WO2006022512A1 - Adhesif acrylique sensible a la pression a propriete antistatique - Google Patents
Adhesif acrylique sensible a la pression a propriete antistatique Download PDFInfo
- Publication number
- WO2006022512A1 WO2006022512A1 PCT/KR2005/002784 KR2005002784W WO2006022512A1 WO 2006022512 A1 WO2006022512 A1 WO 2006022512A1 KR 2005002784 W KR2005002784 W KR 2005002784W WO 2006022512 A1 WO2006022512 A1 WO 2006022512A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pressure sensitive
- sensitive adhesive
- meth
- acrylate
- acrylic
- Prior art date
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 120
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 41
- 239000004014 plasticizer Substances 0.000 claims abstract description 26
- 239000003513 alkali Substances 0.000 claims abstract description 21
- 150000002148 esters Chemical class 0.000 claims abstract description 21
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 34
- 239000010410 layer Substances 0.000 claims description 25
- -1 2-ethylhexyl Chemical group 0.000 claims description 24
- 239000000178 monomer Substances 0.000 claims description 22
- 229920006243 acrylic copolymer Polymers 0.000 claims description 20
- 238000004132 cross linking Methods 0.000 claims description 19
- 239000003431 cross linking reagent Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- 125000000524 functional group Chemical group 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000012948 isocyanate Substances 0.000 claims description 6
- 150000002513 isocyanates Chemical class 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 4
- 210000002858 crystal cell Anatomy 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000013522 chelant Substances 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 claims description 2
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 claims description 2
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229910052792 caesium Inorganic materials 0.000 claims description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 claims description 2
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 claims 2
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 claims 1
- VIBDJEWPNNCFQO-UHFFFAOYSA-N ethane-1,1,2-triol Chemical compound OCC(O)O VIBDJEWPNNCFQO-UHFFFAOYSA-N 0.000 claims 1
- 235000019256 formaldehyde Nutrition 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- UOMUPDCRXJLVGR-UHFFFAOYSA-N propane-1,2,2-triol Chemical compound CC(O)(O)CO UOMUPDCRXJLVGR-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000005611 electricity Effects 0.000 description 13
- 230000003068 static effect Effects 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 229920006223 adhesive resin Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 3
- 229920002284 Cellulose triacetate Polymers 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 230000003828 downregulation Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 2
- 230000003827 upregulation Effects 0.000 description 2
- 229940117958 vinyl acetate Drugs 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 1
- IVIDDMGBRCPGLJ-UHFFFAOYSA-N 2,3-bis(oxiran-2-ylmethoxy)propan-1-ol Chemical compound C1OC1COC(CO)COCC1CO1 IVIDDMGBRCPGLJ-UHFFFAOYSA-N 0.000 description 1
- MECNWXGGNCJFQJ-UHFFFAOYSA-N 3-piperidin-1-ylpropane-1,2-diol Chemical compound OCC(O)CN1CCCCC1 MECNWXGGNCJFQJ-UHFFFAOYSA-N 0.000 description 1
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical group CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 102000001708 Protein Isoforms Human genes 0.000 description 1
- 108010029485 Protein Isoforms Proteins 0.000 description 1
- FYAMXEPQQLNQDM-UHFFFAOYSA-N Tris(1-aziridinyl)phosphine oxide Chemical compound C1CN1P(N1CC1)(=O)N1CC1 FYAMXEPQQLNQDM-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000011278 co-treatment Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001268 conjugating effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- GAURFLBIDLSLQU-UHFFFAOYSA-N diethoxy(methyl)silicon Chemical compound CCO[Si](C)OCC GAURFLBIDLSLQU-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002497 iodine compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- IUCJMVBFZDHPDX-UHFFFAOYSA-N tretamine Chemical compound C1CN1C1=NC(N2CC2)=NC(N2CC2)=N1 IUCJMVBFZDHPDX-UHFFFAOYSA-N 0.000 description 1
- 229950001353 tretamine Drugs 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
- C08L2666/22—Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/28—Adhesive materials or arrangements
Definitions
- the present invention relates to an acrylic pressure sensitive adhesive composition having antistatic property, more precisely, an acrylic pressure sensitive adhesive resin composition having excellent durability and antistatic property as well.
- Acrylic pressure sensitive adhesive compositions have been widely used in industry for the production of industrial sheet, optical pressure sensitive adhesive product, and pressure sensitive adhesive for electrical components, etc, and are applied to other industrial fields with the same conception.
- LCD liquid crystal display
- Polarizer includes multilayer such as a row of iodine compounds or dichroic polarizing material, protective film, such as triacetyl cellulose (TAC), to protect polarizing element on both sides, pressure sensitive adhesive layer, and releasing film, etc.
- protective film such as triacetyl cellulose (TAC)
- the production of LCD includes the process of adhering polarizer, during which static electricity is generated after peeling releasing film out of pressure sensitive adhesive layer.
- the generated static electricity affects orientation of liquid crystal in LCD, resulting in defectives.
