charge, e.g. for sensitising; Corona discharge devices by contact, friction or induction, e.g. liquid charging apparatus
- G03G15/0216—Apparatus for electrographic processes using a charge pattern for laying down a uniform charge, e.g. for sensitising; Corona discharge devices by contact, friction or induction, e.g. liquid charging apparatus by bringing a charging member into contact with the member to be charged, e.g. roller, brush chargers
- G03G15/0233—Structure, details of the charging member, e.g. chemical composition, surface properties
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/06—Apparatus for electrographic processes using a charge pattern for developing
- G03G15/08—Apparatus for electrographic processes using a charge pattern for developing using a solid developer, e.g. powder developer
- G03G15/0806—Apparatus for electrographic processes using a charge pattern for developing using a solid developer, e.g. powder developer on a donor element, e.g. belt, roller
- G03G15/0818—Apparatus for electrographic processes using a charge pattern for developing using a solid developer, e.g. powder developer on a donor element, e.g. belt, roller characterised by the structure of the donor member, e.g. surface properties
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/14—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base
- G03G15/16—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer
- G03G15/1665—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer by introducing the second base in the nip formed by the recording member and at least one transfer member, e.g. in combination with bias or heat
- G03G15/167—Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer by introducing the second base in the nip formed by the recording member and at least one transfer member, e.g. in combination with bias or heat at least one of the recording member or the transfer member being rotatable during the transfer
- G03G15/1685—Structure, details of the transfer member, e.g. chemical composition
Definitions
- the present invention relates to a conductive roller used in an image forming apparatus such as an electrophotographic apparatus such as a copying machine or a printer or an electrostatic recording apparatus, and in particular, improves productivity when producing the conductive roller. At the same time it relates to the one that has reduced costs.
- an image forming apparatus using an electrophotographic system such as a copying machine or a printer
- various conductive rollers are used, and a charging roller for applying a charge to a latent image holding member such as a photosensitive drum.
- a developing roller for supplying a non-magnetic developer (toner) to the latent image holding member to visualize the latent image on the latent image holding member, a toner supplying roller for supplying this toner to the developing roller, and a toner on the latent image holding member.
- Transfer roller used to transfer the toner onto a recording medium such as paper, an intermediate transfer roller that acts as a mediator for toner, a tallying roller that removes toner remaining on the latent image carrier,
- An example is a belt drive roller that drives or follows a conductive belt used in the apparatus so that it can run.
- a conductive rubber, a polymer elastomer, and a polymer foam that have been provided with conductivity by combining a conductive agent on the outer periphery of a conductive shaft member.
- An electrically conductive elastic layer having a uniform thickness is formed, and a coating film of a coating layer is further formed on the outer periphery as required.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-150610
- the present invention has been made in view of such problems, and is capable of forming an elastic layer at a low cost without sacrificing the outer dimensional accuracy, and can reduce the cost of the product significantly.
- the object is to provide a roller.
- ⁇ 1> is a method for manufacturing a conductive roller comprising a shaft member that is attached with both ends in the length direction being pivotally supported, and one or more elastic layers disposed on the outer side in the radial direction.
- a compound that forms an elastic body by being cured by electron beam irradiation or ultraviolet irradiation is applied to the outside of the shaft member to form an elastic coating layer, and then the elastic coating layer is cured by irradiation with electron beams or ultraviolet rays.
- This is a method for producing a conductive roller for forming the elastic layer.
- ⁇ 2> is a method for producing a conductive nozzle according to ⁇ 1>, wherein the elastic coating layer is formed by discharging the compound on the shaft member while rotating the shaft member while the shaft member is rotated. .
- ⁇ 3> is a die coater having a discharge head shorter than the length of the elastic coating layer in ⁇ 2>, wherein at least one of the discharge head and the shaft member is a length of the shaft member.
- a layer restricting means for contacting and restricting an elastic coating layer before curing formed by a die coater while rotating the shaft member;
- a method for producing a conductive roller wherein at least one of the shaft member and the shaft member is relatively displaced in the length direction of the shaft member, and the thickness and surface smoothness of the elastic coating layer are adjusted to desired values.
- ⁇ 5> is the discharge head force of the die coater in ⁇ 4>, after discharging the compound to form an elastic coating layer over the entire length, the discharge of the compound from the discharge head is stopped, and this discharge is stopped.
- the ejection head in a stopped state is used as a layer restricting means, and at least one of the layer restricting means and the shaft member is relatively displaced in the length direction of the shaft member, and the thickness and surface smoothness of the elastic coating layer are adjusted.
- conductive roller to adjust to the desired one Production method.
- ⁇ 6> is a method for producing a conductive roller according to ⁇ 4>, wherein the layer restricting unit is attached to the ejection head.
- ⁇ 7> is the method according to ⁇ 4>, wherein the layer regulating means is provided separately from the ejection head, and the elastic coating layer is formed and the elastic coating layer is formed.
- ⁇ 8> is any one of ⁇ 1> to ⁇ 7>, wherein the elastic coating layer is irradiated with an electron beam or an ultraviolet ray to be cured, while rotating the shaft member, The elastic coating layer is semi-cured by relatively displacing a device for irradiating ultraviolet rays in the longitudinal direction with respect to the shaft member, and then the elastic coating layer is formed in a step after the step of forming the elastic coating layer.
- the conductive roller according to any one of claims 1 to 7, wherein when the elastic coating layer is semi-cured after being fully cured, the elastic coating layer is continuously applied while the shaft member is rotated. Manufacturing method.
- ⁇ 9> is any one of ⁇ 1> to ⁇ 8>, wherein a coating that is cured by electron beam irradiation or ultraviolet irradiation is applied to the surface of the elastic layer to form a coating coating layer.