- the present invention relates to an acrylic pressure sensitive adhesive composition having antistatic property, more precisely, an acrylic pressure sensitive adhesive composition containing ester plasticizer having at least one of ether bonds and alkali metallic salt.
- the present invention provides an acrylic pressure sensitive adhesive composition comprising
- Rl and R2 are independently C1-C20 alkyl or aryl, R3 is H or methyl, and n is an integer of 2-20.
- the acrylic copolymer of a) is characteristically prepared by the copolymerization of 90-99.9 weight part of (meth)acrylic acid ester monomer having Cl -C 12 alkyl and 0.1-10 weight part of vinyl and/or acrylic monomer having a functional group capable of crosslinking.
- the present invention also provides a polarizer containing the above acrylic pressure sensitive adhesive composition as a pressure sensitive adhesive layer on one side or both sides of polarizing film.
- the polarizer can additionally contain one or more layers selected from a group consisting of protective layer, reflecting layer, phase retardation film, compensation film for wide view angle and brightness enhancing film.
- the present invention further provides a liquid crystal display containing liquid crystal panel in which above polarizer is adhered on one side or both sides of liquid crystal cell.
- the present invention endowed enhanced antistatic property to an acrylic pressure sensitive adhesive by adding ester plasticizer having one or more ether bonds and alkali metallic salt together to the pressure sensitive adhesive.
- ester plasticizer having one or more ether bonds and alkali metallic salt is a key factor to enhance compatibility, durability, and antistatic property of a pressure sensitive adhesive.
- (meth)acrylic acid ester monomer having C1-C12 alkyl is included by 90-99.9 weight part for 100 weight part of the acrylic copolymer.
- the content is lower than 90 weight part, the initial peel strength is decreased, and when the content is higher than 99.9 weight part, cohesion becomes dropped, resulting in the low durability.
- Cl -C 12 alkyl ester can be used as a (meth)acrylic acid ester monomer having Cl -C 12 alkyl.
- C2-C8 alkyl ester is preferred.
- alkyl of the alkyl(meth)acrylate is in the form of long chain, cohesion of the pressure sensitive adhesive drops.
- C1-C12 alkyl is preferably used, and C2-C8 alkyl is more preferred.
- the (meth)acrylic acid ester monomer having Cl -C 12 alkyl is exemplified by butyl(meth)acrylate, 2-ethylhexyl(meth)acrylate, ethyl(meth)acrylate, methyl(meth)acrylate, n- propyl(meth)acrylate, isopropyl(meth)acrylate, t-butyl(meth)acrylate, pentyl(meth)acrylate, n-octyl(meth)acrylate, isooctylCmettyacrylate, or isononyl(meth)acrylate, etc, and these can be used independently or jointly.
- copolymer monomer can be additionally included in acrylic copolymer to regulate the glass transition temperature of a pressure sensitive adhesive or to endow other functional properties thereto.
- monomers such as acrylonitrille, (meth)acrylamide, styrene, methylstyrene, vinyltoluene, glycidyl(meth)acrylate or vinylacetate are preferably used.
- the preferable content of vinyl monomer and acrylic momoner of a) or the mixture of them having a functional group capable of crosslinking is 0.1-10 weight part.
- the content of a monomer having a functional group capable of crosslinking is less than 0.1 weight part, the cohesion is easily broken under high temperature or high humidity, resulting in the lowering effect on peel strength.
- compatibility is remarkably decreased, causing surface migration, fluidity is reduced and cohesion is increased, losing stress relaxation.
- the monomer having a functional group capable of crosslinking is exemplified by monomers containing hydroxy such as 2-hydroxyethyl(meth)acrylate, 2-hyd ⁇ oxypropyl(meth)acrylate, 4-hydroxybutyl(meth)acrylate, 2-hydroxyethyleneglycol(meth)acrylate, 2-hydroxypropyleneglycol(meth)acrylate, and monomers containing carboxylic acid such as acrylic acid, methacrylic acid, acrylic acid dimer, itaconic acid, maleic acid, and maleic anhydride, etc, but not always limited thereto. These monomers can be used independently or jointly.
- monomers containing hydroxy such as 2-hydroxyethyl(meth)acrylate, 2-hyd ⁇ oxypropyl(meth)acrylate, 4-hydroxybutyl(meth)acrylate, 2-hydroxyethyleneglycol(meth)acrylate, 2-hydroxypropyleneglycol(meth)acrylate, and monomers containing carboxylic acid such as acrylic acid, methacryl
- the viscoelastic property of a pressure sensitive adhesive depends on molecular weight of polymer chain, distribution of molecular weight, or abundant numbers of molecular structures, and in particular it might be determined by molecular weight.
- the preferable molecular weight of acrylic copolymer used in the present invention is 800,000-2,000,000 and the copolymer of the invention can be prepared by the conventional radical copolymerization.
- the method for the production of acrylic copolymer of the present invention is not limited to a specific one but solution polymerization, photo-polymerization, bulk poly ⁇ merization, suspension polymerization, and emulsion polymerization are preferred and in particular solution polymerization is more preferred. It is also preferred to set the temperature between 50-140°C, and to add an initiator after monomers are evenly mixed.
- ester plasticizer having one or more ether bonds, represented by formula 1, in the above b) forms a complex together with alkali metallic salt of the above c), resulting in ionic conductivity of the pressure sensitive adhesive.
- the ester plasticizer is optically transparent and has excellent compatibility and no surface migration.
- ester plasticizer having one or more ether bonds is represented by the following formula 1.
- Rl and R2 are independently C1-C20 alkyl or aryl, R3 is H or methyl, and n is an integer of 2-20.
- the preferable content of the ester plasticizer having one or more ether bonds, presented by formula 1, is 0.01-20 weight part for 100 weight part of the acrylic copolymer of the above a).
- the content of ester plasticizer having one or more ether bonds is less than 0.01 weight part, it cannot properly form a complex with alkali metallic salt, resulting in the decrease of antistatic property.
- the content of the plasticizer is over 20 weight part, cohesion of a pressure sensitive adhesive is reduced, resulting in the decrease of durability.
- the ester plasticizer having one or more ether bonds, represented by formula 1, is exemplified by diethylene glycol di-2-ethylhexonate, tetraethylene glycol di- 2-ethylhexonate, polyethylene glycol di-2-ethylhexonate, triethylene glycol di- ethylbutylate, polyethylene glycol diethylbutylate, polypropylene glycol di- ethylhexonate, triethylene glycol dibenzonate, polyethylene glycol dibenzonate, polypropylene glycol dibenzonate, polyethylene glycol-2-ethylhexonate benzonate, etc, and these plasticizers can be used independently or jointly.
- the alkali metallic salt of the above c) is also involved in antistatic property by forming a complex together with ether bonds of ester plasticizer of the above b).
- the addition of alkali metallic salt itself endows antistatic property to an acrylic pressure sensitive adhesive, and the co-treatment with ester plasticizer having one or more ether bonds enhances ionic conductivity.
- alkali metallic salt it is preferred for the alkali metallic salt to be included by 0.001-7 weight part to
- the alkali metallic salt is composed of cations and anions.
- the alkali metallic salt is composed of a kind of ionic combination made from a cation selected from a group consisting of lithium, sodium, potassium, magnesium, calcium, barium, and cesium and an anion selected from a group consisting of chloride, bromide, iodide, perclorate, trifluoromethanesulfonate, hexafluorophosphate, tetraborate, and carbonate, and is used independently or jointly.
- the multi ⁇ functional crosslinking agent of the above d) increases cohesion of the pressure sensitive adhesive by reacting with carboxyl and hydroxy.
- the preferable content of the crosslinking agent is 0.01-10 weight part for 100 weight part of acrylic copolymer of a).
- the multifunctional crosslinking agent can be selected among isocyanate, epoxy, aziridine, metal chelate crosslinking agents, etc, and in particular isocyanate crosslinking agent is preferred.
- Isocyanate crosslinking agent is exemplified by tolylene diisocyanate, xylene diisocyanate, diphenylmethane diisocyanate, hex- amethylene diisocyanate, isoform diisocyanate, tetramethyl xylene diisocyanate, naphthalene diisocyanate, and their reactants with polyol like trimethylolpropane, etc.
- the epoxy crosslinking agent is exemplified by ethyleneglycol diglycidylether, triglycidylether, trimethylolpropane triglycidylether, N,N,N'N'-tetraglycidylethylenediamine, glycerine diglycidylether, etc.
- the aziridine crosslinking agent is exemplified by
- a metal chelate crosslinking agent compounds prepared by coordination of multivalent metal such as Al, Fe, Zn, Sn, Ti, Sb, Mg, and V with acethylacetone or ethyl acetoacetate can be used.
- a preparation method of the pressure sensitive adhesive composition of the present invention is not limited to a specific one but in general, it is produced by mixing an acrylic copolymer and a crosslinking agent.
- the proper crosslinking density of the acrylic pressure sensitive adhesive composition of the present invention is 5-95%, for the optimum substantial balance.
- the crosslinking density is calculated by the conventional quantification method of gel content in acrylic pressure sensitive adhesive, which calculates the parts forming a crosslinking structure dissoluble in a solvent by weight%.
- the crosslinking density of the pressure sensitive adhesive is under 5%, cohesion of the pressure sensitive adhesive is reduced, causing weakness of durability, to form bubbles or induce edge lifting.
- the crosslinking density is over 95%, durability is remarkably reduced.
- the pressure sensitive adhesive composition of the present invention can ad ⁇ ditionally include silane coupling agent, which is able to enhance thermal/moisture resistance by improving pressure sensitive adhesive stability on the glass substrate.
- silane coupling agent plays a role in the increase of peel strength when it is left for a long time under high temperature and high humidity.
- the preferable content of silane coupling agent is 0.005-5 weight part for 100 weight part of an acrylic copolymer.