- ⁇ 10> is the method according to ⁇ 9>, wherein when the coating coating layer is formed, the coating roll and the conductive roller in the middle of formation are supplied while supplying the coating to the peripheral surface of the coating roll of the roll coater. At least one of the coating roll and the conductive roller in the process of forming while rotating both the coating roll and the conductive roller in the process of crossing at a predetermined angle including 10.
- ⁇ 12> is any one of ⁇ 9> to ⁇ 11>, wherein when the coating coating layer is cured by irradiation with an electron beam or ultraviolet ray, the conductive roller being formed is rotated, The length of a conductive roller that is in the process of forming an electron beam or ultraviolet irradiation device The coating coating layer is semi-cured by relative displacement in the direction, and then the coating coating layer is fully cured in a step after the step of forming the coating coating layer, and the semi-curing of the coating coating layer is performed. Is a method for producing a conductive roller, which is performed continuously with the coating application layer while the shaft member is rotated.
- ⁇ 13> is any one of ⁇ 1> to ⁇ 12>, wherein the shaft member is made of a metal pipe, a hollow cylindrical body made of resin containing a conductive agent, or a solid cylindrical body.
- a method for manufacturing a conductive roller using a roller is any one of ⁇ 1> to ⁇ 12>, wherein the shaft member is made of a metal pipe, a hollow cylindrical body made of resin containing a conductive agent, or a solid cylindrical body.
- a compound that is cured by electron beam irradiation or ultraviolet irradiation to form an elastic body is applied to the outside of the shaft member to form an elastic coating layer, and then an electron beam is applied to the elastic coating layer. Or, it is cured by irradiating with ultraviolet rays to form an elastic layer, which hinders cost reduction! / Eliminates the need for a mold that rubs and does not contain UV curable resin! / The drying process required in some cases can be made unnecessary, which can greatly contribute to the cost reduction of the product.
- the die coater having a discharge head shorter than the length of the elastic coating layer is used, and the discharge head is relatively displaced in the length direction with respect to the shaft member. Since the coating layer is formed, the compound can be spirally coated on the shaft member, and this can be applied to a die coater having a discharge head longer than the length of the elastic coating layer on the shaft member.
- the separation line when separating the conductive roller formed with the elastic coating layer from the ejection head remains on the elastic coating layer, resulting in uneven thickness. turn into.
- the ejection head in a state where ejection is stopped is used as the layer regulating means, it is not necessary to invest a new device for regulating the layer.
- the layer regulating means is provided separately from the ejection head, and the formation of the elastic coating layer and the layer regulation of the formed elastic coating layer are performed as described above. Since it is continuously performed while rotating the shaft member, formation of the elastic coating layer and layer regulation of the formed elastic coating layer can be performed efficiently.
- ⁇ 0027> ⁇ 8> is a method in which an elastic coating layer is semi-cured by rotating a shaft member while irradiating an electron beam or an ultraviolet ray relative to the shaft member in the length direction thereof. Since the elastic coating layer is fully cured in a step subsequent to the step of forming the coating layer, the shape of the conductive roller can be stabilized at an early stage, and the curing can be performed completely. In semi-curing, since the elastic coating layer is continuously applied while the shaft member is rotated, this can be carried out efficiently.
- the coating coating layer formed by applying a paint on the elastic layer is formed by irradiating and curing with an electron beam or ultraviolet ray. This makes it possible to make the mold that is an obstacle to reduction unnecessary, and also eliminate the need for a drying process, which can make a significant contribution to reducing product costs.
- the coating application layer is formed while rotating the coating roller of the roll coater and the conductive roller being formed while supplying the coating material to the peripheral surface of the coating roll. Therefore, the forming process can be made efficient without wasteful use of the paint, and the coating roll and the conductive roller in the process of forming intersect at a predetermined angle including 90 degrees, and these surfaces are Since at least one of the coating roll and the conductive roller in the middle of formation is applied with relative displacement in the length direction of the conductive roller with respect to the other in the posture in which the coating roller is in contact with or close to the coating roller, It is possible to suppress generation of a separation line when being separated from the roller paint, and to prevent the surface from becoming uneven due to the separation line.
- a gravure roll that accommodates and transports the paint in a recess provided on the peripheral surface is used as the coating roll, so that it is retained on the peripheral surface even if the viscosity of the paint slightly changes.
- the amount of paint to be applied can be made constant, and as a result, the film thickness of the coating layer can be formed uniformly.
- the coating application layer is fully cured in a step after the step of forming the coating application layer. Since the coating is continuously performed while the shaft member is rotated, as described above for the elastic layer, the shape of the conductive roller is stabilized at an early stage, and the force is also cured. Can be done completely.
- the shaft member is made of a metal pipe or a hollow cylindrical body or a solid cylindrical body containing a conductive agent, a conductive roller is used. It can be lightweight.
- FIG. 1 is a cross-sectional view showing a conductive roller according to an embodiment of the present invention.
- FIG. 2 is a cross-sectional view showing a conductive roller according to another embodiment.
- FIG. 3 is a cross-sectional view showing a conductive roller according to still another embodiment.
- FIG. 4 is a perspective view showing a conductive roller of still another embodiment.
- FIG. 5 is a cross-sectional view showing a mold for forming a hollow cylindrical body.
- FIG. 6 is a side view showing a shaft member having end portions of different structures.
- FIG. 7 is a perspective view showing a modification of the shape of the shaft portion, shaft hole portion, and gear portion.
- FIG. 8 is a perspective view showing a conductive roller of still another embodiment.
- FIG. 9 is a perspective view showing a shaft member of the conductive roller shown in FIG.
- FIG. 10 is a perspective view and a sectional view showing a cylindrical member.