- the silane coupling agent is exemplified by ⁇ -glycydoxypropyl trimethoxysilane, ⁇ - glycydoxypropyl methyldiethoxysilane, ⁇ -glycydoxypropyl triethoxysilane, 3-mercaptopropyl trimethoxysilane, vinyl trimethoxysilane, vinyl triethoxysilane, ⁇ - methacryloxypropyl trimethoxysilane, ⁇ -methacryloxypropyl triethoxysilane, ⁇ - aminopropyl trimethoxysilane, ⁇ -aminopropyl triethoxysilane, 3-isocyanatepropyl tri ⁇ ethoxysilane, ⁇ -acetoacetatepropyl trimethoxysilane, etc.
- These silane coupling agents can be used independently or jointly.
- a pressure sensitive adhesive resin can be additionally added to the tackifier of the present invention, and the content thereof is determined in the range of 1-100 weight part for 100 weight part of an acrylic copolymer. At this time, when the tackifier is over-treated, compatibility and cohesion of a pressure sensitive adhesive decrease, so the content of the pressure sensitive adhesive resin has to be properly regulated.
- the tackifier is exemplified by (hydrogenated)hydrocarbon resin,
- acrylic low molecular weight substances epoxy resins and hardners can be additionally included.
- UV stabilizers, antioxidants, coloring agents, reinforcing agents, fillers, antifoaming agents, surfactants, plasticizer, etc, can also be added.
- the present invention further provides a polarizer containing the acrylic pressure sensitive adhesive composition as a pressure sensitive adhesive layer of polarizing film.
- the polarizer of the present invention has a pressure sensitive adhesive layer formed from the pressure sensitive adhesive composition of the invention on one side or both sides of the polarizing film.
- Polarizing film or polarizing device forming polarizer is not limited to a specific one.
- the polarizing film by elongation by adding a polarizing component such as iodine or dichroic dye onto polyvinyl alcohol resin film, and there is no limitation in thickness of polarizing film, which means conventional thickness of film is accepted.
- a polyvinyl alcohol resin polyvinyl alcohol, polyvinyl formal, polyvinyl acetal and ethylene, saponified vinyl acetate copolymer, etc can be used.
- protective films are laminated to form a multi ⁇ layer film, and the protective films are cellulose film such as triacetyl cellulose, etc, polyester film such as polycarbonate film, polyethylene terephthalate, etc, polyether sulphone film, polyolefin film including those having the structure of polyethylene, polypropylene, cyclo or norbornene, and ethylene propylene copolymer.
- the thickness of such protective films is not fixed and conventional film thickness is accepted.
- a method for forming pressure sensitive adhesive layer on polarizing film is not limited, either, but generally, a method comprising the steps of coating the pressure sensitive adhesive directly on the surface of the polarizing film with Bar Coater and then drying thereof, or a method comprising the steps of coating the pressure sensitive adhesive on the surface of dissecting substrate, drying, transfering of the pressure sensitive adhesive layer formed on the surface of the dissecting substrate onto the surface of polarizing film, and aging is applicable.
- the polarizer of the present invention can include one or more additional layers providing supplementary functions, which might be protective layer, reflecting layer, phase retardation film, compensation film for wide view angle and brightness enhancing film.
- the polarizer loaded with the pressure sensitive adhesive of the present invention can be applied to every LCD generally used, and liquid crystal panel is not limited. It is preferred in the present invention to construct LCD including liquid crystal panel prepared by conjugating the pressure sensitive adhesive polarizer to one side or both sides of liquid crystal cell.
- the acrylic pressure sensitive adhesive resin composition of the present invention can be widely used without limitation, for example for industrial sheet in particular reflective sheet, structural pressure sensitive adhesive sheet, photographic pressure sensitive adhesive sheet, lane marking pressure sensitive adhesive sheet, optical pressure sensitive adhesive product, pressure sensitive adhesive for electronic components, etc.
- the pressure sensitive adhesive composition can also be applied to the equal operating field such as the production of multi-layer laminate products, for example general industrial pressure sensitive adhesive sheet products, medical patches, heat activated pressure sensitive pressure sensitive adhesives, etc.
- the pressure sensitive adhesive composition of the present invention has excellent long-term durability and improved antistatic property by containing ester plasticizer having one or more ether bonds and alkali metallic salt. Best Mode for Carrying Out the Invention
- a monomer mixture composed of 98.3 weight part of n-butylacrylate (BA), 0.5 weight part of acrylic acid (AA), and 1.2 weight part of hydroxyethylmethacrylate (2-HEMA) is put into a 1 L reactor equipped with cooling system for the reflux of nitrogen gas and the regulation of temperature, to which 100 weight part of ethyl acetate (EAc) was added as a solvent.
- EAc ethyl acetate
- nitrogen gas was purged for 1 hour, during which the temperature was kept at 62°C.
- AIBN azobisisobutyronitrile
- the mixture was reacted for 8 hours, resulting in an acrylic copolymer.
- LiClO 4 Lithium perchlorate
- LiSO CF Lithiumtrifluoromethanesulfonate
- Example 1 -4 of the present invention were proved to have excellent durability and antistatic property, compared with those of Comparative Examples 1-7.
- the acrylic pressure sensitive adhesive composition of the present invention shows excellency in major characteristics including durability and antistatic property.
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Nonlinear Science (AREA)
- Organic Chemistry (AREA)
- Mathematical Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Polarising Elements (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE602005011457T DE602005011457D1 (de) | 2004-08-24 | 2005-08-24 | Druckempfindlicher acrylklebstoff mit antistatischer eigenschaft |
CN2005800169409A CN1957050B (zh) | 2004-08-24 | 2005-08-24 | 具有抗静电性能的丙烯酸压敏粘合剂 |
EP05781093A EP1781748B1 (fr) | 2004-08-24 | 2005-08-24 | Adhesif acrylique sensible a la pression a propriete antistatique |
JP2007513080A JP4549389B2 (ja) | 2004-08-24 | 2005-08-24 | 帯電防止性能を有するアクリル系粘着剤組成物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020040066880A KR100694445B1 (ko) | 2004-08-24 | 2004-08-24 | 대전 방지 성능을 갖는 아크릴계 점착제 조성물 |
KR10-2004-0066880 | 2004-08-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006022512A1 true WO2006022512A1 (fr) | 2006-03-02 |
Family
ID=35943561
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2005/002784 WO2006022512A1 (fr) | 2004-08-24 | 2005-08-24 | Adhesif acrylique sensible a la pression a propriete antistatique |
Country Status (9)
Country | Link |
---|---|
US (1) | US7767752B2 (fr) |
EP (1) | EP1781748B1 (fr) |
JP (1) | JP4549389B2 (fr) |
KR (1) | KR100694445B1 (fr) |
CN (1) | CN1957050B (fr) |
AT (1) | ATE416240T1 (fr) |
DE (1) | DE602005011457D1 (fr) |
TW (1) | TWI274779B (fr) |
WO (1) | WO2006022512A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010509438A (ja) * | 2006-11-07 | 2010-03-25 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 帯電防止ホットメルト接着剤 |
JP2010525098A (ja) * | 2007-04-19 | 2010-07-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
US9328264B2 (en) | 2009-02-27 | 2016-05-03 | Nitto Denko Corporation | Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, and pressure-sensitive adhesive sheet |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005314579A (ja) * | 2004-04-30 | 2005-11-10 | Nitto Denko Corp | 粘着剤組成物、および粘着シート類 |
JP4562070B2 (ja) * | 2004-05-14 | 2010-10-13 | 日東電工株式会社 | 粘着剤組成物、粘着シート類、および表面保護フィルム |
JP4717943B2 (ja) * | 2004-09-16 | 2011-07-06 | 日東電工株式会社 | 粘着剤組成物、粘着シート類、および表面保護フィルム |
JP4917267B2 (ja) * | 2004-09-16 | 2012-04-18 | 日東電工株式会社 | 粘着剤組成物、粘着シート類、および表面保護フィルム |
JP4531628B2 (ja) * | 2004-09-16 | 2010-08-25 | 日東電工株式会社 | 粘着剤組成物、粘着シート類、および表面保護フィルム |
KR100784991B1 (ko) * | 2005-06-10 | 2007-12-11 | 주식회사 엘지화학 | 아크릴계 점착제 조성물 |
JP5259940B2 (ja) * | 2005-09-05 | 2013-08-07 | 日東電工株式会社 | 粘着剤組成物、粘着シートおよび表面保護フィルム |
GB0607744D0 (en) * | 2006-04-20 | 2006-05-31 | Pilkington Plc | Head-up display |
JP2009535440A (ja) * | 2006-04-28 | 2009-10-01 | ビーエーエスエフ ソシエタス・ヨーロピア | 2−エチルヘキシルアクリレートおよびヒドロキシブチル(メタ)アクリレートを含有する感圧接着剤 |
JP4814000B2 (ja) * | 2006-07-26 | 2011-11-09 | リンテック株式会社 | 光学機能性フィルム貼合用粘着剤、光学機能性フィルム及びその製造方法 |
EP2139971A4 (fr) * | 2007-04-13 | 2011-09-21 | 3M Innovative Properties Co | Adhésif auto-collant transparent antistatique |
KR101061939B1 (ko) * | 2007-12-12 | 2011-09-05 | 주식회사 엘지화학 | 편광판용 아크릴계 점착제 조성물 |
KR101424015B1 (ko) * | 2008-03-19 | 2014-07-31 | 동우 화인켐 주식회사 | 점착제 조성물의 대전방지성을 향상시키는 방법, 대전방지성 점착제 조성물 및 이의 제조방법 |
KR101524612B1 (ko) * | 2008-08-06 | 2015-06-01 | 동우 화인켐 주식회사 | 대전방지성 점착제 조성물 및 이를 이용한 편광판 |