- FIG. 11 is a perspective view showing a modification of the shaft member shown in FIG. 9.
- FIG. 12 is a perspective view showing another modification of the shaft member shown in FIG.
- FIG. 13 is a perspective view illustrating a method for connecting cylindrical members.
- FIG. 14 is a perspective view showing a conductive roller being formed when a layer is formed by a die coating method.
- FIG. 15 is a side view showing another embodiment of the die coater.
- FIG. 16 is a plan view and an arrow view showing a conductive roller being formed when a layer is formed by a roll coating method.
- FIG. 17 is a plan view and a cross-sectional view showing a gravure roll.
- FIG. 18 is a schematic diagram of a gravure roll pattern example.
- a Cylindrical member B Other cylindrical member: Convex
- FIG. 1 is a cross-sectional view showing a conductive roller formed according to the method for manufacturing a conductive roller according to the present invention.
- the conductive roller 1 has an elastic layer formed on the outer side of the shaft member 2, and preferably has a coating layer 4 on the outer side thereof.
- the shaft member 2 Since the shaft member 2 is made of resin, the diameter of the shaft member 2 can be increased without causing a significant increase in weight, and since the resin contains a conductive agent, the shaft member 2 is good. It has conductivity, and this allows a desired potential to be applied to the surface of the conductive roller 1.
- a general-purpose resin can be selected as appropriate as long as it has moderate strength and can be molded by injection molding or the like.
- engineering plastics include, for example, polyacetal, polyamide resin (for example, polyamide 6, polyamide 6 ⁇ 6, polyamide 12, polyamide 4 ⁇ 6, polyamide 6 ⁇ 10, polyamide 6 ⁇ 12, Polyamide 11, Polyamide MXD6 (polyxylenediamine, adipic acid, and polyamide that can also be used), polybutylene terephthalate, polyphenylene oxide, polyphenylene ether, polyphenylene sulfide, polyethersulfone, polycarbonate, polyimide , Polyamideimide, polyetherimide, polysulfone, polyetheretherketone, polyethylene terephthalate, polyarylate, liquid crystal polymer, polytetrafluoroethylene and the like can be mentioned.
- Examples of the general-purpose resin include polypropylene, acrylonitrile-butadiene-styrene (ABS) resin, polystyrene, and polyethylene.
- ABS acrylonitrile-butadiene-styrene
- melamine resin phenol resin, silicone resin, etc. can also be used. These can be used alone or in combination of two or more.
- polyacetal, polyamide resin, polybutylene terephthalate, polyphenylene ether, polyphenylene sulfide, polycarbonate and the like are thermoplastic and have excellent moldability, and This is preferable from the viewpoint of excellent mechanical strength.
- polyamide 6 ⁇ 6, aromatic polyamide, polyamide 6 ⁇ 12, polybutylene terephthalate, or a mixed resin thereof is preferable. It should be noted that although there is no problem in using thermosetting resin, it is preferable to use thermoplastic resin in consideration of recyclability.
- the conductive agent various materials can be used as long as they can be uniformly dispersed in the resin material.
- Carbon black powder, graphite powder, carbon fiber, aluminum, Powdered conductive agents such as metal powders such as copper and nickel, metal oxide powders such as tin oxide, titanium oxide and zinc oxide, and conductive glass powder are preferably used. These may be used alone or in combination of two or more.
- the blending amount of the conductive agent is not particularly limited as long as it is selected so that an appropriate resistance value can be obtained according to the intended use and situation of the conductive roller, but usually the material of the shaft member 2
- the total content is preferably 5 to 40% by weight, particularly 5 to 20% by weight.
- the volume resistivity of the shaft member 2 may be appropriately set according to the use of the roller as described above, but is usually 1 X 10 ° to 1 X 10 12 ⁇ 'cm, preferably 1 X 10 2 ⁇ 1 X 10 1 0 ⁇ 'cm, more preferably 1 X 10 5 ⁇ 1 X 1 ⁇ 10 ⁇ ' and cm.
- various conductive or non-conductive fibrous materials such as whisker and ferrite can be blended as necessary for the purpose of reinforcement or increase in weight.
- fibrous materials include fibers such as carbon fibers and glass fibers
- whisker include inorganic whiskers such as potassium titanate. These may be used alone or in combination of two or more. These amounts can be appropriately selected according to the length and diameter of the fibrous whisker to be used, the type of the main resin material, the desired roller strength, etc.
- the shaft member 2 constitutes the core portion of the conductive roller 1, the shaft member 2 needs to have sufficient strength to stably exhibit good performance as a roller. It is preferable that the bending strength in accordance with 71 has a strength of 80 MPa or more, particularly 130 MPa or more, so that good performance can be reliably exhibited over a long period of time.
- the upper limit of bending strength is not particularly limited, but generally it is about 500 MPa or less.
- FIG. 1 shows the force of the shaft member 2 made of a solid cylindrical body 5.
- FIG. 2 shows a shaft member 12 made of a hollow hollow resin body 13 instead of the shaft member 2.
- FIG. 6 is a cross-sectional view showing a conductive aperture 11 used.
- the conductive roller 11 is the same as the conductive roller 1 in that the elastic layer 3 and the coating layer 4 are formed in this order on the outside of the shaft member 12.
- the shaft member 12 is formed by joining a hollow cylindrical body 13 and a cap member 14 by bonding or the like.
- the hollow cylindrical body 13 includes a cylindrical portion 13a, a bottom portion 13b, and a shaft portion 6, and includes a cap member 14. Consists of a lid portion 14a and a shaft portion 6. Both shaft portions 6 are pivotally supported by a roller support portion of an electrophotographic apparatus (not shown) in the attached state.