JP4496262B2 (ja) * | 2008-10-20 | 2010-07-07 | 三光化学工業株式会社 | 制電性組成物、それを用いた成形品、塗料、制電性被覆物、粘着剤およびその製造方法 |
CN101768415B (zh) * | 2008-12-30 | 2013-03-27 | 第一毛织株式会社 | 抗静电粘合剂组合物、粘合膜及其制备方法 |
KR101072767B1 (ko) * | 2009-04-28 | 2011-10-11 | 율촌화학 주식회사 | 무기재 양면점착필름 |
WO2010143643A1 (fr) * | 2009-06-09 | 2010-12-16 | 日本合成化学工業株式会社 | Composition d'adhésif autocollant, adhésif autocollant, adhésif autocollant pour élément optique et élément optique comprenant une couche d'adhésif autocollant obtenue à l'aide de celle-ci |
US9816011B2 (en) | 2010-02-26 | 2017-11-14 | Lg Chem, Ltd. | Pressure sensitive adhesive composition |
JP5235021B2 (ja) * | 2010-04-26 | 2013-07-10 | 日東電工株式会社 | 粘着剤組成物、粘着シート類、および表面保護フィルム |
JP5470217B2 (ja) * | 2010-10-15 | 2014-04-16 | 日東電工株式会社 | 光学用水分散型粘着剤、光学用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP5583001B2 (ja) * | 2010-12-24 | 2014-09-03 | 綜研化学株式会社 | 光学フィルム用粘着剤組成物および粘着型光学フィルム |
TWI490299B (zh) * | 2011-05-05 | 2015-07-01 | Eternal Materials Co Ltd | 丙烯酸系黏著組合物及其用途 |
JP2013008019A (ja) * | 2011-05-26 | 2013-01-10 | Nitto Denko Corp | 粘着剤層付偏光フィルムおよび画像表示装置 |
JP5912833B2 (ja) * | 2011-05-26 | 2016-04-27 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付光学フィルムおよび画像表示装置 |
JP5572589B2 (ja) * | 2011-05-26 | 2014-08-13 | 日東電工株式会社 | 粘着剤層付偏光板及び画像表示装置 |
JP2012247574A (ja) * | 2011-05-26 | 2012-12-13 | Nitto Denko Corp | 粘着型偏光板および画像表示装置 |
JP5860673B2 (ja) | 2011-11-07 | 2016-02-16 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、粘着剤層付偏光板および画像形成装置 |
KR101367177B1 (ko) * | 2011-11-08 | 2014-02-27 | 주식회사 엘지화학 | 대전방지성 보호필름용 점착제 조성물 및 이의 제조방법 |
JP5875106B2 (ja) | 2011-11-24 | 2016-03-02 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、粘着剤層付偏光板および画像形成装置 |
KR101435252B1 (ko) * | 2012-03-30 | 2014-08-28 | 주식회사 엘지화학 | 점착 테이프 |
JP5425258B2 (ja) | 2012-04-16 | 2014-02-26 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルムおよび画像形成装置 |
JP6423574B2 (ja) * | 2012-08-31 | 2018-11-14 | 日東電工株式会社 | 粘着剤層付偏光フィルムおよび画像表示装置 |
WO2014097719A1 (fr) * | 2012-12-19 | 2014-06-26 | 昭和電工株式会社 | Composition adhésive pour film optique et film de protection de surface |
JP6346413B2 (ja) | 2013-06-10 | 2018-06-20 | 日東電工株式会社 | セパレータ付き粘着剤層、その製造方法およびセパレータ付きの粘着剤層付き光学フィルム |
CN104854206B (zh) * | 2013-11-29 | 2019-04-09 | Dic株式会社 | 光固化性光学粘接剂组合物、其固化物、以及液晶显示装置 |
CN103788886B (zh) * | 2014-02-17 | 2015-11-18 | 广东可逸智膜科技有限公司 | Ogs制程用抗静电耐酸保护膜 |
JP6384985B2 (ja) * | 2014-04-17 | 2018-09-05 | 日東電工株式会社 | 偏光板、機能性積層体、液晶表示装置、及び、偏光板の製造方法 |
KR101866957B1 (ko) * | 2014-04-24 | 2018-06-12 | 동우 화인켐 주식회사 | 대전 방지성 점착제 조성물 및 이를 이용하여 제조되는 편광판 |
WO2015163643A1 (fr) * | 2014-04-24 | 2015-10-29 | 동우화인켐 주식회사 | Composition adhésive antistatique et plaque polarisante fabriquée à l'aide de celle-ci |
WO2016072197A1 (fr) * | 2014-11-04 | 2016-05-12 | 綜研化学株式会社 | Composition adhésive pour plaques polarisantes et plaque polarisante comprenant une couche adhésive |
DK3253341T3 (en) | 2015-02-02 | 2019-03-25 | Coloplast As | STOMA DEVICE |
JP5802851B2 (ja) * | 2015-02-04 | 2015-11-04 | 三光化学工業株式会社 | 制電性粘着剤組成物の製造方法 |
JP6125063B2 (ja) | 2015-02-13 | 2017-05-10 | 日東電工株式会社 | 粘着剤層付偏光フィルム、その製造方法並びに画像表示装置およびその連続製造方法 |
CA2982012C (fr) | 2015-04-10 | 2024-03-05 | Coloplast A/S | Dispositif de stomie |
KR101911995B1 (ko) * | 2015-08-20 | 2018-10-25 | 동우 화인켐 주식회사 | 점착제 조성물 및 이를 포함하는 편광판 |
JP6414983B2 (ja) * | 2015-09-10 | 2018-10-31 | 藤森工業株式会社 | 表面保護フィルム、及びそれが貼合された光学部品 |
JP2016028288A (ja) * | 2015-09-18 | 2016-02-25 | 日東電工株式会社 | 粘着型偏光板および画像表示装置 |