- the conductive roller 11 can be further reduced in weight, particularly when the outer diameter of the conductive roller exceeds 12 mm. A structure is preferable.
- FIG. 3 is a sectional view showing a conductive roller 21 using a shaft member 22 instead of the shaft member 12, and FIG. 4 is a perspective view thereof.
- the shaft member 22 is formed by bonding a hollow cylindrical body 23 and a cap member 24 by bonding or the like.
- the hollow cylindrical body 23 includes a cylindrical portion 23a, a bottom portion 23b, a gear portion 7 and a shaft hole portion 8, and
- the cap member 24 includes a lid portion 24a and a shaft portion 6 in the same manner as the conductive roller 11.
- the shaft portion 6 and the shaft hole portion 8 are pivotally supported by a roller support portion of an electrophotographic apparatus (not shown).
- the rotational driving force of the conductive roller is directly transmitted to the shaft member 22 via the gear portion 7.
- the gear portion 7 can be integrally molded, whether it is a spur gear or a haze gear.
- the thickness of the hollow cylindrical portion 13a or 23a is preferably thinner in terms of light weight as long as the strength is sufficient, for example, a force that can be set to 0.3 to 3 mm. More preferably, it should be 1 to 2 mm.
- FIG. 5 is a cross-sectional view showing a mold 30 for forming the hollow cylindrical body 23 in a closed state.
- the mold 30 includes a cylindrical mold 31, a core mold 32, and a runner mold 33.
- the molds are configured to be opened and closed by moving the molds apart from each other in the length direction of the cylindrical mold 31.
- the resin 35 is injected into the cavity 35 formed by the cylindrical mold 31 and the core mold 32 through the first sprue 36 force, the runner 37 and the first varnish 34.
- the hollow cylindrical body 23 can be formed by cooling and solidifying it in the mold 30. Further, by using the hot runner method, the material in the runner 37 can be used without waste.
- the hollow cylindrical body 23 can be made uniform in the circumferential direction.
- an inert gas can be introduced and the hollow portion can be formed by the pressure of this gas.
- FIG. 6 is a side view showing a shaft member having a different end structure.
- FIGS. 6 (a) and 6 (b) show an example in which both ends are constituted by a shaft portion 6, and FIG. c) is an example in which both end portions are configured by the shaft hole portion 8.
- FIGS. 6 (d) and 6 (e) are configured such that one of the both end portions is the shaft portion 6 and the other is the shaft hole portion 8.
- Each example is shown.
- the examples in FIGS. 6 (b) to 6 (e) show an example in which the gear portion 7 is provided at one end.
- the gear portion 7 can be provided on both sides of the end portion, and in this case, the shaft member plays a function of mediating the transmission of dynamic force. In either case, the gear portion 7 can be formed integrally with the cylindrical portion or the column portion.
- FIG. 6 (a) corresponds to the shaft member 2 or 12
- FIG. 6 (d) corresponds to the shaft member 22.
- the shaft portion 6 of the shaft members 2 and 12 shown in FIG. 6 has the simplest cylindrical shape as shown in a perspective view in FIG. 7 (a).
- Fig. 7 (b) has a tapered part
- Fig. 7 (c) has a D-cut process
- Fig. 7 (d) has a prismatic shape
- Fig. 7 (e) has a pointed tip.
- annular groove as shown in Fig. 7 (f) with a stepped portion as shown in Fig. 7 (g), spline or gear external teeth as shown in Fig. 7 (h)
- a flange or the like shown in (q) can also be used.
- FIG. 8 is a perspective view showing a conductive roller 51 using a shaft member 52 instead of the shaft member 12 shown in FIG. 2.
- FIG. 9 is a perspective view showing the shaft member 52. .
- the shaft member 52 includes a hollow cylindrical body 53 and a metal shaft 56.
- the hollow cylindrical body 53 is provided with reinforcing ribs 55 extending from the outer peripheral surface thereof in the radial direction, and the hollow cylindrical body. 53 is configured by connecting a plurality of cylindrical members 54 in the length direction.
- the hollow cylindrical body 53 is composed of a plurality of cylindrical members 54, and the length of the member is smaller than that of a conventional metal pipe-resin integral molded product by dividing the hollow cylindrical body 54 in the length direction. Since the length is shortened, the processing accuracy can be improved and the processing of individual members can be facilitated, thereby contributing to the improvement of productivity.
- a metal shaft 56 that passes through the hollow cylinder is disposed,
- the shaft 56 is configured to support the radially inner ends of the reinforcing ribs 55, and this configuration can improve the rigidity of the roller and increase the strength against bending.
- the connecting means between the cylindrical members 54 is not particularly limited.
- a structure as shown in Fig. 10 can be exemplified, and the coupling can be achieved by fitting the end portions thereof. be able to.
- the illustrated cylindrical member 54 has a convex portion 62 and a rotation prevention pin 63 on one end portion 61A side ((a) in the figure), and a concave portion 65 and a rotation stop hole 66 on the other end portion 61B side. It has ((b) in the figure).
- (C) in the drawing is a cross-sectional view of the cylindrical member 54.
- the cylindrical members 54 having such a structure are fitted together while rotating with the end portions 61A and 61B facing each other, so that the convex portions 62 are the concave portions 65 and the rotation prevention pins 63 are the rotation prevention holes. It is possible to fit firmly to each other by fitting with 66 respectively. Since the roller is used by being rotated, it is preferable that the connecting means between the members is provided with a rotation preventing mechanism.
- the convex portion 62 and the concave portion 65 are tapered for centering.
- the shape of the shaft member 52 itself is not particularly limited, and may be a desired shape as appropriate.
- a gear portion 57 (see FIG. 11) or a shaft portion having an appropriate shape such as a D-cut shape is formed on a member that hits the end portion in the longitudinal direction, or a member having only a gear portion is formed after forming the roller body
- the end of the shaft member 52 in the longitudinal direction can have the shape of these functional parts as desired.
- there is no need to use a shaft separately or to perform complicated machining on the shaft and there is also an advantage that it is easy to center the functional parts.
- the outer shape of the shaft member 52 is not limited to the cylindrical shape shown in FIG. 9 and the like, but has a crown shape in which the diameter increases toward the center of the force at both ends in the longitudinal direction as shown in FIG. It can also be.
- the outer shape of the roller body is generally a straight cylindrical shape.
- the crown shape whose center is larger in diameter than both ends, etc. Difficult and necessary to control the film thickness during molding by expensive mold production, polishing of the elastic layer 3 and coating of the coating layer 4 (dip etc.).
- the number of members forming the roller body is not particularly limited, and may be determined as appropriate from the viewpoint of strength and cost.
- the same material as described for the shaft member 2 can be used, and as the metal shaft 56, for example, sulfur free cutting steel or aluminum Um, stainless steel, etc., with nickel, zinc plating or the like can be used.
- the coupling between the hollow cylindrical body 53 and the metal shaft 56 may be usually performed by a conventional adhesive or the like, and is not particularly limited.
- the metal shaft can be obtained by heating the hollow member 54 in an oven or the like. It is also possible to use a method in which the resin material of the hollow member 54 is contracted and fixed to the metal shaft 56 by passing 56 and then cooling. Further, it is also preferable to provide a groove or a D-cut on the metal shaft 56 as this coupling means (not shown).
- the coupling means in this case is also preferably provided with an anti-rotation mechanism as in the case of the member described above, and this can prevent the metal shaft 56 from idling during use.
- the conductive roller 51 can be manufactured by connecting the plurality of cylindrical members 54 in the length direction to form the shaft member 52 and then providing the elastic layer 3 on the outer periphery thereof.
- the procedure for forming the hollow cylindrical body 53 by the cylindrical member 54 is not particularly limited.
- the cylindrical member 54 having a fitting structure as shown in FIG. Can be directly combined to form a hollow cylindrical body 53, and when there is no fitting structure, as shown in FIGS. 13 (a) to (c), the metal shaft 56 is connected to each cylindrical member 54.
- a method may be used in which the rollers are fixed to each other with an adhesive or the like to form a roller shape.
- the shaft member is made of metal, it is preferably made of a hollow cylindrical body as shown in Fig. 2 as a metal material in this case, which is preferable in terms of weight reduction.
- a metal material in this case, which is preferable in terms of weight reduction.
- Aluminum, stainless steel and iron, and alloy strengths containing any of these may be exemplified.
- the elastic layer 3 is made of an ultraviolet curable resin containing a conductive agent and an ultraviolet polymerization initiator, or an electron beam curable resin containing a conductive agent, and generally has a glass transition point of ⁇ 40 ° C. or lower.
- a compound that forms an elastic body by being cured by electron beam irradiation or ultraviolet irradiation is used.
- the elastic coating layer is formed by coating the outer side of the shaft member 2, the elastic coating layer is cured by irradiation with an electron beam or ultraviolet rays.
- Fig. 14 (a) is a perspective view showing the conductive roller 1 being formed when the elastic layer 3 is formed by the die coating method
- Fig. 14 (b) is a side view of Fig. 14 (a).
- a compound which forms an elastic body by being cured by electron beam irradiation or ultraviolet irradiation is discharged onto the shaft member 2 from the discharge head 74 of the die coater 70.
- the elastic coating layer 3R is irradiated with an electron beam or ultraviolet rays and cured to form the elastic layer 3.
- the die coater 70 has a discharge head 74 composed of a divided upper die head 71 and a lower die head 72, and a supply passage for the compound is formed between the upper die head 71 and the lower die head 72.
- An opening 77 that opens in a slit shape is provided at the tip of the passage.
- the die coater 70 is fixed in such a posture that the opening 77 is directed in the axial direction of the shaft member 2.
- the paint enters the supply passage between the upper and lower die heads 71 and 72 from the metering pump 76 through the supply pipe 73 and is discharged from the opening 77 to the peripheral surface of the shaft member 2.
- a blade 79 that functions as a layer restricting means for contacting and restricting the pre-curing elastic coating layer formed by the die coater 70 together with the die coater 70, and an ultraviolet irradiation means or an electron beam irradiation means 78 is provided.
- both ends of the shaft member 2 are pivotally supported by means not shown, and one of these ends is driven by a motor or the like.
- the compound By rotating the shaft member 2 in the length direction (arrow A) while rotating at a predetermined rotational speed by means (arrow B), the compound is applied in a spiral shape and applied over the entire length on the shaft member 2.
- the elastic coating layer 3R is formed and the shaft member 2 is rotated, the elastic coating layer 3R is irradiated with an electron beam or ultraviolet rays using the irradiation means 78 continuously with the formation of the elastic coating layer 3R.
- the shaft can be displaced in the length direction while rotating the shaft 2 with respect to the fixed die coater 70 and irradiation means 78.
- the movement of the shaft member 2 relative to the die coater 70 and the irradiation device 78 is only required to be relative.
- the force that displaced the shaft shaft 2 in the length direction is used instead.
- the die coater 70 and the irradiation means 78 may be displaced in the shaft member length direction.
- the curing of the elastic coating layer 3R by ultraviolet irradiation or electron beam irradiation which is performed continuously with the formation of the elastic coating layer 3R, is cured to such an extent that it does not sag during transport to the next process, rather than a complete curing reaction.