JP6208728B2 (ja) | 2015-09-30 | 2017-10-04 | 日東電工株式会社 | セパレータ付き粘着剤層、セパレータ付き粘着剤層付きの光学フィルム、画像表示装置及びその製造方法 |
EP3390504A2 (fr) * | 2015-12-18 | 2018-10-24 | Rohm and Haas Company | Composition acrylique |
JP6392798B2 (ja) * | 2016-02-16 | 2018-09-19 | 藤森工業株式会社 | 表面保護フィルム、及びそれが貼合された光学部品 |
JP6392799B2 (ja) * | 2016-02-16 | 2018-09-19 | 藤森工業株式会社 | 表面保護フィルム、及びそれが貼合された光学部品 |
JP6382873B2 (ja) * | 2016-03-11 | 2018-08-29 | 住友化学株式会社 | 粘着剤層付光学部材 |
JP6580540B2 (ja) * | 2016-09-28 | 2019-09-25 | 藤森工業株式会社 | 粘着剤組成物及び粘着フィルム |
JPWO2018155032A1 (ja) * | 2017-02-27 | 2019-12-19 | 昭和電工株式会社 | 硬化型水系樹脂エマルジョン組成物 |
JP6782664B2 (ja) * | 2017-04-28 | 2020-11-11 | 藤森工業株式会社 | 粘着剤組成物、及び表面保護フィルム |
JP6891036B2 (ja) * | 2017-04-28 | 2021-06-18 | 藤森工業株式会社 | 粘着剤組成物、及び粘着フィルム |
KR102184387B1 (ko) * | 2017-08-11 | 2020-11-30 | 주식회사 엘지화학 | 점착제 조성물 |
JP2018124578A (ja) * | 2018-04-27 | 2018-08-09 | 住友化学株式会社 | 粘着剤層付光学部材 |
JP7105633B2 (ja) * | 2018-06-28 | 2022-07-25 | 日東電工株式会社 | 粘着剤組成物、粘着シート、及び、光学部材 |
CN110746903B (zh) * | 2019-10-25 | 2021-08-06 | 江苏国胶新材料有限公司 | 一种汽车保护膜用水性丙烯酸酯压敏胶及其制备方法 |
US11827723B1 (en) | 2020-07-27 | 2023-11-28 | Dane K. Parker | Method for the diimide hydrogenation of emulsified unsaturated polymers |
JP7328387B2 (ja) * | 2020-10-19 | 2023-08-16 | 藤森工業株式会社 | 粘着フィルム、それが用いられた表面保護フィルム、及び光学フィルム |
CN113528042B (zh) * | 2021-08-02 | 2024-01-05 | 合肥乐凯科技产业有限公司 | 一种聚酯薄膜保护膜 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997031077A1 (fr) * | 1996-02-26 | 1997-08-28 | Minnesota Mining And Manufacturing Company | Adhesifs adherant sous pression |
JPH10279907A (ja) * | 1997-04-09 | 1998-10-20 | Soken Chem & Eng Co Ltd | 偏光板用粘着剤組成物および偏光板 |
WO2000024839A1 (fr) * | 1998-10-27 | 2000-05-04 | Minnesota Mining And Manufacturing Company | Composition adhesive antistatique sensible a la pression |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1166682A (en) * | 1965-12-23 | 1969-10-08 | Johnson & Johnson | Pressure-Sensitive Acrylate Adhesives |
US4033918A (en) * | 1972-03-24 | 1977-07-05 | Beiersdorf Aktiengesellschaft | Water removable pressure sensitive adhesive |
US4340524A (en) * | 1980-06-30 | 1982-07-20 | Union Carbide Corporation | Water-resistant latex sealants |
US4767813A (en) * | 1987-03-23 | 1988-08-30 | Polysar Financial Services S.A. | High solids PSA Compounds |
JP2955089B2 (ja) | 1991-11-19 | 1999-10-04 | 日東電工株式会社 | 静電気発生の少ない表面保護粘着テープ又はシート |
JP3190743B2 (ja) | 1992-10-14 | 2001-07-23 | 日東電工株式会社 | 粘着テープまたはシート |
US5508107A (en) * | 1993-07-28 | 1996-04-16 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive tapes for electronics applications |
WO1995030720A1 (fr) * | 1994-05-06 | 1995-11-16 | Minnesota Mining And Manufacturing Company | Bande adhesive autocollante, antistatique resistant a de hautes temperatures |
JPH08155040A (ja) * | 1994-12-08 | 1996-06-18 | Nitto Denko Corp | 導電性粘着剤およびこれを用いてなる電極パッド |
JP4256481B2 (ja) * | 1997-02-14 | 2009-04-22 | リンテック株式会社 | 粘着剤組成物およびその利用方法 |
JP2004131571A (ja) * | 2002-10-09 | 2004-04-30 | Toyo Tire & Rubber Co Ltd | タイヤ用導電性ゴム糊及び空気入りタイヤ |
-
2004
- 2004-08-24 KR KR1020040066880A patent/KR100694445B1/ko active IP Right Grant
-
2005
- 2005-08-23 US US11/209,042 patent/US7767752B2/en active Active
- 2005-08-24 CN CN2005800169409A patent/CN1957050B/zh not_active Expired - Fee Related
- 2005-08-24 JP JP2007513080A patent/JP4549389B2/ja active Active
- 2005-08-24 DE DE602005011457T patent/DE602005011457D1/de active Active