- the semi-cured conductive roller 3R having the semi-cured cured elastic coating layer 3R is transported to the next process, and a separate irradiation device installed there is used for ultraviolet or electron. Irradiate the line to completely cure the elastic coating layer 3R.
- the layer thickness of the elastic coating layer 3R can be controlled with high accuracy once formed by the die coater 70.
- the thickness of the elastic coating layer can be further increased and the surface property of the layer can be set to a predetermined level by scoring the surface of the layer to remove the layer.
- a blade 79 (see FIGS. 14 (a) and (b)) provided separately from the discharge head 74 can be used.
- the formation of the elastic coating layer 3R of the die coater 70 and the layer regulation of the formed elastic coating layer 3R are continuously performed while the shaft member 2 is rotated, thereby efficiently controlling the layer. It can be performed.
- the discharge head 74 in a state where the discharge of the compound is stopped may be used as a layer restricting means.
- the compound from the discharge head 74 of the die coater 70 is used.
- the discharge of the compound from the discharge head is stopped, and the discharge head in a state in which the discharge is stopped is used as a layer regulating means with respect to the shaft member 2.
- the thickness and surface smoothness of the elastic coating layer are adjusted to the desired values by relative displacement in the vertical direction (direction A or the direction opposite to A).
- an integrated blade 79A integrally attached to the discharge head 74 can be used.
- the discharge head 74 is discharged.
- the composite material is layer-regulated immediately after being discharged.
- the elastic layer 3 In order to impart conductivity to the elastic layer 3, it is cured by electron beam irradiation or ultraviolet irradiation.
- the conductive compound is added to the compound that forms the elastic body.
- an electronic conductive agent that uses either an electronic conductive agent or an ionic conductive agent as the conductive agent, a small amount of carbon-based conductive agent is added. It is preferable in that high conductivity can be obtained.
- Ketjen black or acetylene black is preferably used as the carbon-based conductive agent, but for inks such as SAF, ISAF, HAF, FEF, GPF, SRF, FT, MT and other rubber carbon blacks and oxidized carbon black. Carbon black, pyrolytic carbon black, graphite, etc. can be used.
- Examples of electronic conductive agents other than carbon-based materials include fine particles of metal oxides such as ITO, tin oxide, titanium oxide, and zinc oxide; oxides of metals such as nickel, copper, silver, and germanium; Examples include titanium whiskers and transparent whiskers such as conductive barium titanate whiskers.
- metal oxides such as ITO, tin oxide, titanium oxide, and zinc oxide
- oxides of metals such as nickel, copper, silver, and germanium
- Examples include titanium whiskers and transparent whiskers such as conductive barium titanate whiskers.
- Examples of the ionic conductive agent include tetraethyl ammonium, tetraptyl ammonium, lauryl trimethyl ammonium, dodecyl trimethyl ammonium, hexadecyl trimethyl ammonium, stearyl trimethyl ammonium.
- Perchlorate, chlorate, hydrochloride of octadecyl trimethyl ammonium such as minium, benzyl trimethyl ammonium, modified dimethyl ether ether, etc.
- the conductive agent two or more types may be used in combination. In this case, the conductivity can be stably expressed even when applied voltage changes or environmental changes occur.
- the mixture include a carbon-based conductive agent mixed with a non-carbon-based electronic conductive agent or ionic conductive agent.
- Examples of the compound curable by ultraviolet ray or electron beam irradiation constituting the elastic layer of the present invention include polyester resin, polyether resin, fluorine resin, epoxy resin, amino resin, polyamide resin, acrylic resin. Resin, acrylic urethane resin, urethane resin, alkyd resin, Examples include enol resin, melamine resin, urea resin, silicone resin, polybutyl petal resin, bull ether resin, vinyl ester resin, and one or more of these are mixed. Can be used.
- modified rosin having a specific functional group introduced into these rosins can also be used.
- composition formed from a (meth) acrylate-containing compound containing a (meth) acrylate oligomer is particularly preferable.
- Such (meth) acrylate oligomers include, for example, urethane (meth) acrylate oligomers, epoxy (meth) acrylate oligomers, ether (meth) acrylate oligomers, ester (meth) acrylates. Examples include rate oligomers, polycarbonate-based (meth) acrylate oligomers, and fluorine-based and silicone-based (meth) acrylic oligomers.
- the (meth) acrylate oligomer is composed of polyethylene glycol, polyoxypropylene glycol, polytetramethylene ether glycol, bisphenol A type epoxy resin, phenol novolac type epoxy resin, polyhydric alcohol and ⁇ It can be synthesized by reacting a compound such as a carotenoid with (meth) acrylic acid or by urethanizing a polyisocyanate compound and a (meth) acrylate compound having a hydroxyl group.
- the urethane-based (meth) acrylate oligomer can be obtained by urethane-forming a polyol, an isocyanate compound and a (meth) acrylate relay compound having a hydroxyl group.
- Examples of the epoxy-based (meth) acrylate oligomer may be any reaction product of a compound having a glycidyl group and (meth) acrylic acid, and among them, a benzene ring, a naphthalene ring, and a spiro ring.
- a reaction product of a compound having a cyclic structure such as dicyclopentadiene and tricyclodecane and having a glycidyl group and (meth) acrylic acid is preferred.
- ether (meth) acrylate oligomer, ester (meth) acrylate oligomer and polycarbonate (meth) acrylate oligomer are polyols (polyether polyol, polyester polyol and polycarbonate polyol) for each. ) And (meth) acrylic acid.
- a reactive diluent having a polymerizable double bond is blended with the compound as necessary to adjust the viscosity.
- Such reactive diluents include, for example, monofunctional, bifunctional or polyfunctional structures having a structure in which (meth) acrylic acid is bonded to a compound containing an amino acid or a hydroxyl group by an esterification reaction or an amidity reaction.
- a polymerizable compound or the like can be used.
- These diluents are preferably used in an amount of usually 10 to 200 parts by weight per 100 parts by weight of the (meth) acrylate ester.
- the compound when a compound curable by ultraviolet irradiation is used as the resin constituting the elastic layer 3, the compound contains an ultraviolet polymerization initiator for accelerating the initiation of the resin curing reaction in the formation process. .
- an ultraviolet polymerization initiator that absorbs long-wavelength ultraviolet light that can penetrate deep into the layer and that has a maximum wavelength in the ultraviolet absorption wavelength band of 400 nm or more is used.
- an ultraviolet polymerization initiator OC aminoalkylphenone, acylphosphine oxide, thixanthone, etc. can be used, and more specific examples thereof include bis (2 , 4, 6 Trimethylbenzoyl) monophenyl phosphine oxide or 2-methyl-1 [4 (methylthio) phenol] 2 morpholinopropane 1one.
- Examples of the ultraviolet polymerization initiator having such an absorption band of short wavelength include 2,2 dimethoxy 1,2 diphenylethane 1-one, 1-hydroxy-cyclohexyl roof enyl ketone. , 2-hydroxy 2-methyl 1-phenolpropane 1-one, 1- [4- (2-hydroxyethoxy) phenol] 2-hydroxy-1-2-methyl-1- 1-propane-1-one, etc. Togashi.
- an ultraviolet polymerization initiator that does not depend on the maximum wavelength in the ultraviolet absorption wavelength band can be selected. For example, those listed above choose from.
- the blending amount is preferably, for example, 0.1 to 10 parts by weight per 100 parts by weight of the (meth) ate acrylate oligomer.
- a tertiary amine such as triethylamine and triethanolamine, and triphenylphosphine are used to promote the polymerization reaction by the polymerization initiator, if necessary.
- Alkylphosphine photopolymerization accelerators such as p-thiodiglycol and other thioether photopolymerization accelerators may be added to the ultraviolet curable compound. When these compounds are added, the amount added is usually (meth) acrylate oligomer 1
- a range of 0.01 to 10 parts by weight per 00 parts by weight is preferred.
- the compound that is cured by ultraviolet rays or electron beams may contain a reaction diluent as required.
- the elastic layer 3 is used in contact with a photoreceptor or a layered blade directly or indirectly through the coating layer 4, even when the hardness is set to a low hardness, it is preferable to make the compression permanent strain as small as possible. Specifically, it is preferably 20% or less.
- the elastic layer 3 is composed of an ultraviolet curable resin or an electron beam curable resin. This is because the elastic layer 3 is coated with a paint without using a mold. It is designed to reduce the equipment cost by eliminating the drying process at that time, and for that purpose, it is irradiated with ultraviolet rays or electron beams using a solvent-free or low-solvent paint. It is necessary to be able to be cured only by this, and in this case, the paint is inevitably high in viscosity.
- the elastic layer 3 As a method of forming the elastic layer 3, it is necessary to use a method that can be applied with high precision even with such a high-viscosity paint.
- the die coating method described in detail above is used for this purpose. This is preferable.
- the coating layer 4 can be composed of various types of resin.
- the coating layer 4 is an ultraviolet curable resin containing a conductive agent and an ultraviolet polymerization initiator, or an electron containing a conductive agent. It is preferable that the coating layer 4 is formed as a method of forming the coating layer 4 by applying the coating material made of the above-described resin to the peripheral surface of the conductive roller on which the elastic layer 3 has been formed. Therefore, it is preferable to cure the coating coating layer formed by irradiating it with an electron beam or ultraviolet rays. This eliminates the need for a mold or a drying apparatus for forming the coating layer 4. be able to.
- FIG. 16 (a) is a perspective view showing a conductive roller in the middle of formation when the coating layer 4 is formed by the roll coating method
- FIG. 16 (b) is a diagram showing the conductive layer in FIG. 16 (a). It is an arrow view which shows the layer control blade seen from the axial direction of the roller.
- the roll coater 80 includes a paint roll 81 that is immersed in the paint stored in the paint tank 82, and a roll drive motor 84 that rotates the paint roll 81 (direction E).
- the conductive roller 1A on which the elastic layer 3 is formed is pivotally supported at both ends by means (not shown) and rotated at a predetermined rotational speed by means such as a motor that drives one of these ends (arrows). D), the entire conductive roller 1A is displaced in the axial direction (arrow F). Further, an ultraviolet irradiation means or an electron beam irradiation means 88 is fixedly provided along with the roll coater 80.
- the surface of the coating roll 81 is in direct contact with the circumferential surface of the conductive roller 1A that is being formed, or is close to the surface of the coating roller 81 through a predetermined gap d, and the coating roll pumped up by the circumferential surface of the coating roll 81.
- the coating material 4R can be formed on the peripheral surface of the conductive roller 1A by transferring the material onto the peripheral surface of the conductive roller 1A.
- the axis of the coating roll 81 and the axis of the conductive roller 1A are arranged so as to incline by an angle ⁇ . With this arrangement, the conductive roller 1A is rotated and simultaneously displaced in the axial direction (length direction).
- the coating layer 4R is formed on the entire peripheral surface of the conductive roller 1A on which the elastic layer 3 has been formed by applying the paint in a spiral shape.
- the conductive roller 1A can be continuously cured while rotating to form the coating layer 4.
- the equipment for forming the elastic layer 3 is simple and space-saving, The force can also be reduced.
- the coating applied layer 4R by the irradiation means 78 can be completely cured only when the coating layer 4 is a thin layer, but when the curing is insufficient only by this step, In this case, it is only necessary to provide a separate process for complete curing. In this case, the irradiation means 78 alone has completed the curing required for the transport up to the next stage. There is no.