- 2005-08-24 EP EP05781093A patent/EP1781748B1/fr active Active
- 2005-08-24 WO PCT/KR2005/002784 patent/WO2006022512A1/fr active Application Filing
- 2005-08-24 TW TW094128850A patent/TWI274779B/zh active
- 2005-08-24 AT AT05781093T patent/ATE416240T1/de not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997031077A1 (fr) * | 1996-02-26 | 1997-08-28 | Minnesota Mining And Manufacturing Company | Adhesifs adherant sous pression |
JPH10279907A (ja) * | 1997-04-09 | 1998-10-20 | Soken Chem & Eng Co Ltd | 偏光板用粘着剤組成物および偏光板 |
WO2000024839A1 (fr) * | 1998-10-27 | 2000-05-04 | Minnesota Mining And Manufacturing Company | Composition adhesive antistatique sensible a la pression |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010509438A (ja) * | 2006-11-07 | 2010-03-25 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 帯電防止ホットメルト接着剤 |
JP2010525098A (ja) * | 2007-04-19 | 2010-07-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
JP2015014011A (ja) * | 2007-04-19 | 2015-01-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
US9499725B2 (en) | 2007-04-19 | 2016-11-22 | Lg Chem, Ltd. | Acrylic pressure-sensitive adhesive compositions |
US9328264B2 (en) | 2009-02-27 | 2016-05-03 | Nitto Denko Corporation | Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, and pressure-sensitive adhesive sheet |
Also Published As
Publication number | Publication date |
---|---|
CN1957050B (zh) | 2010-06-09 |
JP4549389B2 (ja) | 2010-09-22 |
JP2007536427A (ja) | 2007-12-13 |
CN1957050A (zh) | 2007-05-02 |
EP1781748B1 (fr) | 2008-12-03 |
DE602005011457D1 (de) | 2009-01-15 |
KR20060018495A (ko) | 2006-03-02 |
TWI274779B (en) | 2007-03-01 |
US7767752B2 (en) | 2010-08-03 |
ATE416240T1 (de) | 2008-12-15 |
KR100694445B1 (ko) | 2007-03-12 |
US20060045990A1 (en) | 2006-03-02 |
EP1781748A1 (fr) | 2007-05-09 |
EP1781748A4 (fr) | 2007-10-03 |
TW200613494A (en) | 2006-05-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7767752B2 (en) | Acrylic pressure sensitive adhesive having antistatic property | |
US7750075B2 (en) | Acrylic pressure sensitive adhesive with good antistatic property | |
US7696278B2 (en) | Acrylic pressure sensitive adhesive compositions | |
EP1776433B1 (fr) | Adhésif sensible à la pression acrylique | |
EP2231807B1 (fr) | Composition d'adhésif sensible à la pression, film protecteur, polariseur et dispositif d'affichage à cristaux liquides la comprenant | |
US8318852B2 (en) | Acrylic pressure-sensitive adhesive composition for polarizing film | |
EP1737921B1 (fr) | Composition acrylique adhesive autocollante pour film de polarisation | |
KR100812507B1 (ko) | 아크릴계 점착제 조성물 | |
US20060279922A1 (en) | Acrylic pressure sensitive adhesive compositions | |
EP2044162A1 (fr) | Composition autoadhésive acrylique à compensation optique, plaque polarisante et dispositif d'affichage à cristaux liquides comprenant ladite plaque | |
CN101679826A (zh) | 光学补偿的丙烯酸压敏粘合剂组合物以及含有该组合物的偏振片和液晶显示器装置 | |
KR20070043558A (ko) | 점착제 조성물 | |
KR100980187B1 (ko) | 편광판 | |
KR20100058429A (ko) | 아크릴계 점착제 조성물 | |
KR20090110812A (ko) | 아크릴계 점착제 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 6399/DELNP/2006 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005781093 Country of ref document: EP Ref document number: 2007513080 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 200580016940.9 Country of ref document: CN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 2005781093 Country of ref document: EP |