- the roll coater 80 is provided with a doctor blade 86 that regulates the amount of paint pumped up by the coating roll 81, thereby controlling the thickness of the coating coating layer 4R formed on the conductive roller 1A with high accuracy. Furthermore, by providing gravure-like irregularities on the peripheral surface of the paint mouthpiece 81, it is possible to secure the amount of paint to be pumped and to control the amount of paint transferred to the shaft member 2 with high accuracy. it can.
- FIG. 17 is a view showing a coating roll 81 (hereinafter also referred to as a “gravure roll”) having a gravure-like unevenness on the peripheral surface
- FIG. 17 (a) is a front view
- Fig. 18 is a cross-sectional view corresponding to the cc arrow view of Fig. 17 (a).
- the gravure roll 81 is a roll made of a metal such as iron, and rotates while being supported by 8 lb at both ends in the length direction.
- the peripheral surface 81 a that pumps up the paint from the tank 82 and transports it is formed with a concave portion 81 c that becomes a gravure plate, and the paint pumped up by the peripheral surface 81 a is scraped off by the doctor blade 86.
- the dominant factors that determine the amount of paint transported in gravure mouth 81 are the number of rotations and the total volume of recess 81c, compared to the case of coating with a flat roll without recess 81c. Thus, it can be made highly accurate.
- the transfer amount when the paint held in the recess 81c is transferred to the peripheral surface of the conductive roller 1A being formed is influenced by the viscosity of the paint, but is determined mainly by the shape of the recess 81c. Therefore, also in this respect, it is possible to form the covering layer 4 having a film thickness with higher accuracy on the elastic layer 3 as compared with the flat roll.
- FIG. 18 is a schematic diagram showing an example of a gravure pattern.
- Fig. 18 (a) to (e) show the lattice type, pyramid type, diagonal line type, turtle shell type, and TF type patterns shown in this order.
- the lattice type, pyramid type, and diagonal line type are preferable.
- lattice gravure When using the plate, the density of the lattice is 10 to 300 lines / inch, and the depth is 20 to 650! ⁇ Force to set the volume of the recess to 5 to 400 cm 3 / m 2 It is preferable to ensure a highly accurate film thickness.
- the coating layer 4 is made of an ultraviolet curable resin containing a conductive and ultraviolet polymerization initiator, or an electron beam curable resin containing a conductive agent.
- an ultraviolet curable resin containing a conductive and ultraviolet polymerization initiator or an electron beam curable resin containing a conductive agent.
- the same conductive agent and ultraviolet polymerization initiator as described for the elastic layer 3 can be used.
- the conductive roller 1 having a single coating layer 4 on the outermost elastic layer 3 in the layer adjacent to the inner side of the outer layer.
- the elastic layer when the total thickness of the elastic layer is large, it is preferable to divide the elastic layer into a plurality of layers and arrange the fine particles only in the outermost layer. The adverse effect on the original properties of the inertia layer can be suppressed.
- the fine particles are preferably rubber or synthetic resin fine particles or carbon fine particles. Specifically, silicone rubber, acrylic resin, styrene resin, acrylic / styrene copolymer, fluorine resin, urethane elastomer. One or more of urethane acrylate, melamine resin, epoxy resin, phenol resin, and silica are suitable.
- the amount of fine particles added is preferably 0.1 to: LOO parts by weight, particularly 5 to 80 parts by weight, per 100 parts by weight of the resin.
- the conductive roller according to the present invention includes a charging roller, a conductive roller, and a transfer roller in image forming apparatuses such as a plain paper copying machine, a plain paper facsimile machine, a laser beam printer, a color laser beam printer, and a toner jet printer. It is preferably used as a conductive roller, an intermediate transfer roller, a toner supply roller, a cleaning roller, a belt drive roller, a paper feed roller, or the like.
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- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Electrophotography Configuration And Component (AREA)
- Rolls And Other Rotary Bodies (AREA)
- Electrostatic Charge, Transfer And Separation In Electrography (AREA)
Abstract
Description
Claims
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US11/663,626 US8663748B2 (en) | 2004-09-22 | 2005-09-21 | Method of producing a conductive roller utilizing a semi-curing step |
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JP2004275355A JP2006091303A (ja) | 2004-09-22 | 2004-09-22 | 導電性ローラの製造方法およびこの方法により製造された導電性ローラ |
JP2004-350106 | 2004-12-02 | ||
JP2004350175 | 2004-12-02 | ||
JP2004-350175 | 2004-12-02 | ||
JP2004350091A JP2006162684A (ja) | 2004-12-02 | 2004-12-02 | 導電性ローラの製造方法およびこの方法により製造された導電性ローラ |
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JP2009098519A (ja) * | 2007-10-18 | 2009-05-07 | Bridgestone Corp | 弾性ローラの製造装置および製造方法 |
JP2009098520A (ja) * | 2007-10-18 | 2009-05-07 | Bridgestone Corp | 弾性ローラの製造装置および製造方法 |
EP2101224A1 (en) | 2008-03-10 | 2009-09-16 | Ricoh Company, Ltd. | Developer carrier, developing device, image forming apparatus, process cartridge, and image forming method |
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WO2010021403A1 (ja) | 2008-08-22 | 2010-02-25 | 株式会社ブリヂストン | 帯電ローラ |
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JP5236095B1 (ja) * | 2011-04-12 | 2013-07-17 | キヤノン株式会社 | 膜、膜を有する装置、電子写真感光体、プロセスカートリッジおよび電子写真装置 |
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US8663748B2 (en) | 2014-03-04 |
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